EP0743359B1 - Nettoyant aqueux pour sol hautement concentré - Google Patents

Nettoyant aqueux pour sol hautement concentré Download PDF

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Publication number
EP0743359B1
EP0743359B1 EP96107465A EP96107465A EP0743359B1 EP 0743359 B1 EP0743359 B1 EP 0743359B1 EP 96107465 A EP96107465 A EP 96107465A EP 96107465 A EP96107465 A EP 96107465A EP 0743359 B1 EP0743359 B1 EP 0743359B1
Authority
EP
European Patent Office
Prior art keywords
cleaner
alcohol
weight
intensive
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP96107465A
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German (de)
English (en)
Other versions
EP0743359A1 (fr
Inventor
Heiko Dr. Faubel
Birgit Skodell
Karl-Heinz Rogmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab GmbH and Co oHG
Original Assignee
Henkel Ecolab GmbH and Co KG
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Publication of EP0743359A1 publication Critical patent/EP0743359A1/fr
Application granted granted Critical
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Anticipated expiration legal-status Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents

Definitions

  • the present invention relates to a water-based basic cleaner, which as an active Contains substances solvents and non-ionic surfactants.
  • Basic cleaners are a special type of detergent that is one of a kind thorough cleaning of heavy soiling, e.g. in the industry, in the Kitchen and sanitary areas or for removing film layers on polymer and / or wax base is used.
  • the basic cleaners are usually in a dilution of 1: 1 to 1:10.
  • the basic cleaners also include the so-called universal basic cleaners, the have a pH value less than 10.5. They are due to their relatively low pH value also for use on more sensitive floor coverings, such as linoleum and rubber, suitable.
  • These universal basic cleaners are a mixture of solvents, Surfactants, builders, solubilizers and volatile alkalis, either amines or ammonia.
  • the builders are usually Phosphates, citrates, nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA) and carbonates are used.
  • NTA nitrilotriacetic acid
  • EDTA ethylenediaminetetraacetic acid
  • the known from the prior art Basic cleaners are available in a relatively large dilution because they are concentrated usually leads to separation of the solvents or salting out of the builders used fails. In U.S.
  • Patent 5,342,551 describes a composition for removing film layers on floors, which contains monoethanolamine citrate, coupling agent and solvent, the pH between 8.0 and 10 by adding a sufficient amount of monoethanolamine or other alkaline agent.
  • surfactants can the composition described e.g. Disodium isodecyl sulfosuccinate contain.
  • the detergent composition described is only suitable for removing film layers on floors, thorough cleaning the removal of heavy soiling does not lead to satisfactory results.
  • De DE-A-42 43 468 describes an aqueous cleaning agent which in undiluted state has a pH in the range between 5 and 9 and the 1 to 25 wt .-% of surfactant from the classes of nonionic and synthetic anionic surfactants and 0.1 to 12% by weight of alcohol from the Group benzyl alcohol, 2-phenoxyethanol, 2-phenylethanol and their mixtures contains.
  • the detergent is used undiluted for cleaning hard Surfaces, after dilution with water in a weight ratio of 1: 3 to 1: 500 for cleaning textile coverings or hard surfaces.
  • the usual universal basic cleaners usually have an active concentration of 20% by weight. These cleaners are, depending on the degree of contamination the surface to be cleaned, used in different dilutions. In the Development of new detergents is constantly striving to be means to develop, which have a higher performance and thus in lower Concentrations can be used.
  • the object of the present invention was to provide a basic cleaner to provide its cleaning performance both at removal of old film layers on floors as well as when cleaning strong ones Soiling that exceeds that of conventional basic cleaners.
  • the cleaning agent according to the invention a higher cleaning performance than that of conventional cleaners reached.
  • the as Component A) solvent mixture called a significant improvement the cleaning performance as by the individual solvent components also as can be obtained by adding these individual effects.
  • the basic cleaner contains a solvent mixture of a) phenoxy alcohol and b) a further alcohol selected from the group consisting of C 2 -C 4 alkyl glycols and ethers of C 1 -C 4 alcohols with (poly) glycols, in particular C 2 -C 4 glycols.
  • Components a) and b) can be present in a ratio of 1: 0.5 to 1:10, preferably 1: 0.5 to 1: 2 and particularly preferably 0.9: 1 to 1: 0.9.
  • Particularly preferred alcohols of group b) are n-butyl glycol, propylene glycol n-butyl ether, n-butyl diglycol and mixtures of the above.
  • the solvent components a) and b) can each be present in the inventive composition in amounts of 5 to 40% by weight, particularly preferably 5 to 30% by weight, based on the finished composition.
