EP0700265B1 - Machine dish-washing process and device - Google Patents

Machine dish-washing process and device Download PDF

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Publication number
EP0700265B1
EP0700265B1 EP94918791A EP94918791A EP0700265B1 EP 0700265 B1 EP0700265 B1 EP 0700265B1 EP 94918791 A EP94918791 A EP 94918791A EP 94918791 A EP94918791 A EP 94918791A EP 0700265 B1 EP0700265 B1 EP 0700265B1
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EP
European Patent Office
Prior art keywords
enzyme
detergent
dosing
wash liquor
feed
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP94918791A
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German (de)
French (fr)
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EP0700265A1 (en
EP0700265B2 (en
Inventor
Jacques Breyer
Günter Hellmann
Dieter Hemm
Klaus Wilbert
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Ecolab GmbH and Co OHG
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Henkel Ecolab GmbH and Co KG
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Priority claimed from DE4324106A external-priority patent/DE4324106C1/en
Application filed by Henkel Ecolab GmbH and Co KG filed Critical Henkel Ecolab GmbH and Co KG
Publication of EP0700265A1 publication Critical patent/EP0700265A1/en
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00Washing or rinsing machines for crockery or tableware
    • A47L15/42Details
    • A47L15/44Devices for adding cleaning agents; Devices for dispensing cleaning agents, rinsing aids or deodorants

Definitions

  • the invention is directed to a method for machine dishwashing in commercial dishwashers, in which a cleaning agent and a cleaning enhancer, preferably carbohydrate-degrading, enzyme, in particular amylase, containing this effect are added to the dishwasher. Furthermore, the invention relates to a device for performing the method, which has a detergent dosing system and a dosing system for another active ingredient with an associated pump and pump control.
  • a commercial dishwasher contains, for example, several tanks arranged one behind the other, from which washing or washing liquor is sprayed against the dishes passing through the dishwasher.
  • the tanks are placed in a cascade-like manner, the washing or washing liquor passing through the tanks one after the other from the dishes outlet end to the dishes inlet end, so that the degree of contamination of the washing or washing liquor increases from the outlet end to the inlet end.
  • Fresh water is fed to the dishwashers at the outlet end.
  • the required amount of cleaning agent is metered into at least one wash tank, also known as a metering tank.
  • detergent is added automatically depending on the conductivity or the pH of the wash liquor or, if liquid or powder detergent is already dissolved in water, possibly also by means of a time-controlled metering pump.
  • the detergents used in practice often do not prevent starch deposits that form on the dishes during normal machine cleaning in a dishwasher and do not remove existing starch deposits. At certain time intervals, dishes with starch deposits will become so-called Undergo thorough cleaning. In the case of such basic cleaning, the concentration of detergent in the rinsing or washing liquor is significantly higher than in normal rinsing processes.
  • Another alternative is to spray a highly concentrated alkaline detergent onto the dishes as part of a normal dishwashing cycle. There is also the option of performing manual tank cleaning.
  • DE-A-12 85 087 Also known from DE-A-12 85 087 is a method for machine dishwashing, in which an alkaline detergent is dosed in the main wash cycle and an enzyme-containing, in particular amylase-containing, rinse aid in the rinse and optionally pre-wash cycle is dosed into the dishwasher. This is done in order to reduce the starch formed on the dishes in the rinse and possibly pre-wash cycle.
  • an enzyme-containing, in particular amylase-containing, rinse aid in the rinse and optionally pre-wash cycle is dosed into the dishwasher. This is done in order to reduce the starch formed on the dishes in the rinse and possibly pre-wash cycle.
  • the addition of the enzyme-containing rinse aid in the main rinse cycle is not possible, since the alkalinity of the detergent would destroy the fermentation immediately.
  • the reference to the cold pre-wash cycle shows that a dishwasher is understood to be a household dishwasher. Cold pre-wash cycles are only common in household dishwashers.
  • an enzyme-containing detergent for avoiding scissors and stains that form in particular on glasses after drying is also known from EP-A-0 271 155. This detergent was also tested in a household dishwasher, which can be deduced from the incorrect washing time of 60 minutes for commercial dishwashers.
  • a generic method is known from DE-A-4 110 764.
  • a mechanical pre-cleaning of the dishes from coarse impurities and a spraying of the dishes with a concentrated surfactant solution and subsequent action of the concentrated surfactant solution in a commercial dishwasher carried out.
  • These process steps can also be carried out in a separate work station before the actual dishwasher.
  • the concentrated surfactant solution is slightly acidic to weakly alkaline and contains carbohydrate-degrading enzyme, especially amylase.
  • the exposure time is 10 to 90 seconds, which is within the usual contact times between cleaning agents and dishes in commercial dishwashing processes.
  • a method for machine dishwashing in commercial dishwashers in which a detergent and a further active ingredient that supports its action are metered into the washing or washing liquor, and a device for carrying out the method, which includes a detergent dosing system and a dosing system for another active ingredient assigned pump and pump control are known from DE-A-39 20 728.
  • active oxygen is metered into the metering or washing tank of the dishwasher as this further active ingredient which supports its action.
  • active oxygen is replenished into the wash tank during the interruptions.
  • a method and an apparatus for machine dishwashing in commercial dishwashers in which the two different active ingredients, namely cleaning agents and, for example, a bleaching agent, are added to the washing liquor of a dishwasher by means of a detergent dosing system and a dosing system for a further active ingredient with an associated pump and pump control. is also known from US-A-3,490,467.
  • the object of the invention is to provide a solution which prevents the formation of a starch coating on the dishes during machine dishwashing in commercial dishwashers.
  • this object is achieved according to the invention in that the cleaning booster is part of the low-alkaline cleaning agent formulated, in particular based on phosphate or nitriloacetic acid or its salts (NTA), and / or additionally in combination with the lower-alkaline cleaning agent, the rinsing - or washing liquor to which at least one rinsing or washing tank of the dishwasher is added.
  • NTA phosphate or nitriloacetic acid or its salts
  • the lower-alkaline cleaner may also contain complexing agents other than those listed, if so desired.
  • a concentration of 0.5 to 15 g / l of low-alkaline cleaning agent is expediently set in the rinsing or washing liquor.
  • the low-alkaline cleaning agent is metered in in use concentration with a pH of 7 to 11, preferably 9.1 to 10.8, which is also provided by the invention.
  • a concentration of 0.05 to 2 g / l of cleaning enhancer is expediently set in the rinsing or washing liquor according to a further embodiment of the invention.
  • the invention provides that the enzyme-containing cleaning booster during normal dishwasher operation with a normal cleaning concentration in the washing or washing liquor of 0.5 to 8 g / l and / or during a periodic basic cleaning with an increased cleaning concentration in the washing or washing liquor of 3 to 15 g / l is metered into the rinsing or washing liquor.
  • the invention provides in one embodiment that the cleaning booster is replenished to the extent of the enzyme breakdown.
  • the enzyme breakdown or the enzyme decay (consumption) in standstill phases of the dishwasher operation is lower than during the wash phases, so that the invention provides in an expedient development that the replenishment in standstill phases is low in comparison to wash phases.
  • the enzyme-containing cleaning booster like conventional cleaning agents, can either be metered into the at least one dosing or washing tank of the dishwasher, but also into the liquid flowing through the rinse line and / or the spray system of the commercial dishwasher, and in this way fed to the dishwasher.
  • the invention therefore provides as a further development that detergents and cleaning boosters are metered separately into the washing or washing liquor.
  • the enzyme-containing detergent booster is metered into the rinsing or washing liquor in parallel or subsequently to the lower-alkaline detergent.
  • a cleaning booster is metered in, which contains about 0.01 to 0.6% by weight, preferably 0.45 to 0.55% by weight, of enzyme, in particular amylase, and 10 to 25 % By weight, preferably 15 to 20% by weight, of propylene glycol, in particular 1,2-propylene glycol, and a corresponding amount of water, as provided by the invention in one embodiment.
  • the cleaning enhancer can contain as an enzyme amylase, lipase, protease or other, in particular carbohydrate-degrading, enzymes, either individually or in suitable mixtures.
  • an enzyme-free, liquid or powdery, low-alkaline cleaning agent is used in combination with an enzyme-containing cleaning booster.
  • the invention provides in one embodiment that an enzyme-free, in particular liquid, low-alkaline cleaning agent is metered into the rinsing or washing liquor during detergent dosing times, and the enzyme-containing cleaning booster is metered in parallel to the extent of the detergent consumption.
  • an enzyme-free, in particular liquid, low-alkaline cleaning agent is metered into the rinsing or washing liquor during detergent dosing times, and the enzyme-containing cleaning booster is metered in parallel to the extent of the detergent consumption.
  • enzyme is already incorporated into the liquid or powdered low-alkaline cleaning agent.
  • a solid enzyme carrier for example amylase carrier
  • amylase carrier can be incorporated into a powdery, low-alkaline cleaner.
  • This enzyme-containing cleaning agent is then used in combination with the enzyme-containing cleaning enhancer.
  • the invention provides in an embodiment that during detergent dosing times in the rinsing or washing liquor, an enzyme for immediate rinsing containing a sufficient amount, in particular powdery, low-alkaline cleaning agent and immediately after completion or during interruptions or downtimes of the dishwasher operation and / or Dosing pauses of the cleaning agent, the enzyme-containing cleaning booster is metered into the rinsing or washing liquor.
  • the enzyme-containing cleaning booster is therefore only metered into the washing or washing liquor during or immediately after the dosing pauses of the cleaning agent and / or the interruptions or downtimes of the dishwasher operation. During the times of the active rinsing cycle, during which the detergent is dosed into the washing tank of the dishwasher, the enzyme-containing cleaning booster is not dosed.
  • the enzyme-containing cleaning enhancer is metered into the rinsing or washing liquor to maintain the enzyme concentration to the extent of the enzyme breakdown or enzyme decay (consumption), which the invention further provides.
  • enzymes such as amylase, lipase or protease are not stable in the washing liquor of commercial dishwashers. After being washed into the wash tank of a commercial dishwasher Enzyme-containing cleaning agents or cleaning boosters lose their effect relatively quickly. In the event of interruptions or downtimes in the operation of the dishwasher and / or dosing of the cleaning agent or cleaning booster, enzyme degradation or enzyme breakdown (consumption) occurs, in which the enzyme content in the washing or washing liquor often drops at around 40 to 60% per hour. Depending on the degree of consumption, z. B. even after a half-hour break in machine operation, the enzyme content dropped to well below half.
  • the invention provides in one embodiment that the washing under conditions in a commercial Dishwasher undergoing enzyme degradation or enzyme decay (consumption) enzyme-containing cleaning enhancers in the event of interruptions or downtimes in the dishwasher operation and / or dosing intervals of the cleaning agent or cleaning enhancer in the washing or washing liquor in an amount that is added during the respective interruption or downtime phase and / or dosing breakdown occurring enzyme breakdown or enzyme breakdown (consumption) compensates so that after the end of the respective interruption or standstill phase and / or Do the machine operation is continued with essentially the same enzyme concentration in the rinsing or washing liquor as before the respective interruption or standstill phase and / or dosing break. This ensures that with each active cleaning phase of the washing cycle in a commercial dishwasher there is a sufficiently high enzyme concentration in the wash liquor
  • the invention provides that the enzyme-containing cleaning enhancer is added to the rinsing or washing liquor to maintain the enzyme concentration immediately after completion or during the interruptions or standstill phases and / or the dosing pauses of the detergent to the extent of the enzyme breakdown or enzyme decay (consumption).
  • the invention provides two alternatives for the metering-in or metering-in of the enzyme-containing cleaning booster.
  • the enzyme-containing cleaning booster can be dosed or re-dosed during the interruptions or standstill phases of the dishwasher operation and / or dosing pauses of the cleaning agent, and on the other hand the dosing or re-dosing of the enzyme-containing cleaning booster can be carried out immediately after the interruptions or downtime phases of the dishwasher operation and / or Dosing intervals of the cleaning agent take place.
  • the invention provides in a further embodiment that the enzyme concentration in the rinsing or snacking liquor is maintained during the respective interruption or standstill phase and / or during the dosing pauses of the cleaning agent by maintenance dosing of the enzyme-containing cleaning booster. It is advantageous here if the maintenance dosing takes place in individual dosing strokes, as the invention provides in a further development.
  • the embodiment accordingly aims primarily at maintenance dosing of the enzyme-containing cleaning booster in the downtimes of the dishwasher between two successive washing phases or during the dosing pauses between two dosing times of the cleaning agent.
  • the maintenance dosing ensures that in the extent of the enzyme breakdown or enzyme decay (consumption) new, enzyme-containing cleaning boosters in the at least one dosing or Wash tank arrives.
  • the washing tank or the washing liquor of the dishwasher is thus always ready for a new washing phase.
  • a wash liquor which has been sufficiently admixed with enzymes or has a sufficiently high enzyme concentration is immediately available.
  • the enzyme-containing cleaning booster is replenished into the at least one wash tank only during the standstill phases or dosing pauses of the detergent to the extent of the enzyme breakdown.
  • an enzyme-free cleaning agent in particular a liquid cleaner, is used, in addition to maintenance dosing during the dosing times for the cleaning agent, the enzyme-containing cleaning booster is dosed in parallel.
  • enzyme-free cleaning agent enzyme is metered into the wash tank or the rinsing or washing liquor during the rinsing phases of the amount of detergent used and during the standstill phases or the detergent dosing breaks to the extent of the enzyme breakdown or enzyme breakdown.
  • the parallel dosing enables the use of enzyme-containing cleaning boosters such as B. amylase solution that cannot be formulated with the usual enzyme-free alkaline, in particular lower-alkaline, cleaning agents.
  • enzyme-containing cleaning boosters such as B. amylase solution
  • liquid or powder detergents are metered in depending on the measured conductivity or the measured pH value or time-controlled only during certain metering times.
  • the enzyme delivery rate of the maintenance dosing is optimized on the basis of an enzyme activity determination, as is further provided by the invention. After knowing the rate of decay of the enzymes, it may be sufficient to add detergent enhancers at certain intervals.
  • the invention further provides that the maintenance dosage of the enzyme-containing cleaning booster is started after each disintegration of about 20% of the original enzyme content in the rinsing or washing liquor.
  • a surge dose is carried out immediately after the end of the respective interruption or standstill phase and / or dosing pause, in which a quantity of enzyme-containing cleaning booster is added to the rinsing or washing liquor, which during the The duration of the respective interruption or standstill phase and / or dosing break corresponds to enzyme degradation or enzyme breakdown (consumption).
  • the enzyme-containing cleaning booster is dosed, the amount of enzyme-containing cleaning booster added during the dosing being adapted to the duration of the interruption and dimensioned such that it compensates for the enzyme breakdown or decay (consumption) that occurred during the interruption. Accordingly, during the interruption or standstill phase of the machine operation and / or the detergent dosing break, no enzyme-containing cleaning booster is fed to the at least one dosing or wash tank or the washing or washing liquor of the dishwasher.
  • the enzyme-containing cleaning booster is supplied only after the interruption or dosing break has ended within a relatively short time, so that the amount of enzyme which was consumed during the interruption or dosing break is replaced.
  • the measurement of the amount of the cleaning booster added during the batch dosing is carried out as a function of the duration of the interruption and / or dosing pause and as a function of the course of the enzyme decay which can be described by a mathematical function, for example an e-function. This ensures that the enzyme consumed is replaced fairly accurately without substantial underdosing or overdosing.
  • the time course of enzyme consumption essentially follows an exponential function, the concentration decreasing exponentially starting from an initial concentration.
  • a practice-oriented pulse dosage after a pause t must consequently follow the complementary function of the course of the enzyme consumption.
  • the enzyme-containing cleaning booster In the case of surge dosing as well as maintenance dosing, it is possible for the enzyme-containing cleaning booster to be metered in during the dosing times in parallel, if an enzyme-free cleaning agent is used.
  • a metering system for metering an enzyme-containing cleaning amplifier which is separate from the detergent metering system and which has an operating state for maintenance metering during interruptions or downtimes of the dishwasher operation and / or metering pauses of the detergent.
  • the device according to the invention for carrying out the method is fundamentally characterized by a metering system for the enzyme-containing cleaning booster, which is separate from the detergent dosing system, the latter having an operating state for maintenance dosing and / or an operating state for impact dosing.
  • the detergent dosing system can be designed in a conventional manner, for. B. as a metering pump in a liquid cleaner or as fresh water or liquor in a powder cleaner.
  • the dosing system for the enzyme-containing cleaning booster which is separate or separate from the detergent dosing system. This has either an operating state for maintenance dosing or an operating state for surge dosing and is provided with the technical equipment necessary for the respective operating state.
  • the cleaning amplifier dosing system has either only technical devices for the operating state of maintenance dosing or technical devices for the operating state of shock dosing
  • the device thus enables maintenance dosing during the interruptions or standstill phases of the dishwasher operation and / or the cleaning agent dosing breaks or a shock dosing immediately after the end of interruptions or standstill phases of the dishwasher operation and / or cleaning agent dosing breaks, so that a through Enzyme degradation or decomposition-induced decrease in enzyme activity is compensated for during this time.
  • the device in a development of the invention contains a counter, to which pause pulses are regularly supplied during the interruption times. With these pause pulses, the counter reading is not increased in a linear manner, but rather in a step-wise approximated function that is complementary to the enzyme decay, in particular an e-function, in order to finally approach a predetermined final value asymptotically with a minimal count rate.
  • the counter is counted down linearly from the achieved counter reading at a constant clock rate until the counter reading reaches zero.
  • the down counting pulses activate a pump, which effects the surge metering.
  • the duration of the surge metering therefore depends on the meter reading reached during the interruption time.
  • the duration of the shock metering is orders of magnitude shorter than the duration of the interruption times in question.
  • the surge dosage thus compensates for the drug consumption of several 10 minutes to hours within a period of seconds.
  • the level of the meter reading is therefore a measure of the duration of the surge metering.
  • This duration is in any case much shorter than the duration of possible break times, so that the shock dosage of the enzyme-containing cleaning boosters occur at a much higher rate than the breakdown or decay (consumption) of the enzyme in the wash liquor.
  • the enzyme consumption of several 10 minutes is compensated in this way.
  • This type of shock metering is not only carried out immediately after interruptions or downtimes in the dishwasher operation, but if desired also immediately after the detergent dosing breaks.
  • the term "counter” is to be understood broadly in this context. It includes any counting device that counts supplied pause pulses according to a given function and thus also non-linear, e.g. B. following an e-function enables counting.
  • the variation in the time interval of the pause pulses can be used to accelerate (compress) or decelerate (stretch) the counting process in the time domain.
  • the pause pulses can be present at a constant time interval and can be multiplied by a factor whose time profile corresponds to an e-function.
  • the counter can also contain a summing device which increases the counter reading by a time-varying amount with each pause pulse.
  • the invention provides for devices with the operating state of maintenance dosing as well as for devices with the operating state of shock dosing that the dosing system for the enzyme-containing cleaning booster additionally has an operating state which promotes parallel to the cleaning agent dosing system for parallel dosing when the cleaning agent dosing system is switched on.
  • both enzyme-containing and enzyme-free cleaning agents can be used with the device, the parallel dosing allowing the addition of enzyme-containing cleaning enhancers when using enzyme-free cleaning agents.
  • the parallel dosing and the maintenance dosing or the surge dosing differ essentially only in that per unit of time in each case in the metering tank or the rinsing or washing liquor conveyed amount of enzyme-containing cleaning enhancer.
  • a frequency-controlled peristaltic pump or a diaphragm pump is provided for conveying the enzyme-containing cleaning amplifier, as the invention further provides.
  • Such a pump can be operated with a number of pump strokes per unit of time corresponding to the enzyme breakdown. Relatively few pump strokes are then sufficient for maintenance dosing, while a much larger number of pump strokes are required for surge dosing and / or if necessary for parallel dosing when using an enzyme-free cleaner.
  • the associated frequency control of the pump has a first control range for maintenance dosing and a second control range for the dishwashing phase of the dishwasher when the detergent dosing system is switched on, with a significantly increased delivery rate compared to the dose in the first control range.
  • a conventional liquid detergent metering pump 1 delivers liquid, enzyme-free cleaning agent 2 from a liquid detergent tank, for example regulated via a conductivity or pH value measurement, through a line 3 to at least one (not shown) metering or washing tank of a dishwasher.
  • a frequency-controlled peristaltic pump 4 which also conveys from a liquid, enzyme-containing cleaning booster 5 through a line 6 to the above-mentioned, at least one metering or washing tank.
  • This dosing system for liquid-made, enzyme-containing cleaning boosters 5 can be controlled by means of internal and / or external electronics in such a way that a function diagram according to FIG. 2 is established, i.e. maintenance dosing 17, 18 and, if necessary, parallel dosing 16 of cleaning booster 5 in addition to the dosing of cleaning agents is possible.
  • the second line, designated 8 shows the dosage of the enzyme-free cleaning agent 2, ie the active operating state of the liquid cleaner metering pump 1.
  • a two-time start of the metering pump 1 is assumed during a machine switch-on state 10.
  • the corresponding two detergent dosing times are designated 12 and 13.
  • An intermediate dosing pause is indicated by 14 and the dosing pause corresponding to the interruption or the standstill phase 11 of the dishwasher operation is identified by 15.
  • the dosage of the enzyme-containing cleaning amplifier 5, ie the active operating state of the peristaltic pump 4, is given.
  • the liquid detergent 2 is not replenished during the interruption or standstill phase 11 of the dishwasher (Detergent dosing break 15). Such dosing is not necessary since the concentration of detergent in the wash liquor will not be significantly reduced. Only the enzyme breakdown or enzyme decay (consumption) during the standstill phase 11 is compensated for by the slowed down metering or maintenance metering 17 during this period. It can be cheap for longer Dosing pauses 14 in the dishwashing phases 10 of the dishwasher provide individual pump strokes for maintenance dosing 18 to compensate for the constant enzyme breakdown or decay (consumption) during this time.
  • FIGS 3 and 4 an embodiment from FIGS 3 and 4 can be seen, with FIG. 3 the detergent dosing system assigned to a commercial dishwasher for an enzyme-containing, low-alkaline powder cleaner 19 and the separate dosing system for the enzyme-containing liquid cleaning booster 5 and FIG. 4 in the three lines 7a, 8a and FIG. 9a shows the different switch-on and switch-off states (1/0) of the commercial dishwasher and the metering systems as a function of the time t. 3 consists of a funnel 20 with an enzyme-containing, low-alkaline powder cleaner 19 filled therein. As is known from conventional dosing systems, the enzyme-containing powder cleaner 19 is dosed in the funnel 20 via a fresh water or liquor flush 21 and a line 22 to at least one dosing or wash tank of a commercial dishwasher (arrow direction).
  • a dosing system for enzyme-containing cleaning booster 5 with a frequency-controlled peristaltic pump 4 is provided, which also conveys the enzyme-containing cleaning booster 5 from a tank via a line 6 to the at least one dosing or washing tank of the dishwasher.
  • the peristaltic pump 4 according to FIG. 3/4 only works during the standstill phase 11 of the dishwasher and possibly during the dosing pause 14, as indicated in line 9a of FIG. 4.
  • Lines 7a and 8a show identical operating states as lines 7 and 8 according to the embodiment of FIG. 1/2.
  • a modification of a frequency-controlled peristaltic pump 4, 27 is preferably used to operate the maintenance metering 17, 18 and the shock metering SD explained below as well as the desired parallel metering 16, the pump used in the maintenance metering in FIGS. 1 and 3 with the reference numerals 4 and the pump used in the surge metering is provided with the reference number 27 in FIG. 5.
  • Two control ranges for frequency control are possible, firstly an area I for parallel dosing 16 or the shock dosing SD explained below with a delivery rate range of 8 to 290 ml / min and secondly an area II for maintenance dosing 17, 18 with a delivery rate range of 1, 5 to 3.5 ml / min.
  • control ranges can be selected externally so that readjustment is possible according to the washing result.
  • the addition or subsequent dosing of enzyme-containing cleaning boosters 5 can also be carried out by a surge metering SD.
  • the shock dosing SD becomes immediate after the end of a Interruption or standstill phase 11 and / or a detergent dosing break 14, 15 activated.
  • the corresponding function diagrams for a surge dose SD in lines 7, 7a and 8, 8a would not differ from the function diagrams shown in FIGS.
  • FIG. 5 shows a commercial dishwasher 23 through which the dishes to be washed are conveyed from left (inlet end) to right (outlet end).
  • the dishwasher 23 contains several tanks one behind the other, from which washing or washing liquor is sprayed against the dishes in order to then run back into the tanks.
  • the tanks are cascaded together in a known manner, the washing or washing liquor passing through the tanks in succession from the outlet end (right) to the inlet end (left), so that the degree of contamination of the washing liquor increases from the outlet end to the inlet end.
  • water is introduced into the dishwasher 23 and additionally from a detergent tank 24 low-alkaline cleaning agent 2, which is contained in the detergent tank 24 in liquid form.
  • the cleaning agent 2 is conveyed by a pump 25 in metered form.
  • This pump 25 is driven by a pump control unit 26.
  • the detergent 2 is dosed as a function of the conductivity or pH of the washing liquor contained in the dishwasher 23.
  • the pump control unit 26 controls a further pump 27, which doses a liquid, enzyme-containing cleaning amplifier 5 into the dishwasher 23 from a tank 28.
  • the cleaning booster contains enzymes such as amylase, lipase or protease.
  • the cleaning amplifier 5, which is contained in the tank 28 in liquid form is fed into the dishwasher 23 by the pump 27, which is preferably a peristaltic pump.
  • the pump 27 is controlled by pulses that it are supplied via a control line 29.
  • the pump is driven by a stepper motor, each pulse in the control line 29 corresponding to a specific delivery rate of the pump 27.
  • the control line 29 is connected to an operating pulse line 30 coming from the pump control unit 26.
  • the operating pulse line 30 supplies operating pulses 10 during the operating state 10 of the dishwasher, the frequency of which is dimensioned such that the pump 27 maintains a certain concentration of enzyme-containing cleaning amplifier 5 in the washing liquor, that is to say a parallel metering 16 is carried out.
  • the pump control unit 26 does not deliver any pulses to the pump 25 for the cleaning agent 2 and likewise does not supply any operating pulses to the operating pulse line 30 2 illustrated example analog case of a shock metering (explained below) in combination with a parallel metering 16 before.
  • a counter 32 is connected to a pause pulse line 31 of the pump control unit 26.
  • the pause pulse line 31 supplies pulses to the counter 32 at a constant time interval in the event of an interruption in operation or a standstill phase 11 of the dishwasher and / or during dosing pauses 15 and possibly dosing pauses 14.
  • the counter 32 counts non-linearly in the manner shown in FIG. 6. 6, the pause time t is plotted along the abscissa during an interruption or standstill phase 11 and / or a dosing pause 14, 15 and the counter reading n along the ordinate.
  • a pause pulse is delivered every minute. With each pause pulse, the counter reading of the counter 32 is increased by a varying counting step. The size of the counting steps decreases with increasing pause time t.
  • the counting capacity of the counter 32 here is 128.
  • the time course of the counter reading corresponds to a stair curve 33 which is approximated to an e-function 34.
  • C t is the enzyme concentration at time t
  • C 0 is the initial concentration of the enzyme
  • 1 / ⁇
  • is the consumption time constant
  • V t is the shock metering time for a pause time of t and V max the maximum shock metering time.
  • This function V t corresponds to the ideal curve 34 from FIG. 6, which is approximated by the stair curve 33.
  • the stair curve 33 is implemented in the counter 32 by means of a programmable logic module (PLD).
  • PLD programmable logic module
  • the non-linear counting function is achieved by varying the counting step.
  • the clock rate of the pause pulses is adapted to the drainage function of the enzyme or the enzyme-containing cleaning amplifier 5.
  • the maximum counter reading n max of counter 32 is 128, which corresponds to a resolution of 7 bits.
  • the counter reading of the counter 32 is counted linearly in steps from 1 down to 0. 35 pulses are generated at the counter output, which are supplied to the pump 27 via the control line 29. The pulses generated when counting down the counter 32 at the output 35 cause the surge metering by the pump 27. When the counter reading 0 is reached, the surge metering is ended.
  • FIG. 7 shows the time course of the enzyme concentration C in the wash liquor in the event of an interruption or standstill phase 11 in the dishwasher operation or a dosing break 14, 15, the length of which is t 1 .
  • the enzyme concentration C / C 0 normalized to the normal value C 0 is given along the ordinate.
  • the break in operation ends at the start of the surge metering duration t 2 .
  • the operation of the dishwasher begins, that is, the active operating state 10 or the dosing times 12, 13, with a shock metering SD being carried out in the initial phase.
  • the enzyme concentration rises linearly steeply to the normal value of "1".
  • the subsequent operation is then carried out with this normal concentration.
  • the duration t 2 of the shock metering SD is, for example, 1 to 2 minutes and is considerably shorter than the break t 1 .
  • the counter 32 increments as a result of the pause pulses, the counter reading n developing in accordance with curve 33 in FIG. 6 and approaching asymptotically to the maximum counter reading n max , which is finally reached when the pause in operation Dishwasher is not interrupted beforehand.
  • the maximum counter reading n max corresponds to the maximum surge metering time.
  • the maximum count is reached when the pause time is about 5 ⁇ , where ⁇ is the consumption time constant of the enzyme.
  • the clock rate of the counter 32 when counting down is chosen so that the maximum concentration C 0 of enzyme in the wash liquor is just reached again at the maximum burst dosing time.
  • the maximum count is reached after a break of 0.5 to 3 hours.
  • a low-alkaline cleaner based on phosphate or nitrilotriacetic acid or its salts are used as cleaning agents in the devices described. and metered an amylase-containing cleaning booster 5 into the dishwasher.
  • the cleaning enhancer can also contain lipase or protease.
  • Cleaners 2, 19 and / or cleaning boosters 5 can be metered into at least one washing or dosing tank of the dishwasher and / or the rinse line and / or the spraying device of the dishwasher.
  • the enzyme-containing cleaning booster is used during regular dishwasher operation with a normal cleaning agent concentration in the washing or washing liquor of 0.5 to 8 g / l and / or a periodic basic cleaning with an increased concentration of 3 to 15 g / l in the rinsing or washing liquor is only metered in parallel or subsequently to the lower alkaline detergent of the rinsing or washing liquor. It is sufficient to equip a commercial dishwasher with two dosing systems, one for the cleaner and one for the cleaning booster. For example, these can be two metering pumps that can be operated parallel to one another.

