EP1288008A2 - Elément pour impression par jet d'encre et procédé d'impression - Google Patents
Elément pour impression par jet d'encre et procédé d'impression Download PDFInfo
- Publication number
- EP1288008A2 EP1288008A2 EP02078397A EP02078397A EP1288008A2 EP 1288008 A2 EP1288008 A2 EP 1288008A2 EP 02078397 A EP02078397 A EP 02078397A EP 02078397 A EP02078397 A EP 02078397A EP 1288008 A2 EP1288008 A2 EP 1288008A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- recording element
- particles
- ink jet
- cationic
- receiving layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Definitions
- the present invention relates to a porous ink jet recording element and a printing method using the element.
- ink droplets are ejected from a nozzle at high speed towards a recording element or medium to produce an image on the medium.
- the ink droplets, or recording liquid generally comprise a recording agent, such as a dye or pigment, and a large amount of solvent.
- the solvent, or carrier liquid typically is made up of water and an organic material such as a monohydric alcohol, a polyhydric alcohol or mixtures thereof.
- An ink jet recording element typically comprises a support having on at least one surface thereof an ink-receiving or image-receiving layer, and includes those intended for reflection viewing, which have an opaque support, and those intended for viewing by transmitted light, which have a transparent support.
- porous recording elements have been developed which provide nearly instantaneous drying as long as they have sufficient thickness and pore volume to effectively contain the liquid ink.
- a porous recording element can be manufactured by cast coating, in which a particulate-containing coating is applied to a support and is dried in contact with a polished smooth surface.
- EP 1,002,660 relates to a porous ink jet recording element comprising fine particles, hydrophilic binder and a water-soluble, cationic polymer.
- a porous ink jet recording element comprising fine particles, hydrophilic binder and a water-soluble, cationic polymer.
- this element there is a problem with this element in that the density of an image printed on such an element using a water-soluble cationic polymer is lower than one would like.
- U.S. Patent 6,089,704 relates to a nonporous ink jet recording element comprising cationic polymeric vinyl latex and a hydrophilic polymer.
- this nonporous recording element there is a problem with this nonporous recording element in that it images printed thereon dry too slowly.
- U.S. Patent 6,096,469 relates to an ink jet recording element comprising mesoporous particles dispersed in an organic binder.
- the organic binder can be a cationic latex polymer "having less than 10 mole percent of a copolymerizable monomer having a tertamino or quaternary ammonium functionality.”
- this element there is a problem with this element in that the density of an image printed on such an element with a binder having less than 10 mole percent of a cationic mordant functionality is lower than one would like.
- Another object of the invention is to provide a printing method using the above-described element.
- an ink jet recording element comprising a support having thereon a porous image-receiving layer comprising:
- a porous ink jet recording element is obtained that, when printed with dye-based inks, provides superior optical densities, good image quality and has an excellent dry time.
- Another embodiment of the invention relates to an ink jet printing method comprising the steps of
- the (a) particles useful in the invention include alumina, boehmite, hydrated aluminum oxide, clay, calcium carbonate, titanium dioxide, calcined clay, aluminosilicates, silica, barium sulfate, or organic particles such as polymeric beads.
- organic particles useful in the invention are disclosed and claimed in U.S. Patent Application Serial Numbers: 09/458,401, filed Dec. 10, 1999; 09/608,969, filed June 30, 2000; 09/607,417, filed June 30, 2000; 09/608,466 filed June 30, 2000; 09/607,419, filed June 30, 2000; and 9/822,731, filed March 30, 2001.
- the (a) particles may be porous or nonporous.
- the particles are inorganic oxides.
- the (a) particles have a mean particle size of from 0.05 ⁇ m to 1 ⁇ m.
- the (b) water insoluble, cationic, polymeric particles comprising at least 20 mole percent of a cationic mordant moiety useful in the invention can be in the form of a latex, water dispersible polymer, beads, or core/shell particles wherein the core is organic or inorganic and the shell in either case is a cationic polymer.
- Such particles can be products of addition or condensation polymerization, or a combination of both. They can be linear, branched, hyper-branched, grafted, random, blocked, or can have other polymer microstructures well known to those in the art. They also can be partially crosslinked. Examples of core/shell particles useful in the invention are disclosed and claimed in U.S. Patent Application Serial No.
