EP0696661B1 - Multifunctionnal textile agents compositions - Google Patents

Multifunctionnal textile agents compositions Download PDF

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Publication number
EP0696661B1
EP0696661B1 EP95810494A EP95810494A EP0696661B1 EP 0696661 B1 EP0696661 B1 EP 0696661B1 EP 95810494 A EP95810494 A EP 95810494A EP 95810494 A EP95810494 A EP 95810494A EP 0696661 B1 EP0696661 B1 EP 0696661B1
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EP
European Patent Office
Prior art keywords
weight
alkyl
hydrogen
methyl
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95810494A
Other languages
German (de)
French (fr)
Other versions
EP0696661A1 (en
Inventor
Rainer Hans Dr. Traber
Albert Stehlin
Vladimir Dr. Arnold
Rolf Kuratli
Werner Schreiber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
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Publication date
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Publication of EP0696661A1 publication Critical patent/EP0696661A1/en
Application granted granted Critical
Publication of EP0696661B1 publication Critical patent/EP0696661B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2034—Monohydric alcohols aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2048—Dihydric alcohols branched
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2058—Dihydric alcohols aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3788—Graft polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
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    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/14—De-sizing
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    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
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    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/614—Optical bleaching or brightening in aqueous solvents
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
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    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/272—Unsaturated compounds containing sulfur atoms
    • D06M13/278—Vinylsulfonium compounds; Vinylsulfone or vinylsulfoxide compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
    • D06M13/447—Phosphonates or phosphinates containing nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/667—Organo-phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear

