CO5130036A1 - MULTIPLE PHASE DETERGENT TABLET FOR USE IN WASHING MACHINE - Google Patents

MULTIPLE PHASE DETERGENT TABLET FOR USE IN WASHING MACHINE

Info

Publication number
CO5130036A1
CO5130036A1 CO99045196A CO99045196A CO5130036A1 CO 5130036 A1 CO5130036 A1 CO 5130036A1 CO 99045196 A CO99045196 A CO 99045196A CO 99045196 A CO99045196 A CO 99045196A CO 5130036 A1 CO5130036 A1 CO 5130036A1
Authority
CO
Colombia
Prior art keywords
weight
salts
phase
compound
corrosion inhibitor
Prior art date
Application number
CO99045196A
Other languages
Spanish (es)
Inventor
Patrizio Ricci
Frances Bennie Brenda
Christopher James Binder
Del Duca Valerio
Andrea Esposito
Original Assignee
Procter & Gamble
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter & Gamble filed Critical Procter & Gamble
Publication of CO5130036A1 publication Critical patent/CO5130036A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0086—Laundry tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0091—Dishwashing tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Abstract

La presente invención se relaciona con una tableta detergente de fase múltiple para uso en una máquina de lavar, la tableta comprende: a) una primera fase en la forma de un cuerpo moldeado que tiene al menos un molde dentro, dicha primera fase comprende uno o más componentes de detergentes seleccionados del grupo consistente de 1% a 80% en peso de un componente mejorador, desde 0.2% a 30% en peso de un surfactante, niveles de 0.0001% a 2% de enzima activa en peso de la composición detergente, agentes blanqueadores que incluyen sales de perhidrato inorgánico de desde 1% a 40% en peso, y compuestos precursores peroxiácidos de blanqueo de desde 0.5% a 20% en peso, sales de relleno, desde 0.1% a 30% de un compuesto polimérico orgánico, perfumes, desde 0.01% a 10% de agentes poliméricos de inhibición de transferencia de colorantes, desde 0.005% a 20% de secuestrantes de iones de metal pesado, fuentes de alcalinidad, desde 0.01% a 5% de un inhibidor de cristal, sales de ion de metal incluyendo desde 0.1 %a 40% de una sal de sulfato soluble en agua y un silicato de metal alcalino presente a un nivel de menos de 20 %, desde 0.001% a 1.5% de un colorante, un compuesto inhibidor de corrosión incluyendo desde 0.05% a 10% de un agente de revestimiento de plata orgánico y desde 0.005% a 5% en peso de un compuesto inhibidor de corrosión con Mn(II), solventes, desde 0.005% a 20% de un compuesto de bismuto soluble en agua, desde 0.001% a 10% de un sistema estabilizante de enzima, desde 0.1% a 40% en peso de un dispersante de jabón de cal, desde 0.01% a 15% de un supresor de espuma, aceites de hidrocarburo, desde 0.005% a 5% en peso de un abrillantador óptico, hidrótopos, agentes suavizantes de telas incluyendo desde 05% a 15% en peso de un agente catiónico suavizante de telas y un sistema suavizante con arcilla; y b) una segunda fase en la forma de un sólido particulado comprimido dentro de dicho molde en donde dicha segunda fase comprende uno o más componentes de detergentes seleccionados del grupo consistente de 1% a 80% en peso de un componente mejorador, desde 0.2% a 30% en peso de un surfactante, niveles de 0.0001% a 2% de enzima activa en peso de la composición detergente, agentes blanqueadores que incluyen sales de perhidrato inorgánico de desde 1% a 40% en peso, y compuestos precursores peroxiácidos de blanqueo de desde 05% a 20% en peso, sales de