EP1042125B2 - Verfahren zum herstellen eines mehrfarbigen fotolumineszierenden bildes, so hergestelltes bild und seine anwendungen - Google Patents

Verfahren zum herstellen eines mehrfarbigen fotolumineszierenden bildes, so hergestelltes bild und seine anwendungen Download PDF

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EP1042125B2
EP1042125B2 EP99950811A EP99950811A EP1042125B2 EP 1042125 B2 EP1042125 B2 EP 1042125B2 EP 99950811 A EP99950811 A EP 99950811A EP 99950811 A EP99950811 A EP 99950811A EP 1042125 B2 EP1042125 B2 EP 1042125B2
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image
printed
monochromatic
images
photoluminescent
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French (fr)
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EP1042125A1 (de
EP1042125B1 (de
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François Trantoul
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/14—Multicolour printing
    • B41M1/18—Printing one ink over another
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/06—Veined printings; Fluorescent printings; Stereoscopic images; Imitated patterns, e.g. tissues, textiles

Definitions

  • the invention relates to a method for producing a photoluminescent printed polychromatic image of any kind (that is to say that can incorporate all shades of colors and various shapes including possibly continuous color variations (degraded, melted, etc.). .) shadows, variations of intensity, effects of mottled ...) invisible under lighting in visible light, and visible under illumination by at least one non-visible light source, designated hereinafter throughout the text "image any photoluminescent printed polychromatic ".
  • visible light is meant a light whose spectral composition is located in the visible spectrum, from 0.4 ⁇ to 0.8 ⁇ .
  • Non-visible light denotes a light whose spectral composition is located outside the visible spectrum, especially in the ultraviolet and / or infrared spectrum.
  • Photoluminescent printed monochromatic imprints invisible under visible light and visible under non-visible light are often used for authentication of documents such as banknotes.
  • Various printed monochromatic markings can be juxtaposed and / or superimposed, which creates color spots composed in finite number and discontinuously.
  • Such a photoluminescent printed polychromatic image may have many interests and various applications, especially as an authentication element and / or for decoration purposes.
  • any photoluminescent printed polychromatic image may provide at least three levels of authentication: image printing creates raised patterns and / or visible opalescence in visible light; under illumination in non-visible light, it is possible to verify the conformity of the image which is extremely difficult to counterfeit with perfection, given its complexity and the fact that it is applied to a background of a document with other visible patterns by transparency, except to have the original visible in visible light, the reproduction from the visible image in non-visible light does not provide the original image; a spectrophotometric analysis makes it possible to identify the photoluminescent components used, and therefore their authentic character.
  • any such photoluminescent printed polychromatic image illuminated in non-visible light has a particular unusual appearance.
  • traditional printed polychromatic images visible in visible light are generally made in four-color process (yellow, magenta, cyan, black) on a white background.
  • the original image is filtered with three color filters (blue, green, red) having a spectral bandwidth of 100 ⁇ (one third of the visible spectrum).
  • the appearance of the colors on the printed image is due to the reflection of the visible natural light (daylight or a lighting lamp) by the medium printed through the transparent colored inks which selectively absorb the incident light according to the principle called "matter color" in subtractive synthesis.
  • the support reflects two-thirds of the visible spectrum, according to a spectral composition complementary to the absorption spectrum of the ink in the visible.
  • the methods described in these documents do not allow the production of a photoluminescent polychromatic image by automatic and reliable reproduction of a polychromatic image. Indeed, the methods described in these documents consist in first producing a trichromatic positive manually. Subsequently, this trichromic positive is used to be reproduced by printing using inks some of which incorporate fluorescent pigments. Consequently, these documents show that the automatic obtaining of a tri-chromic positive photoluminescent had been abandoned, since these documents consider that this positive is necessarily achieved manually.
  • the document RJ TUTOR "Fluorescent Multicolor Additive System" XP 002108747, PRODUCT LICENSING INDEX., No. 84, pages 81-85, INDUSTRIAL OPPORTUNITIES LTD. HAVANT., GB ISSN: 0374-4353, April Issue, 1971 teaches to make by printing with the aid of an etching plate press, a multicolor fluorescent image under ultraviolet.
  • the method implemented in this document consists in producing red, green and blue separation negatives from a continuous positive by exposure through a red, green and blue filter, respectively. With this method, since each of the negatives is not finely filtered, the largest proportion of the surface of the final image comprises an abnormal overload of the three predominantly white colors. Therefore, the fluorescent image obtained is extremely pale and is in practice, either invisible or a "ghost" image, despite the realization of a large number of successive final layers of green ink.