Definitions

  • the present invention relates to storage-stable, low-foam, silicone-free, aqueous Textile auxiliaries, their production and multiple uses e.g. as a wetting agent, Detergents, dispersants or as stabilizers in peroxide bleaching liquors.
  • Components (a) to (g) can each consist of individual compounds or else be composed of several individual connections.
  • the substituents R 6 and R 7 in the formulas (4) and (5) advantageously represent the hydrocarbon radical of a saturated aliphatic monoalcohol.
  • the hydrocarbon radical can be straight-chain or branched.
  • aliphatic saturated monoalcohols natural alcohols, such as, for example, lauryl alcohol, myristyl alcohol, cetyl alcohol or stearyl alcohol, and synthetic alcohols, such as, for example, 2-ethylhexanol, 1,1,3,3-tetramethylbutanol, octan-2-ol, isononyl alcohol, trimethylhexanol, trimethylnonyl alcohol
  • Decanol, C 9 -C 11 oxo alcohol, tridecyl alcohol, isotridecanol or linear primary alcohols (alfoles) can be used. Some representatives of these alfoles are Alfol (8-10), Alfol (9-11), Alfol (10-14), Alfol (12-13) or Alfol (16-18).
  • Alfol is a registered trademark).
  • the alcohol residues can be present individually or in the form of mixtures of two or more components.
  • are preferably divalent radicals of the formulas R 4 represents the straight-chain hydrocarbon radical of a saturated aliphatic monoalcohol with 8 to 14 carbon atoms, ie n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl or n-tetradecyl.
  • R 5 in formula (3) in the meaning of C 1 -C 8 alkyl is the methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl or tert-butyl radical.
  • R 5 is preferably the n-butyl radical.
  • cycloaliphatic radical examples include cycloheptyl, cyclooctyl or preferably Cyclohexyl.
  • nonionic surfactants which correspond to component (a) are Addition products of 3 to 15 mol, preferably 4 to 10 mol, of alkylene oxides, in particular Ethylene oxide, where individual ethylene oxide units are substituted by substituted epoxides, such as propylene oxide, can be replaced, to higher saturated fatty alcohol with 8 to 13 or 8 to 18 carbon atoms, or mixtures of these compounds.
  • monomeric starting compounds for the preparation of the polymeric compounds of Component (b) are called acrylic acid and methacrylic acid.
  • Free radicals are preferably used as catalysts for the production of component (b) forming organic initiators used.
  • Suitable initiators for implementation radical polymerization are e.g. symmetrical aliphatic azo compounds such as azo-bis-isobutyronitrile, azo-bis-2-methylvaleronitrile, 1,1'-azo-bis-1-cyclohexanitrile and 2,2'-azo-bis-isobutyric acid alkyl ester; symmetrical diacyl peroxides, such as e.g.
  • Suitable peroxides are: tert-butyl hydroperoxide, Di-tert-butyl peroxide, cumene hydroperoxide, di-cumene peroxide and tert-butyl perpivalate.
  • Another suitable compound is potassium persulfate, which is used in the manufacture component (b) is preferably used.
  • the catalysts are generally used in amounts of 0.1 to 10% by weight, preferably 0.5 to 2 wt .-%, based on the starting products, used.
  • Component (b) is preferably in the form of a partially neutralized compound Has a pH of 3 to 6.
  • the polymeric compound is produced e.g. by reacting acrylic acid or methacrylic acid in the presence of a nonionic Surfactants of the formula (5) or in the presence of mixtures of nonionic surfactants Formula (5).
  • the reaction product is then mixed with an inorganic and / or organic base to a pH of 3 to 6, preferably 4 to 5, partially neutralized.
  • bases one uses e.g. 1 to 8% by weight inorganic or organic bases, such as.
  • the polymerization is advantageously carried out in an inert atmosphere, e.g. in the presence of Nitrogen.
  • Exemplary compounds of the formula (6) are benzyl alcohol, 2,4-dichlorobenzyl alcohol, Phenylethanol, phenoxyethanol, 1-phenoxy-2-propanol (phenoxyisopropanol) and cinnamon alcohol.
  • organic acids mentioned can also be in the form of their water-soluble salts, such as the alkali metal, in particular sodium or potassium salts or the amine salts are present.
  • alkyl sulfate is present as a salt, sodium, potassium or Ammonium salts into consideration.
  • the sodium salt is preferred.
  • the aliphatic saturated radical R 11 is derived from monoalcohols. Natural or synthetic alcohols can be used. Examples of natural alcohols are lauryl, myristyl, cetyl, stearyl, arachidyl or behenyl alcohol.
  • R 11 is derived from branched aliphatic synthetic alcohols having 4 to 12, in particular 4 to 8, carbon atoms, for example isobutyl alcohol, sec-butanol, tert-butanol, isoamyl alcohol, 2-ethylbutanol, 2-methylpentanol, 5-methylheptane -3-ol, 2-ethylhexanol, 1,1,3,3-tetramethylbutanol, octan-2-ol, isononyl alcohol, trimethylhexanol, trimethylnonyl alcohol, n-decanol or C 9 -C 11 oxo alcohol.
  • alkyl sulfates can already be in the form of their salts and alone or as (Technical) mixture with each other used in the wetting agent according to the invention become.
  • hydrotroping agents of the formula (7) are 2-ethylhexyl sulfate.
  • alkyl sulfates are prepared by reaction in a manner known per se the corresponding alcohols with e.g. Sulfuric acid, oleum, chlorosulfonic acid or sulfur trioxide.
  • hydrotroping agents used according to the invention are the amphoteric surfactants: Sodium laurimino dipropionate, dihydroxyethyl tallow fat glycinate, disodium cocoamphodiacetate, Disodium capryloamphodiacetate or preferably disodium dicarboxyethyl cocopropylene diamine or tallow amphopolycarboxyglycinate.
  • Examples of the end-capped nonionic surfactants of component (d) are C 10 -C 12 fatty alcohol-ethylene oxide or ethylene oxide / propylene oxide addition products or the reaction product of one mole of a C 10 fatty alcohol with 6 moles of ethylene oxide and 1 mole of butylene oxide name, where the addition products can be end-capped with C 1 -C 4 alkyl, preferably methyl or butyl.
  • the nonionic surfactants of the formulas (4) and (5) are prepared in a manner known per se, for example by reacting the corresponding alkylene oxide adducts with thionyl chloride and then reacting the chlorine compound formed with a saturated aliphatic C 8 -C 13 or C 8 -C 18 mono alcohol.
  • the end-capped nonionic surfactants of the formula (3) are prepared in a manner known per se, for example by reacting ethylene oxide and / or propylene oxide and / or butylene oxide in the corresponding molar ratios with one mole of the alcohol R 4 -OH, and subsequent reaction of the adduct formed with an alkyl halide R 5 -Hal, preferably C 1 -C 4 -alkyl chloride.
  • the optional component (s) are salts of gluconic acid, citric acid, Malic acid, lactic acid, L-glutamic acid and L-aspartic acid.
  • the magnesium salts of gluconic acid are used as component (e) and especially magnesium mono- or magnesium digluconate.
  • the magnesium gluconate can be in the composition according to the invention as such and preferably be used as a solid.
  • this can Gluconate can also be formed from gluconic acid and magnesium oxide or in situ preferably magnesium hydroxide.
  • Gluconic acid or its sodium salt can also be used in Combination with a water-soluble magnesium salt can be used.
  • water soluble Magnesium salt comes here the acetate, especially the sulfate or its Heptahydrate and especially the chloride or its hexahydrate.
  • the Magnesium salt is usually used as a solid, with solid magnesium chloride hexahydrate is in the foreground.
  • the mixtures of the monomeric and oligomeric compounds of the type indicated are known per se and are prepared by known methods.
  • the mixture of the formulas (10a) and (10b) is preferably prepared by reacting phosphorus trichloride, acetic acid and optionally acetic anhydride in an aqueous medium.
  • the oligomeric components (f 1 ) are at least partially hydrolyzed in the aqueous composition according to the invention in the presence of an alkali metal hydroxide to give the corresponding monomeric compounds.
  • component (f 1 ) of the compositions according to the invention are also, above all, monomeric compounds of one of the formulas (9a) or (10a).
  • Component (f 1 ) is preferably used in the composition according to the invention as 35 to 90, preferably 40 to 85, in particular 40 to 60 percent by weight aqueous solution.
  • component (f 4 ) examples include nitrilotrimethylenephosphonic acid, the Na salt of ethylenediamine-tetramethylenephosphonic acid, the Na salt of diethylenetriamine-pentamethylenephosphonic acid or N, N-bis (phosphonomethyl) glutamic acid.
  • Compounds of component (f) act as complexing agents for alkaline earth and heavy metals in aqueous liquors containing a per-compound, e.g. Contain hydrogen peroxide, in pretreatment, especially in bleaching processes of cellulosic fiber materials.
  • a per-compound e.g. Contain hydrogen peroxide
  • the presence of these components causes decomposition the per-connection by free, i.e. heavy metals not present as a complex, which are present in the process water of the fiber material or in the added alkali can suppressed.
  • Suitable as component (g) are dihydric or polyhydric alcohols.
