EP0787808B1 - Method and device for in-line-pickling of hot rolled strip in sequence with thin slab production - Google Patents
Method and device for in-line-pickling of hot rolled strip in sequence with thin slab production Download PDFInfo
- Publication number
- EP0787808B1 EP0787808B1 EP97250023A EP97250023A EP0787808B1 EP 0787808 B1 EP0787808 B1 EP 0787808B1 EP 97250023 A EP97250023 A EP 97250023A EP 97250023 A EP97250023 A EP 97250023A EP 0787808 B1 EP0787808 B1 EP 0787808B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strip
- pickling
- plant
- rolled
- thin slab
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005554 pickling Methods 0.000 title claims description 55
- 238000000034 method Methods 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title description 6
- 230000008569 process Effects 0.000 claims description 23
- 238000001816 cooling Methods 0.000 claims description 19
- 238000005266 casting Methods 0.000 claims description 15
- 238000005096 rolling process Methods 0.000 claims description 14
- 238000004804 winding Methods 0.000 claims description 7
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 4
- 238000009966 trimming Methods 0.000 claims description 4
- 238000010924 continuous production Methods 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 230000008439 repair process Effects 0.000 claims description 2
- 238000003466 welding Methods 0.000 claims description 2
- 238000010583 slow cooling Methods 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 238000005520 cutting process Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 238000002791 soaking Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000003860 storage Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 235000021110 pickles Nutrition 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910000734 martensite Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G3/00—Apparatus for cleaning or pickling metallic material
- C23G3/02—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B13/00—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
- B21B13/22—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories for rolling metal immediately subsequent to continuous casting, i.e. in-line rolling of steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B15/0085—Joining ends of material to continuous strip, bar or sheet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B15/0007—Cutting or shearing the product
- B21B2015/0021—Cutting or shearing the product in the rolling direction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B2015/0057—Coiling the rolled product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B39/00—Arrangements for moving, supporting, or positioning work, or controlling its movement, combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B39/02—Feeding or supporting work; Braking or tensioning arrangements, e.g. threading arrangements
- B21B39/08—Braking or tensioning arrangements
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/573—Continuous furnaces for strip or wire with cooling
Definitions
- the invention relates to a working method and a system for pickling in one Thin slab plant produced and subsequently hot rolled strip, especially low-carbon steel strip, in a directly to the Rolling process subsequent continuous process,
- a working process for pickling a and produced in a thin slab plant Subsequently hot-rolled strip is useful if there are large batch sizes can be processed, especially low-carbon steels are suitable for Execution of the procedure.
- the working method is characterized by the im Claim 1 specified process steps.
- these successive Process steps can be pickled a low-carbon steel strip inline, the through the thin slab caster and the subsequent hot strip mill given speeds are appropriate with appropriate coordination that To master temperature control in preparation for the pickling process as well the pickling process for the common rolling stock thicknesses and widths.
- the procedure can be perform inline, i.e. that following an endless rolling of the An endless pickling process is carried out. By cooling of the belt in several cooling sections and intervening recovery martensite formation in the band is guaranteed at the specified process stages avoid.
- the abrupt cooling of the strip from 480 ° C to 95 ° C also closes the danger of martensite formation because the transformation at 480 ° C is finished, but this cooling is helpful to form a readily detachable scale.
- the tape prepared in this way which is less than 100 ° C. cold, is replaced by a number of Pickling tank led, the number of which depends on the width and thickness of each tape to be treated, possibly with individual containers over Corresponding pump systems are drained or filled with acid.
- the working method is thereby designed that for inserting the tape into the treatment system previously threaded pilot tape is connected at the end to the tape beginning that the Pilot belt after passing through the treatment plant on one of two Coil mandrels wound up and off the belt after the winding process has ended is separated and that the tape separated from the pilot tape on the second reel dome is wound up.
- the stain threading process is rarely required, for example only twice in the year. Then the pilot strip leads the hot strip beginning through the pickling line and becomes even wound on one dome of a reel. Once the hot strip is through the stain and the subsequent system parts is drawn, the connection point separated between pilot strip and hot strip and the hot strip on the second mandrel wrapped.
- the pilot band is used by the first cathedral removed and reused at the next start.
- a pickling line for performing the working method according to the invention is in Claim 6 claimed
- the inline arrangement of the plant components mentioned there includes the significant one
- the system can thus be very compact and operate functionally, so that large batch sizes of a certain material can be treated economically.
- the device is in the form of a circulation chain frame designed with which the necessary transport and pulling forces can be easily applied are.
- the Winding mandrels arranged on a carousel reel with reversing freedom and empty space are.
- the pilot strip is opened by the stain when threading the beginning of the hot strip the mandrel 1 of the turning reel is wound up, the reel is turned. Once the Hot strip begins, the connection point between the pilot strip and Hot strip separated and the hot strip is on the second dome of the Reversible reel coiled.
- Known turbolence pickling tanks are preferably used as pickling tanks in the pickling system provided, is injected into the treatment acid.
- the containers are traversed by the belt in a horizontal direction, they are over in no time Filling or emptying pump systems, also for adaptation the temperature of the acid in the pickling tanks for different pickling tasks is controllable.
- the pickling plant can be realized particularly advantageously if after a preferred feature of the invention, the process parts of the pickling plant in at least three Layers are arranged one above the other, in which the double deflected by 180 ° Belt is guided by this measure, the system builds very compact, at correspondingly large distance between the individual floors for example, 4 meters, there are only tensions in the elastic for the tape Area.
