EP1063338A2 - Procédé et dispositif pour la teinture d'un substrat textile dans au moins un fluide supercritique - Google Patents
Procédé et dispositif pour la teinture d'un substrat textile dans au moins un fluide supercritique Download PDFInfo
- Publication number
- EP1063338A2 EP1063338A2 EP00109392A EP00109392A EP1063338A2 EP 1063338 A2 EP1063338 A2 EP 1063338A2 EP 00109392 A EP00109392 A EP 00109392A EP 00109392 A EP00109392 A EP 00109392A EP 1063338 A2 EP1063338 A2 EP 1063338A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- dye
- supercritical fluid
- dyestuff
- supercritical
- fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 105
- 238000000034 method Methods 0.000 title claims abstract description 44
- 238000004043 dyeing Methods 0.000 title claims abstract description 33
- 239000004753 textile Substances 0.000 title claims abstract description 15
- 239000000758 substrate Substances 0.000 title claims abstract description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 7
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 7
- 238000004040 coloring Methods 0.000 claims description 11
- 239000011148 porous material Substances 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 238000007789 sealing Methods 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000003780 insertion Methods 0.000 claims 1
- 230000037431 insertion Effects 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 141
- 239000000463 material Substances 0.000 abstract description 3
- 230000003134 recirculating effect Effects 0.000 abstract 1
- 239000000986 disperse dye Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000003973 paint Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- 238000006073 displacement reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000009958 sewing Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- FIKFLLIUPUVONI-UHFFFAOYSA-N 8-(2-phenylethyl)-1-oxa-3,8-diazaspiro[4.5]decan-2-one;hydrochloride Chemical compound Cl.O1C(=O)NCC11CCN(CCC=2C=CC=CC=2)CC1 FIKFLLIUPUVONI-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/94—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in solvents which are in the supercritical state
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
- D06B23/205—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation for adding or mixing constituents of the treating material
Definitions
- the present invention relates to a method for dyeing a textile substrate in at least one supercritical Fluid, preferably for dyeing yarn packages in the supercritical Carbon dioxide, with the features of the preamble of the claim 1 and a dyeing device with the features of Preamble of claim 6.
- DE 196 31 604 A proposes a contribution the dye required for dyeing in supercritical fluids submitted, the relevant contribution of the to be dissolved or dispersed in the corresponding dye supercritical fluid takes place in that with the Dye to be loaded into a supercritical fluid in a bypass arranged and filled with the total amount of the dye flows through a special paint container.
- the object of the present invention is a method of the specified type and a corresponding device to make available, even with such dyes, that tend to cake or sinter together, a quick and particularly easy introduction of the respective Allows dye in the supercritical fluid.
- the method according to the invention for dyeing a textile substrate in at least one supercritical fluid provides, like the known method, that the respective arranges textile substrate in an autoclave and there with the at least one supercritical fluid containing dye flows towards or through.
- the at least one fixed, preferably powdery, dye with the supercritical Fluid to form a stable solution and / or dispersion of the dye in the supercritical fluid.
- the invention Process compared to the prior art more complex appears because in the method according to the invention amount of dye to be dissolved or dispersed to a variety of dye subsets divided and separately one after the other has been introduced into the supercritical fluid
- the inventive method in particular for critical, for clumping or for sintering together tending dyes, compared to the previously practiced Dyeing process does not require an increased amount of time.
- the inventive Processes relatively small amounts of dye a relative large amount of supercritical fluid is offered, so that accordingly the dissolving or dispersing process of the dye in the supercritical fluid accelerates without a clumping or sintering together of the related Partial dye amount could be observed.
- the method according to the invention is also capable of adding Inert particles or on the creation of a specific dye granulate size to do without, as is the case with critical dyes is the case with the known method.
- the composition of the dye subset can be varied so that by using the the method according to the invention a shading of the coloring at any time is possible, which is also not the case in the prior art given is.
- the inventive Process preferably the entry of the dye subset in the main flow of the pumped supercritical fluid takes place, the dissolving or dispersing process of each is introduced Dye subset accelerated significantly, which in particular is not the case in the prior art if that Paint preparation vessel is arranged in a bypass to the main stream.
- the one used in the method according to the invention also calls Dye subset compared to the conventionally used Total amount of dye does not produce any significant counterpressure, so that in the process according to the invention this partial dye amount can be flowed through much better, which in turn a considerable acceleration of the dissolving or dispersing behavior of the dye used in the supercritical Fluid causes.