  • bivalent Alcohols are in particular those with 2 to 6 carbon atoms in the alkylene part, such as ethylene glycol, 1,2- or 1,3-propanediol, 1,3-, 1,4- or 2,3-butanediol, 1,5-pentanediol and 1,6-hexanediol or to name 2-methyl-2,4-pentanediol.
  • the latter connection is in the composition according to the invention is preferably used.
  • polyhydric alcohols examples include glycerol, erythritol, the pentites, e.g. arabitol, Adonite and xylitol as well as the hexites such as D-sorbitol, D-mannitol and dulcitol.
  • the textile auxiliaries according to the invention can be prepared by adding components (a), (b), (c), and optionally (d), (e), (f) and (g) in water (component (h)) or by mixing the corresponding components with stirring and add deionized water until a homogeneous solution is obtained. It is about a purely mechanical process, which may take place at elevated temperature, for example from 30 to 40 ° C is carried out. A chemical reaction takes place not instead.
  • component (b) is first reacted from 5 to 45 % By weight of a nonionic surfactant of the formula (5) with 45 to 5% by weight of acrylic acid or methacrylic acid in the presence of a free radical class catalyst forming organic initiators, and then partial neutralization to one pH of 3 to 6 with 1 to 8 wt .-% of an inorganic or organic base manufactures, adjusts the pH to about 4.5 and then the remaining components add until a homogeneous solution is obtained.
  • a nonionic surfactant of the formula (5) with 45 to 5% by weight of acrylic acid or methacrylic acid in the presence of a free radical class catalyst forming organic initiators, and then partial neutralization to one pH of 3 to 6 with 1 to 8 wt .-% of an inorganic or organic base manufactures, adjusts the pH to about 4.5 and then the remaining components add until a homogeneous solution is obtained.
  • the finished textile auxiliaries have a pH of z. B. 2 to 5, preferably from 2.5 to 3.5.
  • the pH value always refers to a 1% aqueous solution of the formulation according to the invention.
  • the desired pH is used e.g. magnesium hydroxide, Potassium hydroxide, mono-, di- or triethanolamine and especially sodium hydroxide.
  • the new formulations provide storage-stable, single-phase, low-foam and silicone-free Textile auxiliaries with good complexing and sequestering properties dirt-removing effect. They show good emulsifying power and are alkaline Fleet stable. In alkaline bleaching liquors, they have no creams or deposits on. They also have good peroxide-stabilizing properties and cause good rewettability of the textile goods. In addition, the wording readily biodegradable. They are characterized by their liquid trading form easy handling, which is why they are particularly suitable for modern dosing systems are suitable.
  • the universal applicability of the formulations according to the invention enables various applications. For example, as a wetting agent, textile detergent, Dispersant or used as a stabilizer in peroxide bleaching liquors become. They are also ideal as a universal household detergent.
  • the present invention accordingly also relates to a method for wetting, Washing and / or bleaching fiber materials, which is characterized in that to these materials in an aqueous medium in the presence of one defined in claim 1 Textile auxiliaries treated.
  • the amounts in which the textile auxiliaries according to the invention are added to the treatment liquors added are 0.1 to 60, preferably 1 to 20 g per liter of treatment liquor.
  • These fleets can also contain other additives, e.g. desizing, Dyes, optical brighteners, alkalis such as sodium hydroxide and hydrogen peroxide.
  • Possible fiber materials are: cellulose, in particular untreated natural ones Cellulose such as Hemp, linen, jute, rayon, viscose, acetate treyon, native cellulose fiber and especially raw cotton, wool, polyamide, polyacrylonitrile or polyester fiber materials as well as fiber blends, e.g. those made of polyacrylonitrile / cotton or polyester / cotton.
  • the fiber material to be treated can be in different processing stages, so e.g. the cellulose-containing material as loose material, yarn, woven or knitted fabric. As a rule, these are always textile fiber materials made from pure textile cellulose fibers or from mixtures of textile cellulose fibers with textile synthetic fibers getting produced.
  • the fiber material can be continuous or discontinuous be treated in an aqueous liquor.
  • the aqueous treatment liquors can be applied to the fiber materials in a known manner be applied, advantageously by impregnation on the foulard, the liquor intake is about 70 to 120% by weight.
  • the padding process comes in particular for pad-steam and pad-batch processes.
  • the impregnation can be carried out at 10 to 60 ° C, but preferably at room temperature become.
  • the cellulose material optionally heat treatment, e.g. Subject at temperatures from 80 to 140 ° C.
  • the heat treatment is preferably carried out by steaming at 95 to 140, in particular at 100 to 106 ° C. Depending on the type of heat development and the temperature range the heat treatment can take 30 seconds to 60 minutes.
  • the impregnated goods are rolled up without drying and then optionally wrapped with plastic wrap, and at room temperature 1 to 24 Stored for hours.
  • the treatment of the fiber materials can also in long liquors with a liquor ratio from e.g. 1: 3 to 1: 100, preferably 1: 4 to 1:25 and 10 to 100, preferably 60 to 98 ° C for about 1/4 to 3 hours under normal conditions, i.e. under atmospheric pressure in conventional equipment, e.g. a jigger, jet or one Reel skids take place. If necessary, however, the treatment can also be carried out up to 150 ° C., preferably 105 to 140 ° C under pressure in so-called high-temperature equipment (HT equipment) be performed.
  • HT equipment high-temperature equipment
  • the fiber materials are then, if required by the process, with hot Water from about 90 to 98 ° C and then with warm and finally with cold water rinsed thoroughly, neutralized if necessary and then preferably at elevated Temperatures dried.
  • Example 3 The following components are mixed with one another with stirring:
  • the formulation is used as a textile auxiliary for alkaline digestion processes, Leach and mercerize.
  • Example 4 The following components are mixed with one another with stirring:
  • the formulation is used as a textile auxiliary for alkaline Digestion process, leaching and mercerization.
  • Example 5 The following components are mixed with one another with stirring:
  • the formulation is used as a textile aid for cold storage peroxide bleaching.
  • Example 6 The following components are mixed with one another with stirring:
  • the formulation is used as a textile aid for boiling and bleaching processes.
  • Example 7 The following components are mixed with one another with stirring:
  • the formulation is used as a textile aid for pad steam peroxide bleaching.
  • Example 8 The following components are mixed with one another with stirring:
  • the formulation is used as a textile aid for pad steam peroxide bleaching.
  • Example 9 The following components are mixed with one another with stirring:
  • Example 10 The following components are mixed with one another with stirring:
  • Example 11 The following components are mixed with one another with stirring:
  • Example 12 The following components are mixed with one another with stirring:
  • Example 13 The following components are mixed with one another with stirring:
  • Example 14 Alkaline digestion using the pad-steam method
  • Raw cotton fabric is impregnated on a foulard at room temperature with a treatment liquor of the following composition: 2 g / l of the textile auxiliary produced according to Example 4 and 30 g / l NaOH (100%).
  • the fleet intake is 100%.
  • the goods are then fed into a steamer with saturated steam at 102 ° C for 10 minutes and then washed out with hot water.
  • the result is a desized product with high absorbency.
  • Example 1 5 Cold storage peroxide bleach
  • Raw cotton fabric is impregnated on a foulard at room temperature with a treatment liquor of the following composition: 12 g / l the textile auxiliary produced according to Example 5, 30 g / l NaOH (100%) and 50 ml / l Hydrogen peroxide.
  • the fleet intake is 100%.
  • the damp goods are wound up on a dock, packed with plastic wrap and with slow rotation of the dock 20 hours Stored at room temperature. The goods are then washed out with hot water. The result is an absorbent fabric with a high degree of whiteness and only low Fiber damage.
  • Raw cotton fabric is sprayed with a treatment liquor of the following composition: 20 g / l of the textile auxiliary produced according to Example 8 40 g / l NaOH (100%) and 30 ml / l Hydrogen peroxide (35%).
  • the spraying takes place e.g. in a Raco-Yet system from Rimisch-Kleinwefers.
  • the order quantity is 140%.
  • the damp goods are kept in a steamer for 2 hours treated with saturated steam at 102 ° C and then washed out with hot water.
  • the result is an absorbent fabric with a high degree of whiteness and little fiber damage.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)
  • Biological Depolymerization Polymers (AREA)

