EP0896556B1 - Mehrschichtiges, flexibles übertragungsband - Google Patents
Mehrschichtiges, flexibles übertragungsband Download PDFInfo
- Publication number
- EP0896556B1 EP0896556B1 EP97906154A EP97906154A EP0896556B1 EP 0896556 B1 EP0896556 B1 EP 0896556B1 EP 97906154 A EP97906154 A EP 97906154A EP 97906154 A EP97906154 A EP 97906154A EP 0896556 B1 EP0896556 B1 EP 0896556B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- sensitive adhesive
- pressure
- white
- transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J29/00—Details of, or accessories for, typewriters or selective printing mechanisms not otherwise provided for
- B41J29/26—Devices, non-fluid media or methods for cancelling, correcting errors, underscoring or ruling
- B41J29/36—Devices, non-fluid media or methods for cancelling, correcting errors, underscoring or ruling for cancelling or correcting errors by overprinting
- B41J29/367—Devices, non-fluid media or methods for cancelling, correcting errors, underscoring or ruling for cancelling or correcting errors by overprinting sheet media carrying a pigmented transferable correction layer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
- Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
Definitions
- the invention relates to a multilayer, flexible transmission belt with a Subcarrier and a pressure sensitive adhesive layer, between the subcarrier and the Pressure-sensitive adhesive layer is a binder-containing white pigmented transfer layer which is used for PSA layer has a stronger adhesion than to the auxiliary carrier, is present, as well as the Use of this transfer tape in rolled up form in a handheld device.
- a transmission band of the above type is shown in EP-A-0 318 804. After that it is preferably used in a handheld device in a rolled up form so that it is easy to quickly and evenly apply the transfer layer to a substrate in order to to cover incorrect characters in texts or illustrations and then Make corrections.
- the applied transfer layer can then for example with ink or India ink.
- the white-pigmented one Transfer layer by incorporating black pigments, especially carbon black, is tinted.
- This tinting makes the transfer layer opaque improved.
- there are limits to this tinting as far as too high Proportion of black pigment the white appearance is impaired or one can no longer speak of a white transmission layer. All in all is not satisfied with this solution.
- the invention was therefore based on the object, the above To further develop the transmission tape so that when used, the Opacity of the transfer layer is improved without the "whiteness" is strong is affected.
- the multilayer, flexible transmission band according to the invention accordingly comprises three configurations.
- the configuration is preferred in which Pressure-sensitive adhesive layer b) the non-white pigment is finely dispersed. If in individual cases Supervision of the pressure-sensitive adhesive layer, the dark impression of which is undesirable, in particular if the non-white pigment is a black pigment such as carbon black, then it is advantageous to use one of the two variants of the configuration a).
- FIG. 1 shows a prior art transmission belt with an auxiliary carrier (1), a transfer layer (2) and a pressure sensitive adhesive layer (3).
- FIG. 2 is an illustration of a transmission tape according to the invention according to the Design a1). Between the white pigmented transfer layer (2) and the Pressure sensitive adhesive layer (3) is a plastic-bound intermediate layer (4), which in contains a non-white pigment.
- FIG. 3 shows a transmission band according to the invention in the configuration a2), in which sandwiches the non-white pigmented plastic-bound intermediate layer from the white pigmented transfer layer, i.e. the non-white pigmented Intermediate layer (4) is located between the transfer layer (2) and an additional layer (2A), which have an identical composition.
- the additional layer (2A) is responsible for the dark color printing of the intermediate layer (4). when overseeing a translucent PSA layer.
- FIG. 4 shows an inventive transmission band according to embodiment b), at that in the PSA layer (3A) is a non-white pigment in a finely dispersed distribution is included.
- non-white pigment is used in the context of the invention, then this should preferably be one which is largely similar to the symbols to be covered, in particular characters. These are regularly blue, black, red or green. In general, the yellow hue will therefore have to be excluded. Black pigments, in particular carbon black, are particularly preferred in practical applications.
