EP0894843A1 - Process and apparatus for gazifying compacted and compactable organic materials - Google Patents
Process and apparatus for gazifying compacted and compactable organic materials Download PDFInfo
- Publication number
- EP0894843A1 EP0894843A1 EP97113072A EP97113072A EP0894843A1 EP 0894843 A1 EP0894843 A1 EP 0894843A1 EP 97113072 A EP97113072 A EP 97113072A EP 97113072 A EP97113072 A EP 97113072A EP 0894843 A1 EP0894843 A1 EP 0894843A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fuel
- gasification
- chamber
- slag
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/08—Continuous processes with ash-removal in liquid state
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/22—Arrangements or dispositions of valves or flues
- C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
- C10J3/26—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/723—Controlling or regulating the gasification process
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/152—Nozzles or lances for introducing gas, liquids or suspensions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/158—Screws
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
- C10J2300/1628—Ash post-treatment
- C10J2300/1634—Ash vitrification
Definitions
- the invention relates to a process for the gasification of compacted and compactable organic materials to a Co and H 2 -rich fuel gas and a device for carrying out the process.
- such materials have to be roughly comminuted before gasification, thermally homogenized, thermally embrittled and then finely comminuted in a processing stage.
- the thermal treatment is usually carried out in a pyrolysis stage, which includes a complex, problematic separation of the pyrolysis products into pyrolysis coke, pyrolysis gas and liquid products.
- Such combined processes are known as the THERMOSELECT process from EP 0 520 086, NOELL CONVERSION PROCESS in DE 41 39 512 and VTA entrained flow gasification in EP 0 600 923 B1 and DE 41 23 406.
- the invention has for its object to provide a gasification process that without thermal pretreatment and without fine grinding of agricultural and forestry products, waste paper, textiles and. ⁇ .
- a hydrogen / carbon monoxide-rich fuel gas that is free of hydrocarbons, dioxins, furans and that provides a solid residue that can be recycled or simply deposited without further treatment.
- the task is performed by a method according to the characteristics of the first and one Device according to the features of the fifth claim solved.
- the sub-claims reflect advantageous embodiments of the invention.
- the solution according to the invention provides that, in industry and agriculture, prepared, dimensionally defined bales of waste textiles, straw products are pressed by means of a stamp or pre-comminuted, lumpy or fibrous materials by means of a stuffing screw into a horizontal gasification chamber operated at approximately atmospheric pressure.
- the temperature in the gasification chamber is kept above the melting temperature of the mineral constituents of the substances to be gasified, which occurs when the gasifier is started up by the pilot and auxiliary burner alone and in continuous operation by the partial oxidation of the substances to be gasified with oxygen.
- Primary oxygen is blown into the fuel to be gasified directly at the end of the fuel channel, that is to say when it enters the gasification chamber, and secondly, secondary oxygen is blown up during the decay of the fuel train and when it falls into the slag pan surrounded by a cooling screen.
- a reducing atmosphere is maintained in the gasification room. Due to the temperature between 1200 ° C and 1800 ° C, hydrocarbons and chlorinated hydrocarbons (dioxins, furans) are totally split and mineral components melted. The melt collects in a slag pan of the gasification chamber and runs over the slag drain body, which is standing vertically and protrudes into the gasification chamber, into the quench chamber.
- the slag pan in the gasification chamber is formed by the cooling screen in such a way that a thick and dense, solid slag layer forms over the cooling screen by cooling the melt of the slag and protects the metallic part of the cooling screen with ceramic.
- the H 2 - / CO-rich gasification gas also enters the quench chamber via the slag drain body, in which the gasification or raw gas is cooled with quench water below 100 ° C. and the slag is granulated in a glass-like manner, resistant to elution.
- the raw gas emerges from the side of the quench chamber for further raw gas purification and desulfurization, and the granulate falls into a water immersion, from which it is mechanically discharged.
- the conversion of the fuels to CO and H 2 , the reducing atmosphere in the gasification chamber and the melting of the mineral components of the fuels are monitored and controlled by means of a delay-free temperature measurement of the raw gas before it leaves the gasification chamber.
- the fuel feed, the primary / secondary oxygen addition are regulated and the water vapor addition is controlled via the auxiliary burner.
- an oxygen content measurement of the raw gas after the quenching is used, which serves as a plausibility check for the temperature measurement and control.
- the cleaned raw gas, the clean gas becomes a gas engine Electrical power generation and the granulate as a building material for the building materials industry fed for recycling.
- the self-generated clean gas can also be used as a fuel gas can be used for the pilot and auxiliary burner.
- FIG. 1 shows a gasification device according to the invention as it is used to gasify fuel bales. These are fed via the fuel feed housing 1 into the fuel inlet channel 4, in which there is a stamp 3 which conveys the bale to the feed regulation device 5 via a stamp drive 2.
- This feed regulating device 5 can be equipped with an endlessly rotating, speed-controlled driver belt, which conveys the fuel to the fuel channel end 6, into which the primary oxygen supply 13 opens.
