EP0719459A1 - Tuile/element de couverture solaire - Google Patents

Tuile/element de couverture solaire

Info

Publication number
EP0719459A1
EP0719459A1 EP94927556A EP94927556A EP0719459A1 EP 0719459 A1 EP0719459 A1 EP 0719459A1 EP 94927556 A EP94927556 A EP 94927556A EP 94927556 A EP94927556 A EP 94927556A EP 0719459 A1 EP0719459 A1 EP 0719459A1
Authority
EP
European Patent Office
Prior art keywords
roof tile
wall plate
plate according
solar
roof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94927556A
Other languages
German (de)
English (en)
Inventor
Bernd Melchior
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BLUESUN TECHNOLOGIE GMBH
Original Assignee
Blue Planet AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4331425A external-priority patent/DE4331425A1/de
Priority claimed from DE4411458A external-priority patent/DE4411458C2/de
Application filed by Blue Planet AG filed Critical Blue Planet AG
Publication of EP0719459A1 publication Critical patent/EP0719459A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00Supporting structures for PV modules
    • H02S20/20Supporting structures directly fixed to an immovable object
    • H02S20/22Supporting structures directly fixed to an immovable object specially adapted for buildings
    • H02S20/23Supporting structures directly fixed to an immovable object specially adapted for buildings specially adapted for roof structures
    • H02S20/25Roof tile elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S20/00Solar heat collectors specially adapted for particular uses or environments
    • F24S20/60Solar heat collectors integrated in fixed constructions, e.g. in buildings
    • F24S20/69Solar heat collectors integrated in fixed constructions, e.g. in buildings in the form of shingles or tiles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/049Protective back sheets
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00Supporting structures for PV modules
    • H02S20/20Supporting structures directly fixed to an immovable object
    • H02S20/22Supporting structures directly fixed to an immovable object specially adapted for buildings
    • H02S20/23Supporting structures directly fixed to an immovable object specially adapted for buildings specially adapted for roof structures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S25/00Arrangement of stationary mountings or supports for solar heat collector modules
    • F24S25/60Fixation means, e.g. fasteners, specially adapted for supporting solar heat collector modules
    • F24S2025/6004Fixation means, e.g. fasteners, specially adapted for supporting solar heat collector modules by clipping, e.g. by using snap connectors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/20Solar thermal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • Y02E10/44Heat exchange systems
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S136/00Batteries: thermoelectric and photoelectric
    • Y10S136/291Applications

