EP1288012B1 - Elément pour impression par jet d'encre et procédé d'impression - Google Patents

Elément pour impression par jet d'encre et procédé d'impression Download PDF

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Publication number
EP1288012B1
EP1288012B1 EP20020078432 EP02078432A EP1288012B1 EP 1288012 B1 EP1288012 B1 EP 1288012B1 EP 20020078432 EP20020078432 EP 20020078432 EP 02078432 A EP02078432 A EP 02078432A EP 1288012 B1 EP1288012 B1 EP 1288012B1
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EP
European Patent Office
Prior art keywords
particles
recording element
cationic
ink jet
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP20020078432
Other languages
German (de)
English (en)
Other versions
EP1288012A2 (fr
EP1288012A3 (fr
Inventor
Sridhar Sadasivan
Lixin Chu
John Marion Baier
Yongcai Wang
Lori Jeanne Shaw-Klein
Elizabeth Ann Gallo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/944,555 external-priority patent/US6447110B1/en
Priority claimed from US09/943,952 external-priority patent/US6689430B2/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of EP1288012A2 publication Critical patent/EP1288012A2/fr
Publication of EP1288012A3 publication Critical patent/EP1288012A3/fr
Application granted granted Critical
Publication of EP1288012B1 publication Critical patent/EP1288012B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Definitions

