EP1236380B1 - Plasma nozzle - Google Patents

Plasma nozzle Download PDF

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Publication number
EP1236380B1
EP1236380B1 EP00990703A EP00990703A EP1236380B1 EP 1236380 B1 EP1236380 B1 EP 1236380B1 EP 00990703 A EP00990703 A EP 00990703A EP 00990703 A EP00990703 A EP 00990703A EP 1236380 B1 EP1236380 B1 EP 1236380B1
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EP
European Patent Office
Prior art keywords
nozzle
channel
plasma
housing
slot
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Expired - Lifetime
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EP00990703A
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German (de)
French (fr)
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EP1236380A1 (en
Inventor
Peter FÖRNSEL
Christian Buske
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Plasmatreat GmbH
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Plasmatreat GmbH
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Publication of EP1236380A1 publication Critical patent/EP1236380A1/en
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • H05H1/3468Vortex generators
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • H05H1/3478Geometrical details

Definitions

  • the invention relates to a plasma nozzle for the treatment of Surfaces, in particular for the pretreatment of Plastic surfaces, with a tubular, electric conductive housing, one of a working gas flowed through nozzle channel forms, and a High frequency generator for applying a voltage between the electrode and the housing.
  • a plasma nozzle of this type is described in DE 195 32 412 A1 described and serves, for example, Pre-treat plastic surfaces so that applying of adhesives, inks and the like on the Plastic surface allows or easier.
  • a such pretreatment is required because Plastic surfaces in the normal state not with Liquids are wettable and therefore the printing ink or do not accept the adhesive.
  • the surface structure of the plastic is changed so that the surface for liquids with relatively large Surface tension is wetted. The surface tension the fluids with which the surface just barely is a measure of the quality of the Pretreatment.
  • the plasma nozzle is a relatively cool, but highly reactive plasma jet reached, the about the shape and dimensions of a candle flame has and thus also the pretreatment of profile parts with relatively deep relief allowed. Because of the high Reactivity of the plasma jet is sufficient for a very short time Pre-treatment, so that the workpiece with correspondingly high Speed past the plasma jet are passed can. Due to the comparatively low temperature of the Plasma jet is therefore also the pretreatment of heat-sensitive plastics possible. There no Counter electrode on the back of the workpiece is required, the surfaces of any thick, block-like workpieces, hollow bodies and be easily pretreated. For one uniform treatment of larger surfaces is in the mentioned publication a battery of several offset plasma nozzles have been proposed. In However, this case is a relatively high apparatus Effort required.
  • the object of the invention is therefore to a plasma nozzle which defies a very compact construction Larger surface treatment of workpiece surfaces allows.
  • This task is characterized by a plasma nozzle of the type mentioned solved that the outlet of the nozzle channel as transverse to the longitudinal axis of the nozzle channel extending narrow slot is formed.
  • the working gas in the nozzle channel be twisted.
  • the twisted plasma jet can be with the help of the outlet slot fan-shaped. At most, the twisting leads to a minor S-shaped distortion of the fan when facing the mouth frontal the plasma nozzle looks.
  • the intensity distribution of the plasma along the length of the slot can be, for example thereby controlling that the width of the slot varies over the length becomes.
  • This arrangement is particularly simply connect when the mouth of the nozzle channel including the Slot and the cross channel through a separate mouthpiece of insulating Material (ceramic) or preferably made of metal is formed in the mouth of the housing is pressed or screwed.
  • the transverse channel is open at both ends, and these open ends are surrounded only with a certain distance from the walls of the housing, so that a part of the plasma can escape at the ends of the transverse channel and then deflected by the housing walls obliquely in the direction of the workpiece becomes.
  • the plasma compartment will then be particularly intense at both edges Boundary rays limited, which pull apart the fan formally. hereby can be the shape of the fan and the intensity distribution of the plasma jet within the fan, for example, adjust so that the downstream Edge of the plasma fan assumes a concave shape, so that the fan a Dovetail resembles.
  • the outer jacket of the housing of the plasma nozzle on both sides the plane of the fan auxiliary air to be supplied.
  • the outer surface of the housing of the plasma nozzle in the mouth region not conical, but is prism-shaped, so that two flat surfaces are formed, which converge to the plane of the fan.
  • the plasma nozzle shown in the drawing has a tubular housing 10, the one elongated, conically tapered at the bottom nozzle channel 12 forms.
  • the nozzle channel 12 is an electrically insulating ceramic tube 14 used.
  • a working gas, such as air, is from the drawing fed into the upper end of the nozzle channel 12 and with the aid of an in the ceramic tube 14 used twisting device 16 so twisted that it is vortex-shaped flows through the nozzle channel 12, as in the drawing by a helical arrow is symbolized.
  • a vortex core extending along the axis of the housing.
  • a pin-shaped electrode 18 is mounted, which is coaxial projects into the nozzle channel 12 and to the by means of a high voltage generator 20 a high-frequency AC voltage is applied.
  • High frequency generator 20 generated voltage is of the order of a few kilovolts and has, for example, a frequency of the order of 20 kHz.
  • the metal housing 10 is grounded and serves as a counter electrode, such that an electrical discharge between the electrode 18 and the housing 10 can be caused.
  • a corona discharge at the swirl device 16 and the electrode 18.
  • This corona discharge is a Arc discharge from the electrode 18 to the housing 10 ignited.
  • the arc 22 of this discharge is taken by the twisted inflowing working gas and channeled at the core of the vortex-shaped gas flow, so that the Arc then almost straight from the top of the electrode 18 along the Housing axis extends and only in the region of the mouth of the housing 10th branched radially on the housing wall.
  • a cylindrical mouthpiece 24 made of copper used In the mouth of the housing 10 is a cylindrical mouthpiece 24 made of copper used, the axially inner end rests against a shoulder 26 of the housing.
  • the conically tapered end of the nozzle channel 12 settles in the mouthpiece 24 continuous, with the same or slightly changed cone angle.
  • the arc 22 branches within the mouthpiece 24 on the conical walls of the mouthpiece.
  • the mouthpiece 24 has at the free, in Figure 1 lower end of a section 28th with a reduced diameter, with the peripheral wall of the housing 10th forms an open in the mouth direction annular channel 30.
  • the conically tapered Tip of the nozzle channel 12 opens into a transverse channel 32 through a Cross hole is formed in the section 28 and at both ends to the Ring channel 30 is open towards.
  • This transverse channel 32 according to Figure 2 a has circular cross-section, closes axially a narrower, diametrically through the mouthpiece extending slot 34 which, to the end face of the mouthpiece is open.
  • the swirling through the nozzle channel 12 flowing working gas comes in the vortex core in intimate contact with the arc 22, so that a highly reactive Plasma is produced at a relatively low temperature.
  • This plasma is distributed in the transverse channel 32 and then enters partly through the slot 34 and partly also through the open ends of the transverse channel 32 and the annular channel 30 from the plasma nozzle.
  • a plasma jet 36 in the form of a flat fan generated in the edge regions 38 a greater density and a greater flow velocity than near the nozzle axis having.
  • the range of the plasma jet 36 at the edges is greater as in the middle, so that the downstream edge 40 of the plasma jet a has concave curvature and thus the subjects overall the shape of a Swallowtail accepts.
  • This shape of the plasma jet ensures that the plasma jet fits snugly against the workpiece, not shown.
  • Figure 3 shows a modified embodiment in which the annular channel and the transverse channel are absent and at the mouthpiece at the free end is bounded on both sides of the slot 34 by inclined surfaces with corresponding inclined surfaces of the housing 10 are flush.
  • the housing 10 is here surrounded by an air distributor 42, by the auxiliary air 44 parallel to the inclined surfaces of the housing and the mouthpiece 24 from both sides blown out of the slot 34 plasma jet 36 is blown to the fan-shaped plasma jet to bundle and premature expansion of this To prevent plasma jet in the direction perpendicular to the plane of the fan direction.
  • the auxiliary air also makes intimate contact with the plasma jet supported with the surface of the workpiece.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Geometry (AREA)
  • Plasma Technology (AREA)
  • Arc Welding In General (AREA)
  • Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Discharge Heating (AREA)