  • the invention therefore aims generally to allow the realization of any photoluminescent printed polychromatic image.
  • the invention aims to enable the reproduction in printed and photoluminescent form of an image of polychromatic origin formed in subtractive synthesis (material color principle), any visible in visible light (printed image, painted, photograph,. ..) automatically and reliably.
  • the invention also aims to provide a simple and inexpensive method for quickly obtaining and reproducing such an image on an industrial scale automatically and reliably, especially in a similar way to traditional printing techniques, without requiring the manually performing a tri-chromatic positive by an artist, and providing an image of high quality and high contrast.
  • the invention also aims to propose applications of such a photoluminescent printed polychromatic image of any kind.
  • the wavelength of the emission peak may be in the entire bandwidth less than or equal to 15 nm of the filtering wavelength. In other words, we accept a certain margin of error for the wavelengths, and this margin of error is of the order of the bandwidth of the filters used.
  • the invention thus makes it possible for the first time to automatically obtain any photoluminescent printed polychromatic image which is a faithful reproduction, with all the color shades and shapes that can infinitely vary to infinity, of a original image of any polychromatic origin visible in visible light.
  • This original can be printed or a stored analog image (photographic, cinematographic, video ...), or a digitized image stored on a computer mass memory or other.
  • the method according to the invention makes it possible to obtain an invisible photoluminescent printed polychromatic image under light in visible light, and visible under illumination by at least one non-visible light source, comprising at least one set of at least three images, called printed images, printed one above the other, each printed image comprising a photoluminescent pigment emitting a color under illumination by a non-visible light source, the different colors of the printed images of the same set being adapted to be able to form by synthesis additive all the colors of the visible spectrum under illumination by at least one non-visible light source, characterized in that each printed image, called monochromatic printed image corresponds to the filtering of an image of polychromatic origin in subtractive synthesis visible in visible light, at a spectral bandwidth less than or equal to 15 nm centered a wavelength, referred to as the wavelength of filtering, chosen from wavelengths of at least three fundamental colors, the different filtering wavelengths being two by two distinct and adapted to make it possible to form by additive synthesis all colors of the visible spectrum, each of these filtering wavelengths
  • a colored polychromatic origin image 1 is represented according to the principle of color matter (subtractive synthesis), visible in visible light such as a photograph or a printed image in traditional quadrichromy, which one wants to reproduce with all the nuances of colors and forms, obtaining a printed polychromatic image any photoluminescent any invisible under lighting in visible light and visible under illumination by at least one non-visible light source.
  • An original of this original image 1 is illuminated from a visible light source 2 such as an incandescent lamp or daylight.
  • the light illuminating the original image 1 is a visible white light which is reflected by the original image 1 towards a CCD camera 3 connected to a microcomputer 4 for storing the images captured by the camera. 3.
  • This filter 5 is chosen from at least three interference filters 5a, 5b, 5c which have a spectral bandwidth of less than 15 nm, in particular of the order of 10 nm, and whose filtering wavelength is chosen at less than approximately equal to the wavelength of an emission peak of a photoluminescent pigment under illumination by at least one non-visible light source, this pigment being otherwise adapted to allow the subsequent printing of the image polychromatic, that is to say to be compatible with the means and printing techniques used as described below.
  • the filtering wavelengths are chosen from wavelengths of at least three fundamental colors that can form all the colors of the visible spectrum by additive synthesis. In particular, three wavelengths are sufficient provided that each fundamental color can not be balanced by the other two. It is also possible to use more than three wavelengths.
  • the monochromatic image from the filter 5 is a contrasted monochromatic filtered image.
  • the camera 3 is a monochrome camera.
  • Three monochromatic filtered images 6a, 6b, 6c are thus produced with, respectively, each of the three filters 5a, 5b, 5c, monochromators from the same original image 1.
  • These three monochromatic filtered images 6a, 6b, 6c are digitized images recorded in the microcomputer 4.
  • Each monochromatic filtered image 6a, 6b, 6c captured and digitized by the CCD camera 3 is recorded by the microcomputer 4.
  • the image of polychromatic origin may be a digitized image recorded and digital filtering means are used to perform, by software calculation, each monochromatic filtered image 6a, 6b, 6c. It is also possible to use digital filtering of a scanner having a transfer function adapted to the filtering wavelengths.
