EP1320877A2 - Siliziumoxydstrukturierung mittels cvd-photolacks - Google Patents

Siliziumoxydstrukturierung mittels cvd-photolacks

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Publication number
EP1320877A2
EP1320877A2 EP01964510A EP01964510A EP1320877A2 EP 1320877 A2 EP1320877 A2 EP 1320877A2 EP 01964510 A EP01964510 A EP 01964510A EP 01964510 A EP01964510 A EP 01964510A EP 1320877 A2 EP1320877 A2 EP 1320877A2
Authority
EP
European Patent Office
Prior art keywords
layer
silicon oxide
substrate
hydrocarbon
regions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01964510A
Other languages
English (en)
French (fr)
Inventor
Gill Lee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Infineon Technologies North America Corp
Original Assignee
Infineon Technologies North America Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Infineon Technologies North America Corp filed Critical Infineon Technologies North America Corp
Publication of EP1320877A2 publication Critical patent/EP1320877A2/de
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69Inorganic materials
    • H10P14/692Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
    • H10P14/6921Inorganic materials composed of oxides, glassy oxides or oxide-based glasses containing silicon
    • H10P14/6922Inorganic materials composed of oxides, glassy oxides or oxide-based glasses containing silicon the material containing Si, O and at least one of H, N, C, F or other non-metal elements, e.g. SiOC, SiOC:H or SiONC
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P76/00Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/63Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the formation processes
    • H10P14/6326Deposition processes
    • H10P14/6328Deposition from the gas or vapour phase
    • H10P14/6334Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • H10P14/6336Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/65Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials
    • H10P14/6502Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed before formation of the materials
    • H10P14/6506Formation of intermediate materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/65Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials
    • H10P14/6516Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials
    • H10P14/6518Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials by introduction of substances into an already-existing insulating layer
    • H10P14/6519Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials by introduction of substances into an already-existing insulating layer the substance being oxygen
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/65Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials
    • H10P14/6516Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials
    • H10P14/6529Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials by exposure to a gas or vapour
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/65Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials
    • H10P14/6516Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials
    • H10P14/6536Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials by exposure to radiation, e.g. visible light
    • H10P14/6538Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials by exposure to radiation, e.g. visible light by exposure to UV light
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/65Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials
    • H10P14/6516Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials
    • H10P14/6548Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by treatments performed before or after the formation of the materials of treatments performed after formation of the materials by forming intermediate materials, e.g. capping layers or diffusion barriers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/66Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
    • H10P14/668Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials
    • H10P14/6681Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si
    • H10P14/6682Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si the compound being a silane, e.g. disilane, methylsilane or chlorosilane
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69Inorganic materials
    • H10P14/6903Inorganic materials containing silicon
    • H10P14/6905Inorganic materials containing silicon being a silicon carbide or silicon carbonitride and not containing oxygen, e.g. SiC or SiC:H

