EP1525060B1 - Method and device for the continuous production of metallic strips - Google Patents
Method and device for the continuous production of metallic strips Download PDFInfo
- Publication number
- EP1525060B1 EP1525060B1 EP03766145A EP03766145A EP1525060B1 EP 1525060 B1 EP1525060 B1 EP 1525060B1 EP 03766145 A EP03766145 A EP 03766145A EP 03766145 A EP03766145 A EP 03766145A EP 1525060 B1 EP1525060 B1 EP 1525060B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strip
- equipment
- rolling
- chemical treatment
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000010924 continuous production Methods 0.000 title claims abstract description 5
- 238000005096 rolling process Methods 0.000 claims abstract description 57
- 238000010438 heat treatment Methods 0.000 claims abstract description 23
- 238000011282 treatment Methods 0.000 claims abstract description 22
- 239000000126 substance Substances 0.000 claims abstract description 20
- 238000005554 pickling Methods 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 229910001220 stainless steel Inorganic materials 0.000 claims description 7
- 239000010935 stainless steel Substances 0.000 claims description 5
- 238000005238 degreasing Methods 0.000 claims description 4
- 238000009966 trimming Methods 0.000 claims description 4
- 238000005097 cold rolling Methods 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 abstract description 5
- 239000010959 steel Substances 0.000 abstract description 5
- 238000000137 annealing Methods 0.000 description 19
- 238000003860 storage Methods 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000013980 iron oxide Nutrition 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
- B21B1/28—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by cold-rolling, e.g. Steckel cold mill
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B15/0035—Forging or pressing devices as units
- B21B15/005—Lubricating, cooling or heating means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B3/02—Rolling special iron alloys, e.g. stainless steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/28—Control of flatness or profile during rolling of strip, sheets or plates
- B21B37/44—Control of flatness or profile during rolling of strip, sheets or plates using heating, lubricating or water-spray cooling of the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/004—Heating the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/04—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing
- B21B45/06—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing of strip material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49988—Metal casting
- Y10T29/49991—Combined with rolling
Definitions
- the invention relates to a method for continuously producing a metallic, preferably cold-rolled strip, in particular a stainless steel strip, wherein the strip to be produced is guided in a conveying direction through a device in which the strip is subjected to a rolling process, a heating and a chemical treatment. Furthermore, the invention relates to a suitable system.
- a metal strip passes through a production device in which various processes are carried out on the strip.
- the strip is reduced in a rolling process in its thickness.
- a heat treatment can be followed, which gives the band special material properties.
- the tape must have a scale-free surface, which is why it passes through a pickling line in which the scale is removed by means of a chemical treatment.
- the hot-rolled steel strip For further processing - eg., by cold rolling, for a metallic coating or the direct processing into a final product - the hot-rolled steel strip must have a scale-free surface. Therefore, the scale formed during hot rolling and subsequent cooling must be removed completely. This is usually done by a pickling process, wherein the consisting of the various iron oxides (FeO, Fe 3 O 4 , Fe 2 O 3 ) or in stainless steels also chromium-rich iron oxides existing scale depending on the steel quality by means of various acids (eg., Hydrochloric acid, sulfuric acid , Nitric acid or mixed acid) is dissolved at elevated temperatures by chemical reaction with the acid.
- various acids eg., Hydrochloric acid, sulfuric acid , Nitric acid or mixed acid
- a method or a system of the generic type is known from DE 100 22 045 C1. There, it is disclosed that a strip is passed through a pickling device, wherein in front of and behind the pickling device a respective rolling unit is arranged. In the conveying direction of the belt behind the second roller unit, the belt passes through an annealing furnace and then a pickling tank in which the scale is removed from the surface of the belt. Before winding up the tape that has been completed so far, it can be finally finished in a temper rolling mill.
- WO 00/37189 and WO 00/37190 disclose a device for producing a metal strip, in which the strip is first reduced in its thickness to a multi-stand rolling course. Subsequently, the tape enters an annealing furnace; in the further course, the strip is passed through a pickling device. Before the tape is wound up, a rolling operation can follow, but only a slight reduction of the thickness on the belt is required.
- US 2001/0037667 A1 discloses a similar apparatus for producing a metal strip. Here, however, no heating of the band is provided. The strip is passed through a rolling mill only after descaling in a pickling line.
- the rolling mill following facilities and in particular the annealing furnace and the pickling line, must be adjusted in their dimensions of the reduced by the rolling process typically 30 to 40% band thickness ; Since the strip is already thinner, but longer, the annealing furnace and the pickling line must be designed to be correspondingly long, which leads to high costs of the system.
- the invention is therefore based on the object to provide a method and an associated system of the type mentioned, with which or with which it is possible to avoid the disadvantages mentioned, which in particular achieves a higher productivity and efficiency in the production of a strip to be Furthermore, the surface quality of the finished strip is to be improved.
- the solution of this problem by the invention according to the method is characterized in that the rolling process is carried out only after the heating of the belt and after the chemical treatment.
- This procedure ensures that the three process steps of rolling the strip to the desired thickness, carrying out a heat treatment of the strip by an annealing process and descaling the strip by means of pickling are carried out in the production plant, the above-mentioned disadvantages not being apparent Bandes of the original to the reduced, final thickness takes place only in the conveying direction after annealing and pickling, both the annealing furnace and the pickling line can be made smaller in their respective dimensions. Furthermore, said rolling process takes place only on a completely descaled strip surface, so that the roller wear remains low. Furthermore, the proposed procedure results in improved strip surface quality without the need for further measures.
- the rolling process is preferably a tandem rolling process.