- the particle size of the pigments is not critical in itself. However, a particle size of approximately 1.5 to 0.005 ⁇ m , in particular less than approximately 1 ⁇ m, up to a colloidal particle size is preferred.
- finely divided metal powders such as, in particular, finely divided aluminum.
- the aluminum particles are preferably platelet-shaped and preferably have a thickness of approximately 3 to 10 ⁇ m .
- the linear expansion can easily be up to about 15 ⁇ m .
- Water-based aluminum pastes have proven particularly suitable. Such aluminum pastes are produced using a special wet grinding process. A particularly preferred paste is commercially available from Carl Schlenk AG under the name Aquasilber aluminum paste LPW / 1380.
- the intermediate layer and / or the pressure-sensitive adhesive layer preferably contains at least about 0.1% by weight of non-white pigment, in particular about 0.1 to 5% by weight, and particularly preferably about 0.2 to 3.5% by weight, non-white pigment. Will the crowd less than 0.1% by weight of non-white pigments in both layers falls below, then the desired effect is not to the desired extent achieve. However, if the amount of 5% by weight is exceeded, none will be significant improvement achieved more. Exceeding can also e.g. in the Connection with the pressure-sensitive adhesive layer leads to its adhesive ability is affected. To preserve the functional requirements, there should be a value here of about 3.5 are not exceeded.
- the transfer layer is "white pigmented".
- white pigmented means that it contains the usual white pigments in the required amount in order to To impart a certain opacity to the transfer layer.
- These include in particular Titanium dioxide (titanium white), as well as precipitated chalk, clay and / or colloidal Silicas. In the context of the invention, this does not preclude them from being additionally suitable different colored pigments is tinted.
- This tinting can be done by Incorporation of suitable amounts of black pigment, especially carbon black, but also by tinting with other pigments, for example yellow and green.
- This Tinting may be required if there is a color match to the substrate Characters etc. should be covered, must be done.
- the comments on Particle size made in connection with the "non-white pigments" apply here accordingly.
- the choice of the respective Binder to form the transfer layer also the type of used plasticizer are considered. This should be when applying the Transfer layer on the area to be corrected or covered not by the normally thinly formed PSA layer penetrate and with the correcting point or the colorants located there and in this way cause an undesirable coloring of the transfer layer.
- plasticizers such as silicone, castor and mineral oils serve this purpose suitable.
- plasticizers such as for example phthalic acid esters or oleic alcohol are not equally good suitable.
- the binder-containing transfer layer can be a so-called "Laking agent” are incorporated, the possibly migrating colorant fails or insoluble, so that it does not enter the applied transfer layer migrate and color them again.
- Suitable varnishes are tannin and Tannin derivatives.
- varnish can be used, which in Inks and inks are included. They should preferably be in an amount of about 0.5 to 5 wt .-%, in particular about 1.5 to 3.5 wt .-% in the binder-containing Transfer layer are present, the range from about 2 to 2.5 wt .-% whole is particularly preferred.
- the binder selected in each case is used to form the transfer layer preferably as an aqueous solution or dispersion.
- the additives discussed below added are discussed below added.
- the choice of the appropriate solvent or dispersant depends on the type of binder used. For this include in particular low to medium-boiling organic solvents from the group of Alcohols such as ethanol, isopropanol and butanol, the ketones such as acetone and Methyl ethyl ketone, the ester, such as methyl and ethyl acetate, the aromatic Hydrocarbons such as toluene, the aliphatic hydrocarbons such as gasoline Boiling range from 70 to 140 ° C, alone or in a mixture, but especially water, alone or in a mixture with low-boiling, water-soluble organic solvents.
- the concentration of the binder in the solution or dispersion is not essential to the invention.
- a rough guideline can be that it is between about 3 and 15% by weight, with the range of about 6 to 12% by weight being preferred.
- the solution or dispersion is preferably applied to the auxiliary carrier in an amount of about 15 to 25 g / m 2 (dry weight) and very particularly preferably between about 18 and 22 g / m 2 .
