EP0944700A2 - Detergents for universal and special cleaning operations - Google Patents
Detergents for universal and special cleaning operationsInfo
- Publication number
- EP0944700A2 EP0944700A2 EP97951784A EP97951784A EP0944700A2 EP 0944700 A2 EP0944700 A2 EP 0944700A2 EP 97951784 A EP97951784 A EP 97951784A EP 97951784 A EP97951784 A EP 97951784A EP 0944700 A2 EP0944700 A2 EP 0944700A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- module
- water
- cleaning
- solubilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the invention reports on a group of chemical products, which are used for cleaning objects made of metal, wood, plastic etc. as well as masonry, doors, wall and floor tiles etc. and thus due to their modular structure for both universal and special cleaning tasks can be used.
- Such a cleaner for dishes, glasses, tiles and objects made of plastic in the patent specification RO 109753 consisting of: 10 - 30% sodium or potassium salt of the monoester of sulfosuccinic acid with alkyl polyglycol ether or alkylphenol polyglycol ether, 2 - 8% sodium, potassium, Diethanolamine or triethanolamine salt of the monoester of maleic acid with alkyl polyglycol ether or alkylphenol polyglycol ether, 2-6% polyethylene fumarate or polydiethylene fumarate, 2-6% nonionic surfactant of the type nonylphenol polyethoxylate or alcohol polyethoxylate, 3 - 6% harp, 3 - 6% harp, 3 - 6% harp, 3 - 6% 1 - 4% citric acid or tartronic acid, 2 - 6% ethyl alcohol or isopropyl alcohol, 0.1 - 0.8 formaldehyde, 1 - 3%
- a similar solution for cleaning and degreasing metals contains 1-10% by weight of trisodium phosphate, sodium carbonate, sodium silicate, 1-5% by weight of nonylphenol polyethoxylate, octylphenol polyethoxylate, sodium alkylarylsulfonate, as non-ionic and ionic surface-active substances, 1% by weight of a mixture of organic polymer with reduced molecular weight and the salt of a dibasic acid as a corrosion inhibitor, 75-95% by weight of demineralized water as a solvent. (Patent specification RO 110259).
- Another liquid product for cleaning dishes and hard surfaces contains fatty alcohol (C10-C14) ethoxylate with 2-4 moles of ethylene oxide and the corresponding sulfates, sodium or potassium alkylbenzenesulfonate, nonylphenol ethoxylate with 8-12 moles of ethylene oxide, sodium citrate, sodium chloride, coconut fatty acid diethanolamide, Sodium triphosphate, ethylenediaminetetraacetic acid, perfume, dye and water (patent document RO 106582).
- the known products have a specific determination with regard to the use or the materials for cleaning, they are not intended for universal use. The majority contain substances that have an undesirable effect on the environment.
- the problem solved by the invention is to be reduced by a new composition of cleaning agents and fixed proportions between the constituents, their number and thus at the same time the pollution of the environment with harmful substances.
- the products according to the invention have in their composition alkylbenzenesulfonate, fatty alcohol ethoxylate, fatty alcohol alkoxylate and complexing agents, and consist of an anion module, which contains 5-15% by weight of alkyl (C12) benzenesulfonate dissolved in water, a nonionic module Which contains 10-20% by weight of fatty alcohol ethoxylate, 5-10% by weight of fatty alcohol alkoxylate and 0-0.2% by weight of complexing agent in demineralized Contains water dissolved, a solubilizer module from 45 - 100 wt.% Dipropylene glycol and 0 - 55 wt.% Diethanolamine.
- the proportion of the modules in the respective cleaning concentrate is at least 96%, the remaining composition to 100% by weight is supplemented with substances specific to the respective application, such as, for example, an anti-corrosive and / or fragrance.
- the universal cleaners consist of 26-27.5% by weight of anion module, 60% by weight of nonionic module, 10% by weight of solubilizer module, 2.5-4% by weight of fragrance and the rest 100%.
- % Water preferably demineralized.