- the water insoluble, cationic, polymeric particles comprise at least 50 mole percent of a cationic mordant moiety.
- the (b) water insoluble, cationic, polymeric particles useful in the invention can be derived from nonionic, anionic, or cationic monomers. In a preferred embodiment, combinations of nonionic and cationic monomers are employed. In general, the amount of cationic monomer employed in the combination is at least 20 mole percent.
- the nonionic, anionic, or cationic monomers employed can include neutral, anionic or cationic derivatives of addition polymerizable monomers such as styrenes, alpha-alkylstyrenes, acrylate esters derived from alcohols or phenols, methacrylate esters, vinylimidazoles, vinylpyridines, vinylpyrrolidinones, acrylamides, methacrylamides, vinyl esters derived from straight chain and branched acids (e.g., vinyl acetate), vinyl ethers (e.g., vinyl methyl ether), vinyl nitriles, vinyl ketones, halogen-containing monomers such as vinyl chloride, and olefins, such as butadiene.
- addition polymerizable monomers such as styrenes, alpha-alkylstyrenes, acrylate esters derived from alcohols or phenols, methacrylate esters, vinylimidazoles, vinylpyridines, vinylpyrroli
- nonionic, anionic, or cationic monomers employed can also include neutral, anionic or cationic derivatives of condensation polymerizable monomers such as those used to prepare polyesters, polyethers, polycarbonates, polyureas and polyurethanes.
- the (b) water insoluble, cationic, polymeric particles employed in this invention can be prepared using conventional polymerization techniques including, but not limited to bulk, solution, emulsion, or suspension polymerization.
- the amount of (b) water insoluble, cationic, polymeric particles used should be high enough so that the images printed on the recording element will have a sufficiently high density, but low enough so that the interconnected pore structure formed by the aggregates is not filled.
- the weight ratio of (b) water insoluble, cationic, polymeric particles to (a) particles is from 1:2 to 1:10, preferably 1:5.
- (b) water insoluble, cationic, polymeric particles which may be used in the invention include those described in U.S. Patent 3,958,995. Specific examples of these polymers include:
- the image-receiving layer also contains a polymeric binder in an amount insufficient to alter the porosity of the porous receiving layer.
- the polymeric binder is a hydrophilic polymer such as poly(vinyl alcohol), poly(vinyl pyrrolidone), gelatin, cellulose ethers, poly(oxazolines), poly(vinylacetamides), partially hydrolyzed poly(vinyl acetate/vinyl alcohol), poly(acrylic acid), poly(acrylamide), poly(alkylene oxide), sulfonated or phosphated polyesters and polystyrenes, casein, zein, albumin, chitin, chitosan, dextran, pectin, collagen derivatives, collodian, agar-agar, arrowroot, guar, carrageenan, tragacanth, xanthan, rhamsan and the like.
- the hydrophilic polymer is poly(vinyl alcohol), hydroxypropyl cellulose, hydroxypropyl methyl cellulose, gelatin, or a poly(alkylene oxide).
- the hydrophilic binder is poly(vinyl alcohol). The polymeric binder should be chosen so that it is compatible with the aforementioned particles.
- the amount of binder used should be sufficient to impart cohesive strength to the ink jet recording element, but should also be minimized so that the interconnected pore structure formed by the aggregates is not filled in by the binder.
- the weight ratio of the binder to the total amount of particles is from 1:20 to 1:5.
- the recording element may also contain a base layer, next to the support, the function of which is to absorb the solvent from the ink.
- Materials useful for this layer include (a) particles, (b) particles, polymeric binder and/or crosslinker.
- the void volume must be sufficient to absorb all of the printing ink. For example, if a porous layer has 60 volume % open pores, in order to instantly absorb 32 cc/m 2 of ink, it must have a physical thickness of at least 54 ⁇ m.