  • These printing frames 7a, 7b, 7c are each formed of a film carrying a contrasting image whose dot density at each point of the image corresponds to the luminous intensity of the polychromatic image that is wish to reproduce.
  • the dot density at each point of the contrasting image of the negative printing frame corresponds to the luminous flux of the image.
  • the original polychromatic image 1 reflected at this point, respectively according to each filtering wavelength. It is therefore necessary in this case to perform an inversion of the monochromatic filtered images 6a, 6b, 6c, which are positive, to obtain negative frames of screen printing 7a, 7b, 7c.
  • This inversion can be performed either by the image capture software by the CCD3 camera, or by using traditional image processing software from the scanned and recorded images, or by the image processing software. the printer to make the printing frames.
  • the printing frames 7a, 7b, 7c are produced on transparent films which then make it possible, by exposure of a photopolymer, to screen silk screen printing, one for each monochromatic filtered image 6a, 6b, 6c.
  • Each screen is made for example from a fabric whose mesh comprises 165 threads / cm, the son having a diameter of 27 ⁇ .
  • a layer of photopolymer material 18 microns thick is used.
  • Each screen is thus representative, for each filtering wavelength, of a luminous flux reflected by the original polychromatic image 1 in the filter wavelength corresponding to the filter used, or of the inverse of this luminous flux.
  • a printing medium 9 three images, called images.
  • the printing medium 9 can be of any kind as long as it is compatible with the printing technique used.
  • this printing medium 9 is itself not photoluminescent, -party devoid of optical brightener- not to disturb the chromatic balance of the image 8 to form.
  • the screen-printing screen made from one of the monochromatic filtered images 6a, 6b, 6c, and a transparent printing composition comprising a photoluminescent pigment whose length is emission peak wave, under illumination by at least one non-visible light source 14, is equal to the filtering wavelength used to obtain said monochromatic filtered image.
  • photoluminescent pigments it is advantageous to use mineral pigments - especially selected from the rare earths - which are well adapted to be printed by screen printing, and resist the radiation of the non-visible light source. which ensures the maintenance in time of the chromatic balance.
  • organic pigments whose durability is a little less good, but have a better transparency.
  • a monochromator filter 5 it is possible to use, for example, the interference bandpass filters marketed by the company LOT ORIEL (Courtaboeuf, France) as mentioned in the table below, and in which are also indicated examples of references of corresponding photoluminescent pigments which can be used, marketed by the company RIEDEL DE HAN (Germany) (RDH in the table) or USR OPTONICS (New Jersey, USA) (USR in the table).
  • the chosen pigment is incorporated in a screen-printing varnish chosen to be transparent, or at least translucent, when it is dry and placed under illumination by the source (s). (s) of light 14 not visible, at least for wavelength light corresponding to the wavelength of the emission peak of this photoluminescent pigment, and for each of the emission peak wavelengths of the photoluminescent pigment (s) of the monochromatic printed image (s) previously printed on the printing medium. In this way, the light emitted by each of the photoluminescent pigments can pass through the printed screen printing varnish to be visible from the outside, and without color imbalance.
  • the concentrations of each pigment in the screen-printing varnish may be as follows: 27% for the blue pigment, 27% for the red pigment and 13.5% for the pigment green. These values can be decreased or increased (provided that the composition can be printed) provided that the relative proportions of the different colors for the chromatic balance are respected.
  • the three monochromatic printed images 8a, 8b, 8c blue, red, green are printed on the support 9, starting with the monochromatic printed image 8a whose photoluminescent pigment emits in green (wavelength of 530 nm in the example above), then printing the monochromatic printed image 8b whose photoluminescent pigment emits in the red (wavelength of 620 nm in the example above), and ending with the monochromatic printed image 8c whose photoluminescent pigment emits in the blue (wavelength of 440nm in the example above).
  • the various monochromatic printed images 8a, 8b, 8c are in the order 8c blue, 8b red, 8a green emission wavelengths of the photoluminescent pigments, in the order of reception of the non-visible light causing this show.
  • the silk-screen printing varnish used must also be transparent for light to length wave of the source 14 of non-visible light (or non-visible light sources when multiple sources are used), so as to allow photoluminescence of the various pigments.
  • the different monochromatic printed images 8a, 8b, 8c are printed successively, either directly on one another, respecting a drying time between each layer, or by interposing possibly continuous transparent layers between them.