Description

Die vorliegende Erfindung betrifft lagerstabile, schaumarme, silikonfreie, wässrige Textilhilfsmittel, ihre Herstellung und vielfache Verwendung z.B. als Netzmittel, Waschmittel, Dispergiermittel oder als Stabilisatoren in Peroxid-Bleichflotten.The present invention relates to storage-stable, low-foam, silicone-free, aqueous Textile auxiliaries, their production and multiple uses e.g. as a wetting agent, Detergents, dispersants or as stabilizers in peroxide bleaching liquors.

Die erfindungsgemässen Textilhilfsmittel enthalten

  • (a) 10 bis 60 Gew.% ein nichtionogenes Tensid der Formel
    Figure 00010001
  • (b) 10 bis 60 Gew.% einer polymeren Verbindung, hergestellt durch Umsetzung von 5 bis 45 Gew.-% eines oder mehrerer nichtionogener Tenside der Formel
    Figure 00010002
    mit 45 bis 5 Gew.-% Acrylsäure oder Methacrylsäure in Anwesenheit eines Katalysators aus der Klasse der freien Radikale bildenden organischen Initiatoren, und anschliessender Teilneutralisation auf einen pH-Wert von 3 bis 6 mit 1 bis 8 Gew.-% einer anorganischen oder organischen Base und
  • (c) 4 bis 20 Gew.% eines Hydrotropiermittels
    - aromatischen Alkohole der Formel
    Figure 00010003
    worin
  • X1 -(CH2)1-6-, -CH=CH-CH2- oder -O-(CH2)2-6- und
  • R8, R9 und R10, unabhängig voneinander, Wasserstoff, Hydroxy, Halogen oder C1-C6-Alkoxy
    -Verbindungen der Formel
    • (7)   R11O-SO3X2, worin
  • R11 einen aliphatischen gesättigten, verzweigten oder geradkettigen Rest mit 4 bis 24 Kohlenstoffatomen und X2 Wasserstoff, Alkalimetall oder Ammonium bedeutet,
    • ein amphoteres Tensid, ausgewählt aus der Natriumlauriminodipropionat, Dihydroxyethyl-talgfettglycinat, Dinatriumcocoamphodiacetat, Dinatriumcapryloamphodiacetat oder vorzugsweise Dinatriumdicarboxyethylcocopropylendiamin oder Talgfettamphopolycarboxyglycinat
  • (d) 0 bis 20 Gew.% eines nichtionogenen Tensids der Formel
    Figure 00020001
  • (e) 0 bis 8 Gew.% eines Magnesiumsalzes einer organischen Carbonsäure
  • (f) 0 bis 30 Gew.% eines Komplexier- oder Sequestriermittels ausgewählt aus
    (f1)
    einem Gemisch aus monomeren und oligomeren Verbindungen entsprechend den Formeln
    Figure 00020002
    und
    Figure 00020003
       worin
  • Y7 Wasserstoff oder -COT1,
  • R14, X3 und T1 unabhängig voneinander jeweils C1-C4-Alkyl und
  • q1 1 bis 16 bedeuten,
    •
    (f2)
    D-Gluconsäure,
    (f3)
    Zitronensäure und
    (f4)
    Aminophosphonsäure,
  • (g) 0 bis 10 Gew.% eines Diols oder Polyols und
  • (h) 0 bis 60 % Wasser,
    •  wobei einer der Komponenten (e) bis (g) im Textilhilfsmittel immer vorhanden sein muss,
    worin in den Formeln (3), (4) und (5)
    R4
    C9 bis C14-Alkyl,
    R5
    C1 bis C8-Alkyl, einen cycloaliphatischen Rest mit mindestens 5 C-Atomen, Niederalkylphenyl oder Styryl,
    R6
    C8-C13-Alkyl,
    R7
    C8-C18-Alkyl,
    Y1, Y2, Y3 und Y4,
    unabhängig voneinander Wasserstoff, Methyl oder Ethyl, wobei einer der Reste Y1, Y2 bzw. Y3, Y4 immer Wasserstoff ist,
    Y5
    Wasserstoff oder Methyl,
    Y6
    Wasserstoff, Methyl oder Ethyl,
    m2
    3 bis 15
    p1
    eine ganze Zahl von 4 bis 10 und
    p2
    eine ganze Zahl von 0 bis 8,
    bedeuten.The textile auxiliaries according to the invention contain
  • (a) 10 to 60% by weight of a nonionic surfactant of the formula
    Figure 00010001
  • (b) 10 to 60% by weight of a polymeric compound, prepared by reacting 5 to 45% by weight of one or more nonionic surfactants of the formula
    Figure 00010002
    with 45 to 5% by weight of acrylic acid or methacrylic acid in the presence of a catalyst from the class of free radical-forming organic initiators, and then partial neutralization to a pH of 3 to 6 with 1 to 8% by weight of an inorganic or organic base and
  • (c) 4 to 20% by weight of a hydrotroping agent
    - aromatic alcohols of the formula
    Figure 00010003
    wherein
  • X 1 - (CH 2 ) 1-6 -, -CH = CH-CH 2 - or -O- (CH 2 ) 2-6 - and
  • R 8 , R 9 and R 10 , independently of one another, are hydrogen, hydroxy, halogen or C 1 -C 6 alkoxy
    Compounds of the formula
    • (7) R 11 O-SO 3 X 2 , wherein
  • R 11 is an aliphatic saturated, branched or straight-chain radical having 4 to 24 carbon atoms and X 2 is hydrogen, alkali metal or ammonium,
    • an amphoteric surfactant selected from sodium laurimino dipropionate, dihydroxyethyl tallow fat glycinate, disodium cocoamphodiacetate, disodium capryloamphodiacetate or preferably disodium dicarboxyethyl cocopropylene diamine or tallow fat amphopolycarboxyglycinate
  • (d) 0 to 20% by weight of a nonionic surfactant of the formula
    Figure 00020001
  • (e) 0 to 8% by weight of a magnesium salt of an organic carboxylic acid
  • (f) 0 to 30% by weight of a complexing or sequestering agent selected from
    (F1)
    a mixture of monomeric and oligomeric compounds according to the formulas
    Figure 00020002
    and
    Figure 00020003
    wherein
  • Y 7 is hydrogen or -COT 1 ,
  • R 14 , X 3 and T 1 each independently of one another are C 1 -C 4 alkyl and
  • q 1 mean 1 to 16,
    • (f 2 )
    D-gluconic acid,
    (f 3 )
    Citric acid and
    (f 4 )
    aminophosphonic
  • (g) 0 to 10% by weight of a diol or polyol and
  • (h) 0 to 60% water,
    • one of the components (e) to (g) must always be present in the textile auxiliary,
    where in formulas (3), (4) and (5)
    R 4
    C 9 to C 14 alkyl,
    R 5
    C 1 to C 8 alkyl, a cycloaliphatic radical having at least 5 C atoms, lower alkylphenyl or styryl,
    R 6
    C 8 -C 13 alkyl,
    R 7
    C 8 -C 18 alkyl,
    Y 1 , Y 2 , Y 3 and Y 4 ,
    independently of one another hydrogen, methyl or ethyl, where one of the radicals Y 1 , Y 2 or Y 3 , Y 4 is always hydrogen,
    Y 5
    Hydrogen or methyl,
    Y 6
    Hydrogen, methyl or ethyl,
    m 2
    3 to 15
    p 1
    an integer from 4 to 10 and
    p 2
    an integer from 0 to 8,
    mean.