- the present invention solves the coupling of a thin slab caster, a hot strip mill and a pickle for the production of thin hot strip in a surprisingly simple way.
- the facility is special suitable for processing low-carbon steels (e.g. ST 37, ST 52 and ST10), which can be economically manufactured in large batch sizes.
- the attachment is compact and simple to build and is also inexpensive to manufacture because of the Inline process, essential plant parts are only required once. The handling The system is simple and safe, so that a good cost performance ratio too is expected.
- 1 is the last stand of a hot strip mill referred to, which, located immediately behind a thin slab caster, the Thin slab into a band with final dimensions in the range between 2.5 mm and Rolled out 1 mm.
- a driver 2 for the tape is following the Hot strip mill a cooling device 3 is provided, in which the strip of approx. Is mildly cooled to 850 ° C. to 680 ° C.
- a roller driver 4 On the outlet side of the cooling device 3, followed by a roller driver 4 a 38 m long compensation section is provided, the 5 is designated and in which the tape over the entire tape cross-section through the Compensation of outside and inside temperature receives a temperature of 680 ° C.
- a further driver 6 for the belt is followed by a further cooling section 7 for a mild one Cooling of the belt from 680 ° C to 480 ° C, with which the belt, supported by a another driver 8 is introduced into the second compensation section 9.
- the strip cross-section is equalized to a temperature of 480 ° C equalized before the tape, supported by another driver 10 in one Loop storage is routed to where it is known in a multiple way Redirection around roles that can be changed in their intervals.
- the stapling device 12 is provided, in which the Start of the tape with the end of a pilot tape fed at 13 Stitch can be connected.
- the stapler 12 is a pair of scissors 14 upstream, in which the beginning of the band can be straightened.
- the band will turn 180 ° again redirected in its direction of passage and arrives, driven by a Circulating chain frame, which is designated 21, in the pickling device, the total of 22 is designated.
- the pickling system is composed of a total of 5, each 18 m long pickling tanks, which are used as turbulence pickling with a horizontal pass for the Tape are formed.
- the pickling tanks are designated 23 a to 23 e.
- Pump systems shown are the containers optionally filled with acid or drainable.
- the pickling device is followed by the known rinsing of the belt in the Rinsing devices 24 with subsequent drying in the drying device 25 and if necessary, trimming the band edges in the trimming shear 26
- Pickling device is a second circulating chain frame 27 is arranged, in which the necessary Belt tension between this and the first circulating chain frame 21 can be applied.
- the System ends with a drum shear 28 and the reel 29, in which the finished tape or the pilot tape can be wound up.
- this is done Threading the tape into the stain with the help of a wound at 13, in the Plant extending pilot tape, which in the stapler 12 at the beginning of Band is connected.
- the pilot tape is attached together with the tape pulled through the entire plant, including the pickling device 22, and at the end the system wound on the first reel dome of the turning reel 29.
- Pilot tape cut off and passed to the second reel dome of the reversible reel 29.
- the pilot tape can be unwound and returned to the next threading process be while the hot strip in a known manner on the reel is coiled up.
- a pilot tape it is expedient to use a flexible one Metal fabric tape is used, which is not when moving through the 180 ° bypasses large forces required.
- the entire system is in the preferred version between the last scaffolding the hot strip mill and the turning reel are 178 m long.
- This compact Construction can be achieved by arranging the entire system on three floors, which are 4 m apart.
- the first cooling section with a length of 10 m allows cooling with the specified in claim 2 Speeds, the compensation section 5 with a length of 38 m leads to the specified Temperatures.
- the second cooling section with a length of 15 m is the second Equalization route followed, for which a length of 38 m is also provided.
- For the pickling tanks are each provided for 18 m, which proved to be sufficient in order to pickle even the thickest strip to be produced in the system.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Metal Rolling (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
Die Erfindung betrifft ein Arbeitsverfahren und eine Anlage zum Beizen eines in einer Dünnbrammenanlage erzeugten und im Anschluß daran warmgewalzten Bandes, insbesondere kohlenstoffarmen Stahlbandes, in einem unmittelbar an den Walzvorgang anschließenden kontinuierlichen Prozeß,The invention relates to a working method and a system for pickling in one Thin slab plant produced and subsequently hot rolled strip, especially low-carbon steel strip, in a directly to the Rolling process subsequent continuous process,
Für bestimmte Einzweck-Produkte in großen Losgrößen ist eine Kopplung zwischen einer Dünnbrammengießanlage, einem Warmbandwalzwerk und einer Beize sinnvoll. Bis heute sind solche Kopplungen nicht bekannt. Der Überlegung zur Schaffung einer solchen Anlage und des zugehörigen Verfahrens liegt die Tatsache zugrunde, daß dünnes Warmband billiger erzeugt werden kann als Kaltband. Bei der Substitution von Kaltband durch Warmband kommt aber nur gebeiztes Warmband in Frage, damit auf das fertige Band Oberflächenschutz und Beschichtung problemlos aufgebracht werden können. Für eine sinnvolle Verbindung von Gießanlage, Warmbandwalzwerk und Beize ist vorauszusetzen, daß die Gesamtanlage Inline arbeiten muß, so daß unter Berücksichtigung des Gieß- und Walzprozeßes eine Abstimmung aller Geschwindigkeiten vorgenommen werden muß. Doppelte Anlagenteile sollen möglichst vermieden werden, damit die Anlage kostengünstig erstellt werden kann und produktiv arbeitet.For certain single-purpose products in large batch sizes, there is a coupling between a thin slab caster, a hot strip mill and a pickle. To date, such couplings are not known. Considering creating a such plant and the associated method is based on the fact that thin hot strip can be produced cheaper than cold strip. When substituting Cold strip through hot strip is only possible with pickled hot strip the finished tape surface protection and coating can be applied easily can. For a sensible connection of the casting plant, hot strip mill and Pickling is assumed that the entire system must work inline, so that under Taking into account the casting and rolling process a coordination of all Speeds must be made. Duplicate plant parts are said to should be avoided as far as possible so that the system can be created inexpensively and works productively.