  • a transparent layer is for example a layer of polymerizable two-component printing composition containing a hydroxylated polyol and an isocyanate or a polyisocyanate so as to cause the polymerization in situ of the mixture leading to a thin transparent polyurethane film, as described for example by EP-0 271 941 or U.S. 5,232,527 .
  • the monochromatic printed images 8a, 8b, 8c are all printed with the same printing tools (the screen screens used being made from the same fabrics and with the same photopolymer material).
  • the monochromatic printed images 8a, 8b, 8c are printed with the same printing thickness.
  • This thickness is advantageously between 3 ⁇ and 12 ⁇ according to the characteristics of the screen screen used, in particular and is of the order of 5 ⁇ in the example above.
  • the actual thickness of the monochromatic image 8a, 8b, 8c at each point depends on the image pattern, as is always the case in screen printing.
  • the amount of photoluminescent pigment at each point is a function of the light intensity of the image of polychromatic origin at this point according to the corresponding filtering wavelength. .
  • the screen printing varnish used incorporating the photoluminescent pigment is chosen to be itself non-photoluminescent so as to allow the formation of the image 8 by additive synthesis later by the three pigments of the three monochromatic images 8a, 8b, 8c.
  • the different monochromatic printed images 8a, 8b. 8c are transparent or translucent in visible light when placed under illumination in visible light, so that the image 8 formed is itself, in total, transparent or translucent for visible light when it is placed under illumination. visible light. In this way, it allows the display of any mentions 12 previously listed on the support 9, by transparency.
  • the screen printing varnish used is advantageously a varnish curing under ultraviolet rays. Indeed, the photoluminescent inorganic pigments are generally sensitive to temperature.
  • the photoluminescent pigments all have the same absorption spectrum, and emit visible light at a single emission peak under illumination by a non-visible light source 14, for example ultraviolet length wave equal to 365nm.
  • a photoluminescent pigment whose absorption spectrum is included in the long ultraviolet the non-visible light source may emit at a length of wave of the order of 365 nm
  • a photoluminescent pigment whose absorption spectrum is located in the short ultraviolet the corresponding non-visible light source can emit at a transmission wavelength in the order of 250 nm
  • the corresponding non-visible light source can emit at a wavelength of the order of 950 nm.
  • the advantage of using photoluminescent pigments having different absorption spectra is to require the use of several different sources of non-visible light to view the image later, which
  • the different sets of monochromatic printed images can be printed successively, the two photoluminescent reproductions thus formed being superimposed on one another.
  • the monochromatic printed images of different games can be nested. For example, we can print first of all the different monochromatic printed images with green pigments, then the different monochromatic printed images with red pigments, then the different monochromatic printed images with blue pigments.
  • photoluminescent pigments are chosen whose wavelengths of the emission peaks are at least approximately equal, so as to use the same images.
  • monochromatic filtered 6a, 6b, 6c to achieve these two photoluminescent reproductions. It suffices to perform the inversion of these monochromatic filtered images during the preparation of the printing screens to obtain positive polychromatic reproductions, and not to perform this inversion to obtain the polychromatic reproduction in negative.
  • the concentration of the infrared-excited pigments must be greater in the printing varnish than that of the pigments with excitation under ultraviolet light.
  • At least one image can be printed with a printing composition comprising at least one pigment, called infrared pigment, having at least one emission peak wavelength located in the infrared range. , but no emission in visible light, when this pigment is activated by lighting under a visible light source.
  • infrared image is a monochrome image that will be visible in the infrared range but will remain invisible in the visible light domain.
  • a photoluminescent polychromatic reproduction 8 is carried out under ultraviolet or infrared as indicated above which is a positive reproduction of the original image, then an infrared image which is a negative reproduction of the image of origin.
  • the infrared image is a positive while the photoluminescent polychromatic reproductions is a negative.
  • the excitation sources of the pigments are different, nothing prevents even printing on the same printing medium 9 an infrared image in positive or negative on two superimposed photoluminescent polychromatic reproductions 8 made as indicated above.
  • a printing composition comprising, for example, the reference varnish CD 170 marketed by the company Riedel de Han (Germany).
  • the reflected image of the original image 1, picked up by the CCD3 camera without filtering is used, and the steps of dithering, possible inversion, flashing, insolation, revelation and printing are carried out as described above. .
  • the support 9 is illuminated with a visible light source.
  • a filtered light source is used in a spectral band of 40 nm to 100 nm centered on 585 nm.