  • the basic cleaner contains at least one nonionic surfactant from the group of the C 12 -C 22 alcohol alkoxylates, the end-capped C 12 -C 22 alcohol alkoxylates and the alkyl polyglycosides as further constituents.
  • the C 12 -C 22 alcohol alkoxylates are nonionic surfactants of the formulas I or II R 1 O- (CH 2 CH 2 O) m -H wherein R 1 represents a saturated or unsaturated C 12 -C 22 alkyl group and m represents numbers from 1 to 20, wherein R 2 and o can have the same meaning as R 1 and m in formula I and n stands for numbers from 0.5 to 2.
  • C 12 -C 22 alcohols can be obtained by alkoxylation of C 12 -C 22 alcohols.
  • the ethoxylates and the mixed ethoxylates / propoxylates are used as alkoxylates.
  • Suitable C 12 -C 22 alcohols are, for example, the native fatty alcohols based on plants, such as, for example, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, behen alcohol, oleyl alcohol, elaidyl alcohol, ricinol alcohol, linoleyl alcohol, linolenyl alcohol and their naturally occurring mixtures, such as coconut oil palm oil or peanut fatty alcohol.
  • the end-capped C 12 -C 22 alcohol alkoxylates are prepared from the compounds of the formula I or II in a manner known per se by etherification of the terminal OH group with, for. B. a lower alcohol or alkyl halide.
  • a butyl group is preferably used as the terminal group.
  • alkyl glycosides are suitable as further nonionic surfactants.
  • Alkyl glycosides (APG) are known substances that can be obtained from alcohols and carbohydrates by the relevant methods of preparative organic chemistry, for example by condensation reactions or transetherification.
  • APG Alkyl glycosides
  • the alkyl glycosides follow the formula III, R 3 O [G] x in which R 3 is a linear or branched, saturated or unsaturated alkyl radical having 6 to 22 carbon atoms, [G] is a glycosidically bound sugar and x is a number from 1 to 10.
  • Alkyl glycosides are preferably used an average degree of oligomerization x of 1.1 to 3.0 is used. For application technology In view of such alkyl glycosides are preferred, their degree of oligomerization is less than 1.7 and is in particular between 1.2 and 1.6. As glycoses glucose and xylose are preferably used.
  • the alkyl or alkenyl radical R 3 can be derived from primary alcohols having 6 to 22, preferably 12 to 18, carbon atoms. Typical examples are capronic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as those obtained in the course of the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis.
  • the alkyl or alkenyl radical R 3 is preferably derived from lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol and mixtures thereof, such as coconut fatty alcohol.
  • lauryl alcohol myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol and mixtures thereof, such as coconut fatty alcohol.
  • Elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and their technical mixtures should also be mentioned.
  • the nonionic surfactants can be used in the agents according to the invention in quantities from 1 to 20% by weight, preferably in amounts of 1 to 10% by weight, in each case based on the finished product.
  • the basic cleaner according to the invention can contain soap as a further component.
  • Saturated fatty acid soaps, the salts in particular are particularly suitable as soap the alkali salts, lauric acid, myristic acid, palmitic acid or stearic acid, and in particular from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures.
  • the soaps can be used in quantities up to to 10 wt .-%, preferably 1 to 5 wt .-%, each based on the finished Cleaner to be included.
  • the agent according to the invention may further contain anionic surfactants as cleaning-active constituents.
  • Suitable anionic surfactants are, for example, C 8 -C 18 alkyl sulfates, C 8 -C 18 alkyl ether sulfates, C 8 -C 18 alkane sulfates, C 8 -C 18 ⁇ -olefin sulfonates, sulfonated C 8 -C 18 fatty acids C 1 - C 4 alkyl esters, C 6 -C 18 alkylbenzenesulfonates, sulfosuccinic acid mono- and di-C 8 -C 12 alkyl esters, C 8 -C 18 alkyl polyglycol ether carboxylates, C 8 -C 18 -N-acyl taurides, C 8 -C 18 -N-Sarcosinate and C 8 -C 18 alkyl isethionates.
  • the anionic surfactants can be present in
  • this broker e.g. Cumene sulfonate, octyl sulfate, toluenesulfonate or Urea.
  • Solubilizers can in the cleaner of the invention Amounts up to 10 wt .-%, in particular 1 to 5 wt .-%, each based on the finished cleaner. If soap is also contained in the cleaner, it can The amount of solvency mediators will usually be very small.
  • the detergent can contain alkalis, e.g. NaOH and KOH, ammonia and / or amines, e.g. Monoethanolamine, can be added.
  • alkalis e.g. NaOH and KOH
  • ammonia and / or amines e.g. Monoethanolamine
  • the pH is preferably between 8 and 10.
  • the basic cleaner can also contain color and other optional components Fragrances are added in amounts of up to 3% by weight, preferably 0.01 to 1.5 wt .-%, may be included. More common in such basic cleaners Auxiliaries can also be included, provided they have the effect according to the invention do not interfere.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Peptides Or Proteins (AREA)