- cellulose derivatives are those in organic solvents and / or water-soluble cellulose ethers, such as methyl, ethyl, Hydroxyethyl, ethylhydroxyethyl and carboxymethyl celluloses, cellulose esters, such as Cellulose Acetobutyrate and Propionate.
- cellulose esters such as Cellulose Acetobutyrate and Propionate.
- Suitable cellulose derivatives that produce the desired effects. Apparently it is Cellulose backbone important in the soluble cellulose derivative, while by the Cellulose modification introduced groups only to increase the solubility in the lead selected solvent.
- the pressure sensitive adhesive layer can consist of commercially available pressure sensitive adhesives. These are elastic and permanently adhesive self-adhesive compositions with great adhesive forces that adhere immediately to the various surfaces even under low pressure at room temperature. They are preferably applied in aqueous dispersion to the transfer layer and, if appropriate, the intermediate layer already on the auxiliary carrier, since the layers already formed are not dissolved again. Among pressure-sensitive adhesives of this type, those based on acrylate are particularly advantageous.
- the starting materials can be viscous solutions and dispersions based on rubber, polyacrylates, polyvinyl ethers or polyvinyl isobutylene. Commercial materials based on polyacrylates are preferred.
- Suitable commercial products are Ucecryl 913 and Ucecryl PC 80 (sold by ucb Dogenbos, Belgium) and the plastic dispersion VP 959/6 (sold by Freihoff).
- the pressure-sensitive adhesive to be applied which is initially present in an aqueous medium, preferably contains wetting agents or surfactants (sold under the trade name Byk W).
- a non-white pigment in a finely dispersed distribution is included in the solution or dispersion of the pressure sensitive adhesive to be applied.
- the dispersion / solution of the pressure-sensitive adhesive is preferably used to form the pressure-sensitive adhesive layer in an amount of about 1 to 5 g / m 2 (dry weight) and very particularly preferably in an amount of about 2 to 4 g / m 2 Transfer layer or additional layer applied.
- the pressure-sensitive adhesive layer is preferably approximately 1 to 5 ⁇ m , in particular approximately 2 to 4 ⁇ m thick.
- the same framework applies to the above-mentioned plastic-bonded intermediate layer after configuration a).
- the white-pigmented transfer layer ists preferably 15 to 25 ⁇ m, in particular ewta 18 to 22 ⁇ m thick. Falling short of the information below would lead to difficulties in production or impair the functionality of the respective layer. Exceeding the limit values would not offer any appreciable improvement and would also mean unnecessary costs.
- a thicker tape is also not equally advantageous to use in a hand-held device, since a loss of tape length would have to be accepted through the given volume of the cassette if the thickness is too thick.
- the present invention has no significant limitations.
- those binders that are already in the construction of the white pigmented transfer layer were used.
- those binders or plastics can be used that are part of it the pressure sensitive adhesive layer.
- the subcarrier of the transfer belt according to the invention preferably consists of a plastic film, such as those used for typewriter ribbons is usually used, e.g. made of polyethylene terephthalate, polypropylene, Polyethylene, polyvinyl chloride or polycarbonate. Also has silicone coated paper proved to be suitable as subcarriers. The silicone coating leads to a Reduction of the adhesive tension between the binder-containing transfer layer and the subcarrier. It can be replaced by other non-stick agents such as for example by polytetrafluoroethylene.
- the auxiliary carrier preferably has a thickness of approximately 10 to 16 ⁇ m , in particular approximately 15 to 55 ⁇ m .
- the materials of the individual layers of the transfer belt according to the invention described above generally meet the basic requirement that, in the case of configuration a), the lowest adhesive stress occurring in the layer composite of transfer layer / intermediate layer / pressure-sensitive adhesive layer (defined by the work of adhesion in accordance with Dupre's equation, lit .: KL Wolf “Physics and Chemistry of Interfaces", Springer Verlag 1957, p. 164) or, in the case of configuration b), the adhesive tension between the transfer layer and the pressure-sensitive adhesive layer is greater than the adhesive tension occurring between the auxiliary carrier and the transfer layer. If this is not the case in individual cases, then a suitable non-stick layer would have to be applied to the auxiliary carrier in order to meet this basic requirement.