- the fuel channel end 6 opens into the combustion chamber 7, at one end of which primary oxygen nozzles 22 are arranged.
- the secondary oxygen supply 11, the pilot and auxiliary burner 10 and the supply for fuel gas 26, oxygen 27 and water vapor 8 open into the combustion chamber 7.
- the combustion chamber 7 is surrounded by a cooling screen 9, which forms a slag pan 8 in which the slag forms collects that can leave the combustion chamber 7 via a cooled slag drain body 14.
- a temperature measurement, control and monitoring 24 is arranged opening into the combustion chamber 7.
- the secondary oxygen supply 11 takes place via an oxygen ring line 12.
- a quench chamber 16 is arranged under the gasification chamber 7, on which the quench water supply lines 15, a raw gas discharge 17 and a granulate discharge 18 are located. Furthermore, the oxygen measuring and monitoring point 29 is arranged on the raw gas discharge 17.
- FIG. 2 shows the gasification device according to the invention, in which a stuffing screw 19 with a control drive is provided as a feed for the firing material. This is especially the case if the fuel to be entered is coarse fuel.
- the primary oxygen supply 13, the cooling water inlet 20 and the cooling water outlet 21 are arranged on the fuel inlet channel.
- This combustion chamber 7 is also controlled by a temperature measurement, regulation and monitoring 24 and is surrounded in its upper part by a refractory support structure 25 and in its lower part by a cooling screen 9.
- the slag pan 8 is arranged in the lower part, into which a cooled slag drain body 14 projects.
- the pilot and auxiliary burner 10, through which fuel gas 26, oxygen 27 and water vapor 28 reach the combustion chamber 7, projects through the cooling screen 9 from the other side.
- the fuel in the case of the waste paper, is converted to CO / H 2 -rich fuel gas by the gasification reaction, whereby all hydrocarbons, chlorinated hydrocarbons (dioxins, furans) decompose and the inert, mineral components of the fuel are melted and used as a cooling screen collect the trained slag tray 8 and reach the cooled slag drain body 14 into the gasification chamber 7 in order to leave the reaction chamber together with the raw gas.
- the raw gas temperature measurement 24 monitors and controls the temperature in the combustion chamber 7 by regulating the temperature measurement signal, the feed of the fuel via the stuffing screw with control drive 19, the amount of oxygen 11 and the amount of water vapor 28, and the amount of oxygen in the raw gas 29.
- the slag granules are discharged from the quench chamber 16 by means of discharge device 23, the raw gas exiting via the raw gas discharge 17 into the raw gas purification and desulfurization system.
- the inventive method has the advantages that agricultural and forestry renewable raw materials, waste paper, textiles and the like without thermal pretreatment and without fine comminution in a hydrogen / carbon monoxide-rich fuel gas, which is free of hydrocarbons, dioxins, furans, are converted and that without Further after-treatment of usable and easy to deposit solid residue arises.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Gasification And Melting Of Waste (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zur Vergasung kompaktierter und kompaktierfähiger organischer Materialien zu einem Co- und H2-reichen Brenngas und eine Vorrichtung zur Durchführung des Verfahrens.The invention relates to a process for the gasification of compacted and compactable organic materials to a Co and H 2 -rich fuel gas and a device for carrying out the process.
Das Verfahren ist überall dort einsetzbar, wo nachwachsende landwirtschaftliche sowie forstwirtschaftliche Produkte wie Stroh, Schilf, andere Halmprodukte, Reisigholz u. ä., Altpapier, Textilien, Wolle, fasrige brennbare Stoffe zu einem Brenngas verarbeitet werden sollen. Die Hauptmerkmale der zu verarbeitenden Stoffe sind
- ihr annähernd trockener Zustand
- ihre mangelnde Fließfähigkeit und Förderbarkeit
- ihre schwierige, teils nicht mögliche Zerkleinerbarkeit zu feinkörnigen Gütern.
- their almost dry condition
- their lack of fluidity and conveyability
- their difficult, sometimes impossible to crush into fine-grained goods.
Nach bekanntem Stand der Technik müssen solche Materialien vor dem
Vergasen grob vorzerkleinert, thermisch homogenisiert, thermisch versprödet und
anschließend in einer Aufbereitungsstufe feinzerkleinert werden. Die thermische
Behandlung erfolgt üblicherweise in einer Pyrolysestufe, zu der eine aufwendige,
problematische Trennung der Pyrolyseprodukte in Pyrolysekoks, Pyrolysegas und
Flüssigprodukte gehört. Solche kombinierte Verfahren sind als THERMOSELECT-Verfahren
aus EP 0 520 086, NOELL-KONVERSIONSVERFAHREN in DE
41 39 512 und VTA-Flugstromvergasung in EP 0 600 923 B1 und DE 41 23 406
bekannt. Wegen der der Flugstrom- und auch der Festbettvergasung
vorgeschalteten Trocknungs- und Pyrolysestufen fallen hohe Investitions- und
Betriebskosten bei der Verwertung von Restabfall oder anderer anorganisch und
organisch toxischer Stoffe an, so daß die annähernd schadstofffreie Produkte
erzeugenden Vergasungsverfahren insbesondere gegenüber der Kompostierung,
Deponie oder auch gegenüber der Verbrennung nicht konkurieren können.
