EP0893490B1 - Composition adoucissante pour tissus sans azote - Google Patents

Composition adoucissante pour tissus sans azote Download PDF

Info

Publication number
EP0893490B1
EP0893490B1 EP98113305A EP98113305A EP0893490B1 EP 0893490 B1 EP0893490 B1 EP 0893490B1 EP 98113305 A EP98113305 A EP 98113305A EP 98113305 A EP98113305 A EP 98113305A EP 0893490 B1 EP0893490 B1 EP 0893490B1
Authority
EP
European Patent Office
Prior art keywords
fatty
nitrogen
acid
weight
alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98113305A
Other languages
German (de)
English (en)
Other versions
EP0893490A2 (fr
EP0893490A3 (fr
Inventor
Karl-Heinz Scheffler
Theodor Völkel
Ansgar Dr. Behler
Almud Folge
Anneliese Dr. Wilsch-Irrgang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0893490A2 publication Critical patent/EP0893490A2/fr
Publication of EP0893490A3 publication Critical patent/EP0893490A3/fr
Application granted granted Critical
Publication of EP0893490B1 publication Critical patent/EP0893490B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters

Definitions

  • the invention is in the field of nitrogen-free fabric softeners, especially suitable for use in the rinse cycle of a washing program.
  • liquid fabric softeners containing 2 to 10 wt .-% of a fabric softening Fatty and anionic emulsifiers and optionally other ingredients contain.
  • Softener compositions for rinse-aid are broad in the art described. Usually these compositions contain as active substance one cationic quaternary ammonium compound (QAV) or an amine salt or mixtures of both, which is dispersed in water. For environmental reasons, the use is of cationic surfactants by the consumer increasingly critical. But cationic surfactant-based fabric softener compositions also have an application-related point of view some disadvantages. For example, they react through their cationic character with anionic substances under salt formation and lose thereby their softening Effect. The incorporation of the cationic surfactants in the fabric softener often turns out difficult as they are poorly water-soluble to water-insoluble compounds only form difficult stable emulsions. In addition, there are also new generation of cationic Textile softeners, the so-called “esterquats", although completely biodegradable, however, as desired, nitrogen-free agents are being used by the consumer as Alternative desired.
  • esterquats although completely biodegradable, however, as desired,
  • EP-A-0 569 847 discloses nitrogen-free active components for fabric softener formulations based on alkoxylated natural fats or oils (for example ethoxylated palm oil or skin fat) in combination with free fatty acids or mono- and / or diglycerides and their use as fabric softener, wherein these active components can also be used in combination with conventional nitrogen-containing plasticizers.
  • Fabric softening aqueous compositions which preferably contain from 1 to 25% by weight of a pentaerythritol ester or of a pentaerythritol oligomer or of an alkoxylated pentaerythritol derivative and from 0.2 to 10% by weight of an emulsifier, for example diethylene glycol ether, are described in EP-A-0 494 769 (Colgate).
  • EP-A-0 530 959 also discloses fabric softeners based on a pentaerythritol ester, pentaerythritol oligomers or alkoxylated pentaerythritol derivatives.
  • dispersants for the active substances synthetic organic surfactants are used here.
  • U.S. Patent 5,599,473 (Colgate) describes a process for preparing nitrogen-free fabric softener in which room temperature water, anionic surfactant (s) and fatty matter (s), referred to herein as hydrophobic liquid oxidized hydrocarbons, are mixed.
  • the oxidized hydrocarbons used are fatty acid polyol esters, fatty alcohols, fatty acids or fatty ethers.
  • the anionic surfactants are used in amounts between 2 and 30 wt .-%, the fatty substances in amounts between 2 and 40 wt .-%.
  • Other ingredients are cosurfactants in amounts of 2 to 30 wt .-% and electrolytes.
  • This softener should be present as a mandatory microemulsion, which is stabilized by anion and cosurfactant and requires a complex preparation.
  • the present invention is therefore based on the object, a nitrogen-free Softener to provide the softness performance of conventional QAC-based agents achieved and has a high storage stability, while continuing to be light and without should be able to produce large equipment costs.
  • fatty substances a) from the group of C 16-18 fatty alcohols and mono- or diesters of C 16-18 -fatty acids are in the context of this application at normal temperature (20 ° C) liquid to solid substances from the group of C 16- 18 fatty alcohols and the fatty acid esters of C 16-18 fatty acids with certain polyols understood.
  • hexadecanol or octadecanol and mixtures of these alcohols are used as C 16-18 fatty alcohols.
  • Guerbet alcohols and oxo alcohols can also be used without problems as fatty substances.
  • alcohol mixtures for example those such as C 16-18 -alcohols produced by ethylene polymerization according to Ziegler.
  • Specific examples of alcohols which can be used as component a) are the abovementioned alcohols as well as palmityl and stearyl alcohol and mixtures thereof.
  • Suitable fatty acid polyol esters are mono- or diesters of C 16-18 fatty acids with certain polyols.
  • the C 16-18 fatty acids which are esterified with the polyols are preferably saturated or unsaturated fatty acids having 16 to 18 C atoms, for example palmitic acid or stearic acid, wherein preferably the technically occurring mixtures of the fatty acids are used.
  • acids or mixtures of acids having 16 to 18 carbon atoms such as tallow fatty acid are suitable for esterification with the polyhydric alcohols.
  • Suitable polyols which are esterified with the abovementioned fatty acids are, for the purposes of the present invention, sorbitol, trimethylolpropane, neopentyl glycol, ethylene glycol, polyethylene glycols, glycerol and polyglycerols.
  • Preferred embodiments of the present invention provide that glycerol is used as the polyol which is esterified with C 16-18 fatty acid (s). Accordingly, preference is given to nitrogen-free textile softening agents which contain 2 to 10% by weight of one or more fatty substances from the group of fatty alcohols and fatty acid glycerides as component a). Particularly preferred fabric softeners contain as component 2 to 10 wt .-% of a fatty acid monoglyceride.