- rolling process is to be understood here as meaning that the strip is substantially reduced in its thickness, preferably by at least 20%.
- the chemical treatment of the strip is preferably a pickling process.
- the device according to the invention for the continuous production of a metal, cold-rolled strip has a device for heating, i. H. in particular for annealing the strip, means for chemically treating the strip, and means for rolling the strip.
- the device for rolling the strip in the conveying direction is arranged behind the device for heating the strip and the device for chemically treating the strip, wherein the device for rolling the strip has at least one tandem rolling train.
- This consists of several rolling stands, which can be designed as a rolling mill of the type 6-high or as a rolling mill of the Z-high type. In addition to this rolling device no further device for the purpose of reducing the thickness of the tape is required.
- a draft straightening unit can be arranged between the device for heating the strip (annealing furnace) and the device for chemically treating the strip (pickling line). Furthermore, a metal grain jet unit can be arranged between the annealing furnace and the pickling line.
- a trimming unit may further be arranged to laterally trim the strip.
- the device has at least one, preferably three band memory.
- the described manufacturing device can also be operated as a combined hot and cold strip annealing and pickling line with integrated rolling train (tandem mill).
- a degreasing device can additionally be arranged in the conveying direction before the device for heating the strip, in particular in front of the inlet strip store.
- FIG. 1 An embodiment of the invention is shown.
- the single figure shows schematically a device for producing a stainless steel strip.
- a device 2 can be seen, on which a metal strip 1 (metal strand) is processed.
- the tape 1 of the device 2 is supplied.
- the belt 1 is unwound from an unwinding unit, not shown, and directed into the device 2.
- a degreasing device 12 follows, in which the strip surface is cleaned.
- the tape 1 enters a tape storage 9 (inlet storage), which is positioned below a device 3 for heating the strip 1 (annealing furnace).
- About the tape storage 9 can be achieved that even with minor external disturbances in the tape feed a continuous run of the tape is achieved.
- the strip 1 is subjected to a heat treatment.
- Ansch manend it comes to a stretcher straightening unit 6, in which the band 1 is smoothed.
- Downstream of the drafting straightening unit 6 is a metal-grain jet unit 7.
- a device 4 for the chemical treatment of the belt 1 is arranged, namely a pickling line, in which the belt 1 is passed through tanks, which are filled with acid.
- a pickling line in which the belt 1 is passed through tanks, which are filled with acid.
- a tape storage 11 (buffer) is arranged below the pickling line 4. From this, the tape 1 runs in a Beklamyer 8, in which the sides of the tape 1 are cut. From the trimming unit 8, the belt 1 passes through a further belt store 10 (discharge storage) to the device 5 for rolling the belt 1.
- This device 5 is designed as a tandem rolling mill. There are three consecutively arranged rolling stands 5a, 5b and 5c, in which the strip 1 is rolled and thereby reduced in thickness.
- an outlet section 14 is arranged, which has a winding unit, not shown, with which the finished tape 1 can be wound.
- the tandem rolling train 5 has three rolling stands 5a, 5b and 5c, which may be designed in the form of a multi-roll cold rolling mill, a 6-high rolling mill or a Z-high rolling mill. Due to the fact that the reduction in the thickness of the strip 1 takes place only in the only device 5 for rolling the strip 1 at the end of the device 2, the strip 1 has before the tandem rolling mill 5 still a relatively large thickness, namely the thickness at which the tape 1 enters the device 2, on. This has the consequence that the length of both the annealing furnace 3 and the pickling line 4 can be kept relatively low.
- Both the annealing furnace 3 and the pickling line 4 can therefore be designed for the original thickness of the strip 1, with which the strip 1 enters the device 2.
- a reduction in thickness can be made without prior annealing, resulting in a smaller maximum thickness reduction of a maximum of 30 to 40%.
- the maximum thickness reduction of the belt 1 per pass through the device 2 depends only on the materials and the performance of the tandem rolling mill 5; no consideration has to be given to the unannealed tape.
- a rolling stand of the tandem rolling train 5 can be designed so that the band 1 can be dressed during a final annealing.
- the descaled and preferably already edged strip can - following the device 2 - without intermediate storage under constant tension continuously in a follow-up device (hot dip galvanizing, etc.) enter.
- the finished tape can be wound behind the Nach Riverside Published alternately with two reels and divided with a pair of scissors.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metal Rolling (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Coating With Molten Metal (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Manufacturing Of Electric Cables (AREA)
- Winding, Rewinding, Material Storage Devices (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zum kontinuierlichen Herstellen eines metallischen, vorzugsweise kaltgewalzten Bandes, insbesondere eines Edelstahlbandes, wobei das zu fertigende Band in eine Förderrichtung durch eine Vorrichtung geführt wird, in der das Band einem Walzprozess, einer Erwärmung und einer chemischen Behandlung unterzogen wird. Des weiteren betrifft die Erfindung eine geeignete Anlage.The invention relates to a method for continuously producing a metallic, preferably cold-rolled strip, in particular a stainless steel strip, wherein the strip to be produced is guided in a conveying direction through a device in which the strip is subjected to a rolling process, a heating and a chemical treatment. Furthermore, the invention relates to a suitable system.
Bei der Herstellung kaltgewalzter Bänder, insbesondere von Edelstahlbändern, durchläuft ein Metallband eine Fertigungsvorrichtung, in der verschiedene Prozesse am Band vorgenommen werden. Dabei wird das Band in einem Walzprozess in seiner Dicke reduziert. Weiterhin kann sich eine Wärmebehandlung anschließen, mit der dem Band spezielle Werkstoffeigenschaften verliehen werden. Ferner muss das Band eine zunderfreie Oberfläche aufweisen, weshalb es eine Beizlinie passiert, in der mittels einer chemischen Behandlung der Zunder entfernt wird.In the production of cold-rolled strips, in particular of stainless steel strips, a metal strip passes through a production device in which various processes are carried out on the strip. In this case, the strip is reduced in a rolling process in its thickness. Furthermore, a heat treatment can be followed, which gives the band special material properties. Furthermore, the tape must have a scale-free surface, which is why it passes through a pickling line in which the scale is removed by means of a chemical treatment.