  • the infrared image formed, for example, is then read by means of an infrared camera, or a CCD camera via a high-pass filter having a cutoff threshold of 800 nm filtering the light directly from the visible light source. excitation.
  • the printing medium 9 can be a transparent protective film or a transparent film of such a film, so that the image 8 according to the invention is carried by or incorporated in a protective film.
  • the image 8 according to the invention can be formed inside a transparent protective film as described by EP-0 271 941 or U.S. 5,232,527 .
  • FIGS. 3 and 4 represent an example of application of a transparent protective film 9 carrying a photoluminescent printed polychromatic image 8 of any kind according to the invention.
  • This film 9 is applied to a part of a face 13 of a document 10 to serve as an authentication means.
  • the face 13 of the document 10 is coated with an image 11 visible in visible light and common or variable mentions 12 visible by transparency through the film 9 when it is illuminated in visible light.
  • the image 8 carried by the film 9 is not visible in visible light.
  • the image 8 is formed of a transparent composition in visible light, and the photoluminescent pigments do not emit light in visible light.
  • the presence of the photoluminescent pigments in the image 8 results in practice, in general, to make it slightly whitish and translucent.
  • the thickness variations of the patterns of these different images create opalescence on the surface (represented schematically by dotted lines figure 3 ) allowing to distinguish certain contours of the image 8, but without allowing the precise vision of the outlines, or especially the colors of the polychromatic image.
  • the document 10 is illuminated by a source 14 of non-visible light corresponding to the absorption spectrum of the different photoluminescent pigments of a set of monochromatic printed images 8a, 8b, 8c of the image 8.
  • a source 14 of non-visible light corresponding to the absorption spectrum of the different photoluminescent pigments of a set of monochromatic printed images 8a, 8b, 8c of the image 8.
  • several sources non-visible light must be used to excite the photoluminescent pigments of the image 8.
  • the polychromatic image 8 appears photoluminescent with all of its color shades, identical to the image of polychromatic origin 1. Photoluminescence also creates a certain decorative and surprising effect, the colors appearing with a luminosity and unusual chromatic purity according to the principle of light color.
  • the photoluminescent polychromatic image 8 is superimposed on the indications 12 carried by the face 13 of the document, which are still visible by transparency through the film 9 and the image 8.
  • the document 10 thus protected may be a passport, an identity card, a driver's license, a vehicle registration card or other official documents of identification and / or authentication, a fiduciary document such as a ticket bank, a check, a card or other payment.
  • the film 9 can be applied to the face 13 of the document 10 in the traditional way, by means of an adhesive layer, for example by cold dry transfer or hot rolling.
  • the film 9 may itself be an anti-forgery film that can incorporate other authentication marks or prevent its reproduction by optical reading.
  • the transparent image 8 being applied to the document can not be infringed because of the other mentions of the document or mentions embedded in the film 9 which, by combining with the image 8, prevent its reproduction by non-illuminated light. visible and filtering.
  • the photoluminescent printed polychromatic image 8 also protects the document 10 against any reproduction in optical reading in visible light, for example by photocopy or otherwise.
  • the references 12 of the document may themselves be formed at least in part of an image according to the invention printed on the face 13 of the document. In this case, it is advantageous to use for the second image pigments different from those of the first image.
  • the invention is also applicable for purely decorative or advertising purposes to produce images 8 particularly aesthetic and providing a surprising effect.
  • the image 8 can be shown or disappear intermittently.
  • a photoluminescent ultraviolet polychromatic image according to the invention was printed on a white paper free of optical brightener from a printed quadrichromic origin image formed of a complete continuous visible color spectrum. .
  • the mineral pigments CD144, CD105 and CD166 are used. It is found that the image according to the invention perfectly reproduces the color spectrum under illumination in ultraviolet light.
  • a quadrichromic landscape image printed in A4 format is used which is reproduced by a process according to the invention as described above on the free face of a transparent adhesive polyurethane protective film marketed by the company FASVER (France) under the FASPROTEK ® name, corresponding format.
  • This transparent film is then applied to an official document to be protected bearing a pre-printed text. We note that the film does not prevent the reading of the pre-printed text.
  • the screen printed image forms visible opalescent reliefs at low incidence. It is not visible in visible white light. Under illumination by an ultraviolet lamp, the image appears with all its shades of colors.
  • the invention can be the subject of multiple embodiments with respect to the embodiments described and shown.
  • other printing techniques than screen printing can be used, provided that that the photoluminescent pigments used are compatible with these printing techniques.