- the transfer layer formed on the substrate should not be adhesive to other materials that come into contact with it, ie when touched by hand or with paper.
- the following adhesive tension ratios for the successful use of the transfer tape according to the invention can be specified, the symbol "S" representing the adhesive tension ratio between the different materials: S 1 paper / pressure-sensitive adhesive layer, S 2 weakest bond in the layered composite transfer layer / intermediate layer / pressure-sensitive adhesive layer, S 3 transfer layer / Auxiliary carrier, S 4 transfer layer / paper and S 5 pressure sensitive adhesive layer / (back of) auxiliary carrier.
- S 1 greater than S 3 S 2 greater than S 3
- S 5 very much smaller than S 2 and S 5 less than S 3 .
- the free surface of the transfer layer applied to a substrate, in particular paper, should not show any adhesion to the outside, ie S 4 is then zero or tends towards zero. Furthermore, it is ensured that when the transfer tape according to the invention is rolled up in a hand-held device, the pressure-sensitive adhesive layer has an adhesion to the back of the auxiliary carrier which is less than the lowest adhesion in the layer combination of transfer layer / intermediate layer / pressure-sensitive adhesive layer and less than the adhesion between the transfer layer and the subcarrier.
- the To use the transfer belt the user takes the housing in his hand and presses the outer (detachable) outer edge running over its end edge by means of the application foot Tape layer against the substrate to which it is to be transferred (e.g. a printed one Sheet of paper to make corrections). While pressing, the User relative to the substrate and thereby transmits e.g. a covering layer or a fluorescent layer on the substrate, the flexible auxiliary carrier from the Unwrapped supply spool and wound on the take-up spool.
- the outer (detachable) outer edge running over its end edge by means of the application foot Tape layer against the substrate to which it is to be transferred (e.g. a printed one Sheet of paper to make corrections).
- the User relative to the substrate and thereby transmits e.g. a covering layer or a fluorescent layer on the substrate, the flexible auxiliary carrier from the Unwrapped supply spool and wound on the take-up spool.
- the present invention can be explained as follows without this Explanations a bond should be seen.
- the transfer layer is also already tinted.
- the achieved here Effects can be explained by the fact that between the relatively large White pigment particles, in particular titanium dioxide particles, noticeable voids are present, which have a noticeable passage of light rays except for those to be covered Allow characters so that they are not completely covered and to shine through.
- the white pigments mentioned cannot be combined with useful ones Produce labor or production effort in a noticeably smaller particle size.
- the situation is different here, for example, with soot particles, the particles of which are readily can be produced in coloidal particle size.
- aqueous dispersion is produced to form the white-pigmented transfer layer: Aqueous acrylic dispersion (25% in water / commercial product Worleecryl® 7712W from Worlee Chemie GmbH, Hamburg) 23.42 parts by weight Lactimon® WS (alkyl ammonium salts of polycarboxylic acids and polysiloxane copolymer) 0.8 parts by weight 2-butoxyethanol 1.5 parts by weight Byk® -034 (hydrophobic, silicone-like components in mineral oil) 0.2 parts by weight Byk® -307 (polyether modified dimethylpolysiloxane copolymer) 0.02 parts by weight Sorbitol 5.00 parts by weight Silica 4.00 parts by weight Titanium dioxide 35.00 parts by weight Ivory black 0.06 part by weight aqueous dispersion of fine hollow spheres 30.00 parts by weight 100.00 parts by weight
- aqueous hollow sphere dispersion is prepared as follows: 800 parts by weight of the commercially available Ropaque® emulsion Op-62 LO-E from Rohm & Haas Company, Philadelphia, USA (consisting of a non-film-forming polymer with an effective solids content of 52% and an actual solids content of 37.5 % and a pH of 8.0 to 8.7 (particle diameter 0.4 ⁇ m, inner diameter 0.28 ⁇ m) are mixed with 176 parts by weight of water and 2 parts by weight of a defoamer additive (Byk® -034) ( hydrophobic, silicone-containing components in mineral oil) and 22 parts by weight of a formic acid solution (produced by mixing 100 parts by weight of concentrated formic acid and 900 parts by weight of water). 30 of this acidified dispersion are mixed in the above formulation Parts by weight used.