- the metal surface cleaners consist of 27 - 35% by weight of anion module, 55 - 63% by weight of nonionic module, -9.8 - 9.95% by weight of solubilizer module, 0.05
- the cleaners for plastic surfaces each consist of 10% by weight of anion module, nonionic module and solubilizer module and 0.4-1% by weight of fragrance and the rest to 100% by weight of water, preferably demineralized.
- the cleaners for jewelry and jewels each consist of 10% by weight of anion module, nonionic module and solubilizer module, 0.02% by weight of anticorrosive and 0.4-1% by weight of fragrance and the rest 100% by weight. Water, preferably demineralized.
- Example 1 5-15% by weight of alkyl (C12) benzenesulfonate is dissolved in demineralized water at 30-40 ° C. until the solution appears clear. This solution results in the anion module. Separately, 0-0.2% by weight of complexing agent, preferably ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), o- (carboxymethyl) malic acid or poly (tetramethylene-1,2-dicarboxylic acid), 10-20, are separated from this in demineralized water %
- fatty alcohol ethoxylate preferably C10 with 5 moles of ethylene oxide or 3-7 moles of ethylene oxide
- the remaining 100% by weight is demineralized water.
- the solution is stirred until it appears clear.
- This solution is the nonionic module. 1-55% by weight diethanolamine or triethanolamine are stirred into 99-45% by weight dipropylene glycol until a clear solution is obtained.
- This solution is the solubilizer module, but can also consist of 100% by weight exclusively of dipropylene glycol.
- Example 2 Anion module, nonionic module and solubilizer module are produced as described in Example 1. 27-35% by weight of anion module, 55-63% by weight of nonionic module, 9.8-9.95% by weight of solubilizer module and 0.05-0.2% by weight of an anti-corrosive are mixed and made up to 100% with demineralized water .% added.
- This concentrate is used to clean metallic surfaces (including aluminum). Thanks to the built-in corrosion inhibitor, the concentrate can also be used in warm (pH-neutral) metal baths.
- the preparation of the cleaning solution depends on the respective application.
- 1 part of the concentrate When used as a cold cleaner, 1 part of the concentrate is stirred into 1, 2 or 4 parts of water (for oil and fat-containing impurities, concentration depending on the degree of contamination), when used as a warm cleaner, 1 part of the concentrate is stirred into 4 - 19 parts of water .
- the cleaning solution prepared in this way is applied (or sprayed on) to the surface to be cleaned or the parts to be cleaned are placed in the cleaning solution. After the exposure time (depending on the degree of soiling and the method of application (cold / warm)), rinse with water ("rinse off").
- the cleaning solution When used as a pressure washer, 1 part of the concentrate is stirred into 19 - 49 parts of water.
- the cleaning solution is made according to the manufacturer's instructions. of the high-pressure cleaner and applied.
- the cleaning solution (cold cleaner) is applied to the surface to be cleaned. After the exposure time (depending on the degree of contamination) with the high-pressure cleaner solution (usually a concentration of 1:49 is sufficient), proceed according to the instructions of the manufacturer of the high-pressure cleaner (corresponding to the single-phase cleaning).
- Example 3 Anion module, nonionic module and solubilizer module are produced as described in Example 1. 10% by weight of anion module, nonionic module and solubilizer module are mixed with 0.4-1% by weight of fragrance oil and made up to 100% by weight with demineralized water.
- This special cleaning solution is used to remove dirt, oil and grease residues on polymer-coated housings of computers, monitors, printers and other peripheral devices in the IT industry. The cleaning solution is either sprayed onto the surface to be cleaned using a commercially available pump atomizer or applied to the surface to be cleaned using a cotton cloth which is moistened with the solution. Both methods should cover the area as completely as possible. After a short exposure time (usually and with normal soiling approx. 6 to 10 seconds), the surface is wiped dry with a dry cotton cloth in the second cleaning step. No further cleaning steps are required.
