EP1056691A1 - Method and plant for the treatment of liquid organic waste - Google Patents
Method and plant for the treatment of liquid organic wasteInfo
- Publication number
- EP1056691A1 EP1056691A1 EP98902971A EP98902971A EP1056691A1 EP 1056691 A1 EP1056691 A1 EP 1056691A1 EP 98902971 A EP98902971 A EP 98902971A EP 98902971 A EP98902971 A EP 98902971A EP 1056691 A1 EP1056691 A1 EP 1056691A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquid
- biogas
- reactor
- fraction
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 114
- 238000000034 method Methods 0.000 title claims abstract description 51
- 238000011282 treatment Methods 0.000 title claims abstract description 43
- 239000010815 organic waste Substances 0.000 title claims abstract description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 141
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 70
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000012466 permeate Substances 0.000 claims abstract description 63
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 52
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 42
- 210000003608 fece Anatomy 0.000 claims abstract description 34
- 239000010871 livestock manure Substances 0.000 claims abstract description 34
- 150000003839 salts Chemical class 0.000 claims abstract description 33
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 32
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 32
- 239000012141 concentrate Substances 0.000 claims abstract description 25
- 235000015097 nutrients Nutrition 0.000 claims abstract description 25
- 238000000855 fermentation Methods 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 19
- 239000003337 fertilizer Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000002829 reductive effect Effects 0.000 claims abstract description 13
- 244000144972 livestock Species 0.000 claims abstract description 11
- 239000012223 aqueous fraction Substances 0.000 claims abstract description 9
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 9
- 239000012528 membrane Substances 0.000 claims description 31
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 241000894006 Bacteria Species 0.000 claims description 14
- 239000005416 organic matter Substances 0.000 claims description 13
- 230000004151 fermentation Effects 0.000 claims description 12
- 239000010808 liquid waste Substances 0.000 claims description 10
- 238000000926 separation method Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 230000000717 retained effect Effects 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000003546 flue gas Substances 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 235000008504 concentrate Nutrition 0.000 claims 4
- 238000012544 monitoring process Methods 0.000 claims 2
- 239000010791 domestic waste Substances 0.000 claims 1
- 239000002361 compost Substances 0.000 abstract description 6
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 6
- 229910052700 potassium Inorganic materials 0.000 abstract description 6
- 238000001914 filtration Methods 0.000 abstract description 5
- 239000007795 chemical reaction product Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 description 15
- 239000010865 sewage Substances 0.000 description 10
- 239000002699 waste material Substances 0.000 description 9
- 239000000306 component Substances 0.000 description 7
- 238000002203 pretreatment Methods 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 241000282887 Suidae Species 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical class [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000011236 particulate material Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000011591 potassium Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- -1 fertilisers Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000011146 organic particle Substances 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000009295 crossflow filtration Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004931 filters and membranes Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
- C05F3/06—Apparatus for the manufacture
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
- C02F3/2853—Anaerobic digestion processes using anaerobic membrane bioreactors
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/40—Treatment of liquids or slurries
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/90—Apparatus therefor
- C05F17/989—Flow sheets for biological or biochemical treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Definitions
- the present invention relates to a method and a plant for the treatment of organic waste materials in liquid form such as liquid manure from livestock production or sewage.
- Danish utility model No. DK 95 00113 U3 describes a plant for the treatment of liquid manure, in which the manure is converted to compost, fertilisers, water and biogas.
- the plant comprises 1) a filtration unit for separating fibrous and particulate material having a size of over 1 mm from the liquid and particles less than 1 mm, the fibrous material being e.g.
- a reactor for the production of biogas 2) a reactor for the production of biogas, 3) an ultraflltration unit that retains bacteria and suspended organic material and returns such material to the biogas reactor, 4) a desulphurisation unit that removes hydrogen sulphide from the biogas before the biogas is used for the production of heat and power, 5) a reverse osmosis unit, in which the permeate stream from the ultrafilter is 2 separated into a water fraction and a fertiliser concentrate fraction.
- BIOREK® A separation plant for liquid manure referred to as BIOREK® is known from Bioscan A/S (Odense, Denmark) .
- the BIOREK® plant is based on the plant described in DK 95 00113 U3 and further contains, between the ultraflltration unit and the reverse osmosis unit, an ammonia stripper for the removal of ammonia and carbon dioxide from the permeate stream from the ultrafliter.
