EP1183418A1 - Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles - Google Patents
Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textilesInfo
- Publication number
- EP1183418A1 EP1183418A1 EP00938892A EP00938892A EP1183418A1 EP 1183418 A1 EP1183418 A1 EP 1183418A1 EP 00938892 A EP00938892 A EP 00938892A EP 00938892 A EP00938892 A EP 00938892A EP 1183418 A1 EP1183418 A1 EP 1183418A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- radical
- formula
- compound
- alkyl
- branched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65131—Compounds containing ether or acetal groups
Definitions
- the present invention relates to the use, during the treatment of textile fibers, of derivatives of polyaicoxylated terpene compounds, and more particularly during dyeing operations.
- the present invention is equally applicable to the treatment of natural textile fibers (natural and regenerated cellulosic fibers (cotton), wool) as well as synthetic fibers (polyester, polyamide (nylon), polyacrylonitrile (acrylic)).
- the treatment of textile fibers includes various stages, such as, inter alia, roasting, destacking, cleaning, bleaching, mercerization, f) dyeing stages, finishing. And during these stages, it is necessary to use wetting and / or penetrating agents so as to make effective the agent used during the stage concerned.
- ethoxylated nonylphenols are used. They are very effective agents, but they have the disadvantage of producing a large amount of foam. It is possible to use them combined with an anti-foaming agent, such as, for example, anti-foaming agents based on silicone emulsions.
- an anti-foaming agent such as, for example, anti-foaming agents based on silicone emulsions.
- anti-foaming agents are often destabilized and a silicone gel is formed which is deposited on the fibers, which causes the appearance of permanent stains on the fabric.
- the object of the present invention is therefore to propose the use of a wetting / penetrating agent which is as effective as the compounds usually used in the stages of the treatment of textile fibers, but which does not have the drawbacks due to the appearance of moss.
- the subject of the present invention is a process for treating textile fibers comprising at least one of the following steps: (a) toasting, (b) de-embedding, (c) cleaning, (d) bleaching, (e) mercerization, ( f) dyeing steps, (g) finishing, in which a compound of formula (I) Zj - X - [CH (R 3 ) - CH (R 4 ) is used in at least one of the above-mentioned steps -O] n - A;
- - X represents -CH 2 -C (Ri) (R2) -O- or -O-CH (R'i) -CH (R'2) -O- in which:
- R 1 and R2 identical or different, represent hydrogen or a hydrocarbon radical, saturated or not, linear, branched or cyclic, in Ci-C ⁇
- a R ' 1 and R'2 identical or different, represent the hydrogen or a hydrocarbon radical, saturated or unsaturated, linear, branched or cyclic, C1-C-22.
- R 3 and R 4 identical or different, represent a hydrogen atom or a linear or branched (cyclo) alkyl or (cyclo) alkenyl group at CC 22 , - n is an average value between 1 and 200
- - A represents a hydrogen atom, an alkyl radical in an aryl or alkylaryl radical, a halogen atom, a group -CH 2 -CH (OH) R 5 , where R 5 represents a linear or branched or cyclic alkyl radical in CC 22 or aryl, or a group chosen from -SO 3 M, -OPO 3 (M) 2, - (CH2) a -COOM, - (CH 2) b -SO 3 M, with a and b ranging from 1 to 6, M represents H, Na, K, Li, N (R 4 ) + where the radicals R, which are identical or different, represent a hydrogen atom or a linear or branched or cyclic alkyl radical in CC 22 optionally hydroxylated, or a mixture of these compounds.
- the compounds (hereinafter called terpene compounds) used will first be described.
- the derivatives of terpene compounds used in the process according to the invention correspond to the formula mentioned above.
- the radical Zj is preferably attached to the rest of the chain via any one of its carbon atoms numbered 1 to 6. According to a more particular mode, the radical Zj is attached to the remainder of the chain through carbon atoms 1, 5 and 6.