Das Hauptproblem bei der Schaffung einer aufgabengemäßen Anlage und bei der Durchführung des darauf betriebenen Arbeitsverfahrens ist die Anpassung der Beizdauer an die durch die Warmbandproduktion vorgegebenen Geschwindigkeiten; denn die Beize muß in der Lage sein, unterschiedliche Bandstärken und Geschwindigkeiten in optimierter Weise zu verarbeiten. Beizanlagen arbeiten günstigerweise mit ca. 90°C kaltem Band.The main problem with the creation of a task-oriented system and with the Implementation of the working process operated on it is the adaptation of Pickling time at the speeds specified by the hot strip production; because the stain must be able to use different strip thicknesses and Process speeds in an optimized way. Pickling plants work conveniently with approx. 90 ° C cold tape.
Ein Arbeitsverfahren zum Beizen eines in einer Dünnbrammenanlage erzeugten und im Anschluß daran warmgewalzten Bandes ist dann sinnvoll, wenn große Losgrößen verarbeitet werden können, insbesondere kohlenstoffarme Stähle eignen sich zur Durchführung des Verfahrens.A working process for pickling a and produced in a thin slab plant Subsequently hot-rolled strip is useful if there are large batch sizes can be processed, especially low-carbon steels are suitable for Execution of the procedure.
Erfindungsgemäß ist das Arbeitsverfahren gekennzeichnet durch die im Patentanspruch 1 angegebenen Verfahrensschritte. Mit diesen aufeinanderfolgenden Verfahrensschritten läßt sich ein kohlenstoffarmes Stahlband inline beizen, wobei die durch die Dünnbrammengießanlage und das anschließende Warmbandwalzwerk vorgegebenen Geschwindigkeiten bei entsprechender Abstimmung geeignet sind, die Temperaturführung zur Vorbereitung des Beizprozeßes ebenso zu beherrschen, wie den Beizvorgang für die gängigen Walzgutdicken und -breiten. Das Verfahren läßt sich inline durchführen, d.h. daß im Anschluß an eine endlose Walzung des Dünnbrammenvormaterials ein endloses Beizen durchgeführt wird. Durch das Kühlen, des Bandes in mehreren Kühlstrecken und dazwischengeschaltetes Erholen läßt sich bei den angegebenen Verfahrensstufen eine Martensit-Bildung im Band sicher vermeiden. Die schroffe Abkühlung des Bandes von 480°C auf 95°C schließt ebenfalls die Gefahr der Bildung von Martensit aus, weil die Umwandlung bei 480°C beendet ist, doch ist diese Abkühlung zur Bildung eines gut lösbaren Zunders hilfreich. Das so vorbereitete, weniger als 100°C kalte Band wird durch eine Anzahl von Beizbehältem geführt, deren Anzahl abhängig ist von der Breite und Dicke des jeweils zu behandelnden Bandes, wobei gegebenenfalls einzelne Behälter über entsprechende Pumpsysteme entleert oder mit Säure gefüllt sind.According to the working method is characterized by the im Claim 1 specified process steps. With these successive Process steps can be pickled a low-carbon steel strip inline, the through the thin slab caster and the subsequent hot strip mill given speeds are appropriate with appropriate coordination that To master temperature control in preparation for the pickling process as well the pickling process for the common rolling stock thicknesses and widths. The procedure can be perform inline, i.e. that following an endless rolling of the An endless pickling process is carried out. By cooling of the belt in several cooling sections and intervening recovery martensite formation in the band is guaranteed at the specified process stages avoid. The abrupt cooling of the strip from 480 ° C to 95 ° C also closes the danger of martensite formation because the transformation at 480 ° C is finished, but this cooling is helpful to form a readily detachable scale. The tape prepared in this way, which is less than 100 ° C. cold, is replaced by a number of Pickling tank led, the number of which depends on the width and thickness of each tape to be treated, possibly with individual containers over Corresponding pump systems are drained or filled with acid.