Definitions

  • the invention relates to a roof tile / Dachstein / a wall plate made of a plate made of clay, ceramic, concrete, fiber cement or plastic as a carrier of a solar panel attached to the top with photovoltaic solar cells, the solar panel with at least two opposite sides on the top of the roof tile / Dachstein / wall plate is positively attached to the inner edges of a roof tile / Dachstein / wall plate recess.
  • the object of the invention is to improve a roof tile / roof tile / wall panel with a solar panel so that even with large manufacturing tolerances of the roof tile / roof tile, the solar panel always finds a secure and precise hold without damaging the solar cells during installation.
  • the laterally protruding, elastic projections of the solar panel can adapt to the most varied dimensions on the roof tile / roof tile / wall panel, so that there is always a secure and firm hold.
  • the solar panels fit into the roof tile / roof tile / wall panel even if the internal dimensions of the roof tile / roof tile / wall panel are considerably smaller than intended.
  • the recesses have a length that is a fraction of the total length of the inner edge.
  • the recesses can also be groove sections, elongated holes, pockets and / or bores.
  • the projections should also be carried or formed by a frame, in particular molded onto a frame that surrounds the solar cell (s).
  • the projections are arranged very deep on the solar panel, so that they find a relatively low hold on the roof tile and thus the module itself sits high in the roof structure, so that the top of the solar panel can align with the top of the roof tile and thus dirt does not form in the edges and can make protrusions.
  • a secure seal is achieved if a tongue-length profile protrudes laterally on the upper edge of the frame, which lies tightly against the roof tile / roof tile / wall panel.
  • micro-containers can contain a part of a first component and a part of a second component of a two-component adhesive.
  • a particularly good connection and optimum hold of the photovoltaic element in the frame of the solar panel is achieved if a non-metallic, elastic material, in particular silicone, is introduced between the photovoltaic element and the frame, which forms a watertight connection after it has hardened.
  • the silicone forms a chemical connection to the glass of the photovoltaic element as well as to the plastic, in particular silicone of the frame. This leads to the creation of an insoluble hold, which protects the solar cells from the penetration of corrosive atmospheres.
  • the frame forms a smooth plane with the glass pane.
  • a particularly simple and safe cabling is achieved if a cable holder protrudes downward on the underside of the solar plate, which is attached to the solar plate, in particular integrally formed thereon.
  • the roof element photovoltaic system according to the invention brings a number of significant advantages.
  • the roofs can initially be covered conventionally. Subsequently, the solar panels can be pressed into the roof tiles and fixed in a non-slip manner, the energy supply can be built up gradually without the roof having to be covered or changed.
  • a profile is fastened to at least one, in particular to both of the two opposite sides of the solar panel, which has at least one downward-pointing elastic leg, the end of which forms the projection or projections which snap into at least one recess of the Insert roof tile / roof tile / wall plate recess. This ensures that the solar panel is held securely over a long period of time.
  • the profile is made of stainless steel or aluminum.
  • Figure 1 A section through the roof tile.
  • Figure 2 A top view and side view of the roof tile / roof tile / wall plate.
  • Figure 3 A section through the side edge of the solar panel in the area of a long side.
  • Figure 4 A section through the side edge of the solar panel in the area of a narrow side with molded cable holder.
  • Figure 5 A section through the side edge of the solar panel in the area of a narrow side with molded cable holder.
  • Figure 7 A section through an embodiment in which the carrier plate of the solar plate forms the lateral elastic projections.
  • Figure 8 A section through the roof tile / roof tile / wall plate in a third embodiment with holding profiles made of metal.
  • Figure 9 A section through the roof tile / roof tile / wall plate in a fourth embodiment with holding profiles made of metal.
  • Figure 10 The underside of the third or fourth version with stiffening ribs.
  • Figure 11 The top of the third or fourth
  • Wall plate with resilient holding profiles or brackets
  • Figure 13 A section through the fastening area with spring pin elements
  • Figure l a section through the mounting area with inserted adapter sleeves.
  • a roof tile / roof tile / wall plate hereinafter only called roof tile 1, consists of clay, ceramic, concrete or plastic and has an upwardly open recess 2, so that the roof tile 1 has a U-shaped cross section of great width, whose free legs are angled outwards to create the traditional, interlocking, interlocking overlaps.
  • the projections 5 are formed on both longitudinal sides, which consist of a soft material, in particular a soft plastic (silicone).
  • the frame 8 can be made of the same material.
  • the projections 5 do not extend over the entire length of the side edge of the frame 8, but each side of the frame has two or more individual projections 5, which are in correspondingly shaped individual recesses in the Insert the inner edges or inner side walls in a form-fitting manner.
  • the recesses 4 have a length that is only a fraction of the total length of the inner edge 3.
  • the recesses can be 4 groove sections, slots, pockets and / or bores.
  • the projections 5 extend at the lower edge laterally outwards obliquely downward at an angle of approximately 45 degrees, so that the frame 8 can lie so high in the roof tile 1 that there is no depression or only a depression of lesser height above the solar plate 6 . With this arrangement, the shading of the roof tile edge on the solar panel is negligible, so that the direct incidence of light on the solar cells is guaranteed even when the sun is at an angle.
  • the special arrangement of the projections 5 below the solar panel 6 creates the spring-clamping effect for fixing the solar panel 6 to the roof tile.
  • a tongue-shaped longitudinal profile 9 is formed that protrudes laterally approximately horizontally and rests sealingly on the inner edge 3 above.
  • a plurality of micro-containers containing an adhesive can be attached to the surface of the projection 5.