Einfache, einstufige Vergasungsverfahren im technischen Maßstab für
nichtfließfähige, nichtförderbare Güter existieren nicht. Diese Stoffe sind allenfalls
ohne vorherige aufwendige Aufbereitung einer Verwertung in
Verbrennungsanlagen vorbehalten.
Der Erfindung liegt die Aufgabe zugrunde, ein Vergasungsverfahren zu schaffen,
das ohne thermische Vorbehandlung und ohne Feinzerkleinerung von land- und
forstwirtschaftlich nachwachsenden Produkten, Altpapier, Textilien u. ä. ein
wasserstoff-/kohlenmonoxidreiches Brenngas, das frei von Kohlenwasserstoffen,
Dioxinen, Furanen ist und das einen ohne weitere Nachbehandlung verwertbaren
oder einfach zu deponierenden, festen Rückstand liefert.According to the known prior art, such materials have to be roughly comminuted before gasification, thermally homogenized, thermally embrittled and then finely comminuted in a processing stage. The thermal treatment is usually carried out in a pyrolysis stage, which includes a complex, problematic separation of the pyrolysis products into pyrolysis coke, pyrolysis gas and liquid products. Such combined processes are known as the THERMOSELECT process from EP 0 520 086, NOELL CONVERSION PROCESS in DE 41 39 512 and VTA entrained flow gasification in EP 0 600 923 B1 and DE 41 23 406. Because of the drying and pyrolysis stages upstream of the entrained-flow gas and also the fixed-bed gasification, high investment and operating costs are incurred in the utilization of residual waste or other inorganic and organic toxic substances, so that the gasification processes which produce almost no pollutants, in particular compared to composting, landfill or also cannot compete with combustion. Simple, one-step gasification processes on a technical scale for non-flowable, non-conveyable goods do not exist. At most, these substances are reserved for recycling in incineration plants without extensive preparation.
The invention has for its object to provide a gasification process that without thermal pretreatment and without fine grinding of agricultural and forestry products, waste paper, textiles and. Ä. A hydrogen / carbon monoxide-rich fuel gas that is free of hydrocarbons, dioxins, furans and that provides a solid residue that can be recycled or simply deposited without further treatment.
Die Aufgabe wird durch ein Verfahren nach den Merkmalen des ersten und eine Vorrichtung nach den Merkmalen des fünften Patentanspruches gelöst.The task is performed by a method according to the characteristics of the first and one Device according to the features of the fifth claim solved.
Die Unteransprüche geben vorteilhafte Ausgestaltungen der Erfindung wieder. Die erfindungsgemäße Lösung sieht vor, daß in der Industrie und Landwirtschaft vorbereitete, maßlich definierte Ballen von Alttextilien, Halmprodukten mittels eines Stempels oder vorzerkleinerte, stückige oder fasrige Stoffe mittels einer Stopfschnecke in einen bei annähernd Atmosphärendruck betriebenen, waagerecht liegenden Vergasungsraum gepreßt werden. Die Temperatur im Vergasungsraum wird oberhalb der Schmelztemperatur der mineralischen Bestandteile der zu vergasenden Stoffe gehalten, was beim Anfahren des Vergasers allein durch den Zünd- und Stützbrenner und im kontinuierlichen Betrieb zusätzlich durch die partielle Oxydation der zu vergasenden Stoffe mit Sauerstoff erfolgt. Primärsauerstoff wird einmal direkt am Brennstoffkanalende, d. h., bei Eintritt in den Vergasungsraum in den zu vergasenden Brennstoff eingeblasen, und zum anderen wird Sekundärsauerstoff während des Zerfalls des Brennstoffstranges sowie bei seinem Fallen in die mit einem Kühlschirm umgebene Schlackewanne aufgeblasen. Im Vergasungsraum wird eine reduzierende Atmosphäre aufrechtgehalten. Wegen der Temperatur zwischen 1200 °C und 1800 °C werden Kohlen- und Chlorkohlenwasserstoffe (Dioxine, Furane) total gespalten und mineralische Bestandteile aufgeschmolzen. Die Schmelze sammelt sich in einer Schlackewanne des Vergasungsraumes und läuft am senkrecht stehenden, in den Vergasungsraum hineinragenden Schlackeablaufkörper über in den Quenchraum hinein. Die Schlackewanne im Vergasungsraum wird durch den Kühlschirm so gebildet, daß sich über dem Kühlschirm durch Abkühlung der Schmelze der Schlacke eine dicke und dichte, feste Schlackeschicht bildet, die den metallischen Teil des Kühlschirmes keramisch schützt. Auch das H2 -/CO-reiche Vergasungsgas tritt über den