EP1264561B9 - Matériau non-tissé et procédé de fabrication - Google Patents

Matériau non-tissé et procédé de fabrication Download PDF

Info

Publication number
EP1264561B9
EP1264561B9 EP02011653A EP02011653A EP1264561B9 EP 1264561 B9 EP1264561 B9 EP 1264561B9 EP 02011653 A EP02011653 A EP 02011653A EP 02011653 A EP02011653 A EP 02011653A EP 1264561 B9 EP1264561 B9 EP 1264561B9
Authority
EP
European Patent Office
Prior art keywords
layer
fibres
cotton wool
pad according
wool pad
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02011653A
Other languages
German (de)
English (en)
Other versions
EP1264561A1 (fr
EP1264561B2 (fr
EP1264561B1 (fr
Inventor
Rainer Dr. Mangold
Maximilian Pütz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Paul Hartmann AG
Original Assignee
Paul Hartmann AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7687413&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1264561(B9) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Paul Hartmann AG filed Critical Paul Hartmann AG
Publication of EP1264561A1 publication Critical patent/EP1264561A1/fr
Publication of EP1264561B1 publication Critical patent/EP1264561B1/fr
Publication of EP1264561B2 publication Critical patent/EP1264561B2/fr
Application granted granted Critical
Publication of EP1264561B9 publication Critical patent/EP1264561B9/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5412Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/02Cotton wool; Wadding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266Natural fibres not provided for in group D04H1/425
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/4291Olefin series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5418Mixed fibres, e.g. at least two chemically different fibres or fibre blends
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542Adhesive fibres
    • D04H1/544Olefin series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542Adhesive fibres
    • D04H1/55Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics

Definitions

  • the invention relates to a cotton pad for skin care and cleansing and for cosmetic purposes, with two nonwoven fabric layers.
  • a composite nonwoven fabric having a first soft feel surface and a second face away from the first and rough to the first is known.
  • the layer which forms the rough-feeling surface comprises at least partially thermoplastic fibers, preferably from the class of polyolefins.
  • the other layer comprises natural and / or synthetic fibers, which have a lower fiber thickness than those of the other layer and form the soft-feeling surface.
  • the document teaches to connect the layers by water jet needling together. In a subsequent heat treatment, only the free ends of the thermoplastic fibers projecting from the rough-feeling surface layer are melted to enhance the impression of a rough surface.
  • Out EP 0 405 043 A1 For example, there is known a composite nonwoven material for cosmetic use which has two outer layers forming the first and second surfaces and an inner layer disposed therebetween.
  • the layers may be formed of cotton, viscose, synthetic fibers or a mixture thereof.
  • the cohesion of the layers is created by bonding the outer layers to their peripheral edge regions by means of suitable adhesives or by compression.
  • US-A-5,480,699 shows a two-layer composite nonwoven material for cosmetic use with at least two layers. At least the outer layers are compacted to the same or different extent by embossing. As materials cotton, viscose, synthetic fibers or mixtures thereof are indicated. The possibility of producing embossed patterns on the outer layers is also mentioned.
  • FR-A-2052089 shows a two-layer composite nonwoven fabric for cosmetic purposes made of cotton, whose layers are connected by punctiform or linear embossing
  • EP-A-0 441 667 discloses an at least three-layered cotton pad, wherein on both sides of a thin barrier layer per an absorbent nonwoven fabric layer is provided.
  • the present invention has for its object to provide a cotton pad for skin care and cleansing and cosmetic purposes with two nonwoven fabric layers, which can be produced easily and inexpensively and has different trained surfaces, which can preferably be distinguished by tactile perception, wherein the cotton pad is said to be at least equivalent to known materials in terms of a pleasant feel on the skin of a user.
  • the cellulosic fibers of the first layer which are preferably cotton fibers; especially cotton noils, acts to form a first soft-feeling surface of the cotton pad.
  • the second surface facing away from this first surface which is formed by the second nonwoven fabric layer, feels rougher. This rough feel is due to the melt-set thermoplastic fibers of the second layer and the embossing pattern on the surface of the second layer.
  • first layer has been subjected to water jet needling prior to being bonded to the second nonwoven layer in order to increase the integrity of the fibers of that first layer, particularly if there are a few thermoplastic fibers in that first layer ,
  • the thermoplastic fibers present in the first layer are preferably polyester fibers.
  • the thermoplastic fibers of the second layer are at least partially, but especially 100% polyester fibers.
  • PET fibers polyester fibers
  • the use of polyester fibers (PES) as the first thermoplastic fiber in the top layer proves to be particularly advantageous because of its lofty resiliency, as this can easily and effectively prevent it from being deposited on the opposite surface the second layer provided embossing pattern transmits to the first layer or pushed through to the first layer.
  • the melting point of the first thermoplastic fibers provided in the first layer is higher than the melting point of the second thermoplastic fibers, these first thermoplastic fibers themselves are not melted and the surface of the first layer remains soft and gives a soft, perceived as pleasant feeling, due to the cellulosic fibers, which preferably form 90 to 98% by weight of the first layer.
  • the polyester fibers of the first and in particular of the second layer are bicomponent fibers.
  • the polyester bicomponent fibers of the second layer may comprise a low-melting component of polyethylene (PE) and a higher-melting component of polyester (PES).
  • the polyester bicomponent fibers have a polyester core (PES) and a polyethylene (PE) shell.
  • the fiber thickness of the bicomponent fibers is advantageously 1.0 to 6.5 dtex, in particular 1.2 to 4.0 dtex, and preferably 1.5 to 3.0 dtex.
  • the fiber length is advantageously selected from 10 to 80 mm, in particular from 20 to 70 mm and preferably from 40 to 50 mm.
  • the second layer in addition to the thermoplastic fibers and cellulosic fibers in particular from 50 to 95 wt .-%, and preferably comprises from 70 to 95 wt .-%.
  • the proportion of the thermoplastic fibers preferably formed from polyester bicomponent fibers is from 5 to 50% by weight, and preferably from 5 to 30% by weight, of the particular layer considered.
  • the weight per unit area of the first and the second layer is in each case 100 to 150 g / m 2 .
  • the invention also relates to a method for producing a cotton pad according to the invention with the features of claim 20.
  • the first layer is water jet-needled before the layers are arranged one above the other and joined together by heating the layer arrangement.
  • the heating of the layer arrangement can be achieved in any way ansich, advantageously, a hot gas flow is used for this purpose.
  • FIG. 1 1 schematically shows an embodiment of a composite nonwoven material 2 having a first nonwoven fabric layer 4 which forms a first soft-feeling surface 6, and a second nonwoven fabric layer 8 which forms a rough-feeling surface 10 with respect to the first surface 6.
  • the first layer 4 consists of 100% cotton seedlings. It was water jet needled before being placed over and bonded to the second layer 8.
  • the second layer 8 comprises 87% by weight of cotton combing and 13% by weight of polyester bicomponent fibers.
  • the polyester (PES) bicomponent fibers comprise, as a low-melting component, co-polyesters having a melting point of 160 ° C and, as a higher-melting component, polyesters having a melting point of 260 ° C.
  • the length of the fibers is 51 mm.
  • the fiber thickness is 2.5 dtex.
  • the first surface provides a very soft feel and is suitable for applying lotions, creams or the like.
  • the second surface 10, which has an embossed pattern, is suitable for make-up removal.
  • FIG. 12 shows an embodiment of a composite nonwoven material 12 for forming a cotton pad according to the invention, comprising a first layer 14 consisting of 95% by weight of cotton seedlings and 5% of PES bicomponent fibers associated with FIG. 1
  • the second nonwoven fabric layer 16 consists of 85% by weight of cotton fibers and 15% by weight of polyethylene / polyester (PE / PES) bicomponent fibers, with polyethylene (PE) being the low melting component with a melting point of 120 ° C and polyester (PES) as the core of the bicomponent fiber forms the higher melting component with a melting point of 260 ° C.
  • PE polyethylene
  • PET polyester

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)
  • Laminated Bodies (AREA)

Claims (24)