- the BIO- REK® plant is described e.g. m a brochure, published 10/97, from Bioscan A/S entitled "BIOREK® separation plant for liquid manure, Sandager Skovgaard'X
- the present invention represents a further development of the technology known from DK 95 00113 U3 and from the BIOREK ⁇ plant, allowing surprisingly advantageous results to be obtained in the treatment of liquid manure and other liquid organic waste materials .
- One aspect of the present invention relates to a method for the treatment of an organic waste material in liquid form, comprising subjecting the liquid to anaerobic fermentation in a biogas reac- tor, separating a substantially sterile and particle-free permeate stream from the biogas reactor, subjecting the permeate stream to treatment with an ammonia stripper to result in an ammonia fraction and a nutrient salt fraction, and separating the nutrient salt fraction into a fertiliser concentrate fraction and a water fraction, wherein treatment of the permeate stream with the ammonia stripper is performed at an elevated temperature.
- Another aspect of the invention relates to a plant for treatment of an organic waste material in liquid form, comprising a biogas reactor, means for separating a substantially sterile and particle-free permeate stream from liquid in the biogas reactor, an ammonia stripper for separating the permeate stream into an ammonia fraction and a nutrient salt fraction, and means for separating the nutrient salt fraction into a fertiliser concentrate and a water fraction, wherein the ammonia stripper includes a heating means for heating the permeate stream.
- a further aspect of the invention relates to a method for produc- ing biogas enriched in methane, the method comprising subjecting an organic waste material in liquid form to anaerobic fermenta ⁇ tion in a biogas reactor, wherein liquid from the biogas reactor is subjected to ultrafiltration to result in a permeate fraction enriched in carbon dioxide and a methane-enriched fraction, said methane-enriched fraction being returned to the biogas reactor to result in biogas having an increased methane content.
- a still further aspect of the invention relates to methane- enriched biogas produced by this method.
- the method and plant of the invention are suitable for treatment of any aqueous organic waste material, including waste water from households, industry or agriculture, including sewage from institutions such as hospitals, as well as liquid manure from livestock production.
- the invention is particularly suitable for treating the liquid manure that results from intensive livestock production, e.g. intensive production of pigs.
- intensive livestock production e.g. intensive production of pigs.
- reference will often be made for the sake of simplicity to liquid manure. It will be clear to persons skilled in the art, however, that the method and plant of the invention are equally applicable to other types of liquid organic waste material.
- the liquid waste material to be treated in accordance with the present invention e.g. liquid manure
- the liquid waste material is therefore typically filtered to remove larger fibres and particles, optionally after having been treated with a macerator, whereby material with a particle size of more than about 1 mm is removed.
- the filter mass comprising the fibres and particles that have been filtered off can then be pressed to remove excess liquid, and this liquid, together with the liquid fraction from the filtration process (containing particles of e.g. less than about 1 mm) can then be combined and subjected to anaerobic fermentation in the biogas reactor.
- the liquid resulting from the filter pre-treatment is not added directly to the biogas reactor, but rather to a buffer tank.
- the buffer tank also serves to allow particles such as sand particles, which are unde- sired in the subsequent treatment process, to sediment, while suspended organic particles are led, together with the liqui ⁇ , to the biogas reactor.
- liquid manure or other liquid waste material is led to the biogas reactor, in which anaerobic fermentation takes place.
- the residence time in the biogas reactor will vary depending on such factors as the nature of the waste material, the organic matter content, the bacteria mix present and the temperature of the liquid, it has been found that for liquid manure from pigs, a residence time of about 1-7 days, e.g. about 3-6 days, such as about 3-4 days, is generally suitable.
- the liquid to be treated is typically pumped into the reac- tor via an inlet in the lower part of the reactor, and an outlet is typically located slightly below the liquid surface.
- the bottom of the reactor vessel is preferably conical, thereby allowing any sedimented particles or sludge to be removed as necessary via an outlet at the bottom.
- the level of liquid in the reactor may be regulated e.g. by means of a pressure gauge at or near the bottom of the reactor vessel, the pressure gauge being functionally connected to a valve, e.g. placed downstream of the ultra- filtration unit, that automatically allows permeate to be re- turned to the reactor vessel as necessary in order to maintain a desired level of liquid in the reactor.
