EP1098575B1 - Textilverbundmaterial zur herstellung von wärmeschutzkleidungstücken - Google Patents

Textilverbundmaterial zur herstellung von wärmeschutzkleidungstücken Download PDF

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Publication number
EP1098575B1
EP1098575B1 EP99932966A EP99932966A EP1098575B1 EP 1098575 B1 EP1098575 B1 EP 1098575B1 EP 99932966 A EP99932966 A EP 99932966A EP 99932966 A EP99932966 A EP 99932966A EP 1098575 B1 EP1098575 B1 EP 1098575B1
Authority
EP
European Patent Office
Prior art keywords
lining
beads
fabric
composite according
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99932966A
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English (en)
French (fr)
Other versions
EP1098575B2 (de
EP1098575A1 (de
Inventor
Thierry Lanier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Europrotect France SA
Original Assignee
Europrotect France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Europrotect France filed Critical Europrotect France
Publication of EP1098575A1 publication Critical patent/EP1098575A1/de
Publication of EP1098575B1 publication Critical patent/EP1098575B1/de
Application granted granted Critical
Publication of EP1098575B2 publication Critical patent/EP1098575B2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • A41D31/085—Heat resistant; Fire retardant using layered materials
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
    • A41D31/102—Waterproof and breathable
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/12—Hygroscopic; Water retaining
    • A41D31/125—Moisture handling or wicking function through layered materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24562—Interlaminar spaces

