EP0826502A1 - Vorrichtung und Verfahren zum Herstellen einer Reinigungslösung und zum Behandeln der verwendeten Reinigungslösung - Google Patents
Vorrichtung und Verfahren zum Herstellen einer Reinigungslösung und zum Behandeln der verwendeten Reinigungslösung Download PDFInfo
- Publication number
- EP0826502A1 EP0826502A1 EP97810589A EP97810589A EP0826502A1 EP 0826502 A1 EP0826502 A1 EP 0826502A1 EP 97810589 A EP97810589 A EP 97810589A EP 97810589 A EP97810589 A EP 97810589A EP 0826502 A1 EP0826502 A1 EP 0826502A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solution
- tank
- wiping
- fresh
- ultrafiltration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000004140 cleaning Methods 0.000 title abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 26
- 238000005189 flocculation Methods 0.000 claims abstract description 23
- 230000016615 flocculation Effects 0.000 claims abstract description 23
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 20
- 239000012153 distilled water Substances 0.000 claims abstract description 14
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 12
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000001110 calcium chloride Substances 0.000 claims abstract description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 137
- 239000000976 ink Substances 0.000 claims description 14
- 238000001704 evaporation Methods 0.000 claims description 13
- 230000008020 evaporation Effects 0.000 claims description 13
- 238000001914 filtration Methods 0.000 claims description 11
- 239000004359 castor oil Substances 0.000 claims description 9
- 235000019438 castor oil Nutrition 0.000 claims description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 9
- 239000012266 salt solution Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 238000011109 contamination Methods 0.000 claims description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 2
- 238000005086 pumping Methods 0.000 claims description 2
- 235000004443 Ricinus communis Nutrition 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 1
- 239000003518 caustics Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 3
- 108010039491 Ricin Proteins 0.000 abstract description 2
- 239000012530 fluid Substances 0.000 abstract 2
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F35/00—Cleaning arrangements or devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41P—INDEXING SCHEME RELATING TO PRINTING, LINING MACHINES, TYPEWRITERS, AND TO STAMPS
- B41P2235/00—Cleaning
- B41P2235/30—Recovering used solvents or residues
- B41P2235/32—Recovering used solvents or residues by distilling
Definitions
- the present invention relates to a production method fresh wiping solution, containing at least 90% of water and additives, and treating this wiping solution used by the inks of one or multiple intaglio printing machines operating in closed circuit and a device for the implementation of this process.
- the printing plates mounted on the plate cylinder in which the designs are engraved, are wiped by the friction of a wiping cylinder turning in the same direction as the plate cylinder and which removes the ink outside the sizes of the plate.
- a wiping cylinder turning in the same direction as the plate cylinder and which removes the ink outside the sizes of the plate.
- the part bottom of it is in a tank wiping, this tank being further equipped with brushes and squeegees.
- a system of nozzles spurts from the fresh wiping solution on the wiping cylinder and the fresh solution when mixed with the ink goes exit the wiping tank as used solution.
- US patent 5,390,598 describes a such as permanent cylinder cleaning system wiping in an intaglio printing machine.
- wiping solutions is described in patent DE 1,546,776 and consists of an aqueous solution containing 1 to 5% by weight of alkaline detergent, 2 to 10% by weight of a commercial cleaning product. containing alkaline phosphate and 1 to 10% by weight of a wetting agent. More particularly, this aqueous solution contains 1.5 to 2.5% by weight of caustic soda NaOH, 2 to 5% by weight of sodium phosphate Na 3 (PO 4 ) and 1 to 3% by weight of castor oil sulfonated.
- the recycling capacity of this process after ultrafiltration is around 80%, this value additionally dependent on the quality of the ink used and of its concentration in the wiping solution.
- the object of the present invention is to provide a closed circuit process, in particular in which most of the water and flocculation products in circuit is recovered from the used wiping solution, reused to produce the fresh wiping solution and no longer rejected at taste. Consumption of water and flocculation of the process can thus be strongly decreased and we will only get waste solids which can then be treated with respect environmental protection standards.
- the invention also makes it possible to no longer use coal active that corrected the chemical oxygen demand.
- Such a method of producing wiping solution fresh and used wiping solution treatment is defined by the steps of claims 1 and 2.
- Independent claim 9 defines a device for implementing the method according to the invention.
- Claims 10 to 18 define modes of particular realization of the setting device process work.