- the support for the ink jet recording element used in the invention can be any of those usually used for ink jet receivers, such as resin-coated paper, paper, polyesters, or microporous materials such as polyethylene polymer-containing material sold by PPG Industries, Inc., Pittsburgh, Pennsylvania under the trade name of Teslin ®, Tyvek ® synthetic paper (DuPont Corp.), and OPPalyte® films (Mobil Chemical Co.) and other composite films listed in U.S. Patent 5,244,861.
- Opaque supports include plain paper, coated paper, synthetic paper, photographic paper support, melt-extrusion-coated paper, and laminated paper, such as biaxially oriented support laminates. Biaxially oriented support laminates are described in U.S.
- biaxially oriented supports include a paper base and a biaxially oriented polyolefin sheet, typically polypropylene, laminated to one or both sides of the paper base.
- Transparent supports include glass, cellulose derivatives, e.g., a cellulose ester, cellulose triacetate, cellulose diacetate, cellulose acetate propionate, cellulose acetate butyrate; polyesters, such as poly(ethylene terephthalate), poly(ethylene naphthalate), poly(1,4-cyclohexanedimethylene terephthalate), poly(butylene terephthalate), and copolymers thereof; polyimides; polyamides; polycarbonates; polystyrene; polyolefins, such as polyethylene or polypropylene; polysulfones; polyacrylates; polyetherimides; and mixtures thereof.
- the papers listed above include a broad range of papers, from high end papers, such as photographic paper to low end papers, such as newsprint. In a preferred embodiment, polyethylene-coated paper is employed.
- the support used in the invention may have a thickness of from 50 to 500 ⁇ m, preferably from 75 to 300 ⁇ m.
- Antioxidants, antistatic agents, plasticizers and other known additives may be incorporated into the support, if desired.
- the surface of the support may be subjected to a corona-discharge treatment prior to applying the image-receiving layer.
- Coating compositions employed in the invention may be applied by any number of well known techniques, including dip-coating, wound-wire rod coating, doctor blade coating, rod coating, air knife coating, gravure and reverse-roll coating, slide coating, bead coating, extrusion coating, curtain coating and the like.
- Known coating and drying methods are described in further detail in Research Disclosure no. 308119, published Dec. 1989, pages 1007 to 1008. Slide coating is preferred, in which the base layers and overcoat may be simultaneously applied. After coating, the layers are generally dried by simple evaporation, which may be accelerated by known techniques such as convection heating.
- crosslinkers which act upon the binder discussed above may be added in small quantities. Such an additive improves the cohesive strength of the layer.
- Crosslinkers such as carbodiimides, polyfunctional aziridines, aldehydes, isocyanates, epoxides, polyvalent metal cations, and the like may all be used.
- UV absorbers may also be added to the image-receiving layer as is well known in the art.
- Other additives include pH modifiers, adhesion promoters, rheology modifiers, surfactants, biocides, lubricants, dyes, optical brighteners, matte agents, antistatic agents, etc.
- additives known to those familiar with such art such as surfactants, defoamers, alcohol and the like may be used.
- a common level for coating aids is 0.01 to 0.30 % active coating aid based on the total solution weight.
- These coating aids can be nonionic, anionic, cationic or amphoteric. Specific examples are described in MCCUTCHEON's Volume 1: Emulsifiers and Detergents, 1995, North American Edition.
- the coating composition can be coated either from water or organic solvents, however water is preferred.
- the total solids content should be selected to yield a useful coating thickness in the most economical way, and for particulate coating formulations, solids contents from 10-40% are typical.
- the ink jet inks used to image the recording elements of the present invention are well-known in the art.
- the ink compositions used in ink jet printing typically are liquid compositions comprising a solvent or carrier liquid, dyes or pigments, humectants, organic solvents, detergents, thickeners, preservatives, and the like.
- the solvent or carrier liquid can be solely water or can be water mixed with other water-miscible solvents such as polyhydric alcohols.
- Inks in which organic materials such as polyhydric alcohols are the predominant carrier or solvent liquid may also be used. Particularly useful are mixed solvents of water and polyhydric alcohols.
- the dyes used in such compositions are typically water-soluble direct or acid type dyes.
- Such liquid compositions have been described extensively in the prior art including, for example, U.S. Patents 4,381,946; 4,239,543 and 4,781,758.
