WO1997005223A1 - Melange tensioactif aqueux - Google Patents

Melange tensioactif aqueux Download PDF

Info

Publication number
WO1997005223A1
WO1997005223A1 PCT/EP1996/003210 EP9603210W WO9705223A1 WO 1997005223 A1 WO1997005223 A1 WO 1997005223A1 EP 9603210 W EP9603210 W EP 9603210W WO 9705223 A1 WO9705223 A1 WO 9705223A1
Authority
WO
WIPO (PCT)
Prior art keywords
alcohol
weight
alkyl
surfactant mixture
aqueous surfactant
Prior art date
Application number
PCT/EP1996/003210
Other languages
German (de)
English (en)
Inventor
Axel Böhmer
Udo Hees
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to EP96927564A priority Critical patent/EP0863972A1/fr
Publication of WO1997005223A1 publication Critical patent/WO1997005223A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the present invention relates to a surfactant mixture which contains nonionic surfactant, anionic surfactant and alcohols of medium chain length, and to the use of this surfactant mixture as an aqueous hand dishwashing detergent.
  • Liquid cleaning agents usually consist of aqueous solutions of synthetic anionic and / or nonionic surfactants and conventional additives. They are especially used for cleaning hard surfaces, e.g. of glass, ceramic materials, plastics, painted and polished surfaces.
  • An important area of application for liquid detergents is the manual washing of dishes and cookware.
  • the dishes are usually cleaned at slightly elevated temperatures of around 25 to 45 ° C in very dilute liquors.
  • the cleaning power of an agent is assessed by the consumer as the better, the stronger and the longer the cleaning liquor foams. Because of the contact of the hands with the cleaning liquor over a longer period of time, the skin-friendliness of the agent is of particular importance when washing dishes. For these reasons, the expert makes different considerations when selecting the components and the composition of an agent for the manual cleaning of dishes than with liquid detergents for other hard surfaces.
  • Hand dishwashing detergents usually contain a high proportion of anionic surfactants as an active ingredient.
  • the anionic surfactants are both the performers for the rinsing process and the components which make the greatest contribution to the formation of foam.
  • the anionic surfactants have a disadvantageous effect on human skin, which also degreases during the rinsing process and is attacked as a result becomes.
  • the anionic surfactants in dishwashing detergents are partially replaced by nonionic surfactants.
  • the use of non-ionic surfactants is often associated with poorer cleaning performance.
  • German patent application 21 63 195 discloses liquid surfactant concentrates for cleaning textiles and dishes based on anionic surface-active substances which are used to improve the solubility and storage stability of the concentra occur and C 8 -C 14 fatty alcohols are added to enhance the cleaning effect.
  • anionic surface-active substances which are used to improve the solubility and storage stability of the concentra occur and C 8 -C 14 fatty alcohols are added to enhance the cleaning effect.
  • the skin-friendliness of these agents is unsatisfactory because of the high content of anionic surfactants.
  • the present invention is based on the object of improving the cleaning performance of surfactant mixtures, in particular hand dishwashing detergents which contain anionic and nonionic surfactants.
  • the present invention relates to aqueous surfactant mixtures containing
  • Another object of the present invention is accordingly the use of the surfactant mixtures in aqueous hand dishwashing detergents.
  • Undecanol and dodecanol are preferred as component (A).
  • a cut with 12 to 14 C atoms obtained by distillation from fatty alcohols is particularly preferably used.
  • factors such as boiling point and Processability are taken into account.
  • the alcohols are preferably used in amounts of 0.1 to 6% by weight, based on the finished agent.
  • the C 8 -C 8 alcohol alkoxylates of component (B) are compounds of the formulas I or II:
  • R 1 represents a saturated or unsaturated, straight-chain or branched C 8 -C 8 -alkyl group and m represents numbers from 1 to 10,
  • R 2 and p can have the same meaning as R 1 and m in formula I and n stands for numbers from 0.5 to 2.
  • the compounds can be obtained by ethoxylation or ethoxylation and propoxylation of linear or branched C 8 -C 16 alcohols.
  • the ethoxylates and the mixed ethoxylates / propoxylates are used as alkoxylates.