Für die Weiterverarbeitung - z. B. durch Kaltwalzen, für eine metallische Beschichtung oder die direkte Verarbeitung zu einem Endprodukt - muss das warmgewalzte Stahlband eine zunderfreie Oberfläche haben. Daher muss der beim Warmwalzen und während der nachfolgenden Abkühlung entstandene Zunder restlos entfernt werden. Dies erfolgt zumeist durch einen Beizprozess, wobei der aus den verschiedenen Eisenoxiden (FeO, Fe3O4, Fe2O3) oder bei nichtrostenden Stählen auch aus chromreichen Eisenoxiden bestehende Zunder je nach Stahlqualität mittels verschiedener Säuren (z. B. Salzsäure, Schwefelsäure, Salpetersäure oder Mischsäure) bei erhöhten Temperaturen durch chemische Reaktion mit der Säure gelöst wird. Vor dem Beizen ist bei Normalstahl meist noch eine zusätzliche mechanische Behandlung durch Streckbiegerichten erforderlich, um den Zunder aufzubrechen und somit ein schnelleres Eindringen der Säure in die Zunderschicht zu ermöglichen. Bei den wesentlich schwieriger zu beizenden nichtrostenden, austenitischen und ferritischen Stählen sind ein Glühen und eine mechanische Vorentzunderung des Bandes beim Beizprozess vorgeschaltet, um eine möglichst gut beizbare Bandoberfläche zu erzielen.For further processing - eg. For example, by cold rolling, for a metallic coating or the direct processing into a final product - the hot-rolled steel strip must have a scale-free surface. Therefore, the scale formed during hot rolling and subsequent cooling must be removed completely. This is usually done by a pickling process, wherein the consisting of the various iron oxides (FeO, Fe 3 O 4 , Fe 2 O 3 ) or in stainless steels also chromium-rich iron oxides existing scale depending on the steel quality by means of various acids (eg., Hydrochloric acid, sulfuric acid , Nitric acid or mixed acid) is dissolved at elevated temperatures by chemical reaction with the acid. Before pickling, normal steel usually has an additional mechanical treatment Stretch bends are required to break up the scale and thus allow faster penetration of the acid into the scale layer. For the stainless steels, austenitic and ferritic steels, which are much more difficult to pickle, annealing and mechanical descaling of the strip during the pickling process are used upstream to achieve the best possible strip surface.
Ein Verfahren bzw. eine Anlage der gattungsgemäßen Art ist aus der DE 100 22 045 C1 bekannt. Dort ist offenbart, dass ein Band durch eine Beizeinrichtung geführt wird, wobei vor und hinter der Beizeinrichtung jeweils eine Walzeinheit angeordnet ist. In Förderrichtung des Bandes hinter der zweiten Walzeinheit durchläuft das Band einen Glühofen und anschließend ein Beizbecken, in dem der Zunder von der Bandoberfläche entfernt wird. Vor dem Aufwickeln des insoweit fertiggestellten Bandes kann dieses noch in einem Dressierwalzwerk abschließend bearbeitet werden.A method or a system of the generic type is known from DE 100 22 045 C1. There, it is disclosed that a strip is passed through a pickling device, wherein in front of and behind the pickling device a respective rolling unit is arranged. In the conveying direction of the belt behind the second roller unit, the belt passes through an annealing furnace and then a pickling tank in which the scale is removed from the surface of the belt. Before winding up the tape that has been completed so far, it can be finally finished in a temper rolling mill.
Die WO 00/37189 und die WO 00/37190 offenbaren eine Vorrichtung zur Herstellung eines Metallbandes, bei dem das Band zunächst ein einer mehrgerüstigen Walzstrasse in seiner Dicke reduziert wird. Anschließend gelangt das Band in einen Glühofen; im weiteren Verlauf wird das Band durch eine Beizvorrichtung geführt. Vor dem Aufwickeln des Bandes kann sich auch hier eine Walzoperation anschließen, die jedoch nur noch eine geringfügige Dickenreduzierung am Band vornimmt.WO 00/37189 and WO 00/37190 disclose a device for producing a metal strip, in which the strip is first reduced in its thickness to a multi-stand rolling course. Subsequently, the tape enters an annealing furnace; in the further course, the strip is passed through a pickling device. Before the tape is wound up, a rolling operation can follow, but only a slight reduction of the thickness on the belt is required.
Die US 2001/0037667 A1 offenbart eine ähnliche Vorrichtung zur Herstellung eines Metallbandes. Hier ist jedoch keine Erwärmung des Bandes vorgesehen. Das Band wird lediglich nach dem Entzundern in einer Beizlinie durch ein Walzwerk geführt.US 2001/0037667 A1 discloses a similar apparatus for producing a metal strip. Here, however, no heating of the band is provided. The strip is passed through a rolling mill only after descaling in a pickling line.