  1. Tampon d'ouate à deux couches pour les soins et le nettoyage de la peau et pour applications cosmétiques, réalisé à partir d'un matériau non tissé comportant deux couches de non-tissé, la première couche de non-tissé comprenant des fibres cellulosiques et la deuxième couche de non-tissé comprenant des fibres thermoplastiques, et les deux couches de non-tissé étant reliées entre elles par l'intermédiaire de liaisons obtenues par fusion entre les fibres de la première couche et les fibres de la deuxième couche, et la deuxième couche présentant, sur sa surface dont l'orientation est à l'opposé à la première couche, un modèle gaufré, et la première couche de non-tissé comprenant des premières fibres thermoplastiques et la deuxième couche de non-tissé comprenant des deuxièmes fibres thermoplastiques, dont la température de fusion est inférieure à celle des premières fibres thermoplastiques prévues dans la première couche de non-tissé.
  2. Tampon d'ouate selon la revendication 1, caractérisé en ce que les fibres cellulosiques sont des fibres de coton.
  3. Tampon d'ouate selon la revendication 1 ou 2, caractérisé en ce que la première couche comprend 90 à 98 % en poids de fibres cellulosiques.
  4. Tampon d'ouate selon l'une des revendications 1 à 3, caractérisé en ce que la première couche est aiguilletée par jet d'eau.
  5. Tampon d'ouate selon l'une des revendications précédentes, caractérisé en ce que les fibres thermoplastiques prévues dans la première couche sont des fibres de polyester.
  6. Tampon d'ouate selon l'une des revendications précédentes, caractérisé en ce que les fibres thermoplastiques de la deuxième couche sont au moins en partie des fibres de polyester.
  7. Tampon d'ouate selon la revendication 6, caractérisé en ce que les fibres de polyester de la deuxième couche sont au moins en partie des fibres à deux composants.
  8. Tampon d'ouate selon la revendication 7, caractérisé en ce que les fibres, à deux composants de polyester de la deuxième couche, présentent un composant en polyéthylène (PE) à point de fusion bas et un composant en polyester (PES) à point de fusion élevé.
  9. Tampon d'ouate selon la revendication 8, caractérisé en ce que les fibres à deux composants de polyester de la deuxième couche présentent un noyau en polyester (PES) et une enveloppe à base de polyéthylène (PE).
  10. Tampon d'ouate selon l'une des revendications 7 à 9, caractérisé en ce que les fibres à deux composants présentent une épaisseur de fibres comprise entre 1,0 et 6,5 dtex.
  11. Tampon d'ouate selon la revendication 10, caractérisé en ce que les fibres à deux composants présentent une épaisseur de fibres comprise entre 1,2 et 4,0 dtex.
  12. Tampon d'ouate selon la revendication 11, caractérisé en ce que les fibres à deux composants présentent une épaisseur de fibres comprise entre 1,5 et 3,0 dtex.
  13. Tampon d'ouate selon l'une des revendications 7 à 12, caractérisé en ce que les fibres à deux composants présentent une longueur de fibres comprise entre 10 et 80 mm.
  14. Tampon d'ouate selon la revendication 13, caractérisé en ce que les fibres à deux composants présentent une longueur de fibres comprise entre 20 et 70 mm.
  15. Tampon d'ouate selon la revendication 14, caractérisé en ce que les fibres à deux composants présentent une longueur de fibres comprise entre 40 et 50 mm.
  16. Tampon d'ouate selon l'une des revendications précédentes, caractérisé en ce que la deuxième couche comprend, en plus des fibres thermoplastiques, 50 à 95 % en poids de fibres cellulosiques.
  17. Tampon d'ouate selon la revendication 16, caractérisé en ce que la deuxième couche comprend, en plus des fibres thermoplastiques, 70 à 95 % en poids de fibres cellulosiques.
  18. Tampon d'ouate selon la revendication 16 ou 17, caractérisé en ce que les fibres cellulosiques sont des fibres de coton.
  19. Tampon d'ouate selon l'une des revendications précédentes, caractérisé en ce que le poids par unité de surface des différentes couches est de 100 à 150 g/m2.
  20. Procédé de fabrication d'un tampon d'ouate selon l'une des revendications précédentes comprenant les étapes consistant à :
    - former une première couche avec des fibres cellulosiques et avec premières fibres thermoplastiques,
    - former une deuxième couche avec deuxièmes fibres thermoplastiques, dont la température de fusion est inférieure à celle des premières fibres thermoplastiques prévues dans la première couche de non-tissé,
    - agencer les couches l'une au-dessus de l'autre,
    - exercer une pression sur l'agencement de couches et chauffer l'agencement de couches, de telle sorte que les deuxièmes fibres thermoplastiques fondent au moins à leur surface et qu'il se forme ainsi des liaisons par fusion entre les fibres de la première couche et les fibres de la deuxième couche, lesquelles liaisons relient les couches entre elles, et qu'il se forme, en plus, des liaisons par fusion entre les fibres de la deuxième couche, lesquelles liaisons consolident la deuxième couche en elle-même, et qu'il est produit, par calandrage, un modèle gaufré sur la surface de la deuxième couche orientée à l'opposé de la première couche.
  21. Procédé selon la revendication 20, caractérisé en ce que la première couche est aiguilletée par jet d'eau avant que les couches soient agencées l'une au-dessus de l'autre.
  22. Procédé selon la revendication 21, caractérisé en ce que la première couche aiguilletée par jet d'eau est séchée avant que les couches soient agencées l'une au-dessus de l'autre.
  23. Procédé selon l'une des revendications 20 à 22, caractérisé en ce que le chauffage de l'agencement des couches est obtenu au moyen d'un flux de gaz chaud.
  24. Procédé selon l'une des revendications 20 à 23, caractérisé en ce que la pression exercée sur l'agencement de couches et le chauffage de l'agencement de couches sont réalisés par calandrage.
EP02011653A 2001-06-06 2002-05-31 Matériau non-tissé et procédé de fabrication Expired - Lifetime EP1264561B9 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10127514A DE10127514A1 (de) 2001-06-06 2001-06-06 Verbundvliesstoffmaterial und Verfahren zu seiner Herstellung
DE10127514 2001-06-06