Landscapes

  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Washing And Drying Of Tableware (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Enzymes And Modification Thereof (AREA)
  • Cleaning In General (AREA)

Abstract

The process of dishwashing in an institutional dishwashing machine by adding to the wash liquor of the dishwashing machine a low-alkali content detergent composition and adding to a washing tank of the dishwashing machine a detergency booster composition containing an enzyme. Apparatus to practice the process is also disclosed.

Description

Die Erfindung richtet sich auf ein Verfahren zur maschinellen Geschirreinigung in gewerblichen Geschirrspülmaschinen bei welchem ein Reinigungsmittel und ein dieses in der Wirkung unterstützender, vorzugsweise kohlenhydratabbauendes, Enzym, insbesondere Amylase, enthaltender Reinigungsverstärker in die Geschirrspülmaschine eindosiert werden. Weiterhin betrifft die Erfindung eine Vorrichtung zum Durchführen des Verfahrens, welche ein Reinigungsmittel-Dosiersystem und ein Dosiersystem für einen weiteren Wirkstoff mit zugeordneter Pumpe und Pumpensteuerung aufweist.The invention is directed to a method for machine dishwashing in commercial dishwashers, in which a cleaning agent and a cleaning enhancer, preferably carbohydrate-degrading, enzyme, in particular amylase, containing this effect are added to the dishwasher. Furthermore, the invention relates to a device for performing the method, which has a detergent dosing system and a dosing system for another active ingredient with an associated pump and pump control.

Eine gewerbliche Geschirrspülmaschine enthält beispielsweise mehrere hintereinander angeordnete Tanks, aus denen Spül- bzw. Waschflotte gegen das die Geschirrspülmaschine durchlaufende Geschirr gesprüht wird. Die Tanks sind kaskadenartig aneinandergesetzt, wobei die Spül- bzw. Waschflotte die Tanks nacheinander vom Geschirr-Auslaßende zum Geschirr-Einlaßende hin durchläuft, so daß der Verschmutzungsgrad der Spül- oder Waschflotte vom Auslaßende zum Einlaßende hin zunimmt. Am Auslaßende wird den Geschirrspülmaschinen Frischwasser zugeführt. Die benötigte Menge an Reinigungsmittel wird in zumindest einen auch als Dosiertank bezeichneten Waschtank zudosiert. Üblicherweise erfolgt die Zudosierung von Reinigungsmittel automatisch in Abhängigkeit von der Leitfähigkeit oder dem pH-Wert der Waschflotte oder bei Zugabe von flüssigem oder bereits in Wasser gelöstem pulverförmigem Reiniger gegebenenfalls auch mittels einer zeitgesteuerten Dosierpumpe.A commercial dishwasher contains, for example, several tanks arranged one behind the other, from which washing or washing liquor is sprayed against the dishes passing through the dishwasher. The tanks are placed in a cascade-like manner, the washing or washing liquor passing through the tanks one after the other from the dishes outlet end to the dishes inlet end, so that the degree of contamination of the washing or washing liquor increases from the outlet end to the inlet end. Fresh water is fed to the dishwashers at the outlet end. The required amount of cleaning agent is metered into at least one wash tank, also known as a metering tank. Usually, detergent is added automatically depending on the conductivity or the pH of the wash liquor or, if liquid or powder detergent is already dissolved in water, possibly also by means of a time-controlled metering pump.

Mit den in der Praxis eingesetzten Reinigungsmitteln lassen sich bei üblicher Reinigerkonzentration Stärkeablagerungen, die sich auf dem Geschirr bilden, im Rahmen der üblichen maschinellen Reinigung in einer Geschirrspülmaschine oftmals nicht verhindern und vorhandene Stärkeablagerungen nicht entfernen. In gewissen zeitlichen Abständen wird Stärkeablagerungen aufweisendes Geschirr daher einer sogenannten Grundreinigung unterzogen. Bei einer solchen Grundreinigung wird in der Spül- bzw. Waschflotte eine gegenüber normalen Spülvorgängen deutlich erhöhte Konzentration an Reinigungsmittel eingestellt. Eine andere Alternative besteht darin, im Rahmen eines üblichen Geschirrspülreinigungszyklus auf das Geschirr ein hochkonzentriertes alkalisches Reinigungsmittel aufzusprühen. Daneben besteht ferner die Möglichkeit eine manuelle Tankreinigung durchzuführen.With the usual detergent concentration, the detergents used in practice often do not prevent starch deposits that form on the dishes during normal machine cleaning in a dishwasher and do not remove existing starch deposits. At certain time intervals, dishes with starch deposits will become so-called Undergo thorough cleaning. In the case of such basic cleaning, the concentration of detergent in the rinsing or washing liquor is significantly higher than in normal rinsing processes. Another alternative is to spray a highly concentrated alkaline detergent onto the dishes as part of a normal dishwashing cycle. There is also the option of performing manual tank cleaning.

Aus der DE-A-17 28 093 ist es für das Reinigen von Geschirr in Haushaltsgeschirrspülmaschinen bekannt, zur Entfernung von Stärkeablagerungen auf dem Geschirr dem Spülwasser ein Klarspülmittel zusammen mit Amylase zuzugeben. Gewünschtenfalls kann zusätzlich zu der Amylase auch Protease oder Lipase dem Klarspülmittel zugegeben werden.From DE-A-17 28 093 it is known for cleaning dishes in household dishwashers to add a rinse aid together with amylase to the starch water to remove starch deposits on the dishes. If desired, protease or lipase can also be added to the rinse aid in addition to the amylase.

Ebenso ist aus der DE-A-12 85 087 ein Verfahren zur maschinellen Geschirreinigung bekannt, bei welchem im Hauptspülgang ein alkalisches Reinigungsmittel und im Nachspül- und gegebenenfalls Vorspülgang ein enzymhaltiges, insbesondere amylasehaltiges, Nachspülmittel in die Geschirrspülmaschine dosiert wird. Dies geschieht, um im Nachspül- und gegebenenfalls Vorspülgang auf dem Geschirr gebildete Stärke abzubauen. Es wird aber ausdrücklich darauf hingewiesen, daß die Zugabe des enzymhaltigen Nachspülmittels im Hauptspülgang nicht möglich ist, da die Alkalität des Reinigungsmittels die Fermente sofort zerstören würde. Außerdem zeigt der Hinweis auf den kalten Vorspülgang, daß hier unter Geschirrspülmaschine eine Haushaltsgeschirrspülmaschine verstanden wird. Kalte Vorspülgänge sind nur bei Haushaltsgeschirrspülmaschinen üblich.Also known from DE-A-12 85 087 is a method for machine dishwashing, in which an alkaline detergent is dosed in the main wash cycle and an enzyme-containing, in particular amylase-containing, rinse aid in the rinse and optionally pre-wash cycle is dosed into the dishwasher. This is done in order to reduce the starch formed on the dishes in the rinse and possibly pre-wash cycle. However, it is expressly pointed out that the addition of the enzyme-containing rinse aid in the main rinse cycle is not possible, since the alkalinity of the detergent would destroy the fermentation immediately. In addition, the reference to the cold pre-wash cycle shows that a dishwasher is understood to be a household dishwasher. Cold pre-wash cycles are only common in household dishwashers.