Die vorbekannten Verfahren weisen den Nachteil auf, dass teilweise auf verzunderten bzw. auf nur teilentzunderten Oberflächen gewalzt werden muss. Durch das Walzen auf diesen Bandoberflächen tritt ein wesentlich höherer Walzenverschleiß auf als bei der Walzung auf einer entzunderten Oberfläche. Weiterhin kann dadurch nicht die Oberflächenqualität erzeugt werden, wie sie vielfach gefordert wird, so dass aufwendige Nachbehandlungen notwendig sind.The previously known methods have the disadvantage that it is necessary to roll partially on scaled or on only partially demineralized surfaces. By rolling on these belt surfaces occurs a significantly higher roller wear as when rolling on a descaled surface. Furthermore, this can not produce the surface quality, as it is often required, so that expensive post-treatments are necessary.
Weiterhin ist es mit Blick auf die Wirtschaftlichkeit des in Rede stehenden Verfahrens sehr nachteilig, dass die dem Walzwerk nachfolgenden Einrichtungen, und hier namentlich der Glühofen und die Beizlinie, in ihren Ausmaßen der durch den Walzprozess typischerweise um 30 bis 40 % reduzierten Banddicke angepasst werden müssen; da das Band bereits dünner, jedoch länger ist, müssen auch der Glühofen und die Beizlinie entsprechend lang ausgelegt werden, was zu hohen Kosten der Anlage führt.Furthermore, it is very disadvantageous in view of the economic viability of the process in question that the rolling mill following facilities, and in particular the annealing furnace and the pickling line, must be adjusted in their dimensions of the reduced by the rolling process typically 30 to 40% band thickness ; Since the strip is already thinner, but longer, the annealing furnace and the pickling line must be designed to be correspondingly long, which leads to high costs of the system.
Der Erfindung liegt daher die Aufgabe zugrunde, ein Verfahren und eine zugehörige Anlage der eingangs genannten Gattung zu schaffen, mit dem bzw. mit der es möglich ist, die genannten Nachteile zu vermeiden, womit insbesondere eine höhere Produktivität und Wirtschaftlichkeit bei der Herstellung eines Bandes erzielt werden sollen; weiterhin soll die Oberflächenqualität des gefertigten Bandes verbessert werden.The invention is therefore based on the object to provide a method and an associated system of the type mentioned, with which or with which it is possible to avoid the disadvantages mentioned, which in particular achieves a higher productivity and efficiency in the production of a strip to be Furthermore, the surface quality of the finished strip is to be improved.
Die Lösung dieser Aufgabe durch die Erfindung ist verfahrensgemäß dadurch gekennzeichnet, dass der Walzprozess erst nach der Erwärmung des Bandes und nach der chemischen Behandlung durchgeführt wird.The solution of this problem by the invention according to the method is characterized in that the rolling process is carried out only after the heating of the belt and after the chemical treatment.
Mit dieser Vorgehensweise wird erreicht, dass in der Fertigungsanlage die drei Prozessschritte Walzen des Bandes auf die gewünschte Dicke, Durchführung einer Wärmebehandlung des Bandes durch einen Glühprozess und Entzundern des Bandes mittels Beizen erfolgen, wobei die obigen angesprochenen Nachteile nicht zutage treten: Da das Walzen des Bandes von der ursprünglichen auf die reduzierte, endgültige Dicke erst in Förderrichtung hinter dem Glühen und dem Beizen stattfindet, können sowohl der Glühofen als auch die Beizlinie in ihren jeweiligen Ausmaßen kleiner ausgelegt werden. Ferner erfolgt der genannte Walzprozess erst auf einer vollkommen entzunderten Bandoberfläche, so dass der Walzenverschleiß gering bleibt. Weiterhin entsteht durch den vorgeschlagenen Verfahrensablauf eine verbesserte Bandoberflächen-Qualität, ohne, dass weitergehende Maßnahmen ergriffen werden müssen.This procedure ensures that the three process steps of rolling the strip to the desired thickness, carrying out a heat treatment of the strip by an annealing process and descaling the strip by means of pickling are carried out in the production plant, the above-mentioned disadvantages not being apparent Bandes of the original to the reduced, final thickness takes place only in the conveying direction after annealing and pickling, both the annealing furnace and the pickling line can be made smaller in their respective dimensions. Furthermore, said rolling process takes place only on a completely descaled strip surface, so that the roller wear remains low. Furthermore, the proposed procedure results in improved strip surface quality without the need for further measures.
Es wird vorgeschlagen, dass vorzugsweise die Erwärmung des Bandes, die chemische Behandlung des Bandes und der Walzprozess in dieser Reihenfolge durchgeführt werden. Bei dem Walzprozess handelt es sich bevorzugt um einen Tandem-Walzprozess. Generell ist unter Walzprozess hier zu verstehen, dass das Band durch ihn in seiner Dicke wesentlich, vorzugsweise mindestens um 20 %, reduziert wird. Wie bereits oben angesprochen, handelt es sich bei der chemischen Behandlung des Bandes bevorzugt um einen Beizprozess.It is suggested that preferably the heating of the belt, the chemical treatment of the belt and the rolling process are performed in this order. The rolling process is preferably a tandem rolling process. In general, rolling process is to be understood here as meaning that the strip is substantially reduced in its thickness, preferably by at least 20%. As already mentioned above, the chemical treatment of the strip is preferably a pickling process.