  • the printing can be performed on a support other than a transparent film 9, and the original polychromatic image 1 can not be a photographic or printed image, but an image previously digitized in a computer system that is printed. for example using a color laser printer to allow its filtering by the filters 5, or even that is filtered by numerical calculation.

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  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
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Claims (21)

  1. Verfahren zur Herstellung eines polychromatischen fotolumineszenten Druckbildes (8), das unter Beleuchtung durch sichtbares Licht unsichtbar und unter Beleuchtung durch wenigstens eine Quelle (14) von unsichtbarem Licht sichtbar ist, umfassend die folgenden Schritte:
    - Wählen oder Erzeugen eines bei sichtbarem Licht sichtbaren polychromatischen Ausgangsbildes (1) durch subtraktive Synthese,
    - Erzeugen und Speichern von wenigstens einem Satz von wenigstens drei Bildern, gefilterte Bilder (6a, 6b, 6c) genannt, durch Filtern des Ausgangsbildes (1),
    - getrenntes Drucken, nacheinander und übereinander, von wenigstens einem Satz von wenigstens drei Bildern, Druckbilder (8a, 8b, 8c) genannt, unter Verwendung und Reproduzierung von jeweils einem der gefilterten Bilder (6a, 6b, 6c), mit einer Druckzusammensetzung, die ein fotolumineszentes Pigment umfasst, wobei die verschiedenen fotolumineszenten Pigmente von verschiedenen Druckbildern aus demselben Satz, unter der Beleuchtung durch wenigstens eine Quelle (14) von unsichtbarem Licht, Farben emittieren, die durch additive Synthese alle Farben des sichtbaren Spektrums bilden,
    dadurch gekennzeichnet, dass:
    - die gefilterten Bilder, monochromatische gefilterte Bilder (6a, 6b, 6c) genannt, durch Filtern des Ausgangsbildes (1) mit einem Spektralpassband von kleiner oder gleich 15 nm erzeugt werden, das auf einer Wellenlänge zentriert ist, Filterwellenlänge genannt, die ausgewählt ist aus den Wellenlängen von wenigstens drei Grundfarben, wobei die unterschiedlichen Filterwellenlängen von monochromatischen gefilterten Bildern jeweils paarweise unterschiedlich und so gestaltet sind, dass sie die Bildung aller Farben des sichtbaren Spektrums durch additive Synthese zulassen, wobei jede dieser Filterwellenlängen wenigstens näherungsweise gleich einer Emissionspeak-Wellenlänge eines fotolumineszenten Pigments unter der Beleuchtung durch wenigstens eine Quelle (14) von unsichtbarem Licht ist,
    - Drucken jedes Druckbildes, monochromatisches Druckbild (8a, 8b, 8c) genannt, unter Verwendung und Reproduzierung eines der monochromatischen gefilterten Bilder (6a, 6b, 6c) mit einer Druckzusammensetzung, die ein fotolumineszentes Pigment mit einer Emissionspeak-Wellenlänge umfasst, unter der Beleuchtung durch wenigstens eine Quelle (14) von unsichtbarem Licht, die wenigstens näherungsweise gleich der Filterwellenlänge ist, die zum Erhalten des genannten monochromatischen gefilterten Bildes (6a, 6b, 6c) verwendet wird.
  2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass zum Erzeugen jedes der monochromatischen gefilterten Bilder (6a, 6b, 6c) ein Original des polychromatischen Ausgangsbildes (1) unter sichtbarem Licht sichtbar beleuchtet wird und das durch dieses beleuchtete Original reflektierte polychromatische Bild mit einem Spektralpassband gefiltert wird, das kleiner oder gleich 15 nm ist, zentriert auf der Filtrierwellenlänge der Grundfarbe, die dem monochromatischen gefilterten Bild (6a, 6b, 6c) entspricht.
  3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, dass das reflektierte polychromatische Bild (1) mit Monochromfiltern (5a, 5b, 5c) mit einem Spektralpassband von etwa 10 nm, insbesondere mit Interferenz-Passbandfiltern (5a, 5b, 5c), gefiltert wird.
  4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass als Filterwellenlänge und als Emissionspeaks von fotolumineszenten Pigmenten wenigstens eine Wellenlänge im grünen, wenigstens eine Wellenlänge im roten und wenigstens eine Wellenlänge im blauen Bereich gewählt wird..
