EP1103597A3 - Detergent tablet - Google Patents

Detergent tablet Download PDF

Info

Publication number
EP1103597A3
EP1103597A3 EP01104427A EP01104427A EP1103597A3 EP 1103597 A3 EP1103597 A3 EP 1103597A3 EP 01104427 A EP01104427 A EP 01104427A EP 01104427 A EP01104427 A EP 01104427A EP 1103597 A3 EP1103597 A3 EP 1103597A3
Authority
EP
European Patent Office
Prior art keywords
phase
detergent tablet
mould
tablet
enzyme
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01104427A
Other languages
German (de)
French (fr)
Other versions
EP1103597B1 (en
EP1103597A2 (en
Inventor
Patrizio Ricci
Brenda Frances Bennie
Christopher James Binder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority claimed from EP99305384A external-priority patent/EP0976819B1/en
Publication of EP1103597A2 publication Critical patent/EP1103597A2/en
Publication of EP1103597A3 publication Critical patent/EP1103597A3/en
Application granted granted Critical
Publication of EP1103597B1 publication Critical patent/EP1103597B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0086—Laundry tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0091—Dishwashing tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

A multi-phase detergent tablet comprising:
  • a) a first phase in the form of a shaped body having at least one mould therein; and
  • b) a second phase in the form of a compressed body adhesively contained within said mould, and wherein the second phase comprises an enzyme. The multi-phase tablets provide improved dissolution and cleaning characteristics together with excellent tablet integrity and strength.
    •
    EP01104427A 1998-07-17 1999-07-07 Detergent tablet Expired - Lifetime EP1103597B1 (en)

    Applications Claiming Priority (5)

    Application Number Priority Date Filing Date Title
    GB9815525 1998-07-17
    GBGB9815525.2A GB9815525D0 (en) 1998-07-17 1998-07-17 Detergent tablet
    GB9911218 1999-05-17
    GB9911218A GB2339791B (en) 1998-07-17 1999-05-17 Detergent tablet
    EP99305384A EP0976819B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Related Parent Applications (1)

    Application Number Title Priority Date Filing Date
    EP99305384A Division EP0976819B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Publications (3)

    Publication Number Publication Date
    EP1103597A2 EP1103597A2 (en) 2001-05-30
    EP1103597A3 true EP1103597A3 (en) 2001-06-06
    EP1103597B1 EP1103597B1 (en) 2003-09-24

    Family

    ID=10835661

    Family Applications (6)

    Application Number Title Priority Date Filing Date
    EP03003528A Expired - Lifetime EP1327677B1 (en) 1998-07-17 1999-07-07 detergent tablet
    EP03003527A Expired - Lifetime EP1327676B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104427A Expired - Lifetime EP1103597B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104425A Expired - Lifetime EP1103595B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104424A Expired - Lifetime EP1104805B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104426A Expired - Lifetime EP1103596B1 (en) 1998-07-17 1999-07-07 Detergent Tablets and their Production

    Family Applications Before (2)

    Application Number Title Priority Date Filing Date
    EP03003528A Expired - Lifetime EP1327677B1 (en) 1998-07-17 1999-07-07 detergent tablet
    EP03003527A Expired - Lifetime EP1327676B1 (en) 1998-07-17 1999-07-07 Detergent tablet

    Family Applications After (3)

    Application Number Title Priority Date Filing Date
    EP01104425A Expired - Lifetime EP1103595B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104424A Expired - Lifetime EP1104805B1 (en) 1998-07-17 1999-07-07 Detergent tablet
    EP01104426A Expired - Lifetime EP1103596B1 (en) 1998-07-17 1999-07-07 Detergent Tablets and their Production

    Country Status (8)

    Country Link
    EP (6) EP1327677B1 (en)
    AR (1) AR019408A1 (en)
    CO (1) CO5130036A1 (en)
    DE (4) DE29923874U1 (en)
    GB (5) GB9815525D0 (en)
    HK (1) HK1046425A1 (en)
    PE (1) PE20001007A1 (en)
    SA (3) SA99200727B1 (en)

    Families Citing this family (13)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    GB2347431A (en) * 1999-03-04 2000-09-06 Procter & Gamble Detergent tablet
    US6770616B1 (en) 1999-03-04 2004-08-03 The Procter & Gamble Company Detergent tablet
    ATE235545T1 (en) * 1999-12-17 2003-04-15 Unilever Nv USE OF DISHWASHING DETERGENT
    GB2384244B (en) 2002-01-18 2004-03-24 Reckitt Benckiser Cleaning compositions and uses
    GB2386130A (en) 2002-03-06 2003-09-10 Reckitt Benckiser Nv Detergent dosing delay device for a dishwasher
    EP1371720B1 (en) * 2002-06-11 2008-04-02 Unilever N.V. Detergent tablets
    ATE439422T1 (en) * 2002-06-11 2009-08-15 Unilever Nv DETERGENT TABLETS
    DE60301968T2 (en) * 2002-06-11 2006-05-11 Unilever N.V. DETERGENT TABLETS
    DE102004011256B4 (en) * 2004-03-09 2007-11-15 Henkel Kgaa Multi-phase tablets with improved fragrance perception
    EP3181672A1 (en) * 2015-12-17 2017-06-21 The Procter and Gamble Company Automatic dishwashing detergent composition
    US10808207B2 (en) * 2015-12-17 2020-10-20 The Procter & Gamble Company Automatic dishwashing detergent composition
    DE102019220460A1 (en) * 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Method for cleaning and maintaining an automatic dishwasher
    DE102019220454A1 (en) * 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Method for cleaning and maintaining an automatic dishwasher