Definitions

  • the subject of the present invention is a textile complex for realization of thermal protective clothing.
  • Thermal stress is reflected in an elevation of the internal temperature of the body that is no longer able to thermoregulate, which can lead to discomfort, or even a syncope or a heart attack.
  • the latest study on the deaths of firefighters U.S.A. announces only 8% of burn deaths, 42% of deaths are directly due to heat stress and the remaining 50% are accidents with no apparent cause but that specialists bring closer to more and more intelligent accidents related to impaired judgment related to thermal stress.
  • a jacket must have a number of criteria, including protection against radiant heat, protection against heat convective, possess good thermal stability of materials constituents, fulfill criteria of pure non-flammability, and possess a good impermeability.
  • a jacket must allow an operator to protect it in extreme conditions of an accidental nature, including by providing a time of escape.
  • it is necessary to protect a firefighter against a phenomenon of "flash-over". Flash-over is a very fast transition stage in the development of a city fire and occurs when gases and vapors in a room reach a temperature of 500 to 600 ° C and ignite suddenly. In a fraction of a second, the temperature rises from 500 to 1000 ° C, corresponding to an incident heat flux of the order of 40 kW / m 2 .
  • An operator should be allowed to resist this sudden increase in temperature long enough to be able to move away from home.
  • Such a textile complex comprises a fabric outer protection made of non-flammable material, for example base of aramid fiber, meta-aramid or polyamide imide.
  • This fabric integrates thermal protection qualities, brings performance mechanical resistance to abrasion and tearing, and suffered a water repellent treatment to make it water and water repellent in general.
  • Behind this protective fabric find a waterproof and breathable membrane, usually fixed on a textile surface ensuring its mechanical strength, allowing to leave pass the resulting water vapor for example from the perspiration of a user, but not water in its liquid form.
  • this membrane provides a windbreak effect, which contributes to the thermal insulation of the jacket by slowing the penetration of heat flows.
  • thermal insulation constituted by a mesh knit three-dimensional, as described in EP 0443991, or by a felt likely to trap air, as described in the document EP 0 364 370. This thermal insulation is generally sewn on a lining of cleanliness.
  • Such a jacket has the advantage of providing excellent thermal protection under an extremely high heat flow of 40 kW / m 2 , a very important efficiency, even too important because of its high insulating power it does not allow to the user to be sensitive to heat to heat flows of 0 to 1 kW / m 2, corresponding to the usual working conditions of firefighters, and to detect a possible danger. Under these conditions, the overprotected operator may have to take unmeasured risks due to an alteration of the perception of the heat flow.
  • Such a jacket is also uncomfortable insofar as it is thick and heavy, and where it is loaded with water, especially at the level of the thermal insulating material, which can be translated, in case of sudden rise in temperature, by a vaporization of this water likely to burn the operator.
  • Figures 1 and 2 show two graphs that illustrate the behavior of different complexes to make clothes for firefighters, taking into account the European standard EN 469.
  • FIG. 1 illustrates the evolution of the heat transfer factor TF%, which is the ratio of the heat flux that has passed through the product to the incident heat flux Q o .
  • the incident heat flux is the heat flux generated by a thermal source to which the sample is exposed.
  • FIG. 2 illustrates the evolution of the warning time T. 12 as a function of the incident heat flux Q o .
  • the warning time is the time after which the user painfully feels the heat. It is sought to obtain a T. 12 of about 15 seconds for an incident flux of 40 kW / m 2 .
  • the object of the invention is to provide a textile complex for clothing production, which is light and comfortable, which, under usual conditions of intervention (flow of 0 to 1 kW / m 2 approximately), transmits the heat relatively well (which corresponds to a high TF%) and quickly alerts the operator of the presence of a hazard (which corresponds to a low T. 12 ), and which, in critical conditions, such as a resulting heat flow a flash-over phenomenon (flow of the order of 40 kW / m 2 ), ensures for a sufficient period of time and in compliance with the standards, a high insulation rate (ie a low TF%), to ensure the operator a reasonable time of escape.
  • this complex must allow rapid drying when wet.
  • the textile complex concerned of the type comprising at least one fabric or textile web, made of a material non-flammable, intended to form the outer face of the complex and a lining of comfort and cleanliness intended to form the inner face of the complex, is characterized in that on the inner side of the fabric and / or on the outer face of the lining are arranged beads in textile material having substantially the same orientation, fixed by binding on the fabric and / or the lining during its manufacture, to make integral part and delimiting between the fabric and the lining of the channels filled with air.
  • the beads delimit with the lining, on the one hand, and the wall of the complex vis-à-vis the lining, on the other hand, channels that are filled with air.
  • This air is not static but can circulate, insofar as it is not trapped, by a tight mesh, as is the case for example with structures of knit type three-dimensional mesh or net.
  • the amount of air in the channels defined by the beads constitutes a sufficient thermal insulation, and meets the standard EN 469, to allow the operator to move away from the dangerous place.
  • thermoregulation of the operator's body and reduce stress and on the other hand facilitate the drying of the garment when the latter has been wet during an intervention or for maintenance.