- Figure 1 is the block diagram of a method of wiping solution treatment known in the state of the technique.
- FIG. 2 is the block diagram of a method of production and recycling of the wiping solution according to the invention.
- Figure 3 is the block diagram of a setting device implementing the method according to the invention.
- the wiping solution may optionally contain more detergent.
- the wiping solution fresh is produced by mixing water, caustic soda and sulfonated castor oil.
- the fresh solution is introduced into one or more wiping tanks in step (b) of the process and contaminated with the inks.
- the used wiping solution is then transferred from the wiping tank (s) to the ultrafiltration installation to undergo step (c) of the process, namely ultrafiltration.
- This step (c) produces on the one hand a clear solution which is without further recycled as a fresh wiping solution in step (d), and on the other hand a concentrated residual solution containing ink.
- This ultrafiltration step makes it possible to recover approximately 80% of the solution.
- the concentrated residual solution then undergoes step (e) of the process which is flocculation. This flocculation occurs by adding calcium chloride CaCl 2 and ferric chloride FeCl 3 .
- step (f) of the process The result of the flocculation is then filtered in step (f) of the process, and solid residues and a filtered solution are thus obtained.
- this filtered solution is neutralized by adding hydrochloric acid HCL.
- the neutralized solution undergoes in stage (h) an evaporation which gives on the one hand distilled water, and on the other a concentrated saline solution.
- the distilled water is collected in order to use it to produce fresh wiping solution in step (i) of the process, while the concentrated salt solution is filtered in step (j) and this filtration gives d on one side of the solid salts and on the other a solution highly concentrated in salt which is reused to carry out the flocculation of step (e) of the process.
- Distilled water is sent to a tank where it is mixed with softened water taken from the city network. This mixture is finally used to produce fresh wiping solution by adding sulphonated castor oil and caustic soda NaOH, in the proportions indicated above for example
- Figure 3 shows an example of a device for implementation of the process which is the subject of the invention.
- This device comprises a tank 1 into which the spent solution passes and is transferred into a first ultrafiltration tank 2, from which it then passes into a first ultrafiltration unit 3.
- the clear solution from this first ultrafiltration unit 3 is brought into a tank of fresh solution 21 from where it is reused as a fresh wiping solution, while the concentrated residual solution from this first ultrafiltration unit 3 is sent to a second ultrafiltration tank 4 and there in a second ultrafiltration unit 5.
- the clear solution from this second ultrafiltration unit 5 is in turn sent to the fresh solution tank 21 to be reused as a fresh wiping solution, while the concentrated residual solution is brought into a concentrated solution tank 6.
- This concentrated residual solution then passes into the flocculation 7 where the flocculation step is carried out.
- Means for adding the calcium chloride CaCl 2 and the ferric chloride FeCl 3 necessary for flocculation are mounted on the flocculation tank 7. These means comprise at least one reservoir and a metering pump for each compound added.
- the flocculated solution is then brought into a filter press 8 separating the solid residues from the solution.
- the filtered residual solution is stored in a filtered solution tank 9.
- This solution is then brought into a neutralization tank 10 where it is neutralized by the addition of hydrochloric acid HCL and recovered in a neutralized solution tank 11.
- means for adding hydrochloric acid are mounted on the neutralization tank 10. These means comprise at least one tank and a metering pump.
- the solution is sent to a first evaporation unit 12.
- the water vapor obtained from this first evaporation unit 12 is recovered in a tank of distilled water 17, while the solution salt passes into a salt solution tank 13 then into a second evaporation unit 14.
- the water vapor obtained from this second evaporation unit 14 is also recovered in the distilled water tank while the salt solution and concentrate passes into a tank 15 and then into a filtration system 16 from which one side extracts solid salts and the other a solution which is recycled by suitable means, such as for example a pump, in the flocculation tank 7
- suitable means such as for example a pump
- the water is sent to a water tank 19, which also receives city water once it has passed through a water softener 18, and the water softened and the distilled water are sent to the wiping solution mixture tank 20 where the fresh solution is prepared by adding sulphonated castor oil and caustic soda. This is finally transported in the fresh solution tank 21 and again passes through the wiping tank or tanks of the printing machines after use.
- the modes of execution described are given for example and variations as part of the claimed protection are possible.
- the proportion of the components of the wiping solution may be slightly varied.
- the acid used to perform neutralization can be acid sulfuric.