Publications (4)

Publication Number Publication Date
EP1264561A1 EP1264561A1 (fr) 2002-12-11
EP1264561B1 EP1264561B1 (fr) 2006-06-21
EP1264561B2 EP1264561B2 (fr) 2009-08-19
EP1264561B9 true EP1264561B9 (fr) 2009-11-18

Family

ID=7687413

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02011653A Expired - Lifetime EP1264561B9 (fr) 2001-06-06 2002-05-31 Matériau non-tissé et procédé de fabrication

Country Status (3)

Country Link
EP (1) EP1264561B9 (fr)
AT (1) ATE330505T1 (fr)
DE (2) DE10127514A1 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE20118890U1 (de) * 2001-11-20 2002-01-24 Rauscher Consumer Products Gmbh, Wien Flächiges Produkt
JP4118640B2 (ja) 2002-09-17 2008-07-16 ユニ・チャーム株式会社 吸収性複合シートおよびこれを用いた吸収性物品
DE20305717U1 (de) * 2003-04-09 2004-08-19 W. Pelz Gmbh & Co. Wattepad
FR2867067B1 (fr) * 2004-03-08 2007-09-07 Oreal Article cosmetique a usage unique
US7514071B2 (en) 2004-03-08 2009-04-07 L'oreal S.A. Single-use cosmetic article
DE102005022577A1 (de) * 2005-05-09 2006-11-16 Paul Hartmann Ag Mehrfach auf sich selbst gefaltetes Watteband
DE102006020590A1 (de) * 2006-05-02 2007-11-08 Sandler Ag Tampon mit verbesserter Haftung zwischen Hülle & Kern
DE102007022368B4 (de) * 2007-05-07 2015-11-19 Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. Mehrlagiges Faserverbundhalbzeug aus kurzen Verstärkungsfasern mit optimierter Drapierbarkeit
US9682512B2 (en) 2009-02-06 2017-06-20 Nike, Inc. Methods of joining textiles and other elements incorporating a thermoplastic polymer material
US20100199406A1 (en) 2009-02-06 2010-08-12 Nike, Inc. Thermoplastic Non-Woven Textile Elements
US8906275B2 (en) 2012-05-29 2014-12-09 Nike, Inc. Textured elements incorporating non-woven textile materials and methods for manufacturing the textured elements
US8850719B2 (en) * 2009-02-06 2014-10-07 Nike, Inc. Layered thermoplastic non-woven textile elements
US20130255103A1 (en) 2012-04-03 2013-10-03 Nike, Inc. Apparel And Other Products Incorporating A Thermoplastic Polymer Material
CN106192200B (zh) * 2016-08-16 2018-07-13 南通纺织丝绸产业技术研究院 一种功能性保暖复合絮片的制备方法
CN111058188B (zh) * 2019-12-24 2022-02-15 福建恒安集团有限公司 天然纤维基无纺布