Abstract

A plasma nozzle for treating surfaces, especially for the pre-treatment of plastic surfaces, with a tubular, electrically conductive housing (10), which forms a nozzle channel (12), through which the working gas is flowing, an electrode (18), disposed coaxially in the nozzle channel, and a high-frequency generator (20) for applying a voltage between the electrode (18) and the housing, the outlet of the nozzle channel (12) is constructed as a narrow slot (32), which extends transversely to the longitudinal axis of the nozzle channel.

Description

Die Erfindung betrifft eine Plasmadüse zur Behandlung von Oberflächen, insbesondere zur Vorbehandlung von Kunststoffoberflächen, mit einem rohrförmigen, elektrisch leitfähigen Gehäuse, das einen von einem Arbeitsgas durchströmten Düsenkanal bildet, und einem Hochfrequenzgenerator zum Anlegen einer Spannung zwischen der Elektrode und dem Gehäuse.The invention relates to a plasma nozzle for the treatment of Surfaces, in particular for the pretreatment of Plastic surfaces, with a tubular, electric conductive housing, one of a working gas flowed through nozzle channel forms, and a High frequency generator for applying a voltage between the electrode and the housing.

Eine Plasmadüse dieser Art wird in DE 195 32 412 A1 beschrieben und dient beispielsweise dazu, Kunststoffoberflächen so vorzubehandeln, dass ein Auftragen von Klebstoffen, Druckfarben und dergleichen auf die Kunststoffoberfläche ermöglicht oder erleichtert wird. Eine solche Vorbehandlung ist erforderlich, da Kunststoffoberflächen im Normalzustand nicht mit Flüssigkeiten benetzbar sind und deshalb die Druckfarbe oder den Klebstoff nicht annehmen. Durch die Vorbehandlung wird die Oberflächenstruktur des Kunststoffs so verändert, dass die Oberfläche für Flüssigkeiten mit relativ großer Oberflächenspannung benetzbar wird. Die Oberflächenspannung der Flüssigkeiten, mit denen die Oberfläche gerade noch benetzbar ist, stellt ein Maß für die Qualität der Vorbehandlung dar.A plasma nozzle of this type is described in DE 195 32 412 A1 described and serves, for example, Pre-treat plastic surfaces so that applying of adhesives, inks and the like on the Plastic surface allows or easier. A such pretreatment is required because Plastic surfaces in the normal state not with Liquids are wettable and therefore the printing ink or do not accept the adhesive. By the pretreatment the surface structure of the plastic is changed so that the surface for liquids with relatively large Surface tension is wetted. The surface tension the fluids with which the surface just barely is a measure of the quality of the Pretreatment.

