EP0946760B1 - Verfahren und vorrichtung zur erzeugung von siliziumreichen giessereiroheisen - Google Patents
Verfahren und vorrichtung zur erzeugung von siliziumreichen giessereiroheisen Download PDFInfo
- Publication number
- EP0946760B1 EP0946760B1 EP97918880A EP97918880A EP0946760B1 EP 0946760 B1 EP0946760 B1 EP 0946760B1 EP 97918880 A EP97918880 A EP 97918880A EP 97918880 A EP97918880 A EP 97918880A EP 0946760 B1 EP0946760 B1 EP 0946760B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- furnace
- vessel
- iron
- direct current
- sleeve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 18
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 9
- 239000010703 silicon Substances 0.000 title claims abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 41
- 229910052742 iron Inorganic materials 0.000 title claims description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims description 8
- 239000000463 material Substances 0.000 claims abstract description 24
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 11
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 iron-carbon metals Chemical class 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 229910000805 Pig iron Inorganic materials 0.000 claims abstract 2
- 238000007514 turning Methods 0.000 claims description 8
- 239000000969 carrier Substances 0.000 claims description 5
- 239000005028 tinplate Substances 0.000 claims 3
- YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 claims 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000209035 Ilex Species 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910005347 FeSi Inorganic materials 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/08—Manufacture of cast-iron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
- C21B13/023—Making spongy iron or liquid steel, by direct processes in shaft furnaces wherein iron or steel is obtained in a molten state
- C21B13/026—Making spongy iron or liquid steel, by direct processes in shaft furnaces wherein iron or steel is obtained in a molten state heated electrically
Definitions
- the invention relates to a method for producing silicon-rich Foundry iron and a direct current furnace with a centrally arranged ins Oven vessel protruding into the vicinity of the bottom and an electrode Counter electrode arranged in the bottom of the furnace vessel for carrying out the Procedure.
- Silicon-rich foundry iron is an alloy of iron, about 3% carbon and up to 20% silicon. It is melted in foundries, for example at one Silicon content of about 2.5% around centrifugal cast iron pipes for To manufacture water pipes.
- WO-A-94/10348 relates to the melting of scrap in a direct current furnace with a cathode 21 projecting centrally into the shaft furnace vessel 11 into the vicinity of the base and an anode 22 arranged in the base.
- the cathode 21 is surrounded by a coaxial tube 31 , whose lower section 34 narrows conically downwards (Fig. 1).
- Burners are arranged near the bottom of the vessel in order to melt the scrap used with the open flame in addition to the arc on the outer edge of the flat cross section.
- the aim of the invention is to provide a method and a corresponding device create the final alloy with simple means and inexpensively of the silicon-rich foundry iron is melted.
- the invention achieves this goal by the characterizing features of Process claim 1 and device claim 7.
- silicon oxides and ferrous carbon metals are proposed in a shaft furnace Ferrous materials such as scrap, sponge iron, briquetted sponge iron etc. and carbonaceous feedstocks to reduce silicon oxides and Charging carburizing, feeding the batch through a ring shaft, doing it to keep in a strongly reducing atmosphere and the radiation heat, especially by a transferring arc to melt.
- Ferrous materials such as scrap, sponge iron, briquetted sponge iron etc. and carbonaceous feedstocks to reduce silicon oxides and Charging carburizing, feeding the batch through a ring shaft, doing it to keep in a strongly reducing atmosphere and the radiation heat, especially by a transferring arc to melt.
- the melting process conducted by electrical energy is independent of the electrical conductivity of the feed materials as well as their bed angle. Furthermore, there are no special requirements for the size of the input materials posed. For example, scrap pieces can only be used be limited by the clear width of the ring shaft.
- the silicon oxides and independently of the normal material column come to this Material feed lances for use or a hollow electrode. This will make it possible, precisely metered amounts of silicon oxide of sufficiently fine grain size in melt as short as possible. This silicon oxide condenses further on relatively cold coal at the top of the shaft. It undergoes a transformation and is melted as the batch sinks further.
- a downhole furnace is used to carry out the process has an annular shaft, which has a combustion chamber, the under Consideration of the angle of repose of the feed throughout Process is kept free, so that the radiant heat to the material is unhindered can be transferred.
- the inner shaft is conical, so that the Feedstocks can be guided towards the furnace floor without hindrance.
- the ring shaft has a size that allows the feed materials to be melted down safely.
- a closed furnace vessel is used to carry out the method, in which maintains a strongly reducing atmosphere. This will make it possible to safely reduce the silicon oxide.
- the silicon content of the input materials can be up to 20%.
- Iron carriers are used: 80% scrap pieces, 10% turnings, 5% tin and 5% iron turnings.
- the iron carriers mentioned can in a further step by iron ore or Sponge iron to be replaced.
- a furnace vessel 11 is shown, the furnace bottom 12, in which a bottom opening 13 is provided. Furthermore, the in the furnace vessels shown in the figures have a gas vent 19.
- the electrode 21 corresponds to a counter electrode 22 provided in the bottom 13.
- the outer diameter of the sleeve is denoted by d and the inner diameter of the Oven vessel 11 with D,
- the sleeve surrounding the electrode is closed with a cover 15.
- the sleeve is conical, wherein it is at an angle ⁇ in Tapered towards the bottom of the furnace.
- feed means 31 provided, here on the conveyor belt 33, which can be loaded via a lock 32.
- the sleeve 14 can be displaced vertically by displacement elements 41. Furthermore, a lance 34 is provided in FIG. 2 as material supply means 31 the entry end of which is arranged a lock wheel 35. The lance 34 is also included connected to a pump 36 via which the supplied material can be conveyed pneumatically is.