  • the present invention relates to a porous ink jet recording element and printing method using the recording element.
  • ink droplets are ejected from a nozzle at high speed towards a recording element or medium to produce an image on the medium.
  • the ink droplets, or recording liquid generally comprise a recording agent, such as a dye or pigment, and a large amount of solvent.
  • the solvent, or carrier liquid typically is made up of water and an organic material such as a monohydric alcohol, a polyhydric alcohol or mixtures thereof.
  • An ink jet recording element typically comprises a support having on at least one surface thereof an ink-receiving or image-receiving layer, and includes those intended for reflection viewing, which have an opaque support, and those intended for viewing by transmitted light, which have a transparent support.
  • porous recording elements have been developed which provide nearly instantaneous drying as long as they have sufficient thickness and pore volume to effectively contain the liquid ink.
  • a porous recording element can be manufactured by cast coating, in which a particulate-containing coating is applied to a support and is dried in contact with a polished smooth surface.
  • EP 1,002,660 relates to a porous ink jet recording element comprising fine particles, hydrophilic binder and a water-soluble, cationic polymer.
  • a porous ink jet recording element comprising fine particles, hydrophilic binder and a water-soluble, cationic polymer.
  • this element there is a problem with this element in that the density of an image printed on such an element using a water-soluble cationic polymer is lower than one would like.
  • U.S. Patent 6,089,704 relates to a nonporous ink jet recording element comprising a cationic polymeric vinyl latex and a hydrophilic polymer.
  • a nonporous recording element in that images printed thereon dry too slowly.
  • U.S. Patent 6,096,469 relates to an ink jet recording element comprising mesoporous particles dispersed in an organic binder.
  • the organic binder can be a cationic latex polymer "having less than 10 mole percent of a copolymerizable monomer having a tertamino or quaternary ammonium functionality.”
  • this element there is a problem with this element in that the density of an image printed on such an element with a binder having less than 10 mole percent of a cationic mordant functionality is lower than one would like.
  • EP-A-1226962 discloses inorganic primary particle in a porous base layer and, in a porous base layer, particles that are agrgregated. Water insoluble, cationic polymeric particles comprising at least 20 mole % of a cationic mordant are also present in the porous upper layer.
  • Another object of the invention is to provide a printing method using the above-described element.
  • an ink jet recording element comprising a support having thereon an image-receiving layer comprising in the same layer:
  • the porous ink jet recording element of the invention has superior optical densities, good image quality and has an excellent dry time.
  • Examples of (a) inorganic particles useful in the invention include alumina, boehmite, hydrated alumina, silica, titanium dioxide, zirconium dioxide, clay, calcium carbonate, inorganic silicates or barium sulfate.
  • the particles may be porous or nonporous.
  • the (a) inorganic particles are alumina fumed oxides. Fumed oxides are available in dry form or as dispersions of the aggregates.
  • inorganic particles While many types of inorganic particles are manufactured by various methods and commercially available for an image-receiving layer, porosity of the image-receiving layer is necessary in order to obtain very fast ink drying.
  • the pores formed between the particles must be sufficiently large and interconnected so that the printing ink passes quickly through the layer and away from the outer surface to give the impression of fast drying.
  • the particles must be arranged in such a way so that the pores formed between them are sufficiently small so that they do not scatter visible light.
  • the (a) inorganic particles are in the form aggregated particles.
  • the aggregates are comprised of smaller primary particles 7 to 40 nm in diameter, and are aggregated up to 500 nm in diameter.
  • the (a) inorganic particles have a mean aggregate particle size of from 50 nm to 200 nm.
  • colloidal particles useful in the invention include alumina, boehmite, hydrated alumina, silica, titanium dioxide, zirconium dioxide, clay, calcium carbonate, inorganic silicates, barium sulfate or organic particles.
  • organic particles useful in the invention are disclosed and claimed in U.S. Patent Application Serial Numbers: 09/458,401, filed Dec. 10, 1999; 09/608,969, filed June 30, 2000; 09/607,417, filed June 30, 2000; 09/608,466, filed June 30, 2000; 09/607,419, filed June 30, 2000; and 9/822,731, filed March 30, 2001.
  • the (b) colloidal particles are silica, alumina, boehmite or hydrated alumina.
  • the particles may be porous or nonporous.
  • the (b) colloidal particles are in the form of primary particles.
  • the mean particle size of the primary particles may range from 20 nm to 500 nm.
  • the (c) water insoluble, cationic, polymeric particles comprising at least 20 mole percent of a cationic mordant moiety useful in the invention can be in the form of a latex, water dispersible polymer, beads, or core/shell particles wherein the core is organic or inorganic and the shell in either case is a cationic polymer.
  • Such particles can be products of addition or condensation polymerization, or a combination of both. They can be linear, branched, hyper-branched, grafted, random, blocked, or can have other polymer microstructures well known to those in the art. They also can be partially crosslinked.. Examples of core/shell particles useful in the invention are disclosed and claimed in U.S. Patent Application Serial No.
  • the (c) water insoluble, cationic, polymeric particles comprise at least 50 mole percent of a cationic mordant moiety.
  • the (c) water insoluble, cationic, polymeric particles which may be used are in the form of a latex.
  • the latex contains a polymer having a quaternary ammonium salt moiety.
  • the latex contains a polymer having a (vinylbenzyl)trimethyl ammonium salt moiety.
  • the latex contains a polymer having a (vinylbenzyl)dimethyl benzyl quaternary ammonium salt moiety.
  • the (c) water-insoluble, cationic, polymeric particles comprises a mixture of a latex containing a polymer having a (vinylbenzyl)trimethyl quaternary ammonium salt moiety and a polymer having a (vinylbenzyl)dimethylbenzyl quaternary ammonium salt moiety.