  • Suitable C 8 -C 8 alcohols are, for example, the so-called fatty alcohols obtainable from naturally occurring fats, in particular from vegetable-based fats, such as octanol, decanol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, oleyl alcohol, elaidyl alcohol, Ricinoyl alcohol, linoleyl alcohol, linolenyl alcohol and their mixtures available from the naturally occurring fats, such as coconut oil alcohol, palm and palm kernel oil alcohol or peanut oil alcohol.
  • vegetable-based fats such as octanol, decanol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, oleyl alcohol, elaidyl alcohol, Ricinoyl alcohol, linoleyl alcohol, linolenyl alcohol and their mixtures available from the naturally occurring fats, such as coconut oil
  • C 8 -C 8 alcohols which are obtained, for example, in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis, or the so-called Ziegler alcohols.
  • C 1 -C 14 -fatty alcohol ethoxylates are particularly preferably used.
  • the proportion by weight of the alkoxylate unit is preferably between 30 and 90%, in particular between 35 and 75%.
  • the C 8 -C 22 alkyl sulfates of component (C) are also known anionic surfactants with the formula (V),
  • R 6 represents a saturated or unsaturated C ⁇ -Ca alkyl group and X represents an alkali or alkaline earth metal or a quaternary ammonium ion.
  • the C 8 -C 22 alkyl sulfates can be obtained by sulfating primary or branched C ⁇ -C ⁇ alcohols.
  • the primary C 8 -C-> 2-alkyl sulfates are preferably derived from the so-called fatty alcohols, such as, for example, caprylic alcohol, capric alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, arachyl alcohol, arachyl alcohol and erucyl alcohol and their technical mixtures.
  • Sulphates of technical C 1 - / 4 4 - or Ci-yi ⁇ coconut fatty alcohol cuts are preferably used in the form of their sodium or magnesium salts.
  • nonionic surfactants that can be used include, for example, alkylphenol polyglycol ethers, C ⁇ -C 22 alkyl polyglycosides, Ce-C ⁇ carboxylic acid polyglycol esters, C-rC-sr carboxylic acid amide polyglycol ethers, C6-C 22 amine polyglycol ethers, mixed ethers, alkoxylated triglycerides, C 6 -C 22 - Bonic acid-N-alkyl polyhydroxyalkylamides, polyol-C for rC- 22 carboxylic acid esters, sugar esters, sorbitan esters, polysorbates and any mixtures of the above are used.
  • non-ionic surfactants preferably C6-C22 alkyl polyglycosides, fatty acid N-alkyl polyhydroxyalkyl amides and fatty acid used.
  • C-rC 22 alkyl glycosides are known substances which can be obtained by the relevant methods of preparative organic chemistry.
  • the C ⁇ -Ca alkyl glycosides follow the formula III,
  • the alkyl or alkenyl radical R 3 is preferably derived from primary alcohols having 8 to 18, in particular 8 to 14, carbon atoms. Typical examples are caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained in the course of the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis.
  • the alkyl or alkenyl radical R 3 is preferably derived from lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol.
  • Elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoieyl alcohol, behenyl alcohol, erucyl alcohol and their technical mixtures are also to be mentioned.
  • the fatty acid N-alkyl polyhydroxyalkylamides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • a reducing sugar with ammonia, an alkylamine or an alkanolamine
  • subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride With regard to the processes for their production, reference is made to US Pat. Nos. 1,985,424, 2,016,962 and 2,703,798 and international patent application WO 92/06984. An overview of this topic by H. Kelkenberg can be found in Tens. Surf. Det. 25, 8 (1988).
  • the fatty acid N-alkylpolyhydroxyalkylamides are preferably derived from reducing sugars having 5 or 6 carbon atoms, in particular from glucose.
  • the preferred fatty acid N-alkylpolyhydroxyalkylamides are therefore fatty acid N-alkylglucamides as represented by the formula (IV):
  • the fatty acid N-alkylpolyhydroxyalkylamides used are preferably glucamides of the formula (IV) in which R s is hydrogen or an amino group and R 4 CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arachic acid, gadoleic acid, behenic acid or erucic acid or their technical mixtures.
  • R s is hydrogen or an amino group
  • R 4 CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid,
  • fatty acid N-alkyl glucamides of formula (IV) Particularly preferred are fatty acid N-alkyl glucamides of formula (IV), the amine by reductive amination of glucose with Methyl ⁇ and subsequent acylation with lauric acid or C 2/4 ⁇ coconut oil fatty acid or a corresponding derivative is obtained.