Die erfindungsgemäße Vorrichtung zum kontinuierlichen Herstellen eines metallischen, kaltgewalzten Bandes weist eine Einrichtung zum Erwärmen, d. h. insbesondere zum Glühen, des Bandes, eine Einrichtung zum chemischen Behandeln des Bandes und eine Einrichtung zum Walzen des Bandes auf. Erfindungsgemäß ist vorgesehen, dass die Einrichtung zum Walzen des Bandes in Förderrichtung hinter der Einrichtung zum Erwärmen des Bandes und der Einrichtung zum chemischen Behandeln des Bandes angeordnet ist, wobei die Einrichtung zum Walzen des Bandes mindestens eine Tandem-Walzstrasse aufweist. Diese besteht aus mehreren Walzgerüsten, die als Walzwerk des Typs 6-high oder als Walzwerk des Typs Z-high ausgebildet sein können. Außer dieser Walzeinrichtung ist keine weitere Einrichtung zwecks Dickenreduzierung des Bandes erforderlich.The device according to the invention for the continuous production of a metal, cold-rolled strip has a device for heating, i. H. in particular for annealing the strip, means for chemically treating the strip, and means for rolling the strip. According to the invention, the device for rolling the strip in the conveying direction is arranged behind the device for heating the strip and the device for chemically treating the strip, wherein the device for rolling the strip has at least one tandem rolling train. This consists of several rolling stands, which can be designed as a rolling mill of the type 6-high or as a rolling mill of the Z-high type. In addition to this rolling device no further device for the purpose of reducing the thickness of the tape is required.
Zur Qualitätsverbesserung kann ferner zwischen der Einrichtung zum Erwärmen des Bandes (Glühofen) und der Einrichtung zum chemischen Behandeln des Bandes (Beizlinie) eine Streckrichteinheit angeordnet sein. Weiterhin kann zwischen dem Glühofen und der Beizlinie eine Metallkorn-Strahleinheit angeordnet werden.In order to improve the quality further, a draft straightening unit can be arranged between the device for heating the strip (annealing furnace) and the device for chemically treating the strip (pickling line). Furthermore, a metal grain jet unit can be arranged between the annealing furnace and the pickling line.
In Förderrichtung hinter der Einrichtung zum chemischen Behandeln des Bandes kann ferner eine Besäumeinheit angeordnet werden, um das Band seitlich zu beschneiden.In the conveying direction downstream of the device for the chemical treatment of the strip, a trimming unit may further be arranged to laterally trim the strip.
Die Einhaltung eines möglichst gleichmäßigen Laufs des Bandes durch die Fertigungsanlage wird dadurch erleichtert, dass die Vorrichtung mindestens einen, vorzugsweise drei Bandspeicher aufweist.The maintenance of the smoothest possible running of the belt through the manufacturing facility is facilitated by the fact that the device has at least one, preferably three band memory.
Je nach der Produktionsmenge des Bandes kann die erläuterte Fertigungsvorrichtung auch als kombinierte Warm- und Kaltbandglüh- und -beizlinie mit integrierter Walzstrasse (Tandemstraße) betrieben werden. Um dies zu begünstigen, kann zusätzlich in Förderrichtung vor der Einrichtung zum Erwärmen des Bandes, insbesondere vor dem Einlauf-Bandspeicher, eine Entfettungseinrichtung angeordnet werden.Depending on the production volume of the strip, the described manufacturing device can also be operated as a combined hot and cold strip annealing and pickling line with integrated rolling train (tandem mill). In order to favor this, a degreasing device can additionally be arranged in the conveying direction before the device for heating the strip, in particular in front of the inlet strip store.
In der Zeichnung ist ein Ausführungsbeispiel der Erfindung dargestellt. Die einzige Figur zeigt schematisch eine Vorrichtung zur Herstellung eines Edelstahlbandes.In the drawing, an embodiment of the invention is shown. The single figure shows schematically a device for producing a stainless steel strip.
In der Figur ist eine Vorrichtung 2 zu sehen, auf der ein Metallband 1 (Metallstrang) verarbeitet wird. Dabei wird das Band 1 in Förderrichtung R - d. h. in der Figur von links nach rechts - durch die Vorrichtung 2 geführt, wobei ein kontinuierlicher Durchlauf des Bandes 1 (Durchlauf mit weitgehend konstanter Bandgeschwindigkeit) angestrebt wird.In the figure, a device 2 can be seen, on which a metal strip 1 (metal strand) is processed. In this case, the band 1 in the conveying direction R - d. H. in the figure from left to right - guided by the device 2, wherein a continuous passage of the belt 1 (pass with a substantially constant belt speed) is sought.
In einem nicht näher dargestellten Eintrittsabschnitt 13 wird das Band 1 der Vorrichtung 2 zugeführt. Das Band 1 wird dabei von einer nicht dargestellten Abwickeleinheit abgewickelt und in die Vorrichtung 2 geleitet. In Förderrichtung R schließt sich eine Entfettungseinrichtung 12 an, in der die Bandoberfläche gereinigt wird. Anschließend gelangt das Band 1 in einen Bandspeicher 9 (Einlaufspeicher), der unterhalb einer Einrichtung 3 zum Erwärmen des Bandes 1 (Glühofen) positioniert ist. Über den Bandspeicher 9 kann erreicht werden, dass auch bei geringfügigen äußeren Störungen in der Bandzuführung ein kontinuierlicher Lauf des Bandes erreicht wird.In an
Im Glühofen 3 wird das Band 1 einer Wärmebehandlung unterzogen. Anschießend gelangt es zu einer Streckrichteinheit 6, in der das Band 1 geglättet wird. Der Streckrichteinheit 6 nachgeordnet ist eine Metallkorn-Strahleinheit 7.In the annealing furnace 3, the strip 1 is subjected to a heat treatment. Anschießend it comes to a
In Förderrichtung R hinter der Metallkorn-Strahleinheit 7 ist eine Einrichtung 4 zum chemischen Behandeln des Bandes 1 angeordnet, nämlich eine Beizlinie, in der das Band 1 durch Becken geführt wird, die mit Säure gefüllt sind. Mittels des Beizvorgangs kann die Zunderschicht auf der Oberfläche des Bandes 1 entfernt und dem Band 1 so eine verbesserte Oberflächenqualität verliehen werden.In the conveying direction R behind the metal
Unterhalb der Beizlinie 4 ist ein Bandspeicher 11 (Zwischenspeicher) angeordnet. Von diesem läuft das Band 1 in eine Besäumeinheit 8, in der die Seiten des Bandes 1 beschnitten werden. Von der Besäumeinheit 8 gelangt das Band 1 über einen weiteren Bandspeicher 10 (Auslaufspeicher) zur Einrichtung 5 zum Walzen des Bandes 1. Diese Einrichtung 5 ist als Tandem-Walzstraße ausgeführt. Es sind drei hintereinander angeordnete Walzgerüste 5a, 5b und 5c vorhanden, in denen das Band 1 gewalzt und dadurch in seiner Dicke reduziert wird.Below the pickling line 4, a tape storage 11 (buffer) is arranged. From this, the tape 1 runs in a Besäumeinheit 8, in which the sides of the tape 1 are cut. From the trimming unit 8, the belt 1 passes through a further belt store 10 (discharge storage) to the device 5 for rolling the belt 1. This device 5 is designed as a tandem rolling mill. There are three consecutively arranged rolling stands 5a, 5b and 5c, in which the strip 1 is rolled and thereby reduced in thickness.
