EP0888224B1 - Feuille decorative pour decorer des surfaces de substrat tridimensionnelles - Google Patents

Feuille decorative pour decorer des surfaces de substrat tridimensionnelles Download PDF

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Publication number
EP0888224B1
EP0888224B1 EP19960907272 EP96907272A EP0888224B1 EP 0888224 B1 EP0888224 B1 EP 0888224B1 EP 19960907272 EP19960907272 EP 19960907272 EP 96907272 A EP96907272 A EP 96907272A EP 0888224 B1 EP0888224 B1 EP 0888224B1
Authority
EP
European Patent Office
Prior art keywords
coat
film
decorative
decoration
coating material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19960907272
Other languages
German (de)
English (en)
Other versions
EP0888224A1 (fr
Inventor
Robert Reck
Joachim Süss
Heinrich Wild
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Leonhard Kurz Stiftung and Co KG
Original Assignee
Leonhard Kurz GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Leonhard Kurz GmbH and Co KG filed Critical Leonhard Kurz GmbH and Co KG
Publication of EP0888224A1 publication Critical patent/EP0888224A1/fr
Application granted granted Critical
Publication of EP0888224B1 publication Critical patent/EP0888224B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1712Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/1729Hot stamping techniques
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10Applying flat materials, e.g. leaflets, pieces of fabrics
    • B44C1/105Applying flat materials, e.g. leaflets, pieces of fabrics comprising an adhesive layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]