Es hat sich herausgestellt, daß ein mit konstant 1300 mm Breite das Walzwerk
verlassendes Band mit bestimmten Durchlaufgeschwindigkeiten behandelt werden
muß, die abhängig sind von der Dicke und Breite des jeweils in der Anlage
eingefädelten Bandes. Entsprechende Verhältnisse zwischen Banddicke und
Durchlaufgeschwindigkeit sind im Patentanspruch 2 angegeben.It has been found that a rolling mill with a constant 1300 mm width
leaving the belt are treated at certain throughput speeds
must, which depend on the thickness and width of each in the system
threaded ribbon. Corresponding relationships between strip thickness and
Throughput speed are specified in
Nach einem anderem Merkmal der Erfindung wird das Arbeitsverfahren dadurch ausgestaltet, daß zum Einführen des Bandes in die Behandlungsanlage ein zuvor eingefädeltes Pilotband endseitig mit dem Bandanfang verbunden wird, daß das Pilotband nach dem Durchlauf durch die Behandlungsanlage auf einem von zwei Haspeldornen aufgewickelt und nach Beendigung des Wickelvorganges vom Band getrennt wird und daß das vom Pilotband getrennte Band auf dem zweiten Haspeldom aufgewickelt wird.According to another feature of the invention, the working method is thereby designed that for inserting the tape into the treatment system previously threaded pilot tape is connected at the end to the tape beginning that the Pilot belt after passing through the treatment plant on one of two Coil mandrels wound up and off the belt after the winding process has ended is separated and that the tape separated from the pilot tape on the second reel dome is wound up.
Der Einfädelprozeß für die Beize ist nur selten erforderlich, beispielsweise nur zweimal im Jahr. Dann führt das Pilotband den Warmbandanfang durch die Beize und wird selbst auf den einen Dom eines Haspels aufgewickelt. Sobald das Warmband durch die Beize und die nachfolgenden Anlagenteile gezogen ist, wird die Verbindungsstelle zwischen Pilotband und Warmband getrennt und das Warmband auf den zweiten Dorn gewickelt.The stain threading process is rarely required, for example only twice in the year. Then the pilot strip leads the hot strip beginning through the pickling line and becomes even wound on one dome of a reel. Once the hot strip is through the stain and the subsequent system parts is drawn, the connection point separated between pilot strip and hot strip and the hot strip on the second mandrel wrapped.
Das Pilotband wird nach einem anderem Merkmal der Erfindung vom ersten Dom entfernt und beim nächsten Start wiederverwendet.According to another feature of the invention, the pilot band is used by the first cathedral removed and reused at the next start.
Nach jeder Produktionsperiode von ca. 4 Stunden ist ein Aufarbeiten der Arbeitswalzen in der Warmbandstraße erforderlich. Auch müssen die Tauchrohre in der Dünnbrammengießanlage erneuert werden, wozu erfahrungsgemäß eine Pause von ca. 30 Minuten erforderlich ist. In einer Weiterbildung des erfindungsgemäßen Arbeitsverfahrens ist deshalb vorgesehen, daß beim Zustellen von Anlageteilen, beim Walzenwechsel, beim Austausch von Gießrohren in der Gießanlage oder zur Reperaturzwecken das angehaltene Band in der Behandlungsanlage verbleibt und als "Pilotband" für die nächste Beizkampagne verwendet wird. Auf diese Weise wird ein neues Einfädeln des Bandes mittels eines separaten Pilotbandes über einen sehr langen Zeitraum überflüssig. In einer Produktionsperiode von ca. 4 Stunden wird nur die Banddicke geändert, die Übergangsstücke werden herausgeschnitten.After each production period of approx. 4 hours, the Work rolls in the hot strip mill required. The dip tubes must also be in the thin slab caster are renewed, experience has shown that a break of about 30 minutes is required. In a development of the invention Working method is therefore provided that when delivering parts of the system when Roller change, when replacing pouring tubes in the pouring system or for The stopped belt remains in the treatment plant for repair purposes and as "Pilot tape" is used for the next pickling campaign. In this way, a new threading of the tape by means of a separate Pilot tape is superfluous over a very long period of time. In one production period of about 4 hours only the strip thickness is changed, the transition pieces become cut out.
Eine Beizanlage zur Durchführung des erfindungsgemäßen Arbeitsverfahrens ist im Patentanspruch 6 beanspruchtA pickling line for performing the working method according to the invention is in Claim 6 claimed
Die Inlineanordnung der dort genannten Anlagenteile beinhaltet den bedeutsamen Vorteil, daß doppelte Anlagenteile vermeidbar sind. So hat die erfindungsgemäße Anlage nur eine Aufwickelstation mit zwei Aufwickeldornen, während Einzelanlagen diese Anlagenteile doppel benötigen würden. Die Anlage läßt sich somit sehr kompakt und funktionell betreiben, so daß große Losgrößen eines bestimmten Werkstoffes wirtschaftlich optimal behandelt werden können.The inline arrangement of the plant components mentioned there includes the significant one The advantage that double parts of the system can be avoided. So has the invention System only one winding station with two winding mandrels, while single systems these plant parts would need double. The system can thus be very compact and operate functionally, so that large batch sizes of a certain material can be treated economically.
Innerhalb der Beizanlage ist zwischen den Kühleinrichtungen mit jeweils anschließender Ausgleichstrecke und der Beizeinrichtung ein Schlingenspeicher und eine Hefteinrichtung zum Zusammenfügen des Pilotbandes mit dem zu beizendem Band vorgesehen. Der Vorschlag verzichtet bewußt auf eine Schweißvorrichtung mit teurem erforderlichen Bandspeicher, statt dessen wird eine schnell arbeitende Heftvorrichtung vorgeschlagen, die nur einen kurzen Schlingenspeicher benötigt.Within the pickling system is between the cooling devices with each subsequent compensation section and the pickling device a loop storage and a stapling device for joining the pilot tape with the one to be pickled Tape provided. The proposal deliberately dispenses with a welding device expensive tape storage required, instead, a fast-moving Stapling device proposed that only requires a short loop storage.