- the sleeve 14 is enveloped by a double sleeve 17.
- the gap between the sleeves 14 and 17 is used as a material feed into which the batch Via conveyor 31, here a conveyor belt 33 is fed, which via a Lock 32 on the belt 33 is conveyable.
- a pump 36 is still on the feeder connected.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Silicon Compounds (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19632403A DE19632403C1 (de) | 1996-08-02 | 1996-08-02 | Verfahren und Vorrichtung zur Erzeugung von siliziumreichen Gießereiroheisen |
DE19632403 | 1996-08-02 | ||
PCT/DE1997/001609 WO1998005800A1 (de) | 1996-08-02 | 1997-07-25 | Verfahren und vorrichtung zur erzeugung von siliziumreichen giessereiroheisen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0946760A1 EP0946760A1 (de) | 1999-10-06 |
EP0946760B1 true EP0946760B1 (de) | 2001-08-29 |
Family
ID=7802379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97918880A Expired - Lifetime EP0946760B1 (de) | 1996-08-02 | 1997-07-25 | Verfahren und vorrichtung zur erzeugung von siliziumreichen giessereiroheisen |
Country Status (14)
Country | Link |
---|---|
US (1) | US6235075B1 (no) |
EP (1) | EP0946760B1 (no) |
AT (1) | ATE204915T1 (no) |
AU (1) | AU4293997A (no) |
BR (1) | BR9711010A (no) |
CA (1) | CA2262490C (no) |
CZ (1) | CZ34999A3 (no) |
DE (2) | DE19632403C1 (no) |
NO (1) | NO323393B1 (no) |
PL (1) | PL331421A1 (no) |
SK (1) | SK283573B6 (no) |
TW (1) | TW461921B (no) |
WO (1) | WO1998005800A1 (no) |
ZA (1) | ZA976825B (no) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19755890A1 (de) * | 1997-12-05 | 1999-06-17 | Mannesmann Ag | Beschickungseinrichtung für Schachtöfen |
DE10346337B4 (de) * | 2003-10-06 | 2014-06-12 | Schott Ag | Aggregat, ausgebildet als Schmelz- oder Läuteraggregat, Verteilersystem oder Rinnensystem für konduktiv beheizbare Glasschmelzen |
DE102004061944A1 (de) * | 2004-12-22 | 2006-07-06 | Polysius Ag | Verfahren und Vorrichtung zur Behandlung einer Schmelze oder Schlacke |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3985545A (en) | 1970-09-24 | 1976-10-12 | Sadamu Kinoshita | Metal melting method using electric arc furnace |
DE2342959B1 (de) * | 1973-08-25 | 1975-02-13 | Kloeckner Werke Ag | Vorrichtung zur kontinuierlichen Erzeugung von Stahl aus Erz |
AUPM792594A0 (en) | 1994-09-05 | 1994-09-29 | Illawarra Technology Corporation Limited, The | Smelting ferrous materials |
DE4236510C2 (de) * | 1992-10-26 | 1996-05-30 | Mannesmann Ag | Vorrichtung zum Einschmelzen von Schrott |
US5588982A (en) * | 1995-05-01 | 1996-12-31 | Alabama Power Company | Process for producing foudry iron |
-
1996
- 1996-08-02 DE DE19632403A patent/DE19632403C1/de not_active Expired - Fee Related
-
1997
- 1997-07-25 BR BR9711010A patent/BR9711010A/pt not_active IP Right Cessation
- 1997-07-25 AU AU42939/97A patent/AU4293997A/en not_active Abandoned
- 1997-07-25 WO PCT/DE1997/001609 patent/WO1998005800A1/de not_active Application Discontinuation
- 1997-07-25 CA CA002262490A patent/CA2262490C/en not_active Expired - Lifetime
- 1997-07-25 US US09/011,416 patent/US6235075B1/en not_active Expired - Lifetime
- 1997-07-25 DE DE59704480T patent/DE59704480D1/de not_active Expired - Lifetime
- 1997-07-25 CZ CZ99349A patent/CZ34999A3/cs unknown
- 1997-07-25 SK SK128-99A patent/SK283573B6/sk unknown
- 1997-07-25 AT AT97918880T patent/ATE204915T1/de active
- 1997-07-25 EP EP97918880A patent/EP0946760B1/de not_active Expired - Lifetime
- 1997-07-25 PL PL97331421A patent/PL331421A1/xx unknown
- 1997-07-31 ZA ZA9706825A patent/ZA976825B/xx unknown
- 1997-08-01 TW TW086111021A patent/TW461921B/zh not_active IP Right Cessation
-
1999
- 1999-01-29 NO NO19990439A patent/NO323393B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US6235075B1 (en) | 2001-05-22 |
DE59704480D1 (de) | 2001-10-04 |
AU4293997A (en) | 1998-02-25 |
ATE204915T1 (de) | 2001-09-15 |
CA2262490C (en) | 2008-10-14 |
SK283573B6 (sk) | 2003-09-11 |
NO323393B1 (no) | 2007-04-23 |
BR9711010A (pt) | 1999-08-17 |
WO1998005800A1 (de) | 1998-02-12 |
EP0946760A1 (de) | 1999-10-06 |
NO990439L (no) | 1999-01-29 |
ZA976825B (en) | 1998-02-11 |
PL331421A1 (en) | 1999-07-19 |
CZ34999A3 (cs) | 1999-05-12 |
DE19632403C1 (de) | 1998-03-26 |
TW461921B (en) | 2001-11-01 |
CA2262490A1 (en) | 1998-02-12 |
SK12899A3 (en) | 1999-07-12 |
NO990439D0 (no) | 1999-01-29 |
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