Schlackeablaufkörper in den Quenchraum ein, in dem das Vergasungs- bzw. Rohgas mit Quenchwasser unter 100 °C abgekühlt und die Schlacke glasartig, eluationsfest granuliert wird. Das Rohgas tritt seitlich aus dem Quenchraum zur weiteren Rohgasreinigung und -entschwefelung aus, und das Granulat fällt in eine Wassertauchung, aus der es mechanisch ausgetragen wird.The sub-claims reflect advantageous embodiments of the invention. The solution according to the invention provides that, in industry and agriculture, prepared, dimensionally defined bales of waste textiles, straw products are pressed by means of a stamp or pre-comminuted, lumpy or fibrous materials by means of a stuffing screw into a horizontal gasification chamber operated at approximately atmospheric pressure. The temperature in the gasification chamber is kept above the melting temperature of the mineral constituents of the substances to be gasified, which occurs when the gasifier is started up by the pilot and auxiliary burner alone and in continuous operation by the partial oxidation of the substances to be gasified with oxygen. Primary oxygen is blown into the fuel to be gasified directly at the end of the fuel channel, that is to say when it enters the gasification chamber, and secondly, secondary oxygen is blown up during the decay of the fuel train and when it falls into the slag pan surrounded by a cooling screen. A reducing atmosphere is maintained in the gasification room. Due to the temperature between 1200 ° C and 1800 ° C, hydrocarbons and chlorinated hydrocarbons (dioxins, furans) are totally split and mineral components melted. The melt collects in a slag pan of the gasification chamber and runs over the slag drain body, which is standing vertically and protrudes into the gasification chamber, into the quench chamber. The slag pan in the gasification chamber is formed by the cooling screen in such a way that a thick and dense, solid slag layer forms over the cooling screen by cooling the melt of the slag and protects the metallic part of the cooling screen with ceramic. The H 2 - / CO-rich gasification gas also enters the quench chamber via the slag drain body, in which the gasification or raw gas is cooled with quench water below 100 ° C. and the slag is granulated in a glass-like manner, resistant to elution. The raw gas emerges from the side of the quench chamber for further raw gas purification and desulfurization, and the granulate falls into a water immersion, from which it is mechanically discharged.
Erfindungsgemäß werden die Umsetzung der Brennstoffe zu CO und H2, die reduzierende Atmosphäre im Vergasungsraum und das Aufschmelzen der mineralischen Bestandteile der Brennstoffe mittels einer verzögerungsfreien Temperaturmessung des Rohgases vor Austritt aus dem Vergasungsraum überwacht und gesteuert. In Abhängigkeit dieser Temperatur werden der Brennstoffvorschub, die Primär-/Sekundärsauerstoffzugabe geregelt und die Wasserdampfzugabe über den Stützbrenner gesteuert. Für die Betriebsführung und -überwachung wird eine Sauerstoffgehaltsmessung des Rohgases nach der Quenchung genutzt, die als Plausibilitätsnachweis für die Temperaturmessung und -regelung dient.According to the invention, the conversion of the fuels to CO and H 2 , the reducing atmosphere in the gasification chamber and the melting of the mineral components of the fuels are monitored and controlled by means of a delay-free temperature measurement of the raw gas before it leaves the gasification chamber. Depending on this temperature, the fuel feed, the primary / secondary oxygen addition are regulated and the water vapor addition is controlled via the auxiliary burner. For operational management and monitoring, an oxygen content measurement of the raw gas after the quenching is used, which serves as a plausibility check for the temperature measurement and control.
Das gereinigte Rohgas, das Reingas, wird einem Gasmotor zur Elektroenergieerzeugung und das Granulat als Baurohstoff der Baustoffindustrie zur Verwertung zugeführt. Das eigenerzeugte Reingas kann auch als Brenngas für den Pilot- und Stützbrenner verwendet werden.The cleaned raw gas, the clean gas, becomes a gas engine Electrical power generation and the granulate as a building material for the building materials industry fed for recycling. The self-generated clean gas can also be used as a fuel gas can be used for the pilot and auxiliary burner.