Um die in der Anlage erforderlichen Zug- und Transportkräfte kostengünstig aufbringen zu können, wird jeweils vor und hinter der Beizeinrichtung eine Einrichtung zum Aufbringen der Zugspannungen auf das Band vorgesehen. Jede dieser Einrichtung ist in einer günstigen Ausgestaltung der Erfindung als Umlaufkettengerüst ausgeführt, mit dem die erforderlichen Transport- und Zugkräfte einfach aufbringbar sind.To the traction and transport forces required in the system inexpensively To be able to apply, there will be a facility in front of and behind the pickling facility provided for applying the tensile stresses to the belt. Any of these In a favorable embodiment of the invention, the device is in the form of a circulation chain frame designed with which the necessary transport and pulling forces can be easily applied are.
Die Bandbreiten innerhalb der vorgesehenen Beizanlage bleiben im wesentlichen konstant, es wird von Bändern mit einer Breite von 1300 mm ausgegangen. Über eine hinter der Beizeinrichtung vorgesehene Besäumeinrichtung für die Längskanten des gebeizten Bandes kann die Bandbreite im Bereich + 100 mm / - 100 mm verändert werden.The bandwidths within the intended pickling line remain essentially the same constant, strips with a width of 1300 mm are assumed. Over a Trimming device for the longitudinal edges of the pickled strip can change the strip width in the range + 100 mm / - 100 mm become.
In einer besonders günstigen Ausgestaltung der Erfindung ist vorgesehen, daß die Aufwickeldorne auf einem Karussellhaspel mit Wendedom und Leerplatz angeordnet sind. Das Pilotband wird beim Einfädeln des Warmbandanfanges durch die Beize auf den Dorn 1 des Wendehaspels aufgewickelt, der Haspel wird gewendet. Sobald der Warmbandanfang kommt, wird die Verbindungsstelle zwischen Pilotband und Warmband getrennt und das Warmband wird auf den zweiten Dom des Wendehaspels aufgewickelt.In a particularly favorable embodiment of the invention it is provided that the Winding mandrels arranged on a carousel reel with reversing freedom and empty space are. The pilot strip is opened by the stain when threading the beginning of the hot strip the mandrel 1 of the turning reel is wound up, the reel is turned. Once the Hot strip begins, the connection point between the pilot strip and Hot strip separated and the hot strip is on the second dome of the Reversible reel coiled.
Als Beizbehälter in der Beizanlage werden vorzugsweise an sich bekannte Turbolenz-Beizbehälter vorgesehen, in die Behandlungssäure eingedüst wird. Die Behälter werden vom Band in horizontaler Richtung durchlaufen, sie sind in kürzester Zeit über Pumpsysteme zu füllen oder zu entleeren, wobei darüberhinaus auch zur Anpassung an unterschiedliche Beizaufgaben die Temperatur der Säure in den Beizbehältern steuerbar ist.Known turbolence pickling tanks are preferably used as pickling tanks in the pickling system provided, is injected into the treatment acid. The containers are traversed by the belt in a horizontal direction, they are over in no time Filling or emptying pump systems, also for adaptation the temperature of the acid in the pickling tanks for different pickling tasks is controllable.
Verschiedene innerhalb der Beizanlage vorgesehene Treiber sorgen für den Transport des Bandes durch die gesamte Anlage.Various drivers provided within the pickling system ensure transport of the tape through the entire system.
Die Beizanlage läßt sich besonders vorteilhaft verwirklichen, wenn nach einem bevorzugten Merkmal der Erfindung die Prozeßteile der Beizanlage in mindestens drei Ebenen übereinander angeordnet sind, in denen das zweifach um 180° umgelenkte Band geführt ist Durch diese Maßnahme baut die Anlage sehr kompakt, bei entsprechend groß gewähltem Abstand der einzelnen Etagen voneinander von beispielsweise 4 Metern ergeben sich für das Band nur Spannungen im elastischen Bereich.The pickling plant can be realized particularly advantageously if after a preferred feature of the invention, the process parts of the pickling plant in at least three Layers are arranged one above the other, in which the double deflected by 180 ° Belt is guided by this measure, the system builds very compact, at correspondingly large distance between the individual floors for example, 4 meters, there are only tensions in the elastic for the tape Area.
Die vorliegende Erfindung löst die Kopplung einer Dünnbrammenstranggießanlage, eines Warmbandwalzwerkes und einer Beize zur Herstellung von dünnem Warmband in überraschend einfacher Weise. Die Anlage ist besonders geeignet für die Verarbeitung von kohlenstoffarmen Stählen (z.B. ST 37, ST 52 und ST10), die in großen Losgrößen wirtschaftlich hergestellt werden können. Die Anlage ist kompakt und baut einfach und ist auch kostengünstig herzustellen, weil infolge des Inline-Prozesses wesentliche Anlagenteile nur einmal benötigt werden. Das Handling der Anlage ist einfach und sicher, so daß ein gutes Kosten - Leistungsverhältnis zu erwarten ist.The present invention solves the coupling of a thin slab caster, a hot strip mill and a pickle for the production of thin hot strip in a surprisingly simple way. The facility is special suitable for processing low-carbon steels (e.g. ST 37, ST 52 and ST10), which can be economically manufactured in large batch sizes. The attachment is compact and simple to build and is also inexpensive to manufacture because of the Inline process, essential plant parts are only required once. The handling The system is simple and safe, so that a good cost performance ratio too is expected.
