EP0796393A1 - Elektromagnetisch betätigbares ventil, insbesondere brennstoffeinspritzventil - Google Patents
Elektromagnetisch betätigbares ventil, insbesondere brennstoffeinspritzventilInfo
- Publication number
- EP0796393A1 EP0796393A1 EP96920711A EP96920711A EP0796393A1 EP 0796393 A1 EP0796393 A1 EP 0796393A1 EP 96920711 A EP96920711 A EP 96920711A EP 96920711 A EP96920711 A EP 96920711A EP 0796393 A1 EP0796393 A1 EP 0796393A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- valve
- valve member
- stop element
- valve according
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 20
- 238000002347 injection Methods 0.000 title claims abstract description 17
- 239000007924 injection Substances 0.000 title claims abstract description 17
- 238000007906 compression Methods 0.000 claims abstract description 6
- 238000002485 combustion reaction Methods 0.000 claims abstract description 4
- 239000012530 fluid Substances 0.000 claims description 10
- 239000007921 spray Substances 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 claims 1
- 238000004026 adhesive bonding Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229910000639 Spring steel Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M51/00—Fuel-injection apparatus characterised by being operated electrically
- F02M51/06—Injectors peculiar thereto with means directly operating the valve needle
- F02M51/061—Injectors peculiar thereto with means directly operating the valve needle using electromagnetic operating means
- F02M51/0625—Injectors peculiar thereto with means directly operating the valve needle using electromagnetic operating means characterised by arrangement of mobile armatures
- F02M51/0632—Injectors peculiar thereto with means directly operating the valve needle using electromagnetic operating means characterised by arrangement of mobile armatures having a spherically or partly spherically shaped armature, e.g. acting as valve body
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M51/00—Fuel-injection apparatus characterised by being operated electrically
- F02M51/06—Injectors peculiar thereto with means directly operating the valve needle
- F02M51/08—Injectors peculiar thereto with means directly operating the valve needle specially for low-pressure fuel-injection
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M61/00—Fuel-injectors not provided for in groups F02M39/00 - F02M57/00 or F02M67/00
- F02M61/16—Details not provided for in, or of interest apart from, the apparatus of groups F02M61/02 - F02M61/14
- F02M61/18—Injection nozzles, e.g. having valve seats; Details of valve member seated ends, not otherwise provided for
- F02M61/1853—Orifice plates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S239/00—Fluid sprinkling, spraying, and diffusing
- Y10S239/90—Electromagnetically actuated fuel injector having ball and seat type valve
Definitions
- Electromagnetically actuated valve in particular fuel injection valve
- the invention is based on an electromagnetically actuated valve, in particular a fuel injector according to the preamble of the main claim.
- a fuel injector which has a spherical valve member which can move axially in the valve and also serves as a valve closing body.
- the spherical valve member interacts with a fixed, non-magnetic valve seat, the one end position of the valve member when the solenoid is not energized is determined by the contact of the valve member with the valve seat.
- a magnetic inner pole lies exactly opposite the valve seat.
- the spherical valve member is attracted toward the inner pole, abutting directly on a contact surface of the inner pole.
- the valve is now open.
- the valve member is surrounded by a magnetic side pole, which is a magnetic disc with a cylindrical opening.
- the magnetic field lines run from the side pole to the inner pole via the valve member, a large radial air gap occurring between the side pole and the valve member, which results from the geometry of the cylindrical opening.
- Another disadvantage is the difficult handling of the inner pole when designing the stop surface. In the shaping and surface treatment (coating) of these
- the electromagnetically actuated valve according to the invention in particular fuel injection valve, with the characterizing features of the main claim has the advantage that a high effectiveness of the magnetic circuit is achieved in a simple and inexpensive manner, since the losses of the magnetic field can be kept very low due to simple design measures.
- An inventive, soft magnetic guide body surrounding a spherical valve member ensures, due to its partially spherical design in the area of an inner guide opening, both good guidance of the valve member and an optimal transition of the magnetic field lines to the valve member, since a radial air gap formed between the two can be kept to a minimum.
- the measures listed in the subclaims allow advantageous developments and improvements of the electromagnetically actuated valve specified in the main claim.