    Citations (4)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    DE2527534A1 (en) * 1974-06-24 1976-01-15 Johnson & Johnson ENZYMAL CLEANING TABLET FOR ARTIFICIAL BITES
    EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
    EP0851025A2 (en) * 1996-12-23 1998-07-01 Unilever N.V. Machine dishwashing tablets containing an oxygen bleach system
    GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet

    Family Cites Families (11)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    DE2065153C3 (en) * 1969-02-18 1974-04-11 Raion Yushi K.K., Tokio MULTI-COMPONENT DETERGENT MOLDING
    CA1182371A (en) * 1980-12-18 1985-02-12 Jeyes Group Limited Lavatory cleansing blocks
    GB9015503D0 (en) * 1990-07-13 1990-08-29 Unilever Plc Detergent composition
    GB9022724D0 (en) * 1990-10-19 1990-12-05 Unilever Plc Detergent compositions
    GB9114184D0 (en) * 1991-07-01 1991-08-21 Unilever Plc Detergent composition
    GB9422924D0 (en) * 1994-11-14 1995-01-04 Unilever Plc Detergent compositions
    ES2155613T3 (en) * 1995-07-13 2001-05-16 Reckitt Benckiser Nv PRODUCT IN THE FORM OF A DISHWASHER TABLET.
    GB9711829D0 (en) * 1997-06-06 1997-08-06 Unilever Plc Detergent compositions
    ES2257375T3 (en) * 1997-11-26 2006-08-01 THE PROCTER & GAMBLE COMPANY DETERGENT PAD.
    DE19758175A1 (en) * 1997-12-30 1999-07-01 Henkel Kgaa Dishwasher detergent tablets with specific solubility
    DE29911484U1 (en) * 1998-07-17 2000-02-24 Procter & Gamble Detergent tablet

    Patent Citations (4)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    DE2527534A1 (en) * 1974-06-24 1976-01-15 Johnson & Johnson ENZYMAL CLEANING TABLET FOR ARTIFICIAL BITES
    EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
    EP0851025A2 (en) * 1996-12-23 1998-07-01 Unilever N.V. Machine dishwashing tablets containing an oxygen bleach system
    GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet

    Also Published As

    Publication number Publication date
    EP1327676A3 (en) 2003-08-13
    EP1327677B1 (en) 2006-09-06
    GB9911268D0 (en) 1999-07-14
    GB2339792B (en) 2001-01-24
    GB9911217D0 (en) 1999-07-14
    EP1104805B1 (en) 2003-06-04
    GB2339791B (en) 2001-01-24
    SA99200727B1 (en) 2006-05-23
    DE29923872U1 (en) 2001-08-30
    EP1103596A2 (en) 2001-05-30
    EP1327676B1 (en) 2006-10-18
    EP1103596B1 (en) 2003-05-21
    GB2339791A (en) 2000-02-09
    PE20001007A1 (en) 2000-10-09
    GB2339792A (en) 2000-02-09
    CO5130036A1 (en) 2002-02-27
    EP1104805A3 (en) 2001-06-13
    EP1103595A2 (en) 2001-05-30
    EP1103595A3 (en) 2001-06-13
    DE29923873U1 (en) 2001-07-26
    HK1046425A1 (en) 2003-01-10
    GB2339793A (en) 2000-02-09
    GB9815525D0 (en) 1998-09-16
    GB9911218D0 (en) 1999-07-14
    GB2339790B (en) 2001-01-24
    SA99200726B1 (en) 2006-05-23
    GB9911264D0 (en) 1999-07-14
    EP1103596A3 (en) 2001-06-13
    EP1327677A2 (en) 2003-07-16
    AR019408A1 (en) 2002-02-20
    GB2339793B (en) 2001-01-24
    DE29923874U1 (en) 2001-08-30
    DE29923876U1 (en) 2001-08-30
    EP1327677A3 (en) 2003-08-13
    EP1104805A2 (en) 2001-06-06
    EP1103597B1 (en) 2003-09-24
    GB2339790A (en) 2000-02-09
    EP1103597A2 (en) 2001-05-30
    EP1327676A2 (en) 2003-07-16
    EP1103595B1 (en) 2003-06-04
    SA99200725B1 (en) 2006-07-30

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