Claims (9)

  1. Nettoyant pour sol liquide aqueux, qui renferme
    A) un mélange de solvants constitué de
       a) du phénoxyéthanol et de b) un alcool sélectionné dans le groupe formé par des alkylglycols en C2-C4 et des éthers d'alcools en C1-C4 avec des (poly)glycols, dans lequel a et b sont entre eux dans un rapport allant de 1:0,5 à 1:10 et
    B) des tensioactifs non ioniques appartenant au groupe des alcoxylates d'alcools en C12-C22, des alcoxylates d'alcools en C12-C22 fermés au niveau du groupe terminal et des alkylpolyglycosides.
  2. Nettoyant pour sol selon la revendication 1, caractérisé en ce que le phénoxyéthanol est présent dans une proportion de 5 à 40 % en poids, par rapport au nettoyant prêt à l'emploi.
  3. Nettoyant pour sol selon la revendication 1 ou 2, caractérisé en ce que le solvant b) est présent dans une proportion de 5 à 40 % en poids par rapport au nettoyant prêt à l'emploi.
  4. Nettoyant pour sol selon une des revendications 1 à 3, caractérisé en ce que le mélange de solvants est un mélange de a) un phénoxyéthanol et b) un alcool sélectionné dans le groupe formé par le propylèneglycol-n-butyléther, le n-butylglycol, le n-butyldiglycol et des mélanges des composés ci-avant dans un rapport de a:b allant de 0,9:1 à 1:0,9.
  5. Produit selon une des revendications 1 à 4, caractérisé en ce que l'on met en oeuvre des alcoxylates d'alcools en C12-C22 de formule I ou II R1O-(CH2CH2O)m-H dans laquelle R1 représente un groupe alkyle en C12-C22 saturé ou insaturé, et m correspond à un nombre de 1 à 20,
    Figure 00140001
    dans laquelle R2 et o possèdent la même signification que R1 et m dans la formule I, et n représente un nombre de 0,5 à 2.
  6. Produit selon une des revendications 1 à 5, caractérisé en ce que l'on met en oeuvre comme alkylglycosides des composés de formule III R3O[G]x dans laquelle R3 représente un radical alkyle à chaíne linéaire ou ramifiée, saturé ou insaturé, comportant 6 à 22 atomes de carbone, [G] correspond à un sucre à liaison glycosidique et x est un nombre de 1 à 10.
  7. Nettoyant pour sol selon une des revendications 1 à 6, caractérisé en ce que le produit renferme du savon dans une proportion de 1 à 10 % en poids, en particulier de 1 à 5 % en poids, dans chaque cas par rapport au nettoyant prêt à l'emploi.
  8. Nettoyant pour sol selon une des revendications 1 à 7, caractérisé en ce qu'il renferme un agent de solubilisation dans une proportion de 1 à 10 % en poids, en particulier de 1 à 5 % en poids, dans chaque cas par rapport au nettoyant prêt à l'emploi.
  9. Nettoyant pour sol selon une des revendications 1 à 8, caractérisé en ce qu'il renferme de l'ammoniac et/ou des amines très volatiles dans une proportion de 0,1 à 5 % en poids, en particulier de 0,1 à 2 % en poids, dans chaque cas par rapport au nettoyant prêt à l'emploi.
EP96107465A 1995-05-18 1996-05-10 Nettoyant aqueux pour sol hautement concentré Expired - Lifetime EP0743359B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19517814 1995-05-18
DE19517814A DE19517814A1 (de) 1995-05-18 1995-05-18 Hochkonzentrierter wasserhaltiger Grundreiniger

