EP0736610B1 - Acier inoxydable austénitique resulfuré à usinabilité améliorée, utilisé notamment dans le domaine de l'usinage à très grande vitesse de coupe et le domaine du décolletage - Google Patents
Acier inoxydable austénitique resulfuré à usinabilité améliorée, utilisé notamment dans le domaine de l'usinage à très grande vitesse de coupe et le domaine du décolletage Download PDFInfo
- Publication number
- EP0736610B1 EP0736610B1 EP96400532A EP96400532A EP0736610B1 EP 0736610 B1 EP0736610 B1 EP 0736610B1 EP 96400532 A EP96400532 A EP 96400532A EP 96400532 A EP96400532 A EP 96400532A EP 0736610 B1 EP0736610 B1 EP 0736610B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel
- resulfurized
- calcium
- austenitic stainless
- field
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000963 austenitic stainless steel Inorganic materials 0.000 title claims abstract description 7
- 238000005520 cutting process Methods 0.000 title description 20
- 229910000831 Steel Inorganic materials 0.000 claims description 50
- 239000010959 steel Substances 0.000 claims description 50
- 238000003754 machining Methods 0.000 claims description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 17
- 239000011575 calcium Substances 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 16
- 229910052802 copper Inorganic materials 0.000 claims description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 15
- 229910052791 calcium Inorganic materials 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 239000011572 manganese Substances 0.000 claims description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 2
- 229910052711 selenium Inorganic materials 0.000 claims description 2
- 239000011669 selenium Substances 0.000 claims description 2
- 229910052714 tellurium Inorganic materials 0.000 claims description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 239000005864 Sulphur Substances 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- -1 from 7 to 12% Chemical compound 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- DBULDCSVZCUQIR-UHFFFAOYSA-N chromium(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Cr+3].[Cr+3] DBULDCSVZCUQIR-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VCTOKJRTAUILIH-UHFFFAOYSA-N manganese(2+);sulfide Chemical class [S-2].[Mn+2] VCTOKJRTAUILIH-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
Definitions
- the present invention relates to an austenitic stainless steel resulfurized with improved machinability, used in particular in the field machining at very high cutting speed and the field of bar turning.
- the speeds which can be used on a steel are, for example, determined by turning tests with tools comprising coated carbide inserts, tests designated Vb 15 / 0.15 , which consist in determining the speed at which the wear in clearance is 0.15 mm after 15 minutes of machining. Beyond this speed, it is not conceivable to machine without risk, below industrial practice is possible.
- the aim sought is training, with the manganese and in a lower proportion, with chromium, of a manganese and chromium sulfide (Mn, Cr) S which generates under the form of specific inclusions solid lubrication of the tool cutting during machining operations.
- Mn, Cr manganese and chromium sulfide
- sulfur has an unfavorable effect on corrosion resistance and that, despite this, an orientation chosen is the introduction, in a resulfurized steel, of inclusions of lime silicoaluminate oxides most often associated with sulfide inclusions.
- Such an austenitic steel has good machinability properties in the field of conventional cutting speeds, i.e. less than 500 m / min while shooting.
- Steel has inclusions associated composed of oxides of the silicoaluminate type which coat preferably sulfide inclusions. These inclusions are more large and more deformable than the sulphide inclusions alone. The effect of the so-called solid lubrication of the cutting tool is thereby improved.
- the steel described in the cited document has a disadvantage. Indeed, sulfur significantly reduces the properties of steel from the point of view of cold deformation with appearance of tapures for example in stretching or drawing.
- the object of the invention is to propose a steel with machinability improved which can be used, on the one hand in the field of very high speed machining, with cutting speeds in turning which can exceed 700 m / min, and, on the other hand in the bar turning area with productivity greater than 30% at those obtained with a resulfurized austenitic stainless steel ordinary.
- the subject of the invention is an austenitic stainless steel resulfurized with improved machinability usable in particular in the field high-speed cutting machining and bar turning, such as as defined in claim 1.
- Figure 1 shows the wear curves in steel clearance resulfurized stainless steels, either copper-free or without inclusion aluminosilicate of lime and of a resulfurized steel according to the invention, these steels being machined at very high cutting speed.
- Figure 2 presents the hardening curves of a steel resulfurized without copper and a steel according to the invention.
- the austenitic stainless steel according to the invention has the following composition by weight: carbon less than 0.1%, silicon less than 2%, manganese less than 2%, nickel, from 7 to 12%, chromium, from 15 to 25% , sulfur, 0.10 to 0.55%, copper, 1 to 5%, calcium greater than 35.10 -4 %, oxygen greater than 70.10 -4 %, the ratio of calcium content to oxygen content being between 0.2 and 0.6.
- This steel is in the field of so-called resulfurized steels whose content in sulfur and the calcium and oxygen contents in a ratio determined ensure said steels good machinability at speeds cutting less than 500 m / min.
- manganese sulfides are very little substituted for chromium because a manganese content adapted to the sulfur content, their malleability and therefore their effectiveness when cutting improved. Sulfur can be partially replaced by selenium and / or tellurium.