relleno, desde 0.1% a 30% de un compuesto polimérico orgánico, perfumes, desde 0.01% a 10% de agentes poliméricos de inhibición de transferencia de colorantes, desde 0.005% a 20% de secuestrantes de iones de metal pesado, fuentes de alcalinidad, desde 0.01% a 5% de un inhibidor de cristal, sales de ion de metal incluyendo desde 0.1% a 40% de una sal de sulfato soluble en agua y un silicato de metal alcalino presente a un nivel de menos de 20%, desde 0.001% a 1.5% de un colorante, un compuesto inhibidor de corrosión incluyendo desde 0.05% a 10% de un agente de revestimiento de plata orgánico y desde 0.005% a 5% en peso de un compuesto inhibidor de corrosión con Mn(II), solventes, ...The present invention relates to a multi-phase detergent tablet for use in a washing machine, the tablet comprises: a) a first phase in the form of a molded body having at least one mold inside, said first phase comprising one or more detergent components selected from the group consisting of 1% to 80% by weight of an improving component, from 0.2% to 30% by weight of a surfactant, levels of 0.0001% to 2% of active enzyme by weight of the detergent composition, bleaching agents including inorganic perhydrate salts of from 1% to 40% by weight, and peroxyacid bleaching precursors of from 0.5% to 20% by weight, filler salts, from 0.1% to 30% of an organic polymeric compound, perfumes, from 0.01% to 10% of polymeric agents for dye transfer inhibition, from 0.005% to 20% of heavy metal ion sequestrants, alkalinity sources, from 0.01% to 5% of a crystal inhibitor, salts of met ion by including from 0.1% to 40% of a water soluble sulfate salt and an alkali metal silicate present at a level of less than 20%, from 0.001% to 1.5% of a dye, a corrosion inhibitor compound including from 0.05 % to 10% of an organic silver coating agent and from 0.005% to 5% by weight of a corrosion inhibitor compound with Mn (II), solvents, from 0.005% to 20% of a water-soluble bismuth compound, from 0.001% to 10% of an enzyme stabilizer system, from 0.1% to 40% by weight of a lime soap dispersant, from 0.01% to 15% of a foam suppressor, hydrocarbon oils, from 0.005% to 5 % by weight of an optical brightener, hydrotopes, fabric softening agents including from 05% to 15% by weight of a cationic fabric softening agent and a clay softening system; and b) a second phase in the form of a compressed particulate solid within said mold wherein said second phase comprises one or more detergent components selected from the group consisting of 1% to 80% by weight of an improver component, from 0.2% to 30% by weight of a surfactant, levels of 0.0001% to 2% of active enzyme by weight of the detergent composition, bleaching agents including inorganic perhydrate salts of from 1% to 40% by weight, and peroxyacid bleaching precursor compounds of from 05% to 20% by weight, filler salts, from 0.1% to 30% of an organic polymer compound, perfumes, from 0.01% to 10% of polymeric agents for dye transfer inhibition, from 0.005% to 20% of heavy metal ion sequestrants, alkalinity sources, from 0.01% to 5% of a crystal inhibitor, metal ion salts including from 0.1% to 40% of a water soluble sulfate salt and an alkali metal silicate present at a menu level 20%, from 0.001% to 1.5% of a dye, a corrosion inhibitor compound including from 0.05% to 10% of an organic silver coating agent and from 0.005% to 5% by weight of a corrosion inhibitor compound with Mn (II), solvents, ...

