EP1300291A2 - Verfahren zum Aufbringen einer Antidröhnmasse auf Basis von Epoxidharzen auf eine Fahrzeugkarosserie - Google Patents
Verfahren zum Aufbringen einer Antidröhnmasse auf Basis von Epoxidharzen auf eine Fahrzeugkarosserie Download PDFInfo
- Publication number
- EP1300291A2 EP1300291A2 EP02021945A EP02021945A EP1300291A2 EP 1300291 A2 EP1300291 A2 EP 1300291A2 EP 02021945 A EP02021945 A EP 02021945A EP 02021945 A EP02021945 A EP 02021945A EP 1300291 A2 EP1300291 A2 EP 1300291A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- drumming
- gelling agent
- compound
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 10
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims description 12
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 title claims description 7
- 239000000463 material Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract description 26
- 239000003349 gelling agent Substances 0.000 claims abstract description 18
- 239000000499 gel Substances 0.000 claims abstract 2
- 239000003973 paint Substances 0.000 claims description 18
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004848 polyfunctional curative Substances 0.000 claims description 2
- 229920001187 thermosetting polymer Polymers 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 3
- 239000004922 lacquer Substances 0.000 claims 1
- 238000010422 painting Methods 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 3
- 238000007591 painting process Methods 0.000 abstract description 2
- 238000002203 pretreatment Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 2
- 208000031872 Body Remains Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005237 degreasing agent Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/58—No clear coat specified
- B05D7/586—No clear coat specified each layer being cured, at least partially, separately
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/105—Intermediate treatments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/007—Processes for applying liquids or other fluent materials using an electrostatic field
Definitions
- the invention relates to a method for applying a Anti-drumming compound based on epoxy resins on a vehicle body, in which the applied anti-drumming compound together with layers of paint applied in a paint shop cures in paint ovens, the paint shop a bodyshell oven for curing glue on the bodyshell and a washer to remove dirt, drawing oils in particular, upstream on the bodyshell is. Furthermore, an anti-droning mass is said to Implementation of this procedure will be created.
- Anti-drumming compounds based on epoxy resins require Curing temperatures of over 160 ° C and residence times of at least 20 to 30 minutes. These conditions are in the paint ovens during vehicle production Paint shop fulfilled. That's why you have the anti-droning mass so far immediately before painting on the body applied so that it is in the paint oven together with the paint can harden. However, there is a desire to Paint shop of all not required for painting Keep operations clear, so no contamination can get onto the body after painting to disturb. That is why the desire arose, the anti-drumming mass already applied to the body shell. It However, it was found that this was the case during pretreatment cannot withstand prevailing conditions.
- the problem underlying the invention is a method for applying an anti-drumming compound based on epoxy resins to develop a vehicle body which can be carried out outside the paint shop and too the smallest possible increase in manufacturing costs leads. Furthermore, an anti-droning compound is to be carried out of this procedure.
- this problem is solved in that added a gelling agent to the anti-drumming compound and that Anti-drumming compound containing gelling agent before insertion the body shell is applied in the body shell becomes.
- the anti-drumming compound is applied to the still oiled metal sheets of the bodyshell, so that it can actually be expected that it will at least partially be washed off again in the subsequent washing process in order to remove the oil.
- the gelling agent causes gelling to occur to such an extent that the anti-drumming compound can withstand the conditions when it passes the bodyshell through the bodyshell oven at the temperature of about 120 ° C and the residence time of 10 - 12 minutes required there anyway that prevail in the pre-treatment prior to the painting process.
- Gelling is a physical process, one Swelling "and not yet about the chemical crosslinking process occurring in the paint oven.
- the gelling agent itself is a foreign substance in the anti-drumming compound, which is not only harmless to the effectiveness of the anti-drumming compound, but surprisingly improves its acoustic effectiveness.
- the anti-drumming mass contains a gelling agent, which at a temperature of about 120 ° C within of about 10 - 12 minutes gelled so that the anti-drumming mass the stress in one of the paint shops upstream scrubber to remove dirt and withstand drawing oils.
- Gelling agents which meet the aforementioned conditions, are available very cheaply for around EUR 3 per kg, while possibly usable as an alternative Accelerators cost about EUR 50 per kg.
- the gelling agent changes the storage stability of the anti-drumming compound not and their applicability will not negatively influenced.
- the acoustic properties of the Anti-drumming mass is even improved by the gelling agent.
- Gelling agents can be used as gelling agents.
- An anti-drumming compound was tested in practice, in which the Gelling agent is an acrylic polymer based on methyl methacrylate and n-butyl methacrylate and its proportion is 1 - 10% by weight.
- the overall anti-drumming mass is optimally composed if it contains the following components: epoxy resin 40 - 45% by weight Hardener, thermosetting (dicyandiamide) 1 - 3% by weight accelerator 0.1 - 4% by weight chalk 45 - 55% by weight dye 0.04% by weight Thixotrophieicosstoff 1 - 5% by weight viscosity aids 0.5% by weight Gelling agent (methyl methacrylate) 1 - 10% by weight
- the invention permits various embodiments. To further clarify their basic principle hereinafter referred to a block diagram.
- the anti-drumming mass contains a gelling agent that is an acrylic polymer based on methyl methacrylic and n-butyl methacrylate is.
- the body shell then goes into a shell furnace 3, the curing process commonly used in automobile manufacturing of the adhesive present on the bodyshell serves and in which there is a temperature of about 120 ° C. and the body shell remains about 10 to 12 minutes.