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Detergent Compositions (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH215296 | 1996-09-02 | ||
CH152/96 | 1996-09-02 | ||
CH215296 | 1996-09-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0826502A1 true EP0826502A1 (de) | 1998-03-04 |
EP0826502B1 EP0826502B1 (de) | 2000-05-17 |
Family
ID=4227097
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97810589A Expired - Lifetime EP0826502B1 (de) | 1996-09-02 | 1997-08-21 | Vorrichtung und Verfahren zum Herstellen einer Reinigungslösung und zum Behandeln der verwendeten Reinigungslösung |
Country Status (10)
Country | Link |
---|---|
US (1) | US5855787A (de) |
EP (1) | EP0826502B1 (de) |
JP (1) | JP4035593B2 (de) |
KR (1) | KR100433740B1 (de) |
CN (1) | CN1116398C (de) |
AT (1) | ATE192972T1 (de) |
AU (1) | AU722323B2 (de) |
CA (1) | CA2193303C (de) |
DE (1) | DE69702032T2 (de) |
UA (1) | UA28061C2 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0927632B1 (de) * | 1997-12-31 | 2003-10-15 | Kba-Giori S.A. | Vorrichtung und Verfahren zum Herstellen einer Reinigungslösung und zum Behandeln der verwendeten Reinigungslösung |
DE10227675A1 (de) * | 2002-06-20 | 2004-01-08 | Neratec Ag | Verfahren und Vorrichtung zum Aufbereiten von gebrauchtem Waschmittel |
EP2363290A1 (de) | 2010-03-05 | 2011-09-07 | KBA-NotaSys SA | Vorrichtung und Verfahren zum Recyceln der Reinigungslösung einer oder mehrerer Tiefdruckmaschinen |
EP2684697A1 (de) * | 2012-07-09 | 2014-01-15 | Oesterreichische Banknoten- und Sicherheitsdruck GmbH | Aufbereitungsanlage |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4212735B2 (ja) | 1999-10-13 | 2009-01-21 | 株式会社小森コーポレーション | ワイピング液処理方法およびその装置 |
EP1361046A1 (de) | 2002-05-06 | 2003-11-12 | Kba-Giori S.A. | Sprühdüse für eine Reinigungsvorrichtung in einer Druckmaschine |
WO2004050561A1 (en) * | 2002-12-04 | 2004-06-17 | Idaho Research Foundation, Inc. | Reactive filtration |
US7445721B2 (en) * | 2003-12-03 | 2008-11-04 | Idaho Research Foundation, Inc. | Reactive filtration |
US8071055B2 (en) * | 2002-12-04 | 2011-12-06 | Blue Water Technologies, Inc. | Water treatment techniques |
US8080163B2 (en) | 2002-12-04 | 2011-12-20 | Blue Water Technologies, Inc. | Water treatment method |
JP2006210751A (ja) * | 2005-01-31 | 2006-08-10 | Mitsubishi Chemical Engineering Corp | シンナーのリサイクル供給装置 |
US7713426B2 (en) * | 2008-01-11 | 2010-05-11 | Blue Water Technologies, Inc. | Water treatment |
EP2559555B1 (de) * | 2011-08-15 | 2016-09-07 | Komori Corporation | Wischervorrichtung |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0043624A1 (de) * | 1980-07-07 | 1982-01-13 | Maschinenfabrik GOEBEL GmbH | Einrichtung zum Reinigen eines an einer Stahlstichdruckmaschine befindlichen Wischzylinders |
EP0514670A1 (de) * | 1991-05-23 | 1992-11-25 | M.A.N.-ROLAND Druckmaschinen Aktiengesellschaft | Vorrichtung zum Waschen eines Zylinders einer Druckmaschine |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4293416A (en) * | 1977-05-27 | 1981-10-06 | Entenmann's, Inc. | Apparatus for treating plant effluent |
US4966628A (en) * | 1988-04-27 | 1990-10-30 | Sicpa Holding Sa | Security document printing ink |
EP0340163B1 (de) * | 1988-04-27 | 1992-12-30 | Sicpa Holding S.A. | Drucktinte für Sichereitsdokumente |
US4938876A (en) * | 1989-03-02 | 1990-07-03 | Ohsol Ernest O | Method for separating oil and water emulsions |