  • the (c) water insoluble, cationic, polymeric particles useful in the invention can be derived from nonionic, anionic, or cationic monomers. In a preferred embodiment, combinations of nonionic and cationic monomers are employed. In general, the amount of cationic monomer employed in the combination is at least 20 mole percent.
  • the nonionic, anionic, or cationic monomers employed can include neutral, anionic or cationic derivatives of addition polymerizable monomers such as styrenes, alpha-alkylstyrenes, acrylate esters derived from alcohols or phenols, methacrylate esters, vinylimidazoles, vinylpyridines, vinylpyrrolidinones, acrylamides, methacrylamides, vinyl esters derived from straight chain and branched acids (e.g., vinyl acetate), vinyl ethers (e.g., vinyl methyl ether), vinyl nitriles, vinyl ketones, halogen-containing monomers such as vinyl chloride, and olefins, such as butadiene.
  • addition polymerizable monomers such as styrenes, alpha-alkylstyrenes, acrylate esters derived from alcohols or phenols, methacrylate esters, vinylimidazoles, vinylpyridines, vinylpyrroli
  • nonionic, anionic, or cationic monomers employed can also include neutral, anionic or cationic derivatives of condensation polymerizable monomers such as those used to prepare polyesters, polyethers, polycarbonates, polyureas and polyurethanes.
  • the (c) water insoluble, cationic, polymeric particles employed in this invention can be prepared using conventional polymerization techniques including, but not limited to bulk, solution, emulsion, or suspension polymerization.
  • the (c) water insoluble, cationic, polymeric particles employed have a mean particle size of from 10 to 500 nm.
  • the amount of (c) water insoluble, cationic, polymeric particles used should be high enough so that the images printed on the recording element will have a sufficiently high density, but low enough so that the interconnected pore structure formed by the aggregates is not filled.
  • the (a) inorganic particles are present in an amount from 10 to 50 weight % of the image-recording layer
  • the (b) colloidal particles are present in an amount of from 50 to 80 weight %
  • the (c) water-insoluble, cationic, polymeric particles are present in an amount of from 5 to 30 weight %.
  • (c) water insoluble, cationic, polymeric particles which may be used in the invention include those described in U.S. Patent 3,958,995. Specific examples of these polymers include:
  • the image-receiving layer also contains a polymeric binder in an amount insufficient to alter the porosity of the porous receiving layer.
  • the polymeric binder is a hydrophilic polymer such as poly(vinyl alcohol), poly(vinyl pyrrolidone), gelatin, cellulose ethers, poly(oxazolines), poly(vinylacetamides), partially hydrolyzed poly(vinyl acetate/vinyl alcohol), poly(acrylic acid), poly(acrylamide), poly(alkylene oxide), sulfonated or phosphated polyesters and polystyrenes, casein, zein, albumin, chitin, chitosan, dextran, pectin, collagen derivatives, collodian, agar-agar, arrowroot, guar, carrageenan, tragacanth, xanthan, rhamsan and the like.
  • the hydrophilic polymer is poly(vinyl alcohol), hydroxypropyl cellulose, hydroxypropyl methyl cellulose, gelatin, or a poly(alkylene oxide).
  • the hydrophilic binder is poly(vinyl alcohol). The polymeric binder should be chosen so that it is compatible with the aforementioned particles.
  • the amount of binder used should be sufficient to impart cohesive strength to the ink jet recording element, but should also be minimized so that the interconnected pore structure formed by the aggregates is not filled in by the binder.
  • the binder is present in an amount of from 5 to 20 weight %
  • the thickness of the image-receiving layer may range from about 5 to 40 ⁇ m, preferably from 10 to 20 ⁇ m.
  • the coating thickness required is determined through the need for the coating to act as a sump for absorption of ink solvent and the need to hold the ink near the coating surface.
  • the recording element also contains a base layer having at least 50% by weight of inorganic particles.
  • the base layer is coated between the support and the image-receiving layer.
  • the inorganic particles in the base layer comprise calcium carbonate, magnesium carbonate, barium sulfate, silica, alumina, boehmite hydrated alumina, clay or titanium oxide.
  • the inorganic particles in the base layer have an anionic surface charge.
  • the inorganic particles in the base layer have a mean particle size of from 100 nm to 5 ⁇ m.
  • the base layer contains a binder such as a polymeric material and/or a latex material, such as poly(vinyl alcohol) and/or styrene-butadiene latex.
  • a binder such as a polymeric material and/or a latex material, such as poly(vinyl alcohol) and/or styrene-butadiene latex.
  • the binder in the base layer is present in an amount of from 5 to 20 weight %.
  • the thickness of the base layer may range from 5 ⁇ m to 50 ⁇ m, preferably from 20 to 40 ⁇ m.
  • the ink jet recording element may be subject to calendering or supercalendering to enhance surface smoothness.
  • the ink jet recording element is subject to hot, soft-nip calendering at a temperature of 65 ° C and pressure of 14000 kg/m at a speed of from 0.15 m/s to 0.3 m/s.
  • the support for the ink jet recording element used in the invention can be any of those usually used for ink jet receivers, such as resin-coated paper, paper, polyesters, or microporous materials such as polyethylene polymer-containing material sold by PPG Industries, Inc., Pittsburgh, Pennsylvania under the trade name of Teslin ®, Tyvek ® synthetic paper (DuPont Corp.), and OPPalyte® films (Mobil Chemical Co.) and other composite films listed in U.S. Patent 5,244,861.
  • Opaque supports include plain paper, coated paper, synthetic paper, photographic paper support, melt-extrusion-coated paper, and laminated paper, such as biaxially oriented support laminates. Biaxially oriented support laminates are described in U.S.
  • biaxially oriented supports include a paper base and a biaxially oriented polyolefin sheet, typically polypropylene, laminated to one or both sides of the paper base.
  • Transparent supports include glass, cellulose derivatives, e.g., a cellulose ester, cellulose triacetate, cellulose diacetate, cellulose acetate propionate, cellulose acetate butyrate; polyesters, such as poly(ethylene terephthalate), poly(ethylene naphthalate), poly(1,4-cyclohexanedimethylene terephthalate), poly(butylene terephthalate), and copolymers thereof; polyimides; polyamides; polycarbonates; polystyrene; polyolefins, such as polyethylene or polypropylene; polysulfones; polyacrylates; polyetherimides; and mixtures thereof.
