EP0745114B1 - Verfahren zur erzeugung von brenngas - Google Patents
Verfahren zur erzeugung von brenngas Download PDFInfo
- Publication number
- EP0745114B1 EP0745114B1 EP95908915A EP95908915A EP0745114B1 EP 0745114 B1 EP0745114 B1 EP 0745114B1 EP 95908915 A EP95908915 A EP 95908915A EP 95908915 A EP95908915 A EP 95908915A EP 0745114 B1 EP0745114 B1 EP 0745114B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- gasification
- process stage
- temperature carbonization
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 43
- 230000008569 process Effects 0.000 title claims abstract description 39
- 238000002309 gasification Methods 0.000 claims abstract description 51
- 239000007789 gas Substances 0.000 claims abstract description 44
- 238000003763 carbonization Methods 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 17
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 15
- 239000001301 oxygen Substances 0.000 claims abstract description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000567 combustion gas Substances 0.000 claims abstract description 11
- 238000002844 melting Methods 0.000 claims abstract description 11
- 230000008018 melting Effects 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 239000000571 coke Substances 0.000 claims abstract description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003245 coal Substances 0.000 claims abstract description 6
- 239000011368 organic material Substances 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 4
- 239000010813 municipal solid waste Substances 0.000 claims abstract description 3
- 238000001035 drying Methods 0.000 claims abstract 3
- 238000002485 combustion reaction Methods 0.000 claims description 12
- 239000000446 fuel Substances 0.000 claims description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- 239000000428 dust Substances 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- -1 sludges Substances 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 2
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000002956 ash Substances 0.000 abstract description 5
- 235000002918 Fraxinus excelsior Nutrition 0.000 abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000010828 elution Methods 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000036284 oxygen consumption Effects 0.000 abstract description 2
- 239000002893 slag Substances 0.000 abstract description 2
- 239000003546 flue gas Substances 0.000 abstract 1
- 239000002737 fuel gas Substances 0.000 description 17
- 239000000126 substance Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000002699 waste material Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 239000002028 Biomass Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000007872 degassing Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000002440 industrial waste Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 206010053615 Thermal burn Diseases 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000010815 organic waste Substances 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- PIYVNGWKHNMMAU-UHFFFAOYSA-N [O].O Chemical compound [O].O PIYVNGWKHNMMAU-UHFFFAOYSA-N 0.000 description 1
- 239000002154 agricultural waste Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000003923 scrap metal Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0903—Feed preparation
- C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
- C10J2300/1628—Ash post-treatment
Definitions
- the invention relates to a method for producing fuel gas from water and ballasted organic substances such as coal, municipal and industrial Sludge, wood and biomass, municipal and industrial waste and refuse as well as waste products, residues and others.
- the invention can be used in particular for energy recovery of biomass and wood from cyclically cultivated agricultural areas, especially recultivated mining areas and thus for the design of carbon dioxide neutral Converting natural fuels into mechanical and Thermal energy and for the useful disposal of municipalities, Commercial, agricultural and industrial waste, other organic waste, Residues, by-products and waste products.
- Procedures determine accordingly for combustion, degassing and gasification individually or in combination State of the art with the following objectives: - Production of combustion gas as Thermal energy source for steam generation by combustion, - production of high calorific solid and liquid fuels such as coke, charcoal and liquid, oil-like tars through smoldering, degassing and gasification, - production of fuel gas while avoiding solid and liquid fuels through complete Gasification.
- the process management decides whether the receive liquid and large molecular carbonization products or also by Oxidation be gasified.
- the oldest type of gasification is fixed bed gasification, where fuel and Gasification agents are moved in countercurrent to each other. This procedure achieve the highest possible gasification efficiency with the lowest possible Oxygen demand.
- the disadvantage of this type of gasification is that in Gasification gas the fuel lamp and all known liquid smoldering products are included. This type of gasification also requires lumpy fuel.
- the gasification in the fluidized bed, known as Winkler gasification eliminated this lack of fixed bed gasification largely, but not completely.