Definitions

  • the present invention relates generally to integrated circuits ("IC”s) and their fabrication, and more particularly to silicon oxide patterning using chemical vapor deposition ("CVD”) photoresist .
  • IC integrated circuits
  • CVD chemical vapor deposition
  • Miniaturization is generally needed to accommodate the increasing density of circuits necessary for today's semiconductor products. For example, it is not uncommon for there to be millions of semiconductor devices or more on a single semiconductor product.
  • a patterned layer may be formed on an integrated circuit through the use of photolithography.
  • a 600 nm thick spin-on photoresist is typically applied to a substrate over a layer to be patterned (e.g., silicon dioxide) .
  • the thickness of the photoresist may vary from 300-1500 nm, although other thicknesses may be used.
  • Portions of the photoresist may then be exposed to some form of radiation (e.g., light, electrons, ions) through a photolithographic mask.
  • the photoresist is then chemically developed, wherein either the exposed portion or unexposed portion of the photoresist may be removed, depending on whether a positive or negative resist is used, respectively.
  • the photoresist should provide adequate etch resistance or selectivity so that the unexposed portions of the underlying layer are protected while the exposed portions of the layer are etched away during the subsequent etching process. Therefore, a sufficient thickness of photoresist is typically required to perform a successful etch.
  • the vertical to horizontal aspect ratio of the patterned photoresist continues to increase.
  • the higher the aspect ratio the less mechanically stable the photoresist.
  • an aspect ratio above 4:1 may not be workable for many applications.
  • a 0.15um minimum feature size would limit the photoresist thickness to less than 0.6um.
  • thinner photoresists with sufficient etch selectivity are generally needed to enlarge the photolithographic process window, and to provide stable mechanical masks during the subsequent etching step.
  • CVD photoresists generally avoid the problems associated with spin-on photoresists.
  • CVD photoresist may be formed in a thinner layer than a spin-on photoresist, thus providing mechanical stability and a larger process window.
  • a CVD photoresist layer may have a typical thickness of 150 nm, with a thickness range of 30-500 nm, although other thicknesses may be used.
  • CVD photoresist may provide superior etch mask properties, such as high selectivity to silicon oxide, aluminum and its compounds, tungsten and its compounds, polysilicon, and so on.
  • CVD photoresist is plasma polymerized met ylsilane ("PPMS").
  • PPMS is a photosensitive material which is transformed into CH 3 -contained silicon oxide (PPMS oxide (“PPMSO”)) after being exposed to ultraviolet ( "UV” ) light in air .
  • PPMSO plasma polymerized met ylsilane
  • hydrocarbon e.g., methyl
  • etch masks there are generally several problems, however, with using hydrocarbon (e.g., methyl) contained silicon oxides, as etch masks.
  • hydrocarbon e.g., methyl
  • these materials are effectively silicon oxide with CH 3 bonds, they generally do not have sufficient etch selectivity with respect to other silicon oxides.
  • the application of PPMSO or equivalent CVD photosensitive materials is generally limited to non-oxide patterning.
  • photosensitive methyl-contained silicon oxides generally do not provide as high a quality silicon oxide as conventional plasma enhanced CVD ("PECVD") processes.
  • PECVD plasma enhanced CVD
  • these materials are susceptible to moisture absorption. Therefore these materials by themselves generally cannot be left on the substrate to function as an oxide layer, and they generally have to be removed from the substrate after the subsequent etching process that uses their hard mask properties .
  • CVD photoresist e.g., PPMS
  • silicon oxide e.g., PPMSO
  • a high quality cap layer e.g., PECVD silicon oxide or nitride
  • PECVD silicon oxide or nitride may then be formed over the lower quality silicon oxide layer (e.g., PPMSO) utilizing a maskless etch process.
  • an additional high quality silicon oxide layer may also be formed on the substrate prior to formation of the CVD photoresist layer.
  • the cap layer may be used to protect the lower quality silicon oxide layer from moisture absorption.
  • a method of forming a patterned silicon oxide layer in an integrated circuit comprises forming a patterned hydrocarbon-contained silicon oxide layer on a first layer of a substrate; and forming a insulating cap layer encasing the patterned hydrocarbon-contained silicon oxide layer.
  • a method of forming a patterned silicon oxide layer in an integrated circuit comprises depositing a chemical vapor deposition (CVD) photoresist layer on a first layer of a substrate; exposing first regions of the CVD photoresist layer to radiation, wherein the exposing converts the CVD photoresist in the first regions into hydrocarbon-contained silicon oxide; removing unexposed second regions of the CVD photoresist layer from the substrate, thereby exposing the first layer in the second regions; depositing a conformal insulating layer on the substrate, wherein the conformal layer is thicker on an upper horizontal surface of the hydrocarbon-contained silicon oxide than on other surfaces on the substrate; and removing the conformal layer from the second regions, thereby exposing the first layer in the second regions, and thereby forming an insulating cap layer encasing the hydrocarbon-contained silicon oxide .
  • CVD chemical vapor deposition
  • an integrated circuit comprises a patterned hydrocarbon-contained silicon oxide layer overlying a first layer of a substrate; and a cap layer encasing the patterned hydrocarbon-contained silicon oxide layer.
  • the hydrocarbon- contained silicon oxide is preferably plasma polymerized methylsilane oxide, and the cap layer is preferably selected from the group consisting of silicon oxide, silicon nitride, and combinations thereof.