  • the polyhydroxyalkylamides can also be derived from maltose and palatinose.
  • Fatty acid alkanolamides can be used as further nonionic surfactants, e.g.
  • Cis alkanols but also the addition products of ethylene oxide with propylene glycols
  • the anionic surfactants can be present in the agent according to the invention in an amount of 1 to 50% by weight, preferably 10 to 35% by weight, based on the finished agent.
  • Suitable further anionic surfactants are e.g. B. C 8 -C 22 alkyl benzene sulfonates, alkanesulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates te, sulfo fatty acids, fatty alcohol ether sulfates, glycerin ether sulfates, hydroxy mixed ether sulfates, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, fatty acids, fatty acid salic acid sulfate sulfate, ether carbonsate sulfate , F
  • R 7 is a saturated or unsaturated C 8 -C 2 r alkyl group
  • n is a number from 0.5 to 5
  • Y is an alkali or alkaline earth metal or a quaternary ammonium ion.
  • Typical examples are the sulfation products of adducts of 0.5 to 10 mol of ethylene oxide (conventional or narrow homolog distribution) with 1 mol of caprylic alcohol, capric alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl , Arachyl alcohol, Gadoieyl alcohol, behenyl alcohol and erucyl alcohol and their technical mixtures.
  • Sulfates of adducts of 1 to 7 moles of ethylene oxide with saturated coconut oil alcohols in the form of their sodium, potassium and / or magnesium salts and ammonium salts, such as monoisopropanolammonium salts, are preferred.
  • fatty alcohol ether sulfates can be used which are derived from corresponding fatty alcohol polyglycol ethers which in turn are prepared in the presence of calcined or, in particular, hydrophobicized hydrotalcite have been and therefore have a particularly advantageous narrow homolog distribution.
  • Soaps i.e. Alkali or ammonium salts of saturated or unsaturated C6-C22 fatty acids are preferably not contained in the agents according to the invention because of their foam-suppressing properties.
  • Amphoteric and zwitterionic surfactants can also be used as further surfactants in the agent according to the invention.
  • Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • the amphoteric and zwitterionic surfactants can be present in an amount of up to 10% by weight, preferably 0.1 to 5% by weight, based on the finished agent.
  • Betaine compounds of the formula VI are preferably used as amphoteric surfactants
  • R 6 is an alkyl radical with 8 to 25, preferably 10 to 21 carbon atoms and R 7 and R 8 , which are optionally interrupted by heteroatoms or heteroatom groups, and R 7 and R 8 are identical or different alkyl radicals with 1 to 3 carbon atoms.
  • C 1 -C 8 -alkyldimethylcarboxymethylbetaine and C ⁇ rC ⁇ -alkylamidopropyldimethylcarboxymethylbetaine are preferred.
  • the total surfactant content in these compositions is preferably above 15% by weight, based on the total composition, an upper limit being 75% by weight, in particular 50% by weight.
  • the agents according to the invention can also contain solvents, perfumes, dyes and opacifiers, as well as skin protection components, as are known, for example, from EP-A1 522 756. Substances such as gelatin or casein can be used to adjust the viscosity of the compositions without impairing the performance of the compositions according to the invention. If products with improved cold behavior are desired, hydrotropes can also be added to the agent according to the invention.
  • the solvents to be added if necessary are low molecular weight alkanols with 1 to 4 carbon atoms in the molecule, preferably ethanol and isopropanol.
  • Optional further solubilizers, for example for dyes and perfume oils, can be alkanolamines, polyols such as ethylene glycol, propylene glycol, glycerol and alkylbenzenesulfonates with 1 to 3 carbon atoms in the alkyl radical.
  • the preferred thickeners include urea, sodium chloride and ammonium chloride, polysaccharides and the like, which can also be used in combination.
  • preservatives which can be mentioned are sodium benzoate, formaldehyde and sodium sulfite.
  • the agents according to the invention can also contain conventional disinfectants.
  • the pH of the agents according to the invention is preferably between 5.0 and 7.5.
  • Ci2 / 14 fatty alcohol ether (3EO) sulfate Na salt 20% by weight Ci2 / 14 fatty alcohol ether (3EO) sulfate Na salt 8% by weight C * i2 / 14 fatty alcohol sulfate Na salt