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2052089A5 (fr) * 1969-07-18 1971-04-09 Riethmann Eugene
US3837995A (en) * 1972-04-24 1974-09-24 Kimberly Clark Co Autogenously bonded composite web
GB1432978A (fr) 1973-04-10 1976-04-22
US4075382A (en) 1976-05-27 1978-02-21 The Procter & Gamble Company Disposable nonwoven surgical towel and method of making it
US4287251A (en) * 1978-06-16 1981-09-01 King Mary K Disposable absorbent nonwoven structure
US4196245A (en) 1978-06-16 1980-04-01 Buckeye Cellulos Corporation Composite nonwoven fabric comprising adjacent microfine fibers in layers
NZ201073A (en) 1981-07-10 1985-12-13 Chicopee An absorbent thermal bonded nonwoven fabric and its use in a catamenial device
CH672249A5 (en) * 1986-09-08 1989-11-15 Flawa Schweiz Verband Wattefab Liq. or paste handling plate - is in several layers, with one layer
ATE106007T1 (de) * 1989-02-22 1994-06-15 Flawa Schweiz Verband Wattefab Scheibe zum auftragen u./oder aufsaugen von flüssigen oder halbfesten substanzen.
FR2656780B1 (fr) * 1990-01-10 1993-08-06 Coativy Rene Dispositif pour demaquillage comportant une couche d'arret.
DE69110874D1 (de) * 1990-03-21 1995-08-03 Fiberweb North America Inc Nichtgewebter stoff für windeldeckblatt und verfahren zu dessen herstellung.
DE69310521T2 (de) 1992-08-27 1997-09-18 Procter & Gamble Seidenpapier mit biologisch abbaubaren nichtionischen weichmachern
DE4305271C2 (de) 1993-02-20 2000-06-08 Corovin Gmbh Verbundvlies sowie Verfahren zur Herstellung eines Verbundvlieses
FR2752248B1 (fr) * 1996-08-09 1998-09-25 Lystil Sa Materiau complexe non tisse absorbant comportant une face souple et une face rugueuse, et procede pour son obtention
JPH10113222A (ja) * 1996-10-15 1998-05-06 Toray Ind Inc 化粧綿
CA2273352A1 (fr) * 1996-12-06 1998-06-11 Charles E. Miller Composite stratifie unitaire
JP3400702B2 (ja) 1997-12-26 2003-04-28 ユニ・チャーム株式会社 不織布の製造方法

Also Published As

Publication number Publication date
ATE330505T1 (de) 2006-07-15
DE50207253D1 (de) 2006-08-03
DE10127514A1 (de) 2003-01-30
EP1264561A1 (fr) 2002-12-11
EP1264561B2 (fr) 2009-08-19
EP1264561B1 (fr) 2006-06-21