  • the fatty substances are selected from the group of fatty acid glycerol esters of fatty acids having 16 to 18 carbon atoms and fatty alcohols having 8 to 28 carbon atoms and mixtures of these substances.
  • Examples of such C 16-18 fatty acids which are preferably used are glycerol monostearic acid esters or glycerol monopalmitic acid esters.
  • a dispersant which disperses the fatty substance a) in the fabric softening agent
  • anionic surface-active compounds in quantities between 0.2 and 5 wt .-%, preferably between 1 to 5 wt .-%, based on the total agent used. This ensures Dispersant that the fat is present in sufficiently fine distribution, but without to be too heavily emulsified. In this way, an optimal mounting on the Wash in the rinse and thus ensures a high degree of softness.
  • anionic surfactants b for example, those of the sulfonate type and sulfates are used.
  • the surfactants of the sulfonate type are preferably C 9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C 12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration.
  • alkanesulfonates which are obtained from C 12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
  • esters of ⁇ -sulfo fatty acids for example the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids are suitable
  • sulfated fatty acid glycerol esters are sulfated fatty acid glycerol esters.
  • fatty acid gly cerinesters are the mono-, di- and triesters and their mixtures, as they are in the preparation by esterification of a monoglycerol with 1 to 3 moles of fatty acid or obtained in the transesterification of triglycerides with 0.3 to 2 moles of glycerol.
  • Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated Fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, Capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
  • Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C 12 -C 18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical having an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
  • C 12 -C 16 alkyl sulfates and C 12 -C 15 alkyl sulfates and C 14 -C 15 alkyl sulfates are preferred.
  • 2,3-alkyl sulfates prepared, for example, according to U.S. Patents 3,234,258 or 5,075,041, which can be obtained as commercial products of the Shell Oil Company under the name DAN®, are suitable anionic surfactants.
  • Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • alcohols preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • Preferred sulfosuccinates contain C 8-18 fatty alcohol residues or mixtures of these.
  • Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which in themselves constitute nonionic surfactants (see description below).
  • Sulfosuccinates whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred.
  • alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
  • anionic surfactants are particularly soaps into consideration.
  • suitable saturated fatty acid soaps such as the salts of lauric acid, myristic acid, palmitic acid, Stearic acid, hydrogenated erucic acid and behenic acid and in particular from natural Fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures.
  • the anionic surfactants including soaps may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or Triethanolamine.
  • the anionic surfactants are in the form of their Sodium or potassium salts, especially in the form of the sodium salts.
  • a preferred nitrogen-free, liquid fabric softener according to the teachings of the present invention Invention contains as anionic dispersant b) 0.2 to 5 wt .-%, preferably 0.3 to 4 wt .-% of an alkyl sulfate.
  • compositions of the invention contain other ingredients that the application and / or aesthetic properties of the fabric softener continue to improve.
  • preferred agents in addition to the components a) and b) one or several substances from the group of electrolytes, nonaqueous solvents, pH adjusters, Fragrances, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, Anti redeposition agents, thickeners, enzymes, optical brighteners, grayness inhibitors, Opacifiers, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, Wetting improvers, antimicrobial agents, germicides, fungicides, Antioxidants, corrosion inhibitors, antistatic agents, ironing aids, and Phobier- Impregnating agent, swelling and anti-slip agent and UV absorber.
  • salts from the group of inorganic salts a wide number of different salts can be used.
  • Preferred cations are the alkali and alkaline earth metals, preferred anions are the halides and sulfates. From a production point of view, the use of NaCl or MgCl 2 in the agents according to the invention is preferred.
  • Non-aqueous solvents used in the compositions according to the invention can, for example, from the group of monohydric or polyhydric alcohols; Alkanolamines or glycol ethers come into consideration, provided they are in the specified concentration range are miscible with water.
  • the solvents are selected from ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, glycerol, Diglycol, propyl or butyldiglycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, Ethylene glycol propyl ether, etheylene glycol mono-n-butyl ether, diethylene glycol methyl ether, Diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, Dipropylene glycol methyl or ethyl ether, methoxy, ethoxy or butoxy triglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether and Mixtures of these solvents.
  • alkanolamines such as mono-, Di- and triethanolamine are within the scope of the present invention, which is a nitrogen-free Softener to provide, less preferably, in the inventive But funds are used without their application properties to influence negatively.
  • pH adjusters In order to bring the pH value of the agent according to the invention into the desired range, the use of pH adjusters may be indicated.
  • Dyes and fragrances are added to the inventive compositions to the aesthetic To enhance the impression of the products and the consumer in addition to the softness performance a visual and sensory "typical and unmistakable" product to deliver.
  • perfume oils or perfumes individual fragrance compounds, e.g. the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons are used. Fragrance compounds of the ester type are e.g.