- a stop element arranged between a core serving as the inner pole and the spherical valve member can be shaped very well as a separate insert, can easily be subjected to a surface treatment (e.g. coating) and is also easy to assemble. It is advantageous to have the stop element in the form of a disk and to have it pressed against the core by means of a compression spring, the stop element being guided by a non-magnetic intermediate part.
- a particular advantage is that the stop element is designed as a large-pored sintered body.
- the stop element is then sintered from balls that have diameters in the tenths of a millimeter range. A fluid can still flow well between the sintered balls, so that no additional flow channels are required.
- the stop element also acts as a filter that keeps coarse dirt away from the seating area.
- the spherical stop surface of the stop element does not exactly match the surface contour or the radius of the spherical valve member 97/13977 PC17DE96 / 01136
- FIG. 1 shows a partially illustrated electromagnetically actuated valve according to the invention
- FIG. 2 shows a section along the line II-II through a stop element
- FIG. 3 shows the striking of a valve member on the stop element on an outer region
- FIG. 4 shows the striking of a valve member on the stop element on an inner region
- 5 shows the striking of a valve member on the stop element in a central region.
- the electromagnetically actuated valve in the form of an injection valve for fuel injection systems of mixture-compressing, spark-ignited internal combustion engines, for example and only partially shown in FIG. 1, has an electromagnetic circuit including a magnet coil 1, a stepped, tubular magnet housing 3 and a core serving as an inner pole and fuel inlet connector 5, which has a constant diameter over its entire length, for example.
- the magnet coil 1 is embedded in a certain way with its coil former 6 in the stepped magnet housing 3, that is, it is completely surrounded by the magnet housing 3 in the circumferential direction and at least partially downward.
- a cover element not shown, which can be inserted into the magnet housing 3, covers the magnet coil 1 upwards and serves to close the magnetic circuit. The cover element thus connects the core 5 to the magnet housing 3 above the magnet coil 1.
- a step 7 in the magnet housing 3 directly below the coil body 6 results in a reduction in the diameter of the magnet housing 3 seen in the downstream direction, which, among other things, with its downstream end region 9 also acts as a valve seat bracket.
- the coil former 6 lies, for example, on the step 7 of the magnet housing 3.
- the tubular magnet housing 3 extends concentrically to a longitudinal valve axis 10.
- a longitudinal bore 12 runs in the magnet housing 3, which is also designed concentrically to the longitudinal valve axis 10.
- a spherical valve member 13 is arranged in the longitudinal bore 12 and represents both the armature and the valve closing body of the injection valve. With a lower core end
- the coil former 6 lies e.g. on an upper end face 16 of the intermediate part 15.
- the injection valve is actuated electromagnetically in a known manner.
- the electromagnetic circuit with the magnet coil 1 serves to Magnet housing 3 and the core 5.
- a cylindrical valve seat body 20 which has a fixed valve seat 21, is tightly mounted in the longitudinal bore 12, for example by welding.
- a disk-shaped guide member 25 is used to guide the valve member 13 during its axial movement along the valve longitudinal axis 10.
- the spherical valve member 13 interacts with the valve seat 21 of the valve seat body 20 which tapers in the direction of the truncated cone in the direction of flow.
- the circumference of the valve seat body 20 has a slightly smaller diameter than the longitudinal bore 12 of the magnet housing 3.
- the valve seat body 20 is concentric and firm with an, for example, cup-shaped injection orifice plate 27, for example by a circumferential, dense and medium a weld seam formed by a laser.
- the cup-shaped spray perforated disk 27 has a circumferential, downstream one
- Holding edge 30 A direct flow of the fluid, in particular the fuel, into an intake line of the internal combustion engine outside the spray openings 29 is avoided by a weld seam 31 between the spray hole disc 27 and the magnet housing 3.
- the insertion depth of the valve seat body 20 with the cup-shaped spray perforated disk 27 or the arrangement of a disk-shaped stop element 33 upstream of the valve member 13 determine the size of the
- the one end position of the Valve member 13 is fixed when the solenoid 1 is not excited by the contact of the valve member 13 on the valve seat 21 of the valve seat body 20, while the other end position of the valve member 13 results when the solenoid 1 is excited by its contact with the stop element 33.
- An adjusting sleeve 36 which is inserted into a flow bore 35 of the core 5 concentrically to the longitudinal axis 10 of the valve and is formed, for example, from rolled spring steel sheet, serves to adjust the
- the return spring 17 also projects through the stop element 33 in a continuous inner opening 38 which, for example, has a diameter which corresponds exactly to the diameter of the flow bore 35 of the core 5.