Aus der DE-A 27 27 463 und der EP-A-0 256 679 ist es bekannt, Geschirr in automatischen Geschirrspülmaschinen mit einem Enzym enthaltenden niederalkalischen Reinigungsmittel zu reinigen. Auch in diesen Veröffentlichungen findet sich kein Hinweis auf gewerbliche Geschirrspülmaschinen. So wurden die Versuchsbeispiele nach der EP-A-0 256 679 in einer Haushaltsgeschirrspülmaschine durchgeführt und zeigen die Hinweise in der DE-A 27 27 463 auf Abgabevorrichtungen für das Reinigungsmittel, die dieses vor seiner Anwendung in der Geschirrspülmaschine zurückhalten und die meistens nicht flüssigkeitsdicht sind, so dar im Vorspülgang Wasser in die Abgabevorrichtung eindringen kann, daß auch hier Haushaltsgeschirrspülmaschinen gemeint sind.From DE-A 27 27 463 and EP-A-0 256 679 it is known to clean dishes in automatic dishwashers with an enzyme-containing low-alkaline cleaning agent. There is also no reference to commercial dishwashers in these publications. So were the experimental examples according to EP-A-0 256 679 carried out in a household dishwasher and show the instructions in DE-A 27 27 463 on dispensing devices for the cleaning agent, which hold it back before use in the dishwasher and which are usually not liquid-tight, so that water can penetrate into the dispensing device in the pre-rinse cycle that household dishwashers are also meant here.

Weiterhin ist ein enzymhaltiges Spülmittel zur Vermeidung von sich insbesondere auf Gläsern nach dem Trocknen bildenden Scheren und Flecken auch aus der EP-A-0 271 155 bekannt. Dieses Spülmittel wurde ebenfalls in einer Haushaltsgeschirrspülmaschine getestet, was sich aus dem für gewerbliche Geschirrspülmaschinen unzutreffend langen Spülzeitraum von 60 Minuten ableiten läßt.Furthermore, an enzyme-containing detergent for avoiding scissors and stains that form in particular on glasses after drying is also known from EP-A-0 271 155. This detergent was also tested in a household dishwasher, which can be deduced from the incorrect washing time of 60 minutes for commercial dishwashers.

Im Artikel "Enzyme in Spülmitteln für Haushalts-Geschirrspülmachinen" von Dr. Th. Altenschöpfer in der Zeitschrift Fette, Seifen, Anstrichmittel, 73 (1971), Heft 7, Seite 464, linke Spalte, drittletzter Absatz, wird zusammenfassend festgestellt, daß ein Einsatz von enzymhaltigem Reinigungsmittel in gewerblichen Geschirrspülmaschinen wegen der notwendigen langen Kontaktzeiten nicht möglich ist. Im Zusammenhang mit der Tabelle 6 wird in diesem Artikel erläutert, daß gute und sichere Reinigungsergebnisse erst bei Kontaktzeiten ab 10 bis 20 Minuten erreicht werden. Aufgrund der in gewerblichen Geschirrspülmaschinen nur kurzen Kontaktzeit, während welcher das Geschirr mit der Reinigerflotte in Berührung ist, erscheint es der Fachwelt nicht möglich, mit enzymhaltigem Reinigungsmittel in gewerblichen Geschirrspülmaschinen Stärkeablagerungen auf dem Geschirr zu verhindern bzw. abzubauen.In the article "Enzymes in detergents for household dishwashers" by Dr. Th. Altenschöpfer in the magazine Fette, Seifen, Anstrichmittel, 73 (1971), number 7, page 464, left column, third to last paragraph, it is stated in summary that the use of enzyme-containing cleaning agents in commercial dishwashers is not possible because of the long contact times required . In connection with Table 6, this article explains that good and safe cleaning results can only be achieved with contact times of 10 to 20 minutes. Due to the short contact time in commercial dishwashers, during which the dishes are in contact with the detergent fleet, it does not appear to the specialist world to be able to prevent or break down starch deposits on the dishes with commercial detergent in commercial dishwashers.

Schließlich ist aus der DE-A-4 110 764 ein gattungsgemäßes Verfahren bekannt. Hierbei wird in einer Art Vorwasch- oder Vorspülzone zunächst eine mechanische Vorreinigung des Geschirrs von groben Verunreinigungen und ein Besprühen des Geschirrs mit einer konzentrierten Tensidlösung sowie anschließendem Einwirken der konzentrierten Tensidlösung in einer gewerblichen Geschirrspülmaschine durchgeführt. Diese Verfahrensschritte können auch vor der eigentlichen Geschirrspülmaschine in einer separaten Arbeitsstation durchgeführt werden. Die konzentrierte Tensidlösung ist schwach sauer bis schwach alkalisch eingestellt und enthält kohlenhydratabbauendes Enzym, insbesondere Amylase. Als Einwirkzeit werden 10 bis 90 Sekunden angegeben, was im Rahmen üblicher Kontaktzeiten zwischen Reinigungsmittel und Geschirr bei gewerblichen Geschirrspülverfahren liegt. Erst danach erfolgt im eigentlichen Hauptwaschzyklus die Endreinigung des Geschirrs in ansich bekannter Weise durch übliche Reinigungsschritte, einschließlich des Klarspülens, mit üblichen, mit den Tensiden der konzentrierten Tensidlösung verträglichen Reinigungsmitteln. Ähnlich wie bei dem Haushaltsgeschirrspülverfahren nach der DE-A-1 285 087 wird also auch bei diesem Verfahren von der Anwendung und Zudosierung von enzymhaltigem Mittel im eigentlichen Hauptwaschgang oder Hauptwaschzyklus Abstand genommen. In der Vorwasch- oder Vorspülzone wird das Geschirr mit einem niederalkalischen Reinigungsverstärker besprüht und im Hauptwaschzyklus erfolgt die Reinigung mit einem üblichen Reinigungsmittel.Finally, a generic method is known from DE-A-4 110 764. Here, in a kind of pre-wash or pre-wash zone, a mechanical pre-cleaning of the dishes from coarse impurities and a spraying of the dishes with a concentrated surfactant solution and subsequent action of the concentrated surfactant solution in a commercial dishwasher carried out. These process steps can also be carried out in a separate work station before the actual dishwasher. The concentrated surfactant solution is slightly acidic to weakly alkaline and contains carbohydrate-degrading enzyme, especially amylase. The exposure time is 10 to 90 seconds, which is within the usual contact times between cleaning agents and dishes in commercial dishwashing processes. Only then is the final cleaning of the dishes carried out in a manner known per se in the main washing cycle proper, using conventional cleaning steps, including rinsing, with conventional cleaning agents which are compatible with the surfactants of the concentrated surfactant solution. Similar to the household dishwashing process according to DE-A-1 285 087, the use and metering of enzyme-containing agents in the actual main wash cycle or main wash cycle is also avoided in this process. In the pre-wash or pre-wash zone, the dishes are sprayed with a low-alkaline cleaning booster and in the main wash cycle they are cleaned with a conventional cleaning agent.

Ein Verfahren zur maschinellen Geschirreinigung in gewerblichen Geschirrspülmaschinen, bei welchem ein Reinigungsmittel und ein dieses in der Wirkung unterstützender weiterer Wirkstoff der Spül- oder Waschflotte zudosiert werden sowie eine Vorrichtung zum Durchführen des Verfahrens, welche ein Reinigungsmittel-Dosiersystem und ein Dosiersystem für einen weiteren Wirkstoff mit zugeordneter Pumpe und Pumpensteuerung aufweist, sind aus der DE-A-39 20 728 bekannt. Bei diesem bekannten Verfahren zur maschinellen Geschirreinigung in gewerblichen Geschirrspülmaschinen wird zusätzlich zu dem Reinigungsmittel als dieses in seiner Wirkung unterstützender weiterer Wirkstoff Aktivsauerstoff in den Dosier- bzw. Waschtank der Geschirrspülmaschine eindosiert. Zur Aufrechterhaltung der Sauerstoffkonzentration im Waschtank bei Unterbrechungen des Spülzyklus wird während der Unterbrechungen Aktivsauerstoff in den Waschtank nachdosiert.A method for machine dishwashing in commercial dishwashers, in which a detergent and a further active ingredient that supports its action are metered into the washing or washing liquor, and a device for carrying out the method, which includes a detergent dosing system and a dosing system for another active ingredient assigned pump and pump control are known from DE-A-39 20 728. In this known method for machine dishwashing in commercial dishwashers, in addition to the cleaning agent, active oxygen is metered into the metering or washing tank of the dishwasher as this further active ingredient which supports its action. In order to maintain the oxygen concentration in the wash tank when the rinsing cycle is interrupted, active oxygen is replenished into the wash tank during the interruptions.

Ein Verfahren und eine Vorrichtung zur maschinellen Geschirreinigung bei gewerblichen Geschirrspülmaschinen, bei welchen mittels eines Reinigungsmittel-Dosiersystems und eines Dosiersystems für einen weiteren Wirkstoff mit zugeordneter Pumpe und Pumpensteuerung der Waschflotte einer Geschirrspülmaschine die beiden verschiedenen Wirkstoffe, nämlich Reinigungsmittel und beispielsweise ein Bleichmittel, zudosiert werden, ist weiterhin aus der US-A-3,490,467 bekann.A method and an apparatus for machine dishwashing in commercial dishwashers, in which the two different active ingredients, namely cleaning agents and, for example, a bleaching agent, are added to the washing liquor of a dishwasher by means of a detergent dosing system and a dosing system for a further active ingredient with an associated pump and pump control. is also known from US-A-3,490,467.

Aufgabe der Erfindung ist es, eine Lösung zu schaffen, die beim maschinellen Geschirreinigen in gewerblichen Geschirrspülmaschinen die Bildung eines Stärkebelages auf dem Geschirr nachhaltig unterbindet.The object of the invention is to provide a solution which prevents the formation of a starch coating on the dishes during machine dishwashing in commercial dishwashers.

Bei einem Verfahren der eingangs bezeichneten Art wird diese Aufgabe gemäß der Erfindung dadurch gelöst, daß der Reinigungsverstärker als Bestandteil des, insbesondere auf Basis Phosphat oder Nitriloessigsäure oder deren Salze (NTA) formulierten, niederalkalischen Reinigungsmittels und/oder zusätzlich in Kombination zum niederalkalischen Reinigungsmittel der Spül- oder Waschflotte dem zumindests einen Spül- oder Waschtank der Geschirrspülmaschine zudosiert wird.In a method of the type mentioned at the outset, this object is achieved according to the invention in that the cleaning booster is part of the low-alkaline cleaning agent formulated, in particular based on phosphate or nitriloacetic acid or its salts (NTA), and / or additionally in combination with the lower-alkaline cleaning agent, the rinsing - or washing liquor to which at least one rinsing or washing tank of the dishwasher is added.

Überraschenderweise hat sich gezeigt, daß ein niederalkalischer Reiniger in üblicher Konzentration in Verbindung mit Enzym oder einem enzymhaltigen Reinigungsverstärker auch bei den in gewerblichen Geschirrspülmaschinen üblichen kurzen Kontaktzeiten von 10 bis 180 Sekunden zu einer ausgezeichneten Entfernung und Inhibierung des Stärkeaufbaus auf dem Geschirr führt. Gegenüber bekannten gewerblichen Geschirrspülverfahren, bei denen mit hochalkalischem Reiniger oder einer hochkonzentrierten, alkalischen Waschflotte gearbeitet wird, zeichnet sich das erfindungsgemäße Verfahren durch eine erhebliche Verbesserung der Betriebs- bzw. Anwendungssicherheit aus. Eine Gefährdung des Betriebspersonals durch von hochalkalischem Reiniger oder Waschflotte verursachte Ätzverletzungen besteht nicht mehr.Surprisingly, it has been shown that a low-alkaline cleaner in the usual concentration in combination with enzyme or an enzyme-containing cleaning booster leads to excellent removal and inhibition of the starch build-up on the dishes, even with the short contact times of 10 to 180 seconds customary in commercial dishwashers. Compared to known commercial dishwashing processes in which a highly alkaline cleaner or a highly concentrated, alkaline washing liquor is used, the process according to the invention is distinguished by a considerable improvement in operational and application safety. There is no longer any danger to operating personnel from etching injuries caused by highly alkaline cleaners or wash liquors.

Der niederalkalische Reiniger kann gegebenenfalls auch andere als die aufgeführten Komplexbildner enthalten, soweit dies gewünscht wird.The lower-alkaline cleaner may also contain complexing agents other than those listed, if so desired.

Zweckmäßigerweise wird gemäß Ausgestaltung der Erfindung in der Spül- oder Waschflotte eine Konzentration von 0,5 bis 15 g/l an niederalkalischem Reinigungsmittel eingestellt.According to an embodiment of the invention, a concentration of 0.5 to 15 g / l of low-alkaline cleaning agent is expediently set in the rinsing or washing liquor.

Von Vorteil ist es weiterhin, wenn das niederalkalische Reinigungsmittel in Anwendungskonzentration mit einem pH-Wert von 7 bis 11, vorzugsweise 9,1 bis 10,8, eindosiert wird, was die Erfindung ebenfalls vorsieht.It is furthermore advantageous if the low-alkaline cleaning agent is metered in in use concentration with a pH of 7 to 11, preferably 9.1 to 10.8, which is also provided by the invention.

Zweckmäßigerweise wird in der Spül- oder Waschflotte eine Konzentration von 0,05 bis 2 g/l an Reinigungsverstärker gemäß weiterer Ausgestaltung der Erfindung eingestellt.A concentration of 0.05 to 2 g / l of cleaning enhancer is expediently set in the rinsing or washing liquor according to a further embodiment of the invention.

In Weiterbildung sieht die Erfindung vor, daß der enzymhaltige Reinigungsverstärker während des regelmäßigen Geschirrspülmaschinenbetriebes mit üblicher Reinigerkonzentration in der Spül- oder Waschflotte von 0,5 bis 8 g/l und/oder während einer periodischen Grundreinigung mit erhöhter Reinigerkonzentration in der Spül- oder Waschflotte von 3 bis 15 g/l in die Spül- oder Waschflotte eindosiert wird.In a further development, the invention provides that the enzyme-containing cleaning booster during normal dishwasher operation with a normal cleaning concentration in the washing or washing liquor of 0.5 to 8 g / l and / or during a periodic basic cleaning with an increased cleaning concentration in the washing or washing liquor of 3 to 15 g / l is metered into the rinsing or washing liquor.

Da Enzyme in der Spül- oder Waschflotte einer gewerblichen Geschirrspülmaschine in Anwesenheit von Reinigungsmitteln nicht stabil sind, sieht die Erfindung in Ausgestaltung vor, daß der Reinigungsverstärker im Maße des Enzymabbaues nachdosiert wird.Since enzymes in the washing or washing liquor of a commercial dishwasher are not stable in the presence of cleaning agents, the invention provides in one embodiment that the cleaning booster is replenished to the extent of the enzyme breakdown.

Weiterhin ist der Enzymabbau bzw. der Enzymzerfall (Zehrung) in Stillstandsphasen des Geschirrspülmaschinenbetriebes geringer als während der Spülphasen, so daß die Erfindung in zweckmäßiger Weiterbildung vorsieht, daß die Nachdosierung in Stillstandsphasen gering ist im Vergleich zu Spülphasen.Furthermore, the enzyme breakdown or the enzyme decay (consumption) in standstill phases of the dishwasher operation is lower than during the wash phases, so that the invention provides in an expedient development that the replenishment in standstill phases is low in comparison to wash phases.

Der enzymhaltige Reinigungsverstärker kann wie übliche Reinigungsmittel entweder in den zumindest einen Dosier- oder Waschtank der Geschirrspülmaschine eindosiert, aber auch in die die Nachspülleitung und/oder das Sprühsystem der gewerblichen Geschirrspülmaschine durchfließende Flüssigkeit eindosiert und auf diese Weise der Geschirrspülmaschine zugeführt werden. Die Erfindung sieht daher als Weiterbildung vor, daß Reinigungsmittel und Reinigungsverstärker separat in die Spül- oder Waschflotte eindosiert werden.The enzyme-containing cleaning booster, like conventional cleaning agents, can either be metered into the at least one dosing or washing tank of the dishwasher, but also into the liquid flowing through the rinse line and / or the spray system of the commercial dishwasher, and in this way fed to the dishwasher. The invention therefore provides as a further development that detergents and cleaning boosters are metered separately into the washing or washing liquor.

Von Vorteil ist es gemäß Weiterbildung der Erfindung weiterhin, daß der enzymhaltige Reinigungsmittelverstärker parallel oder nachträglich zum niederalkalischen Reinigungsmittel in die Spül- oder Waschflotte eindosiert wird.According to a further development of the invention, it is also advantageous that the enzyme-containing detergent booster is metered into the rinsing or washing liquor in parallel or subsequently to the lower-alkaline detergent.

Als besonders vorteilhaft hat es sich gezeigt, wenn ein Reinigungsverstärker eindosiert wird, der etwa 0,01 bis 0,6 Gew.-%, vorzugsweise 0,45 bis 0,55 Gew.-%, Enzym, insbesondere Amylase, sowie 10 bis 25 Gew.-%, vorzugsweise 15 bis 20 Gew.-%, Propylenglykol, insbesondere Propylenglykol-1,2, und eine entsprechende Menge Wasser enthält, wie dies die Erfindung in Ausgestaltung vorsieht.It has proven to be particularly advantageous if a cleaning booster is metered in, which contains about 0.01 to 0.6% by weight, preferably 0.45 to 0.55% by weight, of enzyme, in particular amylase, and 10 to 25 % By weight, preferably 15 to 20% by weight, of propylene glycol, in particular 1,2-propylene glycol, and a corresponding amount of water, as provided by the invention in one embodiment.

Der Reinigungsverstärker kann als Enzym Amylase, Lipase, Protease oder andere, insbesondere kohlenhydratabbauende, Enzyme, entweder einzeln oder in geeigneten Mischungen enthalten.The cleaning enhancer can contain as an enzyme amylase, lipase, protease or other, in particular carbohydrate-degrading, enzymes, either individually or in suitable mixtures.

Es ist möglich, daß ein enzymfreies, flüssiges oder pulverförmiges, niederalkalisches Reinigungsmittel in Kombination mit enzymhaltigem Reinigungsverstärker verwendet wird. Für diesen Fall sieht die Erfindung in Ausgestaltung vor, daß während Reinigerdosierzeiten in die Spül- oder Waschflotte ein enzymfreies, insbesondere flüssiges, niederalkalisches Reinigungsmittel und im Maße des Reinigerverbrauches in Paralleldosierung der enzymhaltige Reinigungsverstärker eindosiert wird. Im Unterschied zum nachstehend aufgeführten Fall der Kombination von enzymhaltigem Reinigungsmittel mit enzymhaltigem Reinigungsverstärker, wird im Falle der Kombination von enzymfreiem Reinigungsmittel mit enzymhaltigem Reinigungsverstärker auch während der Dosierung bzw. der Dosierzeiten von Reinigungsmittel parallel zum Reinigungsmittel enzymhaltiger Reinigungsverstärker in den zumindest einen Dosier- oder Waschtank der gewerblichen Geschirrspülmaschine eindosiert.It is possible that an enzyme-free, liquid or powdery, low-alkaline cleaning agent is used in combination with an enzyme-containing cleaning booster. In this case, the invention provides in one embodiment that an enzyme-free, in particular liquid, low-alkaline cleaning agent is metered into the rinsing or washing liquor during detergent dosing times, and the enzyme-containing cleaning booster is metered in parallel to the extent of the detergent consumption. In contrast to the case below of combining enzyme-containing cleaning agents with enzyme-containing cleaning agents, in the case of combining enzyme-free cleaning agents with enzyme-containing cleaning enhancers, even during the metering or dosing times of cleaning agents, metered into the at least one metering or washing tank of the commercial dishwasher parallel to the cleaning agent enzyme-containing cleaning enhancer.

