EP0912422A1 - Langreitsstabilisierung von getränk - Google Patents

Langreitsstabilisierung von getränk

Info

Publication number
EP0912422A1
EP0912422A1 EP97930555A EP97930555A EP0912422A1 EP 0912422 A1 EP0912422 A1 EP 0912422A1 EP 97930555 A EP97930555 A EP 97930555A EP 97930555 A EP97930555 A EP 97930555A EP 0912422 A1 EP0912422 A1 EP 0912422A1
Authority
EP
European Patent Office
Prior art keywords
packaging
terpolymer
alcoholic
anethole
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97930555A
Other languages
English (en)
French (fr)
Other versions
EP0912422B1 (de
Inventor
Patrice Robichon
Philippe Noble
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pernod Ricard SA
Original Assignee
Pernod Ricard SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pernod Ricard SA filed Critical Pernod Ricard SA
Publication of EP0912422A1 publication Critical patent/EP0912422A1/de
Application granted granted Critical
Publication of EP0912422B1 publication Critical patent/EP0912422B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • B65D1/0207—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/72—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for edible or potable liquids, semiliquids, or plastic or pasty materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]

Definitions

  • the present invention relates to a new monolayer or multilayer packaging, of long duration, containing an aqueous beverage, alcoholic or not, based on anethole.
  • It also relates to a process intended to limit the loss of anethole contained in an optionally alcoholic solution in contact with the wall of a package, as well as the use of a polymer film for producing a package in contact with possibly alcoholic anethole solutions, in order to limit the loss of anethole in contact with the packaging wall.
  • Aniseed drinks contain anethole or para propenyl methoxy benzene, in the majority trans form (greater than 96-97%) Anethole has the particularity of being very slightly soluble in water ( ⁇ 50 mg / 1) and soluble in alcohol. In the presence of water, the anethole becomes cloudy, whereas in a water / alcohol solution with a high alcohol content (of the order of 45% by volume), the anethole remains in the solubilized state. In the case of alcohol-free or low-alcohol drinks (4-9
  • an emulsifier is used because the anethole is no longer soluble.
  • Anethole has a low coefficient of solubility in water but a high coefficient of solubility in alcohols. This phenomenon is all the more important for drinks with little or no alcohol. This induces a significant electrostatic interaction with the surface of the polymer and the adsorption of anethole thereon. Furthermore, the affinity of anethole for polymers is such that an absorption phenomenon occurs, by insertion of this compound between the chains of the polymer. It is therefore a dynamic phenomenon of adsorption / ab sorption.
  • Anethole also reveals a strong propensity to polymerize polyanethole.
  • This canonical type polymerization is favored by the very electron-donating nature of the methox group>. This phenomenon occurs in particular in the case of polymers derived from styrene, maleic anhydride or acrylonitrile commonly used in tan t quu packaging for beverages. This is due to the fact that anethole reacts to the molecular chains of these polymers.
  • anethole can also react with residual monomers, given the well known copolymerization reaction.
  • ec styrene T. Higashimura et al, Journal of Polymer Science: part A. l, vol.10,85-93 (1972)
  • maleic anhydride and acrylic monomers such as acrylonitrile
  • the invention firstly relates to a long-lasting single-layer or multi-layer packaging for an optionally alcoholic drink comprising anethole, characterized in that the layer in contact with said drink is formed of a terpolymer methyl acrylate-acrylonitrile-butadiene
  • packaging means any packaging capable of containing said drink, whether in the form of a bottle, box or other equivalent closed systems, including bottles and pouches.
  • shelf life is at least 6 months.
  • concept of packaging also extends to the means for sealing and sealing the various containers mentioned above.
  • the present invention relates in particular to sealing means for any packaging intended to contain an anethole-based drink.
  • Such a sealing means is advantageously for ⁇ u an internal film formed of a film of meths acrylate terpolymer acrylonitrile-butadiene coming into application on the opening dudn packaging. It may in particular consist of a capsule c> hndr ⁇ que inside which is housed an internal film formed of a film of methyl acrylate-acrylonitrile-butadiene terpolymer coming into application on the opening of said packaging.
  • the packaging has been found to be particularly advantageous in the case of non-alcoholic or low-alcoholic drinks, the alcohol content of which is preferably less than 10% in olume, preferably between 3 and 9%.
  • the aqueous alcoholic or non-alcoholic drink comprises from 0.01 to 2 g / 1 of anethole, preferably 0.02 g / 1 or more of anethole.