Im folgenden wird die Erfindung an zwei Figuren und einem Ausführungsbeispiel näher erläutert. Die Figuren zeigen:
- Figur 1
- erfindungsgemäße Vergasungsvorrichtung zur Durchführung des Verfahrens mit Stopfschnecke als Zuführeinrichtung,
- Figur 2
- erfindungsgemäße Vergasungsvorrichtung mit Stempel als Zuführeinrichtung
- Figure 1
- Gasification device according to the invention for carrying out the method with a stuffing screw as a feed device,
- Figure 2
- Gasification device according to the invention with stamp as a feed device
Die Figur 1 zeigt eine erfindungsgemäße Vergasungseinrichtung, wie sie
verwendet wird, um Brennstoffballen zu vergasen. Diese werden über das
Brennstoffaufgabegehäuse 1 in den Brennstoffeinlaufkanal 4 aufgegeben, in dem
sich ein Stempel 3 befindet, der über einen Stempelantrieb 2 den Ballen zur
Vorschubregulierungseinrichtung 5 befördert. Diese
Vorschubregulierungseinrichtung 5 kann mit einem endlos umlaufenden,
geschwindigkeitsgeregelten Mitnehmerband ausgerüstet sein, das das Brenngut
in das Brennstoffkanalende 6 befördert, in das die Primärsauerstoffzuführung 13
mündet. Das Brennstoffkanalende 6 mündet im Verbrennungsraum 7, an dessen
einem Ende Primärsauerstoffdüsen 22 angeordnet sind. Weiterhin münden in den
Verbrennungsraum 7 die Sekundärsauerstoffzuführung 11, der Zünd- und
Stützbrenner 10 und die Zuführung für Brenngas 26, Sauerstoff 27 und
Wasserdampf 8. Der Verbrennungsraum 7 ist von einem Kühlschirm 9 umgeben,
der eine Schlackewanne 8 bildet, in der sich die Schlacke sammelt, die über einen
gekühlten Schlackeablaufkörper 14 den Verbrennungsraum 7 verlassen kann. In
den Verbrennungsraum 7 mündend ist eine Temperaturmessung, -regelung und -
überwachung 24 angeordnet. Die Sekundärsauerstoffzuführung 11 erfolgt über
eine Sauerstoffringleitung 12. Unter dem Vergasungsraum 7 ist ein Quenschraum
16 angeordnet, an dem sich die Quenschwasserzuführungen 15, eine
Rohgasabführung 17 und ein Granulataustrag 18 befinden. Weiterhin ist an der
Rohgasabführung 17 die Sauerstoffmeß- und -überwachungsstelle 29
angeordnet.
Die Figur 2 zeigt die erfindungsgemäße Vergasungsvorrichtung, bei der als
Zuführung für das Brenngut eine Stopfschnecke 19 mit Regelantrieb vorgesehen
ist. Das ist vor allem dann der Fall, wenn das einzutragende Brenngut
Brennrohstoffgrobgut ist. Dieses wird in das Brennstoffaufgabegehäuse 1
aufgegeben, von der Stopfschnecke 19 erfaßt und im Brennstoffeinlaufkanal 4
transportiert. Am Brennstoffeinlaufkanal sind die Primärsauerstoffzuführung 13,
der Kühlwassereintritt 20 und der Kühlwasseraustritt 21 angeordnet. Das
Brennstoffkanalende 6, welches von Primärsauerstoffdüsen 22 umgeben ist,
mündet in den Verbrennungsraum 7 des Vergasungsreaktors. Dieser
Verbrennungsraum 7 wird ebenfalls durch eine Temperaturmessung-, regelung
und -überwachung 24 kontrolliert und ist in seinem oberen Teil durch eine
Feuerfeststützkonstruktion 25 und in seinem unteren Teil von einem Kühlschirm 9
umgeben. Weiterhin im unteren Teil ist die Schlackewanne 8 angeordnet, in die
ein gekühlter Schlackeablaufkörper 14 hineinragt. Durch den Kühlschirm 9 ragt
von der anderen Seite der Zünd- und Stützbrenner 10, durch den Brenngas 26,
Sauerstoff 27 und Wasserdampf 28 in den Verbrennungsraum 7 gelangen.
Weiterhin ragt eine Sekundärsauerstoffzuführung 11 aus einer Ringleitung 12 in
den Verbrennungsraum 7. Durch den gekühlten Schlackeablaufkörper 14 gelangt
die Schlacke in den Quenschraum 16, aus dem eine Rohgasabführung 17 und ein
Granulataustrag 18 erfolgen. Die Quenschwasserzuführungen 15 sind am
Quenschraum 16 im oberen Teil angeordnet. Unter dem Quenschraum 16
befindet sich eine Granulatauffang- und -austragvorrichtung 23. Weiterhin ist an
der Rohgasabführung 17 eine Sauerstoffmeß- und -überwachungsstelle 29
angeordnet.