  5. Verfahren nach Anspruch 4, dadurch gekennzeichnet, dass die Wellenlängen so gewählt werden, dass sie durch denselben Spektralabstand zwischen 80 nm und 100 nm, insbesondere von 90 nm voneinander getrennt sind.
  6. Verfahren nach Anspruch 4 oder 5, dadurch gekennzeichnet, dass eine Wellenlänge im grünen Bereich zwischen 520 und 570 nm, eine Wellenlänge im roten Bereich zwischen 610 und 680 nm und eine Wellenlänge im blauen Bereich zwischen 430 und 480 nm gewählt werden.
  7. Verfahren nach einem der Ansprüche 4 bis 6, dadurch gekennzeichnet, dass die monochromatischen Druckbilder (8a, 8b, 8c) so gedruckt werden, dass sie in der Reihenfolge des Empfangs des Beleuchtungslichtes in der Reihenfolge blau, rot, grün von Filterwellenlängen und von Emissionspeaks von fotolumineszenten Pigmenten liegen.
  8. Verfahren nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass zum Speichern der monochromatischen gefilterten Bilder (6a, 6b, 6c) ein gefiltertes Bild mit lichtempfindlichen CCD-Ladungsübertragungsmitteln (3) erfasst wird, ein entsprechendes digitalisiertes Bild gespeichert wird, und dadurch, dass auf der Basis von jedem monochromatischen gefilterten Bild ein digitalisiertes und gerastertes Bild (7a, 7b, 7c) gebildet wird, das ein Raster von 60 x 133 aufweist, das dann zum Drucken des monochromatischen Druckbildes (8a, 8b, 8c) verwendet wird.
  9. Verfahren nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die monochromatischen Druckbilder (8a, 8b, 8c) wenigstens im Wesentlichen mit derselben Druckdicke und so gedruckt werden, dass die Menge an fotolumineszentem Pigment in jedem Punkt von der Lichtintensität des polychromatischen Ausgangsbildes (1) in diesem Punkt gemäß der entsprechenden Filterwellenlänge abhängig ist, und dadurch, dass fotolumineszente Pigmente verwendet werden, die einen Reinheitsfaktor von 1 haben.
  10. Verfahren nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass jedes monochromatische Druckbild (8a, 8b, 8c) nach dem Drucken und vor dem Drucken eines anderen monochromatisches Druckbildes (8a, 8b, 8c) trocknen und/oder härten gelassen wird.
  11. Verfahren nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, dass zur Herstellung desselben Satzes von monochromatischen Druckbildern (8a, 8b, 8c) fotolumineszente Pigmente unter Beleuchtung durch ein und dieselbe Quelle (14) von unsichtbarem Licht verwendet werden.
  12. Verfahren nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, dass zum Erzeugen desselben Satzes von monochromatischen Druckbildern (8a, 8b, 8c) wenigstens ein erstes fotolumineszentes Pigment unter Beleuchtung durch wenigstens eine erste Quelle von unsichtbarem Licht und wenigstens ein zweites fotolumineszentes Pigment unter der Beleuchtung durch wenigstens eine zweite Quelle von unsichtbarem Licht mit (einer) anderen Wellenlänge(n) als der/denen der ersten Quelle von unsichtbarem Licht verwendet wird.
  13. Verfahren nach einem der Ansprüche 1 bis 12, dadurch gekennzeichnet, dass ein Satz von monochromatischen Druckbildern (8a, 8b, 8c) gedruckt wird, die positive Bilder eines Ausgangsbildes (1) sind, um durch additive Synthese ein Positiv des Ausgangsbildes (1) zu reproduzieren.
  14. Verfahren nach einem der Ansprüche 1 bis 13, dadurch gekennzeichnet, dass ein Satz von monochromatischen Druckbildern gedruckt wird, die negative Bilder eines Ausgangsbildes (1) sind, um durch additive Synthese ein Negativ des Ausgangsbildes (1) zu reproduzieren.
  15. Verfahren nach Anspruch 13 und 14, dadurch gekennzeichnet, dass ein erster Satz von monochromatischen positiven Druckbildern (8a, 8b, 8c) mit fotolumineszenten Pigmenten unter Beleuchtung durch eine erste Quelle von unsichtbarem Licht - insbesondere ultraviolett oder infrarot - gedruckt wird, und dadurch, dass ein zweiter Satz von monochromatischen negativen Druckbildern (8a, 8b, 8c) mit fotolumineszenten Pigmenten unter der Beleuchtung durch eine zweite Quelle von unsichtbarem Licht mit einer anderen Wellenlänge als der der ersten Quelle von unsichtbarem Licht - insbesondere infrarot oder ultraviolett - gedruckt wird.
