EP1104805A3 - Detergent tablet - Google Patents

Detergent tablet Download PDF

Info

Publication number
EP1104805A3
EP1104805A3 EP01104424A EP01104424A EP1104805A3 EP 1104805 A3 EP1104805 A3 EP 1104805A3 EP 01104424 A EP01104424 A EP 01104424A EP 01104424 A EP01104424 A EP 01104424A EP 1104805 A3 EP1104805 A3 EP 1104805A3
Authority
EP
European Patent Office
Prior art keywords
phase
tablet
mould
detergent
detergent tablet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01104424A
Other languages
German (de)
French (fr)
Other versions
EP1104805A2 (en
EP1104805B1 (en
Inventor
Patrizio Ricci
Brenda Frances Bennie
Christopher James Binder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP03003527A priority Critical patent/EP1327676B1/en
Priority claimed from EP99305386A external-priority patent/EP0979865B1/en
Publication of EP1104805A2 publication Critical patent/EP1104805A2/en
Publication of EP1104805A3 publication Critical patent/EP1104805A3/en
Application granted granted Critical
Publication of EP1104805B1 publication Critical patent/EP1104805B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0086—Laundry tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0091—Dishwashing tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

1. A multi-phase detergent tablet for use in a washing machine, the tablet comprising:
  • a) a first phase in the form of a shaped body having at least one mould therein; and
  • b) a second phase in the form of a compressed body adhesively contained within said mould, wherein the tablet composition comprises one or more detergent actives which is predominantly concentrated in the second phase, and wherein the second phase additionally comprises a binder. The multi-phase tablets provide improved dissolution and cleaning characteristics together with excellent tablet integrity and strength.
    •
    EP01104424A 1998-07-17 1999-07-07 Detergent tablet Expired - Lifetime EP1104805B1 (en)

    Priority Applications (1)

    Application Number Priority Date Filing Date Title
    EP03003527A EP1327676B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Applications Claiming Priority (5)

    Application Number Priority Date Filing Date Title
    GB9815525 1998-07-17
    GBGB9815525.2A GB9815525D0 (en) 1998-07-17 1998-07-17 Detergent tablet
    GB9911268 1999-05-17
    GB9911268A GB2339793B (en) 1998-07-17 1999-05-17 Detergent tablet
    EP99305386A EP0979865B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Related Parent Applications (1)

    Application Number Title Priority Date Filing Date
    EP99305386A Division EP0979865B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Related Child Applications (1)

    Application Number Title Priority Date Filing Date
    EP03003527A Division EP1327676B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Publications (3)

    Publication Number Publication Date
    EP1104805A2 EP1104805A2 (en) 2001-06-06
    EP1104805A3 true EP1104805A3 (en) 2001-06-13
    EP1104805B1 EP1104805B1 (en) 2003-06-04

    Family

    ID=10835661

    Family Applications (6)

    Application Number Title Priority Date Filing Date
    EP03003528A Expired - Lifetime EP1327677B1 (en) 1998-07-17 1999-07-07 detergent tablet
    EP01104424A Expired - Lifetime EP1104805B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104426A Expired - Lifetime EP1103596B1 (en) 1998-07-17 1999-07-07 Detergent Tablets and their Production
    EP01104427A Expired - Lifetime EP1103597B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP03003527A Expired - Lifetime EP1327676B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104425A Expired - Lifetime EP1103595B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Family Applications Before (1)

    Application Number Title Priority Date Filing Date
    EP03003528A Expired - Lifetime EP1327677B1 (en) 1998-07-17 1999-07-07 detergent tablet

    Family Applications After (4)

    Application Number Title Priority Date Filing Date
    EP01104426A Expired - Lifetime EP1103596B1 (en) 1998-07-17 1999-07-07 Detergent Tablets and their Production
    EP01104427A Expired - Lifetime EP1103597B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP03003527A Expired - Lifetime EP1327676B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104425A Expired - Lifetime EP1103595B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Country Status (8)

    Country Link
    EP (6) EP1327677B1 (en)
    AR (1) AR019408A1 (en)
    CO (1) CO5130036A1 (en)
    DE (4) DE29923876U1 (en)
    GB (5) GB9815525D0 (en)
    HK (1) HK1046425A1 (en)
    PE (1) PE20001007A1 (en)
    SA (3) SA99200726B1 (en)