  • the ethers include, for example, benzyl ethyl ether, to the aldehydes e.g.
  • the linear alkanals with 8-18 C atoms citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, Hydroxycitronellal, lilial and bourgeonal, to the ketones e.g. the Jonone, ⁇ -isomethylionone and methyl cedryl ketone, to the alcohols anethole, citronellol, Eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, to the hydrocarbons mainly include the terpenes such as limes and pinene. To be favoured However, mixtures of different fragrances are used, which together create an appealing Create a fragrance.
  • perfume oils can also be natural fragrance mixtures as available from plant sources, e.g. Pine, Citrus, Jasmine, Patchouly, rose or ylang-ylang oil. Also suitable are muscatel, sage oil, Chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, Vetiver oil, olibanum oil, galbanum oil and labdanum oil, and orange blossom oil, Neroliol, orange peel oil and sandalwood oil.
  • the content of the plasticizers according to the invention is usually lower than that of dyes 0.01% by weight, while perfumes account for up to 2% by weight of the total formulation can.
  • the fragrances can be incorporated directly into the compositions according to the invention but it may also be advantageous to apply the fragrances on carriers, which the adhesion of the Enhance perfumes on the lingerie and through a slower fragrance release for long-lasting Fragrance of the textiles provide.
  • carrier materials for example Cyclodextrins proven, the cyclodextrin-perfume complexes in addition can still be coated with other excipients.
  • dyes In order to improve the aesthetic impression of the agents according to the invention, they can dyed with suitable dyes.
  • Preferred dyes the selection of which Expert has no difficulty, have a high storage stability and insensitivity compared with the other ingredients of the products and against light and none pronounced substantivity to textile fibers so as not to stain them.
  • foam inhibitors which can be used in the agents according to the invention, for example, soaps, paraffins or silicone oils are suitable, if appropriate can be applied to support materials.
  • Suitable antiredeposition agents that Also referred to as soil repellents are, for example, nonionic cellulose ethers such as methylcellulose and methylhydroxypropylcellulose with a proportion of methoxy groups from 15 to 30% by weight and of hydroxypropyl groups from 1 to 15% by weight, respectively based on the nonionic cellulose ether and those of the prior art known polymers of phthalic acid and / or terephthalic acid or of their derivatives, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionic modified derivatives of this. Particularly preferred of these are the sulfonated derivatives of phthalic acid and terephthalic acid polymers.
  • Thickening agents may be added to the compositions of the invention to increase the viscosity increase or improve the thixotropic properties of gels.
  • thickener are often referred to as swelling agents and are mostly organic high-molecular substances that can absorb liquids (mostly water), swell and eventually pass into viscous true or colloidal solutions.
  • examples for such agents are polyacrylic acids or acrylic acid copolymers such as, for example sold by the company Goodrich under the trade name Carbopol®.
  • hydrolases such as proteases, Esterases, lipases or lipolytic enzymes, amylases, cellulases or other Glykosylhydrolasen and mixtures of said enzymes in question. All these hydrolases Wear in the laundry to remove stains such as protein, grease or starchy stains and graying at. Cellulases and other glycosyl hydrolases In addition, by removing pilling and microfibrils Color retention and to increase the softness of the textile contribute. For bleaching or for Inhibition of color transfer can also Oxireduktasen be used.
  • subtilisin-type proteases and in particular proteases, are from Bacillus lentus are used.
  • protease and / or lipase-containing mixtures or mixtures with lipolytic acting enzymes of particular interest are the known cutinases. Also have peroxidases or oxidases proved to be suitable in some cases.
  • suitable amylases include ⁇ -amylases, iso-amylases, pullulanases and pectinases.
  • Being cellulases preferably cellobiohydrolases, endoglucanases and ⁇ -glucosidases, which also include cellobiases be called, or mixtures thereof used.
  • cellulase types by their CMCase and avicelase activities can be distinguished by targeted mixtures of cellulases the desired activities can be adjusted.
  • the enzymes may be adsorbed to carriers or embedded in encapsulating substances to protect them against premature decomposition.
  • the proportion of enzymes, enzyme mixtures or enzyme granules may, for example, about 0.1 to 5 wt .-%, preferably 0.12 to about 2 wt .-% amount.
  • Optical brighteners can be added to the compositions according to the invention to eliminate graying and yellowing of treated textiles. These substances are absorbed by the fiber and cause lightening and faking Bleaching action by turning invisible ultraviolet radiation into visible longer wavelength Convert light, with the ultraviolet light absorbed from the sunlight is emitted as a faint bluish fluorescence and with the yellowness of the brewed or yellowed laundry results in pure white.
  • Suitable compounds are derived, for example from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, Naphthalic acid imides, benzoxazole, benzisoxazole and benzimidazole systems and the substituted by heterocycles pyrene derivatives.
  • the optical brightener are usually in amounts between 0.1 and 0.3 wt .-%, based on the finished agents used.
  • Vergrauungsinhibitoren have the task of the detached from the fiber dirt in the Keep liquor suspended and thus prevent the repatriation of the debris.
  • water-soluble colloids are usually suitable organic nature, for example, the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether sulfonic acids starch or cellulose or salts of acid sulfuric acid esters of cellulose or the strength.
  • water-soluble, acidic groups containing polyamides are for suitable for this purpose, but less preferred because of their nitrogen content.
  • Farther can be soluble starch preparations and other than the above starch products use, e.g. degraded starch, aldehyde levels, etc.