- gasifying bituminous fuels e.g. not always the necessary Freedom from tar of the gasification gas as used for the application of the gas Fuel required for internal combustion engines is reached. Furthermore is due to the higher average temperature level during process control compared to fixed bed gasification the oxygen consumption clearly higher.
- the temperature level of the Winkler gasification has the consequence that a large part of the carbon input is not converted into fuel gas, but in the form of dust and, bound to the ashes, from the process again is carried out.
- This lack of gasification technology can be compensated with the high temperature entrained flow gasification processes, which are usually above the melting point the ashes work, be avoided.
- Waste is broken down by carbonization into carbonization gas and carbonization and thus into one required for gasification in an exothermic entrained-flow gasification Form prepared.
- the transition to exothermic entrained flow gasification is combined with increasing oxygen demand and decreasing efficiency, although the organic matter of waste is almost entirely in Fuel gas is converted.
- the causes are the high temperature level of these gasification processes, which have the consequence that a large part of the Fuel heat is converted into physical enthalpy of the fuel gas.
- DE 42 09 549 remedies this deficiency by combining partial flow combustion / endothermic Entrained flow gasification a pyrolysis for thermal Preparation of the fuels, especially waste materials, upstream.
- the lack this method is that here the hot gasifying agent by combustion of pyrolysis coke with air and / or oxygen and that Olefins, aromatics and others containing smoldering gas is used for the reduction.
- the invention aims to provide a process for the gasification of organic substances, in particular water and ballast, to propose that the inorganic Share of these substances as a glazed, elution-resistant product and the organic Substance of these substances to tar-free fuel gas, which also converts to synthesis gas can be converted, compared to the prior art Entrained-flow gasification lower consumption of oxygen-containing gasifying agent as well as compared to the fluidized bed process and entrained-flow gasification higher gasification efficiency, based on the applied chemical Enthalpy of the fuel gas.
- the technical problem to be solved by the invention is to provide a portion of the physical enthalpy required for reaching the temperature level above the melting point of the inorganic portion of the substances to be gasified is required to return to chemical enthalpy as the process continues convert.
- the inorganic substance contains ballast, organic materials into a glazed, elution-resistant building material is reduced when the need for oxygen-containing gasifying agent is reduced the level of fluidized bed gasification and complete gasification of the organic matter at a temperature level that the Winkler gasification corresponds to and, measured by the chemical enthalpy of the fuel gas, higher gasification efficiency compared to the prior art.
- This material is cut to an edge length of 20 to 50 mm in a shredder (1) crushed and indirectly via a gas-tight lock system (2) heated smoldering chamber (3) working under normal pressure, in which the feed material is moved mechanically if necessary.
- a gas-tight lock system (2) heated smoldering chamber (3) working under normal pressure, in which the feed material is moved mechanically if necessary.
- the indirect Heat supply (4) dries and smoldered the feed, it disintegrates a final temperature of 400 to 500 ° C in approx. 405 kg of solid, which is approximately too 40% carbon, while the rest is mineral, Glass, iron and non-ferrous metals as well as heavy metals and ashes, and 595 kg Smoldering gas, which consists of almost two thirds of water vapor, and all contains other known liquid and gaseous smoldering products.
- the solids from the carbonization are in carbonization gas in a sieve (5) a coarse fraction mainly containing minerals, glass and scrap metal with an edge length greater than 5 mm and a small-grain carbon carrier Cut.
- the coarse fraction is extracted from the via gas-tight lock systems (6) Process carried out and possibly passed to a separation.
- the carbon carrier remains in the system and is passed through a continuous mill (7) and via a pneumatic conveying system (8), the recirculated fuel gas as the conveying medium used, fed to a reduction chamber (9).
- the inorganic part of Carbon carrier is used with that in the reduction chamber (9) Carbon separated in a gas dedusting (10) and together with the in the smoldering chamber (3) produced smoldering gas from a smelting chamber combustion (11) supplied and there with oxygen above the melting temperature of the inorganic substance of the carbon carrier burned.