    Families Citing this family (13)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    GB2347431A (en) * 1999-03-04 2000-09-06 Procter & Gamble Detergent tablet
    US6770616B1 (en) 1999-03-04 2004-08-03 The Procter & Gamble Company Detergent tablet
    DE60001795T2 (en) * 1999-12-17 2003-10-23 Unilever N.V., Rotterdam Use of detergents
    GB2384244B (en) 2002-01-18 2004-03-24 Reckitt Benckiser Cleaning compositions and uses
    GB2386130A (en) 2002-03-06 2003-09-10 Reckitt Benckiser Nv Detergent dosing delay device for a dishwasher
    EP1382668B1 (en) * 2002-06-11 2009-08-12 Unilever N.V. Detergent tablets
    ATE391168T1 (en) * 2002-06-11 2008-04-15 Unilever Nv DETERGENT TABLETS
    AU2003242641A1 (en) * 2002-06-11 2003-12-22 Unilever Plc Detergent tablets
    DE102004011256B4 (en) * 2004-03-09 2007-11-15 Henkel Kgaa Multi-phase tablets with improved fragrance perception
    EP3181671B1 (en) * 2015-12-17 2024-07-10 The Procter & Gamble Company Automatic dishwashing detergent composition
    EP3181672A1 (en) * 2015-12-17 2017-06-21 The Procter and Gamble Company Automatic dishwashing detergent composition
    DE102019220454A1 (en) * 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Method for cleaning and maintaining an automatic dishwasher
    DE102019220460A1 (en) * 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Method for cleaning and maintaining an automatic dishwasher

    Citations (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    EP0466484A2 (en) * 1990-07-13 1992-01-15 Unilever Plc Detergent compositions
    EP0481793A1 (en) * 1990-10-19 1992-04-22 Unilever Plc Detergent composition in tablet form
    EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
    EP0716144A2 (en) * 1994-11-14 1996-06-12 Unilever Plc Detergent tablet having a water-soluble coating
    WO1999027067A1 (en) * 1997-11-26 1999-06-03 The Procter & Gamble Company Detergent tablet

    Family Cites Families (10)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    FR2035622A5 (en) * 1969-02-18 1970-12-18 Lion Fat Oil Co Ltd
    US3962107A (en) * 1974-06-24 1976-06-08 Johnson & Johnson Enzyme-containing denture cleanser tablet
    US4460490A (en) * 1980-12-18 1984-07-17 Jeyes Group Limited Lavatory cleansing blocks
    GB9114184D0 (en) * 1991-07-01 1991-08-21 Unilever Plc Detergent composition
    ATE198349T1 (en) * 1995-07-13 2001-01-15 Benckiser Nv DISHWASHER DETERGENT IN THE FORM OF A TABLET
    US5900395A (en) * 1996-12-23 1999-05-04 Lever Brothers Company Machine dishwashing tablets containing an oxygen bleach system
    GB9711829D0 (en) * 1997-06-06 1997-08-06 Unilever Plc Detergent compositions
    GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet
    DE19758175A1 (en) * 1997-12-30 1999-07-01 Henkel Kgaa Dishwasher detergent tablets with specific solubility
    DE29911484U1 (en) * 1998-07-17 2000-02-24 The Procter & Gamble Co., Cincinnati, Ohio Detergent tablet

    Patent Citations (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    EP0466484A2 (en) * 1990-07-13 1992-01-15 Unilever Plc Detergent compositions
    EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
    EP0481793A1 (en) * 1990-10-19 1992-04-22 Unilever Plc Detergent composition in tablet form
    EP0716144A2 (en) * 1994-11-14 1996-06-12 Unilever Plc Detergent tablet having a water-soluble coating
    WO1999027067A1 (en) * 1997-11-26 1999-06-03 The Procter & Gamble Company Detergent tablet

    Also Published As

    Publication number Publication date
    GB9911217D0 (en) 1999-07-14
    DE29923872U1 (en) 2001-08-30
    EP1103596B1 (en) 2003-05-21
    EP1103596A2 (en) 2001-05-30
    SA99200726B1 (en) 2006-05-23
    HK1046425A1 (en) 2003-01-10
    PE20001007A1 (en) 2000-10-09
    DE29923873U1 (en) 2001-07-26
    EP1327676A2 (en) 2003-07-16
    GB2339792A (en) 2000-02-09
    EP1327677A2 (en) 2003-07-16
    SA99200727B1 (en) 2006-05-23
    GB2339791A (en) 2000-02-09
    EP1103597B1 (en) 2003-09-24
    GB2339793A (en) 2000-02-09
    EP1327677A3 (en) 2003-08-13
    EP1103595B1 (en) 2003-06-04
    EP1103597A3 (en) 2001-06-06
    GB9911264D0 (en) 1999-07-14
    GB2339790B (en) 2001-01-24
    DE29923874U1 (en) 2001-08-30
    EP1104805A2 (en) 2001-06-06
    DE29923876U1 (en) 2001-08-30
    EP1103595A3 (en) 2001-06-13
    EP1327676A3 (en) 2003-08-13
    EP1103597A2 (en) 2001-05-30
    GB2339793B (en) 2001-01-24
    GB2339792B (en) 2001-01-24
    GB9815525D0 (en) 1998-09-16
    GB2339791B (en) 2001-01-24
    EP1103595A2 (en) 2001-05-30
    EP1327676B1 (en) 2006-10-18
    SA99200725B1 (en) 2006-07-30
    CO5130036A1 (en) 2002-02-27
    GB9911268D0 (en) 1999-07-14
    GB9911218D0 (en) 1999-07-14
    EP1103596A3 (en) 2001-06-13
    GB2339790A (en) 2000-02-09
    EP1327677B1 (en) 2006-09-06
    EP1104805B1 (en) 2003-06-04
    AR019408A1 (en) 2002-02-20

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