Durch die bekannte Plasmadüse wird ein verhältnismäßig kühler, jedoch hochreaktiver Plasmastrahl erreicht, der etwa die Gestalt und die Abmessungen einer Kerzenflamme hat und somit auch die Vorbehandlung von Profilteilen mit verhältnismäßig tiefem Relief gestattet. Aufgrund der hohen Reaktivität des Plasmastrahls genügt eine sehr kurzzeitige Vorbehandlung, so dass das Werkstück mit entsprechend hoher Geschwindigkeit an dem Plasmastrahl vorbeigeführt werden kann. Aufgrund der vergleichsweise niedrigen Temperatur des Plasmastrahls ist daher auch die Vorbehandlung von wärmeempfindlichen Kunststoffen möglich. Da keine Gegenelektrode auf der Rückseite des Werkstücks erforderlich ist, können auch die Oberflächen von beliebig dicken, blockartigen Werkstücken, Hohlkörpern und dergleichen problemlos vorbehandelt werden. Für eine gleichmäßige Behandlung größerer Oberflächen ist in der genannten Veröffentlichung eine Batterie aus mehreren versetzt angeordneten Plasmadüsen vorgeschlagen worden. In diesem Fall ist jedoch ein relativ hoher apparativer Aufwand erforderlich.By the known plasma nozzle is a relatively cool, but highly reactive plasma jet reached, the about the shape and dimensions of a candle flame has and thus also the pretreatment of profile parts with relatively deep relief allowed. Because of the high Reactivity of the plasma jet is sufficient for a very short time Pre-treatment, so that the workpiece with correspondingly high Speed past the plasma jet are passed can. Due to the comparatively low temperature of the Plasma jet is therefore also the pretreatment of heat-sensitive plastics possible. There no Counter electrode on the back of the workpiece is required, the surfaces of any thick, block-like workpieces, hollow bodies and be easily pretreated. For one uniform treatment of larger surfaces is in the mentioned publication a battery of several offset plasma nozzles have been proposed. In However, this case is a relatively high apparatus Effort required.

Weitere Plasmaquellen sind aus der GB 969 831 A, der US 5,628,924 A und der DE 26 42 649 A bekannt, deren Strahlgeometrien ebenfalls keine gleichmäßige Behandlung größerer Oberflächen erlauben.Further plasma sources are known from GB 969 831 A, which US 5,628,924 A and DE 26 42 649 A known, whose Beam geometries also no uniform treatment allow larger surfaces.

Aufgabe der Erfindung ist es deshalb, eine Plasmadüse zu schaffen, die trotzt eines sehr kompakten Aufbaus eine großflächigere Behandlung von Werkstückoberflächen ermöglicht.The object of the invention is therefore to a plasma nozzle which defies a very compact construction Larger surface treatment of workpiece surfaces allows.

Diese Aufgabe wird bei einer Plasmadüse der Eingangs genannten Art dadurch gelöst, daß der Auslaß des Düsenkanals als quer zur Längsachse des Düsenkanals verlaufender schmaler Schlitz ausgebildet ist.This task is characterized by a plasma nozzle of the type mentioned solved that the outlet of the nozzle channel as transverse to the longitudinal axis of the nozzle channel extending narrow slot is formed.

Überraschend hat sich gezeigt, daß durch die Verwendung eines solchen Auslaßschlitzes die Geometrie des Plasmastrahls wirksam verändert werden kann. Der Plasmastrahl hat nicht mehr die Form einer Kerzenflamme, sondern erfährt innerhalb des Schlitzes eine extreme Aufweitung, so daß eine großflächige und dennoch gleichmäßige Plasmabehandlung der Werkstückoberfläche ermöglicht wird. Wenn sich eine ausgedehnte Werkstückoberfläche vor der Mündung der Plasmadüse befindet, so strömt das Plasma an den divergierenden Rändern des Fächers nach außen ab, und im Inneren des Fächers bildet sich ein Unterdruck. mit dem Ergebnis, daß sich der fächerförmige Plasmastrahl förmlich an das Werkstück "ansaugt", so daß die Werkstückoberfläche in innigen Kontakt mit dem reaktiven Plasma kommt und somit eine sehr wirksame Oberflächenbehandlung erreicht wird.Surprisingly, it has been found that by the use of such Auslaßschlitzes the geometry of the plasma jet can be effectively changed. The plasma jet no longer has the shape of a candle flame, but experiences within the slot an extreme widening, so that a large area and nevertheless allows uniform plasma treatment of the workpiece surface becomes. If an extended workpiece surface in front of the mouth of the Plasma nozzle is located, so the plasma flows at the divergent edges of the Fan outward, and inside the fan forms a negative pressure. with the result that the fan-shaped plasma jet formally attached to the Workpiece "sucks", so that the workpiece surface in intimate contact with The reactive plasma comes and thus a very effective surface treatment is reached.

Vorteilhafte Ausgestaltungen der Erfindung ergeben sich aus den Unteransprüchen.Advantageous embodiments of the invention will become apparent from the dependent claims.

Wie bei der herkömmlichen Plasmadüse kann das Arbeitsgas im Düsenkanal verdrallt werden. Auch der verdrallte Plasmastrahl läßt sich mit Hilfe des Auslaßschlitzes fächerförmig aufweiten. Allenfalls führt die Verdrallung zu einer geringfügigen S-förmigen Verzerrung des Fächers, wenn man frontal auf die Mündung der Plasmadüse blickt.As with the conventional plasma nozzle, the working gas in the nozzle channel be twisted. Also, the twisted plasma jet can be with the help of the outlet slot fan-shaped. At most, the twisting leads to a minor S-shaped distortion of the fan when facing the mouth frontal the plasma nozzle looks.