- Ropaque® emulsion Op-62 LO-E from Rohm & Haas Company, Philadelphia, USA
- the above masking compound is applied with a doctor blade in an amount of 18 g / m 2 onto a siliconized paper carrier. Then the water is evaporated at about 80 ° C by passing warm air over it.
- aqueous dispersion consisting of the following constituents is then applied to the surface of the transfer layer using a doctor blade.
- water 30.5 parts by weight Colanyl black PR 130 (from Hoechst AG) (content about 30% carbon black, rest water and dispersing agent dough) 0.5 parts by weight
- Example 1 was repeated, except that the following recipe was used for the adhesive layer: water 28.00 parts by weight Aquasilver aluminum paste LPW / 1380 (manufacturer: Carl Schlenk AG, 65% aluminum content, 35% water content) Particle size: 9 ⁇ m (on average 50.3% of the particles) 5.00 parts by weight Lactimon WS 0.50 parts by weight Plastic dispersion VP 859/6 65.00 parts by weight 25% aqueous ammonia 1.50 parts by weight 100.00 parts by weight
Landscapes
- Adhesive Tapes (AREA)
- Decoration By Transfer Pictures (AREA)
- Insulated Conductors (AREA)
- Materials For Medical Uses (AREA)
- Laminated Bodies (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Pens And Brushes (AREA)
- Duplication Or Marking (AREA)
- Manufacturing Of Electric Cables (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Belt Conveyors (AREA)
Description
Wäßrige Acrylatdispersion (25 % ig in Wasser / Handelsprodukt Worleecryl® 7712W der Firma Worlee Chemie GmbH, Hamburg) | 23,42 Gew.-Teile |
Lactimon® WS (Alkylammoniumsalze von Polycarbonsäuren und Polysiloxancopolymer) | 0,8 Gew.-Teile |
2-Butoxyethanol | 1,5 Gew.-Teile |
Byk® -034 (Hydrophobe, silikonartige Komponenten in Mineralöl) | 0,2 Gew.-Teile |
Byk® -307 (Polyethermodifiziertes Dimethylpolysiloxancopolymer) | 0,02 Gew.-Teile |
Sorbit | 5,00 Gew.-Teile |
Kieselsäure | 4,00 Gew.-Teile |
Titandioxid | 35,00 Gew.-Teile |
Elfenbeinschwarz | 0,06 Gew.-Teile |
wäßrige Dispersion von feinen Hohlkugeln | 30,00Gew.-Teile |
100,00 Gew.-Teile |
800 Gew-Teile der im Handel erhältlichen Ropaque® -Emulsion Op-62 LO-E der Firma Rohm & Haas Company, Philadelphia, USA (bestehend aus einem nicht-filmbildenden Polymer eines effektiven Feststoffgehaltes von 52% sowie eines tatsächlichen Feststoffgehaltes von 37,5 % und eines pH-Wertes von 8,0 bis 8,7 (Teilchendurchmesser 0,4 µm, Innendurchmesser 0,28 µm) werden mit 176 Gew.-Teilen Wasser und 2 Gew.-Teilen eines Entschäumeradditivs (Byk® -034) (hydrophobe, silikonhaltige Komponenten in Mineralöl) und 22 Gew.-Teilen einer Ameisensäure-Lösung (hergestellt durch Vermischen von 100 Gew.-Teilen Ameisensäure konz. und 900 Gew.-Teilen Wasser) gemischt. Von dieser angesäuterten Dispersion werden in der obigen Rezeptur 30 Gew.-Teile eingesetzt.