- the opening 38 thus represents a continuation of the flow bore 35.
- the stop element 33 bears against the core end 14 of the core 5.
- the end face 40 is machined, for example, so that the stop element 33 only contacts the core 5 and not the intermediate part 15.
- a circumferential bevel 41 is provided, for example, on the outer circumference of the stop element 33. Otherwise, the stop element 33 is guided in the circumferential direction by the intermediate part 15.
- the opposite lower stop face 43 facing the valve member 13 is dome-shaped in order to make the magnetic circuit as effective as possible through small air gaps.
- FIGS. 3 to 5 show various possibilities for forming the spherical geometry on the stop element 33, which will be explained in more detail later.
- the dome-shaped stop surface 43 is interrupted by at least one, for example four, radial and at the same time also downstream fluid passages, in particular fuel passages 44.
- the at least one fuel passage 44 is introduced in a groove-like manner in the stop element 33.
- the stop element 33 has a stepped outer contour, an upper region having a larger outer diameter than a lower region containing the fuel passages 44. This results in a shoulder 46 on the stop element 33 against which a compression spring 47 presses. While the compression spring 47 abutting the stop element 33 presses the stop element 33 against the core end 14 of the core 5, its opposite side is supported on the guide body 25, which in turn rests on the valve seat body 20.
- the stop element 33 is made of soft magnetic material and is surface-treated at least on the lower spherical stop surface 43 for reasons of wear protection, e.g. chrome-plated.
- the spherical valve member 13 has a spherical equator 48 which lies in a spherical plane which divides the sphere into two spherical halves of equal size.
- the disk-shaped extends in the area of this spherical equator 48
- the guide body 25 which has a guide opening 49 through which the valve member 13 moves.
- the guide body 25 is made of a soft magnetic material and, at least from the axial height of the ball equator 48 with the valve member 13 resting on the valve seat 21, is dome-shaped in the downstream direction in accordance with the contour of the valve member 13.
- the magnetic flux passes through the magnet housing 3, the guide body 25, the valve member 13 and the stop element 33 to the core 5. Due to the dome-shaped design of the guide opening 49 on the guide body 25, the magnetic flux can be minimized Exceed radial air gap on valve member 13.
- the upper part of the guide opening 49 is, for example, cylindrical.
- the Fuhrungskorper 25 can also be installed rotated by 180 ° so that the dome-shaped section of the guide opening 49 is above the ball equator 48.
- axially extending, groove-like depressions can be provided on the guide opening 49 of the guide body 25.
- the guide body 25 is produced, for example, by stamping, sintering or MIM technology (metal injection molding).
- the stop element 33 can also be produced by embossing, sintering or MIM technology.
- the stop element 33 can be sintered from balls that have diameters in the tenth of a millimeter range. In such a coarse-pored sintered body, the fluid passages, in particular fuel passages 44, are then no longer necessary, since the fuel can flow through between the sintered balls. Hydraulic gluing can be effectively prevented by the large-pore surface of the stop element 33.
- the stop element 33 also acts as a filter that keeps dirt away from the seating area.
- a holding ring 52 made of sheet metal is mounted on the end region 9 of the magnet housing 3.
- This circumferential, hook-shaped retaining ring 52 has tabs 53 at three or four points on the circumference, which prevent the retaining ring 52 from being stripped off by self-locking when the injection valve is dismantled.
- an annular groove is formed on the outer circumference of the magnet housing 3, in which a sealing ring 55 is arranged.
- Figure 2 is a sectional view of the stop element 33 along the line II-II in Figure 1.
- four groove-shaped fuel passages 44 are provided, which run radially outward from the inner opening 38. Another number of fuel passages 44 is also conceivable.
- Fuel passages 44 can be dispensed with entirely if the stop element 33 is designed as a coarse-pored sintered body.
- the geometry of the spherical stop surface 43 of the stop element 33 should not correspond exactly to the surface contour or the radius of the spherical valve member 13.
- Figures 3, 4 and 5 show possible contours to avoid hydraulic gluing.