- Example 4 Anion module, nonionic module and solubilizer module are produced as described in Example 1. 10% by weight of anion module, nonionic module and solubilizer module are mixed with 0.02% by weight of anti-corrosive and 0.4-1% by weight of fragrance oil and made up to 100% by weight with demineralized water. This special cleaning solution is used to remove dirt and grease residues from jewelry, jewels and fashion jewelry. Also suitable for cleaning metal watch straps (for waterproof watches) and for use in ultrasonic baths (for jewelers). The jewelry to be cleaned is placed in the cleaning solution.
- the jewelry can be removed from the cleaning solution, rinsed under running water and dried with a cotton cloth (or with a weak air flow (hair dryer)). As a rule, no further cleaning steps are required.
- Table 1 summarizes the modules that form the basis of the products according to the invention.
- Table 2 shows examples of cleaning products for universal and special applications according to the invention.
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RO96-02184A RO112759B1 (en) | 1996-11-20 | 1996-11-20 | Cleaning products for special and universal application |
RO9602184 | 1996-11-20 | ||
PCT/DE1997/002714 WO1998022563A2 (en) | 1996-11-20 | 1997-11-20 | Detergents for universal and special cleaning operations |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0944700A2 true EP0944700A2 (en) | 1999-09-29 |
EP0944700B1 EP0944700B1 (en) | 2001-01-17 |
Family
ID=20104165
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97951784A Expired - Lifetime EP0944700B1 (en) | 1996-11-20 | 1997-11-20 | Detergents for universal and special cleaning operations |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0944700B1 (en) |
AT (1) | ATE198761T1 (en) |
DE (1) | DE59702938D1 (en) |
RO (1) | RO112759B1 (en) |
WO (1) | WO1998022563A2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10357389B4 (en) * | 2003-12-07 | 2005-12-15 | Benda, Jürgen Michael | Process for cleaning soapstone |
EP2177599A1 (en) * | 2008-10-16 | 2010-04-21 | KH LLoreda, S.A. | Jewellery cleaner, procedure and cleaning kit |
DE102016225904A1 (en) * | 2016-12-21 | 2018-06-21 | Henkel Ag & Co. Kgaa | rinse aid |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH525949A (en) * | 1970-07-15 | 1972-07-31 | Clari Ferdinando | Liquid composition with high detergent power, suitable for cleaning jewels and other objects, in gold or precious metals, or precious stones |
JPS5586894A (en) * | 1978-12-25 | 1980-07-01 | Kao Corp | Liquid detergent composition |
SU1147740A1 (en) * | 1983-05-27 | 1985-03-30 | Уральский филиал Всесоюзного научно-исследовательского и проектного института химической промышленности | Agent for cleaning hard surface |
JPS6051794A (en) * | 1983-08-31 | 1985-03-23 | ライオン株式会社 | Liquid detergent composition |
AU627734B2 (en) * | 1988-06-13 | 1992-09-03 | Colgate-Palmolive Company, The | Stable and homogeneous concentrated all purpose cleaner |
JP2899784B2 (en) * | 1994-05-13 | 1999-06-02 | 第一工業製薬株式会社 | Detergent composition |
-
1996
- 1996-11-20 RO RO96-02184A patent/RO112759B1/en unknown
-
1997
- 1997-11-20 DE DE59702938T patent/DE59702938D1/en not_active Expired - Fee Related
- 1997-11-20 WO PCT/DE1997/002714 patent/WO1998022563A2/en active IP Right Grant
- 1997-11-20 EP EP97951784A patent/EP0944700B1/en not_active Expired - Lifetime
- 1997-11-20 AT AT97951784T patent/ATE198761T1/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO9822563A3 * |
Also Published As
Publication number | Publication date |
---|---|
DE59702938D1 (en) | 2001-02-22 |
WO1998022563A2 (en) | 1998-05-28 |
RO112759B1 (en) | 1997-12-30 |
EP0944700B1 (en) | 2001-01-17 |
WO1998022563A3 (en) | 1998-07-23 |
ATE198761T1 (en) | 2001-02-15 |
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