Wasser | 30,5 Gew.-Teile |
Colanylschwarz PR 130 (von der Firma Hoechst AG) (Gehalt etwa 30 % Ruß, Rest Wasser und Dispergiermittel = Teig) | 0,5 Gew.-Teile |
Kunststoffdispersion VP 859/6 (50 %ig Acrylat-Haftkleber) (Hersteller: Firma Freihof) | 67,00 Gew.-Teile |
25 % iger Ammoniak | 2,00 Gew.-Teile |
100,00 Gew.Teile |
Wasser | 28,00 Gew.-Teile |
Aquasilber Aluminiumpaste LPW/1380 (Hersteller: Carl Schlenk AG, 65% Aluminiumgehalt, 35% Wassergehalt) Teilchengröße: 9 µm (im Durchschnitt 50,3% der Teilchen) | 5,00 Gew.-Teile |
Lactimon WS | 0,50 Gew.-Teile |
Kunststoffdispersion VP 859/6 | 65,00 Gew.-Teile |
25 % iger wäßriger Ammoniak | 1,50 Gew.-Teile |
100,00 Gew.-Teile |
Claims (11)
- Mehrschichtiges, flexibles Übertragungsband mit einem Hilfsträger und einer Haftkleberschicht, wobei zwischen dem Hilfsträger und der Haftkleberschicht eine bindemittelhaltige weißpigmentierte Übertragungsschicht, die zur Haftkleberschicht eine stärkere Haftung als zum Hilfsträger aufweist, vorliegt, dadurch gekennzeichnet, daßa) in einer kunststoffgebundenen Zwischenschicht, die sicha1 zwischen der weißpigmentierten Übertragungsschicht und der Haftkleberschicht odera2) in der weißpigmentierten Übertragungsschicht befindet, und/oderb) in der Haftkleberschicht
- Übertragungsband nach Anspruch 1, dadurch gekennzeichnet, daß die Zwischenschicht und/oder die Haftkleberschicht mindestens etwa 0,1 Gew.-% nicht-weißes Pigment enthält.
- Übertragungsband nach Anspruch 2, dadurch gekennzeichnet, daß die Zwischenschicht und/oder die Haftkleberschicht etwa 0,1 bis 5 Gew.-%, insbesondere etwa 0,2 bis 3,5 Gew.-%, nicht-weißes Pigment enthalten.
- Übertragungsband nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die Übertragungsschicht als Weißpigment feinteiliges Titandioxid enthält.
- Übertragungsband nach mindestens einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das nicht-weiße Pigment ein Schwarzpigment ist.
- Übertragungsband nach Anspruch 5, dadurch gekennzeichnet, daß das Schwarzpigment Ruß ist.
- Übertragungsband nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß das nicht-weiße Pigment feinteiliges Aluminium ist.
- Übertragungsband nach mindestens einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die Zwischenschicht a) etwa 1 bis 5 µm, insbesondere etwa 2 bis 4 µ m, stark ist.
- Übertragungsband nach mindestens einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die weißpigmentierte Übertragungsschicht etwa 15 bis 25 µm, insbesondere etwa 18 bis 22 µm, stark ist.
- Übertragungsband nach mindestens einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die Haftkleberschicht b) etwa 1 bis 5 µm, insbesondere etwa 2 bis 4 µm, stark ist.