  • the anethole concentration is of the order of 2 g / 1.
  • ready-to-drink alcoholic beverages it is around 200 to 400 mg / 1.
  • anise flavored drinks it is of the order of 10 to 50 mg / 1.
  • the terpolymer has a content of butadiene comp ⁇ s between 8 and 20%.
  • the terpolymer is chosen from the group consisting of the terpolymer whose level of butadiene is approximately 10% or the terpolymer whose level of butadiene is approximately 18%.
  • Barex 210 R and Barex 21 8 B These polymers are sold by BP Chemicals under the brand names, respectively Barex 210 R and Barex 21 8 B. Barex 210 F polymer has an oxygen permeability of
  • Barex 2181 'polymer has an oxygen permeability of 0.6 cm3.mm/m 2 .day.bar at 23 "C.
  • the films formed of a methyl acrylate-acrylonitrile-butadiene terpolymer must have sufficient impermeability with respect to carbon dioxide. They must also have a tear strength and a modulus of elasticity sufficient for the application considered.
  • the packaging can be in the form of a monolayer or in the multilayer form.
  • the internal layer is formed from a film of methyl acrylate-acrylonitrile-butadiene terpolymer.
  • the film is associated with a structural material, itself possibly multilayer (metal, cardboard, mono or multilayer polymeric material).
  • the thickness of the terpolymer layer may vary significantly depending on whether the packaging is monolayer or multilayer. It will preferably be between 200 and 500 ⁇ m, advantageously between 300 and 400 ⁇ m, but may go down to 50 ⁇ m for films and go up to
  • the packaging therefore takes the form of a monolayer or multilayer material obtained by extrusion.
  • the packaging according to the invention can keep an anethole-based drink, in particular low or non-alcoholic, under the same conditions as a glass bottle, that is to say without substantial degradation of the organoleptic qualities. They are moreover transparent in the case of monolayer packaging or multilayer packaging where the structural layers are transparent, easy to transform and inexpensive.
  • the invention also relates to a sealing means in particular for said packages provided with an internal film of anethole impermeable material in particular of a polymer formed of a methyl acrylate-acrylonitrile-butadiene terpolymer coming into application on said packages .
  • This sealing means is in particular a cylindrical capsule inside which is housed an internal film of a polymer as defined above.
  • Figure 1 There is shown in Figure 1 attached a bottle, ⁇ ue in longitudinal section, wherein the bottle 1 formed of a cylindrical body 2, a neck 3 and a bottom 4 is made of a polymeric material in terpolymer methyl acrylate-acrylonitrile-butadiene.
  • the bottle has a thickness of 0.2 mm at the cylindrical body and 0.6 mm at the bottom.
  • the capsule 5 is formed of a cylindrical body 6 and a circular base 7. Inside the capsule 5 is housed a disc 8 formed of a layer of methyl acrylate-acrylonitrile-butadiene terpolymer 8 applied to the inner face of the base and a layer of methyl acrylate-acrylonitrile-butadiene terpolymer 9 bearing on the neck 3.
  • the invention also relates to the use of a methyl acrylate-acrylonitrile-butadiene terpolymer, as described above for the production of a monolayer or multilayer packaging, intended to contain beverages based on anethole which may be alcoholic in order to limit degradation thereof, said terpolymer forming the layer in contact with said drinks.
  • It also relates to a process intended to limit the degradation of anethole-based drinks, in particular low or non-alcoholic drinks, characterized in that said drinks are stored in a long-lasting single-layer or multi-layer package, the layer of which is in contact with said drinks consists of a terpolymer methyl linkage-acrylonitrile-butadiene as defined above.
  • Bottles consisting of a Barex 218 K monolayer sold by the company BP Chemicals, with an average thickness of 350 ⁇ m, were produced by transformation on a two-orientation blow molding machine for PVC.
  • the bottles are filled cold in the presence of a bacteriostatic, of an aniseed non-alcoholic solution containing 400 mg / 1 of anethole, then are left 12 months at 20 ° C.
  • the loss of anethole is evaluated periodically. It is found that after 9 months, the loss of anethole is 25% and that after one year, it is 28%. We therefore observe a plateau from 9 months, the loss of anethole having changed little since this term.
  • Bottles formed from polyethylene terephthalate are filled with the same solution as that of Example 1 and are left for 12 months at 20 ° C.
  • the loss of anethole is evaluated periodically. It is found that after 6 months, the loss is 92% and 100% after 12 months.
  • Example 2 An example similar to Example 1 was carried out with polyethylene bottles sold by the company Pampr ⁇ l (France) for fruit juices and with polypropylene bottles. After 6 months there is a loss greater than 90% and 100% after 12 months.
  • Example 4 (comparative) An example similar to Example 3 with a PVC bottle is made.