  • polyvinylpyrrolidone is usable.
  • cellulose ethers such as carboxymethyl cellulose are preferred (Na salt), methyl cellulose, hydroxyalkyl cellulose and mixed ethers such as methylhydroxyethyl cellulose, Methylhydroxypropylcellulose, methylcarboxy-methylcellulose and their mixtures in amounts of 0.1 to 5 wt .-%, based on the means used
  • the inventive Means containing synthetic anti-crease agents include, for example synthetic products based on fatty acids, fatty acid esters. fatty acid amides, alkylol esters, alkylolamides or fatty alcohols, usually with ethylene oxide or products based on lecithin or modified phosphoric acid ester.
  • the agents according to the invention can be antimicrobial Contain active ingredients.
  • antimicrobial Contain active ingredients are, for example, benzalkonium chlorides, because of their nitrogen content in the context of the present invention, however are less preferred.
  • Preferred compounds within the scope of the present invention Invention are, for example, alkylarylsulfonates, halophenols and phenolmercuric acetate, wherein dispensed entirely with these compounds in the erfindunnningen agents can be.
  • this class of connection includes substituted phenols, hydroquinones, catechols and aromatic amines and organic Sulfides, polysulfides, dithiocarbamates, phosphites and phosphonates.
  • Antistatic agents increase the surface conductivity and thus allow an improved drainage of formed charges.
  • External antistatic agents are generally substances with at least one hydrophilic molecule ligand and give a more or less hygroscopic film on the surfaces. These mostly surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
  • External antistatic agents are described for example in the patent applications FR 1,156,513, GB 873 214 and GB 839 407.
  • the lauryl (or stearyl) dimethylbenzylammonium chlorides disclosed herein are useful as antistatics for textiles or as additives to laundry detergents, with the additional benefit of providing a softening effect.
  • silicone derivatives are used. These additionally improve the rinsing behavior of the agents according to the invention by their foam inhibiting properties.
  • Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and completely or partially fluorinated.
  • Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and then amino-functional or quaternized or Si-OH, Si-H and / or Si-Cl bonds.
  • the viscosities the preferred silicones are in the range between 100 and 100,000 centistokes at 25 ° C, wherein the silicones in amounts between 0.05 and 5 wt .-%, based on the total Means can be used.
  • compositions of the invention may also contain UV absorbers, which are based on the Treat treated textiles and improve the light resistance of the fibers.
  • Links, which have these desired properties are, for example, by non-radiative deactivation of effective compounds and derivatives of benzophenone with substituents in the 2- and / or 4-position.
  • substituted benzotriazoles, in the 3-position phenyl-substituted acrylates (cinnamic acid derivatives), optionally with Cyano groups in the 2-position, salicylates, organic Ni complexes and natural products such as Umbelliferone and the body's own urocanic acid are suitable.
  • the agents contain nonionic surfactants.
  • Nonionic surfactants may be present in certain formulations contribute to increased efficacy of the plasticizers, but are in accordance with the invention not mandatory.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 3 EO or 4 EO, C 9-11 alcohols with 7 EO, C 13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12-14 -alcohol with 3 EO and C 12-18 -alcohol with 5 EO.
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • nonionic surfactants and alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
  • nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters, as they are for example, in Japanese Patent Application JP 58/217598 , or which are preferably prepared by the method described in International Patent Application WO-A-90/13533 (Henkel).
  • Nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide may be suitable, but are due to their nitrogen content in the context of present invention not preferred.
  • the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half of it.
  • polyhydroxy fatty acid amides of the formula (I), wherein RCO is an aliphatic acyl group having 6 to 22 carbon atoms, R 1 is hydrogen, an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl group having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the group of polyhydroxy fatty acid amides also includes compounds of the formula (II) in the R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms
  • R 1 is a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms
  • R 2 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having from 1 to 8 carbon atoms, with C 1-4 alkyl or phenyl radicals being preferred
  • [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.
  • [Z] is preferably obtained by reductive amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a reduced sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides according to the teaching of international application WO-A-95/07331 (Procter & Gamble) by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
  • Preferred fabric softeners contain, in addition to components a) and b), 0.1 to 5% by weight of one or more nonionic surfactants.
  • the agents were used in the final rinse cycle and the textiles treated with them were evaluated after drying by an expert panel of at least 5 persons with handle marks.
  • the handle scores as an average of at least 3 individual determinations, the classification between the two to be determined standards 0 (rinse with tap water) and 6 (textile equipped with 3 g distearyldimethylammonium chloride per kg of dry laundry) results.
  • the gripping marks of the compositions according to the invention and the comparative examples are shown in Table 2: Softness assessment [handles] V1 V2 V3 V4 E1 E2 E3 E4 E5 E6 E7 E8 E9 2.4 2.3 1.6 4.6 4.3 4.7 4.8 5.1 4.8 4.0 4.1 4.7
  • Table 2 shows that the agents of the invention, the pentaerythritol ester based comparison agents far surpass and the softness performance of conventional, Esterquat-based Reach or exceed softener (E5).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (5)