- the reactor will be designed so as to automatically provide a suitable flow of liquid within the reactor, thus providing sufficient mixing of the contents. Typically, this will take place as a result of the liquid inlet being at the bottom of the tank, while the liquid outlet is near the upper surface of the liquid.
- the tank itself is preferably designed, taking into consideration Stoke' s law, to result in a flow that allows heavier particles, in particular inorganic particles such as clay particles, to sediment, while lighter particles, in particular particles of organic matter, remain suspended.
- the temperature in the reaction vessel can be varied as desired, but will typically be suitable for mesophilic bacteria, e.g. in the range of about 20-40°C, e.g. about 30-40°C. In many cases, a temperature of about 35-37°C will be most advantageous. If appro- priate, depending on the type of bacteria present, the use of higher or lower fermentation temperatures is of course possible. For most purposes, including the treatment of liquid manure, the bacteria responsible for the anaerobic fermentation will simply be those bacteria that are naturally present in the liquid waste in question. However, it is also contemplated that it may in some cases be advantageous to supplement the native bacteria by adding one or more desired bacteria cultures to the biogas reactor or to the liquid.
- the biogas reactor be designed to have a suitable size for the intended type and amount of liquid waste to be treated. Aside from the fact that this results in optimal fermentation, it is also important that organic components in the reactor are degraded sufficiently to avoid fouling of the ultrafliter with protein or fat.
- the organic load in the biogas reactor is thus preferably below about 10 kg volatile solids per cubic meter per day, e.g. not more than about 8 kg vola- tile solids per cubic meter per day, preferably not more than about 5 kg volatile solids per cubic meter per day.
- the load in the reactor (kg VS/mVd, determined according to DS 207:1985 as loss on ignition at 550°C for 1 hour) may be greater.
- a load of about up to about 20 kg VS/m /d will be suitable when treating distillery waste, because the content of sugar and alcohol in such waste enhances the fermentation process .
- Biogas produced by the fermentation is removed from the reactor via an outlet at or near the top of the reactor vessel.
- the gas typically after having been mixed with air, is subjected to a desulphurisation process to remove the hydrogen sulphide.
- the desulphurisation process may be performed using known methods, e.g. using ochre ore filters, iron filing filters, iron hydroxide filters, bark filters or the Sulphinf" wash process.
- the resulting biogas contains predominately methane and some carbon dioxide, and only very small amounts of other gasses, and is therefore highly suitable for use in e.g. gas motors or gen- erators for the production of heat and/or power. This is explained in more detail below in connection with the discussion of the ultraflltration step.
- a substantially sterile and particle-free permeate is separated out of the liquid in the biogas reactor, preferably by means of a membrane separation technique, in particular by means of ultraflltration.
- the fraction retained by the ultrafilter, containing bacteria and suspended organic material is returned to the biogas reactor, e.g. by being added to untreated waste liquid being pumped to the reaction vessel from the buffer tank.
- an improved degradation of the organic components is obtained, as well as an enhanced fermentation, since bacteria which are active in the fermentation process are returned to the reactor.
- permeate exiting the ultraflltration unit can in addition be used to help regulate the liquid level in the reactor vessel.
- the capacity of the ultraflltration unit is larger than that which is strictly necessary with regard to the daily flow of liquid into the reactor and the corresponding flow of permeate exiting the ultrafilter for further treatment.
- the flow of liquid into the reactor vessel can thus be regulated by means of a combination of 1) liquid with a high organic matter content entering from the buffer tank, combined with a certain amount of liquid being returned from the ultraflltration unit to the reactor, and 2) permeate from the ultraflltration unit. This allows both the volume of liquid in the reactor and the organic matter content in the liquid to be "fine-tuned", so that the anaerobic fermentation process can be optimised to any given set of conditions .
- ultraflltration is performed using a tubular ultraflltration membrane.
- the membrane typically has a cut-off of about 10,000-30,000 Dalton, preferably about 15,000-25,000 Dalton, e.g. about 20,000 Dalton, and a diameter of about 5-30 mm, e.g. about 5-25 mm, e.g. about 8-20 mm, such as about 10-15 mm.
- a non-limiting example of such a tubular ultraflltration membrane system is as follows :
- the ultrafilter is composed of a number of modules of equal size, the number of modules in a given system being determined accord- ing to the size of the treatment plant.
- Each module consists of a 19 meter long tube with an inner diameter of 12.5 mm.