Es ist aber auch möglich, daß in das flüssige oder pulverförmige niederalkalische Reinigungsmittel bereits Enzym eingearbeitet ist. Insbesondere in einen pulverförmigen, niederalkalischen Reiniger kann ein fester Enzymträger, beispielsweise Amylaseträger, eingearbeitet sein. Dieses enzymhaltige Reinigungsmittel wird dann in Kombination mit dem enzymhaltigen Reinigungsverstärker verwendet. Für diesen Fall sieht die Erfindung in Ausgestaltung vor, daß während Reinigerdosierzeiten in die Spül- oder Waschflotte ein Enzym zum sofortigen Spülen an sich in ausreichender Menge enthaltendes, insbesondere pulverförmiges, niederalkalisches Reinigungsmittel und unmittelbar nach Beendigung oder während Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder Dosierpausen des Reinigungsmittels der enzymhaltige Reinigungsverstärker in die Spül- oder Waschflotte eindosiert wird. In diesem Fall wird der enzymhaltige Reinigungsverstärker also nur während oder unmittelbar nach Beendigung der Dosierpausen des Reinigungsmittels und/oder der Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes in die Spül- oder Waschflotte eindosiert. Während der Zeiten des aktiven Spülzyklus, während welcher das Reinigungsmittel in den Waschtank der Geschirrspülmaschine eindosiert wird, erfolgt keine Dosierung des enzymhaltigen Reinigungsverstärkers.However, it is also possible that enzyme is already incorporated into the liquid or powdered low-alkaline cleaning agent. In particular, a solid enzyme carrier, for example amylase carrier, can be incorporated into a powdery, low-alkaline cleaner. This enzyme-containing cleaning agent is then used in combination with the enzyme-containing cleaning enhancer. In this case, the invention provides in an embodiment that during detergent dosing times in the rinsing or washing liquor, an enzyme for immediate rinsing containing a sufficient amount, in particular powdery, low-alkaline cleaning agent and immediately after completion or during interruptions or downtimes of the dishwasher operation and / or Dosing pauses of the cleaning agent, the enzyme-containing cleaning booster is metered into the rinsing or washing liquor. In this case, the enzyme-containing cleaning booster is therefore only metered into the washing or washing liquor during or immediately after the dosing pauses of the cleaning agent and / or the interruptions or downtimes of the dishwasher operation. During the times of the active rinsing cycle, during which the detergent is dosed into the washing tank of the dishwasher, the enzyme-containing cleaning booster is not dosed.

Hierbei ist es zweckmäßig, daß der enzymhaltige Reinigungsverstärker im Maße des Enzymabbaus bzw. Enzymzerfalls (Zehrung) zur Aufrechterhaltung der Enzymkonzentration in die Spül- oder Waschflotte eindosiert wird, was die Erfindung weiterhin vorsieht.It is expedient here that the enzyme-containing cleaning enhancer is metered into the rinsing or washing liquor to maintain the enzyme concentration to the extent of the enzyme breakdown or enzyme decay (consumption), which the invention further provides.

Es ist bekannt, daß Enzyme, wie Amylase, Lipase oder Protease, in der Waschflotte von gewerblichen Geschirrspülmaschinen nicht stabil sind. Nach dem Einspülen in den Waschtank einer gewerblichen Geschirrspülmaschine verlieren enzymhaltige Reinigungsmittel oder Reinigungsverstärker relativ schnell ihre Wirkung. Im Falle von Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder Dosierpausen des Reinigungsmittels oder des Reinigungsverstärkers tritt ein Enzymabbau oder Enzymzerfall (Zehrung) ein, bei dem der Enzymgehalt in der Spül- bzw. Waschflotte häufig mit etwa 40 bis 60 % pro Stunde abfällt. Je nach Grad der Zehrung kann aber z. B. auch schon nach einer halbstündigen Unterbrechung des Maschinenbetriebes der Enzymgehalt auf weit unter die Hälfte abgefallen sein. Um sicherzustellen, daß nach einer Unterbrechung oder Stillstandsphase des Geschirrspülmaschinenbetriebes und/oder einer Dosierpause des Reinigungsmittels oder des Reinigungsverstärkers wieder eine zur Erzielung einer befriedigenden Reinigungsleistung ausreichende Enzymkonzentration in der Waschflotte vorhanden ist, sieht die Erfindung in Ausgestaltung vor, daß der unter Spülbedingungen in einer gewerblichen Geschirrspülmaschine einem Enzymabbau bzw. Enzymzerfall (Zehrung) unterliegende enzymhaltige Reinigungsverstärker im Falle von Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder Dosierpausen des Reinigungsmittels oder des Reinigungsverstärkers in die Spül- oder Waschflotte in einer Menge nachdosiert wird, die den während der jeweiligen Unterbrechung oder Stillstandsphase und/oder Dosierpause auftretenden Enzymabbau oder Enzymzerfall (Zehrung) ausgleicht, so daß nach Beendigung der jeweiligen Unterbrechung oder Stillstandsphase und/oder Dosierpause der Maschinenbetrieb mit im wesentlichen gleicher Enzymkonzentration in der Spül- oder Waschflotte wie vor der jeweiligen Unterbrechung oder Stillstandsphase und/oder Dosierpause fortgesetzt wird. Hierdurch ist sichergestellt, daß bei jeder aktiven Reinigungsphase des Spülzyklus in einer gewerblichen Geschirrspülmaschine eine zur Erzielung des gewünschten Reinigungsergebnisses (Verhinderung des Aufbaues oder Entfernung des Stärkebelages auf dem Geschirr) ausreichend hohe Enzymkonzentration in der Waschflotte vorhanden ist.It is known that enzymes such as amylase, lipase or protease are not stable in the washing liquor of commercial dishwashers. After being washed into the wash tank of a commercial dishwasher Enzyme-containing cleaning agents or cleaning boosters lose their effect relatively quickly. In the event of interruptions or downtimes in the operation of the dishwasher and / or dosing of the cleaning agent or cleaning booster, enzyme degradation or enzyme breakdown (consumption) occurs, in which the enzyme content in the washing or washing liquor often drops at around 40 to 60% per hour. Depending on the degree of consumption, z. B. even after a half-hour break in machine operation, the enzyme content dropped to well below half. In order to ensure that after an interruption or standstill phase of the dishwasher operation and / or a dosing pause of the cleaning agent or the cleaning booster, an enzyme concentration sufficient to achieve a satisfactory cleaning performance is again present in the wash liquor, the invention provides in one embodiment that the washing under conditions in a commercial Dishwasher undergoing enzyme degradation or enzyme decay (consumption) enzyme-containing cleaning enhancers in the event of interruptions or downtimes in the dishwasher operation and / or dosing intervals of the cleaning agent or cleaning enhancer in the washing or washing liquor in an amount that is added during the respective interruption or downtime phase and / or dosing breakdown occurring enzyme breakdown or enzyme breakdown (consumption) compensates so that after the end of the respective interruption or standstill phase and / or Do the machine operation is continued with essentially the same enzyme concentration in the rinsing or washing liquor as before the respective interruption or standstill phase and / or dosing break. This ensures that with each active cleaning phase of the washing cycle in a commercial dishwasher there is a sufficiently high enzyme concentration in the wash liquor to achieve the desired cleaning result (prevention of the build-up or removal of the starch deposit on the dishes).

In Ausgestaltung sieht die Erfindung vor, daß unmittelbar nach Beendigung oder während der Unterbrechungen oder Stillstandsphasen und/oder der Dosierpausen des Reinigungsmittels im Maße des Enzymabbaues bzw. Enzymzerfalls (Zehrung) der enzymhaltige Reinigungsverstärker zur Aufrechterhaltung der Enzymkonzentration in die Spül- oder Waschflotte nachdosiert wird.In an embodiment, the invention provides that the enzyme-containing cleaning enhancer is added to the rinsing or washing liquor to maintain the enzyme concentration immediately after completion or during the interruptions or standstill phases and / or the dosing pauses of the detergent to the extent of the enzyme breakdown or enzyme decay (consumption).

Für die Ein- bzw. Nachdosierung des enzymhaltigen Reinigungsverstärkers sieht die Erfindung zwei Alternativen vor. Einmal kann die Ein- bzw. Nachdosierung des enzymhaltigen Reinigungsverstärkers während der Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder Dosierpausen des Reinigungsmittels erfolgen und einmal kann die Ein- bzw. Nachdosierung des enzymhaltigen Reinigungsverstärkers unmittelbar nach Beendigung der Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder der Dosierpausen des Reinigungsmittels erfolgen.The invention provides two alternatives for the metering-in or metering-in of the enzyme-containing cleaning booster. On the one hand, the enzyme-containing cleaning booster can be dosed or re-dosed during the interruptions or standstill phases of the dishwasher operation and / or dosing pauses of the cleaning agent, and on the other hand the dosing or re-dosing of the enzyme-containing cleaning booster can be carried out immediately after the interruptions or downtime phases of the dishwasher operation and / or Dosing intervals of the cleaning agent take place.

In der ersten Alternative sieht die Erfindung in weiterer Ausgestaltung vor, daß die Enzymkonzentration in der Spül- oder Naschflotte während der jeweiligen Unterbrechung oder Stillstandsphase und/oder während der Dosierpausen des Reinigungsmittels durch eine Unterhaltsdosierung des enzymhaltigen Reinigungsverstärkers aufrechterhalten wird. Von Vorteil ist es hierbei, wenn die Unterhaltsdosierung in einzelnen Dosierhüben erfolgt, wie dies die Erfindung in Weiterbildung vorsieht.In the first alternative, the invention provides in a further embodiment that the enzyme concentration in the rinsing or snacking liquor is maintained during the respective interruption or standstill phase and / or during the dosing pauses of the cleaning agent by maintenance dosing of the enzyme-containing cleaning booster. It is advantageous here if the maintenance dosing takes place in individual dosing strokes, as the invention provides in a further development.

Bei dieser ersten Alternative zielt die Ausgestaltung demgemäß in erster Linie auf eine Unterhaltsdosierung des enzymhaltigen Reinigungsverstärkers in den Stillstandszeiten der Geschirrspülmaschine zwischen jeweils zwei aufeinanderfolgenden Spülphasen oder während der Dosierpausen zwischen zwei Dosierzeiten des Reinigungsmittels ab. Durch die Unterhaltsdosierung wird erreicht, daß im Maße des Enzymabbaues bzw. Enzymzerfalls (Zehrung) neuer, enzymhaltiger Reinigungsverstärker in den zumindest einen Dosier- oder Waschtank gelangt. Der Waschtank bzw. die Waschflotte der Geschirrspülmaschine wird somit ständig in Bereitschaft für eine neue Spülphase gehalten. Zu Beginn einer jeden Spülphase steht sofort mit Enzymen ausreichend versetzte bzw. eine ausreichend hohe Enzymkonzentration aufweisende Waschflotte zur Verfügung. Bei Einsatz von Enzym zum sofortigen Spülen an sich in ausreichender Menge enthaltendem, insbesondere pulverförmigem, Reiniger wird der enzymhaltige Reinigungsverstärker nur während der Stillstandsphasen bzw. Dosierpausen des Reinigungsmittels im Maße des Enzymzerfalls in den zumindest einen Waschtank nachdosiert. Bei Verwendung eines enzymfreien Reinigungsmittels, insbesondere eines Flüssigreinigers, erfolgt neben der Unterhaltsdosierung während der Dosierzeiten für das Reinigungsmittel eine Paralleldosierung des enzymhaltigen Reinigungsverstärkers. Es wird also bei Einsatz des enzymfreien Reinigungsmittels während der Spülphasen Enzym im Maße des Reinigerverbrauches und während der Stillstandsphasen bzw. der Reiniger-Dosierpausen im Maße des Enzymabbaues bzw. Enzymzerfalls enzymhaltiger Reinigerverstärker in den Waschtank bzw. die Spül- oder Waschflotte dosiert. Die Paralleldosierung ermöglicht den Einsatz von enzymhaltigem Reinigungsverstärker wie z. B. Amylaselösung, die mit den üblichen enzymfreien alkalischen, insbesondere niederalkalischen, Reinigungsmitteln nicht formulierbar sind. Während der Spülphasen erfolgt das Eindosieren von flüssigem bzw. pulverförmigem Reinigungsmittel in Abhängigkeit von der gemessenen Leitfähigkeit oder dem gemessenen pH-Wert oder zeitgesteuert nur während bestimmter Dosierzeiten. Wenn die entsprechenden Zwischenzeiten bzw. Reiniger-Dosierpausen so lang werden, daß eine die Reinigungsleistung der nächsten Spülphase beeinträchtigende Menge an Enzym zerfallen ist, liegt es im Rahmen der Erfindung, auch in während der Spülphase eintretenden Zwischen- bzw. Regelpausen der Paralleldosierung dem Maße des Enzymzerfalls entsprechend enzymhaltigen Reinigungsverstärker, ebenfalls als Unterhaltsdosierung, nachzudosieren.In the case of this first alternative, the embodiment accordingly aims primarily at maintenance dosing of the enzyme-containing cleaning booster in the downtimes of the dishwasher between two successive washing phases or during the dosing pauses between two dosing times of the cleaning agent. The maintenance dosing ensures that in the extent of the enzyme breakdown or enzyme decay (consumption) new, enzyme-containing cleaning boosters in the at least one dosing or Wash tank arrives. The washing tank or the washing liquor of the dishwasher is thus always ready for a new washing phase. At the beginning of each rinsing phase, a wash liquor which has been sufficiently admixed with enzymes or has a sufficiently high enzyme concentration is immediately available. If enzyme is used for immediate rinsing of a detergent containing itself, in particular in powder form, in sufficient quantities, the enzyme-containing cleaning booster is replenished into the at least one wash tank only during the standstill phases or dosing pauses of the detergent to the extent of the enzyme breakdown. If an enzyme-free cleaning agent, in particular a liquid cleaner, is used, in addition to maintenance dosing during the dosing times for the cleaning agent, the enzyme-containing cleaning booster is dosed in parallel. When the enzyme-free cleaning agent is used, enzyme is metered into the wash tank or the rinsing or washing liquor during the rinsing phases of the amount of detergent used and during the standstill phases or the detergent dosing breaks to the extent of the enzyme breakdown or enzyme breakdown. The parallel dosing enables the use of enzyme-containing cleaning boosters such as B. amylase solution that cannot be formulated with the usual enzyme-free alkaline, in particular lower-alkaline, cleaning agents. During the rinsing phase, liquid or powder detergents are metered in depending on the measured conductivity or the measured pH value or time-controlled only during certain metering times. If the corresponding intermediate times or detergent dosing breaks become so long that an amount of enzyme which has an adverse effect on the cleaning performance of the next rinsing phase has broken down, it is within the scope of the invention, also in the intermediate or control pauses of the parallel dosing occurring during the rinsing phase, to the extent of Enzyme digestion in accordance with enzyme-containing cleaning enhancers, also as maintenance dosing.

Für die Unterhaltsdosierung kann es zweckmäßig sein, wenn die Enzym-Förderleistung der Unterhaltsdosierung anhand einer Enzymaktivitätsbestimmung optimiert wird, wie dies die Erfindung weiterhin vorsieht. Nach Kenntnis der Zerfallsrate der Enzyme kann es genügen, wenn in gewissen zeitlichen Abständen enzymhaltiger Reinigungsverstärker nachdosiert wird.For maintenance dosing, it can be expedient if the enzyme delivery rate of the maintenance dosing is optimized on the basis of an enzyme activity determination, as is further provided by the invention. After knowing the rate of decay of the enzymes, it may be sufficient to add detergent enhancers at certain intervals.

In diesem Zusammenhang sieht die Erfindung weiterhin vor, daß jeweils nach Zerfall von etwa 20 % des ursprünglichen Enzymgehaltes in der Spül- oder Waschflotte mit der Unterhaltsdosierung des enzymhaltigen Reinigungsverstärkers begonnen wird.In this context, the invention further provides that the maintenance dosage of the enzyme-containing cleaning booster is started after each disintegration of about 20% of the original enzyme content in the rinsing or washing liquor.

Die andere der beiden vorstehend erläuterten Alternativen besteht gemäß Ausgestaltung der Erfindung darin, daß unmittelbar nach Beendigung der jeweiligen Unterbrechung oder Stillstandsphase und/oder Dosierpause eine Stoßdosierung erfolgt, in der eine Menge an enzymhaltigem Reinigungsverstärker der Spül- oder Waschflotte zugeführt wird, die dem während der Dauer der jeweiligen Unterbrechung oder Stillstandsphase und/oder Dosierpause erfolgten Enzymabbau bzw. Enzymzerfall (Zehrung) entspricht. Bei dieser Alternative erfolgt also nach Beendigung der Unterbrechung oder Stillstandsphase des Geschirrspülmaschinenbetriebes und/oder der Beendigung einer Reinigungsmittel-Dosierpause eine Stoßdosierung des enzymhaltigen Reinigungsverstärkers, wobei die bei der Stoßdosierung zugeführte Menge an enzymhaltigem Reinigungsverstärker der Dauer der Unterbrechung angepaßt und so bemessen ist, daß sie den während der Unterbrechung erfolgten Enzymabbau bzw. Enzymzerfall (Zehrung) ausgleicht. Während der Unterbrechung bzw. Stillstandsphase des Maschinenbetriebes und/oder der Reinigungsmittel-Dosierpause wird demnach kein enzymhaltiger Reinigungsverstärker dem zumindest einen Dosier- oder Waschtank oder der Spül- oder Waschflotte der Geschirrspülmaschine zugeführt. Die Zufuhr an enzymhaltigem Reinigungsverstärker erfolgt erst nach Beendigung der jeweiligen Unterbrechung oder Dosierpause innerhalb einer relativ kurzen Zeit, so daß diejenige Enzymmenge, die bei der jeweiligen Unterbrechung oder Dosierpause verzehrt worden ist, ersetzt wird. Die Bemessung der Menge des bei der Stoßdosierung zugesetzten Reinigungsverstärkers erfolgt in Abhängigkeit von der Dauer der Unterbrechung und/oder Dosierpause sowie in Abhängigkeit vom durch eine mathematische Funktion, beispielsweise einer e-Funktion, beschreibbaren Verlauf des Enzymzerfalls. Dadurch wird sichergestellt, daß verzehrtes Enzym ziemlich genau ersetzt wird, ohne daß eine wesentliche Unterdosierung oder Überdosierung erfolgt.The other of the two alternatives explained above, according to one embodiment of the invention, is that a surge dose is carried out immediately after the end of the respective interruption or standstill phase and / or dosing pause, in which a quantity of enzyme-containing cleaning booster is added to the rinsing or washing liquor, which during the The duration of the respective interruption or standstill phase and / or dosing break corresponds to enzyme degradation or enzyme breakdown (consumption). In this alternative, after the end of the interruption or standstill phase of the dishwasher operation and / or after the end of a detergent dosing break, the enzyme-containing cleaning booster is dosed, the amount of enzyme-containing cleaning booster added during the dosing being adapted to the duration of the interruption and dimensioned such that it compensates for the enzyme breakdown or decay (consumption) that occurred during the interruption. Accordingly, during the interruption or standstill phase of the machine operation and / or the detergent dosing break, no enzyme-containing cleaning booster is fed to the at least one dosing or wash tank or the washing or washing liquor of the dishwasher. The enzyme-containing cleaning booster is supplied only after the interruption or dosing break has ended within a relatively short time, so that the amount of enzyme which was consumed during the interruption or dosing break is replaced. The measurement of the amount of the cleaning booster added during the batch dosing is carried out as a function of the duration of the interruption and / or dosing pause and as a function of the course of the enzyme decay which can be described by a mathematical function, for example an e-function. This ensures that the enzyme consumed is replaced fairly accurately without substantial underdosing or overdosing.