Definitions

  • the invention relates to decorative films for decorating three-dimensional substrate surfaces under heating, which consists of a carrier film and one on top of it arranged decorative layer consist of at least one with the formation of a precisely fitting decor printed lacquer layer is formed.
  • Such decorative films can generally be used as Transfer foils in the manner of a hot stamping foil, as well as Laminating film to be constructed, when used as Transfer the decorative layer from the carrier film being replaced during the transfer process, while Total laminating films, i.e. both carrier film as well Decorative layer, transferred to the substrate to be decorated become.
  • Decorative films from a carrier film and a die actual decoration forming the decorative layer are in the various areas used, one of the Areas of application for decorating three-dimensionally designed surfaces. If you have one Want to provide a surface with a decorative film, the Application of the decorative film in the decorative film Be able to deal with the surface irregularities adapt as closely as possible, which is why it is necessary that the decorative film may be sufficient can stretch. This property plays especially with the Decoration of three-dimensional molded parts in presses Role in which, be it with the help of a membrane, be it only with appropriate training Differences in pressure, the decorative film against the surface of the molded part is created. Another area of application is the so-called "insert molding", in which the film is in a Injection mold inserted and then with the formation of the Injection molded part with plastic.
  • Such a decorative film is from DE-U-9404567 known, which goes back to the same applicant as the present invention.
  • This document discloses one Decorative film with a backing and one Decorative layer, the decorative layer no has perfectly fitting decor and generally polyester as Carrier layer revealed. It is particularly preferred here a biaxially oriented polyester film. The decoration three-dimensional surfaces takes place in this document no mention.
  • WO92 / 05030 is a decorative film for decoration known three-dimensional surfaces, the carrier film from an unstretched polyethylene terephthalate film.
  • this document discloses only one throughout trained decoration layer, which on different Were manufactured and applied to the substrate can.
  • a reference to a fitting decoration of a three-dimensional surface with a corresponding trained decoration pattern is this document also not to be removed.
  • the invention is based on the object, a To create decorative film that is especially for the Decoration of finely structured, three-dimensional Substrate surfaces is suitable, and in addition Decorative layer of existing, precisely fitting decor when applied the decorative film on the three-dimensional substrate is not changed or is changed in a precisely predetermined manner, so that when using a decorative film according to the Invention becomes possible, finely structured, three-dimensional Substrate surfaces flawless and with an exact to decorate predetermined patterns.
  • Decorative films according to the invention with an amorphous have unstretched polyamide or polyester film as a carrier especially for the specially intended areas of application the advantage that they can be deformed very strongly, and even at relatively low temperatures.
  • polyester films are common is very resistant to the usual solvents.
  • Carrier film is its comparatively low price.
  • films made of amorphous, unstretched polyester or polyamide can deform strongly at low temperatures. This one Properties and the initially strong shrinking behavior such films when heated, however, make them unsuitable appear when it comes to having a perfectly fitting decor to print an appropriate varnish.
  • During the run through the printing press and especially when drying the Lacquer layer can not be avoided that appropriate train is exerted on the carrier film, still its warming can be prevented.
  • the expert fear that the originally printed Decor when passing through the printing press considerable Undergoes changes and loses its accuracy of fit.
  • the inventor's merit in the present case is well, to have realized that these problems with skillful Guiding the carrier film during the printing process and appropriate training of the decor can be prevented can and also using the itself as inappropriate film from amorphous, unstretched Polyester or polyamide for the intended purposes have excellent suitable decorative foils produced.
  • the initially strong shrinking behavior of the Backing film when heated must even be considered a privilege be because it causes the decorative film or in particular their carrier film during transmission a structured surface even at relatively low Temperatures (from approx. 80 ° C) and very low Working pressures almost completely at any one designed surface, whereby, as experiments shown have even grooves with a width of less than 1 mm be decorated accordingly with the decorative film can.
  • the initially strong shrinkage behavior of the carrier films according to The invention leads especially with steep parts Crash edges to a much lower wrinkling in the Compared to previously used PVC supports, but also much lower molded part receptacles are used can, which means cost savings.
  • the resistance of the carrier film to usually in paints or surface coatings used solvents and aqueous systems offers the Advantage of using a wide range of paints can be, e.g. is also possible, in itself predetermined degree of gloss of the carrier film (this is in the generally slightly matt and semi-transparent) by a corresponding intermediate layer of paint the respective To design needs accordingly.
  • the carrier film has a thickness from about 20 to 100 microns.
  • the decorative layer at least one the precisely fitting decor-forming decorative lacquer layer and one these in use after application to the Comprises protective lacquer layer covering the substrate surface, the protective lacquer layer, for example, accordingly high mechanical strength or UV light resistance may have.
  • the decorative layer at least one that forms the perfect fitting decor Decorative lacquer layer and one in use after application the substrate surface under the decorative lacquer layer, covering the entire surface of the colored lacquer layer, whereby further design options open up.
  • an adhesive layer for Fixing provided on the substrate surface.
  • adhesive layer can take into account Art and surface of the substrate to be decorated become.
  • Decorative layer between the carrier film and the adhesive layer is arranged, in such a case appropriate between the decorative layer and the carrier film Removal layer is provided, which is the detachment of the Carrier film after the application of the decorative layer on the Relieved substrate.
  • a heat transfer film according to the invention is useful constructed such that successively on the carrier film - if available - the release layer, the Protective lacquer layer, the decorative lacquer layer, the Colored lacquer layer and the adhesive layer are arranged.
  • the heat transfer film shown in Fig. 1 includes one Carrier film 1, on which a release layer 2, e.g. a Wax layer, a total of 3 decorative layer is set.
  • a release layer 2 e.g. a Wax layer
  • the carrier film 1 is, according to the invention an essentially amorphous, unstretched polyester film, which has a thickness of 20 to 100 ⁇ m, depending on the Field of use.
  • Amorphous, unstretched have proven particularly suitable Polyethylene terephthalate films have been proven Softening range is between 70 ° C and 80 ° C.
  • the Elongation is when the Softening temperature greater than 300%.
  • the Tension model drops when the Softening temperature below 500 N.
  • polyethylene terephthalate films also have amorphous, undrawn polyamide films and Films made from copolymers based on polyamide Softening temperatures of less than 120 ° C and one Elongation of over 300% when this is exceeded Temperature proved to be suitable.
  • the decorative layer 3 of the exemplary embodiment in FIG. 1 then includes a release layer 2 transparent protective lacquer layer 4.
  • a release layer 2 transparent protective lacquer layer 4 is one, for example a grain forming decorative lacquer layer 5 printed with a precise fit.
  • one continuous color lacquer layer 6 is provided.
  • the last Layer of the decorative layer 3 forms an adhesive layer 7, for example from a heat-activated adhesive.
  • the layer thicknesses in the heat transfer film of FIG. 1 are as follows: Peel layer 0.01 to 0.50 ⁇ m Protective coating 1 to 5 ⁇ m Decorative lacquer layer 0.1 to 2 ⁇ m Color coat 3 to 25 ⁇ m Adhesive layer 5 to 20 ⁇ m.
  • the heat transfer film according to FIG. 1 is used either by means of a membrane or simply by appropriate pressure difference - using the Heat transfer film itself as a membrane - against that appropriately structured surface of a substrate pressed, the decorative layer 3 facing the substrate and by means of the adhesive layer 7 on the substrate surface is set. After applying the heat transfer film completely to the substrate surface and optionally certain cooling then the carrier film 1 of the Decorative layer 3 and thus removed from the substrate surface, which is facilitated by the presence of the release layer 2 becomes. If necessary, the release layer 2 to be dispensed with if the protective lacquer layer 4 is so is composed that it is correspondingly easy from the surface of the carrier film 1 can solve.
  • the structure of the decorative layer 3 compared to the embodiment of FIG. 1 be different.
  • the colored lacquer layer 6 or the protective lacquer layer 4 to be dispensed with.
  • the adhesive layer 7 can also under certain circumstances omitted if either the colored lacquer layer 6 or the most distant position from the carrier film 1 Decorative layer 3 are sufficiently sticky to adhere the decorative layer 3 on the substrate surface ensure or if the adhesive layer before Applying the decorative layer 3 to the substrate, for example by spraying or the like.
  • compositions of the different layers of paint depending on the special Areas of use are varied, particularly if necessary, individual layers can be dispensed with can.
  • the thickness of the layers depends on the particular one Application area and must above all take this into account to what extent stretching the film and thus parallel thinning of the layers at Application to the three-dimensional surface of the Substrate is expected.