- the compounds are such that the radical Zj is substituted on at least one of its carbon atoms, by at least two alkyl groups in OpC ⁇ , preferably by two methyl radicals. More particularly, the substituents are located on the carbon atom 7.
- a first family of compounds corresponds to that in which X represents -CH2-C (R) (R2) -O-.
- the radicals Zj more particularly correspond to the radicals Z 3 to Z 7 .
- the cycles include ethylenic unsaturation.
- they carry two substituents, preferably methyl, on the carbon atom 7.
- the preferred compounds are defined by the radicals Z and Z 5 , carrying two methyls on carbon 7.
- a second family of compounds corresponds to that in which X represents -O-CH (R'i) -CH (R'2) -O-. More particularly, the cycles do not contain ethylenic unsaturation and are represented by the radical Z 3 . Note that in the case of this family, it is expected that at least R 1 or R 2 is not hydrogen.
- a preferred embodiment consists of compounds in which R 1 or R ′ 2 is a methyl radical.
- the carbon atom 7 carries two methyl substituents as well as a C 1 -C 6 alkyl substituent, preferably a methyl, located on the carbon atom 2 or the carbon atom. 5.
- R 4 identical or different, represent a hydrogen atom or a group
- radicals R 3 and R 4 which may or may not be identical, represent a hydrogen atom, a methyl radical, or an ethyl radical.
- said units correspond to oxyethylenated units and / or to oxypropylenated units.
- n is an average value between 1 and 200. It corresponds to the total sum of the motifs - [CH (R 3 ) - CH (R 4 ) -O] -.
- the number of oxyethylenated units is between 1 and 200, preferably between 1 and 50, and even more particularly, between 1 and 20.
- oxypropylenated units their average number is between 0 and 20, more particularly between 1 and 10, preferably between 1 and 4. It can be very advantageous to have a terpene compound corresponding to a mixture of compounds of formula (I) in which at least one of them is such that it has the sequence mentioned above.
- the compounds used in the invention exhibit good resistance under the often very harsh conditions encountered during the treatment of the fibers. Indeed, many stages are carried out in very alkaline medium.
- the compounds according to the invention have the advantage of having their structure adapted according to the requirements of the operation in which they are used. Thus, on a common basis, it is possible to have an effective nonionic or ionic compound, compatible with the various compounds present in the solution intended for the treatment of fibers.
- the textile fibers subject to the treatments include residual additives, originating from the previous stages, such as lubricants (sizing additives (lubricants for dies in the case of synthetic fibers), polyvinyl alcohol, carboxymethylcellulose), cohesion of fibers (starch), film-forming agents (hydrocolloids). It is necessary to rid the fibers of these compounds. This operation is carried out during a step called de-interlining (step (b)).
- lubricants size additives (lubricants for dies in the case of synthetic fibers)
- polyvinyl alcohol polyvinyl alcohol, carboxymethylcellulose
- cohesion of fibers starch
- film-forming agents hydrocolloids
- the desizing operation can be carried out enzymatically (aiming to depolymerize the starch, if it is present) and / or by chemical oxidation and / or by an alkaline washing. More particularly, the oxidation reaction is carried out with an oxidizing agent chosen from hydrogen peroxide, persulfates, perborates for example. It is also implemented in an alkaline medium, such as alkaline washing.
- the alkali metal hydroxides such as sodium hydroxide
- the alkali metal carbonate and bicarbonate can be used; soda being preferred.
- concentration of alkaline agent is of the order of 2 to 5 g / l, so as to obtain a pH of between 10 and 12.
- the de-oiling medium can also comprise usual additives (chelating agents, etc.).
- This step is carried out in solution comprising 70 to 80% of water. In addition, it is carried out hot. Thus temperatures above 50 ° C are conventional.
- the preparationooilage can be carried out in the presence of the terpene compound described whose use is the subject of the invention.
- the content of this compound in the stabilizer bath varies more particularly between 1 and 5 g / l.