  • the microcontainers can contain a first component and a second component a second component of a two-component adhesive, so that after pressing the projection 5 into the recess 4, the microcontainers burst, the contents of which mix and form a fast-setting adhesive.
  • a non-metallic elastic material in particular a plastic (silicone) 10, which forms a water-tight connection between these parts at its edges after it has hardened and thereby also forms chemical connections with these edges .
  • a particularly good adhesion of the frame 8 to the solar plate 6 is achieved in that the upper edges 14 of the glass pane 13 facing the light 13 of the solar plate 6 are chamfered so that the chemically reactive plastic (silicone) 10 grips over the glass pane and thus a firmer connection of the frame 8 with the solar panel 6 is achieved.
  • This frame arrangement 8-10 ensures that rainwater can flow off smoothly and no dirt-forming particles are deposited in the edge area. This is a major advantage over all known frames of solar panels.
  • a cable holder 11 is formed on the frame 8 and protrudes downward, with a cable holder being located on the solar plate 6 both on the lower narrow side and on the upper narrow side.
  • the exemplary embodiment according to FIGS. 5 and 6 differs from that according to FIGS. 1 to 4 in that the projections 5 have a spherical outer shape, the main axis (longitudinal axis) of which is horizontal. These projections are particularly flexible if they are made of a very soft material such as foam rubber and / or they are hollow on the inside (hollow body, hollow profile), as shown in FIGS. 5 and 6 on the left side.
  • the carrier plate 6a of the solar plate can consist of a flexible material, on which hook-shaped parts 5 or projections or tongues protrude on both sides in order to springily engage in the recesses 4 of the roof tile / roof tile or the wall plate.
  • the resilient hooks By pushing in the polymer PV module, the resilient hooks are bent inwards over the adaptation geometry and then snap into the corresponding recesses in the roof elements.
  • the spring travel of the snap connection is determined via the arm length, in particular through a curved spring region (18a) (FIG. 12), and the curvature of the polymer PV module is generated via the bending points.
  • the ribbing forces keep the bending forces away from the solar cells.
  • the prestress in the roof element is generated by the slight oversize of the carrier plate in the roof element.
  • the PV module Due to the geometry of the snap connection in combination with the weakly bent parts, the PV module is always slightly curved upwards in the case of slightly larger sizes.
  • Solar cells are fixed on a glass fiber and / or glass ball reinforced carrier plate (6a) made of ceramic, concrete or glass. Notches 20 are worked into the carrier plate 6a between the solar cells, so that the carrier plate can be bent at these weaker points 20 without the bending forces damaging the solar cells. Bending of the solar cells is also prevented by the fact that under the solar cells there are torsion-resistant ribs 21 are located.
  • the carrier plate between the solar cells is so thin-walled that it can be bent (arching inwards).
  • profiles 17 are fastened, which have at least one downward-pointing elastic leg 18, the end of which forms the projection or projections 19, which snap into at least one recess of the
  • the profile 17 has in its upper region a recess, in particular a longitudinal groove (longitudinal channel) 16, in which the side edge of the solar panel lies in a particularly positive manner.
  • the profile 17 is made of metal, in particular stainless steel or aluminum.
  • the tongues 5 are designed so that they can bulge while the module is being pushed in.
  • the slight tension of the carrier plate combined with a slight curvature, compensates for the tolerances of the roof tiles. Through a slight twisting of the carrier plate can compensate for torsion tolerances under the adaptation grooves.
  • the blue tempered V ⁇ A spring element 17, 18, 19 snaps into the adaptation geometry of the roof tile / roof tile. The spring element is pushed into recesses in the carrier plate and firmly fixed in the subsequent lambing process.
  • spring pin elements 22 can also be fastened to the solar plate, which are loaded by a helical compression spring 23 and whose front, tapering end 24 snaps into the correspondingly shaped recess 25 of the roof tile / roof tile / wall plate.
  • the recess 25 can be formed by a bearing part (26) in particular in the form of a socket made of metal or plastic, which is cast, pressed or glued into the material of the roof tile / roof tile / wall plate. This provides a particularly secure hold that is independent of the material of the roof tile / roof tile / wall plate.
  • Clay roof tiles are fired and have tolerances in all axes due to production. These are compensated for by the design-related design of the carrier plate.
  • the carrier plate with the solar cells is hermetically sealed in fluoropolymer. Chemical adhesion promoters and holes in the carrier plate create an insoluble bond chemically and mechanically between the carrier material and the solar cells.
  • the outer sheath of the power cable is made of the same polymer as the polymer enclosing the module. This ensures that a mechanical, tear-resistant and weather-resistant, corrosion-resistant electrical connection is created.
  • the following features are particularly advantageous for roof tiles / roof tiles or wall panels:
  • the surrounding plastic of the solar panel 6 is a fluoropolymer.
  • the polymer plastic is chemically bonded to the solar cells and the carrier material via an adhesion promoter.
  • the polymer plastic can be mechanically connected to the carrier material via through holes, depressions, bores.
  • the tongues on the carrier plate snap into the adaptation geometries of the roof elements in such a way that a slight tension curvature adapts the PV module to the roof tile in such a way that manufacturing tolerances of the roof element in longitudinal, transverse and torsional planes are compensated for.
  • the adaptation geometry of the carrier plate is thus a resilient construction (snap connection).
  • the electrical wiring consists of three components: a cable, a first jacket made of a high temperature-resistant polymer and a second jacket made of the same polymer as the encapsulating polymer.
  • the electrical cable is hermetically sealed and mechanically sealed into the PV module.
  • the electrical cable can be fixed to a U-shaped guide channel.
  • the solar cells are wired on the back of the carrier plate, in particular using printed circuit board technology.