Die Intensitätsverteilung des Plasmas auf der Länge des Schlitzes läßt sich beispielsweise dadurch steuern, daß die Breite des Schlitzes über die Länge variiert wird. In einer bevorzugten Ausführungsform ist jedoch unmittelbar stromaufwärts des Schlitzes ein parallel zu diesem Schlitz verlaufender Querkanal mit größerem Querschnitt angeordnet, in dem sich das Plasma verteilen kann, bevor es in den eigentlichen Auslaßschlitz eintritt. Diese Anordnung läßt sich besonders einfach herstellen, wenn die Mündung des Düsenkanals einschließlich des Schlitzes und des Querkanals durch ein separates Mundstück aus isolierendem Material (Keramik) oder vorzugsweise aus Metall gebildet wird, das in die Mündung des Gehäuses eingepreßt oder eingeschraubt wird.The intensity distribution of the plasma along the length of the slot can be, for example thereby controlling that the width of the slot varies over the length becomes. In a preferred embodiment, however, is immediately upstream of the slot with a parallel to this slot extending transverse channel larger cross section, in which the plasma can spread before it enters the actual outlet slot. This arrangement is particularly simply connect when the mouth of the nozzle channel including the Slot and the cross channel through a separate mouthpiece of insulating Material (ceramic) or preferably made of metal is formed in the mouth of the housing is pressed or screwed.

Bevorzugt ist der Querkanal an beiden Enden offen, und diese offenen Enden sind nur mit gewissem Abstand von den Wänden des Gehäuses umgeben, so daß ein Teil des Plasmas an den Enden aus dem Querkanal austreten kann und dann durch die Gehäusewände schräg in Richtung auf das Werkstück abgelenkt wird. Der Plasmafächer wird dann an beiden Rändern durch besonders intensive Randstrahlen begrenzt, die den Fächer förmlich auseinanderziehen. Hierdurch läßt sich die Form des Fächers und die Intensitätsverteilung des Plasmastrahls innerhalb des Fächers beispielsweise so einstellen, daß der stromabwärtige Rand des Plasmafächers eine konkave Form annimmt, so daß der Fächer einem Schwalbenschwanz ähnelt. Dies ist besonders günstig beim Vorbehandeln von konvex gewölbten, beispielsweise zylindrischen Werkstücken, erweist sich jedoch auch beim Vorbehandeln von flachen Werkstücken als vorteilhaft, weil so in den Randbereichen des Fächers der größere Weg. den das Plasma bis zum Werkstück zurücklegen muß, durch eine entsprechend größere Intensität des Plasmastrahls ausgeglichen wird. Durch Variieren der Tiefe, in der die offenen Enden des Querkanals im Gehäuse der Plasmadüse zurückliegen, läßt sich die Kontur des Fächers variieren, so daß bei Bedarf beispielsweise auch eine konvexe Krümmung des stromabwärtigen Randes des Fächers erreichbar ist.Preferably, the transverse channel is open at both ends, and these open ends are surrounded only with a certain distance from the walls of the housing, so that a part of the plasma can escape at the ends of the transverse channel and then deflected by the housing walls obliquely in the direction of the workpiece becomes. The plasma compartment will then be particularly intense at both edges Boundary rays limited, which pull apart the fan formally. hereby can be the shape of the fan and the intensity distribution of the plasma jet within the fan, for example, adjust so that the downstream Edge of the plasma fan assumes a concave shape, so that the fan a Dovetail resembles. This is particularly favorable when pretreating of convex, for example, cylindrical workpieces, proves However, even when pretreating flat workpieces as advantageous because so in the peripheral areas of the fan the larger way. the plasma until the Workpiece must be covered by a correspondingly greater intensity of the Plasma jet is balanced. By varying the depth in which the open Ends of the transverse channel lie in the housing of the plasma nozzle, can be the Contour of the fan vary, so that if necessary, for example, a convex Curvature of the downstream edge of the fan is achievable.

Um den Fächer in der zur Fächerebene senkrechten Richtung stärker zu bündeln, kann am Außenmantel des Gehäuses der Plasmadüse auf beiden Seiten der Ebene des Fächers Hilfsluft zugeführt werden. In diesem Fall kann es zweckmäßig sein, wenn die Außenfläche des Gehäuses der Plasmadüse im Mündungsbereich nicht konisch, sondern prismenförmig ausgebildet ist, so daß zwei flache Oberflächen gebildet werden, die zur Ebene des Fächers konvergieren.To concentrate the fan more in the direction perpendicular to the fan plane, can on the outer jacket of the housing of the plasma nozzle on both sides the plane of the fan auxiliary air to be supplied. In this case it can be expedient if the outer surface of the housing of the plasma nozzle in the mouth region not conical, but is prism-shaped, so that two flat surfaces are formed, which converge to the plane of the fan.

Im folgenden werden Ausführungsbeispiele der Erfindung anhand der Zeichnung näher erläutert.In the following, embodiments of the invention with reference to the drawing explained in more detail.

Es zeigen:

Fig. 1
einen axialen Schnitt durch die Plasmadüse;
Fig. 2
einen axialen Schnitt durch die Plasmadüse in der zur Schnittebene in Fig. 1 senkrechten Richtung: und
Fig. 3
einen Schnitt analog zu Fig. 2 für eine andere Ausführungsform.
Show it:
Fig. 1
an axial section through the plasma nozzle;
Fig. 2
an axial section through the plasma nozzle in the direction perpendicular to the sectional plane in Fig. 1 direction: and
Fig. 3
a section analogous to FIG. 2 for another embodiment.