- the tube is bent in such a fashion that it fits into an a shell cf aluminium, having a length of 3 meters, encapsulating the membrane tube and sealed at each end by a watertight epoxy seal.
- the ultrafilter membrane is fixed to the inner side of the tube and is of the asymmetric, polysulphone, cross-flow type with a mean molecular weight cut-off of 20,000 Dalton, meaning that only molecules with a mean molecular weight of less than about 20,000 amu (atomic mass units) can pass the membrane.
- the fraction retained by the ultrafilter is pumped through the filter tube at a pressure of about 4-6 bar and a velocity of about 1.5-2.0 m/s, creating a turbulent flow through the tube.
- This turbulent flow is characteristic of cross-flow filtration.
- the filter modules are nor- mally arranged in a parallel flow path, which in the case of treatment of 40 m/day of waste such as liquid manure means about 60 modules with a recirculation flow through the filter of about 50-70 m/hour.
- the permeate passing through the filter membrane is collected in the aluminium shell encapsulating the filter tube and led from here to an intermediate permeate tank, from which it can either be pumped back to the reactor in order to maintain a desired level of liquid in the reactor or pumped to a storage tank upstream from the ammonia stripper.
- the flow of liquid through the ultraflltration unit will typically correspond to a flow that allows a volume corresponding to the entire reactor content to pass through the ultraflltration unit in a few hours. For example, for a reactor vessel with a volume of 240 m 3 , a volume of about 50-70 m 3 /h may pass through the ultraflltration unit. From this volume, a relatively small amount will exit the ultraflltration unit as substantially sterile, particle-free permeate, while the remainder, containing bacteria and suspended organic particles, will be recirculated to the reactor. If 40 mVday of permeate is led on to the next stage of the process, the residence time will be 6 days on average in this case.
- biogas produced in this manner has an unusually high content of methane and a correspondingly low content of carbon dioxide compared to biogas produced by traditional methods.
- biogas normally has a methane content of not more than about 65° by weight and a carbon dioxide content of at least about 35° by weight
- biogas produced according to the present invention typically has a methane content of about at least about 10 by weight, e.g. at least about 75 by weight, for example a methane content of about 75-80 ⁇ by weight and a carbon dioxide content of only about 20-25° by weight.
- the high methane content of the biogas produced according to the present invention means that correct carburation is not as critical, and the result is a smoother and more economical operation of the motor. In effect, the invention results in biogas with a quality close to that of natural gas.
- the ammonia stripping step when the ammonia stripping step is performed at an elevated temperature, and optionally also under a partial vacuum.
- the effective removal of both ammonia and carbon dioxide from the permeate stream is important for the subsequent reverse osmosis step, since insufficient removal of ammonia and carbon dioxide was found to result in deposits on the reverse osmosis membranes, such deposits ultimately requiring the plant to be shut down for repairs and possible replacement of the membranes, which in turn leads to greatly increased costs and reduced waste treatment capacity.
- the removal of carbon dioxide is particularly important in that it leaves the permeate essentially free of bicarbonate ions that would otherwise result n damaging deposits of calcium and magnesium carbonate on the reverse osmosis filter.
- the treatment process as a whole is made easier, cheaper and more reliable, and it is furthermore possible to obtain a larger overall capacity for the plant as a whole for a given reverse osmosis unit, or alternatively, to use a reverse osmosis unit with a smaller capacity than would otherwise be required .
- ammonia stripping is typically performed at a temperature of at least about 40 G C, preferably at least about 50°C, more preferably at least about 60"C, e.g. at least about 70°C.
- the permeate may also be boiled so that ammonia stripping is obtained by means of distillation.
- a combination of heat and reduced pressure may be used, e.g. a pressure of about 0.25-0.75 bar, such as about 0.5 bar, ana a temperature of about 65-85 c C, such as about 70-80 C.
- ammonia stripping method itself is not critical, and various methods known m the art will be able to be adapted to the needs of the present invention.
- An example of a suitable method and apparatus is described in EP 0494154-A.
- heat and reduced pressure are both provided by a compression evaporator, the heat being provided by condensation of evaporated liquid.
- the removal of ammonia and carbon dioxide can also be obtained using heating alone, i.e. at atmospheric pressure.
- the permeate is simply heated to a temperature suffi- 12 cient to distil off the ammonia and carbon dioxide.