- the resulting one Liquid slag is discharged into a water bath (12) and from there as elution-resistant Building material granules removed from the process.
- Combustion gas enters the reduction chamber from the melting chamber furnace (11) (9), where part of its carbon dioxide and water vapor is associated with the Carbon carrier reacts endothermically to carbon monoxide and hydrogen, whereby the gas temperature drops to 800 to 900 ° C.
- the feeding of the in the gas dedusting (10) accumulating carbon-containing dust Melting chamber firing (11) is also carried out with a pneumatic conveyor system (13), which uses recycled fuel gas as the carrier medium. That so
- the fuel gas generated corresponds in its composition to a fuel gas that at 800 to 900 ° C during the gasification of the organic matter of the feed with oxygen under normal pressure. It is comparable to an after the gasification gas generated in the fluidized bed gasification process when used an oxygen-water vapor mixture as a gasifying agent.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Industrial Gases (AREA)
- Catalysts (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Gasification And Melting Of Waste (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4404673 | 1994-02-15 | ||
DE4404673A DE4404673C2 (de) | 1994-02-15 | 1994-02-15 | Verfahren zur Erzeugung von Brenngas |
PCT/EP1995/000443 WO1995021903A1 (de) | 1994-02-15 | 1995-02-08 | Verfahren zur erzeugung von brenngas |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0745114A1 EP0745114A1 (de) | 1996-12-04 |
EP0745114B1 true EP0745114B1 (de) | 1999-03-24 |
Family
ID=6510220
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95908915A Expired - Lifetime EP0745114B1 (de) | 1994-02-15 | 1995-02-08 | Verfahren zur erzeugung von brenngas |
Country Status (13)
Country | Link |
---|---|
US (1) | US5849050A (el) |
EP (1) | EP0745114B1 (el) |
JP (1) | JP4057645B2 (el) |
AT (1) | ATE178086T1 (el) |
AU (1) | AU1705995A (el) |
BR (1) | BR9506803A (el) |
CA (1) | CA2183326C (el) |
DE (2) | DE4404673C2 (el) |
DK (1) | DK0745114T3 (el) |
ES (1) | ES2132638T3 (el) |
GR (1) | GR3029982T3 (el) |
NO (1) | NO315125B1 (el) |
WO (1) | WO1995021903A1 (el) |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009055976A1 (de) | 2009-11-27 | 2011-06-01 | Choren Industries Gmbh | Vorrichtung und Verfahren zur Erzeugung eines Synthesegases aus Biomasse durch Flugstrom-Vergasung |
DE102010008384A1 (de) * | 2010-02-17 | 2011-08-18 | Uhde GmbH, 44141 | Verfahren und Vorrichtung zur Nutzung der Enthalpie eines Synthesegases durch Zugabe von nachwachsenden Brennstoffen in den Abkühlraum einer Flugstromvergasung |
DE102012013670A1 (de) | 2012-07-11 | 2014-01-16 | Linde Aktiengesellschaft | Verfahren zur Vergasung kohlenstoffhaltiger Einsatzstoffe |
EP2703716A1 (de) | 2012-08-28 | 2014-03-05 | Linde Aktiengesellschaft | Erwärmung eines Prozessabgases |
DE102013008518A1 (de) | 2013-05-16 | 2014-11-20 | Linde Aktiengesellschaft | Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial |
DE102013008519A1 (de) | 2013-05-16 | 2014-11-20 | Linde Aktiengesellschaft | Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial |
DE102013009950A1 (de) | 2013-06-13 | 2014-12-18 | Linde Aktiengesellschaft | Verfahren und Anlage zur Aufbereitung und thermischen Vergasung von wasserhaltigem organischem Einsatzmaterial |