Die in der Zeichnung dargestellte Plasmadüse weist ein rohrförmiges Gehäuse 10 auf, das einen langgestreckten, am unteren Ende konisch verjüngten Düsenkanal 12 bildet. In den Düsenkanal 12 ist ein elektrisch isolierendes Keramikrohr 14 eingesetzt. Ein Arbeitsgas, beispielsweise Luft, wird vom in der Zeichnung oberen Ende her in den Düsenkanal 12 zugeführt und mit Hilfe einer in das Keramikrohr 14 eingesetzten Dralleinrichtung 16 so verdrallt, daß es wirbelförmig durch den Düsenkanal 12 strömt, wie in der Zeichnung durch einen schraubenförmigen Pfeil symbolisiert wird. In dem Düsenkanal 12 entsteht so ein Wirbelkern, der längs der Achse des Gehäuses verläuft.The plasma nozzle shown in the drawing has a tubular housing 10, the one elongated, conically tapered at the bottom nozzle channel 12 forms. In the nozzle channel 12 is an electrically insulating ceramic tube 14 used. A working gas, such as air, is from the drawing fed into the upper end of the nozzle channel 12 and with the aid of an in the ceramic tube 14 used twisting device 16 so twisted that it is vortex-shaped flows through the nozzle channel 12, as in the drawing by a helical arrow is symbolized. In the nozzle channel 12 is formed a vortex core extending along the axis of the housing.

An der Dralleinrichtung 16 ist eine stiftförmige Elektrode 18 montiert, die koaxial in den Düsenkanal 12 ragt und an die mit Hilfe eines Hochspannungsgenerators 20 eine hochfrequente Wechselspannung angelegt wird. Die mit Hilfe des Hochfrequenzgenerators 20 erzeugte Spannung liegt in der Größenordnung von einigen Kilovolt und hat beispielsweise eine Frequenz in der Größenordnung von 20 kHz.On the swirl device 16, a pin-shaped electrode 18 is mounted, which is coaxial projects into the nozzle channel 12 and to the by means of a high voltage generator 20 a high-frequency AC voltage is applied. The with the help of High frequency generator 20 generated voltage is of the order of a few kilovolts and has, for example, a frequency of the order of 20 kHz.

Das aus Metall bestehende Gchäuse 10 ist geerdet und dient als Gegenelektrode, so daß eine elektrische Entladung zwischen der Elektrode 18 und dem Gehäuse 10 hervorgerufen werden kann. Beim Einschalten der Spannung kommt es aufgrund der hohen Frequenz der Wechselspannung und aufgrund der Dielektrizität des Keramikrohrs 14 zunächst zu einer Koronaentladung an der Dralleinrichtung 16 und der Elektrode 18. Durch diese Koronaentladung wird eine Bogenentladung von der Elektrode 18 zum Gehäuse 10 gezündet. Der Lichtbogen 22 dieser Entladung wird durch das verdrallt einströmende Arbeitsgas mitgenommen und im Kern der wirbelförmigen Gasströmung kanalisiert, so daß der Lichtbogen dann nahezu geradlinig von der Spitze der Elektrode 18 längs der Gehäuseachse verläuft und sich erst im Bereich der Mündung des Gehäuses 10 radial auf die Gehäusewand verzweigt.The metal housing 10 is grounded and serves as a counter electrode, such that an electrical discharge between the electrode 18 and the housing 10 can be caused. When the voltage comes on it due to the high frequency of the AC voltage and due to the dielectricity of the ceramic tube 14 first to a corona discharge at the swirl device 16 and the electrode 18. By this corona discharge is a Arc discharge from the electrode 18 to the housing 10 ignited. The arc 22 of this discharge is taken by the twisted inflowing working gas and channeled at the core of the vortex-shaped gas flow, so that the Arc then almost straight from the top of the electrode 18 along the Housing axis extends and only in the region of the mouth of the housing 10th branched radially on the housing wall.

In die Mündung des Gehäuses 10 ist ein zylindrisches Mundstück 24 aus Kupfer eingesetzt, dessen axial inneres Ende an einer Schulter 26 des Gehäuses anliegt. Das konisch verjüngte Ende des Düsenkanals 12 setzt sich in dem Mundstück 24 stetig, mit gleichem oder leicht geändertem Kegelwinkel fort. Der Lichtbogen 22 verzweigt sich innerhalb des Mundstücks 24 auf die konischen Wände des Mundstücks.In the mouth of the housing 10 is a cylindrical mouthpiece 24 made of copper used, the axially inner end rests against a shoulder 26 of the housing. The conically tapered end of the nozzle channel 12 settles in the mouthpiece 24 continuous, with the same or slightly changed cone angle. The arc 22 branches within the mouthpiece 24 on the conical walls of the mouthpiece.

Das Mundstück 24 weist am freien, in Figur 1 unteren Ende einen Abschnitt 28 mit reduziertem Durchmesser auf, der mit der Umfangswand des Gehäuses 10 einen in Mündungsrichtung offenen Ringkanal 30 bildet. Die konisch verjüngte Spitze des Düsenkanals 12 mündet in einen Querkanal 32, der durch eine Querbohrung in dem Abschnitt 28 gebildet wird und an beiden Enden zu dem Ringkanal 30 hin offen ist. An diesen Querkanal 32, der gemäß Figur 2 einen kreisförmigen Querschnitt hat, schließt sich axial ein schmalerer, diametral durch das Mundstück verlaufender Schlitz 34 an, der zur Stirnfläche des Mundstücks offen ist.The mouthpiece 24 has at the free, in Figure 1 lower end of a section 28th with a reduced diameter, with the peripheral wall of the housing 10th forms an open in the mouth direction annular channel 30. The conically tapered Tip of the nozzle channel 12 opens into a transverse channel 32 through a Cross hole is formed in the section 28 and at both ends to the Ring channel 30 is open towards. At this transverse channel 32, according to Figure 2 a has circular cross-section, closes axially a narrower, diametrically through the mouthpiece extending slot 34 which, to the end face of the mouthpiece is open.