- the textile fibers are impregnated in the solution, either continuously
- This step can take place in one or more passes.
- step (a) Depending on the nature of the textile fiber, it may be necessary or simply advantageous to implement a prior step, called toasting (step (a)).
- the purpose of this step is to give a smoother surface to the textile fiber. Indeed, it consists in burning the fibers which protrude from the surface thereof.
- this roasting step does not facilitate that of the situooilage stage. Indeed, the textile fiber having undergone such a treatment is overdried and therefore, it is necessary to be able to have a solution having a high wetting power if one wants to maintain good efficiency at the de-embedding stage.
- stage (c) This step is more generally used when the textile fibers include cotton.
- the purpose of this operation is to eliminate the compounds naturally present on cotton fibers, such as, for example, cellulose residues (hemicellulose, immature cellulose), natural oils or waxes which are the cause of heterogeneities in the fabric. final dyed or not.
- This cleaning operation is carried out in a strongly alkaline medium.
- the concentration of alkaline agent in the bath is 20 to 40 g / l.
- soda is used.
- the medium can likewise comprise the terpene compound.
- the content of this compound can advantageously be between 1 and 5 g / l.
- the step is more particularly carried out at a temperature of the order of 60-
- This step is generally carried out in a steam cabin.
- the textile fibers can be directly dyed as soon as the colors are dark. But conventionally, the process for treating textile fibers continues with a bleaching step (step (d)).
- the operation takes place by means of an oxidizing agent which is more particularly hydrogen peroxide.
- a stabilizer such as silicates, hypochlorites, polyphosphonic acid.
- the bleaching step is carried out at high temperatures, of the order of 70 to 80 ° C.
- step (d) a step called mercerization or caustization can optionally be implemented (step (d)).
- This step consists of soaking the textile fibers in an alkaline solution; the textile fibers being possibly subjected, during this step, to a mechanical tension. The purpose of this operation is to improve the yield of the dyeing operation of the fibers, as well as their resistance to tearing.
- the soaking is carried out with a solution whose concentration of alkaline agent and of the order of 200 to 300 g / l.
- the step is carried out at a temperature of the order of 15 to 25 ° C.
- the alkaline solution can likewise comprise the terpene compound, with a concentration varying more particularly between 1 and 5 g / l.
- the textile fibers are then dyed, in a series of steps (e). These steps are well known in the art.
- the dyeing can comprise the following stages: coloring of the synthetic fibers (stage (e1)), fixing of these pigments
- step (e2) salting out of the non-fixed pigments (step (e3)), coloring of the natural fibers (step (e4)), washing of the non-fixed pigments (step (e5)).
- the steps specific to this type of fibers are only implemented.
- the dyeing operations are carried out at a pH of at least 7, preferably at least 8.
- Such pHs are obtained through the use of alkaline compounds such as alkali metal hydroxides.
- the solutions or dispersions used are aqueous.
- the solutions or dispersions comprise various surfactants, which are preferably anionic or nonionic.
- surfactants which are preferably anionic or nonionic.
- colloids such as polysulfonates, polycarboxylates (polyacrylate, acid copolymer acrylic / maleic acid), polyvinylsulfonates, alginates, polysaccharides, cellulose derivatives.
- the solutions or dispersions can also comprise the terpene compounds. They are preferably of the nonionic type.
- terpene compounds as defined above are very advantageous in the context of the dyeing stages. In fact, they have very little or no foaming or even defoaming properties, even under dyeing conditions, in which the shearing is very high.
- the content of these terpene compounds advantageously varies between 1 and 5 g / l.
- the actual dyeing operations are carried out in a conventional manner, and more particularly in a closed loop (jet type, in a cassette (jigger)).
- the dyeing is generally carried out hot, that is to say at temperatures between 50 and 90 ° C. Higher temperatures are possible if the operation is carried out under pressure.
- the textile fibers are first impregnated in the dye bath, then passed through rollers to remove the excess bath.