- the heat for this process can be provided by excess heat from the burning of the biogas to provide heat and power, e.g. from flue gas.
- ammonia and carbon dioxide are effectively removed from the permeate, they tend to form a salt that precipitates in the form of ammonium bicarbonate. However, this can be readily removed from the ammonia stripper, e.g. by means of a mechanical extraction method combined with a worm pump.
- the nutrient salt fraction exiting the ammonia stripper typically has a pH value about 9-10.
- a lower pH is desired in order to prevent deposits on the membrane of especially phosphates, and the pH of the nutrient salt fraction should therefore be reduced to below about 7.0 prior to the reverse osmosis step.
- the pH is adjusted to about 6.5.
- Any suitable acid may be used, in particular an inorganic acid such as phosphoric acid, nitric acid, hydrochloric acid or sulphuric acid.
- a preferred acid is phosphoric acid.
- the permeate After having passed through the ammonia stripper, the permeate consists of a nutrient salt fraction in which essentially all ammonia and carbon dioxide has been removed, the pH of the nutrient salt fraction having been adjusted to a suitable level as de- scribed above.
- This nutrient salt fraction is then subjected to further purification using a membrane separation technique, in particular a reverse osmosis unit, which performs the final step in the treatment process, namely the separation of nutrient salts to result in a fertiliser concentrate fraction and a water frac- tion.
- the nutrient salts removed in this step are in particular salts of phosphorus and potassium, and the water that remains after the reverse osmosis step is clean, potable water that fulfils the WHO requirements for drinking water. 13
- the reverse osmosis step is e.g. performed using a conventional spiral reverse osmosis membrane unit arranged in a tapered configuration.
- the membranes are e.g. of the polyamide brackish water type normally used for desalination.
- the reverse osmosis may be either performed as a continuous process or a batch process. In a preferred embodiment, however, the reverse osmosis is performed as a fed batch process. This can for example take place using a concentrate tank, e.g. with a volume of about 2 m .
- the concentrate tank is filled up with permeate which is pumped to the reverse osmosis membrane. Clean water is removed from the reverse osmosis unit, while permeate retained by the reverse osmosis membrane is returned to the concentrate tank for further processing. After a period of e.g. about 12-14 hours, the volume of concentrated permeate in the tank has been reduced to, e.g., about 20% of the original permeate volume. At this point, the concentrated permeate (fertiliser concentrate) is removed from the tank, which is then rinsed prior to the start of a new cycle.
- the separation of the liquid manure or other liquid organic waste into the various end products results m a significant improvement in the utilisation of the various components m the waste material, and correspondingly a significant reduction of the environmental impact. In this way, it is in fact possible to recycle as much as 98-100 o of the organic matter in liquid manure into useful products.
- the invention makes is possible to obtain sig- nificant improvements in the internal environment of stalls containing livestock, since the stalls can be designed for immediate removal of liquid manure. As a result, it is possible to essentially eliminate ammonia from such stalls, and the stalls can be constructed without any large-scale storage facilities for liquid manure, since the manure can be led out of the stall for substantially immediate treatment.
- the entire system is well-suited for automatic, computerised operation.
- the fermentation process can be monitored by means of automatic measurements of volatile fatty acids, such measurements typically being performed downstream of the ultra- filtration unit, e.g. using an automatic titration process. The results of these measurements can then be used to automatically regulate the feed of untreated liquid waste into the reactor vessel, so as to maintain a desired organic matter content in the reactor and thus an optimum fermentation rate.
- Another preferred embodiment of the invention which is particularly suitable for the treatment of sewage from e.g. households, institutions or industry, comprises the following:
- a coarse screen filter having openings of e.g. about 2-3 cm for removing relatively large objects from the sewage.
- Ultraflltration of liquid from the concentration tank typically results in a permeate volume of about 80 of the total volume of liquid added to the concentration tank, /42423
- the liquid subjected to ultraflltration will contain a significant amount of macromolecu- lar material (proteins and fat) that will tend to be collected on the ultrafilter membrane.
- the ultrafilter membrane will thus require cleaning at regular intervals, for example once a day, which typically takes about 4-6 hours.
- the concentration tank will therefore be designed so that it can hold a much larger volume than that which is actually present in the tank most of the time, thereby allowing the concentration tank to also function as a buffer tank into which liquid to be treated may flow during pe- nods in which the ultraflltration unit is not in operation due to cleaning of the ultrafilter membrane.