Das drallförmig durch den Düsenkanal 12 strömende Arbeitsgas kommt im Wirbelkern in innige Berührung mit dem Lichtbogen 22, so daß ein hochreaktives Plasma mit relativ niedriger Temperatur erzeugt wird. Dieses Plasma verteilt sich im Querkanal 32 und tritt dann zum Teil durch den Schlitz 34 und zum Teil auch durch die offenen Enden des Querkanals 32 und den Ringkanal 30 aus der Plasmadüse aus. Auf diese Weise wird ein Plasmastrahl 36 in der Form eines flachen Fächers erzeugt, der in den Randbereichen 38 eine größere Dichte und eine größere Strömungsgeschwindigkeit als in der Nähe der Düsenachse aufweist. Somit ist die Reichweite des Plasmastrahls 36 an den Rändern größer als in der Mitte, so daß der stromabwärtige Rand 40 des Plasmastrahls eine konkave Krümmung aufweist und somit der Fächer insgesamt die Form eines Schwalbenschwanzes annimmt. Diese Form des Plasmastrahls stellt sicher, daß sich der Plasmastrahl gut an das nicht gezeigte Werkstück anschmiegt.The swirling through the nozzle channel 12 flowing working gas comes in the vortex core in intimate contact with the arc 22, so that a highly reactive Plasma is produced at a relatively low temperature. This plasma is distributed in the transverse channel 32 and then enters partly through the slot 34 and partly also through the open ends of the transverse channel 32 and the annular channel 30 from the plasma nozzle. In this way, a plasma jet 36 in the form of a flat fan generated in the edge regions 38 a greater density and a greater flow velocity than near the nozzle axis having. Thus, the range of the plasma jet 36 at the edges is greater as in the middle, so that the downstream edge 40 of the plasma jet a has concave curvature and thus the subjects overall the shape of a Swallowtail accepts. This shape of the plasma jet ensures that the plasma jet fits snugly against the workpiece, not shown.

Figur 3 zeigt eine abgewandelte Ausführungsform, bei der der Ringkanal und der Querkanal nicht vorhanden sind und bei der das Mundstück am freien Ende auf beiden Seiten des Schlitzes 34 durch Schrägflächen begrenzt wird, die mit entsprechenden Schrägflächen des Gehäuses 10 bündig sind. Das Gehäuse 10 ist hier von einem Luftverteiler 42 umgeben, durch den Hilfsluft 44 parallel zu den Schrägflächen des Gehäuses und des Mundstücks 24 von beiden Seiten auf den aus dem Schlitz 34 austretenden Plasmastrahl 36 geblasen wird, um den fächerförmigen Plasmastrahl zu bündeln und eine vorzeitige Aufweitung dieses Plasmastrahls in der zur Ebene des Fächers senkrechten Richtung zu verhindern. Zugleich wird durch die Hilfsluft auch eine innige Berührung des Plasmastrahls mit der Oberfläche des Werkstücks unterstützt.Figure 3 shows a modified embodiment in which the annular channel and the transverse channel are absent and at the mouthpiece at the free end is bounded on both sides of the slot 34 by inclined surfaces with corresponding inclined surfaces of the housing 10 are flush. The housing 10 is here surrounded by an air distributor 42, by the auxiliary air 44 parallel to the inclined surfaces of the housing and the mouthpiece 24 from both sides blown out of the slot 34 plasma jet 36 is blown to the fan-shaped plasma jet to bundle and premature expansion of this To prevent plasma jet in the direction perpendicular to the plane of the fan direction. At the same time, the auxiliary air also makes intimate contact with the plasma jet supported with the surface of the workpiece.

Claims (10)

  1. A plasma nozzle for surface treatment, comprising: a tubular, electrically conductive housing (10) which forms a nozzle channel (12) through which a working gas flows, an electrode (18) disposed coaxially in the nozzle channel, and a high-frequency generator (20) for applying a voltage between the electrode (18) and the housing, characterized in that said outlet of said nozzle channel (12) is constructed as a slot (34) which extends transversely to the longitudinal axis of the nozzle channel.
  2. The plasma nozzle of claim 1, wherein the housing (10) includes a twisting device (16) which twists the working gas in the nozzle channel (12).
  3. The plasma nozzle of claim 1 or 2, wherein the nozzle channel (12) discharges into a transverse channel (32), which extends parallel to the slot (34) and is, in turn, connected with the slot (34).
  4. The plasma nozzle of claim 3, wherein the nozzle channel (12) tapers conically at the outlet and is connected only in a central region of the transverse channel (32) with this transverse channel.
  5. The plasma nozzle of claim 3 or 4, wherein the transverse channel (32) is open at opposite ends thereof.
  6. The plasma nozzle of claim 5, wherein inner walls of the housing (10) at an outlet end of the plasma nozzle are at a distance from the open ends of the transverse channel (32) and deflect the plasma, emerging from these ends, towards a side of the slot (34).
  7. The plasma nozzle of claim 6, wherein the ends of the transverse channel (32) discharge into an annular channel (30), which is bounded by the housing (10) and is open towards the same side as the slot (34).
  8. The plasma nozzle according to any of the above mentioned claims, wherein the slot (34) and the outlet of the nozzle channel (12) are formed in a mouthpiece (24), which is inserted into the end of the housing (10) .
  9. The plasma nozzle of claim 8, wherein the mouthpiece (24) is made of metal.
  10. The plasma nozzle of claim 1, further comprising an air distributor (42) mounted outside of the housing (10), which directs auxiliary air (44) in a converging manner in a direction at right angles to a plane of the slot (34) onto the plasma jet (36) emerging from the slot (34).
EP00990703A 1999-12-09 2000-12-11 Plasma nozzle Expired - Lifetime EP1236380B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE29921694U 1999-12-09
DE29921694U DE29921694U1 (en) 1999-12-09 1999-12-09 Plasma nozzle
PCT/EP2000/012501 WO2001043512A1 (en) 1999-12-09 2000-12-11 Plasma nozzle