  • the papers listed above include a broad range of papers, from high end papers, such as photographic paper to low end papers, such as newsprint. In a preferred embodiment, polyethylene-coated paper is employed.
  • the support used in the invention may have a thickness of from 50 to 500 ⁇ m, preferably from 75 to 300 ⁇ m.
  • Antioxidants, antistatic agents, plasticizers and other known additives may be incorporated into the support, if desired.
  • the surface of the support may be subjected to a corona-discharge treatment prior to applying the image-receiving layer.
  • Coating compositions employed in the invention may be applied by any number of well known techniques, including dip-coating, wound-wire rod coating, doctor blade coating, rod coating, air knife coating, gravure and reverse-roll coating, slide coating, bead coating, extrusion coating, curtain coating and the like.
  • Known coating and drying methods are described in further detail in Research Disclosure no. 308119, published Dec. 1989, pages 1007 to 1008. Slide coating is preferred, in which the base layers and overcoat may be simultaneously applied. After coating, the layers are generally dried by simple evaporation, which may be accelerated by known techniques such as convection heating.
  • crosslinkers which act upon the binder discussed above may be added in small quantities. Such an additive improves the cohesive strength of the layer.
  • Crosslinkers such as carbodiimides, polyfunctional aziridines, aldehydes, isocyanates, epoxides, polyvalent metal cations, and the like may all be used.
  • UV absorbers may also be added to the image-receiving layer as is well known in the art.
  • Other additives include pH modifiers, adhesion promoters, rheology modifiers, surfactants, biocides, lubricants, dyes, optical brighteners, matte agents, antistatic agents, etc.
  • additives known to those familiar with such art such as surfactants, defoamers, alcohol and the like may be used.
  • a common level for coating aids is 0.01 to 0.30 % active coating aid based on the total solution weight.
  • These coating aids can be nonionic, anionic, cationic or amphoteric. Specific examples are described in MCCUTCHEON's Volume 1: Emulsifiers and Detergents, 1995, North American Edition.
  • the coating composition can be coated either from water or organic solvents, however water is preferred.
  • the total solids content should be selected to yield a useful coating thickness in the most economical way, and for particulate coating formulations, solids contents from 10-40% are typical.
  • Inkjet inks used to image the recording elements of the present invention are well-known in the art.
  • the ink compositions used in ink jet printing typically are liquid compositions comprising a solvent or carrier liquid, dyes or pigments, humectants, organic solvents, detergents, thickeners, preservatives, and the like.
  • the solvent or carrier liquid can be solely water or can be water mixed with other water-miscible solvents such as polyhydric alcohols.
  • Inks in which organic materials such as polyhydric alcohols are the predominant carrier or solvent liquid may also be used. Particularly useful are mixed solvents of water and polyhydric alcohols.
  • the dyes used in such compositions are typically water-soluble direct or acid type dyes.
  • Such liquid compositions have been described extensively in the prior art including, for example, U.S. Patents 4,381,946; 4,239,543 and 4,781,758.
  • a coating solution for a base layer was prepared by mixing 100 dry g of precipitated calcium carbonate Albagloss-s® (Specialty Minerals Inc.) as a 70% solution and 8.5 dry g of silica gel Gasil® 23F (Crosfield Ltd.) with 0.5 dry g of a poly(vinyl alcohol) Gohsenol® GH-17 (Nippon Gohsei Co., Ltd.) as a 10% solution and 5 dry g of styrene-butadiene latex CP692NA ® (Dow Chemicals) as a 50% solution. The solids of the coating solution was adjusted to 35% by adding water.
  • the base layer coating solution was bead-coated at 25 °C on a base paper, basis weight 185 g/m 2 , and dried at 60°C by forced air.
  • the thickness of the base coating was 25 ⁇ m or 27 g/m 2 .
  • a coating solution for the image-receiving layer was prepared by combining alumina Dispal® 14N4-80 (Condea Vista Co.), fumed alumina Cab-O-Sperse® PG003 (Cabot Corp.), poly(vinyl alcohol) (Gohsenol® GH-17, Nippon Gohsei Co.) and Polymer A illustrated above in a ratio of 66:20:4:10 to give an aqueous coating formulation of 15% solids by weight.
  • Surfactants Zonyl® FS-300 (DuPont Co.) and Silwet® L-7602 (Witco Corp.) were added in small amounts as coating aids.
  • the image-receiving layer coating solution was coated on top of this base layer.
  • the recording element was then dried at 60°C by forced air to yield a two-layer recording element.
  • the thickness of the image-receiving layer was 8 ⁇ m or 8.6 g/m 2 .
  • Element 2 was prepared the same as Element 1 except that Polymer B was used instead of Polymer A.
  • Element 3 was prepared the same as Element 1 except that the ratio for the image-receiving layer was 62:19:4:15 for alumina to fumed alumina to poly (vinyl alcohol) to Polymer A.
  • Element 4 was prepared the same as Element 1 except that the ratio for the image-receiving layer was 62:19:4:15 for alumina to fumed alumina to poly (vinyl alcohol) to Polymer B.
  • Comparative Element 1 no water-insoluble, cationic polymeric particles
  • This element was prepared the same as Element 1 except that water-soluble Polymer C-1 was used instead of Polymer A.
  • Comparative Element 2 no water-insoluble, cationic polymeric particles
  • This element was prepared the same as Element 1 except that water-soluble Polymer C-2 was used instead of Polymer A.
  • This element was prepared the same as Element 1 except that the image-receiving layer contained only alumina, fumed alumina and poly (vinyl alcohol) in the ratio 74:22:4.
  • Comparative Element 4 no aggregate particles or cationic polymeric particles
  • This element was prepared the same as Element 1 except that the image-receiving layer contained only alumina and poly (vinyl alcohol) in a ratio of 96:4.
  • Comparative Element 5 no colloidal particles or cationic polymeric particles
  • This element was prepared the same as Element 1 except that the image-receiving layer contained only fumed alumina and poly (vinyl alcohol) in a ratio of 96:4.
  • Test images of cyan, magenta, yellow, red, green and blue patches at 100% ink laydown were printed on the above elements using a Hewlett-Packard DeskJet 970 printer with an ink cartridge having catalogue number C6578DN.
  • the Status A D-max densities were measured using an X-Rite® 820 densitometer. For each of the red, green and blue densities, the two component color densities were measured and averaged.