  • absorption and storage of water of the invention are practically reduced to those of the lining supporting the beads, compared to those of a felt which acts like a sponge.
  • the beads are made of a material not very compressible under the effect of an increase of heat.
  • each bead is made from heat-stable fibers, such as para-aramid.
  • each bead is constituted by a bundle of son assembled to each other, for example two Nm 8/2 retords twisted together.
  • Such a structure is less compressible than an equivalent title thread composed of a single end.
  • each bead is attached to the liner by bonding with threads of this lining, during the manufacture thereof.
  • the thickness of each bead is greater than 0.3 mm, and preferably between 1 and 10 mm, and the spacing of the beads is greater than 2 mm, and preferably between 2 and 15 mm.
  • the beads and the channels they delimit have a general longitudinal orientation to the garment, and in particular vertical in the case of a jacket, promoting the circulation of air by a phenomenon natural convection.
  • the complex represented in the drawing comprises an outer protective fabric 2 made of a non-flammable material, consisting of a fabric reference 4781 from DMC Tissus Techniques, Twill 2/1, 195 g / m 2 , in Nomex® Delta TA from Dupont de Nemours, blend of 75% meta aramid fibers, 23% aramid fibers and 2% antistatic fibers.
  • a waterproof and breathable membrane consisting of the 89/55 company Proline, waterproof and breathable microporous membrane in flame retardant polyurethane of about 40 g / m 2 , laminated on a nonwoven Sontara ⁇ Nomex ⁇ SL Type E-89, mixture of meta and para aramid of about 90 g / m 2 .
  • the complex finally comprises a liner 4 consisting for example of a fabric reference 4948 from DMC Tissus Techniques, Canvas 120 g / m 2 , made of Nomex® / Viscose FR, a blend of 50% of meta-aramid fibers and 50% of fibers. viscose flame retardant in the mass.
  • a liner 4 consisting for example of a fabric reference 4948 from DMC Tissus Techniques, Canvas 120 g / m 2 , made of Nomex® / Viscose FR, a blend of 50% of meta-aramid fibers and 50% of fibers. viscose flame retardant in the mass.
  • a series of continuous parallel beads 5 representing a mass per unit area of 70/80 g / m 2 , in this case made of 100% Nm aramid fiber yarn. 8/2/2 (doubling of 2 ends of Nm 8/2).
  • the lining is constituted by a fabric, the connection of the beads with the fabric is obtained during weaving, by a particular evolution of certain background threads of said fabric.
  • the layers 2, 3 and 4 are generally not assembled, but simply juxtaposed. However it is quite possible that some of these layers are assembled by gluing for example, in the case of specific needs.
  • each bead is of the order of 1 mm, and the spacing of the beads is of the order of 10 mm.
  • FIG. 5 represents a jacket 6 made from the complex textile which has just been defined, and in which the beads 5 are oriented vertically.
  • FIGS. 1 and 2 illustrate the behavior of a complex I according to the invention.
  • This complex has the advantage, compared to some existing complexes, to be lighter, and more flexible, the bulges 5 advantageously replacing a felt for trapping air. These beads are lighter and more flexible than such felt or knit three-dimensional mesh.
  • the pumping and water storage capacities of the insulation complex of the invention are practically reduced to those of the lining used as support beads, which in its form embodiment as described above represents 2.5 times its weight dry.
  • the F complex using a felt, which acts like a sponge is 10 times its dry weight.
  • the lining serving as a support for the complex of the invention is converted into an exchange surface of the sweat water (which it absorbs) with the air circulating in the formed channels. by these so-called beads, accelerating evaporation and allowing the body to thermoregulate much more quickly.
  • the onset of heat stress is delayed or suppressed, especially under the usual working conditions of 0-1 kW / m 2 .
  • This low water absorption capacity of the complex according to the invention also has the advantage of limiting the risk of burns by spraying the water trapped in the jacket in the event of exposure to a brutal heat flow.
  • the volume of air maintained in the channels ensures a satisfactory thermal insulation by limiting a rapid transmission of heat under critical conditions (flow of the order of 40 kW / m 2 ).
  • the structure of this complex also ensures good sensitivity to heat under normal conditions of use, and therefore a low warning time T. 12 , due to its low surface area, as shown in FIG. Warning in normal conditions is similar to that of leather + lining complexes, recognized as being more reassuring than that of traditional textiles too insulating (curves E and F).
  • the complex according to the invention provides a good comfort at low energy, 0 to 1 kW / m 2 (usual working conditions) comparable to that of leather + lining complexes recognized as posing few problems of heat stress, which results in a relatively high TF% (good heat transfer).
  • it has high incident heat fluxes (about 40 kW / m 2 ), a TF% heat transmission factor, low (good insulation), comparable to that of much heavier complexes, less comfortable and retaining much more the water.
  • the invention is not limited to the only form execution of this textile complex or its sole application to the realization of a jacket, it embraces all the variants.
  • the lining could be made of a material other than tissue, that it could be associated with a membrane or a film, that the beads could be discontinuous and / or could be made in another material, such as silicone, or fixed by other means such as by gluing or sewing on the lining, or that the complex could two unrelated layers, such as trousers and an overpantal on the inner side of which are arranged beads, without it being beyond the scope of the invention.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Laminated Bodies (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)