    Die Komponenten (a) bis (g) können jeweils aus Einzelverbindungen bestehen oder auch aus mehreren Einzelverbindungen zusammengesetzt sein.Components (a) to (g) can each consist of individual compounds or else be composed of several individual connections.

    Auf Grund der extremen Schaumarmut und des guten Dämpfungsvermögens von Prozeßschäumen kann bei den erfindungsgemässen Textilhilfsmitteln auf den Zusatz weiterer schaumdämpfender Mittel, insbesondere silikonhaltiger Verbindungen, verzichtet werden.Due to the extreme low foam and the good damping ability of process foams can in the textile auxiliaries according to the invention to the addition of further foam-suppressing agents, in particular compounds containing silicone, are dispensed with.

    Die Substituenten R6 und R7 in den Formeln (4) und (5) stellen vorteilhafterweise den Kohlenwasserstoffrest eines gesättigten aliphatischen Monoalkohols dar. Der Kohlenwasserstoffrest kann geradkettig oder verzweigt sein.The substituents R 6 and R 7 in the formulas (4) and (5) advantageously represent the hydrocarbon radical of a saturated aliphatic monoalcohol. The hydrocarbon radical can be straight-chain or branched.

    Als aliphatische gesättigte Monoalkohole können natürliche Alkohole, wie z.B. Laurylalkohol, Myristylalkohol, Cetylalkohol oder Stearylalkohol, sowie synthetische Alkohole, wie z.B. 2-Ethylhexanol, 1,1,3,3-Tetramethylbutanol, Octan-2-ol, Isononylalkohol, Trimethylhexanol, Trimethylnonylalkohol, Decanol, C9-C11-Oxoalkohol, Tridecylalkohol, Isotridecanol oder lineare primäre Alkohole (Alfole) in Betracht kommen. Einige Vertreter dieser Alfole sind Alfol (8-10), Alfol (9-11), Alfol (10-14), Alfol (12-13) oder Alfol (16-18). ("Alfol" ist ein eingetragenes Warenzeichen). As aliphatic saturated monoalcohols, natural alcohols, such as, for example, lauryl alcohol, myristyl alcohol, cetyl alcohol or stearyl alcohol, and synthetic alcohols, such as, for example, 2-ethylhexanol, 1,1,3,3-tetramethylbutanol, octan-2-ol, isononyl alcohol, trimethylhexanol, trimethylnonyl alcohol Decanol, C 9 -C 11 oxo alcohol, tridecyl alcohol, isotridecanol or linear primary alcohols (alfoles) can be used. Some representatives of these alfoles are Alfol (8-10), Alfol (9-11), Alfol (10-14), Alfol (12-13) or Alfol (16-18). ("Alfol" is a registered trademark).

    Die Alkoholreste können einzeln oder in Form von Gemischen aus zwei oder mehreren Komponenten vorhanden sein.

    Figure 00040001
    sind bevorzugt zweiwertige Reste der Formeln
    Figure 00040002
    R4 stellt den geradkettigen Kohlenwasserstoffrest eines gesättigten aliphatischen Monoalkohols mit 8 bis 14 Kohlenstoffatomen dar, also n-Octyl, n-Nonyl, n-Decyl, n-Undecyl, n-Dodecyl, n-Tridecyl oder n-Tetradecyl.The alcohol residues can be present individually or in the form of mixtures of two or more components.
    Figure 00040001
    are preferably divalent radicals of the formulas
    Figure 00040002
    R 4 represents the straight-chain hydrocarbon radical of a saturated aliphatic monoalcohol with 8 to 14 carbon atoms, ie n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl or n-tetradecyl.

    R5 in Formel (3) in der Bedeutung von C1-C8-Alkyl ist der Methyl-, Ethyl-, n-Propyl-, Isopropyl-, n-Butyl-, sec.Butyl- oder tert.Butyl-Rest. Vorzugsweise bedeutet R5 den n-Butylrest.R 5 in formula (3) in the meaning of C 1 -C 8 alkyl is the methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl or tert-butyl radical. R 5 is preferably the n-butyl radical.

    Beispiele für einen cycloaliphatischen Rest sind Cycloheptyl, Cyclooctyl oder vorzugsweise Cyclohexyl.Examples of a cycloaliphatic radical are cycloheptyl, cyclooctyl or preferably Cyclohexyl.

    Als Beispiele für nichtionogene Tenside, die der Komponente (a) entsprechen, seien die Anlagerungsprodukte von 3 bis 15 Mol, vorzugsweise 4 bis 10 Mol Alkylenoxiden, insbesondere Ethylenoxid, wobei einzelne Ethylenoxideinheiten durch substituierte Epoxide, wie Propylenoxid, ersetzt sein können, an höhere gesättigte Fettalkohle mit 8 bis 13 bzw. 8 bis 18 Kohlenstoffatomen, bzw. Gemische dieser Verbindungen genannt.Examples of nonionic surfactants which correspond to component (a) are Addition products of 3 to 15 mol, preferably 4 to 10 mol, of alkylene oxides, in particular Ethylene oxide, where individual ethylene oxide units are substituted by substituted epoxides, such as propylene oxide, can be replaced, to higher saturated fatty alcohol with 8 to 13 or 8 to 18 carbon atoms, or mixtures of these compounds.

    Als monomere Ausgangsverbindungen zur Herstellung der polymeren Verbindungen der Komponente (b) sind Acrylsäure und Methacrylsäure genannt.As monomeric starting compounds for the preparation of the polymeric compounds of Component (b) are called acrylic acid and methacrylic acid.