Hinter der Tandem-Walzstraße 5 ist ein Austrittsabschnitt 14 angeordnet, der eine nicht dargestellte Aufwickeleinheit aufweist, mit der das fertige Band 1 aufgewickelt werden kann.Behind the tandem rolling train 5, an
Die Tandem-Walzstraße 5 weist - wie bereits gesagt - drei Walzgerüste 5a, 5b und 5c auf, die in der Bauart eines Mehrwalzen-Kaltwalzwerkes, eines 6-high-Walzwerkes oder eines Z-high-Walzwerkes ausgebildet sein können. Dadurch, dass die Dickenreduzierung des Bandes 1 erst in der- einzigen - Einrichtung 5 zum Walzen des Bandes 1 am Ende der Vorrichtung 2 erfolgt, weist das Band 1 vor der Tandem-Walzstraße 5 noch eine relativ große Dicke, nämlich die Dicke, mit der das Band 1 in die Vorrichtung 2 eintritt, auf. Dies hat zur Folge, dass die Baulänge sowohl des Glühofens 3 als auch der Beizlinie 4 relativ gering gehalten werden kann.As already mentioned, the tandem rolling train 5 has three rolling stands 5a, 5b and 5c, which may be designed in the form of a multi-roll cold rolling mill, a 6-high rolling mill or a Z-high rolling mill. Due to the fact that the reduction in the thickness of the strip 1 takes place only in the only device 5 for rolling the strip 1 at the end of the device 2, the strip 1 has before the tandem rolling mill 5 still a relatively large thickness, namely the thickness at which the tape 1 enters the device 2, on. This has the consequence that the length of both the annealing furnace 3 and the pickling line 4 can be kept relatively low.
Es ergibt sich dadurch ein relativ kompakter Aufbau der Vorrichtung 2, der die Investitionskosten für die Vorrichtung 2 gering hält. Sowohl der Glühofen 3 als auch die Beizlinie 4 können also auf die ursprüngliche Dicke des Bandes 1 ausgelegt werden, mit der das Band 1 in die Vorrichtung 2 eintritt.This results in a relatively compact design of the device 2, which keeps the investment costs for the device 2 low. Both the annealing furnace 3 and the pickling line 4 can therefore be designed for the original thickness of the strip 1, with which the strip 1 enters the device 2.
Zumindest für die austenitischen und die einfachen ferritischen Materialien kann eine Dickenreduzierung ohne vorherige Glühung vorgenommen werden, was zu einer kleineren maximalen Dickenreduzierung von maximal 30 bis 40 % führt.At least for the austenitic and simple ferritic materials, a reduction in thickness can be made without prior annealing, resulting in a smaller maximum thickness reduction of a maximum of 30 to 40%.
Die maximale Dickenreduzierung des Bandes 1 pro Durchlauf durch die Vorrichtung 2 richtet sich nur nach den Materialien und der Leistungsfähigkeit der Tandem-Walzstraße 5; auf das ungeglühte Band muss keine Rücksicht genommen werden.The maximum thickness reduction of the belt 1 per pass through the device 2 depends only on the materials and the performance of the tandem rolling mill 5; no consideration has to be given to the unannealed tape.
Ein Walzgerüst der Tandem-Walzstraße 5 kann so ausgelegt sein, dass bei einer Schlussglühung das Band 1 dressiert werden kann.A rolling stand of the tandem rolling train 5 can be designed so that the band 1 can be dressed during a final annealing.
Das entzunderte und vorzugsweise bereits besäumte Band kann - im Anschluss an die Vorrichtung 2 - ohne Zwischenlagerung unter gleichmäßigem Bandzug kontinuierlich in einer Nachfolgeeinrichtung (Feuerverzinkungsanlage, etc.) einlaufen. Das fertige Band kann dabei hinter der Nachfolgeeinrichtung wechselweise mit zwei Haspeln aufgewickelt und mit einer Schere unterteilt werden.The descaled and preferably already edged strip can - following the device 2 - without intermediate storage under constant tension continuously in a follow-up device (hot dip galvanizing, etc.) enter. The finished tape can be wound behind the Nachfolgeeinrichtung alternately with two reels and divided with a pair of scissors.