  16. Verfahren nach Anspruch 15, dadurch gekennzeichnet, dass die Wellenlängen von Emissionspeaks von fotolumineszenten Pigmenten, die zum Drucken des ersten Satzes verwendet werden, wenigstens näherungsweise gleich den Wellenlängen von Emissionspeaks von fotolumineszenten Pigmenten sind, die zum Drucken des zweiten Satzes verwendet werden, so dass dieselben monochromatischen gefilterten Bilder (6a, 6b, 6c) zum Drucken der beiden Sätze dienen können.
  17. Verfahren nach einem der Ansprüche 13 bis 16, dadurch gekennzeichnet, dass darüber hinaus wenigstens ein Bild, Infrarotbild genannt, mit einer Druckzusammensetzung gedruckt wird, die wenigstens ein Pigment mit wenigstens einer Emissionspeak-Wellenlänge umfasst, die sich im Infrarotbereich befindet, aber keine Emission im Bereich des sichtbaren Lichts, wenn dieses Pigment durch Beleuchtung unter einer Quelle von sichtbarem Licht aktiviert wird.
  18. Verfahren nach einem der Ansprüche 1 bis 17, dadurch gekennzeichnet, dass zum Drucken jedes monochromatischen Druckbildes (8a, 8b, 8c) eine Druckzusammensetzung verwendet wird, die ein fotolumineszentes Pigment beinhaltet, die aber, wenigstens nach dem Trocknen, transparent oder für das sichtbare Licht transluzid ist, wenn es unter Beleuchtung durch die Quelle (14) von unsichtbarem Licht oder durch jede der Quellen von unsichtbarem Licht gelegt wird.
  19. Verfahren nach einem der Ansprüche 1 bis 18, dadurch gekennzeichnet, dass zum Drucken jedes monochromatischen Druckbildes (8a, 8b, 8c) eine Druckzusammensetzung verwendet wird, die, wenigstens nach dem Trocknen, transparent oder für das sichtbare Licht transluzid ist, wenn es unter Beleuchtung durch sichtbares Licht gelegt wird.
  20. Verfahren nach einem der Ansprüche 1 bis 19, dadurch gekennzeichnet, dass die monochromatischen Druckbilder (8a, 8b, 8c) durch Siebdruck gedruckt werden, dadurch, dass ein Siebdruckschirm hergestellt wird, ausgehend von jedem monochromatischen gefilterten Bild (6a, 6b, 6c), und die verschiedenen Siebdruckschirme auf der Basis desselben Gewebes erzeugt werden, und dadurch, dass eine Druckzusammensetzung verwendet wird, die von einem unter ultravioletten Strahlen polymerisierenden Siebdruckfirnis gebildet wird.
  21. Verfahren nach einem der Ansprüche 1 bis 20, dadurch gekennzeichnet, dass fotolumineszente Pigmente unter der Beleuchtung durch wenigstens eine Quelle (14) von unsichtbarem Licht verwendet wird, deren Spektralzusammensetzung im ultravioletten oder infraroten Bereich liegt.
EP99950811A 1998-10-23 1999-10-22 Verfahren zum herstellen eines mehrfarbigen fotolumineszierenden bildes, so hergestelltes bild und seine anwendungen Expired - Lifetime EP1042125B2 (de)

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FR9813307 1998-10-23
PCT/FR1999/002573 WO2000024587A1 (fr) 1998-10-23 1999-10-22 Procede de realisation d'une image polychromatique imprimee photoluminescente quelconque, image obtenue et applications

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ATE267710T1 (de) 2004-06-15
DE69917590T2 (de) 2005-02-03
US6494490B1 (en) 2002-12-17
ES2221448T3 (es) 2004-12-16
EP1042125A1 (de) 2000-10-11
FR2785061B1 (fr) 2000-12-15
DE69917590T3 (de) 2009-01-22
WO2000024587A1 (fr) 2000-05-04
FR2785061A1 (fr) 2000-04-28
CA2315354C (fr) 2009-08-11
ES2221448T5 (es) 2009-01-01
DE69917590D1 (de) 2004-07-01
EP1042125B1 (de) 2004-05-26
CA2315354A1 (fr) 2000-05-04

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