Abstract

L'invention concerne des mélanges tensioactifs au pouvoir de nettoyage amélioré et contenant: (A) 0,01 à 6 % en poids, par rapport au produit fini, d'alcool C11-C14; (B) 1,0 à 30 % en poids, par rapport au produit fini, d'alcoxylat d'alcool C8-C18; (C) 1,0 à 50 % en poids, par rapport au produit fini, C8-C20 de sulfate d'alcool; et (D) 14 à 97,99 % en poids d'eau. Ces substances se caractérisent par des performances élevées et une bonne tolérance cutanée.
PCT/EP1996/003210 1995-07-28 1996-07-20 Melange tensioactif aqueux WO1997005223A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP96927564A EP0863972A1 (fr) 1995-07-28 1996-07-20 Melange tensioactif aqueux

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19527596.9 1995-07-28
DE19527596A DE19527596A1 (de) 1995-07-28 1995-07-28 Wäßrige Tensidmischung

Publications (1)

Publication Number Publication Date
WO1997005223A1 true WO1997005223A1 (fr) 1997-02-13

Family

ID=7768008

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1996/003210 WO1997005223A1 (fr) 1995-07-28 1996-07-20 Melange tensioactif aqueux

Country Status (3)

Country Link
EP (1) EP0863972A1 (fr)
DE (1) DE19527596A1 (fr)
WO (1) WO1997005223A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008514771A (ja) * 2004-09-29 2008-05-08 ロディア・シミ 繊維または硬質表面のメンテナンス用発泡性洗剤組成物における脂肪族アルコールの使用
CN104487560A (zh) * 2012-07-26 2015-04-01 荷兰联合利华有限公司 液体洗涤剂组合物
WO2020236873A1 (fr) * 2019-05-20 2020-11-26 Ecolab Usa Inc. Ensemble tensioactif pour détergents hautement moussants ayant un faible niveau de milieu à des alcools à longues chaînes linéaires
US10947480B2 (en) 2016-05-17 2021-03-16 Conopeo, Inc. Liquid laundry detergent compositions

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19732073C1 (de) * 1997-07-25 1998-08-20 Henkel Kgaa Flüssiger stickstofffreier Textilweichmacher
WO1999010463A1 (fr) * 1997-08-25 1999-03-04 Cognis Deutschland Gmbh Detergents aqueux pour laver la vaisselle a la main
ATE376049T1 (de) * 2003-01-22 2007-11-15 Cognis Ip Man Gmbh Verwendung von lösevermittlern für wässrige waschmittelzusammensetzungen enthaltend duftstoffe

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2163195A1 (de) * 1971-12-20 1973-07-05 Henkel & Cie Gmbh Fluessige tensidkonzentrate
DE2608565A1 (de) * 1975-03-04 1976-09-09 Shell Int Research Fluessiges reinigungsmittel und seine verwendung in geschirrspuelmaschinen
DE2536107A1 (de) * 1975-08-13 1977-02-24 Hoechst Ag Geschirrspuelmittel
DE2641263A1 (de) * 1975-09-16 1977-03-17 Ciba Geigy Ag Detachiermittel und verfahren zum reinigen und gegebenenfalls faerben von textilmaterialien
DE4320119A1 (de) * 1993-06-18 1994-12-22 Henkel Kgaa Flüssigkristalline wäßrige Tensidzubereitung
US5476614A (en) * 1995-01-17 1995-12-19 Colgate Palmolive Co. High foaming nonionic surfactant based liquid detergent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2163195A1 (de) * 1971-12-20 1973-07-05 Henkel & Cie Gmbh Fluessige tensidkonzentrate
DE2608565A1 (de) * 1975-03-04 1976-09-09 Shell Int Research Fluessiges reinigungsmittel und seine verwendung in geschirrspuelmaschinen
DE2536107A1 (de) * 1975-08-13 1977-02-24 Hoechst Ag Geschirrspuelmittel
DE2641263A1 (de) * 1975-09-16 1977-03-17 Ciba Geigy Ag Detachiermittel und verfahren zum reinigen und gegebenenfalls faerben von textilmaterialien
DE4320119A1 (de) * 1993-06-18 1994-12-22 Henkel Kgaa Flüssigkristalline wäßrige Tensidzubereitung
US5476614A (en) * 1995-01-17 1995-12-19 Colgate Palmolive Co. High foaming nonionic surfactant based liquid detergent