- 11
- Band (Metallstrang)Ribbon (metal strand)
- 22
- Vorrichtungcontraption
- 33
- Einrichtung zum Erwärmen des Bandes (Glühofen)Device for heating the strip (annealing furnace)
- 44
- Einrichtung zum chemischen Behandeln des Bandes (Beizeinrichtung)Device for the chemical treatment of the strip (pickling device)
- 55
- Einrichtung zum Walzen des Bandes (Tandem-Walzstraße)Device for rolling the strip (tandem rolling mill)
- 5a5a
- Walzgerüstrolling mill
- 5b5b
- Walzgerüstrolling mill
- 5c5c
- Walzgerüstrolling mill
- 66
- StreckrichteinheitTension leveling unit
- 77
- Metallkorn-StrahleinheitMetal grain blowing unit
- 88th
- Besäumeinheittrimming shear
- 99
- Bandspeicher (Einlaufspeicher)Tape storage (infeed storage)
- 1010
- Bandspeicher (Auslaufspeicher)Tape storage (discharge storage)
- 1111
- Bandspeicher (Zwischenspeicher)Tape storage (cache)
- 1212
- Entfettungseinrichtungdegreasing
- 1313
- Eintrittsabschnittentry section
- 1414
- Austrittsabschnittexit section
- RR
- Förderrichtungconveying direction
Claims (12)
- Method for continuous production of a cold-rolled, metallic strap (1), particularly a stainless steel strip, wherein a hot-rolled metal strip is unwound from an unwinding unit and the strip (1) to be produced is led in conveying direction (R) through a device (2) in which the strip (1) is subjected to a rolling process, a heating and a chemical treatment, characterised in that the rolling process is carried out only after the heating of the strip and after the chemical treatment.
- Method according to claim 1, characterised in that the heating of the strip (1), the chemical treatment of the strip (1) and the rolling process are carried out in this sequence.
- Method according to claim 1 or 2, characterised in that the rolling process is a tandem rolling process.
- Method according to one of claims 1 to 3, characterised in that the strip (1) is substantially reduced in its thickness by the rolling process, preferably by at least 20%.
- Method according to one of claims 1 to 4, characterised in that the chemical treatment is a pickling process.
- Plant with an unwinding unit and a device (2) for continuous production of a cold-rolled metallic strip (1), particularly a stainless steel strip, particularly for carrying out the method according to one of claims 1 to 5, wherein a hot-rolled metal strip is unwound from the unwinding unit and the strip (1) to be produced transits the device (2) in conveying direction (R) and the device (2) comprises equipment (3) for heating the strip (1), equipment (4) for chemical treatment of the strip (1) and equipment (5) for rolling the strip (1), characterised in that the equipment (5) for rolling the strip (1) is arranged behind, in conveying direction (R), the equipment (3) for heating the strip (1) and the equipment (4) for chemical treatment of the strip (1), and the equipment (5) for rolling the strip (2) comprises a tandem rolling train (5a, 5b, 5c).
- Plant according to claim 6, characterised in that the roll stands (5a, 5b, 5c) are constructed as a multi-roll cold-rolling mill with six-high or Z-high roll arrangement.
- Plant according to claim 6 or 7, characterised in that the equipment (4) for chemical treatment of the strip (1) is pickling equipment.
- Plant according to one of claims 6 to 8, characterised in that a stretch-levelling unit (6) is arranged between the equipment (3) for heating the strip (1) and the equipment (4) for chemical treatment of the strip (1).
- Plant according to one of claims 6 to 9, characterised in that a metal grain blast unit (7) is arranged between the equipment (3) for heating the strip (1) and the equipment (4) for chemical treatment of the strip (1).
- Plant according to one of claims 6 to 10, characterised in that a trimming unit (8) is arranged behind, in conveying direction (R), the equipment (4) for chemical treatment of the strip (1).
- Plant according to one of claims 6 to 11, characterised in that degreasing equipment (12) is arranged in front, in conveying direction (R), of the equipment (3) for heating the strip (1).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10234109 | 2002-07-26 | ||
DE10234109A DE10234109A1 (en) | 2002-07-26 | 2002-07-26 | Method and device for the continuous production of metallic strips |
PCT/EP2003/007464 WO2004012878A1 (en) | 2002-07-26 | 2003-07-10 | Method and device for the continuous production of metallic strips |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1525060A1 EP1525060A1 (en) | 2005-04-27 |
EP1525060B1 true EP1525060B1 (en) | 2006-08-30 |
Family
ID=30010423
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03766145A Expired - Lifetime EP1525060B1 (en) | 2002-07-26 | 2003-07-10 | Method and device for the continuous production of metallic strips |
Country Status (15)
Country | Link |
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US (1) | US20060053617A1 (en) |
EP (1) | EP1525060B1 (en) |
JP (1) | JP2006502003A (en) |
KR (1) | KR100990865B1 (en) |
CN (1) | CN1671490A (en) |