- the term also covers supercritical fluid especially the fluids that are in DE 39 06 724 A are described, but with the invention Supercritical carbon dioxide method preferred is used.
- the method according to the invention preferably relates to also such a method in which yarn packages, in particular Sewing thread spools, in supercritical carbon dioxide with disperse dye be colored, the used for this Disperse dyes, in particular commercially available disperse dyes are like these widely used in trade and for the aqueous dyeing of polyester yarn spools are offered. That which is preferably used in the method according to the invention
- Yarn material comprises or consists in particular of polyester, including the modified polyester types also preferably fall polyethylene terephthalate yarn materials.
- a first embodiment of the method according to the invention stipulates that one needs the necessary for the coloring Dye amount to 5 to 200, especially 20 to 90, dye portions divides, which has surprisingly shown that such a division into the aforementioned dye subsets for a large number of dyes or dye mixtures and over a wide range of hues and depths of color leads to excellent results, especially in that that the total amount of dye required within dissolved or dispersed in the supercritical fluid in a very short time without lumps or mergers occurring, and that particularly level and genuine colors result.
- each dye subset in the stream of supercritical Fluid brings in that the supercritical circulated per unit of time Total fluid with the dye subset at least once such a method variant brings into contact that the entire dye dissolves particularly quickly and that for dyeing the textile substrate a supercritical Dyeing liquor is used, which is always the same Has concentration of dissolved or dispersed dye, so that such a supercritical dyeing liquor always contains a maximum of dissolved or dispersed dye.
- the present invention further relates to a device for introducing a dye into a for dyeing a textile Substrate used supercritical fluid with the characteristics of claim 6.
- the device according to the invention with which the entry of a Dye in portions in a for dyeing a textile substrate supercritical fluid used is enabled assigned an autoclave provided with a fluid circulation system, the fleet circulation system being a feed pump includes.
- the device according to the invention has a Dye application device between a first Position in which at least one dye receiving section of the Dye application device is freely accessible, and one second position, in which the at least one dye receiving section in contact with the supercritical fluid is located, and vice versa, is movable.
- Dye applicator sure that by one movement the dye application device from a first position, in which the at least one dye receiving section with the Part of the dye is freely accessible, in which second position, in which the loaded with the dye subset Dye receiving section in contact with the supercritical Fluid is brought, the corresponding dye subset is fed into the supercritical fluid without it the temperature and / or the pressure is required for this to change the supercritical fluid.
- the device according to the invention has a number of advantages on. So it should first be noted that with the help of the invention Device anytime and in any Amount of dye can be entered into the system without it is necessary for this, the temperature and / or the pressure to change the supercritical fluid. Furthermore, the device according to the invention the dye dosage described above, without increasing the volume of the system occurs, which is not the case in the prior art, if a corresponding color approach vessel is arranged in a bypass is.
- the invention allows Device in a particularly simple manner, a quick dosage of the dye, without corresponding fluctuations in the pressure and / or the temperature of the supercritical fluid occur, so that the device according to the invention is also essential contributes to the reproducibility of dyeings.
- the invention Device a simple and individual adjustment of each used amount of dye allows so that depending from a determined color loss, the coloration is interrupted, further Dye added or by adding others Dyes the coloring created up to now are nuanced can, without it being necessary for this, a paint preparation vessel and shut off the associated bypass lines, ventilate them and pressurize again, as with the State of the art is always the case. Therefore, the invention Device significantly contributes to the total staining times to shorten the reproducibility accordingly to improve the coloring and to avoid misstaining, whereby the application of the device according to the invention is crucial also influences the economy of the dyeing process.
- the device in a first embodiment of the device according to the invention is the dye delivery device as transverse to the flow direction of the supercritical fluid slidable rod formed, the rod at least one, as an annular Groove and / or dye receiving portion configured as a through hole having.
- Such has preferably a rod-shaped Dye application device then two, with an axial distance grooves or through openings arranged from one another, the axial distance between these two grooves or through holes is chosen so that a groove or a through hole freely accessible from the outside and thus with the partial dye amount can be loaded (first position), while the other groove or through hole at this time in the supercritical Fluid is positioned (second position). Details about this preferred embodiment will be discussed below the specific embodiments explained.
- the device according to the invention has a housing, preferably a cylindrical housing, the cylindrical Housing with a connection area for feeding the supercritical Fluids and with a discharge area for discharge of the supercritical fluid loaded with dye.