Zur Erzielung einer genau bemessenen, bedarfgerechten Dosierung wird gemäß einer bevorzugten weiteren Ausgestaltung der Erfindung berücksichtigt, daß der zeitliche Verlauf der Enzymzehrung im wesentlichen einer Exponentialfunktion folgt, wobei die Konzentration, ausgehend von einer Anfangskonzentration, exponentiell abnimmt. Eine praxisgerechte Stoßdosierung nach einer Pausenzeit t muß folglich der Komplementärfunktion des Verlaufes der Enzymzehrung folgen.In order to achieve a precisely measured, needs-based dosage, it is taken into account according to a preferred further embodiment of the invention that the time course of enzyme consumption essentially follows an exponential function, the concentration decreasing exponentially starting from an initial concentration. A practice-oriented pulse dosage after a pause t must consequently follow the complementary function of the course of the enzyme consumption.

Auch bei der Stoßdosierung ist es ebenso wie bei der Unterhaltsdosierung möglich, daß während der Reinigungsmittel-Dosierzeiten in Paralleldosierung der enzymhaltige Reinigungsverstärker zudosiert wird, wenn ein enzymfreies Reinigungsmittel Verwendung findet.In the case of surge dosing as well as maintenance dosing, it is possible for the enzyme-containing cleaning booster to be metered in during the dosing times in parallel, if an enzyme-free cleaning agent is used.

Bei einer Vorrichtung der eingangs bezeichneten Art zum Durchführen des Verfahrens wird die Aufgabe gemäß der Erfindung gelöst durch ein vom Reinigungsmittel-Dosiersystem getrenntes Dosiersystem zur Dosierung eines enzymhaltigen Reinigungsverstärkers, welches einen Betriebszustand zur Unterhaltsdosierung während Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder Dosierpausen des Reinigungsmittel-Dosiersystems und/oder einen Betriebszustand zur Stoßdosierung nach Beendigung von Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder Dosierpausen des Reingiungsmittel-Dosiersystems aufweist.In a device of the type mentioned at the outset for carrying out the method, the object is achieved according to the invention by a metering system for metering an enzyme-containing cleaning amplifier which is separate from the detergent metering system and which has an operating state for maintenance metering during interruptions or downtimes of the dishwasher operation and / or metering pauses of the detergent. Dosing system and / or an operating state for batch dosing after interruptions or standstill phases of the dishwasher operation and / or dosing pauses of the detergent dosing system.

Die erfindungsgemäße Vorrichtung zum Durchführen des Verfahrens ist grundsätzlich gekennzeichnet durch ein vom Reinigungsmittel-Dosiersystem getrenntes Dosiersystem für den enzymhaltigen Reinigungsverstärker, wobei letzteres einen Betriebszustand zur Unterhaltsdosierung und/oder einen Betriebszustand zur Stoßdosierung aufweist. Das Reinigungsmittel-Dosiersystem kann in üblicher Weise ausgebildet sein, z. B. als Dosierpumpe bei einem Flüssigreiniger oder als Frischwasser- oder Flotteneinspülung bei einem Pulverreiniger. Hinzu kommt erfindungsgemäß also im wesentlichen nur das vom Reinigungsmittel-Dosiersystem getrennte bzw. gesonderte Dosiersystem für den enzymhaltigen Reinigungsverstärker. Dieses besitzt entweder einen Betriebszustand zur Unterhaltsdosierung oder einen Betriebszustand zur Stoßdosierung und ist mit den für den jeweiligen Betriebszustand notwendigen technischen Einrichtungen versehen. Neben dieser Ausführungsform, bei welcher das Reinigungsverstärker-Dosiersystem entweder nur technische Einrichtungen für den Betriebszustand Unterhaltsdosierung oder technische Einrichtungen für den Betriebszustand Stoßdosierung aufweist, ist es aber auch möglich, das Reinigungsverstärker-Dosiersystem mit technischen Einrichtungen für beide Betriebszustände auszustatten, so daß vom Bedienungspersonal der jeweils gewünschte Betriebszustand frei anwählbar ist. Die Vorrichtung ermöglicht somit eine Unterhaltsdosierung während der Unterbrechungen bzw. Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder der Reinigungsmittel-Dosierpausen oder eine Stoßdosierung unmittelbar nach Beendigung von Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes und/oder Reinigungsmittel-Dosierpausen, so daß eine durch Enzymabbau bzw. -zerfall bedingte Zehrung der Enzymaktivität während dieser Zeit ausgeglichen wird. Eine derartige Nach- oder Zusatzdosierung ist erforderlich, wenn die Reinigungsmittelversorgung der gewerblichen Geschirrspülmaschine wie üblich über eine den Enzymgehalt in der Waschflotte nicht berücksichtigende Regelung erfolgt. Im Gegensatz zum Enzymgehalt bleibt nämlich die Reinigungsmittelkonzentration in der Waschflotte während der Unterbrechungen oder Stillstandsphasen der Geschirrspülmaschine im wesentlichen konstant. Ohne das Nachdosieren von Enzym würde bei Beginn eines erneuten Spülzylkuses ansonsten üblicherweise nur Reinigungsmittel entsprechend dem Frischwasserzulauf in den zumindest einen Dosier- oder Waschtank oder die Spül- oder Waschflotte der Geschirrspülmaschine eindosiert werden. Es ergäbe sich dann ein Defizit an Enzymgehalt und damit ein zumindest im Hinblick auf Stärkeanschmutzungen unbefriedigendes Spülergebnis. Dieses Problem wird durch die erfindungsgemäße Vorrichtung überwunden.The device according to the invention for carrying out the method is fundamentally characterized by a metering system for the enzyme-containing cleaning booster, which is separate from the detergent dosing system, the latter having an operating state for maintenance dosing and / or an operating state for impact dosing. The detergent dosing system can be designed in a conventional manner, for. B. as a metering pump in a liquid cleaner or as fresh water or liquor in a powder cleaner. In addition, according to the invention there is essentially only the dosing system for the enzyme-containing cleaning booster which is separate or separate from the detergent dosing system. This has either an operating state for maintenance dosing or an operating state for surge dosing and is provided with the technical equipment necessary for the respective operating state. In addition to this embodiment, in which the cleaning amplifier dosing system has either only technical devices for the operating state of maintenance dosing or technical devices for the operating state of shock dosing, it is also possible to equip the cleaning amplifier dosing system with technical devices for both operating states, so that the operating personnel can the desired operating state can be freely selected. The device thus enables maintenance dosing during the interruptions or standstill phases of the dishwasher operation and / or the cleaning agent dosing breaks or a shock dosing immediately after the end of interruptions or standstill phases of the dishwasher operation and / or cleaning agent dosing breaks, so that a through Enzyme degradation or decomposition-induced decrease in enzyme activity is compensated for during this time. Such a subsequent or additional metering is necessary if the cleaning agent supply to the commercial dishwasher is carried out, as usual, via a regulation which does not take into account the enzyme content in the washing liquor. In contrast to the enzyme content, the detergent concentration in the washing liquor remains essentially constant during the interruptions or downtimes of the dishwasher. Without the additional metering of enzyme, otherwise only cleaning agents corresponding to the fresh water supply would otherwise be metered into the at least one metering or washing tank or the washing or washing liquor of the dishwasher at the beginning of a new rinse cycle. There would then be a deficit in enzyme content and thus an unsatisfactory washing result, at least with regard to starch soiling. This problem is overcome by the device according to the invention.

Bei einer Ausführungsform der Vorrichtung zur Durchführung der Stoßdosierung enthält die Vorrichtung in Weiterbildung der Erfindung einen Zähler, dem während der Unterbrechungszeiten regelmäßig Pausenimpulse zugeführt werden. Mit diesen Pausenimpulsen wird der Zählerstand nicht linear, sondern vielmehr einer stufenweise angenäherten, zum Enzymzerfall komplementären Funktion, insbesondere einer e-Funktion, entsprechend erhöht, um sich schließlich mit minimaler Zählrate asymptotisch einem vorgegebenen Endwert zu nähern. Nach Beendigung der Unterbrechung bzw. Stillstandsphase und Wiederaufnahme des Maschinenbetriebes wird der Zähler vom erreichten Zählerstand an mit konstanter Taktrate linear abwärts gezählt bis der Zählerstand Null erreicht ist. Während des Abzählvorganges aktivieren die Abwärtszählimpule eine Pumpe, die die Stoßdosierung bewirkt. Die Dauer der Stoßdosierung hängt also von dem während der Unterbrechungszeit erreichten Zählerstand ab. Die Dauer der Stoßdosierung ist um Größenordnungen kleiner als die Dauer der in Betracht kommenden Unterbrechungszeiten. Die Stoßdosierung gleicht damit innerhalb eines Zeitraumes von Sekunden bis Minuten die Wirkstoffzehrung von mehreren 10 Minuten bis Stunden aus. Die Höhe des Zählerstandes ist also ein Maß für die Dauer der Stoßdosierung. Diese Dauer ist in jedem Fall viel kürzer als die Dauer in Betracht kommender Pausenzeiten, so daß die Stoßdosierung des enzymhaltigen Reinigungsverstärkers mit einer viel höheren Rate erfolgt als der Abbau bzw. Zerfall (Zehrung) des Enzyms in der Waschflotte. Bereits nach sehr kurzer Zeit von wenigen Minuten wird auf diese Weise die Enzymzehrung von mehreren 10 Minuten ausgeglichen. Diese Art der Stoßdosierung erfolgt nicht nur unmittelbar nach Beendigung von Unterbrechungen oder Stillstandsphasen des Geschirrspülmaschinenbetriebes, sondern gewünschtenfalls auch unmittelbar nach Beendigung von Reinigungsmittel-Dosierpausen.In one embodiment of the device for carrying out the shock metering, the device in a development of the invention contains a counter, to which pause pulses are regularly supplied during the interruption times. With these pause pulses, the counter reading is not increased in a linear manner, but rather in a step-wise approximated function that is complementary to the enzyme decay, in particular an e-function, in order to finally approach a predetermined final value asymptotically with a minimal count rate. After the end of the interruption or standstill phase and resumption of machine operation, the counter is counted down linearly from the achieved counter reading at a constant clock rate until the counter reading reaches zero. During the counting process, the down counting pulses activate a pump, which effects the surge metering. The duration of the surge metering therefore depends on the meter reading reached during the interruption time. The duration of the shock metering is orders of magnitude shorter than the duration of the interruption times in question. The surge dosage thus compensates for the drug consumption of several 10 minutes to hours within a period of seconds. The level of the meter reading is therefore a measure of the duration of the surge metering. This duration is in any case much shorter than the duration of possible break times, so that the shock dosage of the enzyme-containing cleaning boosters occur at a much higher rate than the breakdown or decay (consumption) of the enzyme in the wash liquor. After a very short time of a few minutes, the enzyme consumption of several 10 minutes is compensated in this way. This type of shock metering is not only carried out immediately after interruptions or downtimes in the dishwasher operation, but if desired also immediately after the detergent dosing breaks.

Der Begriff "Zähler" soll in diesem Zusammenhang weitgefaßt verstanden werden. Er umfaßt jegliche Zähleinrichtung, die zugeführte Pausenimpulse einer vorgegebenen Funktion entsprechend zählt und damit auch nicht lineare, z. B. einer e-Funktion folgende, Zählvorgänge ermöglicht. Die Variation des Zeitabstandes der Pausenimpulse kann zur Beschleunigung (Stauchung) oder Verzögerung (Dehnung) des Zählvorganges im Zeitbereich benutzt werden. Hierbei können die Pausenimpulse mit zeitlich konstantem Abstand vorliegen und mit einem Faktor vervielfacht werden, dessen zeitlicher Verlauf einer e-Funktion entspricht. Andererseits ist es auch möglich, die Pausenimpulse mit unterschiedlichen zeitlichen Abständen dem Zähler zuzuführen. Schließlich kann der Zähler auch eine Summiereinrichtung enthalten, die bei jedem Pausenimpuls den Zählerstand um einen zeitlich variierenden Betrag erhöht.The term "counter" is to be understood broadly in this context. It includes any counting device that counts supplied pause pulses according to a given function and thus also non-linear, e.g. B. following an e-function enables counting. The variation in the time interval of the pause pulses can be used to accelerate (compress) or decelerate (stretch) the counting process in the time domain. The pause pulses can be present at a constant time interval and can be multiplied by a factor whose time profile corresponds to an e-function. On the other hand, it is also possible to feed the pause pulses to the counter at different time intervals. Finally, the counter can also contain a summing device which increases the counter reading by a time-varying amount with each pause pulse.

Sowohl für Vorrichtungen mit dem Betriebszustand Unterhaltsdosierung als auch für Vorrichtungen mit dem Betriebszustand Stoßdosierung sieht die Erfindung in weiterer Ausgestaltung vor, daß das Dosiersystem für den enzymhaltigen Reinigungsverstärker zusätzlich einen parallel zum Reinigungsmittel-Dosiersystem fördernden Betriebszustand für eine Paralleldosierung bei eingeschaltetem Reinigungsmittel-Dosiersystem besitzt. Nach dieser Ausgestaltung kann mit der Vorrichtung sowohl enzymhaltiges als auch enzymfreies Reinigungsmittel verwendet werden, wobei die Paralleldosierung eine Zudosierung von enzymhaltigem Reinigungsverstärker bei der Verwendung von enyzmfreiem Reinigungsmittel ermöglicht. Die Paralleldosierung und die Unterhaltsdosierung oder die Stoßdosierung unterscheiden sich dabei im wesentlichen nur in der pro Zeiteinheit jeweils in den Dosiertank bzw. die Spül- oder Waschflotte geförderten Menge an enzymhaltigem Reinigungsverstärker.In a further embodiment, the invention provides for devices with the operating state of maintenance dosing as well as for devices with the operating state of shock dosing that the dosing system for the enzyme-containing cleaning booster additionally has an operating state which promotes parallel to the cleaning agent dosing system for parallel dosing when the cleaning agent dosing system is switched on. According to this embodiment, both enzyme-containing and enzyme-free cleaning agents can be used with the device, the parallel dosing allowing the addition of enzyme-containing cleaning enhancers when using enzyme-free cleaning agents. The parallel dosing and the maintenance dosing or the surge dosing differ essentially only in that per unit of time in each case in the metering tank or the rinsing or washing liquor conveyed amount of enzyme-containing cleaning enhancer.

Von Vorteil ist es, wenn zum Fördern des enzymhaltigen Reinigungsverstärkers eine frequenzgesteuerte Schlauchquetschpumpe oder eine Membranpumpe vorgesehen ist, wie dies die Erfindung weiterhin vorsieht. Eine solche Pumpe kann mit einer dem Enzymzerfall entsprechenden Anzahl von Pumpenhüben pro Zeiteinheit betrieben werden. Für die Unterhaltsdosierung genügen dann relativ wenig Pumpenhübe, während für die Stoßdosierung und/oder gegebenenfalls für die Paralleldosierung bei Verwendung eines enzymfreien Reinigers eine viel größere Zahl von Pumpenhüben erforderlich ist. In der Praxis hat es sich daher als zweckmäßig erwiesen, wenn die zugehörige Frequenzsteuerung der Pumpe einen ersten Regelbereich für die Unterhaltsdosierung sowie einen zweiten Regelbereich für die Spülphase der Geschirrspülmaschine bei eingeschaltetem Reinigungsmittel-Dosiersystem mit einer gegenüber der Dosis des ersten Regelbereichs wesentlich verstärkten Förderleistung besitzt, wie dies die Erfindung in Ausgestaltung schließlich vorsieht.It is advantageous if a frequency-controlled peristaltic pump or a diaphragm pump is provided for conveying the enzyme-containing cleaning amplifier, as the invention further provides. Such a pump can be operated with a number of pump strokes per unit of time corresponding to the enzyme breakdown. Relatively few pump strokes are then sufficient for maintenance dosing, while a much larger number of pump strokes are required for surge dosing and / or if necessary for parallel dosing when using an enzyme-free cleaner. In practice, it has therefore proven to be expedient if the associated frequency control of the pump has a first control range for maintenance dosing and a second control range for the dishwashing phase of the dishwasher when the detergent dosing system is switched on, with a significantly increased delivery rate compared to the dose in the first control range. as the invention finally provides in an embodiment.

Die Erfindung ist nachstehend anhand der Zeichnung beispielsweise näher erläutert. Diese zeigt in

Fig. 1
ein Blockschaltbild von Reinigungsmittel-Dosiersystem und Reinigungsverstärker-Dosiersystem für flüssiges, enzymfreies Reinigungsmittel und für flüssigen, enzymhaltigen Reinigungsverstärker,
Fig. 2
ein Funktionsdiagramm für eine Parallel- und Unterhaltsdosierung von enzymhaltigem Reinigungsverstärker bei Verwendung von enzymfreiem Reinigungsmittel,
Fig. 3
ein Blockschaltbild von Reinigungsmittel-Dosiersystem und Reinigungsverstärker-Dosiersystem für enzymhaltigen Pulverreiniger und flüssigen, enzymhaltigen Reinigungsverstärker,
Fig. 4
ein Funktionsdiagramm für eine Unterhaltsdosierung von enzymhaltigem Reinigerverstärker bei Verwendung von enzymhaltigem Reinigungsmittel,
Fig. 5
ein schematisches Blockschaltbild einer Vorrichtung für eine Stoßdosierung,
Fig. 6
ein Diagramm zur Veranschaulichung der theoretischen Dosierfunktion und der durch einen Zählalgorithmus des Zählers angenäherten Funktion bei der Stoßdosierung und in
Fig. 7
den zeitlichen Verlauf der Enzymkonzentration in der Waschflotte während einer Betriebsunterbrechung und anschließender Stoßdosierung.
The invention is explained below with reference to the drawing, for example. This shows in
Fig. 1
a block diagram of detergent dosing system and cleaning amplifier dosing system for liquid, enzyme-free cleaning agent and for liquid, enzyme-containing cleaning amplifier,
Fig. 2
1 shows a functional diagram for parallel and maintenance dosing of enzyme-containing cleaning boosters when using enzyme-free cleaning agent,
Fig. 3
a block diagram of detergent dosing system and cleaning amplifier dosing system for enzyme-containing powder cleaner and liquid, enzyme-containing cleaning amplifier,
Fig. 4
a functional diagram for a maintenance dosage of enzyme-containing Detergent booster when using enzyme-containing detergent,
Fig. 5
1 shows a schematic block diagram of a device for shock metering,
Fig. 6
a diagram illustrating the theoretical dosing function and the approximated by a counting algorithm of the counter function in the batch dosing and in
Fig. 7
the time course of the enzyme concentration in the wash liquor during an interruption in operation and subsequent surge dosing.