    Als Katalysatoren für die Herstellung der Komponente (b) werden vorzugsweise freie Radikale bildende organische Initiatoren verwendet. Geeignete Initiatoren zur Durchführung der radikalischen Polymerisation sind z.B. symmetrische aliphatische Azoverbindungen wie Azo-bis-isobuttersäurenitril, Azo-bis-2-methyl-valeronitril, 1,1'-Azo-bis-1-cyclohexanitril und 2,2'-Azo-bis-isobuttersäurealkylester; symmetrische Diacylperoxide, wie z.B. Acetyl-, Propionyl- oder Butyrylperoxid, Benzoylperoxid, brom-, nitro-, methyl- oder methoxy-substituierte Benzoylperoxide sowie Lauroylperoxid; symmetrische Peroxydicarbonate, wie z.B. Diethyl-, Diisopropyl-, Dicyclohexyl-, sowie Dibenzylperoxidicarbonat; tert.-Butylperoctoat, tert.-Butylperbenzoat oder tert.-Butylphenylperacetat sowie Peroxidicarbamate wie tert.-Butyl-N-(phenylperoxi)-carbamat oder tert.-Butyl-N-(2,3-dichlor- oder -4-chlorphenyl-peroxi)-carbamat. Weitere geeignete Peroxide sind: tert.-Butylhydroperoxid, Di-tert.-butylperoxid, Cumolhydroperoxid, Di-cumolperoxid und tert.-Butylperpivalat. Eine weitere geeignete Verbindung ist Kaliumpersulfat, das bei der Herstellung der Komponente (b) bevorzugt eingesetzt wird.Free radicals are preferably used as catalysts for the production of component (b) forming organic initiators used. Suitable initiators for implementation radical polymerization are e.g. symmetrical aliphatic azo compounds such as azo-bis-isobutyronitrile, azo-bis-2-methylvaleronitrile, 1,1'-azo-bis-1-cyclohexanitrile and 2,2'-azo-bis-isobutyric acid alkyl ester; symmetrical diacyl peroxides, such as e.g. Acetyl, propionyl or butyryl peroxide, benzoyl peroxide, bromine, nitro, methyl or methoxy-substituted benzoyl peroxides and lauroyl peroxide; symmetrical peroxydicarbonates, such as. Diethyl, diisopropyl, dicyclohexyl and dibenzyl peroxidicarbonate; tert-butyl peroctoate, tert-butyl perbenzoate or tert-butylphenyl peracetate and Peroxidicarbamates such as tert-butyl-N- (phenylperoxy) carbamate or tert-butyl-N- (2,3-dichloro- or -4-chlorophenyl peroxy) carbamate. Other suitable peroxides are: tert-butyl hydroperoxide, Di-tert-butyl peroxide, cumene hydroperoxide, di-cumene peroxide and tert-butyl perpivalate. Another suitable compound is potassium persulfate, which is used in the manufacture component (b) is preferably used.

    Die Katalysatoren werden in der Regel in Mengen von 0,1 bis 10 Gew.-%, vorzugsweise 0,5 bis 2 Gew.-%, bezogen auf die Ausgangsprodukte, eingesetzt.The catalysts are generally used in amounts of 0.1 to 10% by weight, preferably 0.5 to 2 wt .-%, based on the starting products, used.

    Die Komponente (b) liegt vorzugsweise als teilneutralisierte Verbindung vor, die einen pH-Wert von 3 bis 6 aufweist. Die Herstellung der polymeren Verbindung erfolgt z.B. durch Umsetzung von Acrylsäure oder Methacrylsäure in Gegenwart eines nichtionogenen Tensides der Formel (5) oder in Gegenwart von Mischungen nichtionogener Tenside der Formel (5). Anschliessend wird das Umsetzungsprodukt mit einer anorganischen und/oder organischen Base auf einen pH-Wert von 3 bis 6, vorzugsweise 4 bis 5, teilneutralisiert. Als Basen verwendet man z.B. 1 bis 8 Gew.-%ige anorganische oder organische Basen, wie z.B. Natriumhydroxid, Magnesiumhydroxid, Ethanolamin, Triethanolamin,N,N,N,N-Tetrakis(2-hydroxypropyl)-ethylenamin oder 1-Amino-1-deoxysorbit oder Mischungen davon. Wasser wird ad 100 Gew.% hinzugefügt.Component (b) is preferably in the form of a partially neutralized compound Has a pH of 3 to 6. The polymeric compound is produced e.g. by reacting acrylic acid or methacrylic acid in the presence of a nonionic Surfactants of the formula (5) or in the presence of mixtures of nonionic surfactants Formula (5). The reaction product is then mixed with an inorganic and / or organic base to a pH of 3 to 6, preferably 4 to 5, partially neutralized. As bases one uses e.g. 1 to 8% by weight inorganic or organic bases, such as. Sodium hydroxide, magnesium hydroxide, ethanolamine, Triethanolamine, N, N, N, N-tetrakis (2-hydroxypropyl) -ethyleneamine or 1-amino-1-deoxysorbitol or mixtures thereof. Water is added to 100% by weight.

    Die Polymerisation wird vorteilhafterweise in inerter Atmosphäre, z.B. in Gegenwart von Stickstoff durchgeführt.The polymerization is advantageously carried out in an inert atmosphere, e.g. in the presence of Nitrogen.

    Als Hydrotropiermittel entsprechend Komponente (c) kommen in Betracht:

    • Aromatische Alkohole der Formel
      Figure 00050001
    worin
  • X1 -(CH2)1-6-, -CH=CH-CH2- oder -O-(CH2)2-6- und
  • R8, R9 und R10, unabhängig voneinander, Wasserstoff, Hydroxy, Halogen oder C1-C6-Alkoxy bedeuten.
    •  Possible hydrotroping agents corresponding to component (c) are:
    • Aromatic alcohols of the formula
      Figure 00050001
    wherein
  • X 1 - (CH 2 ) 1-6 -, -CH = CH-CH 2 - or -O- (CH 2 ) 2-6 - and
  • R 8 , R 9 and R 10 , independently of one another, are hydrogen, hydroxy, halogen or C 1 -C 6 alkoxy.

    • Als Beispielhafte Verbindungen der Formel (6) sind Benzylalkohol, 2,4-Dichlorbenzylalkohol, Phenylethanol, Phenoxyethanol, 1-Phenoxy-2-propanol (Phenoxyisopropanol) und Zimtalkohol.Exemplary compounds of the formula (6) are benzyl alcohol, 2,4-dichlorobenzyl alcohol, Phenylethanol, phenoxyethanol, 1-phenoxy-2-propanol (phenoxyisopropanol) and cinnamon alcohol.