- the rod-shaped described above is inside the housing Dye application device provided, which preferably transverse to the direction of flow of the supercritical fluid in the housing as an axially displaceable rod with grooves arranged therein and / or through holes is configured.
- the device of the invention has the housing opposite closures, in particular the opposite Closures bearing and sealing elements for fluid-tight axial slidable mounting of the rod have designed dye introduction devices.
- the at least one through hole head and / or Assignable sieve plates on the foot side are the at least one through hole head and / or Assignable sieve plates on the foot side. This will prevents from the through hole by means of the supercritical Fluids coarse disperse dye particles washed out that are undesirable on the color to be colored knock down textile substrate and there corresponding errors cause.
- the laxation area to discharge the supercritical loaded with dye Fluids assigned a corresponding sieve plate in this way be that the fluid loaded with dye before leaving the Housing must flow through this sieve plate, so that this also corresponding coarsely disperse dye particles in the supercritical fluid loaded with dye can be avoided.
- the sieve plate is designed as a sintered metal plate, its pores a pore size smaller than or equal to 30 ⁇ m, preferably smaller or equal to 15 ⁇ m, so that this sieve plate is effective the formation of coarsely disperse dye particles in the Avoid supercritical fluid.
- the dye application device as rotatable disc, this disc on its outer Edge at least one dye receiving section, preferably at its outer edge over its radial circumference evenly distributed at least two dye absorption sections, having.
- this disc which has at least two dye-receiving sections these arranged in such a way that there is always at least one Dye receiving section in the first position and the at least another dye-receiving section in the second Position, so that by rotating the disc at least one dye-receiving section from the first one in the second position and the at least one other dye receiving section simultaneously from the second to the first Position can be brought.
- the Dye absorption section with the dye subset to be entered in each case be loaded while in the second position, which is brought about by rotation of the disk, the related dye receiving section in contact with the Supercritical fluid is located, so that the dye subset can thereby be dissolved or finely dispersed.
- a special, particularly suitable and quick dosing of the dye enabling embodiment of the previously described Design of the device according to the invention provides for a disk that is four to eight in circumference Area of its outer edge evenly distributed dye-receiving sections has, so that in this embodiment always two to four dye receiving sections in the first Position accordingly two to four Dye receiving sections are in the second position.
- the dye receiving sections as through holes are designed, which are preferably in Main direction of flow of the supercritical fluid.
- the supercritical fluid is capable of being in the second position to flow through these through bores and the one arranged therein to quickly dissolve or finely disperse partial dye, whereby the dye entry in this embodiment accelerated accordingly the device according to the invention becomes.
- an advantageous further development provides the previously described embodiment of the invention Device before that the through holes Can be closed at the top and / or bottom with a sintered metal plate are whose pores are a pore size smaller or equal to 30 ⁇ m, preferably less than or equal to 15 ⁇ m. This prevents coarsely dispersed parts in the Fluid flow arrive, which, as already mentioned, false colorations cause, in addition to the arrangement of the sintered metal plates at the through holes or instead of Arrangement of the sintered metal plates on the through holes also the discharge area for the discharge of the dye-laden supercritical fluid a corresponding sintered metal plate can be assigned through which the loaded with dye supercritical fluid then discharged and the staining autoclave is fed.
- this dye feeder a predetermined Dye subset of each dye receiving section feeds.
- a dyeing plant is shown schematically in FIG the dyeing system has a dyeing autoclave 1 in which, for example a column consisting of four packages one Sewing thread, arranged for dyeing.
- the dyeing autoclave 1 has a first circulation system provided, the first circulation system having a corresponding Pipe system 2 includes.
- a circulation pump 3 arranged, further comprising the first circulation system Not shown heat exchanger and a feed for the supercritical fluid is assigned.
- Downstream of the circulation pump 3 is a device A for in the piping system 2 Entry of a dye provided in subsets, wherein this device is shown in detail in FIG.
- the system shown schematically in FIG. 1 has a second circulation system, which is designated as a whole by 11.
- This second circulation system 11, which is also referred to as the adsorption circuit, comprises three valves 9, 10 and 13 and an autoclave 12, the autoclave 12 being filled with a suitable sorbent, for example a silica gel, type Trysil.
- a suitable sorbent for example a silica gel, type Trysil.