- Verwendung des Übertragungsbandes nach mindestens einem der vorhergehenden Ansprüche in aufgerollter Form in einem Handgerät.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19617850 | 1996-05-03 | ||
DE19617850A DE19617850C1 (de) | 1996-05-03 | 1996-05-03 | Mehrschichtiges, flexibles Übertragungsband |
PCT/EP1997/001050 WO1997042036A1 (de) | 1996-05-03 | 1997-03-03 | Mehrschichtiges, flexibles übertragungsband |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0896556A1 EP0896556A1 (de) | 1999-02-17 |
EP0896556B1 true EP0896556B1 (de) | 2001-07-25 |
Family
ID=7793277
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97906154A Expired - Lifetime EP0896556B1 (de) | 1996-05-03 | 1997-03-03 | Mehrschichtiges, flexibles übertragungsband |
Country Status (16)
Country | Link |
---|---|
US (1) | US6432515B1 (de) |
EP (1) | EP0896556B1 (de) |
JP (1) | JP2000510173A (de) |
CN (1) | CN1169676C (de) |
AT (1) | ATE203461T1 (de) |
AU (1) | AU717828B2 (de) |
BR (1) | BR9708895A (de) |
CA (1) | CA2253630A1 (de) |
CZ (1) | CZ352198A3 (de) |
DE (2) | DE19617850C1 (de) |
DK (1) | DK0896556T3 (de) |
ES (1) | ES2161441T3 (de) |
GR (1) | GR3036402T3 (de) |
PT (1) | PT896556E (de) |
TR (1) | TR199802201T2 (de) |
WO (1) | WO1997042036A1 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19744957C1 (de) * | 1997-10-10 | 1999-07-29 | Pritt Produktionsgesellschaft | Mehrschichtiges, flexibles Korrekturband |
RU2200670C1 (ru) * | 1999-01-15 | 2003-03-20 | БИК Корпорейшн | Корректирующая лента, обладающая свойствами блокирования миграции красителя |
US6331352B1 (en) * | 1999-08-13 | 2001-12-18 | Bic Corporation | Correction tape having dye migration blocking properties |
BE1015087A3 (fr) * | 2002-09-02 | 2004-09-07 | Faco Sa | Procede de decoration des cheveux et dispositif a cet effet. |
JP4471280B2 (ja) * | 2004-08-31 | 2010-06-02 | 株式会社トンボ鉛筆 | 変色性感圧転写修正テープおよび転写具 |
US20070077410A1 (en) * | 2005-09-30 | 2007-04-05 | Guangda Shi | Plastic films |
US8318847B2 (en) * | 2005-09-30 | 2012-11-27 | Sabic Innovative Plastics Ip B.V. | Plastic compositions and products produced therefrom |
EP2110715B1 (de) * | 2008-04-15 | 2012-06-06 | Ten Cate Enbi International B.V. | Entwicklungsrolle, Entwicklungsvorrichtung mit einer solchen Entwicklungsrolle sowie Verfahren zur Bereitstellung einer solchen Entwicklungsrolle |
JP2010012671A (ja) * | 2008-07-02 | 2010-01-21 | Plus Stationery Corp | 転写テープ |
US8397784B2 (en) | 2010-08-31 | 2013-03-19 | Sanford, L.P. | Correction tape dispenser with variable clutch mechanism |
US8746313B2 (en) | 2010-12-29 | 2014-06-10 | Sanford, L.P. | Correction tape re-tensioning mechanism and correction tape dispenser comprising same |
US8578999B2 (en) | 2010-12-29 | 2013-11-12 | Sanford, L.P. | Variable clutch mechanism and correction tape dispenser with variable clutch mechanism |
US8746316B2 (en) | 2011-12-30 | 2014-06-10 | Sanford, L.P. | Variable clutch mechanism and correction tape dispenser with variable clutch mechanism |
WO2013121886A1 (ja) * | 2012-02-15 | 2013-08-22 | 日東電工株式会社 | 表面保護シート |
CN103254820A (zh) * | 2012-02-15 | 2013-08-21 | 日东电工株式会社 | 表面保护片 |