- the fibers can follow several passages before having their dyes fixed. It is more particularly during the impregnation steps that we are in the presence of significant shearing conditions, which are the cause of the appearance of foam.
- the fabric In batch processes implemented in Gigger cassette) the fabric is unwound from one cassette to another with, in the meantime, immersion in the bath. In this case, the agitation is average. Therefore, the levels of foam created are also average. However, it may happen that the foam is deposited on the textile fibers and is the cause of the appearance of stains.
- a finishing step can be carried out, with the aim of giving the textiles special properties according to the end use for which they are intended.
- the textile fibers can be treated with softeners (anionic, cationic, silicone), agents making the fabric more or less stiff (resins), anti-stain agents (fluorocarbons), agents making it possible to transform the appearance of the fabric (polyurethanes on which we can apply flocks in order to obtain a velvet appearance, for example).
- softeners anionic, cationic, silicone
- agents making the fabric more or less stiff agents making the fabric more or less stiff (resins), anti-stain agents (fluorocarbons), agents making it possible to transform the appearance of the fabric (polyurethanes on which we can apply flocks in order to obtain a velvet appearance, for example).
- the preparationooilage bath includes:
- Chelating agent (Neocrystal 70, sold by the company Nicca) 1 g / l
- Desizing agent (terpene compound, or usual surfactant) 1 g / l
- the fabric is spread on a support then a drop of oil is deposited (paraffinic mineral oil HN100), esterified oil (methyl ester of rapeseed oil), and wax (ethylene bis stearamide). The whole is then treated at 180 ° C for 1 minute.
- oil paraffinic mineral oil HN100
- esterified oil methyl ester of rapeseed oil
- wax ethylene bis stearamide
- the fabric is then immersed in the concerningooilage bath at 110 ° C for 20 minutes.
- the weight ratio of the part to be treated in the stabilizer bath is 1:20.
- the fabric is rinsed with excess water for 30 seconds, and drained for 30 seconds.
- the resulting fabric is then dyed with a disperse dye
- the part is immersed in the bath comprising the dye at room temperature, then the temperature is increased to 80 ° C., with stirring.
- Test according to the invention compound corresponding to cycle 4), carbon 3 carrying two methyl radicals, and in which X represents -CH2-CH2-O-, and comprising
- Comparative test 2 corresponds to compositions free from de-stabilizing agents.
- the residue corresponds to 100 x dry weight of the extract / weight of the piece of fabric.
- the handlingooilage bath includes 3 g / l of summaryooilage agent.
- the stabilizer bath used is that of test 1.
- the foam is obtained by stirring 900 g of solution using a turbine agitator (40mm turbine, speed 2000 rpm) for 5 minutes.
- the temperature is 50 ° C.
- the foam level is read in a test tube after 5 minutes of rest.
- the agent according to the invention is as effective as the agent of Comparative Example 1 with regard to the de-embedding, and surprisingly, with regard to the level of residue remaining on the fibers after the treatment .