- This silica gel has a particle size preferably between 2 mm and 8 mm, a density in particular of 2,200 kg / m 3 , a bulk density of 550 kg / m 3 , a porosity of 0.55, an inner surface area of about 450 m 2 / g, a pore volume of 0.4 cm 3 / g, an average pore diameter between 4 nm and 10 nm and a tortuosity factor of 5.0.
- the system shown above works as follows: First, the column of, for example, four sewing thread X bobbins made of polyethylene terephthalate is arranged within the autoclave 1. After the autoclave 1 has been closed, the corresponding piping system 2 of the first circulation system and the autoclave 1 itself are filled with supercritical fluid, in particular carbon dioxide, via the feed (not shown) and a pressure booster pump (not shown). Thereafter, the circulation pump 3 is put into operation, which leads to the supercritical fluid flowing through the piping system 2 and the autoclave 1 in the direction of the arrow. At this time, valves 9 and 10 are closed and valve 13 is open.
- supercritical fluid in particular carbon dioxide
- the device A shown schematically in detail in FIG. 2 for the introduction of a dye in partial amounts has a lateral Slidable, as a rod 1 dye-feeding device on, the rod 1 two dye receiving sections 2 owns.
- these dye-receiving sections 2 designed as through holes, both a sintered metal plate on the top and bottom (not shown) can be provided at each through hole 2.
- the rod 1 is provided centrally within a housing 3, the housing 3 has a connection area 10 for feeding of supercritical fluids and a discharge area 11 for Discharge of the supercritical fluid loaded with dye having.
- the flow direction of the supercritical fluid in the Housing 3 is identified by corresponding arrows.
- On Both sides is the housing 3 with a lid 5, which is sealed Flange cover is formed, closed, wherein to seal the cover 5 to the housing 3 in particular known double cone ring 12 is provided.
- Corresponding bearing and sealing elements are assigned to each cover 5, these bearing and sealing elements each one in the flange cover screwed sleeve 6 includes, in the conical Area a circumferential seal 7 is added.
- the internal sealing against the axially sliding rod 1 takes place via a self-sealing with a sealing cover 8 Pack or alternatively via a spring ring seal 9, as in the rest of the field of technology are common.
- the sleeve 6 is also a pressure relief hole 13 assigned to the atmosphere, so that the after emptying the through hole 2, the one taken in here supercritical fluid with an axial displacement of the Rod 1 through this relief bore 13 to the atmosphere can escape.
- the sleeve 6 is also a dye feeder 4 assigned, this dye feeder 4 in the embodiment shown from a funnel consists.
- Rod 1 with the two through holes arranged therein 2 can assume such a position as that in FIG. 2 is shown.
- the right passage hole is located here 2 in a first position in which the right passage hole 2 with a powdery dye portion can be filled via the funnel 4 while the left Through hole 2 is in its second position in the the dye subset arranged here from the on, through or passing supercritical fluid dissolved or fine is dispersed. After that in the left through hole 2 part of the dye present was dissolved or dispersed, the rod 1 is shifted to the left until the left Through hole 2 is aligned with the funnel 4.
- connection area 10 and the discharge area 11 corresponding sintered metals assigned as described above.
- fluid guide elements can be provided through which Flow of the supercritical fluid in the housing 3 accordingly is changed so as to dissolve or finely disperse the Accelerate partial dye quantity from the through hole.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment Of Fiber Materials (AREA)
- Coloring (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19928405A DE19928405A1 (de) | 1999-06-22 | 1999-06-22 | Verfahren zum Färben eines textilen Substrates in mindestens einem überkritischen Fluid sowie Färbevorrichtung |