DE102013012661A1 (de) | 2013-07-30 | 2015-02-05 | Linde Aktiengesellschaft | Verfahren und Anlage zur Anreicherung eines mittels Vergasung erzeugten Synthesegases mit Wasserstoff |
DE102013014042A1 (de) | 2013-08-22 | 2015-02-26 | Linde Aktiengesellschaft | Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial |
DE102013015536A1 (de) | 2013-09-18 | 2015-03-19 | Linde Aktiengesellschaft | Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischen Einsatzmaterial |
DE102013015539A1 (de) | 2013-09-18 | 2015-03-19 | Linde Aktiengesellschaft | Anlage und Verfahren zur zumindest teilweisen Vergasung von festem organischen Einsatzmaterial |
DE102013017546A1 (de) | 2013-10-22 | 2015-04-23 | Linde Aktiengesellschaft | Verfahren und Anlage zur Vergasung von Einsatzmaterial |
DE102013017945A1 (de) | 2013-10-29 | 2015-04-30 | Linde Aktiengesellschaft | Kraftwerk |
DE102013018332A1 (de) | 2013-10-31 | 2015-04-30 | Linde Aktiengesellschaft | Vorrichtung zur Einbringung von festem organischen Einsatzmaterial in eine Vergasungsanlage |
DE102013018992A1 (de) | 2013-11-13 | 2015-05-13 | Linde Aktiengesellschaft | Vorrichtung für eine Zuführung von Vergasungsmittel in einen Niedertemperaturvergaser |
DE102013019655A1 (de) | 2013-11-23 | 2015-05-28 | Linde Aktiengesellschaft | Behälter für einen Niedertemperaturvergaser |
DE102013020889A1 (de) | 2013-12-11 | 2015-06-11 | Linde Aktiengesellschaft | Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial |
DE102013020792A1 (de) | 2013-12-11 | 2015-06-11 | Linde Aktiengesellschaft | Verfahren und Anlage zur Vergasung von festem, organischem Einsatzmaterial |
DE102013020890A1 (de) | 2013-12-11 | 2015-06-11 | Linde Aktiengesellschaft | Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial |
US9234148B2 (en) | 2009-03-04 | 2016-01-12 | Thyssenkrupp Industrial Solution Ag | Process and apparatus for the utilization of the enthalpy of a syngas by additional and post-gasification of renewable fuels |
DE102014016407A1 (de) | 2014-11-05 | 2016-05-12 | Linde Aktiengesellschaft | Verfahren zur Produktion von Synthesegas |
WO2016070988A1 (de) | 2014-11-05 | 2016-05-12 | Linde Aktiengesellschaft | Verfahren zur nutzung von co2 bei der synthesegasproduktion |
CN109539547A (zh) * | 2018-11-14 | 2019-03-29 | 江苏金满穗农业发展有限公司 | 一种以谷糠为燃料的热风炉 |
CN109539548A (zh) * | 2018-11-14 | 2019-03-29 | 江苏金满穗农业发展有限公司 | 一种喷腾燃烧谷壳热风炉 |
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DE19618213A1 (de) * | 1996-05-07 | 1997-11-13 | Petersen Hugo Verfahrenstech | Verfahren zur Erzeugung von Brenngas und Anlage zur Durchführung des Verfahrens |
DE19730385C5 (de) * | 1997-07-16 | 2006-06-08 | Future Energy Gmbh | Verfahren zur Erzeugung von Brenn- und Synthesegas aus Brennstoffen und brennbaren Abfällen und eine Vorrichtung zur Durchführung des Verfahrens |
DE19747324C2 (de) * | 1997-10-28 | 1999-11-04 | Bodo Wolf | Vorrichtung zur Erzeugung von Brenn-, Synthese- und Reduktionsgas aus nachwachsenden und fossilen Brennstoffen, Biomassen, Müll oder Schlämmen |
DE19750327C1 (de) * | 1997-11-13 | 1999-06-02 | Umwelttechnik Stefan Bothur | Verfahren zur Herstellung von Synthesegas aus nachwachsenden zellulosehaltigen Roh- oder Abfallstoffen |