  • An advantage of a preferred embodiment of the present invention is that it provides a simplified oxide patterning technique. Overall process steps may be reduced from the number of steps in prior art techniques. In addition, raw process time in the oxide etching step may be reduced.
  • Another advantage of a preferred embodiment of the present invention is that a thinner photoresist may be used because the technique does not require etch resistance or selectivity.
  • the thickness may generally be determined solely by the requirement of the thickness of the oxide layer being patterned.
  • Another advantage of a preferred embodiment of the present invention is that the thinner photoresist layer permits a larger lithographic process window and increased depth of focus, enabling a more robust process than that used in the prior art.
  • FIGURES 1-6 are cross-sectional views of a prior art integrated circuit structure at various stages of fabrication
  • FIGURES 7-10 are cross-sectional views of an integrated circuit structure in accordance with a preferred embodiment of the present invention at various stages of fabrication;
  • FIGURES 11-15 are cross-sectional views of an integrated circuit structure in accordance with another preferred embodiment of the present invention at various stages of fabrication.
  • FIGURES 16-19 are cross-sectional views of an integrated circuit structure in accordance with another preferred embodiment of the present invention at various stages of fabrication.
  • the invention relates to integrated circuits, including memory ICs, microprocessor ICs, logic ICs, analog and mixed signal ICs, or other ICs comprising a patterned oxide layer.
  • the invention also relates to semiconductor processes and structures, including insulating layers such as capacitor dielectrics, field oxides, or gate oxides, or other processes and structures comprising an oxide layer.
  • Figures 1-6 illustrate cross-sectional views of a well known conventional prior art method of patterning a silicon oxide layer.
  • a silicon oxide layer 102 is formed on silicon substrate 100.
  • the substrate may be gallium arsenide or another form of silicon such as silicon on insulator.
  • Oxide layer 102 may be grown using a local oxidation of silicon process, or deposited using a PECVD silane based or tetraethyloxysilane ("TEOS”) based process.
  • TEOS tetraethyloxysilane
  • ARC anti-reflective coating
  • Spin-on photoresist layer 106 is then deposited on ARC layer 102 using a spin-on method.
  • portions of spin-on photoresist layer 106 are exposed to radiation through a photolithographic mask, followed by development of photoresist layer 106 using an appropriate chemical etch. As shown in Figure 3, the exposed (positive resist) or unexposed (negative resist) portions of spin-on photoresist layer 106 are removed from the substrate, resulting in patterned photoresist layer 108.
  • ARC layer 104 are etched using patterned photoresist layer 106 as a mask to form patterned ARC layer 110.
  • Exposed portions of silicon oxide layer 102 are then etched, again using patterned photoresist layer 106 as a mask.
  • patterned photoresist layer 108 may have etch characteristics similar to that of silicon oxide layer 102, patterned photoresist layer 108 must generally be of sufficient thickness so that a portion of it remains after the etching of silicon oxide layer 102 is complete.
  • the resulting structure is illustrated in Figure 5, with patterned silicon oxide layer 114 shown underlying patterned ARC layer 116 and etched photoresist layer 108.
  • photoresist layer 108 and ARC layer 116 are stripped off the substrate, leaving patterned silicon oxide layer 114 formed on substrate 100, as illustrated in Figure 6.
  • the thicker photoresist required for the silicon oxide etching step narrows the lithographic process window and reduces process robustness due to the decrease in the depth of focus along with the decrease in minimum feature size.
  • FIG. 7 illustrates 150 nm thick CVD photoresist PPMS layer 202 deposited on silicon substrate 200 using a vacuum CVD system.
  • Typical process parameters for the PPMS deposition process are a temperature of 150° C, a pressure of 8 Torr, and an RF power of 300 W.
  • the temperature may vary between 0°-300° C
  • the pressure may vary between 1-20 Torr
  • the RF power may vary between 100-1000 , although other parameter ranges may be used.
  • the thickness of PPMS layer 202 may be 100-300 nm, although other thicknesses may be used.
  • the resist may be formed using any carbon-containing or hydrocarbon- containing silane gas, such as mono-methylsilane, bi- methylsilane, 3-methylsilane or 4-methylsilane (all of which are referred to herein simply as methylsilane) .
  • the substrate may be gallium arsenide or another form of silicon such as silicon on insulator.
  • portions of PPMS layer 202 are exposed to ultraviolet light (e.g., 248 nm, 193 nm or 157 nm wavelengths) through a photolithographic mask in an air atmosphere.
  • ultraviolet light e.g., 248 nm, 193 nm or 157 nm wavelengths
  • the exposed portions of PPMS layer 202 are converted into PPMSO, a CH 3 -contained silicon oxide.
  • the unexposed portions of layer 202 are then removed from the substrate using an appropriate chemical etch, leaving patterned PPMSO layer 204, as shown in Figure 8.
  • a PPMSO layer generally could not be used as a mask to pattern a silicon oxide layer because it does not possess sufficient etch selectivity.
  • cap layer 206 overlying PPMSO layer 204.
  • the thickness of cap layer 206 may be 10-100 nm, although other thicknesses may be used.
  • Cap layer 206 is preferably silicon oxide, but alternatively another insulator such as a silicon nitride cap layer may be used. The capping process prevents moisture absorption into PPMSO layer 204.
  • cap layer 206 is about twice as thick in region 208 directly overlying PPMSO layer 204 as it is in region 210 directly overlying substrate 200. This is generally because the PECVD silane based oxide process produces about 40% bottom step coverage relative to top step coverage, and the TEOS based oxide process produces about 50% to 60% bottom step coverage, depending on the aspect ratio of the step structure .