- the valve member 13 can strike only on an outer region (FIG. 3), only on an inner region (FIG. 4) or only on a central region (FIG. 5) of the stop surface 43 of the stop element 33, while the respective other regions of the stop surface 43 coexist very close to
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Fuel-Injection Apparatus (AREA)
- Magnetically Actuated Valves (AREA)
- Catching Or Destruction (AREA)
- Particle Formation And Scattering Control In Inkjet Printers (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19537382 | 1995-10-07 | ||
DE19537382A DE19537382A1 (de) | 1995-10-07 | 1995-10-07 | Elektromagnetisch betätigbares Ventil, insbesondere Brennstoffeinspritzventil |
PCT/DE1996/001136 WO1997013977A1 (de) | 1995-10-07 | 1996-06-27 | Elektromagnetisch betätigbares ventil, insbesondere brennstoffeinspritzventil |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0796393A1 true EP0796393A1 (de) | 1997-09-24 |
EP0796393B1 EP0796393B1 (de) | 2001-06-13 |
Family
ID=7774265
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96920711A Expired - Lifetime EP0796393B1 (de) | 1995-10-07 | 1996-06-27 | Elektromagnetisch betätigbares ventil, insbesondere brennstoffeinspritzventil |
Country Status (9)
Country | Link |
---|---|
US (1) | US5820032A (de) |
EP (1) | EP0796393B1 (de) |
JP (1) | JP3737119B2 (de) |
KR (1) | KR100420746B1 (de) |
CN (1) | CN1067463C (de) |
BR (1) | BR9606667A (de) |
DE (2) | DE19537382A1 (de) |
RU (1) | RU2160378C2 (de) |
WO (1) | WO1997013977A1 (de) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19705431A1 (de) * | 1997-02-13 | 1998-08-20 | Bosch Gmbh Robert | Rückhaltesystem |
DE19712591A1 (de) * | 1997-03-26 | 1998-10-01 | Bosch Gmbh Robert | Brennstoffeinspritzventil und Verfahren zur Herstellung sowie Verwendung eines Brennstoffeinspritzventils |
DE19712589C1 (de) * | 1997-03-26 | 1998-06-04 | Bosch Gmbh Robert | Brennstoffeinspritzventil und Verfahren zur Herstellung einer Ventilnadel eines Brennstoffeinspritzventils |
DE19744739A1 (de) | 1997-10-10 | 1999-04-15 | Bosch Gmbh Robert | Brennstoffeinspritzventil |
DE19757117A1 (de) | 1997-12-20 | 1999-06-24 | Bosch Gmbh Robert | Verfahren zur Herstellung eines Ventilsitzkörpers für ein Brennstoffeinspritzventil und Brennstoffeinspritzventil |
DE19810330A1 (de) * | 1998-03-11 | 1999-09-16 | Mannesmann Rexroth Ag | Magnetventil |
DE19856920A1 (de) * | 1998-12-10 | 2000-06-15 | Bosch Gmbh Robert | Brennstoffeinspritzventil |
US6142394A (en) * | 1999-06-30 | 2000-11-07 | Caterpillar Inc. | Valve seat for a ball and pin valve member in a hydraulically actuated fuel injector |
JP2001082283A (ja) * | 1999-09-20 | 2001-03-27 | Hitachi Ltd | 電磁式燃料噴射弁 |
US6554591B1 (en) * | 2001-11-26 | 2003-04-29 | Motorola, Inc. | Micropump including ball check valve utilizing ceramic technology and method of fabrication |
US6924965B2 (en) * | 2001-12-29 | 2005-08-02 | Magnasource, Llc | Electro magnetically-operated device, and a method of operating the same |
DE10351207A1 (de) * | 2003-11-03 | 2005-06-02 | Robert Bosch Gmbh | Ventil zum Steuern eines Fluids |
DE102005006228A1 (de) * | 2005-02-10 | 2006-08-17 | Continental Teves Ag & Co. Ohg | Elektromagnetventil |
DE102005061409A1 (de) * | 2005-12-22 | 2007-06-28 | Robert Bosch Gmbh | Elektromagnetisch betätigbares Ventil |