Die Fig. 1 zeigt das einer gewerblichen Geschirrspülmaschine, wie sie nachstehend beispielsweise im Zusammenhang mit der Fig. 5 erläutert ist, zugeordnete Reinigungsmittel-Dosiersystem für flüssiges, enzymfreies, niederalkalisches Reinigungsmittel 2 und das der gewerblichen Geschirrspülmaschine zugeordnete Reinigungsverstärker-Dosiersystem für flüssigen, enzymhaltigen Reinigungsverstärker 5. Eine übliche Flüssigreinigerdosierpumpe 1 fördert aus einem Flüssigreinigertank, beispielsweise geregelt über eine Leitfähigkeits- oder pH-Wert-Wertmessung, flüssiges, enzymfreies Reinigungsmittel 2 durch eine Leitung 3 zu zumindestens einem (nicht dargestellten) Dosier- oder Waschtank einer Geschirrspülmaschine. Parallel zu der Flüssigreinigerdosierpumpe 1 ist eine frequenzgesteuerte Schlauchquetschpumpe 4 vorgesehen, die aus einem flüssigen, enzymhaltigen Reinigungsverstärker 5 enthaltenden Tank durch eine Leitung 6 ebenfalls zu dem vorgenannten, mindestens einen Dosier- oder Waschtank fördert. Dieses Dosiersystem für flüssigkonfektionierten, enzymhaltigen Reinigungsverstärker 5 ist mittels einer interen und/oder externen Elektronik derart steuerbar, daß sich ein Funktionsdiagramm nach Fig. 2 einstellt, also eine Unterhaltsdosierung 17, 18 und gegebenenfalls Paralleldosierung 16 des Reinigungsverstärkers 5 in Ergänzung zur Reinigungsmitteldosierung möglich ist.1 shows the detergent dosing system for liquid, enzyme-free, low-alkaline cleaning agent 2 assigned to a commercial dishwasher, as is explained below, for example, in connection with FIG. 5, and the cleaning amplifier dosing system for liquid, enzyme-containing cleaning enhancer assigned to the commercial dishwasher 5. A conventional liquid detergent metering pump 1 delivers liquid, enzyme-free cleaning agent 2 from a liquid detergent tank, for example regulated via a conductivity or pH value measurement, through a line 3 to at least one (not shown) metering or washing tank of a dishwasher. In parallel with the liquid cleaner metering pump 1, a frequency-controlled peristaltic pump 4 is provided, which also conveys from a liquid, enzyme-containing cleaning booster 5 through a line 6 to the above-mentioned, at least one metering or washing tank. This dosing system for liquid-made, enzyme-containing cleaning boosters 5 can be controlled by means of internal and / or external electronics in such a way that a function diagram according to FIG. 2 is established, i.e. maintenance dosing 17, 18 and, if necessary, parallel dosing 16 of cleaning booster 5 in addition to the dosing of cleaning agents is possible.

Die Fig. 2 zeigt in drei Zeilen 7, 8 und 9 verschiedene Ein- und Ausschaltzustände (1/0) in Abhängigkeit von der Zeit t. In der mit 7 bezeichneten obersten Zeile ist der Betriebszustand der gewerblichen Geschirrspülmaschine symbolisiert. Die Spülphasen bzw. Einschaltzustände sind mit 10, die Unterbrechungen bzw. Stillstandsphasen sind mit 11 bezeichnet. In der mit 8 bezeichneten zweiten Zeile ist die Dosierung des enzymfreien Reinigungsmittels 2, d. h. der aktive Betriebszustand der Flüssigreinigerdosierpumpe 1, dargestellt. In Abhängigkeit von der in zumindest einem Waschtank der Geschirrspülmaschine gemessenen Leitfähigkeit oder dem pH-Wert der in der Geschirrspülmaschine befindlichen Spül- oder Waschflotte wird in diesem Ausführungsbeispiel ein zweimaliges Anspringen der Dosierpumpe 1 während eines Maschinen-Einschaltzustandes 10 angenommen. Die entsprechenden beiden Reinigungsmittel-Dosierzeiten sind mit 12 und 13 bezeichnet. Eine dazwischen liegende Dosierpause ist mit 14 und die der Unterbrechung bzw. der Stillstandsphase 11 des Geschirrspülmaschinenbetriebes entsprechende Dosierpause ist mit 15 gekennzeichnet. In der mit 9 bezeichneten dritten Zeile ist die Dosierung des enzymhaltigen Reinigungsverstärkers 5, d. h. der aktive Betriebszustand der Schlauchquetschpumpe 4, angegeben.2 shows in three lines 7, 8 and 9 different on and off states (1/0) depending on the time t. In the 7th The top line labeled symbolizes the operating state of the commercial dishwasher. The rinsing phases or switch-on states are denoted by 10, the interruptions or standstill phases are denoted by 11. The second line, designated 8, shows the dosage of the enzyme-free cleaning agent 2, ie the active operating state of the liquid cleaner metering pump 1. Depending on the conductivity measured in at least one washing tank of the dishwasher or the pH of the washing or washing liquor located in the dishwasher, in this exemplary embodiment a two-time start of the metering pump 1 is assumed during a machine switch-on state 10. The corresponding two detergent dosing times are designated 12 and 13. An intermediate dosing pause is indicated by 14 and the dosing pause corresponding to the interruption or the standstill phase 11 of the dishwasher operation is identified by 15. In the third line, designated 9, the dosage of the enzyme-containing cleaning amplifier 5, ie the active operating state of the peristaltic pump 4, is given.

Wie aus der Fig. 2 ersichtlich, erfolgt während der Reinigungsmittel-Dosierzeiten 12, 13 der Reinigerdosierpumpe 1 eine Paralleldosierung 16 des Reinigungsverstärkers 5 mit einer schnellen Folge einzelner Pumpenhübe der Schlauchquetschpumpe 4. Jeder einzelne Pumpenhub ist in der Zeile 9 der Fig. 2 - sowie auch in der Zeile 9a der Fig. 4 - als einzelner senkrechter Strich dargestellt. Demgegenüber ist die Arbeit der Schlauchquetschpumpe 4 während der Dosierpausen 14, 15 der Geschirrspülmaschine sehr verlangsamt; in den entsprechenden Unterhaltsdosierungen 17, 18 vollziehen sich pro Zeiteinheit wesentlich weniger Pumpenhübe als während der Paralleldosierung 16 in den Spülphasen 10 bzw. den Reinigungsmittel-Dosierzeiten 12, 13. Ersichtlich wird das flüssige Reinigungsmittel 2 während der Unterbrechung bzw. Stillstandsphase 11 der Geschirrspülmaschine nicht nachdosiert (Reinigungsmittel-Dosierpause 15). Ein solches Nachdosieren ist nicht erforderlich, da sich die Konzentration an Reinigungsmittel in der Waschflotte dann nicht signifikant vermindert. Lediglich der Enzymabbau bzw. Enzymzerfall (Zehrung) während der Stillstandsphase 11 wird durch die verlangsamte Nachdosierung bzw. Unterhaltsdosierung 17 in diesem Zeitraum ausgeglichen. Es kann günstig sein, während längerer Dosierpausen 14 in den Spülphasen 10 der Geschirrspülmaschine einzelne Pumpenhübe einer Unterhaltsdosierung 18 zum Ausgleich des auch in dieser Zeit ständig erfolgenden Enzymabbaus bzw. -zerfalls (Zehrung) vorzusehen.As can be seen from FIG. 2, during the detergent dosing times 12, 13 of the detergent dosing pump 1 there is a parallel dosing 16 of the cleaning amplifier 5 with a rapid sequence of individual pump strokes of the peristaltic pump 4. Each individual pump stroke is in line 9 of FIGS also in line 9a of Fig. 4 - shown as a single vertical line. In contrast, the work of the peristaltic pump 4 is very slowed down during the dosing breaks 14, 15 of the dishwasher; In the corresponding maintenance doses 17, 18, significantly fewer pump strokes are carried out per unit of time than during parallel dosing 16 in the rinsing phases 10 or the detergent dosing times 12, 13. As can be seen, the liquid detergent 2 is not replenished during the interruption or standstill phase 11 of the dishwasher (Detergent dosing break 15). Such dosing is not necessary since the concentration of detergent in the wash liquor will not be significantly reduced. Only the enzyme breakdown or enzyme decay (consumption) during the standstill phase 11 is compensated for by the slowed down metering or maintenance metering 17 during this period. It can be cheap for longer Dosing pauses 14 in the dishwashing phases 10 of the dishwasher provide individual pump strokes for maintenance dosing 18 to compensate for the constant enzyme breakdown or decay (consumption) during this time.

Für den Fall, daß ein Geschirrspülmaschinenreinigungsmittel 19 bereits Enzyme enthält, was vor allem bei Pulverreinigern möglich ist, braucht eine Paralleldosierung von enyzmhaltigem Reinigungsverstärker 5 im allgemeinen nicht vorgesehen zu werden, vielmehr genügt dann eine Unterhaltsdosierung 17. Für diesen Fall ist ein Ausführungsbeispiel aus den Fig. 3 und 4 ersichtlich, wobei die Fig. 3 das einer gewerblichen Geschirrspülmaschine zugeordnete Reinigungsmittel-Dosiersystem für einen enzymhaltigen, niederalkalischen Pulverreiniger 19 und das davon getrennte Dosiersystem für den enzymhaltigen, flüssigen Reinigungsverstärker 5 und die Fig. 4 in den drei Zeilen 7a, 8a und 9a die verschiedenen Ein- und Ausschaltzustände (1/0) der gewerblichen Geschirrspülmaschine und der Dosiersysteme in Abhängigkeit von der Zeit t zeigt. Das Reinigungsmittel-Dosiersystem nach Fig. 3 besteht aus einem Trichter 20 mit darin eingefülltem, enzymhaltigem, niederalkalischem Pulverreiniger 19. Wie von üblichen Dosiersystemen bekannt, erfolgt die Dosierung des enzymhaltigen Pulverreinigers 19 in dem Trichter 20 über eine Frischwasser- oder Flotteneinspülung 21 und eine Leitung 22 zu zumindest einem Dosier- oder Waschtank einer gewerblichen Geschirrspülmaschine (Pfeilrichtung).In the event that a dishwasher detergent 19 already contains enzymes, which is possible especially with powder detergents, a parallel dosage of enzyme-containing cleaning booster 5 does not generally have to be provided, rather a maintenance dosage is sufficient. For this case, an embodiment from FIGS 3 and 4 can be seen, with FIG. 3 the detergent dosing system assigned to a commercial dishwasher for an enzyme-containing, low-alkaline powder cleaner 19 and the separate dosing system for the enzyme-containing liquid cleaning booster 5 and FIG. 4 in the three lines 7a, 8a and FIG. 9a shows the different switch-on and switch-off states (1/0) of the commercial dishwasher and the metering systems as a function of the time t. 3 consists of a funnel 20 with an enzyme-containing, low-alkaline powder cleaner 19 filled therein. As is known from conventional dosing systems, the enzyme-containing powder cleaner 19 is dosed in the funnel 20 via a fresh water or liquor flush 21 and a line 22 to at least one dosing or wash tank of a commercial dishwasher (arrow direction).

Außerdem ist nach Fig. 3 ein Dosiersystem für enzymhaltigen Reinigungsverstärker 5 mit einer frequenzgesteuerten Schlauchquetschpumpe 4 vorgesehen, die den enzymhaltigen Reinigungsverstärker 5 aus einem Tank über eine Leitung 6 ebenfalls zu dem zumindest einen Dosier- oder Waschtank der Geschirrspülmaschine fördert. Im Unterschied zum Fall von Fig. 1/2 arbeitet die Schlauchquetschpumpe 4 nach Fig. 3/4 jedoch nur während der Stillstandsphase 11 der Spülmaschine und gegebenenfalls während der Dosierpause 14, wie dies in der Zeile 9a der Fig. 4 angedeutet ist. Die Zeilen 7a und 8a zeigen identische Betriebszustände wie die Zeilen 7 und 8 nach dem Ausführungsbeispiel der Fig. 1/2 an. Da bei dem Ausführungsbeispiel nach Fig. 3 und 4 bei der Dosierung 12, 13 von enzymhaltigem Reiniger 19 während der Spülphasen 10 bereits Enzym in den zumindest einen Dosier- oder Waschtank eindosiert wird, entfällt bei diesem Ausführungsbeispiel eine Paralleldosierung von enzymhaltigem Reinigungsverstärker während der Dosierzeiten 12 und 13. Lediglich während der Unterbrechung oder Stillstandsphase 11 bzw. der Reinigungsmittel-Dosierpause 15 erfolgt eine Dosierung des enzymhaltigen Reinigungsverstärkers 5 in Form einer Unterhaltsdosierung 17. Darüber hinaus kann es unter Umständen günstig sein, in Dosierpausen 14 zwischen zwei Reinigungsmittel-Dosierungen 12 und 13, ähnlich wie im Ausführungsbeispiel nach der Fig. 2, einen oder mehrere Dosierhübe als Unterhaltsdosierung 18 vorzusehen, was ebenfalls in der Zeile 9a der Fig. 4 dargestellt ist.In addition, according to FIG. 3, a dosing system for enzyme-containing cleaning booster 5 with a frequency-controlled peristaltic pump 4 is provided, which also conveys the enzyme-containing cleaning booster 5 from a tank via a line 6 to the at least one dosing or washing tank of the dishwasher. In contrast to the case of FIG. 1/2, the peristaltic pump 4 according to FIG. 3/4 only works during the standstill phase 11 of the dishwasher and possibly during the dosing pause 14, as indicated in line 9a of FIG. 4. Lines 7a and 8a show identical operating states as lines 7 and 8 according to the embodiment of FIG. 1/2. 3 and 4 in the metering 12, 13 of enzyme-containing cleaner 19 during the rinsing phases 10, enzyme is already metered into the at least one metering or wash tank, this is omitted Embodiment a parallel dosing of enzyme-containing cleaning booster during the dosing times 12 and 13. Only during the interruption or standstill phase 11 or the cleaning agent dosing pause 15 is the enzyme-containing cleaning booster 5 dosed in the form of a maintenance dosing 17. In addition, it can be advantageous under certain circumstances Dosing pauses 14 between two detergent doses 12 and 13, similar to the embodiment according to FIG. 2, to provide one or more dosing strokes as maintenance dosing 18, which is also shown in line 9a of FIG. 4.

Zum Betrieb der Unterhaltsdosierung 17, 18 und der nachstehend erläuterten Stoßdosierung SD sowie der gegebenenfalls gewünschten Paralleldosierung 16 wird bevorzugt eine Modifikation einer frequenzgesteuerten Schlauchquetschpumpe 4, 27 verwendet, wobei die bei der Unterhaltsdosierung verwendete Pumpe in den Fig. 1 und 3 mit dem Bezugszeichen 4 und die bei der Stoßdosierung verwendete Pumpe in der Fig. 5 mit dem Bezugszeichen 27 versehen ist. Dabei sind zwei Regelbereiche der Frequenzsteuerung möglich und zwar erstens ein Bereich I für die Paralleldosierung 16 oder die nachstehend erläuterte Stoßdosierung SD mit einem Förderleistungsbereich von 8 bis 290 ml/min und zweitens ein Bereich II für die Unterhaltsdosierungen 17, 18 mit einem Förderleistungsbereich von 1,5 bis 3,5 ml/min. Diese beiden Regelbereiche sind extern anwählbar, so daß eine Nachregulierung dem Spülergebnis entsprechend möglich ist. Es ist natürlich auch möglich, für jede Art der Dosierung eine separate Pumpe für den jeweils gewünschten Förderbereich bereitzustellen oder im Falle von Stoßdosierung und Paralleldosierung eine Pumpe mit nur einem Regelbereich für beide Dosierarten.A modification of a frequency-controlled peristaltic pump 4, 27 is preferably used to operate the maintenance metering 17, 18 and the shock metering SD explained below as well as the desired parallel metering 16, the pump used in the maintenance metering in FIGS. 1 and 3 with the reference numerals 4 and the pump used in the surge metering is provided with the reference number 27 in FIG. 5. Two control ranges for frequency control are possible, firstly an area I for parallel dosing 16 or the shock dosing SD explained below with a delivery rate range of 8 to 290 ml / min and secondly an area II for maintenance dosing 17, 18 with a delivery rate range of 1, 5 to 3.5 ml / min. These two control ranges can be selected externally so that readjustment is possible according to the washing result. Of course, it is also possible to provide a separate pump for each type of metering for the desired delivery range, or in the case of surge metering and parallel metering, a pump with only one control range for both metering types.

Anstelle der in der Zeile 9 der Fig. 2 dargestellten Unterhaltsdosierungen 17, 18 in Verbindung mit den Paralleldosierungen 16 oder der in der Zeile 9a der Fig. 4 dargestellten Unterhaltsdosierungen 17, 18 ohne Paralleldosierung kann die Zu- oder Nachdosierung von enzymhaltigem Reinigungsverstärker 5 auch durch eine Stoßdosierung SD erfolgen. Im Gegensatz zu den Unterhaltsdosierungen 17, 18, die während der Unterbrechung oder Stillstandsphase 11 und/oder der Reinigungsmittel-Dosierpausen 14, 15 erfolgt, wird die Stoßdosierung SD unmittelbar nach Beendigung einer Unterbrechung oder Stillstandsphase 11 und/oder einer Reinigungsmittel-Dosierpause 14, 15 aktiviert. Von den in den Fig. 2 und 4 dargestellten Funktionsdiagrammen würden sich die entsprechenden Funktionsdiagramme für eine Stoßdosierung SD in den Zeilen 7, 7a und 8, 8a nicht und in den Zeilen 9, 9a dadurch unterscheiden, daß die Unterhaltsdosierungen 17, 18 entfallen und stattdessen nach Beendigung der Stillstandsphase 11 und/oder der Reinigungsmittel-Dosierpausen 14, 15 bzw. zu Beginn der Spülphasen 10 oder der Reinigungsmittel-Dosierzeiten 12, 13 als Stoßdosierung SD dem zumindest einen Dosier- oder Waschtank der Geschirrspülmaschine enzymhaltiger Reinigungsverstärker 5 zudosiert wird. Die Stoßdosierung ist nachstehend anhand der Fig. 5 bis 7 näher erläutert.Instead of the maintenance doses 17, 18 shown in line 9 of FIG. 2 in connection with the parallel doses 16 or the maintenance doses 17, 18 shown in line 9a of FIG. 4 without parallel dosing, the addition or subsequent dosing of enzyme-containing cleaning boosters 5 can also be carried out by a surge metering SD. In contrast to the maintenance doses 17, 18, which takes place during the interruption or standstill phase 11 and / or the cleaning agent dosing breaks 14, 15, the shock dosing SD becomes immediate after the end of a Interruption or standstill phase 11 and / or a detergent dosing break 14, 15 activated. The corresponding function diagrams for a surge dose SD in lines 7, 7a and 8, 8a would not differ from the function diagrams shown in FIGS. 2 and 4 and would differ in lines 9, 9a in that maintenance doses 17, 18 are omitted and instead after the end of the standstill phase 11 and / or the detergent dosing pauses 14, 15 or at the beginning of the rinsing phases 10 or the detergent dosing times 12, 13, the at least one dosing or washing tank of the dishwasher-containing cleaning amplifier 5 is added to the at least one dosing or washing tank. The shock metering is explained in more detail below with reference to FIGS. 5 to 7.