  • a maskless or self-aligned etch process may be used to punch through the portions of cap layer 206 covering the substrate in region 210, in order to clear the insulator from the contact area. Because cap layer 206 is much thinner in region 210 than in region 208, a conventional anisotropic silicon oxide etch process may be used to open the contact area without re-exposing PPMSO layer 204 underlying the thicker portions of cap layer 206.
  • the resulting structure is illustrated in Figure 10, with cap layer 212 encasing PPMSO layer 204, and substrate 200 exposed in region 214.
  • CVD photoresist is not used as a mask to etch an underlying silicon oxide layer, a thinner CVD photoresist layer may be used.
  • the thickness of the CVD photoresist may be determined solely by the final desired thickness of the oxide layer being patterned.
  • FIG. 11-15 cross-sectional views are illustrated of another preferred embodiment method of forming a patterned silicon oxide layer using CVD photoresist.
  • a high quality oxide liner on the substrate to provide a buffer between the substrate and the PPMSO layer, and to completely encircle the PPMSO layer with a high quality oxide. Therefore, in this embodiment, as shown in Figure 11, a 50 nm thick silicon oxide liner 302 is deposited on substrate 300 prior to the deposition of CVD photoresist PPMS layer 304.
  • the thickness of oxide liner may be 10-100 nm, although other thicknesses may be used.
  • Oxide liner 302 may be formed using any high quality oxide formation process, such as LOCOS, or those used to form the cap layer in the previous embodiment. Alternatively, another insulator such as silicon nitride may be used as the liner.
  • portions of PPMS layer 304 are exposed to ultraviolet light through a photolithographic mask in an air atmosphere.
  • the exposed portions of PPMS layer 304 are converted into PPMSO, a CH 3 -contained silicon oxide.
  • the unexposed portions of layer 304 are then removed from the substrate using an appropriate chemical etch, leaving patterned PPMSO layer 306 overlying silicon oxide liner 302, as shown in Figure 12.
  • an anisotropic etch process may be used to remove the exposed portions of oxide liner 302. This process will generally also etch the PPMSO layer 306 because of the similarity of the materials. Therefore PPMSO layer 306 should generally be of sufficient thickness to permit removal of the exposed oxide layer 302.
  • the resulting structure comprises PPMSO layer 310 overlying patterned oxide liner 308.
  • cap layer 312 is preferably silicon oxide, but alternatively a silicon nitride cap layer may be used.
  • cap layer 312 is about twice as thick in the region directly overlying PPMSO layer 310 as it is in the region directly overlying substrate 300. Therefore, a maskless or self-aligned etch process may be used to punch through the portions of cap layer 312 directly overlying the substrate, in order to clear the insulator from the contact area.
  • a conventional anisotropic silicon oxide etch process may be used to open the contact area without re-exposing PPMSO layer 310 underlying the thicker portions of cap layer 312.
  • the resulting structure is illustrated in Figure 15, with cap layer 314 and oxide liner 308 encompassing PPMSO layer 310, and with substrate 300 exposed in the remaining regions.
  • Cap layer 314 and oxide liner 308 together provide a high quality oxide completely surrounding PPMSO layer 310.
  • FIG. 16-19 cross-sectional views are illustrated of another preferred embodiment method of forming a patterned silicon oxide layer using CVD photoresist.
  • a high quality oxide liner is again deposited on the substrate, but it is etched at a different point in the process.
  • silicon oxide liner ,.402 is deposited on substrate 400 prior to the deposition of CVD photoresist PPMS layer 404.
  • Oxide liner 402 may be formed using any high quality oxide formation process, such as LOCOS, or those used to form the cap layer in the previous embodiment .
  • another insulator such as silicon nitride may be used as the liner.
  • portions of PPMS layer 404 are exposed to ultraviolet light through a photolithographic mask in an air atmosphere.
  • the exposed portions of PPMS layer 404 are converted into PPMSO, a CH 3 -contained silicon oxide.
  • the unexposed portions of layer 404 are then removed from the substrate using an appropriate chemical etch, leaving patterned PPMSO layer 406 overlying silicon oxide liner 402, as shown in Figure 17.
  • cap layer 408 is preferably silicon oxide, but alternatively a silicon nitride cap layer may be used. Similar to the previous embodiments, and as can be seen in Figure 18, cap layer 408 is about twice as thick in the region directly overlying PPMSO layer 406 as it is in the region directly overlying oxide liner 402. Therefore, a maskless or self-aligned etch process may be used to punch through the portions of both cap layer 408 and oxide liner 402 directly overlying the substrate, in order to clear the insulators from the contact area.
  • a conventional anisotropic silicon oxide etch process may be used to open the contact area without re-exposing PPMSO layer 406 underlying the thicker portions of cap layer 408, as long as the thick top step of cap layer 408 is thick enough to withstand the etching of both the thin bottom step of cap layer 408 and oxide layer 402.
  • the resulting structure is illustrated in Figure 19, with cap layer 410 and oxide liner 412 encompassing PPMSO layer 406, and with substrate 400 exposed in the remaining regions. Cap layer 410 and oxide liner 412 together provide a high quality.oxide completely surrounding PPMSO layer 406.
  • the remainder of an integrated circuit may be formed using conventional IC processing techniques.
  • the resulting IC may then be employed in a variety of commercial and consumer electronics devices, including computers.