- the resulfurized steel according to the invention which can preferably be used in the field of machining known as high cutting speeds, by the presence of a large number of malleable inclusions at low point fusion of sulfide and associated or unassociated oxide, and by the presence of a copper content according to the invention, ensures on the one hand, machining at exceptional cutting speeds and secondly, conservation of the life of the cutting tool.
- the test consists of a turning operation, without lubrication, with an advance of 0.25 mm / revolution, a depth of 1.5 mm pass and a cutting speed of 700 m / min.
- the tool is regularly dismantled for measurement of draft wear.
- the resulting curves are shown in Figure 1.
- Reference steels A and B are unsuitable for this type of machining. After only a few minutes of turning, the tools machining these steels are destroyed, that is to say that either their wear and tear is greater than 0.15 mm, or their edge is collapsed. It is therefore not thinkable of using, for the machining of these steels, such speeds of chopped off.
- steel C according to the invention the coated tool is still in working condition after 20 minutes of turning, which allows, with conventional carbide coated tools to work industrially at such cutting speeds. This is due to the combined presence, in the composition of steel, of a large quantity of sulfur, malleable oxides with low melting point and a optimal copper content.
- the reference D steel is a resulfurized steel which does not contain calcium or oxygen in its composition. in suitable proportion, and the steel E, according to the invention, in this exemplary embodiment, comprises in its composition, 1.5% copper, 62.10 -4 % calcium and 134.10 -4 % oxygen.
- the test consists in the production, from a drawn bar with a diameter of 5 mm, of a piece 50 mm long comprising essentially turning, with variable depth of pass from 0.5 to 1.5 mm.
- Table 2 presents the results of a bar turning test on a single spindle cam lathe with solid carbide tools and whole oil lubrication. The values in table 2 represent the number of parts with good quality machining before changing the tools.
- Productivity Steel D Steel E 1.82 pieces / min 3,200 8,000 2.30 piece / min 1,500 3,200
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Heat Treatment Of Steel (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Lubricants (AREA)
- Gas Burners (AREA)
- Heat Treatment Of Articles (AREA)
- Turning (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9504140 | 1995-04-07 | ||
FR9504140A FR2732694B1 (fr) | 1995-04-07 | 1995-04-07 | Acier inoxydable austenitique resulfure a usinabilite amelioree, utilise notamment dans le domaine de l'usinage a tres grande vitesse de coupe et le domaine du decolletage |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0736610A1 EP0736610A1 (fr) | 1996-10-09 |
EP0736610B1 true EP0736610B1 (fr) | 2001-02-21 |
Family
ID=9477855
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96400532A Expired - Lifetime EP0736610B1 (fr) | 1995-04-07 | 1996-03-15 | Acier inoxydable austénitique resulfuré à usinabilité améliorée, utilisé notamment dans le domaine de l'usinage à très grande vitesse de coupe et le domaine du décolletage |
Country Status (22)
Country | Link |
---|---|
US (1) | US5656237A (no) |
EP (1) | EP0736610B1 (no) |
JP (1) | JP3687931B2 (no) |
KR (1) | KR100389601B1 (no) |
AT (1) | ATE199267T1 (no) |
CA (1) | CA2173573C (no) |
CZ (1) | CZ292424B6 (no) |
DE (1) | DE69611801T2 (no) |
DK (1) | DK0736610T3 (no) |
ES (1) | ES2154795T3 (no) |
FR (1) | FR2732694B1 (no) |
GR (1) | GR3035595T3 (no) |
IL (1) | IL117765A (no) |
NO (1) | NO312682B1 (no) |
PL (1) | PL184056B1 (no) |
PT (1) | PT736610E (no) |
RO (1) | RO115971B1 (no) |
RU (1) | RU2106426C1 (no) |
SI (1) | SI9600115B (no) |
TR (1) | TR199600293A2 (no) |
TW (1) | TW367373B (no) |
UA (1) | UA39895C2 (no) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000065120A1 (en) * | 1999-04-26 | 2000-11-02 | Crs Holdings, Inc. | Free-machining austenitic stainless steel |