- a first reverse osmosis unit for treatment of the permeate fraction from the ultraflltration unit 4.
- the concentrate fraction from the ultrafiltration unit is subjected to a treatment process substantially as described in more detail above, i.e. using a combination of a biogas reactor, an ultraflltration unit and an ammonia stripper.
- the permeate from the first reverse osmosis unit mentioned in (4) above is combined with the permeate (nutrient salt fraction) from the ammonia stripper mentioned in (5) above, this combined permeate being subjected to reverse osmosis.
- the reverse osmosis unit in this case is substantially as described in more detail above, but will typically be dimensioned to treat a much larger volume of liquid.
- the concentration tank in this embodiment of the invention may have a size of e.g. about 200 m , suitable for daily treatment of about the same sewage volume.
- the volume of liquid in the concentration tank will generally be much less, however, e.g. about 50 m , with the exception of those periods during which the ultraflltration unit is not in operation due to cleaning of 16 the ultrafilter. In these periods, liquid will continue to flow into the concentration tank, so that the level of liquid rises significantly until the ultraflltration unit again begins operating, at which point the amount of liquid in the tank will fall relatively quickly to the equilibrium level of e.g. about 50 m .
- concentration tank typically, about 80% of the total liquid volume added to concentration tank, or in this case about 160 m'/d, will exit the ultra- filtration unit as permeate, while the remaining approximately 20%, i.e. about 40 m /d in this case, will be removed from the concentration tank for further processing using a biogas reactor, an ultraflltration unit and an ammonia stripper as mentioned in (5) above.
- concentration tank in order to obtain a liquid waste with a higher organic matter content before the liquid is treated in the biogas reactor, is preferred for liquids having an initial organic matter content of less than about 0.5-1% by weight, while such a concentration step will not normally be performed when the organic matter content is above about 1 by weight.
- Fig. 1 shows the basic components of a preferred treatment plant according to the invention.
- Fig. 2 shows a mass balance diagram for liquid manure treated according to the invention.
- Fig. 3 shows a treatment plant suitable for treating sewage from e.g. households or institutions.
- the treatment plant comprises a collecting tank 2 for collecting liquid manure from livestock in a stall.
- a pump 4 pumps liquid manure from the collecting tank 2 to a filtration unit 6, which separates the liquid manure into a fibrous fraction 8 and a liquid fraction 10, which is collected in a buffer tank 12.
- liquid is transferred by means of a pump 14 to a biogas reactor 16, wherein anaerobic fermentation 17 takes place.
- An outlet at or near the top of the reactor allows biogas 18 to be removed from the reactor.
- the biogas 18 is then preferably mixed with air and subsequently treated in a desulphurisation unit (not shown) to remove hydrogen sulphide.
- Liquid from the reactor 16 is transferred by means of a pump 20 to an ultraflltration unit 22 that separates a substantially sterile and particle-free permeate stream from liquid in the reactor.
- a pressure gauge (not shown) is located at or near the bottom of the reactor 16, the pressure gauge being in contact with a valve 24 that allows part of the permeate 26 to be returned to the reactor 16 as necessary in order to regulate the level of liquid in the reactor.
- the remainder of the permeate 28 is led on to an ammonia stripper 30.
- Liquid 32 containing recirculated biomass (bacteria and suspended organic matter) retained by the ultrafil- tration unit 22 is mixed with untreated liquid manure from the buffer tank 12 and returned to the reactor 16 for further treatment.
- the liquid 32 first passes through a heat exchanger 34.
- the reactor 16 has an outlet 36 at the bottom through which sedimented particles and sludge can be removed.
- the ammonia stripper 30 separates the permeate into an ammonia fraction 38, containing almost all of the ammonia and carbon dioxide found in the permeate, and a nutrient salt fraction 40 containing water and dissolved salts of phosphorus and potassium.
- the nutrient salt fraction 40 is then subjected to reverse osmosis in a re- verse osmosis unit 42, which results in a fertiliser concentrate fraction 44 comprising salts of P and K and clean water 46 of drinking water quality.
- Fig. 2 shows schematically the result of processing 40 t/day of liquid manure slurry.
- the 40 tons of liquid manure is filtered to result in 1.2 tons of compost and 38.8 tons of filtered slurry.
