EP0699769A1 - Verfahren zur Herstellung eines tiefziehfähigen Verpackungsstahlen und nach diesem Verfahren hergestellter Stahl - Google Patents
Verfahren zur Herstellung eines tiefziehfähigen Verpackungsstahlen und nach diesem Verfahren hergestellter Stahl Download PDFInfo
- Publication number
- EP0699769A1 EP0699769A1 EP95401091A EP95401091A EP0699769A1 EP 0699769 A1 EP0699769 A1 EP 0699769A1 EP 95401091 A EP95401091 A EP 95401091A EP 95401091 A EP95401091 A EP 95401091A EP 0699769 A1 EP0699769 A1 EP 0699769A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel
- ppm
- nitrogen
- under vacuum
- stamped
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims description 57
- 239000010959 steel Substances 0.000 title claims description 57
- 238000000034 method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 60
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 28
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 238000007872 degassing Methods 0.000 claims abstract description 9
- 238000007664 blowing Methods 0.000 claims abstract description 4
- 238000004806 packaging method and process Methods 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 238000005096 rolling process Methods 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 238000000137 annealing Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 239000010955 niobium Substances 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 238000005261 decarburization Methods 0.000 claims description 3
- 238000009849 vacuum degassing Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000004411 aluminium Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 241000397921 Turbellaria Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/10—Handling in a vacuum
Definitions
- the subject of the present invention is a method for producing a steel for packaging suitable for deep drawing and little sensitive to the formation of horns during stamping, and a steel obtained from this process.
- the present invention is particularly applicable to the production of very thin products obtained by deep drawing of the stamped-re-stamped boxes or stamped-ironed boxes type.
- a sheet blank is stamped, generally made of a metal which has undergone a rolling operation, so that this metal has an anisotropy with regard to its resistance to thinning.
- this collar has a sinuous profile comprising "horns" and “hollow horns”.
- this irregularity is located at the end of the peripheral skirt and this irregularity creates a certain number of obstacles during subsequent operations.
- This anisotropy of the metal with regard to its resistance to thinning is also responsible for the formation of folds or ripples in certain areas during stamping.
- This anisotropy of the metal is translated by two coefficients, well known in the technique of stamping, in particular of swaged stamping, the Lankford coefficient r and the coefficient of planar anisotropy ⁇ r.
- the Lankford coefficient r is representative of the resistance to thinning of the metal used in the direction in lacquer! The it is determined.
- the direction in which the Lankford coefficient is highest corresponds to the direction in which the metal flows easily and therefore does not form folds during stamping and therefore at the position of the horns.
- the direction in which the Lankford coefficient is the lowest corresponds to the direction in which the metal has a high resistance to sliding and therefore forms folds during drawing and therefore to the direction of the hollow of the horn.
- This planar anisotropy coefficient ⁇ r is representative of the ability of the sheet blank to present horns and horn recesses when stamped.
- Such steels have a carbon content of the order of 200 to 800 ppm (parts per million) and exhibit, after having undergone a roll-hardening operation, known as a skin pass operation, with a skin pass reduction rate of of the order of 25%, relatively high mechanical characteristics (Rm of the order of 620 MPa).
- planar anisotropy coefficient ⁇ r after the skin pass operation with a reduction rate of around 25% is in the range of 0.15 to 0.20.
- re-rolling with the skin pass has the effect of degrading certain properties such as for example the elongation percent after rupture and the planar anisotropy coefficient ⁇ r.
- planar anisotropy coefficient ⁇ r of an ultra low carbon steel degassed under vacuum with low nitrogen content goes from 0.16 for a rate 25% reduction in skin pass to 0.28 for a skin pass reduction rate of around 35%.
- the subject of the present invention is a process for the preparation of a steel for packaging allowing, at the same reduction rate as the skin pass, to obtain mechanical characteristics substantially equal to those of mild steel which is not degassed under vacuum and properties stamping substantially identical to that of an ultra-low carbon steel degassed under vacuum with low nitrogen content.
- the present invention relates more particularly to a method of producing a steel for packaging suitable for deep drawing and little sensitive to the formation of horns during drawing, in which a low carbon steel is produced by vacuum degassing in a decarburization chamber, characterized in that after degassing under vacuum, nitrogen is blown into the steel bath to add to said steel 80 to 140 ppm of nitrogen.
- the present invention also relates to a steel for packaging suitable for deep drawing and not very sensitive to the formation of horns during stamping produced by the above process, characterized in that after its preparation, it is hot rolled and / or cold rolled, it undergoes continuous or base annealing, and it undergoes hardening by light rolling.
- the present invention also relates to the use of a steel as described above for the production of very thin products obtained by deep drawing of the stamped-re-stamped boxes or stamped-ironed boxes.
- the present invention relates to a steel for packaging suitable for deep drawing and not very sensitive to the formation of horns during stamping, particularly useful for the production of very thin products obtained by deep drawing, in particular by shrinking stamping, of the box type. stamped-stamped or stamped-ironed boxes.
- This steel is a low carbon steel produced in a known manner, using a steelworks converter, then degassed under vacuum in a decarburization chamber.
- the added nitrogen content must be greater than 80 ppm, since a lower content would not be sufficiently effective and the mechanical characteristics of the steel would not be increased significantly enough.