Landscapes

  • Laminated Bodies (AREA)
  • Decoration By Transfer Pictures (AREA)

Claims (7)

  1. Feuille décorative du type feuille de transfert thermique, pour décorer des surfaces substrats tridimensionnelles par chauffage, qui est constituée d'un film support et d'une couche décorative disposée sur ce dernier, couche qui est formée d'au moins une couche de vernis imprimée par zones avec formation d'un décor à repérage exact, où on utilise en tant que film support (1) un film de polyester, de polyamide ou d'un copolymère de polyamide, essentiellement amorphe et non-étiré, une couche adhésive (7) est prévue pour fixation à la surface substrat, et la couche décorative (3) est disposée entre le film support (1) et la couche adhésive (7).
  2. Feuille décorative selon la revendication 1, caractérisée en ce que le film support est un film de poly(téréphtalate d'éthylène).
  3. Feuille décorative selon la revendication 1 ou 2, caractérisée en ce que le film support (1) a une épaisseur d'environ 1 à 100 µm.
  4. Feuille décorative selon l'une des revendications précédentes, caractérisée en ce que la couche décorative (3) comporte au moins une couche de vernis décoratif (5), formant par zones un décor à repérage exact, et une couche de vernis de protection (4), qui recouvre cette dernière en cours d'utilisation après application sur la surface substrat.
  5. Feuille décorative selon l'une des revendications précédentes, caractérisée en ce que la couche décorative (3) comporte au moins une couche de vernis décoratif (5), formant par zone le décor à repérage exact, et une couche de vernis coloré (6), appliquée en pleine surface, qui en cours d'utilisation, et après application sur la surface substrat, se trouve en-dessous de la couche de vernis décoratif (5).
  6. Feuille décorative selon l'une des revendications précédentes, caractérisée en ce qu'une couche détachable (2) est prévue entre la couche décorative (3) et le film support (1).
  7. Feuille décorative selon l'une des revendications précédentes, caractérisée en ce que, sur l'éventuel film support (1), se trouvent successivement la couche détachable (2), la couche de vernis de protection (4), la couche de vernis décoratif par zones (5), la couche de vernis coloré (6) et la couche d'adhésif (7).
EP19960907272 1994-12-23 1996-03-18 Feuille decorative pour decorer des surfaces de substrat tridimensionnelles Expired - Lifetime EP0888224B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4446255A DE4446255C2 (de) 1994-12-23 1994-12-23 Dekorationsfolie zum Dekorieren von dreidimensionalen Substratoberflächen
PCT/DE1996/000516 WO1997034774A1 (fr) 1994-12-23 1996-03-18 Feuille decorative pour decorer des surfaces de substrat tridimensionnelles

Publications (2)

Publication Number Publication Date
EP0888224A1 EP0888224A1 (fr) 1999-01-07
EP0888224B1 true EP0888224B1 (fr) 2000-06-07

Family

ID=25943240

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19960907272 Expired - Lifetime EP0888224B1 (fr) 1994-12-23 1996-03-18 Feuille decorative pour decorer des surfaces de substrat tridimensionnelles

Country Status (9)

Country Link
US (1) US6387472B1 (fr)
EP (1) EP0888224B1 (fr)
JP (1) JPH08183143A (fr)
AU (1) AU713604B2 (fr)
BR (1) BR9612563A (fr)
DE (1) DE4446255C2 (fr)
ES (1) ES2148738T3 (fr)
HK (1) HK1016133A1 (fr)
WO (1) WO1997034774A1 (fr)

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Also Published As

Publication number Publication date
US6387472B1 (en) 2002-05-14
WO1997034774A1 (fr) 1997-09-25
DE4446255A1 (de) 1996-06-27
DE4446255C2 (de) 1997-05-28
AU5099296A (en) 1997-10-10
HK1016133A1 (en) 1999-10-29
EP0888224A1 (fr) 1999-01-07
ES2148738T3 (es) 2000-10-16
AU713604B2 (en) 1999-12-09
BR9612563A (pt) 1999-07-20
JPH08183143A (ja) 1996-07-16

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