  1. Adoucissant liquide pour textile, exempt d'azote, contenant de l'eau, un ou des tensioactifs anioniques et une ou des matières grasses, caractérisé en ce qu'il contient
    a) la ou les matières grasses dans une proportion de 2 à 10 % en poids et que ces matières grasses sont choisies parmi les alcools gras en C16-18 et les mono- ou diesters d'acides gras en C16-18 formés avec du sorbitol, du triméthylolpropane, du néopentylglycol, de l'éthylèneglycol, du polyéthylènegylcol, du glycérol et des polyglycérols,
    b) le ou les tensioactifs anioniques dans une proportion de 0,2 à 5 % en poids,
    c) en tant que complément, de l'eau ou une solution aqueuse d'autres substances actives et adjuvants, et ne se présente pas sous forme de microémulsion mais de dispersion aqueuse.
  2. Adoucissant liquide pour textile, exempt d'azote, selon la revendication 1, caractérisé en ce qu'il contient, en tant que matière grasse a), de 2 à 10 % en poids d'une ou plusieurs matières grasses du groupe des glycérides d'acides gras.
  3. Adoucissant liquide pour textile, exempt d'azote, selon la revendication 1, caractérisé en ce qu'il contient, en tant que matière grasse a), de 2 à 10 % en poids d'un monoglycéride d'acide gras.
  4. Adoucissant liquide pour textile, exempt d'azote, selon l'une quelconque des revendications 1 à 3, caractérisé en ce qu'il contient, en tant que dispersant anionique b), de 0,3 à 4 % en poids d'un alkylsulfate.
  5. Adoucissant liquide pour textile, exempt d'azote, selon l'une quelconque des revendications 1 à 4, caractérisé en ce qu'il contient, en plus des composants a) et b), de 0,1 à 5 % en poids d'un ou plusieurs tensioactifs non ioniques.
EP98113305A 1997-07-25 1998-07-16 Composition adoucissante pour tissus sans azote Expired - Lifetime EP0893490B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19732073 1997-07-25
DE19732073A DE19732073C1 (de) 1997-07-25 1997-07-25 Flüssiger stickstofffreier Textilweichmacher