- the added nitrogen content must also be less than 140 ppm, because if more than 140 ppm of nitrogen is added, the steel becomes too effervescent and very difficult or almost impossible to flow.
- the steel after its production according to the process described above is then cast, hot rolled and / or cold rolled, it undergoes continuous annealing or annealing on base, and it undergoes hardening by light rolling in a finishing train. , also called skin pass operation.
- a first series of blanks was produced from mild steel of standard type with 800 ppm carbon, cold rolled, annealed and having undergone a skin pass operation with a reduction rate of 25%.
- This steel was also cold rolled, annealed and subjected to a skin pass operation with a reduction rate of 25%, under conditions identical to the first series of blanks.
- This steel was then subjected to the same rolling, annealing and skin pass treatment as the other two.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Vacuum Packaging (AREA)
- Packages (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9410361A FR2723964B1 (fr) | 1994-08-29 | 1994-08-29 | Procede d'elaboration d'un acier pour emballage apte a un emboutissage profond et acier obtenu par ce procede |
FR9410361 | 1994-08-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0699769A1 true EP0699769A1 (de) | 1996-03-06 |
EP0699769B1 EP0699769B1 (de) | 1999-11-17 |
Family
ID=9466529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95401091A Revoked EP0699769B1 (de) | 1994-08-29 | 1995-05-11 | Verfahren zur Herstellung eines tiefziehfähigen Verpackungsstahlen und nach diesem Verfahren hergestellter Stahl |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0699769B1 (de) |
AT (1) | ATE186753T1 (de) |
DE (1) | DE69513347T2 (de) |
ES (1) | ES2141311T3 (de) |
FR (1) | FR2723964B1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8012276B2 (en) | 2004-06-18 | 2011-09-06 | Nippon Steel Corporation | Method for manufacturing a steel sheet for tin plated steel sheet and tin-free steel sheet each having excellent formability |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014112286A1 (de) * | 2014-08-27 | 2016-03-03 | Thyssenkrupp Ag | Verfahren zur Herstellung eines aufgestickten Verpackungsstahls |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1120668A (en) * | 1965-07-09 | 1968-07-24 | Maximilianshuette Eisenwerk | Method of producing low-carbon steel sheet |
GB1182144A (en) * | 1966-02-26 | 1970-02-25 | Hoerder Huettenunion Ag | Method of producing a Drawing and Deep Drawing Steel Resistant to Ageing, particularly for Single-Coat Enamelling |
FR2078273A5 (en) * | 1970-02-06 | 1971-11-05 | Armco Steel Corp | Low carbon, iron-contng enamel |
FR2083682A1 (en) * | 1970-03-31 | 1971-12-17 | Nippon Steel Corp | Steel sheet for deep drawn cans |
EP0521808A1 (de) * | 1991-07-04 | 1993-01-07 | Sollac | Verfahren zum Herstellen von Tiefziehblechen |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6428319A (en) * | 1987-07-24 | 1989-01-30 | Nippon Kokan Kk | Production of nitrogen-containing steel |
EP0659890B1 (de) * | 1993-12-21 | 2000-03-29 | Kawasaki Steel Corporation | Verfahren zum Herstellen von dünnen Stahlblechen mit niedriger planarer Anisotropie für Dosen |
-
1994
- 1994-08-29 FR FR9410361A patent/FR2723964B1/fr not_active Expired - Fee Related
-
1995
- 1995-05-11 AT AT95401091T patent/ATE186753T1/de not_active IP Right Cessation
- 1995-05-11 DE DE69513347T patent/DE69513347T2/de not_active Revoked
- 1995-05-11 EP EP95401091A patent/EP0699769B1/de not_active Revoked
- 1995-05-11 ES ES95401091T patent/ES2141311T3/es not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1120668A (en) * | 1965-07-09 | 1968-07-24 | Maximilianshuette Eisenwerk | Method of producing low-carbon steel sheet |
GB1182144A (en) * | 1966-02-26 | 1970-02-25 | Hoerder Huettenunion Ag | Method of producing a Drawing and Deep Drawing Steel Resistant to Ageing, particularly for Single-Coat Enamelling |
FR2078273A5 (en) * | 1970-02-06 | 1971-11-05 | Armco Steel Corp | Low carbon, iron-contng enamel |
FR2083682A1 (en) * | 1970-03-31 | 1971-12-17 | Nippon Steel Corp | Steel sheet for deep drawn cans |
EP0521808A1 (de) * | 1991-07-04 | 1993-01-07 | Sollac | Verfahren zum Herstellen von Tiefziehblechen |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8012276B2 (en) | 2004-06-18 | 2011-09-06 | Nippon Steel Corporation | Method for manufacturing a steel sheet for tin plated steel sheet and tin-free steel sheet each having excellent formability |
Also Published As
Publication number | Publication date |
---|---|
DE69513347D1 (de) | 1999-12-23 |
FR2723964B1 (fr) | 1997-03-14 |
ATE186753T1 (de) | 1999-12-15 |
ES2141311T3 (es) | 2000-03-16 |
DE69513347T2 (de) | 2000-07-27 |
FR2723964A1 (fr) | 1996-03-01 |
EP0699769B1 (de) | 1999-11-17 |
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