Claims (11)

  1. Textilverbundmaterial zur Herstellung von Wärmeschutzkleidung mit mindestens einem Gewebe (2) oder einer Textilschicht aus nicht-entzündlichem Material zur Bildung der Außenfläche des Verbundmaterials, und einem Futter (4) zur Bequemlichkeit und Sauberkeit zur Bildung der Innenfläche des Verbundmaterials, wobei auf der Innenfläche des Gewebes und/oder auf der Außenfläche des Futters (4) Wülste (5) angeordnet sind, die im wesentlichen dieselbe Ausrichtung besitzen, die auf dem Gewebe und/oder auf dem Futter über eine Verbindung befestigt sind und zwischen dem Gewebe und dem Futter luftgefüllte Kanäle begrenzen, dadurch gekennzeichnet, dass die Wülste aus Textilmaterial bestehen und auf dem Gewebe und/oder auf dem Futter während dessen Herstellung befestigt werden, damit sie mit ihm einstückig sind.
  2. Textilverbundmaterial nach Anspruch 1, dadurch gekennzeichnet, dass die Wülste (5) fortlaufend sind.
  3. Textilverbundmaterial nach Anspruch 1, dadurch gekennzeichnet, dass die Wülste nicht-fortlaufend sind.
  4. Verbundmaterial nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass das Futter (4) auf seiner nach außen gekehrten Fläche des Verbundmaterials Wülste (5) aufweist, die im wesentlichen dieselbe Ausrichtung besitzen und mit der gegenüberliegenden Wand des Verbundmaterials luftgefüllte Kanäle begrenzen.
  5. Verbundmaterial nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die Wülste (5) aus einem Material bestehen, das unter der Einwirkung einer Wärmezunahme der Wärme wenig komprimierbar ist.
  6. Verbundmaterial nach Anspruch 5, dadurch gekennzeichnet, dass jeder Wulst (5) aus hitzebeständigen Fasern, wie z.B. aus Para-Aramid, besteht.
  7. Verbundmaterial nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass jeder Wulst (5) aus einem Bündel miteinander verbundener Fäden besteht, wie z.B. zwei miteinander verdrillter Verdrillungsfläche mit Nm 8/2.
  8. Verbundmaterial nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass jeder Wulst (5) an dem Futter während dessen Herstellung mittels einer Verbindung mit Hilfe von Fäden dieses Futters befestigt wird. ,
  9. Verbundmaterial nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die Dicke jedes Wulstes (5) größer als 0,3mm ist und vorzugsweise zwischen 1 und 10mm liegt.
  10. Verbundmaterial nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass der Abstand der Wülste (5) größer als 2mm ist und vorzugsweise zwischen 2 und 15mm liegt.
  11. Kleidungsstück, das aus einem Textilverbundmaterial nach einem der Ansprüche 1 bis 10 hergestellt ist, dadurch gekennzeichnet, dass die Wülste (5) und die von ihnen begrenzten Kanäle eine vorwiegend in der Längsrichtung des Kleidungsstücks verlaufende Ausrichtung und im Fall einer Weste insbesondere eine vertikale Ausrichtung besitzen.
EP99932966A 1998-07-23 1999-07-23 Textilverbundmaterial zur herstellung von wärmeschutzkleidungstücken Expired - Lifetime EP1098575B2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9809582 1998-07-23
FR9809582A FR2781341B1 (fr) 1998-07-23 1998-07-23 Complexe textile pour la realisation de vetements de protection thermique
PCT/FR1999/001822 WO2000004798A1 (fr) 1998-07-23 1999-07-23 Complexe textile pour la realisation de vetements de protection thermique

Publications (3)

Publication Number Publication Date
EP1098575A1 EP1098575A1 (de) 2001-05-16
EP1098575B1 true EP1098575B1 (de) 2003-05-14
EP1098575B2 EP1098575B2 (de) 2007-05-09

Family

ID=9529058

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99932966A Expired - Lifetime EP1098575B2 (de) 1998-07-23 1999-07-23 Textilverbundmaterial zur herstellung von wärmeschutzkleidungstücken

Country Status (16)

Country Link
US (1) US6481015B1 (de)
EP (1) EP1098575B2 (de)
JP (1) JP2002521576A (de)
AT (1) ATE240057T1 (de)
AU (1) AU747771B2 (de)
BR (1) BR9912340A (de)
CA (1) CA2338177C (de)
DE (1) DE69907914T3 (de)
DK (1) DK1098575T4 (de)
ES (1) ES2196833T5 (de)
FR (1) FR2781341B1 (de)
NO (1) NO20010335L (de)
NZ (1) NZ509416A (de)
PT (1) PT1098575E (de)
TR (1) TR200100215T2 (de)
WO (1) WO2000004798A1 (de)