- a pretreatment 4 follows, in particular with washers at temperatures from 50 to 60 ° C and pressures of 4 - 5 bar grease on the body shell be washed off. Phosphating is also carried out there the body shell. Close the pretreatment a cataphoretic dip painting 5 and a Drying process in an oven 6. In this oven 6 the temperature is 180 ° C. The body remains about 20 minutes in the oven 6. This will make the chemical Curing process of the anti-droning compound started and so far completed their painting in a painting station 7 can be done. You will close a paint oven 8 in which the paint and the anti-drumming compound completely dry or harden. The finished painted body then arrives at final assembly 9.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Abstract
Description
| Epoxidharz | 40 - 45 Gew.-% |
| Härter, heißhärtend (Dicyandiamid) | 1 - 3 Gew.-% |
| Beschleuniger | 0,1 - 4 Gew.-% |
| Kreide | 45 - 55 Gew.-% |
| Farbstoff | 0,04 Gew.-% |
| Thixotrophiehilfsmittel | 1 - 5 Gew.-% |
| Viskositätshilfsmittel | 0,5 Gew.-% |
| Geliermittel (Methyl-Methacrylat) | 1 - 10 Gew.-% |
Claims (4)
- Verfahren zum Aufbringen einer Antidröhnmasse auf Basis von Epoxidharzen auf eine Fahrzeugkarosserie, bei dem die aufgebrachte Antidröhnmasse zusammen mit in einer Lackiererei aufgebrachten Lackschichten in Lacköfen aushärtet, wobei der Lackiererei ein Rohbauofen zum Aushärten von Kleber auf der Rohbaukarosserie und ein Wäscher zum Entfernen von Verschmutzungen, insbesondere Ziehölen, auf der Rohbaukarosserie vorgeschaltet ist, dadurch gekennzeichnet, dass der Antidröhnmasse ein Geliermittel zugesetzt und die das Geliermittel enthaltende Antidröhnmasse vor dem Einbringen der Rohbaukarosserie in den Rohbauofen appliziert wird.
- Antidröhnmasse auf Basis von Epoxidharzen zur Durchführung des Verfahrens nach Anspruch 1, dadurch gekennzeichnet, dass sie ein Geliermittel enthält, welches bei einer Temperatur von etwa 120° C innerhalb von etwa 10 - 12 Minuten derart geliert, dass die Antidröhnmasse der Beanspruchung in einem der Lackiererei vorgeschalteten Wäscher zur Entfernung von Verschmutzungen und Ziehölen standzuhalten vermag.
- Antidröhnmasse nach Anspruch 2, dadurch gekennzeichnet, dass das Geliermittel ein Acrylpolymer auf Basis von Methylmethacrylat und n-Butylmethacrylat ist und sein Anteil 1 - 10 Gew.-% beträgt.
- Antidröhnmasse nach zumindest einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass ihre Zusammensetzung wie folgt ist:
Epoxidharz 40 - 45 Gew.-% Härter, heißhärtend (Dicyandiamid) 1 - 3 Gew.-% Beschleuniger 0,1 - 4 Gew.-% Kreide 45 - 55 Gew.-% Farbstoff 0,04 Gew.-% Thixotrophiehilfsmittel 1 - 5 Gew.-% Viskositätshilfsmittel 0,5 Gew.-% Geliermittel (Methyl-Methacrylat) 1 - 10 Gew.-%
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10148103 | 2001-09-28 | ||
| DE10148103 | 2001-09-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1300291A2 true EP1300291A2 (de) | 2003-04-09 |
| EP1300291A3 EP1300291A3 (de) | 2005-10-26 |
Family
ID=7700774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02021945A Withdrawn EP1300291A3 (de) | 2001-09-28 | 2002-09-30 | Verfahren zum Aufbringen einer Antidröhnmasse auf Basis von Epoxidharzen auf eine Fahrzeugkarosserie |
Country Status (1)
| Country | Link |
|---|---|
| EP (1) | EP1300291A3 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006012941A1 (de) * | 2004-07-30 | 2006-02-09 | Röhm Gmbh | Additive für epoxid-harze |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2800914C2 (de) * | 1978-01-10 | 1983-12-29 | Dr. Alois Stankiewicz Schallschluck GmbH & Co KG, 3101 Adelheidsdorf | Schalldämmende Mehrschichtwandverkleidung für die Wände von Fahrzeugen oder Maschinen |
| DE3444863A1 (de) * | 1984-12-08 | 1986-07-17 | Teroson Gmbh, 6900 Heidelberg | Spritzbare plastisolzusammensetzung und deren verwendung zur schalldaempfung |
| CH671546A5 (de) * | 1986-09-26 | 1989-09-15 | Matec Holding | |
| DE3830345C1 (de) * | 1988-09-07 | 1989-11-02 | Teroson Gmbh, 6900 Heidelberg, De | |
| DE4441656A1 (de) * | 1994-11-23 | 1996-05-30 | Teroson Gmbh | Elastomerprodukte mit akustischen Dämpfungseigenschaften |
| US6150428A (en) * | 1999-09-28 | 2000-11-21 | Sika Corporation | Expansion temperature tolerant dry expandable sealant and baffle product and method of preparing same |
-
2002
- 2002-09-30 EP EP02021945A patent/EP1300291A3/de not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006012941A1 (de) * | 2004-07-30 | 2006-02-09 | Röhm Gmbh | Additive für epoxid-harze |
| DE102004037472A1 (de) * | 2004-07-30 | 2006-03-23 | Röhm GmbH & Co. KG | Additive für Epoxid-Harze |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1300291A3 (de) | 2005-10-26 |
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