- Processing of the filtered slurry in the biogas reactor results in 880 Nm of biogas, of which about 70 l is methane.
- the 38,8 tons of permeate result in about 1 ton of ammonia concentrate and about 38 tons of nutrient salt permeate.
- the nutrient salt permeate is converted to 6.2 tons of P/K fertiliser concentrate and 31.6 tons of water.
- VS volatile solids
- TS total solids. 18
- Fig. 3 shows the basic components of a treatment plant for the treatment of sewage.
- the treatment plant comprises a coarse screen filter 2 for removing relatively large ob- jects from the sewage.
- the sewage is then led to a pre-treatment filter 4 to remove fibres and particles of a size of more than about 1 mm and subsequently to a concentration tank 6, the concentration tank 6 being connected to an ultraflltration unit 8 comprising a tubular ultraflltration membrane.
- Permeate 10 from the ultraflltration unit 8 is transferred to a first reverse osmosis unit 12 for further purification.
- Concentrate 14 from the concentration tank 6 is then subjected to a treatment 16 (details not shown) comprising a combination of a biogas reactor, an ultraflltration unit and an ammonia stripper.
- the permeate 18 from the first reverse osmosis unit 12 is then combined with the permeate 20 from the treatment 16, this combined permeate being subjected to reverse osmosis in a second reverse osmosis unit 22.
- a plant as described above and comprising the following compo- nents has been in use on a pig farm in Denmark for a period of 6 months :
- a pre-treatment unit for removing fibrous and particulate material greater than 1 mm (“SWEA separator", available from Swea A/S, Denmark) a buffer tank, a biogas reactor with a volume of about 240 m , operating at a temperature of about 35-37 C, a desulphurisation unit for removal of hydrogen sulphide from the biogas, an ultraflltration unit employing a tubular ultrafilter with a diameter of 12.5 mm and a cut-off point of about 20,000 Dalton (obtained from Membratek, South Africa), with a flow through the unit of about 50-70 m /h, 42423
- an ammonia stripper similar to that described in EP 0494154-A, comprising a compression evaporator to result in a reduced pressure of about 0.5 bar and a permeate temperature of about 75-80°C, and - a spiral reverse osmosis membrane unit arranged in a tapered configuration, with membranes of the polyamide brackish water type.
- This treatment plant was used to treat a volume of liquid manure from pigs of about 40 mVday, the liquid manure having a dry matter content about 6% by weight.
- the end products of the treatment, per day, are as follows:
Abstract
Description
Claims
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/DK1998/000069 WO1999042423A1 (en) | 1998-02-20 | 1998-02-20 | Method and plant for the treatment of liquid organic waste |
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EP1056691A1 true EP1056691A1 (en) | 2000-12-06 |
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EP98902971A Withdrawn EP1056691A1 (en) | 1998-02-20 | 1998-02-20 | Method and plant for the treatment of liquid organic waste |
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US (1) | US6368849B1 (en) |
EP (1) | EP1056691A1 (en) |
JP (1) | JP2002511832A (en) |
CN (1) | CN1284938A (en) |
AU (1) | AU5983298A (en) |
CA (1) | CA2346706C (en) |
WO (1) | WO1999042423A1 (en) |
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- 1998-02-20 EP EP98902971A patent/EP1056691A1/en not_active Withdrawn
- 1998-02-20 WO PCT/DK1998/000069 patent/WO1999042423A1/en not_active Application Discontinuation
- 1998-02-20 CA CA 2346706 patent/CA2346706C/en not_active Expired - Lifetime
- 1998-02-20 CN CN98813703A patent/CN1284938A/en active Pending
- 1998-02-20 JP JP53987899A patent/JP2002511832A/en not_active Ceased
- 1998-02-20 AU AU59832/98A patent/AU5983298A/en not_active Abandoned
- 1998-02-20 US US09/214,347 patent/US6368849B1/en not_active Expired - Fee Related
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CA2346706A1 (en) | 1999-08-26 |
AU5983298A (en) | 1999-09-06 |
US6368849B1 (en) | 2002-04-09 |
WO1999042423A1 (en) | 1999-08-26 |
JP2002511832A (en) | 2002-04-16 |
CA2346706C (en) | 2010-10-05 |
CN1284938A (en) | 2001-02-21 |
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