Im vorliegenden Ausführungsbeispiel wird als loses, grobes Gut Altpapier mit der
regelbaren Stopfschnecke 19 in den Verbrennungsraum 7 hineinbefördert, der
mittels des Zünd- und Stützbrenners 10 auf Temperaturen oberhalb des
Schmelzpunktes der mineralischen Bestandteile des Brennstoffes aufgeheizt wird
und der durch die Vergasung des Brennstoffes auf einer Temperatur zwischen
1200 und 1800 Grad gehalten wird. Dabei werden Primärsauerstoff 13 am
Brennstoffkanalende 6 in den Brennstoff über Primärsauerstoffdüsen 22
eingeblasen, Sekundärsauerstoff 11 auf den in den Verbrennungsraum 7
einfallenden Brennstoff aufgeblasen und Wasserdampf 28 zur
Temperaturmoderierung aufgegeben. Der Brennstoff, in dem Fall das Altpapier,
wird durch die Vergasungsreaktion zu CO/H2-reichem Brenngas umgesetzt, wobei
alle Kohlenwasserstoffe, Chlorkohlenwasserstoffe (Dioxine, Furane) zersetzt und
die inerten, mineralischen Bestandteile des Brennstoffes aufgeschmolzen werden
und sich in der als Kühlschirm ausgebildeten Schlackewanne 8 sammeln und am
gekühlten Schlackeablaufkörper 14 in den Vergasungsraum 7 gelangen, um
gemeinsam mit dem Rohgas den Reaktionsraum zu verlassen. Die
Rohgastemperaturmessung 24 überwacht und steuert die Temperatur im
Verbrennungsraum 7, indem das Temperaturmeßsignal den Vorschub des
Brennstoffes über die Stopfschnecke mit Regelantrieb 19, die Sauerstoffmenge
11 und die Wasserdampfmenge 28 sowie die Sauerstoffgehaltsmenge im Rohgas
29 geregelt werden. Durch die schroffe Abkühlung der flüssigen Schlacke und des
Rohgases im Quenschraum 16 mittels Wasser über die Quenschwasserzuführung
15 entsteht ein verglastes, eluationsfestes Granulat, wodurch keine Rückbildung
der Dioxine und Furane erfolgen kann. Das Schlackegranulat wird mittels
Austragsvorrichtung 23 aus dem Quenschraum 16 ausgetragen, wobei das
Rohgas über die Rohgasabführung 17 in das Rohgasreinigungs- und -
entschwefelungssystem austritt.
Das erfindungsgemäße Verfahren hat die Vorteile, daß land- und
forstwirtschaftlich nachwachsende Rohstoffe, Altpapier, Textilien und ähnliches
ohne thermische Vorbehandlung und ohne Feinzerkleinerung in ein wasserstoff-/kohlenmonoxidreiches
Brenngas, das frei von Kohlenwasserstoffen, Dioxinen,
Furanen ist, umgewandelt werden und daß ein ohne weitere Nachbehandlung
verwertbarer und einfach zu deponierender, fester Rückstand entsteht. FIG. 1 shows a gasification device according to the invention as it is used to gasify fuel bales. These are fed via the fuel feed housing 1 into the
FIG. 2 shows the gasification device according to the invention, in which a
Furthermore, a
In the present exemplary embodiment, waste paper is conveyed into the
The inventive method has the advantages that agricultural and forestry renewable raw materials, waste paper, textiles and the like without thermal pretreatment and without fine comminution in a hydrogen / carbon monoxide-rich fuel gas, which is free of hydrocarbons, dioxins, furans, are converted and that without Further after-treatment of usable and easy to deposit solid residue arises.
- 11
- BrennstoffaufgabegehäuseFuel feed case
- 22nd
- StempelantriebStamp drive
- 33rd
- Stempelstamp
- 44th
- BrennstoffeinlaufkanalFuel inlet channel
- 55
- VorschubregulierungseinrichtungFeed regulation device
- 66
- BrennstoffkanalendeFuel channel end
- 77
- VergasungsraumGasification room
- 88th
- SchlackewanneSlag pan
- 99
- KühlschirmCooling screen
- 1010th
- Zünd- und StützbrennerPilot and auxiliary burner
- 1111
- SekundärsauerstoffzuführungSecondary oxygen supply
- 1212th
- SauerstoffringleitungOxygen ring line
- 1313
- PrimärsauerstoffzuführungPrimary oxygen supply
- 1414
- Gekühlter SchlackeablaufkörperCooled slag drain body
- 1515
- QuenchwasserzuführungQuench water supply
- 1616
- QuenchraumQuench room
- 1717th
- RohgasabführungRaw gas discharge
- 1818th
- GranulataustragGranulate discharge
- 1919th
- Stopfschnecke mit RegelantriebDarning screw with variable speed drive
- 2020th
- KühlwassereintrittCooling water inlet
- 2121
- KühlwasseraustrittCooling water outlet
- 2222
- PrimärsauerstoffdüsenPrimary oxygen nozzles
- 2323
- Granulatauffang- und austragsvorrichtungGranulate collection and discharge device
- 2424th
- Temperaturmessung, -regelung, -überwachungTemperature measurement, control and monitoring
- 2525th
- Feuerfeste StützkonstruktionFireproof support structure
- 2626
- BrenngasFuel gas
- 2727
- Sauerstoffoxygen
- 2828
- WasserdampfSteam
- 2929
- Sauerstoffmeß- und Überwachungs-StelleOxygen measuring and monitoring point
Claims (9)
dadurch gekennzeichnet,
characterized,
gekennzeichnet durch
einen Stempel (3) mit Stempelantrieb (2) als Zuführeinrichtung.Device according to claim 5,
marked by
a stamp (3) with stamp drive (2) as a feed device.