Publications (2)

Publication Number Publication Date
EP0743359A1 EP0743359A1 (fr) 1996-11-20
EP0743359B1 true EP0743359B1 (fr) 2000-10-11

Family

ID=7761962

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96107465A Expired - Lifetime EP0743359B1 (fr) 1995-05-18 1996-05-10 Nettoyant aqueux pour sol hautement concentré

Country Status (6)

Country Link
EP (1) EP0743359B1 (fr)
AT (1) ATE196922T1 (fr)
DE (2) DE19517814A1 (fr)
DK (1) DK0743359T3 (fr)
ES (1) ES2151619T3 (fr)
GR (1) GR3034676T3 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2949574B2 (ja) * 1997-01-09 1999-09-13 花王株式会社 樹脂汚れ用洗浄剤組成物
DE19750456A1 (de) * 1997-11-14 1999-05-27 Henkel Ecolab Gmbh & Co Ohg Mittel zum Reinigen von harten Oberflächen
DE10229421A1 (de) * 2002-06-29 2004-01-29 Ecolab Gmbh & Co. Ohg Bodenreinigungs- und/oder Pflegemittel
DE102007000501A1 (de) * 2007-10-15 2009-04-16 Chemetall Gmbh Reinigerzusammensetzung für metallische Oberflächen

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3829387A (en) * 1972-06-22 1974-08-13 American Home Prod Caustic cleaner composition
DE4005784C2 (de) * 1990-02-23 1994-12-08 Schuelke & Mayr Gmbh Desinfektionsmittel-Konzentrat und dessen Verwendung als Mykobakterizid und Viruzid
US5342551A (en) * 1992-11-04 1994-08-30 Cello Corporation Noncaustic floor finish remover
DE4243468A1 (de) * 1992-12-22 1994-06-23 Henkel Ecolab Gmbh & Co Ohg Neutrales flüssiges Reinigungsmittel (I)

Also Published As

Publication number Publication date
DE59605978D1 (de) 2000-11-16
ES2151619T3 (es) 2001-01-01
DE19517814A1 (de) 1996-11-21
GR3034676T3 (en) 2001-01-31
EP0743359A1 (fr) 1996-11-20
ATE196922T1 (de) 2000-10-15
DK0743359T3 (da) 2000-11-06

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