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008514771A (ja) * 2004-09-29 2008-05-08 ロディア・シミ 繊維または硬質表面のメンテナンス用発泡性洗剤組成物における脂肪族アルコールの使用
CN104487560A (zh) * 2012-07-26 2015-04-01 荷兰联合利华有限公司 液体洗涤剂组合物
CN104487560B (zh) * 2012-07-26 2017-08-01 荷兰联合利华有限公司 液体洗涤剂组合物
US10947480B2 (en) 2016-05-17 2021-03-16 Conopeo, Inc. Liquid laundry detergent compositions
US11572529B2 (en) 2016-05-17 2023-02-07 Conopeo, Inc. Liquid laundry detergent compositions
WO2020236873A1 (fr) * 2019-05-20 2020-11-26 Ecolab Usa Inc. Ensemble tensioactif pour détergents hautement moussants ayant un faible niveau de milieu à des alcools à longues chaînes linéaires
US11261404B2 (en) 2019-05-20 2022-03-01 Ecolab Usa Inc. Surfactant package for high foaming detergents with low level of medium to long chain linear alcohols
JP2022533411A (ja) * 2019-05-20 2022-07-22 エコラボ ユーエスエー インコーポレイティド 低レベルの中鎖から長鎖の直鎖アルコールを有する高発泡洗剤用の界面活性剤パッケージ
AU2020277383B2 (en) * 2019-05-20 2023-03-09 Ecolab Usa Inc. Surfactant package for high foaming detergents with low level of medium to long chain linear alcohols

Also Published As

Publication number Publication date
EP0863972A1 (fr) 1998-09-16
DE19527596A1 (de) 1997-01-30

Similar Documents

Publication Publication Date Title
EP0712436B1 (fr) Produits de lavage ou de nettoyage faiblement moussants
DE19714369A1 (de) Mittel für die Reinigung harter Oberflächen
EP0664830B1 (fr) Melanges aqueux de detergents
EP0693114B1 (fr) Composition pour laver la vaisselle a la main
EP0666898B1 (fr) Utilisation de melanges de tensioactifs non ioniques
WO2001021752A1 (fr) Produit nettoyant aqueux a plusieurs phases
WO2000034425A1 (fr) Nettoyants universels
WO1997005223A1 (fr) Melange tensioactif aqueux
EP1129172A1 (fr) Agents mouillants pour le lavage en machine de la vaisselle
EP0796314A1 (fr) Tensio-actifs non ioniques speciaux pour liquides a vaisselle utilises pour faire la vaisselle a la main
EP0788537B1 (fr) Detergent aqueux pour lavage manuel de la vaisselle
DE19534269A1 (de) Wäßrige Tensidzusammensetzungen
DE19535260A1 (de) Wäßrige Tensidzusammensetzung
DE19519405A1 (de) Wäßrige Reinigungsmittelzusammensetzung
EP0763591A1 (fr) Produit pour laver la vaiselle à la main
DE19641277C2 (de) Syndetseifen
EP0918085B1 (fr) Combinaisons de détergents doux pour la peau contenant un sulfate C8-C22 de l'éther amide d'acide carboxylique
WO1999010458A1 (fr) Agents aqueux pour nettoyer des surfaces dures
DE19806496C2 (de) Syndetseifen
DE4407687A1 (de) Wäßrige Handgeschirrspülmittel
DE19526033A1 (de) Wäßrige Handgeschirrspülmittel
WO1999049007A1 (fr) Produit vaisselle comprenant des sulfates d'ester d'oligoalkylenglycol d'acide gras
DE19813042A1 (de) Handgeschirrspülmittel mit Fettsäureoligoalkylenglykolestersulfaten
DE10237030A1 (de) Alkylaminobetaine auf Basis konjugierter Linolsäure
DE4438221A1 (de) Monoglyceridsulfate als Schaumstabilisatoren

Legal Events

Date Code Title Description
AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1996927564

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1996927564

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: 1996927564

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1996927564

Country of ref document: EP