CO99045196A 1998-07-17 1999-07-16 MULTIPLE PHASE DETERGENT TABLET FOR USE IN WASHING MACHINE CO5130036A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9815525.2A GB9815525D0 (en) 1998-07-17 1998-07-17 Detergent tablet
GB9911218A GB2339791B (en) 1998-07-17 1999-05-17 Detergent tablet

Publications (1)

Publication Number Publication Date
CO5130036A1 true CO5130036A1 (en) 2002-02-27

Family

ID=10835661

Family Applications (1)

Application Number Title Priority Date Filing Date
CO99045196A CO5130036A1 (en) 1998-07-17 1999-07-16 MULTIPLE PHASE DETERGENT TABLET FOR USE IN WASHING MACHINE

Country Status (8)

Country Link
EP (6) EP1327676B1 (en)
AR (1) AR019408A1 (en)
CO (1) CO5130036A1 (en)
DE (4) DE29923872U1 (en)
GB (5) GB9815525D0 (en)
HK (1) HK1046425A1 (en)
PE (1) PE20001007A1 (en)
SA (3) SA99200726B1 (en)

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Publication number Priority date Publication date Assignee Title
GB2347431A (en) * 1999-03-04 2000-09-06 Procter & Gamble Detergent tablet
US6770616B1 (en) 1999-03-04 2004-08-03 The Procter & Gamble Company Detergent tablet
DE60001795T2 (en) * 1999-12-17 2003-10-23 Unilever Nv Use of detergents
GB2384244B (en) 2002-01-18 2004-03-24 Reckitt Benckiser Cleaning compositions and uses
GB2386130A (en) 2002-03-06 2003-09-10 Reckitt Benckiser Nv Detergent dosing delay device for a dishwasher
ES2249731T3 (en) * 2002-06-11 2006-04-01 Unilever N.V. DETERGENT PADS.
DE60320062D1 (en) * 2002-06-11 2008-05-15 Unilever Nv detergent tablets
ES2331788T3 (en) * 2002-06-11 2010-01-15 Unilever N.V. DETERGENT PADS.
DE102004011256B4 (en) * 2004-03-09 2007-11-15 Henkel Kgaa Multi-phase tablets with improved fragrance perception
EP3181671A1 (en) * 2015-12-17 2017-06-21 The Procter and Gamble Company Automatic dishwashing detergent composition
EP3181672A1 (en) * 2015-12-17 2017-06-21 The Procter and Gamble Company Automatic dishwashing detergent composition
DE102019220460A1 (en) * 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Method for cleaning and maintaining an automatic dishwasher
DE102019220454A1 (en) * 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Method for cleaning and maintaining an automatic dishwasher

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FR2035622A5 (en) * 1969-02-18 1970-12-18 Lion Fat Oil Co Ltd
US3962107A (en) * 1974-06-24 1976-06-08 Johnson & Johnson Enzyme-containing denture cleanser tablet
CA1182371A (en) * 1980-12-18 1985-02-12 Jeyes Group Limited Lavatory cleansing blocks
GB9015503D0 (en) * 1990-07-13 1990-08-29 Unilever Plc Detergent composition
US5133892A (en) * 1990-10-17 1992-07-28 Lever Brothers Company, Division Of Conopco, Inc. Machine dishwashing detergent tablets
GB9022724D0 (en) * 1990-10-19 1990-12-05 Unilever Plc Detergent compositions
GB9114184D0 (en) * 1991-07-01 1991-08-21 Unilever Plc Detergent composition
GB9422924D0 (en) * 1994-11-14 1995-01-04 Unilever Plc Detergent compositions
EP0842257B1 (en) * 1995-07-13 2000-12-27 Benckiser N.V. Dish washer product in tablet form
US5900395A (en) * 1996-12-23 1999-05-04 Lever Brothers Company Machine dishwashing tablets containing an oxygen bleach system
GB9711829D0 (en) * 1997-06-06 1997-08-06 Unilever Plc Detergent compositions
GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet
ATE218612T1 (en) * 1997-11-26 2002-06-15 Procter & Gamble DISHWASHING METHOD
DE19758175A1 (en) * 1997-12-30 1999-07-01 Henkel Kgaa Dishwasher detergent tablets with specific solubility
DE29911484U1 (en) * 1998-07-17 2000-02-24 Procter & Gamble Detergent tablet

Also Published As

Publication number Publication date
GB9911217D0 (en) 1999-07-14
DE29923876U1 (en) 2001-08-30
EP1104805A3 (en) 2001-06-13
EP1103595A2 (en) 2001-05-30
GB9911218D0 (en) 1999-07-14
DE29923873U1 (en) 2001-07-26
HK1046425A1 (en) 2003-01-10
DE29923872U1 (en) 2001-08-30
AR019408A1 (en) 2002-02-20
EP1103597A2 (en) 2001-05-30
EP1103597B1 (en) 2003-09-24
GB2339793A (en) 2000-02-09
DE29923874U1 (en) 2001-08-30
EP1104805B1 (en) 2003-06-04
EP1327676A2 (en) 2003-07-16
EP1103596B1 (en) 2003-05-21
GB2339790B (en) 2001-01-24
GB9911264D0 (en) 1999-07-14
EP1103595B1 (en) 2003-06-04
GB9815525D0 (en) 1998-09-16
EP1103596A3 (en) 2001-06-13
GB2339791A (en) 2000-02-09
GB2339792B (en) 2001-01-24
EP1104805A2 (en) 2001-06-06
GB9911268D0 (en) 1999-07-14
EP1103595A3 (en) 2001-06-13
GB2339790A (en) 2000-02-09
GB2339793B (en) 2001-01-24
EP1327677A2 (en) 2003-07-16
SA99200725B1 (en) 2006-07-30
GB2339792A (en) 2000-02-09
EP1327677A3 (en) 2003-08-13
EP1103597A3 (en) 2001-06-06
SA99200726B1 (en) 2006-05-23
SA99200727B1 (en) 2006-05-23
EP1327677B1 (en) 2006-09-06
EP1327676B1 (en) 2006-10-18
EP1327676A3 (en) 2003-08-13
EP1103596A2 (en) 2001-05-30
GB2339791B (en) 2001-01-24
PE20001007A1 (en) 2000-10-09

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