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GB0100560D0 (en) * 2001-01-09 2001-02-21 Lamination Technologies Ltd Clothing
FR2831773B1 (fr) * 2001-11-07 2005-07-29 Kermel Materiau complexe multicouches en feuille utilisable pour la realisation de vetements de protection, notamment pour sapeurs-pompiers
US7410682B2 (en) * 2002-07-03 2008-08-12 High Voltage Graphics, Inc. Flocked stretchable design or transfer
FR2846200B1 (fr) * 2002-10-23 2005-01-14 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fils en relief
FR2846202A1 (fr) * 2002-10-23 2004-04-30 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fibres floquees
US6678895B1 (en) 2003-05-22 2004-01-20 Morning Pride Manufacturing, L.L.C. Protective garment, which is worn with shoulder pad having inflatable bladder, for firefighter or for emergency worker
US7013496B2 (en) 2003-09-05 2006-03-21 Southern Mills, Inc. Patterned thermal liner for protective garments
US20050112967A1 (en) * 2003-11-20 2005-05-26 Grilliot William L. Bladder made from flame-resistant fabric and from fluid-impervious film
US20060026743A1 (en) * 2004-08-06 2006-02-09 Brian Farnworth Gas distribution garment
US7716940B2 (en) * 2004-08-06 2010-05-18 Gore Enterprise Holdings, Inc. Gas distribution garment having a spacer element
US20080102239A1 (en) 2005-07-28 2008-05-01 High Voltage Graphics, Inc. End of roll paper sensing and system management
US20070130667A1 (en) * 2005-12-14 2007-06-14 Marie Gagnon Thermal insulation padding for protective garment
ES2496966T3 (es) * 2005-12-16 2014-09-22 Southern Mills, Inc. Prendas protectoras que proporcionan protección térmica
US7546853B2 (en) * 2006-05-30 2009-06-16 Mmi-Ipco, Llc Advanced engineered garment
ES2327883B1 (es) * 2006-07-18 2010-09-06 Tejidos Estambril, S.A. Tejido de proteccion termica.
US8475905B2 (en) 2007-02-14 2013-07-02 High Voltage Graphics, Inc Sublimation dye printed textile
JP5274186B2 (ja) * 2008-09-30 2013-08-28 セーレン株式会社 耐噴出水蒸気防護服用複合材料
US8176569B2 (en) * 2009-06-24 2012-05-15 Mmi-Ipco, Llc Advanced engineered garment
US8793814B1 (en) 2010-02-09 2014-08-05 International Textile Group, Inc. Flame resistant fabric made from a fiber blend
US20170199011A1 (en) 2010-06-15 2017-07-13 Tyr Tactical, Llc Personal tactical system
ITBO20110638A1 (it) * 2011-11-08 2013-05-09 Angelo Fabrizio Bianchi Capo d'abbigliamento traspirante
CN104837645A (zh) 2012-10-12 2015-08-12 高压制图公司 柔性可热封装饰性制品及其制造方法
BE1021005B1 (nl) * 2012-12-19 2014-12-11 Amitexcon Bvba Multilagensysteem van textielmaterialen voor beschermende kledij voor brandbestrijding.
NO3042030T3 (de) * 2013-09-26 2018-05-26
CA3011354A1 (en) * 2016-01-14 2017-07-20 Southern Mills, Inc. Improved flame resistant thermal liners and garments made with same
WO2017184378A1 (en) * 2016-04-21 2017-10-26 Avent, Inc. Multi-layered structure and articles formed therefrom having improved splash resistance by increased interlayer spacing
US20210352969A1 (en) * 2018-09-07 2021-11-18 Fortiac Corporation Dba Téchin New York Soft Fabric Garment Having Stiff Fabric Structural Elements

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Also Published As

Publication number Publication date
PT1098575E (pt) 2003-07-31
ATE240057T1 (de) 2003-05-15
BR9912340A (pt) 2001-04-17
ES2196833T5 (es) 2007-11-16
DE69907914T2 (de) 2004-01-15
DK1098575T4 (da) 2007-06-11
JP2002521576A (ja) 2002-07-16
AU747771B2 (en) 2002-05-23
AU4916599A (en) 2000-02-14
DK1098575T3 (da) 2003-09-15
DE69907914T3 (de) 2007-08-30
EP1098575B2 (de) 2007-05-09
CA2338177C (fr) 2008-12-16
FR2781341B1 (fr) 2000-10-20
US6481015B1 (en) 2002-11-19
NZ509416A (en) 2003-10-31
NO20010335D0 (no) 2001-01-19
FR2781341A1 (fr) 2000-01-28
TR200100215T2 (tr) 2001-06-21
EP1098575A1 (de) 2001-05-16
WO2000004798A1 (fr) 2000-02-03
CA2338177A1 (fr) 2000-02-03
DE69907914D1 (de) 2003-06-18
ES2196833T3 (es) 2003-12-16
NO20010335L (no) 2001-03-19

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