Ein Ausführungsbeispiel der Erfindung ist in der Zeichnung dargestellt und wird nachfolgend beschrieben.An embodiment of the invention is shown in the drawing and will described below.
In der einzigen Zeichnungsfigur ist mit 1 das letzte Gerüst einer Warmbandwalzstraße
bezeichnet, die, unmittelbar hinter einer Dünnbrammengießanlage angeordnet, die
Dünnbramme zu einem Band mit Endabmessungen im Bereich zwischen 2,5 mm und
1 mm auswalzt. Gefolgt von einem Treiber 2 für das Band ist im Anschluß an die
Warmbandwalzstraße eine Kühleinrichtung 3 vorgesehen, in der das Band von ca.
850°C auf 680"C mild abgekühlt wird. Auslaufseitig der Kühleinrichtung 3, gefolgt von
einem Walzentreiber 4 ist eine 38 m lange Ausgleichstrecke vorgesehen, die mit 5
bezeichnet ist und in der das Band über den gesamten Bandquerschnitt durch den
Ausgleich von Außen- und Innentemperatur eine Temperatur von 680°C erhält. Nach
einem weiterem Treiber 6 für das Band folgt eine weitere Kühlstrecke 7 für eine milde
Kühlung des Bandes von 680°C auf 480°C, mit dem das Band, unterstützt durch einen
weiteren Treiber 8 in die zweite Ausgleichstrecke 9 eingeführt wird. In dieser
Ausgleichstrecke wird der Bandquerschnitt auf eine Temperatur von 480°C
vergleichmäßigt, bevor das Band, unterstützt von einem weiterem Treiber 10 in einem
Schlingenspeicher geleitet wird, wo es in bekannter Weise unter mehrfacher
Umlenkung um in ihren Abständen veränderbare Rollen geführt wird. Am Ausgang
dieses Schlingenspeichers 11 ist die Hefteinrichtung 12 vorgesehen, in der der
Bandanfang des Bandes mit dem Ende eines bei 13 zugeführten Pilotbandes durch
Heftung verbunden werden kann. Der Hefteinrichtung 12 ist eine Schere 14
vorgeordnet, in der Bandanfang begradigt werden kann. Unterstützt von einem
weiteren Treiber 15 verläßt das Band B die Hefteinrichtung, deren Wirkweise später
noch beschrieben wird, und wird bei 16 um 180° umgelenkt in einer zweiten Etage in
der bisherigen Bandlaufrichtung entgegengesetzter Richtung zurückgeführt. Erneut
durch Treiber 17 unterstützt gelangt das Band in eine dritte Kühlstrecke, wo es sehr
schroff von 480° °C auf ca. 95°C abgekühlt wird. Die Kühlstrecke ist mit 18 bezeichnet.
Erneut durch Treiber 19 unterstützt, gelangt das abgekühlte Band in eine ca. 25 m
lange dritte Ausgleichstrecke 30, in der die Temperatur von ca. 95°C über dem
gesamten Bandquerschnitt vergleichmäßigt wird. Bei 20 wird das Band erneut um 180°
in seiner Durchlaufrichtung umgelenkt und gelangt, getrieben durch ein
Umlaufkettengerüst, das mit 21 bezeichnet ist, in die Beizeinrichtung, die insgesamt mit 22
bezeichnet ist. Die Beizeinrichtung ist zusammengesetzt aus insgesamt 5 jeweils 18 m
langen Beizbehältern, die als Turbulenzbeizen mit horizontalem Durchlauf für das
Band ausgebildet sind. Die Beizbehälter sind mit 23 a bis 23 e bezeichnet. Über nicht
dargestellte Pumpensysteme sind die Behälter wahlweise mit Säure füll- bzw.
entleerbar.In the single drawing figure, 1 is the last stand of a hot strip mill
referred to, which, located immediately behind a thin slab caster, the
Thin slab into a band with final dimensions in the range between 2.5 mm and
Rolled out 1 mm. Followed by a
Anschließend an die Beizeinrichtung folgt die bekannte Spülung des Bandes in den
Spüleinrichtungen 24 mit darauf folgendem Trocknen in der Trockeneinrichtung 25 und
ggf. ein Besäumen der Bandkanten in der Besäumschere 26. Ausgangsseitig der
Beizeinrichtung ist ein zweites Umlaufkettengerüst 27 angeordnet, in der der notwendige
Bandzug zwischen diesem und dem ersten Umlaufkettengerüst 21 aufbringbar ist. Die
Anlage endet mit einer Trommelteilschere 28 und dem Wendehaspel 29, in dem das
fertige Band oder das Pilotband aufwickelbar ist.The pickling device is followed by the known rinsing of the belt in the
Wie bereits bei der allgemeinen Beschreibung der Erfindung angedeutet, erfolgt das
Einfädeln des Bandes in die Beize mit Hilfe eines bei 13 aufgewickelten, sich in der
Anlage erstreckenden Pilotbandes, das in der Hefteinrichtung 12 mit dem Anfang des
Bandes verbunden wird. Das Pilotband wird zusammen mit dem angehefteten Band
durch die Gesamtanlage, einschließlich die Beizeinrichtung 22 gezogen und am Ende
der Anlage auf den ersten Haspeldom des Wendehaspels 29 aufgewickelt. Sobald der
Anfang des Bandes in den Bereich des Wendehaspels gelangt, wird dieser vom
Pilotband abgetrennt und auf den zweiten Haspeldom des Wendehaspels 29 geleitet.