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EP1236380A1 EP1236380A1 (en) 2002-09-04
EP1236380B1 true EP1236380B1 (en) 2005-03-02

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US (1) US6677550B2 (en)
EP (1) EP1236380B1 (en)
JP (1) JP3838914B2 (en)
AT (1) ATE290303T1 (en)
DE (2) DE29921694U1 (en)
DK (1) DK1236380T3 (en)
ES (1) ES2237491T3 (en)
WO (1) WO2001043512A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7875356B2 (en) 2005-04-29 2011-01-25 Basf Se Composite element, especially a window pane
WO2011107510A1 (en) 2010-03-02 2011-09-09 Plasmatreat Gmbh Method for producing a packaging

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1170066A1 (en) 2000-07-05 2002-01-09 Förnsel, Peter Process and apparatus for cleaning rollers and bands
US20040011378A1 (en) * 2001-08-23 2004-01-22 Jackson David P Surface cleaning and modification processes, methods and apparatus using physicochemically modified dense fluid sprays
DE50200894D1 (en) * 2002-02-09 2004-09-30 Plasma Treat Gmbh plasma nozzle
EP1349439B1 (en) * 2002-03-28 2005-11-09 Plasma Treat GmbH Method and device for glass ampule sealing
DE10231037C1 (en) * 2002-07-09 2003-10-16 Heraeus Tenevo Ag Making synthetic quartz glass blank by plasma-assisted deposition, for optical fiber manufacture, employs burner to focus flow towards plasma zone
EP1410852B1 (en) * 2002-10-18 2006-04-19 Plasma Treat GmbH Method and apparatus for the removal of a polymer-based layer of paint
DE102004024061A1 (en) * 2004-05-13 2005-12-08 Ticona Gmbh Process for the preparation of polyacetal plastic composites and apparatus suitable therefor
US7164095B2 (en) 2004-07-07 2007-01-16 Noritsu Koki Co., Ltd. Microwave plasma nozzle with enhanced plume stability and heating efficiency
US7806077B2 (en) 2004-07-30 2010-10-05 Amarante Technologies, Inc. Plasma nozzle array for providing uniform scalable microwave plasma generation
US20060021980A1 (en) * 2004-07-30 2006-02-02 Lee Sang H System and method for controlling a power distribution within a microwave cavity
US7271363B2 (en) 2004-09-01 2007-09-18 Noritsu Koki Co., Ltd. Portable microwave plasma systems including a supply line for gas and microwaves
US7189939B2 (en) * 2004-09-01 2007-03-13 Noritsu Koki Co., Ltd. Portable microwave plasma discharge unit
US20060052883A1 (en) * 2004-09-08 2006-03-09 Lee Sang H System and method for optimizing data acquisition of plasma using a feedback control module
JP5319921B2 (en) * 2004-11-19 2013-10-16 ヴェトロテヒ・サン−ゴバン・(インターナショナル)・アクチェンゲゼルシャフト Method and apparatus for processing streaks and planes on the surface of a glass plate
DE102005004280A1 (en) 2005-01-28 2006-08-03 Degussa Ag Process for producing a composite
US20060172081A1 (en) * 2005-02-02 2006-08-03 Patrick Flinn Apparatus and method for plasma treating and dispensing an adhesive/sealant onto a part
DE102005018926B4 (en) 2005-04-22 2007-08-16 Plasma Treat Gmbh Method and plasma nozzle for generating an atmospheric plasma jet generated by means of high-frequency high voltage comprising a device in each case for characterizing a surface of a workpiece
DE102005061247A1 (en) * 2005-12-20 2007-06-21 Peter J. Danwerth Method for sterilization of food such as diary products, vegetables or fruits, cheese or sausage, comprises subjecting surface of the food to an atmospheric plasma jet
US20100021340A1 (en) * 2005-12-20 2010-01-28 Plasmatreat Gmbh Method and device for the disinfection of objects
US7547861B2 (en) * 2006-06-09 2009-06-16 Morten Jorgensen Vortex generator for plasma treatment
US20070284342A1 (en) * 2006-06-09 2007-12-13 Morten Jorgensen Plasma treatment method and apparatus
US8981253B2 (en) * 2006-09-13 2015-03-17 Hypertherm, Inc. Forward flow, high access consumables for a plasma arc cutting torch
US9560732B2 (en) 2006-09-13 2017-01-31 Hypertherm, Inc. High access consumables for a plasma arc cutting system
US10194516B2 (en) 2006-09-13 2019-01-29 Hypertherm, Inc. High access consumables for a plasma arc cutting system
US9662747B2 (en) 2006-09-13 2017-05-30 Hypertherm, Inc. Composite consumables for a plasma arc torch
US10098217B2 (en) 2012-07-19 2018-10-09 Hypertherm, Inc. Composite consumables for a plasma arc torch
DE102007011235A1 (en) 2007-03-06 2008-09-11 Plasma Treat Gmbh Method and device for treating a surface of a workpiece
TWI387400B (en) * 2008-10-20 2013-02-21 Ind Tech Res Inst Plasma system
TWI380743B (en) * 2008-12-12 2012-12-21 Ind Tech Res Inst Casing and jet type plasma system
DE102009000259A1 (en) 2009-01-15 2010-07-22 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method for modifying the surface of particles and device suitable therefor
PL2279801T3 (en) 2009-07-27 2015-06-30 Fraunhofer Ges Forschung Coating methods using plasma jet and plasma coating apparatus
DE102009048397A1 (en) 2009-10-06 2011-04-07 Plasmatreat Gmbh Atmospheric pressure plasma process for producing surface modified particles and coatings
DE102010011643B4 (en) 2010-03-16 2024-05-29 Christian Buske Device and method for plasma treatment of living tissue
DE102010044114A1 (en) 2010-11-18 2012-05-24 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for joining substrates and composite structure obtainable therewith
JPWO2012172630A1 (en) * 2011-06-13 2015-02-23 トヨタ自動車株式会社 Surface processing apparatus and surface processing method
DE102012206081A1 (en) 2012-04-13 2013-10-17 Krones Ag Coating of containers with plasma nozzles
DE102014217821A1 (en) 2014-09-05 2016-03-10 Tesa Se A method for increasing the adhesion between the first surface of a first sheet material and a first surface of a second sheet material
CN107001033B (en) * 2014-09-30 2020-07-10 普拉斯科转换技术有限公司 Non-equilibrium plasma system and method for refining synthesis gas
MX2017006093A (en) * 2014-11-10 2017-07-19 Superior Ind Int Inc Method of coating alloy wheels.
TW201709775A (en) * 2015-08-25 2017-03-01 馗鼎奈米科技股份有限公司 Arc atmospheric pressure plasma device
DE102015121252A1 (en) * 2015-12-07 2017-06-08 Plasmatreat Gmbh Apparatus for generating an atmospheric plasma jet and method for treating the surface of a workpiece
DE102016209097A1 (en) 2016-03-16 2017-09-21 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. plasma nozzle
DE102016204449A1 (en) * 2016-03-17 2017-09-21 Plasmatreat Gmbh Device for forming metallic components and method performed therewith
WO2018115335A1 (en) * 2016-12-23 2018-06-28 Plasmatreat Gmbh Nozzle assembly and device for generating an atmospheric plasma jet
US10300711B2 (en) 2017-05-04 2019-05-28 Xerox Corporation Device for providing multiple surface treatments to three-dimensional objects prior to printing and system using the device
DE102017120017A1 (en) 2017-08-31 2019-02-28 Plasmatreat Gmbh A nozzle arrangement for a device for generating an atmospheric plasma jet, system and method for monitoring and / or control of the system
DE102018132960A1 (en) 2018-12-19 2020-06-25 Plasmatreat Gmbh Device and method for treating a workpiece surface with an atmospheric plasma jet
WO2020153980A1 (en) 2019-01-24 2020-07-30 Superior Industries International, Inc. Method of coating alloy wheels using inter-coat plasma
CN117265628A (en) * 2023-09-18 2023-12-22 广州航海学院 High-voltage jet electrolytic machining device and method based on plasma discharge