Publications (3)

Publication Number Publication Date
EP0893490A2 EP0893490A2 (fr) 1999-01-27
EP0893490A3 EP0893490A3 (fr) 2002-10-02
EP0893490B1 true EP0893490B1 (fr) 2005-04-20

Family

ID=7836899

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98113305A Expired - Lifetime EP0893490B1 (fr) 1997-07-25 1998-07-16 Composition adoucissante pour tissus sans azote

Country Status (4)

Country Link
EP (1) EP0893490B1 (fr)
AT (1) ATE293668T1 (fr)
DE (1) DE19732073C1 (fr)
ES (1) ES2241077T3 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005012479A1 (de) * 2005-03-16 2006-09-21 Cognis Ip Management Gmbh Anionische Weichmacher auf Sulfosuccinatbasis
ES2375742T3 (es) * 2007-03-21 2012-03-05 Cognis Ip Management Gmbh Empleo de un agente para la mejora de la absorción de agua de materiales textiles.
CN102124092B (zh) 2008-08-15 2014-06-18 宝洁公司 包含聚甘油酯的有益组合物

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5130638B2 (fr) * 1972-07-12 1976-09-02
BR8305694A (pt) * 1982-10-21 1984-07-10 Unilever Nv Processo para condicionamento de panos nos estagios de enxaguamento e composicao condicionadora liquida de panos
GB8805448D0 (en) * 1988-03-08 1988-04-07 Bp Chem Int Ltd Liquid detergent compositions
US5419842A (en) * 1994-06-13 1995-05-30 Colgate-Palmolive Company Anionic fabric softening composition containing pentaerythritol softener
US5599473A (en) * 1994-08-04 1997-02-04 Colgate-Palmolive Company Nitrogen-free rinse cycle fabric softeners based on microemulsions
DE19527596A1 (de) * 1995-07-28 1997-01-30 Henkel Kgaa Wäßrige Tensidmischung
JP2000502118A (ja) * 1995-11-16 2000-02-22 アムウェイ コーポレイション 皿洗い用液体洗剤
WO1997026316A1 (fr) * 1996-01-19 1997-07-24 Unilever Plc Systemes non cationiques destines a des feuilles pour seche-linge
EP0839898A1 (fr) * 1996-11-04 1998-05-06 The Procter & Gamble Company Compositions de nettoyage à épaississement propre
GB9709065D0 (en) * 1997-05-02 1997-06-25 Unilever Plc Improvements relating to hard surface cleaning