    Alle erwähnten organischen Säuren können auch in Form ihrer wasserlöslichen Salze, wie der Alkalimetall-, insbesondere Natrium- oder Kaliumsalze oder der Aminsalze vorliegen.All of the organic acids mentioned can also be in the form of their water-soluble salts, such as the alkali metal, in particular sodium or potassium salts or the amine salts are present.

    Weiterhin werden erfindungsgemäss als Hydrotropiermittel der Komponente (c) Alkylsulfate der Formel (7)   R11O-SO3X2, verwendet, worin

    R11
    einen aliphatischen gesättigten, verzweigten oder geradkettigen Rest mit 4 bis 24 Kohlenstoffatomen und
    X2
    Wasserstoff, Alkalimetall oder Ammonium bedeutet.
    Furthermore, according to the invention, alkyl sulfates of the formula are used as hydrotroping agents of component (c) (7) R 11 O-SO 3 X 2 , used where
    R 11
    an aliphatic saturated, branched or straight chain radical having 4 to 24 carbon atoms and
    X 2
    Means hydrogen, alkali metal or ammonium.

    Liegt das Alkylsulfat als Salz vor, so kommen beispielsweise Natrium-, Kalium- oder Ammoniumsalze in Betracht. Das Natriumsalz ist bevorzugt.If the alkyl sulfate is present as a salt, sodium, potassium or Ammonium salts into consideration. The sodium salt is preferred.

    Der aliphatische gesättigte Rest R11 leitet sich von Monoalkoholen ab. Dabei kommen natürliche oder synthetische Alkohole in Betracht. Als natürliche Alkohole sind z.B. Lauryl-, Myristyl-, Cetyl-, Stearyl-, Arachidyl- oder Behenylalkohol zu nennen. Bevorzugt sind Verbindungen, bei denen sich R11 von verzweigten aliphatischen synthetischen Alkoholen mit 4 bis 12, insbesondere 4 bis 8 Kohlenstoffatomen ableitet, z.B. Isobutylalkohol, sek.Butanol, tert.Butanol, Isoamylalkohol, 2-Ethylbutanol, 2-Methylpentanol, 5-Methylheptan-3-ol, 2-Ethylhexanol, 1,1,3,3-Tetramethylbutanol, Octan-2-ol, Isononylalkohol, Trimethylhexanol, Trimethylnonylalkohol, n-Decanol oder C9-C11-Oxoalkohol.The aliphatic saturated radical R 11 is derived from monoalcohols. Natural or synthetic alcohols can be used. Examples of natural alcohols are lauryl, myristyl, cetyl, stearyl, arachidyl or behenyl alcohol. Preferred compounds are those in which R 11 is derived from branched aliphatic synthetic alcohols having 4 to 12, in particular 4 to 8, carbon atoms, for example isobutyl alcohol, sec-butanol, tert-butanol, isoamyl alcohol, 2-ethylbutanol, 2-methylpentanol, 5-methylheptane -3-ol, 2-ethylhexanol, 1,1,3,3-tetramethylbutanol, octan-2-ol, isononyl alcohol, trimethylhexanol, trimethylnonyl alcohol, n-decanol or C 9 -C 11 oxo alcohol.

    Die Alkylsulfate können dabei bereits in Form ihrer Salze vorliegen und allein oder als (technisches) Gemisch untereinander in dem erfindungsgemässen Netzmittel eingesetzt werden.The alkyl sulfates can already be in the form of their salts and alone or as (Technical) mixture with each other used in the wetting agent according to the invention become.

    Beispielhaft erwähnt für Hydrotropiermittel der Formel (7) sei 2-Ethylhexylsulfat.Examples of hydrotroping agents of the formula (7) are 2-ethylhexyl sulfate.

    Die Herstellung dieser Alkylsulfate erfolgt nach an sich bekannter Weise durch Umsetzung der entsprechenden Alkohole mit z.B. Schwefelsäure, Oleum, Chlorsulfonsäure oder Schwefeltrioxid.These alkyl sulfates are prepared by reaction in a manner known per se the corresponding alcohols with e.g. Sulfuric acid, oleum, chlorosulfonic acid or sulfur trioxide.

    Weitere erfindungsgemäss eingesetzte Hydrotropiermittel sind die amphoteren Tenside: Natriumlauriminodipropionat, Dihydroxyethyl-talgfettglycinat, Dinatriumcocoamphodiacetat, Dinatriumcapryloamphodiacetat oder vorzugsweise Dinatriumdicarboxyethylcocopropylendiamin oder Talgfettamphopolycarboxyglycinat.Other hydrotroping agents used according to the invention are the amphoteric surfactants: Sodium laurimino dipropionate, dihydroxyethyl tallow fat glycinate, disodium cocoamphodiacetate, Disodium capryloamphodiacetate or preferably disodium dicarboxyethyl cocopropylene diamine or tallow amphopolycarboxyglycinate.

    Wichtige nichtionogene Tenside der fakultativen Komponente (d) entsprechen der Formel

    Figure 00070001
    worin

    R12
    C9-C14-Alkyl;
    R13
    C1-C4-Alkyl;
    Y7, Y8, Y9 und Y10,
    unabhängig voneinander, Wasserstoff, Methyl oder Ethyl, wobei einer der Reste Y7, Y8 bzw. Y9, Y10 immer Wasserstoff ist;
    p3 und p4,
    unabhängig voneinander, eine ganze Zahl von 4 bis 8;
    bedeuten.Important nonionic surfactants of the optional component (d) correspond to the formula
    Figure 00070001
    wherein
    R 12
    C 9 -C 14 alkyl;
    R 13
    C 1 -C 4 alkyl;
    Y 7 , Y 8 , Y 9 and Y 10 ,
    independently of one another, hydrogen, methyl or ethyl, where one of the radicals Y 7 , Y 8 or Y 9 , Y 10 is always hydrogen;
    p 3 and p 4 ,
    independently of one another, an integer from 4 to 8;
    mean.