AT (1) | ATE337862T1 (en) |
AU (1) | AU2003250025B2 (en) |
BR (1) | BR0312756B1 (en) |
DE (2) | DE10234109A1 (en) |
ES (1) | ES2271651T3 (en) |
MX (1) | MXPA05001083A (en) |
RU (1) | RU2350415C2 (en) |
TW (1) | TWI273929B (en) |
WO (1) | WO2004012878A1 (en) |
ZA (1) | ZA200500458B (en) |
Families Citing this family (6)
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TWI389747B (en) * | 2007-10-16 | 2013-03-21 | Ihi Metaltech Co Ltd | Recoiling facility for magnesium alloy sheet |
KR101103346B1 (en) * | 2009-07-14 | 2012-01-11 | 주식회사 동방플랜텍 | Processing line apparatus for cold rolled steel strip |
RU2499640C1 (en) * | 2012-06-14 | 2013-11-27 | Открытое акционерное общество "Северсталь" (ОАО "Северсталь") | Method of producing cold-rolled stock for wrapping strap |
RU2592609C1 (en) * | 2015-04-21 | 2016-07-27 | Публичное акционерное общество "Северсталь" (ПАО "Северсталь") | Production method of cold-rolled mill products for baling band |
TWI625172B (en) * | 2016-09-19 | 2018-06-01 | Composite cold rolling line | |
KR102503902B1 (en) | 2018-09-28 | 2023-02-27 | 제이에프이 스틸 가부시키가이샤 | Method for producing grain-oriented electrical steel sheet and cold-rolling facility |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05161901A (en) * | 1991-12-12 | 1993-06-29 | Sumitomo Metal Ind Ltd | Manufacture of cold rolled strip metal having good surface gloss |
JPH07164008A (en) * | 1993-12-15 | 1995-06-27 | Nkk Corp | Pickling to cold rolling equipment |
JPH0824936A (en) * | 1994-07-15 | 1996-01-30 | Nisshin Steel Co Ltd | Method and equipment for rolling metal strip |
JPH08246060A (en) * | 1995-03-10 | 1996-09-24 | Kawasaki Steel Corp | Production of steel sheet for can |
DE19532278B4 (en) * | 1995-09-01 | 2006-07-27 | Bwg Bergwerk- Und Walzwerk-Maschinenbau Gmbh | Method for producing a cold-rolled strip in one pass |
FR2775205B1 (en) * | 1998-02-25 | 2000-03-24 | Usinor | INSTALLATION FOR MANUFACTURING COLD ROLLED STAINLESS STEEL STRIPS |
KR100625907B1 (en) * | 1998-12-18 | 2006-09-26 | 아웃토컴푸 스테인레스 에이비 | Method for manufacturing of strips and rolling mill line |
JP3460612B2 (en) * | 1999-03-04 | 2003-10-27 | Jfeスチール株式会社 | Process line with surface defect meter |
JP3695212B2 (en) * | 1999-03-30 | 2005-09-14 | Jfeスチール株式会社 | Cold rolling method for stainless steel strip |
DE10022045C1 (en) * | 2000-02-22 | 2001-07-19 | Sundwig Gmbh | Finishing line for continuously producing cold-rolled metallic strips comprises a device for pickling the strip arranged in region of the start, the conveyor path of the strip and cold roll stands arranged before/after the pickling device |
JP2001262232A (en) * | 2000-03-15 | 2001-09-26 | Kawasaki Steel Corp | Method for producing stainless steel strip |
FR2807957B1 (en) * | 2000-04-21 | 2002-08-02 | Vai Clecim | METHOD AND INSTALLATION FOR COLD ROLLING |
JP2001340905A (en) * | 2000-05-31 | 2001-12-11 | Kawasaki Steel Corp | Rolling method of steel plate having mill scale |
-
2002
- 2002-07-26 DE DE10234109A patent/DE10234109A1/en not_active Withdrawn
-
2003
- 2003-07-03 TW TW092118181A patent/TWI273929B/en active
- 2003-07-10 US US10/522,484 patent/US20060053617A1/en not_active Abandoned
- 2003-07-10 JP JP2004525173A patent/JP2006502003A/en active Pending
- 2003-07-10 ES ES03766145T patent/ES2271651T3/en not_active Expired - Lifetime
- 2003-07-10 KR KR1020057001351A patent/KR100990865B1/en not_active IP Right Cessation
- 2003-07-10 CN CNA03817975XA patent/CN1671490A/en active Pending
- 2003-07-10 MX MXPA05001083A patent/MXPA05001083A/en active IP Right Grant
- 2003-07-10 DE DE50304876T patent/DE50304876D1/en not_active Expired - Fee Related
- 2003-07-10 AT AT03766145T patent/ATE337862T1/en not_active IP Right Cessation
- 2003-07-10 EP EP03766145A patent/EP1525060B1/en not_active Expired - Lifetime
- 2003-07-10 BR BRPI0312756-7A patent/BR0312756B1/en not_active IP Right Cessation
- 2003-07-10 RU RU2005105314/02A patent/RU2350415C2/en not_active IP Right Cessation
- 2003-07-10 WO PCT/EP2003/007464 patent/WO2004012878A1/en active IP Right Grant
- 2003-07-10 AU AU2003250025A patent/AU2003250025B2/en not_active Ceased
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2005
- 2005-01-18 ZA ZA200500458A patent/ZA200500458B/en unknown
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MXPA05001083A (en) | 2005-06-06 |
JP2006502003A (en) | 2006-01-19 |
BR0312756A (en) | 2005-04-26 |
DE10234109A1 (en) | 2004-02-05 |
ZA200500458B (en) | 2006-04-26 |
CN1671490A (en) | 2005-09-21 |
BR0312756B1 (en) | 2011-05-31 |
WO2004012878A1 (en) | 2004-02-12 |
TW200414942A (en) | 2004-08-16 |
ES2271651T3 (en) | 2007-04-16 |
RU2005105314A (en) | 2005-07-20 |
EP1525060A1 (en) | 2005-04-27 |
US20060053617A1 (en) | 2006-03-16 |
RU2350415C2 (en) | 2009-03-27 |
ATE337862T1 (en) | 2006-09-15 |
AU2003250025B2 (en) | 2008-08-28 |
DE50304876D1 (en) | 2006-10-12 |
TWI273929B (en) | 2007-02-21 |
KR20050021565A (en) | 2005-03-07 |
AU2003250025A1 (en) | 2004-02-23 |
KR100990865B1 (en) | 2010-10-29 |
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