DE69401525T2 (de) * | 1993-04-30 | 1997-07-31 | De La Rue Giori Sa | Wischvorrichtung einer Stichtiefdruckmaschine |
US5569701A (en) * | 1995-05-31 | 1996-10-29 | Bureau Of Engraving And Printing | Soybean oil-based intaglio ink and method for making same |
-
1996
- 1996-12-04 UA UA96124541A patent/UA28061C2/uk unknown
- 1996-12-18 CA CA002193303A patent/CA2193303C/en not_active Expired - Lifetime
- 1996-12-26 US US08/773,140 patent/US5855787A/en not_active Expired - Lifetime
- 1996-12-26 JP JP34868896A patent/JP4035593B2/ja not_active Expired - Lifetime
- 1996-12-31 KR KR1019960082495A patent/KR100433740B1/ko active IP Right Grant
-
1997
- 1997-01-15 CN CN97102248A patent/CN1116398C/zh not_active Expired - Lifetime
- 1997-01-28 AU AU12395/97A patent/AU722323B2/en not_active Expired
- 1997-08-21 AT AT97810589T patent/ATE192972T1/de active
- 1997-08-21 EP EP97810589A patent/EP0826502B1/de not_active Expired - Lifetime
- 1997-08-21 DE DE69702032T patent/DE69702032T2/de not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0043624A1 (de) * | 1980-07-07 | 1982-01-13 | Maschinenfabrik GOEBEL GmbH | Einrichtung zum Reinigen eines an einer Stahlstichdruckmaschine befindlichen Wischzylinders |
EP0514670A1 (de) * | 1991-05-23 | 1992-11-25 | M.A.N.-ROLAND Druckmaschinen Aktiengesellschaft | Vorrichtung zum Waschen eines Zylinders einer Druckmaschine |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0927632B1 (de) * | 1997-12-31 | 2003-10-15 | Kba-Giori S.A. | Vorrichtung und Verfahren zum Herstellen einer Reinigungslösung und zum Behandeln der verwendeten Reinigungslösung |
DE10227675A1 (de) * | 2002-06-20 | 2004-01-08 | Neratec Ag | Verfahren und Vorrichtung zum Aufbereiten von gebrauchtem Waschmittel |
EP2363290A1 (de) | 2010-03-05 | 2011-09-07 | KBA-NotaSys SA | Vorrichtung und Verfahren zum Recyceln der Reinigungslösung einer oder mehrerer Tiefdruckmaschinen |
WO2011107950A1 (en) | 2010-03-05 | 2011-09-09 | Kba-Notasys Sa | Installation and process for recycling wiping solution of one or more intaglio printing presses |
CN102802952A (zh) * | 2010-03-05 | 2012-11-28 | 卡巴-诺塔赛斯有限公司 | 用于对一个或多个凹版印刷机的擦拭溶液进行再循环的设备和方法 |
RU2564582C2 (ru) * | 2010-03-05 | 2015-10-10 | КБА-НотаСис СА | Оборудование и способ для повторного использования раствора для удаления краски одной или нескольких машин глубокой печати |
KR101867341B1 (ko) * | 2010-03-05 | 2018-06-15 | 케이비에이-노타시스 에스에이 | 하나 이상의 음각 인쇄 프레스들의 와이핑 용액을 재활용하기 위한 설비 및 방법 |
US10603896B2 (en) | 2010-03-05 | 2020-03-31 | Kba-Notasys Sa | Installation and process for recycling wiping solution of one or more intaglio printing presses |
EP2684697A1 (de) * | 2012-07-09 | 2014-01-15 | Oesterreichische Banknoten- und Sicherheitsdruck GmbH | Aufbereitungsanlage |
Also Published As
Publication number | Publication date |
---|---|
AU722323B2 (en) | 2000-07-27 |
CA2193303C (en) | 2005-04-12 |
CN1116398C (zh) | 2003-07-30 |
JPH1085789A (ja) | 1998-04-07 |
KR19980023916A (ko) | 1998-07-06 |
CN1175625A (zh) | 1998-03-11 |
US5855787A (en) | 1999-01-05 |
AU1239597A (en) | 1998-03-05 |
KR100433740B1 (ko) | 2004-09-16 |
DE69702032T2 (de) | 2001-01-18 |
DE69702032D1 (de) | 2000-06-21 |
UA28061C2 (uk) | 2000-10-16 |
EP0826502B1 (de) | 2000-05-17 |
ATE192972T1 (de) | 2000-06-15 |
JP4035593B2 (ja) | 2008-01-23 |
CA2193303A1 (en) | 1998-03-03 |
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