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE626654A (en) 1962-01-16
DE2642649A1 (en) 1976-09-22 1978-03-23 Nuc Weld Gmbh Plasma burner for underwater welding - where plasma jet is surrounded by high velocity water or gas curtain
JP2591371Y2 (en) * 1993-02-24 1999-03-03 株式会社小松製作所 Plasma arc torch
US5679167A (en) * 1994-08-18 1997-10-21 Sulzer Metco Ag Plasma gun apparatus for forming dense, uniform coatings on large substrates
DE19532412C2 (en) * 1995-09-01 1999-09-30 Agrodyn Hochspannungstechnik G Device for surface pretreatment of workpieces
US6227846B1 (en) * 1996-11-08 2001-05-08 Shrinkfast Corporation Heat gun with high performance jet pump and quick change attachments
DE19820240C2 (en) * 1998-05-06 2002-07-11 Erbe Elektromedizin Electrosurgical instrument

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7875356B2 (en) 2005-04-29 2011-01-25 Basf Se Composite element, especially a window pane
WO2011107510A1 (en) 2010-03-02 2011-09-09 Plasmatreat Gmbh Method for producing a packaging
DE102010055532A1 (en) 2010-03-02 2011-12-15 Plasma Treat Gmbh A method for producing a multilayer packaging material and method for applying an adhesive, and apparatus therefor

Also Published As

Publication number Publication date
US20020179575A1 (en) 2002-12-05
DK1236380T3 (en) 2005-05-30
DE50009671D1 (en) 2005-04-07
EP1236380A1 (en) 2002-09-04
US6677550B2 (en) 2004-01-13
ATE290303T1 (en) 2005-03-15
WO2001043512A1 (en) 2001-06-14
JP2003518317A (en) 2003-06-03
DE29921694U1 (en) 2001-04-19
JP3838914B2 (en) 2006-10-25
ES2237491T3 (en) 2005-08-01

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