Landscapes

  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
  • Formation Of Insulating Films (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
EP01964510A 2000-09-27 2001-08-30 Siliziumoxydstrukturierung mittels cvd-photolacks Withdrawn EP1320877A2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US67074300A 2000-09-27 2000-09-27
US670743 2000-09-27
PCT/US2001/026999 WO2002027777A2 (en) 2000-09-27 2001-08-30 Silicon oxide patterning using cvd photoresist

Publications (1)

Publication Number Publication Date
EP1320877A2 true EP1320877A2 (de) 2003-06-25

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Country Status (3)

Country Link
EP (1) EP1320877A2 (de)
KR (1) KR100564170B1 (de)
WO (1) WO2002027777A2 (de)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6001747A (en) * 1998-07-22 1999-12-14 Vlsi Technology, Inc. Process to improve adhesion of cap layers in integrated circuits
US6114259A (en) * 1999-07-27 2000-09-05 Lsi Logic Corporation Process for treating exposed surfaces of a low dielectric constant carbon doped silicon oxide dielectric material to protect the material from damage

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
None *
See also references of WO0227777A3 *

Also Published As

Publication number Publication date
KR20030067670A (ko) 2003-08-14
KR100564170B1 (ko) 2006-03-27
WO2002027777A2 (en) 2002-04-04
WO2002027777A3 (en) 2002-08-29

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