- a coating solution for a base layer was prepared by mixing 100 dry g of precipitated calcium carbonate Albagloss-s® (Specialty Minerals Inc.) as a 70% solution and 8.5 dry g of silica gel Gasil® 23F (Crosfield Ltd.) with 0.5 dry g of a poly(vinyl alcohol) Gohsenol® GH-17 (Nippon Gohsei Co., Ltd.) as a 10% solution and 5 dry g of styrene-butadiene latex CP692NA® (Dow Chemical) as a 50% solution. The solids of the coating solution was adjusted to 35% by adding water.
- the base layer coating solution was bead-coated at 25°C on a base paper, basis weight 185 g/m 2 , and dried at 60°C by forced air.
- the thickness of the base coating was 25 ⁇ m or 27 g/m 2 .
- a coating solution for the image-receiving layer was prepared by combining alumina Dispal® 14N4-80 (Condea Vista Co.), poly(vinyl alcohol) Gohsenol® GH-17 (Nippon Gohsei Co.) and Polymer A illustrated above in a ratio of 86:4:10 to give an aqueous coating formulation of 15% solids by weight.
- Surfactants Zonyl® FS-300 (DuPont Co.) and Silwet® L-7602 (Witco Corp.) were added in small amounts as coating aids.
- the image-receiving layer coating solution was coated on top of this base layer.
- the recording element was then dried at 60°C by forced air to yield a two-layer recording element.
- the thickness of the image-receiving layer was 8 ⁇ m or 8.6 g/m 2 .
- Element 2 was prepared the same as Element 1 except that Polymer B was used instead of Polymer A.
- Element 3 was prepared the same as Element 1 except that both Polymer A. and Polymer B were used.
- Comparative Element 1 no water-insoluble, cationic polymeric particles
- This element was prepared the same as Element 1 except that water-soluble Polymer C-1 was used instead of Polymer A.
- Comparative Element 2 no water-insoluble, cationic polymeric particles
- This element was prepared the same as Element 1 except that water-soluble Polymer C-2 was used instead of Polymer A.
- This element was prepared the same as Element 1 except that the image-receiving layer contained only alumina and poly (vinyl alcohol) in the ratio 96:4.
- Test images of cyan, magenta, yellow, red, green and blue patches at 100% ink laydown were printed using a Hewlett-Packard DeskJet 970 printer and ink cartridge with catalogue number HP C6578D.
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US944971 | 2001-08-31 | ||
US945085 | 2001-08-31 | ||
US09/944,971 US6815020B2 (en) | 2001-08-31 | 2001-08-31 | Ink jet recording element |
US09/945,085 US6431701B1 (en) | 2001-08-31 | 2001-08-31 | Ink jet printing method |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1288008A2 true EP1288008A2 (fr) | 2003-03-05 |
EP1288008A3 EP1288008A3 (fr) | 2003-10-15 |
EP1288008B1 EP1288008B1 (fr) | 2005-12-14 |
Family
ID=27130214
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20020078397 Expired - Fee Related EP1288008B1 (fr) | 2001-08-31 | 2002-08-16 | Elément pour impression par jet d'encre et procédé d'impression |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1288008B1 (fr) |
JP (2) | JP2003145926A (fr) |
CN (1) | CN1406760A (fr) |
DE (1) | DE60207946T2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008082475A1 (fr) * | 2006-12-29 | 2008-07-10 | Eastman Kodak Company | Elément d'enregistrement d'image comprenant des particules mordantes encapsulées |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050003113A1 (en) * | 2003-07-02 | 2005-01-06 | Tienteh Chen | Inkjet recording materials |
EP1630600A3 (fr) * | 2004-07-29 | 2006-03-22 | Rohm and Haas Electronic Materials, L.L.C. | Composition thermofusible et procédé comportant la formation d'un motif de masquage |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4239543A (en) | 1979-02-09 | 1980-12-16 | Gould Inc. | Non-crusting jet ink and method of making same |