gekennzeichnet durch
eine Stopfschnecke (19) mit Regelantrieb als Zuführeinrichtung.Device according to claim 5,
marked by
a stuffing screw (19) with a control drive as the feed device.
dadurch gekennzeichnet, daß
sich das Brennstoffkanalende (6) in Bewegungsrichtung des Brennstoffes konisch verjüngt und die Vorschubregulierungseinrichtung (5) ein endlos umlaufendes, geschwindigkeitsgeregeltes Mitnehmerband darstellt.Device according to claim 5,
characterized in that
the fuel channel end (6) tapers conically in the direction of movement of the fuel and the feed regulating device (5) represents an endlessly rotating, speed-controlled carrier belt.
dadurch gekennzeichnet, daß
der Vergasungsraum (7) mit einem Kühlschirm (9) in der Weise versehen wird, -daß sich über dem Kühlschirm (9) durch Abkühlung der Schlackeschmelze eine dicke und dichte, feste Schlackeschicht bildet, die den metallischen Teil des Kühlschirms metallisch-keramisch schützt.Device according to claim
characterized in that
the gasification chamber (7) is provided with a cooling screen (9) in such a way that a thick and dense, solid slag layer forms over the cooling screen (9) by cooling the slag melt and protects the metallic part of the cooling screen in a metallic-ceramic manner.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97113072A EP0894843A1 (en) | 1997-07-30 | 1997-07-30 | Process and apparatus for gazifying compacted and compactable organic materials |
JP19916198A JPH11100583A (en) | 1997-07-30 | 1998-07-14 | Process for gasifying compressed or compressible organic material and apparatus therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97113072A EP0894843A1 (en) | 1997-07-30 | 1997-07-30 | Process and apparatus for gazifying compacted and compactable organic materials |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0894843A1 true EP0894843A1 (en) | 1999-02-03 |
Family
ID=8227143
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97113072A Withdrawn EP0894843A1 (en) | 1997-07-30 | 1997-07-30 | Process and apparatus for gazifying compacted and compactable organic materials |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0894843A1 (en) |
JP (1) | JPH11100583A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19853713C2 (en) * | 1998-11-20 | 2003-03-13 | Bbp Power Plants Gmbh | Process for the material and energetic utilization of residual and waste materials |
DE10355912A1 (en) * | 2003-11-29 | 2005-06-30 | Wiebe, Jörg | Gasifying fuel bales comprises continuously feeding the bales through a charging gate into a gasification chamber |
DE102006052345A1 (en) * | 2006-11-07 | 2008-05-08 | Herlt, Christian, Dipl.-Ing. | Fine dust reducing method for use in biomass combustion plant, involves concentrating gas mixture present in gasification area with water vapor, supplying dosed water and/or water vapor, and burning supplied water and/or vapor |
CN106765156A (en) * | 2017-02-22 | 2017-05-31 | 陈世江 | A kind of refuse gasification incinerator |
CN112899028A (en) * | 2021-01-18 | 2021-06-04 | 江苏信科能源有限公司 | Improved biomass gasification furnace with dry slag discharge and continuous feeding functions |
CN113583713A (en) * | 2021-07-26 | 2021-11-02 | 安徽科达洁能股份有限公司 | Horizontal type gas gasification furnace and gasification method thereof |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100413188B1 (en) * | 2001-01-13 | 2003-12-31 | (주)지알텍 | Burner for inflammable pulverized fuel |
KR20030025314A (en) * | 2001-09-20 | 2003-03-29 | 김현영 | Method of gasifying carbonaceous material and apparatus therefor |
JP4486699B1 (en) * | 2009-11-06 | 2010-06-23 | 株式会社リ・サイエンスシステム研究所 | Method for reforming organic waste with generation of hydrogen gas and apparatus for reforming organic waste |
WO2011070624A1 (en) * | 2009-12-11 | 2011-06-16 | 株式会社リ・サイエンスシステム研究所 | Method of organic-waste modification accompanied by generation of high-concentration hydrogen gas and device for modifying organic waste |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0443596A1 (en) * | 1990-02-23 | 1991-08-28 | Thermoselect Aktiengesellschaft | Process for transporting, intermediate storage and energetic and material use of waste and apparatus for carrying out the process |
DE4109063A1 (en) * | 1991-03-20 | 1992-09-24 | Deutsches Brennstoffinst | Combustible waste utilisation method - involves gasifying lumps by using medium flowing in same direction before flame reaction chamber |
DE4330788A1 (en) * | 1993-09-10 | 1994-04-07 | Siemens Ag | Refuse processing mechanism with feeder - has at least one transport screw in degassing duct |
-
1997
- 1997-07-30 EP EP97113072A patent/EP0894843A1/en not_active Withdrawn
-
1998
- 1998-07-14 JP JP19916198A patent/JPH11100583A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0443596A1 (en) * | 1990-02-23 | 1991-08-28 | Thermoselect Aktiengesellschaft | Process for transporting, intermediate storage and energetic and material use of waste and apparatus for carrying out the process |
