Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
  • B41M5/267—Marking of plastic artifacts, e.g. with laser

Definitions

• the invention relates to a method for the manufacture of an object with a coloured mark, by irradiating the surface of an object with laser light in the shape of the mark.
• a problem involved in the known method is that the colours that are obtained are not freely chosen, but accidentally obtained. Furthermore, only a limited number of different colours is obtained.
• the invention aims to provide a method that does not present the above drawbacks.
• the part of the object where the mark is applied consists of a plastic composition that contains at least three colour-forming components that lose their colour-forming capacity under the influence of laser light, which are chosen so and are each present in such a concentration that at every wavelength between 400 and 700 nanometres (nm) at least a portion of the amount of incident light is absorbed, one or more colours being chosen for the mark, the wavelength of the laser light subsequently being set to a value that is dependent on the chosen colour and the surface of the object subsequently being irradiated with the laser light.
• the wavelength is not a factor determining the colour of the marking. In the method according to the invention, however, there is a direct relation between the wavelength of the radiation used to apply the marking and the colour of the marking.
• the wavelength of the laser light can be set to a value dependent on the chosen colour on the basis of the relationship thus obtained.
• 'Colour-forming components' are understood to be components that have a chromatic colour, such as colourants and pigments.
• White or black components including for example titanium dioxide, chalk, barium sulphide, carbon black or iron sulphide, are not understood to be included in the range of colour-forming components.
• the plastic composition may in general contain any thermoplastic or thermosetting plastic or any elastomer. Very suitable are the plastics which the plastic composition in WO94/12352 may contain.
• the colour-forming components are each present in such a concentration that at every wavelength between 400 and 700 nm at least 20%, more preferably at least 50% and even more preferably at least 80%, of the amount of incident light, expressed in lux, is absorbed.
• a person skilled in the art will be able to easily choose the colour-forming components and the concentration, measure the amount of light absorbed at every wavelength between 400 and 700 nm (the absorption spectrum) with the aid of one of the known measuring methods and then adjust the colour-forming component and its concentration until the desired absorption spectrum is obtained.
• the method according to the invention can be carried out with the aid of one or more laser apparatuses, which irradiate laser light with a wavelength that corresponds to the value chosen for the wavelength on the basis of the desired colour of the mark.
• the surface of the plastic composition is irradiated with laser light at at least three different wavelengths, more preferably at a multitude of wavelengths, which are dependent on the colours chosen for the mark.
• marks are obtained that contain a multitude of colours and may even approach or, if use is made of a laser beam with a very small cross-section, even surpass the quality of a colour photograph.
• Very good results are obtained if the cross section of the laser beam is equal to or smaller than the grain diameter of a colour photograph.
• a characteristic value for such a grain diameter is 0.5-3 micrometres.
• the plastic composition according to the invention contains only colour-forming components that lose their colour-forming capacity under the influence of laser light and the colour-forming components have each one single absorption band (the concept 'absorption band' is described in Colour Chemistry, 2nd edition, H. Zollinger, VCH Verlag Weinheim, Germany (1991), ISBN 3-527-28352-8).
• the wavelength of the colour in which the mark is obtained corresponds to the wavelength of the laser light with which the surface of the plastic composition is irradiated. In that way it is very easy to obtain the chosen colour, because the chosen colour will practically correspond to the colour of the laser light.
• the colour chosen for the mark will correspond more or even entirely to the colour of the laser light if the colour forming components and their concentrations are choosen so that, between 400 and 700 nm, at least approximately the same amount of light is absorbed at every wavelength.
• the amounts of light absorbed per wavelength differ not more than 20% from one another, more preferably 10%, even more preferably 5%.
• the surface of the object additionally has a neutral grey or black colour before the mark is applied.
• the plastic composition contains a first colour-forming component that reflects light whose main colour is yellow, a second colour-forming component that reflects light whose main colour is magenta and a third colour-forming component that reflects light whose main colour is cyan.
• the colour-forming components do not or virtually not lose their colour-forming capacity under normal daylight. Therefore the colour-forming components preferably have a colour stability of at least 3, more preferably at least 5, on Wool's scale (according to DIN 54003).
• the invention also relates to an information carrier, at least one surface of which consists of the plastic composition described above and at least 50% of which surface is covered with one or more marks.
• Such an information carrier can be provided with a mark with the aid of the method according to the invention.
• the mark may contain any desired colour.
• the mark may even have the form of a true-to-nature representation of for example objects, animals or persons. It is also possible for at least 50% of the surface of the information carrier to be covered with text.
• the information carrier has a supporting layer, which supports the layer consisting of the plastic composition. That way the layer consisting of the plastic composition may have a small thickness and different types of information carriers, depending on the type of supporting layer chosen, are obtained for all kinds of purposes.
• the supporting layer may for example consist of paper and the information carrier may have the form of a colour photograph or a photocopy.
• the supporting layer may also consist of a plastic or a metal.
• the plastic of the plastic composition is chosen so that it adheres well to the supporting layer.
• the invention also relates to an object that is to be processed into the information carrier described above.
• a dry blend was prepared from 1897 parts by weight of Ronfalin R SFA-34, an acrylonitrile-butadienestyrene copolymer (ABS) supplied by DSM, the Netherlands, 100 parts by weight of Tiofine R R41, a titanium dioxide pigment supplied by Tiofine, the Netherlands, and 1 part by weight of Irgalith R Rubine 4 BP, 1 part by weight of Irgalith Blue LGLD and 1 part by weight of Cromophtal R Yellow 6G, magenta, cyan and yellow pigments, respectively, supplied by Ciba-Geigy, the Netherlands.
• ABS acrylonitrile-butadienestyrene copolymer
• the dry blend was melted, kneaded at 260°C and processed into granulate.
• the granulate was injection-moulded into plates measuring 3.2*120*120 mm with the aid of an Arburg Allrounder R 320-90-750 type of injection-moulding machine, at a temperature of 240°C.
• the coloured pigments in the plates absorb the visible light.
• the plates had a light grey colour.
• the laser setup contained an EEO R -355 type of seeding laser, which was used as a pump laser for a GCR R -230/50 type of Nd:YAG laser.
• the laser setup also included a MOPO R 710 type of optical parameter oscillator (OPO), which received the signal from the latter laser via a frequency doubling optic (FDO).
• OPO optical parameter oscillator
• FDO frequency doubling optic
• Example I was repeated, only Stamylan P R 83 MF 10, a polypropylene supplied by DSM, the Netherlands, was used instead of ABS. The results are shown in Table 1.
• a dry blend was prepared from 98.74 parts by weight of Arnitel R TV4 261, a polybutylene terephthalate supplied by DSM, the Netherlands, 0.03 parts by weight of Paliogen R Red K 3911 HD, a red pigment supplied by BASF, the Netherlands, 0.75 parts by weight of Meteor Plus R Teal Blue, a cyan pigment supplied by Engelhard, Germany, 0.03 parts by weight of PV Echtgelb R HG, a yellow pigment supplied by Hoechst, the Netherlands, 0.3 parts by weight of Kronos R CL 220, a titanium dioxide pigment supplied by Kronos, the Netherlands, and 0.15 parts by weight of magnesium stearate.
• Example 1 The dry blend was injection moulded into plates as described in Example I, only at a temperature of 260°C.
• the plates had a moss grey colour.
• the surface of the plates was provided with marks as described in Example I. The results are shown in Table 1.
• a lacquer was prepared in a beaker by vigorously stirring 65.0 parts by weight of Uracron R HDT EV 412, a hydroxyl-functional resin supplied by DSM Resins, the Netherlands, 20.8 parts by weight of Tolonate R HDT EV 412, supplied by Hüls, Germany, 0.6 parts by weight of dibutyl tin laureate, supplied by Aldrich, Belgium, 10.0 parts by weight of Kronos R CL 220, 1.2 parts by weight of Cromophtal R Yellow 3G, a yellow pigment supplied by Ciba-Geigy, the Netherlands, 1.2 parts by weight of Paliogen R Red L 3910 HD, a red pigment supplied by BASF, the Netherlands, and 1.2 parts by weight of Orasol R Blue GN, a blue pigment supplied by Ciba-Geigy, the Netherlands.
• the lacquer was applied to an aluminium plate in a layer with a thickness of 50 micrometres.
• the lacquer layer had a grey colour. Marks were applied in the lacquer layer as described in Example I, only the line distance was set to 1 mm. The results are shown in Table 1.
• Example IV was repeated, only the concentrations of the yellow and the blue pigment were raised to 1.8 parts by weight.
• the lacquer layer had a green colour.
• the results are included in Table 1.
• Laser settings Example I
• Example II Example III
• Example IV Example V ⁇ (nm)/colour ⁇ max (nm) from reflection spectra 430/violet 428 425 436 427 430 470/blue 475 471 481 468 490 575/yellow 580 575 585 572 520 650/orange 645 655 662 643 680