Landscapes

  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Wrappers (AREA)
  • Laminated Bodies (AREA)
  • Packages (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
  • Tea And Coffee (AREA)
  • Thermally Insulated Containers For Foods (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
EP97930555A 1996-06-21 1997-06-19 Langzeitbehälter für ein anetholhaltiges getränk Expired - Lifetime EP0912422B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9607742 1996-06-21
FR9607742A FR2750116B1 (fr) 1996-06-21 1996-06-21 Conditionnement de longue duree en matiere polymere pour boisson a base d'anethole et procede destine a limiter la deperdition d'anethole contenu dans une solution
PCT/FR1997/001102 WO1997049621A1 (fr) 1996-06-21 1997-06-19 Conditionnement de longue duree pour boisson

Publications (2)

Publication Number Publication Date
EP0912422A1 true EP0912422A1 (de) 1999-05-06
EP0912422B1 EP0912422B1 (de) 2000-08-23

Family

ID=9493299

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97930555A Expired - Lifetime EP0912422B1 (de) 1996-06-21 1997-06-19 Langzeitbehälter für ein anetholhaltiges getränk

Country Status (13)

Country Link
US (1) US5908678A (de)
EP (1) EP0912422B1 (de)
JP (1) JP2000512602A (de)
AT (1) ATE195700T1 (de)
AU (1) AU3446897A (de)
CA (1) CA2259451C (de)
DE (1) DE69702916T2 (de)
DK (1) DK0912422T3 (de)
ES (1) ES2150264T3 (de)
FR (1) FR2750116B1 (de)
GR (1) GR3034878T3 (de)
PT (1) PT912422E (de)
WO (1) WO1997049621A1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2752565B1 (fr) * 1996-08-21 1998-11-13 Pernod Ricard Conditionnement pour boisson a base d'anethole constitue au moins en partie d'un polymere comprenant des motifs aromatiques condenses
US20170252993A1 (en) * 2016-03-03 2017-09-07 Juicero, Inc. Juicer cartridge with coupling

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03187832A (ja) * 1989-12-15 1991-08-15 Mitsui Toatsu Chem Inc 透明容器

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9749621A1 *

Also Published As

Publication number Publication date
CA2259451C (fr) 2007-12-11
WO1997049621A1 (fr) 1997-12-31
FR2750116B1 (fr) 1998-09-11
DE69702916D1 (de) 2000-09-28
FR2750116A1 (fr) 1997-12-26
EP0912422B1 (de) 2000-08-23
JP2000512602A (ja) 2000-09-26
US5908678A (en) 1999-06-01
ES2150264T3 (es) 2000-11-16
AU3446897A (en) 1998-01-14
ATE195700T1 (de) 2000-09-15
CA2259451A1 (fr) 1997-12-31
DK0912422T3 (da) 2000-12-18
PT912422E (pt) 2000-12-29
DE69702916T2 (de) 2001-03-29
GR3034878T3 (en) 2001-02-28

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