Landscapes

  • Engineering & Computer Science (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Architecture (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • General Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Roof Covering Using Slabs Or Stiff Sheets (AREA)
  • Photovoltaic Devices (AREA)
  • Finishing Walls (AREA)

Abstract

L'invention concerne une tuile/un élément de couverture/un panneau mural (1) en argile, en céramique, en béton, en fibrociment ou en plastique servant de support à un panneau solaire (6) pourvu de cellules photovoltaïques (7), fixé sur la face supérieure. Le panneau solaire (6) est fixé par liaison de forme au moins sur deux côtés opposés situés sur la face supérieure de la tuile/de l'élément de couverture/du panneau mural, sur les bords intérieurs (3) du creux (2) pratiqué dans une tuile/un élément de couverture/un panneau mural. En raison de leur propre élasticité, les parties saillantes (5) sont maintenues par liaison de forme de manière encliquetée dans des cavités (4) du creux (2) de la tuile/de l'élément de couverture/du panneau mural.
EP94927556A 1993-09-16 1994-09-03 Tuile/element de couverture solaire Withdrawn EP0719459A1 (fr)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
DE4331425 1993-09-16
DE4331425A DE4331425A1 (de) 1993-09-16 1993-09-16 Solarmodul mit Lochplatte
DE4331424 1993-09-16
DE4331424 1993-09-16
DE4411458 1994-04-01
DE4411458A DE4411458C2 (de) 1993-09-16 1994-04-01 Dachpfanne
PCT/EP1994/002943 WO1995008194A1 (fr) 1993-09-16 1994-09-03 Tuile/element de couverture solaire

Publications (1)

Publication Number Publication Date
EP0719459A1 true EP0719459A1 (fr) 1996-07-03

Family

ID=27205565

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94927556A Withdrawn EP0719459A1 (fr) 1993-09-16 1994-09-03 Tuile/element de couverture solaire

Country Status (4)

Country Link
US (1) US5768831A (fr)
EP (1) EP0719459A1 (fr)
AU (1) AU7694094A (fr)
WO (1) WO1995008194A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110258973A (zh) * 2019-06-11 2019-09-20 河源市源日通能源有限公司 一种高硼硅光热玻璃光伏瓦片

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US5768831A (en) 1998-06-23
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