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  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)

Claims (8)

  1. Elément pour l'enregistrement par jet d'encre poreux comprenant un support revêtu d'une couche réceptrice d'image comprenant dans la même couche :
    (a) des particules inorganiques ayant une taille primaire de particule comprise entre 7 et 40 nm de diamètre, lesdites particules sont agglomérées jusqu'à atteindre une taille de 500 nm, où lesdites particules inorganiques sont de l'alumine calcinée ;
    (b) des particules colloïdales sous la forme de particules primaires ayant une taille moyenne de particule comprise entre 20 et 500 nm, où lesdites particules colloïdales sont l'alumine, la boehmite, l'alumine hydratée, la silice, le dioxyde de titane, le dioxyde de zirconium, l'argile, le carbonate de calcium, les silicates inorganiques ou le sulfate de baryum ; et
    (c) des particules polymères cationiques insolubles dans l'eau comprenant au moins 20% en moles d'un radical mordant cationique.
  2. Elément d'enregistrement selon la revendication 1, dans lequel lesdites particules inorganiques (a) ont une taille moyenne de particule comprise entre 50 et 200 nm.
  3. Elément d'enregistrement selon la revendication 1, dans lequel lesdites particules colloïdales (b) ont une taille moyenne de particule comprise entre 50 et 200 nm.
  4. Elément d'enregistrement selon la revendication 1, dans lequel lesdites particules polymères cationiques insolubles dans l'eau (c) sont sous forme de latex.
  5. Elément d'enregistrement selon la revendication 4, dans lequel ledit latex contient un polymère ayant un radical d'un sel d'ammonium quaternaire.
  6. Elément d'enregistrement selon la revendication 1, dans lequel lesdites particules polymères cationiques insolubles dans l'eau (c) comprennent un mélange de latex contenant un polymère ayant un radical d'un sel d'ammonium quaternaire vinylbenzyl triméthyle et un polymère ayant un radical d'un sel d'ammonium quaternaire vinylbenzyl diméthylbenzyle.
  7. Elément d'enregistrement selon la revendication 1, dans lequel lesdites particules polymères cationiques insolubles dans l'eau ont une taille moyenne de particule comprise entre 10 et 500 nm.
  8. Procédé d'impression par jet d'encre comprenant les étapes suivantes :
    A) disposer d'une imprimante à jet d'encre sensible à des signaux de données numériques ;
    B) charger dans ladite imprimante l'élément pour l'enregistrement par jet d'encre de la revendication 1 ;
    C) charger dans ladite imprimante une composition d'encre pour jet d'encre, et
    D) imprimer sur ladite couche réceptrice d'image en utilisant ladite composition d'encre pour jet d'encre en réponse auxdits signaux de données numériques.
EP20020078432 2001-08-31 2002-08-19 Elément pour impression par jet d'encre et procédé d'impression Expired - Lifetime EP1288012B1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US09/944,555 US6447110B1 (en) 2001-08-31 2001-08-31 Ink jet printing method
US944555 2001-08-31
US943952 2001-08-31
US09/943,952 US6689430B2 (en) 2001-08-31 2001-08-31 Ink jet recording element