US4381946A (en) | 1980-02-25 | 1983-05-03 | Konishiroku Photo Industry Co., Ltd. | Ink composition for ink-jet recording |
US4781758A (en) | 1987-10-22 | 1988-11-01 | International Business Machines Corporation | Ink composition for drop-on-demand ink jet |
US5244861A (en) | 1992-01-17 | 1993-09-14 | Eastman Kodak Company | Receiving element for use in thermal dye transfer |
US6089704A (en) | 1998-10-19 | 2000-07-18 | Eastman Kodak Company | Overcoat for ink jet recording element |
US6096469A (en) | 1999-05-18 | 2000-08-01 | 3M Innovative Properties Company | Ink receptor media suitable for inkjet printing |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5206071A (en) * | 1991-11-27 | 1993-04-27 | Arkwright Incorporated | Archivable ink jet recording media |
JP3215167B2 (ja) * | 1992-07-08 | 2001-10-02 | 三菱化学株式会社 | 印刷性の良好な熱可塑性樹脂フィルム |
DE69402573T2 (de) * | 1993-02-01 | 1997-11-27 | Agfa Gevaert Nv | Tinte empfangende Schichten |
JP3841362B2 (ja) * | 1993-05-21 | 2006-11-01 | 三菱製紙株式会社 | インクジェット記録シート |
WO1999039914A1 (fr) * | 1998-02-04 | 1999-08-12 | Minnesota Mining And Manufacturing Company | Feuille pour encrage |
DE69902072T2 (de) * | 1998-05-11 | 2002-11-14 | Daicel Chem | Farbstoffempfangsschicht für Tintenstrahldruck und Verfahren zu deren Herstellung |
US6045917A (en) * | 1998-07-10 | 2000-04-04 | Eastman Kodak Company | Ink jet recording element |
JP2000247021A (ja) * | 1999-03-04 | 2000-09-12 | Oji Paper Co Ltd | インクジェット記録体 |
US6492005B1 (en) * | 1999-03-09 | 2002-12-10 | Konica Corporation | Ink jet recording sheet |
DE60223734T2 (de) * | 2001-01-26 | 2008-10-30 | Eastman Kodak Co. | Tintenstrahlaufzeichnungselement und Druckverfahren |
-
2002
- 2002-08-16 EP EP20020078397 patent/EP1288008B1/fr not_active Expired - Fee Related
- 2002-08-16 DE DE2002607946 patent/DE60207946T2/de not_active Expired - Lifetime
- 2002-08-28 JP JP2002248865A patent/JP2003145926A/ja not_active Withdrawn
- 2002-08-30 CN CN 02132116 patent/CN1406760A/zh active Pending
-
2008
- 2008-05-28 JP JP2008139840A patent/JP2008260299A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4239543A (en) | 1979-02-09 | 1980-12-16 | Gould Inc. | Non-crusting jet ink and method of making same |
US4381946A (en) | 1980-02-25 | 1983-05-03 | Konishiroku Photo Industry Co., Ltd. | Ink composition for ink-jet recording |
US4781758A (en) | 1987-10-22 | 1988-11-01 | International Business Machines Corporation | Ink composition for drop-on-demand ink jet |
US5244861A (en) | 1992-01-17 | 1993-09-14 | Eastman Kodak Company | Receiving element for use in thermal dye transfer |
US6089704A (en) | 1998-10-19 | 2000-07-18 | Eastman Kodak Company | Overcoat for ink jet recording element |
US6096469A (en) | 1999-05-18 | 2000-08-01 | 3M Innovative Properties Company | Ink receptor media suitable for inkjet printing |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008082475A1 (fr) * | 2006-12-29 | 2008-07-10 | Eastman Kodak Company | Elément d'enregistrement d'image comprenant des particules mordantes encapsulées |
US7833591B2 (en) | 2006-12-29 | 2010-11-16 | Eastman Kodak Company | Image recording element comprising encapsulated mordant particles |
Also Published As
Publication number | Publication date |
---|---|
CN1406760A (zh) | 2003-04-02 |
JP2008260299A (ja) | 2008-10-30 |
EP1288008A3 (fr) | 2003-10-15 |
DE60207946D1 (de) | 2006-01-19 |
EP1288008B1 (fr) | 2005-12-14 |
JP2003145926A (ja) | 2003-05-21 |
DE60207946T2 (de) | 2006-08-17 |
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