Das Pilotband kann abgewickelt und zum nächsten Einfädelvorgang zurückgeführt
werden, während das Warmband in bekannter Weise auf dem Wendehaspel
aufgehaspelt wird. Als Pilotband wird zweckmäßigerweise ein gut biegsames
Metallgewebeband verwendet, das beim Umführen durch die 180°-Umführungen keine
großen Kräfte erfordert.As already indicated in the general description of the invention, this is done
Threading the tape into the stain with the help of a wound at 13, in the
Plant extending pilot tape, which in the
Die gesamte Anlage ist in der bevorzugten Ausführung zwischen dem letzten Gerüst
der Warmbandwalzstraße und dem Wendehaspel 178 m lang. Diese kompakte
Bauweise läßt sich erreichen, indem die Gesamtanlage in drei Etagen angeordnet ist,
die jeweils 4 m von einander beabstandet sind. Die erste Kühlstrecke mit 10 m Länge
ermöglicht ein Abkühlen mit den im Patentanspruch 2 angegebenen
Geschwindigkeiten, die Ausgleichstrecke 5 mit 38 m Länge führt zu den angegebenen
Temperaturen. Die zweite Kühlstrecke mit 15 m Länge wird von der zweiten
Ausgleichstrecke gefolgt, für die ebenfalls eine Länge von 38 m vorgesehen ist. Für
die Beizbehälter sind jeweils 18 m vorgesehen, die sich als ausreichend erwiesen
haben, um selbst das dickste in der Anlage herzustellenden Band zu beizen.The entire system is in the preferred version between the last scaffolding
the hot strip mill and the turning reel are 178 m long. This compact
Construction can be achieved by arranging the entire system on three floors,
which are 4 m apart. The first cooling section with a length of 10 m
allows cooling with the specified in
Mit einer solchen Anlage gelingt es erstmals, einen Inlineprozeß mit Dünnbrammen-Gießen, Walzen und Beizen kontinuierlich zu betreiben und damit ein verkaufsfähiges Warmband zu erzeugen, und zwar in großen Losgrößen, am günstigsten mit kohlenstoffarmen Stahlqualitäten. Als Walzstraße kommt jede beliebige, für die Verarbeitung von Dünnbrammen bekannte Anordnung von Verformungsgerüsten in Frage, so z.B. auch ein sog. PlanetenwalzgerüstWith such a system, an inline process with thin slab casting is possible for the first time, Operate rolling and pickling continuously and thus a salable To produce hot strip, in large batch sizes, the cheapest with low-carbon steel grades. Any rolling mill comes for that Processing of thin slabs known arrangement of deformation structures in Question, e.g. also a so-called planetary mill stand
Claims (12)
- Process for pickling a strip - in particular a strip of low-carbon steel, produced in a thin slab casting line and subsequently hot-rolled - in a continuous process directly following the rolling stage, which is characterised by the sequence of the following process steps in a treatment plant:a) slow cooling on an initial cooling line, to 850° - 680° C, of the strip leaving the rolling process at a temperature of ≥ 880° C,b) equalisation of edge and core temperatures on an initial recovery line to a uniform average temperature of approximately 680° C,c) slow cooling, on an immediately following second cooling line, of the strip from 680° C to 480° C,d) equalisation of edge and core temperatures on a second recovery line to a uniform average temperature of approximately 480° C,e) sudden cooling of the strip from 480° C to approximately 95° C on a third cooling line,f) equalisation of edge and core temperatures on a third recovery line to a uniform average temperature of approximately 100° C,g) feeding of the strip through a number of chemical pickling vats which can be brought into or out of operation, the number of vats being set in accordance with the thickness and/or flow speed of the strip, at suitable pickling temperatures, andh) rinsing, drying and coiling of the pickled strip.