Also Published As

Publication number Publication date
DE19732073C1 (de) 1998-08-20
ES2241077T3 (es) 2005-10-16
ATE293668T1 (de) 2005-05-15
EP0893490A2 (fr) 1999-01-27
EP0893490A3 (fr) 2002-10-02

Similar Documents

Publication Publication Date Title
EP2134826B1 (fr) Agent de lavage anti-gris
EP2142630B1 (fr) Composition detergente contenant un polysaccharide
EP1032626A1 (fr) Assouplissant clair contenant des huiles parfumees micro-emulsionnees
EP1979451A1 (fr) Agent de nettoyage ou de lavage comportant un inhibiteur de transfert de colorant
WO2016012327A2 (fr) Agents de soin textile transparents
EP3775130B1 (fr) Produit de soin des textiles comprenant un copolymère éventuellement réticulé et procédé permettant l'apprêt de textiles
EP3775129B1 (fr) Produit de soin des textiles comprenant un copolymère éventuellement réticulé et procédé permettant l'apprêt de textiles
EP3775128B1 (fr) Produit de soin des textiles comprenant un copolymère éventuellement réticulé et procédé permettant l'apprêt de textiles
WO2016096614A1 (fr) Agents d'entretien transparents pour textiles
WO1999028430A1 (fr) Detergents liquides tres visqueux et faiblement concentres
WO2013186170A1 (fr) Agents de lavage, de nettoyage ou de pré-traitement à pouvoir nettoyant renforcé
WO2008155160A1 (fr) Lessives ou détergents liquides hautement moussants, présentant une viscosité stable
WO2007107191A1 (fr) Agent de lavage, de nettoyage ou de rincage multiphasique avec separations de phases verticales
EP0893490B1 (fr) Composition adoucissante pour tissus sans azote
WO2008012141A2 (fr) Agent de lavage ou de nettoyage ayant une capacité de dispersion améliorée
EP3116984B1 (fr) Mélange de tensioactifs amélioré ayant un degré d'éthoxylation optimisé
WO2007033731A1 (fr) Agent de lavage et de nettoyage comprenant des ingredients actifs doux pour la peau
EP3436560A1 (fr) Agent de traitement de textiles exempt de tensioactifs cationiques
EP3450532B1 (fr) Utilisation d'un copolymère amodiméthicone / organosilicium, détergent, utilisation du détergent et procédé de lavage
DE10029284A1 (de) Flüssiges bis gelförmiges Textilbehandlungsmittel
EP2108038B1 (fr) Lessive ou détergent à viscosité stable
WO2014195215A1 (fr) Agents de lavage, de nettoyage ou de pré-traitement à pouvoir nettoyant iii renforcé
DE102007023872A1 (de) Vergrauungsinhibierendes Waschmittel
WO2008037619A2 (fr) Agent de traitement de textiles
DE102007016382A1 (de) Vergrauungsinhibierendes Waschmittel

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19980716

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

RIC1 Information provided on ipc code assigned before grant

Free format text: 7C 11D 3/20 A, 7C 11D 1/14 B, 7C 11D 1/83 B

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

AKX Designation fees paid

Designated state(s): AT BE DE ES FR IT NL

17Q First examination report despatched

Effective date: 20030924

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

RBV Designated contracting states (corrected)

Designated state(s): AT BE ES FR IT NL

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE ES FR IT NL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20050420

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: 8566

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2241077

Country of ref document: ES

Kind code of ref document: T3

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20060123

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20120719

Year of fee payment: 15

Ref country code: BE

Payment date: 20120713

Year of fee payment: 15

Ref country code: IT

Payment date: 20120714

Year of fee payment: 15

Ref country code: ES

Payment date: 20120824

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20120626

Year of fee payment: 15

BERE Be: lapsed

Owner name: *HENKEL K.G.A.A.

Effective date: 20130731

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 293668

Country of ref document: AT

Kind code of ref document: T

Effective date: 20130716

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20140331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130716

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130716

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130717