US20020179493A1 (en) * | 1999-08-20 | 2002-12-05 | Environmental & Energy Enterprises, Llc | Production and use of a premium fuel grade petroleum coke |
ES2190689B1 (es) * | 2000-03-15 | 2004-10-16 | Luis M. Santi De Azcoitia Y Villanueva | Procedimiento de obtencion de gas combustible a partir de materiales combustibles. |
DE10049887A1 (de) * | 2000-10-10 | 2002-04-18 | Erwin Keller | Verfahren und Vorrichtung zur energetischen Nutzung nachwachsender organischer Rohstoffe |
US6405664B1 (en) * | 2001-04-23 | 2002-06-18 | N-Viro International Corporation | Processes and systems for using biomineral by-products as a fuel and for NOx removal at coal burning power plants |
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US20060180459A1 (en) * | 2005-02-16 | 2006-08-17 | Carl Bielenberg | Gasifier |
CN100340634C (zh) * | 2005-07-01 | 2007-10-03 | 韩连恩 | 生产生物质炭化燃气的方法及反火生物质炭化燃气发生炉 |
DE102005035921B4 (de) | 2005-07-28 | 2008-07-10 | Choren Industries Gmbh | Verfahren zur endothermen Vergasung von Kohlenstoff |
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UY33038A (es) | 2009-11-20 | 2011-06-30 | Rv Lizenz Ag | Uso termico y quimico de sustancias cabonaceas en particular para la generacion de energia sin emisiones |
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US20130199920A1 (en) * | 2011-02-14 | 2013-08-08 | Elhan Demir | Device and method for the thermochemical harmonising and gasification of wet biomass |
KR101890952B1 (ko) * | 2012-12-26 | 2018-08-22 | 에스케이이노베이션 주식회사 | 기류 건조기를 포함하는 탄소 연료의 가스화 복합 설비 |
DE102014002842A1 (de) | 2014-02-25 | 2015-08-27 | Linde Aktiengesellschaft | Verfahren und Vorrichtung zur Flugstromvergasung von kohlenstoffreichem Material |
EP3219777A1 (en) | 2015-12-09 | 2017-09-20 | Ivan Bordonzotti | Process and plant for transforming combustible materials in clean gas without tars |
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- 1995-02-08 DE DE59505441T patent/DE59505441D1/de not_active Expired - Lifetime
- 1995-02-08 US US08/693,167 patent/US5849050A/en not_active Expired - Lifetime
- 1995-02-08 JP JP52095795A patent/JP4057645B2/ja not_active Expired - Lifetime
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- 1995-02-08 CA CA002183326A patent/CA2183326C/en not_active Expired - Lifetime
- 1995-02-08 AT AT95908915T patent/ATE178086T1/de active
- 1995-02-08 ES ES95908915T patent/ES2132638T3/es not_active Expired - Lifetime
- 1995-02-08 EP EP95908915A patent/EP0745114B1/de not_active Expired - Lifetime
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1996
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Also Published As
Publication number | Publication date |
---|---|
JP4057645B2 (ja) | 2008-03-05 |
CA2183326A1 (en) | 1995-08-17 |
JPH09508663A (ja) | 1997-09-02 |
AU1705995A (en) | 1995-08-29 |
US5849050A (en) | 1998-12-15 |
ATE178086T1 (de) | 1999-04-15 |
DE59505441D1 (de) | 1999-04-29 |
ES2132638T3 (es) | 1999-08-16 |
GR3029982T3 (en) | 1999-07-30 |
DK0745114T3 (da) | 1999-05-25 |
CA2183326C (en) | 2005-12-27 |
NO963301L (no) | 1996-08-08 |
NO315125B1 (no) | 2003-07-14 |
WO1995021903A1 (de) | 1995-08-17 |
DE4404673C2 (de) | 1995-11-23 |
NO963301D0 (no) | 1996-08-08 |
EP0745114A1 (de) | 1996-12-04 |
BR9506803A (pt) | 1997-09-30 |
DE4404673A1 (de) | 1995-08-17 |
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