FR2805829B1 (fr) * | 2000-03-03 | 2002-07-19 | Ugine Savoie Imphy | Acier inoxydable austenitique a haute usinabilite, resulfure, et comportant une resistance a la corrosion amelioree |
CA2784760C (en) | 2010-06-09 | 2015-02-03 | Sumitomo Metal Industries, Ltd. | Austenitic stainless steel pipe excellent in steam oxidation resistance and manufacturing method therefor |
JP5818541B2 (ja) * | 2011-07-01 | 2015-11-18 | 新日鐵住金ステンレス株式会社 | オーステナイト系s含有快削ステンレス鋼 |
UA111115C2 (uk) | 2012-04-02 | 2016-03-25 | Ейкей Стіл Пропертіс, Інк. | Рентабельна феритна нержавіюча сталь |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE346813B (no) * | 1970-11-12 | 1972-07-17 | Sandvikens Jernverks Ab | |
US4784828A (en) * | 1986-08-21 | 1988-11-15 | Crucible Materials Corporation | Low carbon plus nitrogen, free-machining austenitic stainless steel |
JPH01319652A (ja) * | 1988-06-20 | 1989-12-25 | Nippon Koshuha Kogyo Kk | 熱間加工性の良好な快削ステンレス鋼 |
FR2648477B1 (fr) * | 1989-06-16 | 1993-04-30 | Ugine Savoie Sa | Acier inoxydable austenitique resulfure a usinabilite amelioree |
JPH0441651A (ja) * | 1990-06-05 | 1992-02-12 | Daido Steel Co Ltd | 被削性の優れた耐食オーステナイト系ステンレス鋼 |
FR2690169B1 (fr) * | 1992-04-17 | 1994-09-23 | Ugine Savoie Sa | Acier inoxydable austénitique à haute usinabilité et à déformation à froid améliorée. |
JPH05339680A (ja) * | 1992-06-08 | 1993-12-21 | Daido Steel Co Ltd | 耐食性を高めた快削オーステナイトステンレス鋼とその製造方法 |
-
1995
- 1995-04-07 FR FR9504140A patent/FR2732694B1/fr not_active Expired - Fee Related
-
1996
- 1996-03-15 ES ES96400532T patent/ES2154795T3/es not_active Expired - Lifetime
- 1996-03-15 DK DK96400532T patent/DK0736610T3/da active
- 1996-03-15 DE DE69611801T patent/DE69611801T2/de not_active Expired - Lifetime
- 1996-03-15 AT AT96400532T patent/ATE199267T1/de active
- 1996-03-15 PT PT96400532T patent/PT736610E/pt unknown
- 1996-03-15 EP EP96400532A patent/EP0736610B1/fr not_active Expired - Lifetime
- 1996-03-25 TW TW085103533A patent/TW367373B/zh not_active IP Right Cessation
- 1996-04-01 IL IL11776596A patent/IL117765A/en not_active IP Right Cessation
- 1996-04-02 NO NO19961353A patent/NO312682B1/no not_active IP Right Cessation
- 1996-04-04 CA CA002173573A patent/CA2173573C/fr not_active Expired - Lifetime
- 1996-04-04 CZ CZ19961000A patent/CZ292424B6/cs not_active IP Right Cessation
- 1996-04-05 TR TR96/00293A patent/TR199600293A2/xx unknown
- 1996-04-05 SI SI9600115A patent/SI9600115B/sl unknown
- 1996-04-05 UA UA96041352A patent/UA39895C2/uk unknown
- 1996-04-05 RO RO96-00736A patent/RO115971B1/ro unknown
- 1996-04-05 RU RU96106422/02A patent/RU2106426C1/ru active
- 1996-04-05 PL PL96313658A patent/PL184056B1/pl unknown
- 1996-04-06 KR KR1019960010364A patent/KR100389601B1/ko not_active IP Right Cessation
- 1996-04-08 JP JP11126396A patent/JP3687931B2/ja not_active Expired - Lifetime
- 1996-04-08 US US08/629,228 patent/US5656237A/en not_active Expired - Lifetime
-
2001
- 2001-03-16 GR GR20010400440T patent/GR3035595T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
PL313658A1 (en) | 1996-10-14 |
RU2106426C1 (ru) | 1998-03-10 |
DE69611801D1 (de) | 2001-03-29 |
JPH09137254A (ja) | 1997-05-27 |
ATE199267T1 (de) | 2001-03-15 |
CZ100096A3 (en) | 1996-10-16 |
DE69611801T2 (de) | 2001-09-06 |
RO115971B1 (ro) | 2000-08-30 |
CA2173573A1 (fr) | 1996-10-08 |
TR199600293A2 (tr) | 1996-10-21 |
PL184056B1 (pl) | 2002-08-30 |
US5656237A (en) | 1997-08-12 |
SI9600115B (en) | 2001-12-31 |
KR960037854A (ko) | 1996-11-19 |
KR100389601B1 (ko) | 2003-10-22 |
EP0736610A1 (fr) | 1996-10-09 |
TW367373B (en) | 1999-08-21 |
NO312682B1 (no) | 2002-06-17 |
NO961353D0 (no) | 1996-04-02 |
JP3687931B2 (ja) | 2005-08-24 |
ES2154795T3 (es) | 2001-04-16 |
NO961353L (no) | 1996-10-08 |
FR2732694B1 (fr) | 1997-04-30 |
UA39895C2 (uk) | 2001-07-16 |
SI9600115A (en) | 1996-10-31 |
IL117765A0 (en) | 1996-08-04 |
IL117765A (en) | 1998-12-06 |
PT736610E (pt) | 2001-07-31 |
GR3035595T3 (en) | 2001-06-29 |
CA2173573C (fr) | 1999-12-28 |
FR2732694A1 (fr) | 1996-10-11 |
CZ292424B6 (cs) | 2003-09-17 |
DK0736610T3 (da) | 2001-06-18 |
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