JP2014133342A (ja) * | 2013-01-09 | 2014-07-24 | Kitamura Seisakusho:Kk | 修正部材、及び、その製造方法 |
JP2018008408A (ja) * | 2016-07-12 | 2018-01-18 | フジコピアン株式会社 | 感圧転写修正テープ |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6036184A (ja) * | 1983-08-09 | 1985-02-25 | General Kk | 感熱転写型修正用部材 |
US5135798A (en) | 1987-12-03 | 1992-08-04 | Pelikan Aktiengesellschaft | Multilayer, flexible transfer strip |
DE3741022C3 (de) * | 1987-12-03 | 1994-12-22 | Pelikan Ag | Mehrschichtiges, flexibles Übertragungsband |
US4891260A (en) | 1987-12-03 | 1990-01-02 | Pelikan Aktiengesellschaft | Multilayer flexible transfer ribbon |
DE3925130A1 (de) * | 1989-07-28 | 1991-01-31 | Pelikan Ag | Mehrschichtiges, flexibles markierband |
US5175058A (en) * | 1990-05-29 | 1992-12-29 | General Electric Company | Pressure sensitive adhesives |
EP0479221B1 (de) | 1990-10-05 | 1996-07-31 | Fuji Kagakushi Kogyo Co., Ltd. | Übertragungsstreifen für Korrektur |
JPH11502477A (ja) * | 1995-03-14 | 1999-03-02 | プリット プロドゥクツィオーンスゲゼルシャフト ミット ベシュレンクテル ハフツング | フレキシブルな多層書換え用テープ、その製法およびハンド装置におけるその使用 |
-
1996
- 1996-05-03 DE DE19617850A patent/DE19617850C1/de not_active Expired - Fee Related
-
1997
- 1997-03-03 CN CNB97194332XA patent/CN1169676C/zh not_active Expired - Fee Related
- 1997-03-03 TR TR1998/02201T patent/TR199802201T2/xx unknown
- 1997-03-03 AU AU20947/97A patent/AU717828B2/en not_active Ceased
- 1997-03-03 EP EP97906154A patent/EP0896556B1/de not_active Expired - Lifetime
- 1997-03-03 BR BR9708895A patent/BR9708895A/pt not_active Application Discontinuation
- 1997-03-03 DK DK97906154T patent/DK0896556T3/da active
- 1997-03-03 PT PT97906154T patent/PT896556E/pt unknown
- 1997-03-03 US US09/180,152 patent/US6432515B1/en not_active Expired - Fee Related
- 1997-03-03 WO PCT/EP1997/001050 patent/WO1997042036A1/de active IP Right Grant
- 1997-03-03 AT AT97906154T patent/ATE203461T1/de not_active IP Right Cessation
- 1997-03-03 CA CA002253630A patent/CA2253630A1/en not_active Abandoned
- 1997-03-03 CZ CZ983521A patent/CZ352198A3/cs unknown
- 1997-03-03 ES ES97906154T patent/ES2161441T3/es not_active Expired - Lifetime
- 1997-03-03 DE DE59704131T patent/DE59704131D1/de not_active Expired - Lifetime
- 1997-03-03 JP JP09539458A patent/JP2000510173A/ja active Pending
-
2001
- 2001-08-16 GR GR20010401260T patent/GR3036402T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE19617850C1 (de) | 1997-06-05 |
BR9708895A (pt) | 1999-08-03 |
ES2161441T3 (es) | 2001-12-01 |
GR3036402T3 (en) | 2001-11-30 |
WO1997042036A1 (de) | 1997-11-13 |
CN1169676C (zh) | 2004-10-06 |
CZ352198A3 (cs) | 1999-07-14 |
AU2094797A (en) | 1997-11-26 |
JP2000510173A (ja) | 2000-08-08 |
ATE203461T1 (de) | 2001-08-15 |
CA2253630A1 (en) | 1997-11-13 |
EP0896556A1 (de) | 1999-02-17 |
DK0896556T3 (da) | 2001-10-08 |
US6432515B1 (en) | 2002-08-13 |
CN1217687A (zh) | 1999-05-26 |
PT896556E (pt) | 2002-01-30 |
AU717828B2 (en) | 2000-04-06 |
DE59704131D1 (de) | 2001-08-30 |
US20020064632A1 (en) | 2002-05-30 |
TR199802201T2 (xx) | 2001-07-23 |
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