Similar Documents

Publication Publication Date Title
EP1264561B9 (fr) Matériau non-tissé et procédé de fabrication
DE69711616T2 (de) Dauerhafte, wasserstrahlenverfestigte vliesstoffe
DE69212169T2 (de) Verbundvliesstoff und sein Herstellungsverfahren
DE69033025T2 (de) Schmelzklebende mikrofasergenerierende Verbundfäden und damit hergestellter gewebter oder nicht gewebter Stoff
EP1228271B1 (fr) Materiau composite servant a former une couche, orientee vers le corps, d'un article d'hygiene, et article d'hygiene ainsi produit
DE60201609T2 (de) Aus faserschichten hergestelltes laminat
DE60132120T2 (de) Elastisches Laminat mit versteifter Bahn und Verfahren zu dessen Herstellung
EP2207926B1 (fr) Surface textile fixable
EP0993854B1 (fr) Filtre d'air
EP1045059A1 (fr) Chiffon de nettoyage
DE69925140T2 (de) Faservliess als unterlage und tufting-teppich
DE3586931T2 (de) Nichtgewobene verflochtene stoffbahn mit oberflaechig enthaltenden thermoplastischen fasern und verfahren zur herstellung derselben.
DE69402420T2 (de) Verbundvliesstoff, herstellungsverfahren und seine anwendung für alle saugfähigen hygienischen artikel
DE2518532B2 (de) Vorrichtung zum stellenweisen thermischen Binden eines Faservlieses
EP1712351A1 (fr) Textile non tisse élastique composite et procédé de préparation
EP1510334B1 (fr) Laminé fibreux et préparation d'un laminé fibreux
DE60012235T2 (de) Vliesstoff mit stabilisierten filamentbündeln
EP0751249B1 (fr) Procédé et dispositif de consolidation d'un non-tissé fibreux
DE69712791T2 (de) Oberflächenmaterial für absorbierende artikel, absorbierende artikel mit dem oberflächenmaterial und die benutzung dieses materials in absorbierenden artikel
DE19927785C2 (de) Textiler Verbundstoff mit hoher textiler Weichheit und verbesserter Lagenhaftung
DE10113425B4 (de) Druckelastisches textiles Klebeband
DE10212842A1 (de) Vliesmaterial mit elastischen Eigenschaften
DE4114839A1 (de) Mikrofaservlies sowie mikrofasern enthaltendes verbundvliesmaterial
DE19804940A1 (de) Textiler Schichtverbundstoff und Verfahren zu dessen Herstellung
WO2003076179A1 (fr) Materiau non tisse presentant des proprietes elastiques

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

17P Request for examination filed

Effective date: 20030503

AKX Designation fees paid

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

17Q First examination report despatched

Effective date: 20050127

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20060621

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060621

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060621

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060621

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: CH

Ref legal event code: NV

Representative=s name: MICHELI & CIE INGENIEURS-CONSEILS

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20060621

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REF Corresponds to:

Ref document number: 50207253

Country of ref document: DE

Date of ref document: 20060803

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060921

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060921

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061002

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061121

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
ET Fr: translation filed
REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: GEORGIA-PACIFIC FRANCE

Effective date: 20070320

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

BERE Be: lapsed

Owner name: PAUL HARTMANN A.G.

Effective date: 20070531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060922

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070531

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

27A Patent maintained in amended form

Effective date: 20090819

AK Designated contracting states

Kind code of ref document: B2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070531

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060621

REG Reference to a national code

Ref country code: CH

Ref legal event code: AEN

Free format text: AUFRECHTERHALTUNG DES PATENTES IN GEAENDERTER FORM

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060621

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

Free format text: REGISTERED BETWEEN 20101209 AND 20101215

REG Reference to a national code

Ref country code: FR

Ref legal event code: TQ

REG Reference to a national code

Ref country code: CH

Ref legal event code: PUEA

Owner name: PAUL HARTMANN AKTIENGESELLSCHAFT

Free format text: PAUL HARTMANN AKTIENGESELLSCHAFT#PAUL-HARTMANN-STRASSE 12#89522 HEIDENHEIM (DE) -TRANSFER TO- PAUL HARTMANN AKTIENGESELLSCHAFT#PAUL-HARTMANN-STRASSE 12#89522 HEIDENHEIM (DE) $ ECOWIPES SP. Z.O.O.#WARSZAWSKA 43/406#15-062 BIALYSTOK (PL)

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20160525

Year of fee payment: 15

Ref country code: CH

Payment date: 20160526

Year of fee payment: 15

Ref country code: GB

Payment date: 20160523

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20160523

Year of fee payment: 15

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 50207253

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20170531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170531

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170531

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20180131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171201

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170531