DE19928405 | 1999-06-22 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1063338A2 true EP1063338A2 (fr) | 2000-12-27 |
EP1063338A3 EP1063338A3 (fr) | 2001-10-10 |
EP1063338B1 EP1063338B1 (fr) | 2002-07-31 |
Family
ID=7912040
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00109392A Expired - Lifetime EP1063338B1 (fr) | 1999-06-22 | 2000-05-03 | Procédé et dispositif pour la teinture d'un substrat textile dans au moins un fluide supercritique |
Country Status (5)
Country | Link |
---|---|
US (1) | US6796151B1 (fr) |
EP (1) | EP1063338B1 (fr) |
AT (1) | ATE221588T1 (fr) |
DE (2) | DE19928405A1 (fr) |
ES (1) | ES2179800T3 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1164214A2 (fr) * | 2000-06-16 | 2001-12-19 | Gütermann AG | Procédé et dispositif pour la teinture des matières textiles |
CN104178948A (zh) * | 2014-08-20 | 2014-12-03 | 山东大学 | 超临界流体喷染纱线用喷射器 |
CN108425196A (zh) * | 2017-12-26 | 2018-08-21 | 晋江市隆盛针织印染有限公司 | 分散染料或/和阳离子染料浸染续缸染色后处理深度节水工艺 |
CN113790031A (zh) * | 2021-09-18 | 2021-12-14 | 河南理工大学 | 一种突出煤层边角供流盾护卸压筛孔弧棱钻杆 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004013338A1 (de) * | 2004-03-17 | 2005-10-06 | Uhde High Pressure Technologies Gmbh | Verfahren zur Suspendierung und Einspeisung von Feststoffen in einen Hochdruckprozeß |
CN100359092C (zh) * | 2005-12-26 | 2008-01-02 | 大连轻工业学院 | 超临界二氧化碳染色装置中的染色釜 |
CN100467701C (zh) * | 2007-06-25 | 2009-03-11 | 山东大学 | 超临界流体连续染纱器 |
CN100510227C (zh) * | 2007-07-02 | 2009-07-08 | 青岛国邦工业科技发展有限公司 | 超临界流体染布器 |
KR102154932B1 (ko) * | 2019-06-26 | 2020-09-10 | 서울대학교산학협력단 | 염색 장치 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19631604A1 (de) * | 1995-10-17 | 1997-04-24 | Amann & Soehne | Verfahren zum Färben eines textilen Substrates in mindestens einem überkritischen Fluid |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH390854A (de) * | 1960-07-19 | 1965-04-30 | Thies Kg Spezialmaschinenfabri | Vorrichtung zum Färben von Textilien |
PL181383B1 (pl) * | 1995-10-16 | 2001-07-31 | Krupp Uhde Gmbh | Sposób farbowania podlozy tekstylnych, zwlaszcza konfekcjonowanych w postaci nawojów przedzy lub zwijek pasm materialu, za pomoca plynunadkrytycznego PL PL PL PL PL |
-
1999
- 1999-06-22 DE DE19928405A patent/DE19928405A1/de not_active Ceased
-
2000
- 2000-05-03 ES ES00109392T patent/ES2179800T3/es not_active Expired - Lifetime
- 2000-05-03 EP EP00109392A patent/EP1063338B1/fr not_active Expired - Lifetime
- 2000-05-03 DE DE50000329T patent/DE50000329D1/de not_active Expired - Fee Related
- 2000-05-03 AT AT00109392T patent/ATE221588T1/de not_active IP Right Cessation
- 2000-06-22 US US09/599,664 patent/US6796151B1/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19631604A1 (de) * | 1995-10-17 | 1997-04-24 | Amann & Soehne | Verfahren zum Färben eines textilen Substrates in mindestens einem überkritischen Fluid |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1164214A2 (fr) * | 2000-06-16 | 2001-12-19 | Gütermann AG | Procédé et dispositif pour la teinture des matières textiles |
EP1164214A3 (fr) * | 2000-06-16 | 2002-07-17 | Gütermann AG | Procédé et dispositif pour la teinture des matières textiles |
CN104178948A (zh) * | 2014-08-20 | 2014-12-03 | 山东大学 | 超临界流体喷染纱线用喷射器 |
CN104178948B (zh) * | 2014-08-20 | 2016-01-13 | 山东大学 | 超临界流体喷染纱线用喷射器 |
CN108425196A (zh) * | 2017-12-26 | 2018-08-21 | 晋江市隆盛针织印染有限公司 | 分散染料或/和阳离子染料浸染续缸染色后处理深度节水工艺 |
CN113790031A (zh) * | 2021-09-18 | 2021-12-14 | 河南理工大学 | 一种突出煤层边角供流盾护卸压筛孔弧棱钻杆 |
CN113790031B (zh) * | 2021-09-18 | 2024-04-19 | 河南理工大学 | 一种突出煤层边角供流盾护卸压筛孔弧棱钻杆 |
Also Published As
Publication number | Publication date |
---|---|
ES2179800T3 (es) | 2003-02-01 |
EP1063338A3 (fr) | 2001-10-10 |
EP1063338B1 (fr) | 2002-07-31 |
DE19928405A1 (de) | 2000-12-28 |
DE50000329D1 (de) | 2002-09-05 |
ATE221588T1 (de) | 2002-08-15 |
US6796151B1 (en) | 2004-09-28 |
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