Landscapes

• Physics & Mathematics (AREA)
• Optics & Photonics (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Treatments Of Macromolecular Shaped Articles (AREA)
• Dot-Matrix Printers And Others (AREA)
• Thermal Transfer Or Thermal Recording In General (AREA)
• Reverberation, Karaoke And Other Acoustics (AREA)
• Crystals, And After-Treatments Of Crystals (AREA)
• Application Of Or Painting With Fluid Materials (AREA)

Applications Claiming Priority (3)

Publications (2)

Family

ID=19761007

Family Applications (1)

Country Status (8)

Families Citing this family (21)

Family Cites Families (4)

• 1995
  • 1995-05-10 NL NL1000331A patent/NL1000331C2/nl not_active IP Right Cessation
• 1996
  • 1996-05-08 DE DE69605788T patent/DE69605788T2/de not_active Expired - Fee Related
  • 1996-05-08 JP JP8533964A patent/JPH11504879A/ja not_active Ceased
  • 1996-05-08 ES ES96915217T patent/ES2142063T3/es not_active Expired - Lifetime
  • 1996-05-08 AU AU57039/96A patent/AU5703996A/en not_active Abandoned
  • 1996-05-08 EP EP96915217A patent/EP0828613B1/en not_active Expired - Lifetime
  • 1996-05-08 AT AT96915217T patent/ATE187934T1/de not_active IP Right Cessation
  • 1996-05-08 WO PCT/NL1996/000197 patent/WO1996035585A1/en active IP Right Grant

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