In Fig. 5 ist eine gewerbliche Geschirrspülmaschine 23 dargestellt, durch die das zu spülende Geschirr von links (Einlaßende) nach rechts (Auslaßende) hindurchgefördert wird. Die Geschirrspülmaschine 23 enthält hintereinander mehrere Tanks, aus denen Spül- bzw. Waschflotte gegen das Geschirr gesprüht wird, um anschließend wieder in die Tanks abzulaufen. Die Tanks sind in bekannter Weise kaskadenartig aneinandergesetzt, wobei die Spül- oder Waschflotte die Tanks nacheinander vom Auslaßende (rechts) zum Einlaßende (links) durchläuft, so daß der Verschmutzungsgrad der Waschflotte vom Auslaßende zum Einlaßende hin zunimmt.5 shows a commercial dishwasher 23 through which the dishes to be washed are conveyed from left (inlet end) to right (outlet end). The dishwasher 23 contains several tanks one behind the other, from which washing or washing liquor is sprayed against the dishes in order to then run back into the tanks. The tanks are cascaded together in a known manner, the washing or washing liquor passing through the tanks in succession from the outlet end (right) to the inlet end (left), so that the degree of contamination of the washing liquor increases from the outlet end to the inlet end.

Am Auslaßende wird in die Geschirrspülmaschine 23 Wasser eingeführt und zusätzlich aus einem Spülmitteltank 24 niederalkalisches Reinigungsmittel 2, das in flüssiger Form in dem Spülmitteltank 24 enthalten ist. Das Reinigungsmittel 2 wird durch eine Pumpe 25 in dosierter Form gefördert. Diese Pumpe 25 wird von einer Pumpensteuereinheit 26 angetrieben. Die Dosierung des Reinigungsmittels 2 erfolgt in Abhängigkeit von dem Leitwert oder pH-Wert der in der Spülmaschine 23 enthaltenen Waschflotte. Die Pumpensteuereinheit 26 steuert eine weitere Pumpe 27, die aus einem Tank 28 einen flüssigen, enzymhaltigen Reinigungsverstärker 5 in die Geschirrspülmaschine 23 eindosiert. Der Reinigungsverstärker enthält Enzyme wie Amylase, Lipase oder Protease. Der Reinigungsverstärker 5, der im Tank 28 in flüssiger Form enthalten ist, wird durch die Pumpe 27, bei der es sich vorzugsweise um eine Schlauchquetschpumpe handelt, in die Geschirrspülmaschine 23 eingegeben. Die Pumpe 27 wird durch Impulse gesteuert, die ihr über eine Steuerleitung 29 zugeführt werden. Der Pumpenantrieb erfolgt über einen Schrittmotor, wobei jeder Impuls in der Steuerleitung 29 einer bestimmten Fördermenge der Pumpe 27 entspricht. Die Steuerleitung 29 ist an eine von der Pumpensteuereinheit 26 kommende Betriebsimpulsleitung 30 angeschlossen. Die Betriebsimpulsleitung 30 liefert während des Betriebszustandes 10 der Geschirrspülmaschine 23 Betriebsimpulse, deren Frequenz so bemessen ist, daß die Pumpe 27 in der Waschflotte eine bestimmte Konzentration an enzymhaltigem Reinigungsverstärker 5 aufrechterhält, also eine Paralleldosierung 16 vorgenommen wird. Bei einer Unterbrechung des Betriebs bzw. einer Stillstandsphase 11 der Spülmaschine oder Dosierpausen 14, 15 liefert die Pumpensteuereinheit 26 an die Pumpe 25 für das Reinigungsmittel 2 keine Impulse und sie liefert ebenfalls keine Betriebsimpulse an die Betriebsimpulsleitung 30. Es liegt also der zu dem in Fig. 2 dargestellten Beispiel analoge Fall einer Stoßdosierung (nachstehend erläutert) in Kombination mit einer Paralleldosierung 16 vor.At the outlet end, water is introduced into the dishwasher 23 and additionally from a detergent tank 24 low-alkaline cleaning agent 2, which is contained in the detergent tank 24 in liquid form. The cleaning agent 2 is conveyed by a pump 25 in metered form. This pump 25 is driven by a pump control unit 26. The detergent 2 is dosed as a function of the conductivity or pH of the washing liquor contained in the dishwasher 23. The pump control unit 26 controls a further pump 27, which doses a liquid, enzyme-containing cleaning amplifier 5 into the dishwasher 23 from a tank 28. The cleaning booster contains enzymes such as amylase, lipase or protease. The cleaning amplifier 5, which is contained in the tank 28 in liquid form, is fed into the dishwasher 23 by the pump 27, which is preferably a peristaltic pump. The pump 27 is controlled by pulses that it are supplied via a control line 29. The pump is driven by a stepper motor, each pulse in the control line 29 corresponding to a specific delivery rate of the pump 27. The control line 29 is connected to an operating pulse line 30 coming from the pump control unit 26. The operating pulse line 30 supplies operating pulses 10 during the operating state 10 of the dishwasher, the frequency of which is dimensioned such that the pump 27 maintains a certain concentration of enzyme-containing cleaning amplifier 5 in the washing liquor, that is to say a parallel metering 16 is carried out. In the event of an interruption in operation or a standstill phase 11 of the dishwasher or dosing breaks 14, 15, the pump control unit 26 does not deliver any pulses to the pump 25 for the cleaning agent 2 and likewise does not supply any operating pulses to the operating pulse line 30 2 illustrated example analog case of a shock metering (explained below) in combination with a parallel metering 16 before.

An eine Pausenimpulsleitung 31 der Pumpensteuereinheit 26 ist ein Zähler 32 angeschlossen. Die Pausenimpulsleitung 31 liefert bei einer Unterbrechung des Betriebs bzw. einer Stillstandsphase 11 der Geschirrspülmaschine und/oder bei Dosierpausen 15 und gegebenenfalls Dosierpausen 14 Impulse mit konstantem zeitlichen Abstand an den Zähler 32.A counter 32 is connected to a pause pulse line 31 of the pump control unit 26. The pause pulse line 31 supplies pulses to the counter 32 at a constant time interval in the event of an interruption in operation or a standstill phase 11 of the dishwasher and / or during dosing pauses 15 and possibly dosing pauses 14.

Der Zähler 32 zählt in der in Fig. 6 dargestellten Weise nicht-linear. In Fig. 6 ist entlang der Abszisse die Pausenzeit t während einer Unterbrechung oder Stillstandsphase 11 und/oder einer Dosierpause 14, 15 und entlang der Ordinate der Zählerstand n aufgetragen. Bei diesem Ausführungsbeispiel wird in jeder Minute ein Pausenimpuls geliefert. Bei jedem Pausenimpuls wird der Zählerstand des Zählers 32 um einen variierenden Zählschritt erhöht. Die Größe der Zählschritte nimmt mit zunehmender Pausenzeit t ab. Die Zählkapazität des Zählers 32 beträgt hier 128. Der zeitliche Verlauf des Zählerstandes entspricht einer Treppenkurve 33, die einer e-Funktion 34 angenähert ist.The counter 32 counts non-linearly in the manner shown in FIG. 6. 6, the pause time t is plotted along the abscissa during an interruption or standstill phase 11 and / or a dosing pause 14, 15 and the counter reading n along the ordinate. In this embodiment, a pause pulse is delivered every minute. With each pause pulse, the counter reading of the counter 32 is increased by a varying counting step. The size of the counting steps decreases with increasing pause time t. The counting capacity of the counter 32 here is 128. The time course of the counter reading corresponds to a stair curve 33 which is approximated to an e-function 34.

Bei diesem Ausführungsbeispiel der Erfindung wird davon ausgegangen, daß der zeitliche Verlauf des Enzymabbaues bzw. Enzymzerfalls (Zehrung) während der Pausenzeit t im wesentlichen der folgenden Exponentialfunktion (Zehrungsfunktion) entspricht: C t = C o * e -lt .

Figure imgb0001
In this embodiment of the invention, it is assumed that the time course of the enzyme breakdown or enzyme decay (consumption) during the pause time t essentially corresponds to the following exponential function (consumption function): C. t = C O * e -lt .
Figure imgb0001

Hier ist Ct die Enzymkonzentration zum Zeitpunkt t, C0 die Ausgangskonzentration des Enzyms und λ = 1/τ

Figure imgb0002
, wobei τ die Zehrungszeitkonstante ist.Here C t is the enzyme concentration at time t, C 0 is the initial concentration of the enzyme and λ = 1 / τ
Figure imgb0002
, where τ is the consumption time constant.

Die Zudosierung von enyzmhaltigem Reinigungsverstärker 5 nach einer Pausenzeit t erfolgt nach der zur Zehrungsfunktion komplementären Funktion V t = V max * (1 - e -lt ).

Figure imgb0003
The addition of enzyme-containing cleaning booster 5 after a pause t takes place according to the function complementary to the drainage function V t = V Max * (1 - e -lt ).
Figure imgb0003

Hierin ist Vt die Stoßdosierzeit für eine Pausenzeit von t und Vmax die maximale Stoßdosierzeit. Dieser Funktion Vt entspricht die ideale Kurve 34 von Fig. 6, die durch die Treppenkurve 33 angenähert ist. Die Treppenkurve 33 wird schaltungstechnisch in dem Zähler 32 mittels eines programmierbaren Logikbausteines (PLD) realisiert. Die nicht-lineare Zählfunktion wird durch Variation der Zählschrittweite erreicht. Die Taktrate der Pausenimpulse wird der Zehrungsfunktion des Enzyms bzw. des enzymhaltigen Reinigungsverstärkers 5 angepaßt. Der maximale Zählerstand nmax des Zählers 32 beträgt 128, was einer Auflösung von 7 bit entspricht.Here V t is the shock metering time for a pause time of t and V max the maximum shock metering time. This function V t corresponds to the ideal curve 34 from FIG. 6, which is approximated by the stair curve 33. In terms of circuitry, the stair curve 33 is implemented in the counter 32 by means of a programmable logic module (PLD). The non-linear counting function is achieved by varying the counting step. The clock rate of the pause pulses is adapted to the drainage function of the enzyme or the enzyme-containing cleaning amplifier 5. The maximum counter reading n max of counter 32 is 128, which corresponds to a resolution of 7 bits.

Nach Beendigung der Pausenzeit t, d. h. zu Beginn der Betriebsphase 10 oder zu Beginn der Dosierzeiten 12 oder gegebenenfalls 13, wird der Zählerstand des Zählers 32 linear in Schritten von 1 abwärts gegen 0 gezählt. Dabei werden an dem Zählerausgang 35 Impulse erzeugt, die über die Steuerleitung 29 der Pumpe 27 zugeführt werden. Die beim Herunterzählen des Zählers 32 am Ausgang 35 erzeugten Impulse bewirken die Stoßdosierung durch die Pumpe 27. Mit dem Erreichen des Zählerstandes 0 wird die Stoßdosierung beendet.After the pause time t, d. H. at the beginning of the operating phase 10 or at the start of the metering times 12 or possibly 13, the counter reading of the counter 32 is counted linearly in steps from 1 down to 0. 35 pulses are generated at the counter output, which are supplied to the pump 27 via the control line 29. The pulses generated when counting down the counter 32 at the output 35 cause the surge metering by the pump 27. When the counter reading 0 is reached, the surge metering is ended.

Fig. 7 zeigt den zeitlichen Verlauf der Enzymkonzentration C in der Waschflotte im Falle einer Unterbrechung oder Stillstandsphase 11 des Geschirrspülmaschinenbetriebes oder einer Dosierpause 14, 15, deren Länge t1 beträgt. Längs der Ordinate ist die auf den Normalwert C0 normierte Enzymkonzentration C/C0 angegeben.FIG. 7 shows the time course of the enzyme concentration C in the wash liquor in the event of an interruption or standstill phase 11 in the dishwasher operation or a dosing break 14, 15, the length of which is t 1 . The enzyme concentration C / C 0 normalized to the normal value C 0 is given along the ordinate.

Nach Beginn der Pausenzeit fällt die Enzymkonzentration von dem Wert 1 aus exponentiell ab. Die Betriebspause, deren Dauer t1 beträgt, ist mit Beginn der Stoßdosierdauer t2 beendet. Mit dem Ende des Zeitraumes t1 bzw. dem Beginn des Zeitraumes t2 beginnt der Betrieb der Geschirrspülmaschine, d. h. der aktive Betriebszustand 10 oder die Dosierzeiten 12, 13 von neuem, wobei in der Anfangsphase eine Stoßdosierung SD durchgeführt wird. Im Zuge dieser Stoßdosierung steigt die Enzymkonzentration linear steil bis auf den Normalwert von "1" an. Der nachfolgende Betrieb wird dann mit dieser Normalkonzentration durchgeführt. Die Zeitdauer t2 der Stoßdosierung SD beträgt beispielsweise 1 bis 2 Minuten und ist wesentlich kürzer als die Pause t1.After the start of the break, the enzyme concentration drops exponentially from the value 1. The break in operation, the duration of which is t 1 , ends at the start of the surge metering duration t 2 . With the end of the period t 1 or the beginning of the period t 2 , the operation of the dishwasher begins, that is, the active operating state 10 or the dosing times 12, 13, with a shock metering SD being carried out in the initial phase. In the course of this surge dosing, the enzyme concentration rises linearly steeply to the normal value of "1". The subsequent operation is then carried out with this normal concentration. The duration t 2 of the shock metering SD is, for example, 1 to 2 minutes and is considerably shorter than the break t 1 .

Während der Pausenzeit t1 zählt der Zähler 32 in Folge der Pausenimpulse schrittweise hoch, wobei sich der Zählerstand n entsprechend der Kurve 33 in Fig. 6 entwickelt und sich asymptotisch an den maximalen Zählerstand nmax nähert, der schließlich erreicht wird, wenn die Betriebspause der Geschirrspülmaschine nicht vorher unterbrochen wird. Der maximale Zählerstand nmax entspricht der maximalen Stoßdosierzeit. Der maximale Zählerstand wird erreicht, wenn die Pausenzeit etwa 5 τ beträgt, wobei τ die Zehrungszeitkonstante des Enzyms ist. Die Taktrate des Zählers 32 beim Abwärtszählen ist so gewählt, daß bei maximaler Stoßdosierzeit gerade wieder die Soll-Konzentration C0 an Enzym in der Waschflotte erreicht wird. Die Taktrate R in 1/s beträgt R = n max V max ,

Figure imgb0004
wobei Vmax die maximale Stoßdosierzeit ist.During the pause time t 1, the counter 32 increments as a result of the pause pulses, the counter reading n developing in accordance with curve 33 in FIG. 6 and approaching asymptotically to the maximum counter reading n max , which is finally reached when the pause in operation Dishwasher is not interrupted beforehand. The maximum counter reading n max corresponds to the maximum surge metering time. The maximum count is reached when the pause time is about 5 τ, where τ is the consumption time constant of the enzyme. The clock rate of the counter 32 when counting down is chosen so that the maximum concentration C 0 of enzyme in the wash liquor is just reached again at the maximum burst dosing time. The clock rate R in 1 / s is R = n Max V Max ,
Figure imgb0004
where V max is the maximum shock dosing time.

In Abhängigkeit von der Verzehrrate des Enzyms wird der maximale Zählerstand nach einer Pausenzeit von 0,5 bis 3 Stunden erreicht.Depending on the consumption rate of the enzyme, the maximum count is reached after a break of 0.5 to 3 hours.

Bei den vorstehend beschriebenen Verfahren zur Dosierung von Reinigungsmittel 2, 19 und enzymhaltigem Reinigungsverstärker 5 werden in den beschriebenen Vorrichtungen als Reinigungsmittel ein niederalkalischer Reiniger auf Basis Phosphat oder Nitrilotriessigsäure oder deren Salze (NTA) und ein amylasehaltiger Reinigungsverstärker 5 der Geschirrspülmaschine zudosiert. Neben oder anstelle von Amylase kann der Reinigungsverstärker aber auch Lipase oder Protease enthalten. Vorzugsweise wird ein Reinigungsverstärker auf der Basis Thermamyl 300 L (Fa. NOVO), bestehend aus 0,55 Gew.-% Amylase, 18,0 Gew.-% Propylenglykol - 1,2, 72 Gew.-% Wasser, 9,45 Gew.-% Restwasser und Salze eingesetzt. Reiniger 2, 19 und/oder Reinigungsverstärker 5 können in zumindest einen Wasch- oder Dosiertank der Geschirrspülmaschine und/oder die Nachspülleitung und/oder die Sprühvorrichtung der Geschirrspülmaschine eindosiert werden.In the above-described methods for dosing cleaning agents 2, 19 and enzyme-containing cleaning boosters 5, a low-alkaline cleaner based on phosphate or nitrilotriacetic acid or its salts (NTA) are used as cleaning agents in the devices described. and metered an amylase-containing cleaning booster 5 into the dishwasher. In addition to or instead of amylase, the cleaning enhancer can also contain lipase or protease. A cleaning amplifier based on Thermamyl 300 L (NOVO), consisting of 0.55% by weight of amylase, 18.0% by weight of propylene glycol - 1.2, 72% by weight of water, 9.45, is preferably used % By weight of residual water and salts are used. Cleaners 2, 19 and / or cleaning boosters 5 can be metered into at least one washing or dosing tank of the dishwasher and / or the rinse line and / or the spraying device of the dishwasher.

Bei Verfahren ohne Unterhalts- oder Stoßdosierung wird der enzymhaltige Reinigungsverstärker während des regelmäßigen Geschirrspülmaschinenbetriebs mit üblicher Reinigerkonzentration in der Spül- oder Waschflotte von 0,5 bis 8 g/l und/oder einer periodischen Grundreinigung mit erhöhter Konzentration von 3 bis 15 g/l in der Spül- oder Waschflotte lediglich parallel oder nachträglich zum niederalkalischen Reiniger der Spül- oder Waschflotte zudosiert. Hierzu reicht es aus, eine gewerbliche Geschirrspülmaschine mit zwei Dosiersystemen, eines für den Reiniger und eines für den Reinigungsverstärker, auszustatten. Beispielsweise können dies zwei parallel zueinander betreibbare Dosierpumpen sein.In processes without maintenance or batch dosing, the enzyme-containing cleaning booster is used during regular dishwasher operation with a normal cleaning agent concentration in the washing or washing liquor of 0.5 to 8 g / l and / or a periodic basic cleaning with an increased concentration of 3 to 15 g / l in the rinsing or washing liquor is only metered in parallel or subsequently to the lower alkaline detergent of the rinsing or washing liquor. It is sufficient to equip a commercial dishwasher with two dosing systems, one for the cleaner and one for the cleaning booster. For example, these can be two metering pumps that can be operated parallel to one another.