DE4109063A1 (en) * | 1991-03-20 | 1992-09-24 | Deutsches Brennstoffinst | Combustible waste utilisation method - involves gasifying lumps by using medium flowing in same direction before flame reaction chamber |
DE4330788A1 (en) * | 1993-09-10 | 1994-04-07 | Siemens Ag | Refuse processing mechanism with feeder - has at least one transport screw in degassing duct |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19853713C2 (en) * | 1998-11-20 | 2003-03-13 | Bbp Power Plants Gmbh | Process for the material and energetic utilization of residual and waste materials |
DE10355912A1 (en) * | 2003-11-29 | 2005-06-30 | Wiebe, Jörg | Gasifying fuel bales comprises continuously feeding the bales through a charging gate into a gasification chamber |
DE10355912B4 (en) * | 2003-11-29 | 2006-02-02 | Wiebe, Jörg | Process and apparatus for gasifying fuel bales |
DE102006052345A1 (en) * | 2006-11-07 | 2008-05-08 | Herlt, Christian, Dipl.-Ing. | Fine dust reducing method for use in biomass combustion plant, involves concentrating gas mixture present in gasification area with water vapor, supplying dosed water and/or water vapor, and burning supplied water and/or vapor |
DE102006052345B4 (en) * | 2006-11-07 | 2009-04-23 | Herlt, Christian, Dipl.-Ing. | Method and device for reducing the formation of fine dust in the thermal gasification of chunky and lumpy biomass in the form of bales |
CN106765156A (en) * | 2017-02-22 | 2017-05-31 | 陈世江 | A kind of refuse gasification incinerator |
CN106765156B (en) * | 2017-02-22 | 2023-09-29 | 陈世江 | Garbage gasification incinerator |
CN112899028A (en) * | 2021-01-18 | 2021-06-04 | 江苏信科能源有限公司 | Improved biomass gasification furnace with dry slag discharge and continuous feeding functions |
CN113583713A (en) * | 2021-07-26 | 2021-11-02 | 安徽科达洁能股份有限公司 | Horizontal type gas gasification furnace and gasification method thereof |
Also Published As
Publication number | Publication date |
---|---|
JPH11100583A (en) | 1999-04-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0545241B1 (en) | Process for thermic valorisation of waste materials | |
EP2082013B1 (en) | Method for producing a product gas rich in hydrogen | |
DE4404673C2 (en) | Process for the production of fuel gas | |
AT402964B (en) | METHOD FOR THE USE OF DISPOSAL GOODS | |
DE60115109T2 (en) | PLASMAPYROLYSIS, GASIFICATION AND GLAZING OF ORGANIC MATERIALS | |
DE102006040077C5 (en) | Apparatus for discharging slag from gasification reactors | |
DE3347554C2 (en) | Process for obtaining usable gas from waste by pyrolysis and apparatus for carrying out the process | |
DE4446803A1 (en) | Utilising residues and e g household and industrial waste material | |
EP0136255A2 (en) | Reactor for producing generatorgas from combustible waste products | |
EP0594231A1 (en) | Process for gasifying waste products containing combustible substances | |
DE102004024672B4 (en) | Apparatus and method for producing a tar-free lean gas by gasification of biomass | |
EP3309240A1 (en) | Method and device for gasification of biomass | |
DE4435349C1 (en) | Destruction of pollutants and gasifying of waste in a fluidised bed | |
EP0689574B1 (en) | Waste disposal process and device | |
DE4123406A1 (en) | METHOD FOR GASIFYING LOW-QUALITY SOLID FUELS IN A SHAFT-SHAPED GASIFICATION REACTOR | |
EP0894843A1 (en) | Process and apparatus for gazifying compacted and compactable organic materials | |
EP1201731A1 (en) | Process for fluidized bed gasifying carbon containing solids and gasifier therefor | |
EP1558709A1 (en) | Method for gasifying substances containing carbon by using a plasma | |
DE4412004A1 (en) | Process for gasifying waste materials in the circulating fluidized bed | |
DE19853717C2 (en) | Methods and devices for the gasification of compact organic materials | |
DE2718539A1 (en) | PROCESS FOR GASIFYING FINE DISTRIBUTED FUELS CONTAINING ASHES | |
DE4226015C1 (en) | Process for the disposal of solid and liquid waste in the gasification process in fixed bed pressure gasification | |
DE3439600C2 (en) | ||
DE19730385C2 (en) | Method for producing fuel and synthesis gas from fuels and combustible waste and an apparatus for carrying out the method | |
DE19536383A1 (en) | Gasification of low value fuels |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE FR GB IT NL SE |
|
AX | Request for extension of the european patent |
Free format text: AL;LT;LV;RO;SI |
|
17P | Request for examination filed |
Effective date: 19990219 |
|
AKX | Designation fees paid |
Free format text: DE FR GB IT NL SE |
|
17Q | First examination report despatched |
Effective date: 20010216 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: BBP POWER PLANTS GMBH |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20040203 |