- the release agent according to the invention is much more efficient than the agent according to Comparative Example 1, as regards the level of foam.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9907240 | 1999-06-07 | ||
FR9907240A FR2794476B1 (fr) | 1999-06-07 | 1999-06-07 | Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles |
PCT/FR2000/001543 WO2000075416A1 (fr) | 1999-06-07 | 2000-06-06 | Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1183418A1 true EP1183418A1 (fr) | 2002-03-06 |
Family
ID=9546538
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00938892A Withdrawn EP1183418A1 (fr) | 1999-06-07 | 2000-06-06 | Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1183418A1 (fr) |
JP (1) | JP2003528988A (fr) |
KR (1) | KR20020019067A (fr) |
CN (1) | CN1358246A (fr) |
AR (1) | AR024303A1 (fr) |
AU (1) | AU5412000A (fr) |
CO (1) | CO5210971A1 (fr) |
FR (1) | FR2794476B1 (fr) |
WO (1) | WO2000075416A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100419524B1 (ko) * | 2001-06-27 | 2004-02-19 | 주식회사 효성 | 천연 테르펜을 캐리어로 사용하는 폴리트리메틸렌 테레프탈레이트 섬유의 염색방법 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2918993B1 (fr) | 2007-07-20 | 2012-12-14 | Rhodia Operations | Utilisation de diesters d'acide carboxylique pour le traitement de textiles et formulation. |
FR2918994B1 (fr) * | 2007-07-20 | 2012-10-19 | Rhodia Operations | Formulations de diesters d'acide carboxylique et leur utilisation pour le traitement de materiaux. |
KR101673589B1 (ko) * | 2009-10-30 | 2016-11-07 | 동우 화인켐 주식회사 | 평판표시장치의 유리기판용 세정제 조성물 |
CN103511897B (zh) * | 2013-09-26 | 2017-02-08 | 江苏彤明高科汽车电器有限公司 | 一种led驱动电路 |
JP6870878B1 (ja) | 2020-09-23 | 2021-05-12 | 竹本油脂株式会社 | 弾性繊維用処理剤及び弾性繊維 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH329338A (de) * | 1953-12-29 | 1958-04-30 | Ciba Geigy | Beständiges Präparat zur Erhöhung des Netzvermögens von Mercerisierflotten |
GB2014618B (en) * | 1978-02-17 | 1982-05-06 | Bayer Ag | Dyeing process |
EP0638635A1 (fr) * | 1993-08-12 | 1995-02-15 | Ciba-Geigy Ag | Adjuvants textiles aqueux |
FR2721921B1 (fr) * | 1994-07-01 | 1996-10-31 | Rhone Poulenc Chimie | Derives d'origine terpenique, composition tensioactive et/ou parfumante en contenant et formulation detergente a base de cette composition |
FR2757508B1 (fr) * | 1996-12-20 | 1999-02-26 | Rhodia Chimie Sa | Composes terpeniques polyalcoxyles, leur procede de preparation et leur utilisation comme agents demoussants |
EP0881324A3 (fr) * | 1997-05-26 | 1999-12-01 | Bayer Ag | Procédé pour teindre et enlever simultanément les agents d'avivage des fibres synthétiques |
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1999
- 1999-06-07 FR FR9907240A patent/FR2794476B1/fr not_active Expired - Fee Related
-
2000
- 2000-06-06 AU AU54120/00A patent/AU5412000A/en not_active Abandoned
- 2000-06-06 JP JP2001501688A patent/JP2003528988A/ja active Pending
- 2000-06-06 KR KR1020017015772A patent/KR20020019067A/ko not_active Application Discontinuation
- 2000-06-06 CN CN00809385A patent/CN1358246A/zh active Pending
- 2000-06-06 EP EP00938892A patent/EP1183418A1/fr not_active Withdrawn
- 2000-06-06 WO PCT/FR2000/001543 patent/WO2000075416A1/fr active Search and Examination
- 2000-06-07 CO CO00042365A patent/CO5210971A1/es not_active Application Discontinuation
- 2000-06-07 AR ARP000102813A patent/AR024303A1/es unknown
Non-Patent Citations (1)
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See references of WO0075416A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100419524B1 (ko) * | 2001-06-27 | 2004-02-19 | 주식회사 효성 | 천연 테르펜을 캐리어로 사용하는 폴리트리메틸렌 테레프탈레이트 섬유의 염색방법 |
Also Published As
Publication number | Publication date |
---|---|
CO5210971A1 (es) | 2002-10-30 |
JP2003528988A (ja) | 2003-09-30 |
FR2794476A1 (fr) | 2000-12-08 |
CN1358246A (zh) | 2002-07-10 |
FR2794476B1 (fr) | 2001-11-16 |
WO2000075416A1 (fr) | 2000-12-14 |
AU5412000A (en) | 2000-12-28 |
AR024303A1 (es) | 2002-09-25 |
KR20020019067A (ko) | 2002-03-09 |
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