DE102007061862A1 (de) * | 2007-12-19 | 2009-06-25 | Thomas Magnete Gmbh | Schaltbare Magnetanordnung als Betätigungselement für ein Ventil oder andere Funktionselemente |
CN101551036B (zh) * | 2008-03-31 | 2011-06-29 | 台达电子工业股份有限公司 | 电磁阀 |
CN102251896B (zh) * | 2011-06-14 | 2012-07-11 | 常州博瑞油泵油嘴有限公司 | 柴油机高压共轨喷油器的平面启闭结构 |
CN102230435B (zh) * | 2011-06-14 | 2012-07-11 | 常州博瑞油泵油嘴有限公司 | 平面启闭型柴油机高压共轨喷油器 |
DE102012207986A1 (de) * | 2012-05-14 | 2013-11-14 | Continental Teves Ag & Co. Ohg | Elektromagnetventil, insbesondere für schlupfgeregelte Kraftfahrzeugbremsanlagen |
FR3002003A1 (fr) * | 2013-02-11 | 2014-08-15 | Bosch Gmbh Robert | Procede de realisation d'une soupape a commande electromagnetique |
CN104074656B (zh) * | 2014-06-20 | 2016-08-24 | 东风悦达起亚汽车有限公司 | 一种喷油嘴 |
US11462960B2 (en) * | 2019-12-02 | 2022-10-04 | Hiwin Mikrosystem Corp. | Rotor with first and second permanent magnets having support members and slots |
RU205532U1 (ru) * | 2021-04-19 | 2021-07-19 | Общество с ограниченной ответственностью Управляющая компания "Алтайский завод прецизионных изделий" | Дозатор шариков |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS603425Y2 (ja) * | 1978-07-05 | 1985-01-30 | 日産自動車株式会社 | 流量制御用電磁弁 |
JPS5510016A (en) * | 1978-07-06 | 1980-01-24 | Nissan Motor Co Ltd | Fuel injection valve |
JPS5546576U (de) * | 1978-09-22 | 1980-03-26 | ||
JPS55130061U (de) * | 1979-03-08 | 1980-09-13 | ||
JPS5675955A (en) * | 1979-11-21 | 1981-06-23 | Nippon Denso Co Ltd | Solenoid type fuel injection valve |
EP0063952B1 (de) * | 1981-04-29 | 1986-02-05 | Solex (U.K.) Limited | Eine elektromagnetische Flüssigkeitseinspritzvorrichtung und ein Einzelpunktkraftstoffeinspritzsystem für eine Verbrennungskraftmaschine |
US4434765A (en) * | 1981-10-30 | 1984-03-06 | Colt Industries Operating Corp. | Fuel injection apparatus and system |
-
1995
- 1995-10-07 DE DE19537382A patent/DE19537382A1/de not_active Withdrawn
-
1996
- 1996-06-27 CN CN96191164A patent/CN1067463C/zh not_active Expired - Fee Related
- 1996-06-27 JP JP51460197A patent/JP3737119B2/ja not_active Expired - Fee Related
- 1996-06-27 BR BR9606667A patent/BR9606667A/pt not_active IP Right Cessation
- 1996-06-27 US US08/817,457 patent/US5820032A/en not_active Expired - Fee Related
- 1996-06-27 DE DE59607084T patent/DE59607084D1/de not_active Expired - Fee Related
- 1996-06-27 WO PCT/DE1996/001136 patent/WO1997013977A1/de active IP Right Grant
- 1996-06-27 RU RU97111874/06A patent/RU2160378C2/ru not_active IP Right Cessation
- 1996-06-27 EP EP96920711A patent/EP0796393B1/de not_active Expired - Lifetime
- 1996-06-27 KR KR1019970703755A patent/KR100420746B1/ko not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO9713977A1 * |
Also Published As
Publication number | Publication date |
---|---|
US5820032A (en) | 1998-10-13 |
JP3737119B2 (ja) | 2006-01-18 |
WO1997013977A1 (de) | 1997-04-17 |
DE59607084D1 (de) | 2001-07-19 |
KR980700516A (ko) | 1998-03-30 |
RU2160378C2 (ru) | 2000-12-10 |
KR100420746B1 (ko) | 2004-05-20 |
CN1166196A (zh) | 1997-11-26 |
JPH10510609A (ja) | 1998-10-13 |
CN1067463C (zh) | 2001-06-20 |
BR9606667A (pt) | 1997-09-30 |
DE19537382A1 (de) | 1997-04-10 |
EP0796393B1 (de) | 2001-06-13 |
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Legal Events
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