- Process for pickling a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 1,
characterised by the fact that - at a substantially constant strip width of 1300 mm - the final rolling speeds of the strip, and thus its throughput speeds through the treatment plant, are set in accordance with the final thickness of the rolled strip as follows:final strip thickness 1.0 mm ≈ final rolling speed 4.0 metres per secondfinal strip thickness 1.5 mm ≈ final rolling speed 2.7 metres per secondfinal strip thickness 2.0 mm ≈ final rolling speed 2.0 metres per secondfinal strip thickness 2.5 mm ≈ final rolling speed 1.6 metres per second - Process for pickling a strip produced in a thin slab casting line and subsequently hot-rolled as in Claims 1 and 2,
characterised by the factthat the strip is fed into the treatment plant by attaching its end to the end of a pilot strip which has been previously threaded through the plant,that the pilot strip, after passing through the treatment plant, is wound on to one of two reel mandrels and is separated from the strip once the winding process is complete,and that the strip, after separation from the pilot strip, is wound on to the second reel mandrel. - Process for pickling a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 3,
characterised by the fact
that the pilot strip is re-usable. - Process for pickling a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 1,
characterised by the fact that
when work is being carried out on parts of the plant - such as changing the rollers, replacement of casting spouts, or repair operations - the halted strip remains within the treatment plant, and is used as a pilot strip for the next pickling run. - Pickling plant to carry out the process as in Claims 1 to 5, consisting of the arrangement in sequence of the following process components which are capable of continuous operation:a) three cooling facilities (3, 7, 18), each having a following soaking line (5, 9, 30)b) a pickling facility (22) with several pickling vats (23a - 23e) which can be brought into and out of operation, and through which passes horizontally the strip (B)c) rinsing (24) and drying (25) facilities for the pickled strip (B)d) a cross-cutting shears (28) ande) at least two winding mandrels (29) for the finished strip
- Pickling plant for a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 6,
characterised by the fact
that a facility (21, 27) is provided both before and after the pickling facility (22) for the application of tensile stress to the strip (B), this facility consisting of rotating chain frameworks. - Pickling plant for a strip produced in a thin slab casting line and subsequently hot-rolled as in one of Claims 6 and 7,
characterised by the fact
that, after the pickling facility (22), there is a trimming facility (26) for the longitudinal edges of the pickled strip (B). - Pickling plant for a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 6,
characterised by the fact
that the winding mandrels e) are arranged on a rotating coiling reel (29) with a reversing mandrel and with space for the pilot strip. - Pickling plant for a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 6,
characterised by the fact that
the pickling vats (23a - 23e) are in the known form of turbulence vats. - Pickling plant for a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 8,
characterised by the fact
that there are drive units (2, 4, 6, 10, 15, 17, 19) for the strip (B) within the plant. - Pickling plant for a strip produced in a thin slab casting line and subsequently hot-rolled as in Claim 6,
characterised by the fact
that the process components of the plant are arranged on top of each other in at least three tiers, within which the strip (B) is passed, being turned twice through 180°.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19606305 | 1996-02-08 | ||
DE19606305A DE19606305C1 (en) | 1996-02-08 | 1996-02-08 | Method and device for in-line pickling of hot strips behind thin slab production plants |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0787808A1 EP0787808A1 (en) | 1997-08-06 |
EP0787808B1 true EP0787808B1 (en) | 2001-11-07 |
Family
ID=7785919
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97250023A Expired - Lifetime EP0787808B1 (en) | 1996-02-08 | 1997-02-04 | Method and device for in-line-pickling of hot rolled strip in sequence with thin slab production |
Country Status (4)
Country | Link |
---|---|
US (1) | US5876522A (en) |
EP (1) | EP0787808B1 (en) |
DE (2) | DE19606305C1 (en) |
ES (1) | ES2163094T3 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1295566B1 (en) * | 1997-06-05 | 1999-05-13 | Danieli Off Mecc | THERMAL TREATMENT PROCESS FOR LAMINATES |
AT407755B (en) | 1998-07-15 | 2001-06-25 | Andritz Patentverwaltung | METHOD FOR STAINLESSING STAINLESS STEEL |
DE102004045296A1 (en) | 2004-09-16 | 2006-03-23 | Röhm GmbH & Co. KG | Use of polyalkyl (meth) acrylate bead polymers and molding compound for the production of extruded molded parts with a matted surface |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1093867A (en) * | 1953-02-24 | 1955-05-10 | Wuppermann Gmbh Theodor | Process for hot manufacturing of strip iron totally or largely free of scale and device for carrying out this process |
DE1123879B (en) * | 1960-01-05 | 1962-02-15 | Thyssen Huette Ag | Process and plant for the continuous descaling of broadband in a continuous pickling plant |
US3623532A (en) * | 1969-03-20 | 1971-11-30 | Southwire Co | Continuous pickling of cast rod |
BE843167A (en) * | 1975-06-24 | 1976-10-18 | COOLING AND PICKLING OF A CONTINUOUS ROLLED MACHINE WIRE | |
US4007750A (en) * | 1975-07-14 | 1977-02-15 | Armco Steel Corporation | Continuous sheet pickling apparatus |
JPS5997705A (en) * | 1982-11-26 | 1984-06-05 | Hitachi Ltd | Continuous rolling method |
NL8702050A (en) * | 1987-09-01 | 1989-04-03 | Hoogovens Groep Bv | METHOD AND APPARATUS FOR THE MANUFACTURE OF TIRE-DEFORMING STEEL WITH GOOD MECHANICAL AND SURFACE PROPERTIES. |
NL8802892A (en) * | 1988-11-24 | 1990-06-18 | Hoogovens Groep Bv | METHOD FOR MANUFACTURING DEFORMING STEEL AND STRAP MADE THEREOF |
AT404907B (en) * | 1993-07-13 | 1999-03-25 | Andritz Patentverwaltung | METHOD AND SYSTEM FOR PRODUCING STAINLESS STEEL STRIP |
JPH08294707A (en) * | 1995-04-21 | 1996-11-12 | Nippon Steel Corp | Manufacture of hot rolled steel strip |
-
1996
- 1996-02-08 DE DE19606305A patent/DE19606305C1/en not_active Expired - Fee Related
-
1997
- 1997-02-04 EP EP97250023A patent/EP0787808B1/en not_active Expired - Lifetime
- 1997-02-04 ES ES97250023T patent/ES2163094T3/en not_active Expired - Lifetime
- 1997-02-04 DE DE59705232T patent/DE59705232D1/en not_active Expired - Lifetime
- 1997-02-05 US US08/795,889 patent/US5876522A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
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DE59705232D1 (en) | 2001-12-13 |
ES2163094T3 (en) | 2002-01-16 |
DE19606305C1 (en) | 1997-10-02 |
US5876522A (en) | 1999-03-02 |
EP0787808A1 (en) | 1997-08-06 |
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