Publications (3)

Publication Number Publication Date
EP1288012A2 EP1288012A2 (fr) 2003-03-05
EP1288012A3 EP1288012A3 (fr) 2003-10-15
EP1288012B1 true EP1288012B1 (fr) 2006-03-22

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EP20020078432 Expired - Lifetime EP1288012B1 (fr) 2001-08-31 2002-08-19 Elément pour impression par jet d'encre et procédé d'impression

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EP (1) EP1288012B1 (fr)
JP (1) JP4149764B2 (fr)
DE (1) DE60209998T2 (fr)

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EP1630600A3 (fr) * 2004-07-29 2006-03-22 Rohm and Haas Electronic Materials, L.L.C. Composition thermofusible et procédé comportant la formation d'un motif de masquage
FR2881230B1 (fr) 2005-01-25 2007-04-20 Essilor Int Methode de coloration d'une lentille optique comprenant un primaire d'impression, et lentille optique teintee comprenant un tel primaire d'impression
US7829160B2 (en) * 2006-02-28 2010-11-09 Eastman Kodak Company Glossy inkjet recording element on absorbent paper
US7718237B2 (en) * 2006-02-28 2010-05-18 Eastman Kodak Company Glossy inkjet recording element on absorbent paper and capable of absorbing high ink flux
US7833591B2 (en) 2006-12-29 2010-11-16 Eastman Kodak Company Image recording element comprising encapsulated mordant particles
US7906185B2 (en) 2007-01-30 2011-03-15 Hewlett-Packard Development Company, L.P. Inkjet recording media
JP5982254B2 (ja) 2012-10-25 2016-08-31 富士フイルム株式会社 印字方法

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Also Published As

Publication number Publication date
JP4149764B2 (ja) 2008-09-17
DE60209998T2 (de) 2006-12-21
EP1288012A2 (fr) 2003-03-05
JP2003145925A (ja) 2003-05-21
EP1288012A3 (fr) 2003-10-15
DE60209998D1 (de) 2006-05-11

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