Claims (28)

  1. A process for machine dishwashing in institutional dishwashing machines (23) in which a detergent (2,19) and a detergency booster (5) containing an enzyme, preferably a carbohydrate-degrading enzyme, more particularly amylase, are introduced into the dishwashing machine (23), characterized in that the detergency booster (5) is added to the wash liquor in at least one washing tank of the dishwashing machine (23) as part of the low-alkali detergent (2,19), more particularly based on phosphate or nitrilotriacetic acid or salts thereof (NTA), and/or additionally in combination with the low-alkali detergent (2,19) and in that the wash liquor is circulated and, at the same time, sprayed onto the articles to be washed.
  2. A process as claimed in claim 1, characterized in that a concentration of 0.5 to 15 g/l of low-alkali detergent (2,19) is established in the wash liquor.
  3. A process as claimed in claim 1 or 2, characterized in that the low-alkali detergent is introduced in the in-use concentration with a pH value of 7 to 11 and preferably in the range from 9.1 to 10.8.
  4. A process as claimed in any of the preceding claims, characterized in that a concentration of 0.05 to 2 g/l of detergency booster (5) is established in the wash liquor.
  5. A process as claimed in any of the preceding claims, characterized in that the enzyme-containing detergency booster (5) is added to the wash liquor during regular operation of the dishwashing machine at typical detergent concentrations of 0.5 to 8 g/l in the wash liquor and/or during periodic thorough cleaning at an increased concentration of detergent in the wash liquor of 3 to 15 g/l.
  6. A process as claimed in any of the preceding claims, characterized in that more detergency booster (5) is added at a rate commensurate with degradation of the enzyme.
  7. A process as claimed in claim 6, characterized in that the amount added in stoppage phases (11) is small by comparison with wash phases (10).
  8. A process as claimed in any of the preceding claims, characterized in that the detergent (2,19) and the detergency booster (5) are separately introduced into the wash liquor.
  9. A process as claimed in any of the preceding claims, characterized in that the enzyme-containing detergency booster (5) is introduced into the wash liquor at the same time as or after the low-alkali detergent (2,19).
  10. A process as claimed in any of the preceding claims, characterized in that the detergency booster (5) introduced contains around 0.01 to 0.6% by weight and preferably 0.45 to 0.55% by weight of enzyme, particularly amylase, and 10 to 25% by weight and preferably 15 to 20% by weight of propylene glycol, more particularly 1,2-propylene glycol, and a corresponding quantity of water.
  11. A process as claimed in any of claims 1 to 10, characterized in that an enzyme-free, more particularly liquid, low-alkali detergent (2) is introduced into the wash liquor during detergent addition times (12,13) and in that the enzyme-containing detergency booster (5) is introduced in parallel (16) as the detergent is consumed.
  12. A process as claimed in any of claims 1 to 10, characterized in that a low-alkali detergent (19), more particularly a powder-form low-alkali detergent, containing sufficient quantities of an enzyme for immediate washing is introduced into the wash liquor during detergent feed periods (12,13) and in that the enzyme-containing detergency booster (5) is introduced into the wash liquor immediately after or during the interruptions or stoppage phases (11) of the operation of the dishwashing machine and/or the feed intervals (14,15) of the detergent (19).
  13. A process as claimed in claim 12, characterized in that the enzyme-containing detergency booster (5) is added to the wash liquor as the enzyme is degraded or decomposed (consumed) to maintain the concentration of enzyme.
  14. A process as claimed in any of the preceding claims, characterized in that, in the event of interruptions in or stoppage phases (11) of the operation of the dishwashing machine and/or intervals (14,15) in the feed of the detergent (2,19) or the detergency booster (5), the enzyme-containing detergency booster (5) undergoing enzyme degradation or enzyme decomposition (consumption) under the washing conditions prevailing in an institutional dishwashing machine (23) is added to the wash liquor in a quantity which equalizes the degradation or decomposition (consumption) of enzyme during the particular interruption or stoppage phase (11) and/or feed interval (14,15) so that, after the particular interruption or stoppage phase (11) and/or feed interval (14,15), the operation of the dishwashing machine is continued with substantially the same concentration of enzyme in the wash liquor as was present before the particular interruption or stoppage phase (11) and/or feed interval (14,15).
  15. A process as claimed in any of the preceding claims, characterized in that, immediately after or during the interruptions or stoppage phases (11) and/or the feed intervals (14,15) of the detergent (2,19), the enzyme-containing detergency booster (5) is added to the wash liquor commensurately with the degradation or decomposition (consumption) of enzyme in order to maintain the enzyme concentration.
  16. A process as claimed in any of claims 1 to 15, characterized in that the concentration of enzyme in the wash liquor during the particular interruption or stop-page phase (11) and/or the feed intervals (14,15) of the detergent (2,19) is maintained by maintenance feeding (17,18) of the enzyme-containing detergency booster (5).
  17. A process as claimed in claim 16, characterized in that the maintenance feeding (17,18) takes place in individual feed strokes.
  18. A process as claimed in claim 16 or 17, characterized in that the enzyme input rate of the maintenance feeding regime (17,18) is optimized on the basis of enzyme activity determination.
  19. A process as claimed in any of claims 16 to 18, characterized in that maintenance feeding (17,18) of the enzyme-containing detergency booster (5) is commenced after the enzyme content of the wash liquor has fallen by around 20%.
  20. A process as claimed in any of claims 1 to 15, characterized in that the particular interruption or stoppage phase (11) and/or feed interval (14,15) is immediately followed by surge feeding (SD) in which enzyme-containing detergency booster (5) is added to the wash liquor in a quantity corresponding to the degradation or decomposition (consumption) of enzyme which has taken place during the particular interruption or stop-page phase (11) and/or feed interval (14,15).
  21. A process as claimed in claim 20, characterized in that surge feeding (SD) takes place at a constant rate over a surge feeding period (Vt) substantially equal to V t = V max * (1 - e -lt )
    Figure imgb0006
    where Vmax is the maximum surge feeding time, λ is the reciprocal value of the time constant τ of the enzyme degradation or decomposition (consumption) and t is the duration of the interruption.
  22. An arrangement for carrying out the process claimed in any of claims 1 to 21 comprising a detergent feed system (1,3;20,21,22;24,25) and a feed system (4,6;27,28) for another active substance with an associated pump (4;27) and pump control system, characterized by a feed system (4,6;27,28) for introducing an enzyme-containing detergency booster (5) which is separate from the detergent feed system (1,3;20,21,22;24,25) and which comprises an operational regime for maintenance feeding (17,18) during interruptions in or stoppage phases (11) of the operation of the dishwashing machine and/or feed intervals (14,15) of the detergent feed system (1,3;20,21,22) and/or an operational regime for surge feeding (SD) after interruptions in or stoppage phases (11) of the operation of the dishwashing machine and/or feed intervals (14,15) of the detergent feed system (24,25).
  23. An arrangement as claimed in claim 22, characterized in that the detergent feed system (24,25) is operatively connected to a counter (19) which counts interval pulses during interruptions in or stoppage phases (11) of the operation of the dishwashing machine and/or feed intervals (14,15), the count (n) asymptotically approaching a predetermined end value (nmax) in steps from a starting value in accordance with a function complementary to the decomposition (consumption) of enzyme in the wash liquor, and which counts the count (n) downwards at a constant rate (R) after the particular interruption or stoppage phase (11) and/or feed interval (14,15), controlling the pump (27) for surge feeding (SD) of the enzyme-containing detergency booster (5).
  24. An arrangement as claimed in claim 23, characterized in that the constant downward counting rate (r) is equal to nmax/Vmax, where nmax is the maximum count and Vmax is the maximum surge feeding time.
  25. An arrangement as claimed in claim 24, characterized in that the constant counting rate (R) of the counter (19) is gauged in such a way that, after an interruption lasting at least 5τ (τ = consumption time constant) for the maximum surge feeding time (Vmax), the enzyme concentration (C0) prevailing before the interruption is just reached again.
  26. An arrangement as claimed in any of claims 22 to 25, characterized in that the feed system (4,6;27,28) for the enzyme-containing detergency booster (5) has an additional operational regime for parallel feeding (16) which operates in parallel with the detergent feed system (1,3;24,25) when the detergent feed system is switched on.
  27. An arrangement as claimed in any of claims 22 to 26, characterized in that a frequency-controlled flow inducer (4,27) or a diaphragm pump is used to feed the enzyme-containing detergency booster (5).
  28. An arrangement as claimed in claim 27, characterized in that the associated frequency control system of the pump (4,27) has a first control range (I) for the maintenance feeding regime (17,18) and a second control range (II) - with a far greater output by comparison with the first control range (I) - for the wash phase (10) of the dishwashing machine when the detergent feed system is switched on.
EP94918791A 1993-05-25 1994-05-25 Machine dish-washing process and device Expired - Lifetime EP0700265B2 (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
DE4317295 1993-05-25
DE4317295 1993-05-25
DE4324106 1993-07-17
DE4324106A DE4324106C1 (en) 1993-05-25 1993-07-17 Method and device for the metered addition of active ingredients to a rinsing machine
DE4324202A DE4324202C2 (en) 1993-05-25 1993-07-19 Method and device for machine dishwashing
DE4324202 1993-07-19
PCT/EP1994/001698 WO1994027488A1 (en) 1993-05-25 1994-05-25 Machine dish-washing process and device

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EP0700265A1 EP0700265A1 (en) 1996-03-13
EP0700265B1 true EP0700265B1 (en) 1997-07-30
EP0700265B2 EP0700265B2 (en) 2005-01-05

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EP (1) EP0700265B2 (en)
JP (1) JP3342702B2 (en)
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Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9423234D0 (en) * 1994-11-24 1995-01-04 Unilever Plc Cleaning compositions and their use
GB9423952D0 (en) * 1994-11-24 1995-01-11 Unilever Plc Cleaning compositions and their use
DE19618725A1 (en) * 1996-05-09 1997-11-13 Weigert Chem Fab Method and kit for cleaning dishes
DE19940645A1 (en) * 1999-08-26 2001-03-08 Henkel Ecolab Gmbh & Co Ohg Dishwashing process and dishwasher
JP2009019130A (en) * 2007-07-12 2009-01-29 Adeka Corp Detergent composition and deterging method of dishes using the same
US9388369B2 (en) 2010-08-20 2016-07-12 Ecolab Usa Inc. Wash water maintenance for sustainable practices
US8888924B2 (en) 2012-08-24 2014-11-18 Ecolab Usa Inc. Freestanding detergent composition not requiring an automated dispenser
US20140308162A1 (en) 2013-04-15 2014-10-16 Ecolab Usa Inc. Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing
US9023784B2 (en) 2012-09-13 2015-05-05 Ecolab Usa Inc. Method of reducing soil redeposition on a hard surface using phosphinosuccinic acid adducts
US9994799B2 (en) 2012-09-13 2018-06-12 Ecolab Usa Inc. Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use
US8871699B2 (en) 2012-09-13 2014-10-28 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US9752105B2 (en) 2012-09-13 2017-09-05 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
MX2016005941A (en) 2013-11-11 2016-07-13 Ecolab Usa Inc Multiuse, enzymatic detergent and methods of stabilizing a use solution.
MX2016005852A (en) 2013-11-11 2016-07-13 Ecolab Usa Inc High alkaline warewash detergent with enhanced scale control and soil dispersion.
WO2015197106A1 (en) * 2014-06-24 2015-12-30 Electrolux Appliances Aktiebolag Method for operating a laundry washing appliance and laundry washing appliance implementing the same
JP6955030B2 (en) 2017-04-27 2021-10-27 エコラボ ユーエスエー インコーポレイティド Solid Control Release Carbonate Detergent Composition
EP3710569A1 (en) 2017-11-14 2020-09-23 Ecolab USA Inc. Solid controlled release caustic detergent compositions
CN114222808A (en) 2019-09-27 2022-03-22 埃科莱布美国股份有限公司 Concentrated two-in-one dishwasher detergent and rinse aid

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2038103A1 (en) * 1970-07-31 1972-02-10 Henkel & Cie Gmbh Dish-washing concentrates - contg enzymes, stabilised with sugar alcohols, monosaccharides or disaccharides
DE2062465A1 (en) * 1970-12-18 1972-06-22 Henkel & Cie. GmbH, 4000 Düsseldorf Scouring agent - for dish washing machines, contg aminopolycarboxylic acid and alkali silicate
US3850832A (en) * 1971-12-17 1974-11-26 Henkel & Cie Gmbh Washing, rinsing and cleansing agent compositions containing furan-maleic anhydride copolymer sequestering agents
DE2727463A1 (en) * 1976-06-24 1978-01-05 Procter & Gamble DETERGENT PARTICULARLY SUITABLE FOR USE IN DISHWASHING MACHINES
EP0256679A1 (en) * 1986-08-05 1988-02-24 Imperial Chemical Industries Plc Dishwashing compositions
EP0271155A2 (en) * 1986-12-10 1988-06-15 Unilever N.V. Enzymatic dishwashing and rinsing process
WO1991000044A1 (en) * 1989-06-24 1991-01-10 Henkel Kommanditgesellschaft Auf Aktien Process for operating a dishwasher and device for implementing the process
DE4110764A1 (en) * 1991-04-03 1992-10-08 Weigert Chem Fab METHOD FOR REMOVING STRENGTHY IMPURITIES FROM DISHWARE AND SUITABLE SURFACTANT CONCENTRATES FOR THIS
WO1992018604A1 (en) * 1991-04-12 1992-10-29 Henkel Kommanditgesellschaft Auf Aktien Process for producing detergent tablets for dishwashing machines
WO1993021299A1 (en) * 1992-04-13 1993-10-28 The Procter & Gamble Company Thixotropic liquid automatic dishwashing composition with enzyme
WO1994005768A1 (en) * 1992-09-04 1994-03-17 Henkel Kommanditgesellschaft Auf Aktien Process for producing detergent tablets
EP0368341B1 (en) * 1988-11-11 1996-01-31 Kao Corporation Enzymatic detergent composition

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3319637A (en) * 1966-07-11 1967-05-16 Intercontinental Chem Corp Means for monitoring and maintaining concentration of depletable work solutions
US3490467A (en) * 1966-07-11 1970-01-20 Intercontinental Chem Corp Method of monitoring and maintaining concentration of depletable work solutions
DE1285087B (en) * 1967-11-13 1968-12-12 Miele & Cie Maschinenfabrik Process for cleaning dishes soiled with starchy dishes in dishwashers
DE1728093A1 (en) * 1968-08-24 1972-03-09 Kronwitter Geb Staiber Lieselo Process for cleaning dishes in household dishwashers and means for carrying out the process
US3896827A (en) * 1973-08-31 1975-07-29 Norman R Robinson Dish machine monitoring of time, temperature, alkalinity, and pressure parameters
US4243543A (en) * 1979-05-11 1981-01-06 Economics Laboratory, Inc. Stabilized liquid enzyme-containing detergent compositions
DE3428834A1 (en) * 1984-08-04 1986-02-13 Henkel KGaA, 4000 Düsseldorf DISHWASHER
EP0258068B1 (en) * 1986-08-29 1994-08-31 Novo Nordisk A/S Enzymatic detergent additive
IT1201783B (en) * 1986-11-27 1989-02-02 Zanussi Elettrodomestici PUMPING GROUP IN PARTICULAR FOR DISHWASHER MACHINES
GB8813687D0 (en) * 1988-06-09 1988-07-13 Unilever Plc Enzymatic dishwashing & rinsing composition
GB8813688D0 (en) * 1988-06-09 1988-07-13 Unilever Plc Enzymatic dishwashing composition
JP2936340B2 (en) * 1990-06-08 1999-08-23 大塚薬品工業株式会社 Stabilization of enzyme aqueous solution
US5308530A (en) * 1990-11-21 1994-05-03 Lever Brothers Company, Division Of Conopco, Inc. Detergent compositions containing polycarboxylates and calcium-sensitive enzymes
AU655274B2 (en) * 1991-05-31 1994-12-15 Colgate-Palmolive Company, The Nonaqueous liquid, phosphate-free, improved automatic dishwashing composition containing enzymes
US5173207A (en) * 1991-05-31 1992-12-22 Colgate-Palmolive Company Powered automatic dishwashing composition containing enzymes
US5474699A (en) * 1991-05-31 1995-12-12 Colgate-Palmolive Co. Phosphate containing powered automatic dishwashing composition with enzymes
US5527484A (en) * 1991-05-31 1996-06-18 Colgate-Palmolive Co. Phosphate containing powdered automatic dishwashing composition with enzymes

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2038103A1 (en) * 1970-07-31 1972-02-10 Henkel & Cie Gmbh Dish-washing concentrates - contg enzymes, stabilised with sugar alcohols, monosaccharides or disaccharides
DE2062465A1 (en) * 1970-12-18 1972-06-22 Henkel & Cie. GmbH, 4000 Düsseldorf Scouring agent - for dish washing machines, contg aminopolycarboxylic acid and alkali silicate
US3850832A (en) * 1971-12-17 1974-11-26 Henkel & Cie Gmbh Washing, rinsing and cleansing agent compositions containing furan-maleic anhydride copolymer sequestering agents
DE2727463A1 (en) * 1976-06-24 1978-01-05 Procter & Gamble DETERGENT PARTICULARLY SUITABLE FOR USE IN DISHWASHING MACHINES
EP0256679A1 (en) * 1986-08-05 1988-02-24 Imperial Chemical Industries Plc Dishwashing compositions
EP0271155A2 (en) * 1986-12-10 1988-06-15 Unilever N.V. Enzymatic dishwashing and rinsing process
EP0368341B1 (en) * 1988-11-11 1996-01-31 Kao Corporation Enzymatic detergent composition
WO1991000044A1 (en) * 1989-06-24 1991-01-10 Henkel Kommanditgesellschaft Auf Aktien Process for operating a dishwasher and device for implementing the process
EP0578666B1 (en) * 1991-04-03 1995-02-08 CHEMISCHE FABRIK DR. WEIGERT (GMBH & CO.) Process for removing starch-containing impurities from crockery and suitable tenside compositions
DE4110764A1 (en) * 1991-04-03 1992-10-08 Weigert Chem Fab METHOD FOR REMOVING STRENGTHY IMPURITIES FROM DISHWARE AND SUITABLE SURFACTANT CONCENTRATES FOR THIS
WO1992018604A1 (en) * 1991-04-12 1992-10-29 Henkel Kommanditgesellschaft Auf Aktien Process for producing detergent tablets for dishwashing machines
WO1993021299A1 (en) * 1992-04-13 1993-10-28 The Procter & Gamble Company Thixotropic liquid automatic dishwashing composition with enzyme
WO1994005768A1 (en) * 1992-09-04 1994-03-17 Henkel Kommanditgesellschaft Auf Aktien Process for producing detergent tablets

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GR3024425T3 (en) 1997-11-28
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US6718991B1 (en) 2004-04-13
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FI955612A (en) 1995-11-22
CA2163757C (en) 2004-09-07
NO311123B1 (en) 2001-10-15
FI955612A0 (en) 1995-11-22
JP3342702B2 (en) 2002-11-11
WO1994027488A1 (en) 1994-12-08
NO954592D0 (en) 1995-11-14
EP0700265B2 (en) 2005-01-05
JPH08510397A (en) 1996-11-05
ES2105725T3 (en) 1997-10-16
DK0700265T3 (en) 1998-03-16
ATE155987T1 (en) 1997-08-15
TR28788A (en) 1997-03-25
CA2163757A1 (en) 1994-12-08

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