    Als Beispiele für die endgruppenverschlossenen nichtionogenen Tenside der Komponente (d) sind C10-C12-Fettalkohol-Ethylenoxid- oder -Ethylenoxid/Propylenoxid-Additionsprodukte oder das Umsetzungsprodukt aus einem Mol eines C10-Fettalkohols mit 6 Mol Ethylenoxid und 1 Mol Butylenoxid zu nennen, wobei die Additionsprodukte jeweils mit C1-C4-Alkyl, vorzugsweise Methyl oder Butyl endgruppenverschlossen sein können.Examples of the end-capped nonionic surfactants of component (d) are C 10 -C 12 fatty alcohol-ethylene oxide or ethylene oxide / propylene oxide addition products or the reaction product of one mole of a C 10 fatty alcohol with 6 moles of ethylene oxide and 1 mole of butylene oxide name, where the addition products can be end-capped with C 1 -C 4 alkyl, preferably methyl or butyl.

    Die Herstellung der nichtionogenen Tenside der Formeln (4) und (5) geschieht in an sich bekannter Weise, so z.B. durch Umsetzung der entsprechenden Alkylenoxidanlagerungsprodukte mit Thionylchlorid und nachfolgender Umsetzung der entstandenen Chlorverbindung mit einem gesättigten aliphatischen C8-C13- bzw. C8-C18-Monoalkohol.The nonionic surfactants of the formulas (4) and (5) are prepared in a manner known per se, for example by reacting the corresponding alkylene oxide adducts with thionyl chloride and then reacting the chlorine compound formed with a saturated aliphatic C 8 -C 13 or C 8 -C 18 mono alcohol.

    Die Herstellung der endgruppenverschlossenen nichtionogenen Tenside der Formel (3) geschieht in an sich bekannter Weise, so z.B. durch Umsetzung von Ethylenoxid und/oder Propylenoxid und/oder Butylenoxid in den entsprechenden molaren Verhältnissen mit einem Mol des Alkohols R4-OH, und nachfolgender Umsetzung des entstandenen Anlagerungsproduktes mit einem Alkylhalogenid R5-Hal, vorzugsweise C1-C4-Alkylchlorid.The end-capped nonionic surfactants of the formula (3) are prepared in a manner known per se, for example by reacting ethylene oxide and / or propylene oxide and / or butylene oxide in the corresponding molar ratios with one mole of the alcohol R 4 -OH, and subsequent reaction of the adduct formed with an alkyl halide R 5 -Hal, preferably C 1 -C 4 -alkyl chloride.

    Bei den Magnesiumsalzen von Carbonsäuren mit komplexierenden Eigenschaften entsprechend der fakultativen Komponente (e) handelt es sich um Salze von Gluconsäure, Zitronensäure, Äpfelsäure, Milchsäure, L-Glutaminsäure und L-Asparaginsäure.The same applies to the magnesium salts of carboxylic acids with complexing properties the optional component (s) are salts of gluconic acid, citric acid, Malic acid, lactic acid, L-glutamic acid and L-aspartic acid.

    Insbesondere werden als Komponente (e) die Magnesiumsalze der Gluconsäure verwendet und ganz besonders Magnesiummono- oder Magnesiumdigluconat. Das Magnesiumgluconat kann dabei in der erfindungsgemässen Zusammensetzung als solches und vorzugsweise als Feststoff eingesetzt werden. In einer weiteren Ausführungsform kann das Gluconat aber auch in situ gebildet werden aus Gluconsäure und Magnesiumoxid oder vorzugsweise Magnesiumhydroxid. Ferner kann Gluconsäure oder dessen Natriumsalz in Kombination mit einem wasserlöslichen Magnesiumsalz eingesetzt werden. Als wasserlösliches Magnesiumsalz kommt dabei das Acetat, vor allem das Sulfat oder dessen Heptahydrat und insbesondere das Chlorid oder dessen Hexahydrat in Betracht. Das Magnesiumsalz wird in der Regel als Feststoff eingesetzt, wobei festes Magnesiumchlorid-Hexahydrat im Vordergrund steht.In particular, the magnesium salts of gluconic acid are used as component (e) and especially magnesium mono- or magnesium digluconate. The magnesium gluconate can be in the composition according to the invention as such and preferably be used as a solid. In a further embodiment, this can Gluconate can also be formed from gluconic acid and magnesium oxide or in situ preferably magnesium hydroxide. Gluconic acid or its sodium salt can also be used in Combination with a water-soluble magnesium salt can be used. As water soluble Magnesium salt comes here the acetate, especially the sulfate or its Heptahydrate and especially the chloride or its hexahydrate. The Magnesium salt is usually used as a solid, with solid magnesium chloride hexahydrate is in the foreground.

    Komplexbildner entsprechend der Komponente (f) in der erfindungsgemässen Zusammensetzung sind Verbindungen, die ausgewählt sind aus

    (f1)
    einem Gemisch aus monomeren und oligomeren Verbindungen entsprechend der Formeln
    Figure 00090001
    und
    Figure 00090002
       worin
  • Y7 Wasserstoff oder -COT1,
  • R14, X3 und T1 unabhängig voneinander jeweils C1-C4-Alkyl und
  • q1 1 bis 16
    •  bedeuten,
    (f2)
    D-Gluconsäure,
    (f3)
    Zitronensäure und
    (f4)
    Aminophosphonsäure.
    Complexing agents corresponding to component (f) in the composition according to the invention are compounds which are selected from
    (f 1 )
    a mixture of monomeric and oligomeric compounds according to the formulas
    Figure 00090001
    and
    Figure 00090002
    wherein
  • Y 7 is hydrogen or -COT 1 ,
  • R 14 , X 3 and T 1 each independently of one another are C 1 -C 4 alkyl and
  • q 1 1 to 16
    • mean,
    (f 2 )
    D-gluconic acid,
    (f 3 )
    Citric acid and
    (f 4 )
    Aminophosphonic.

    Bei dem Gemisch aus monomeren und oligomeren Verbindungen (f1) handelt es sich vorzugsweise um ein Gemisch aus monomeren und oligomeren Verbindungen der Formel

    Figure 00090003
    und
    Figure 00090004
    worin

  • R15 Methyl oder Ethyl und
  • q2 1 bis 13 bedeuten.
    • The mixture of monomeric and oligomeric compounds (f 1 ) is preferably a mixture of monomeric and oligomeric compounds of the formula
    Figure 00090003
    and
    Figure 00090004
    wherein
  • R 15 is methyl or ethyl and
  • q 2 mean 1 to 13.

    • Die Gemische der monomeren und oligomeren Verbindungen der angegebenen Art sind an sich bekannt und werden nach bekannten Methoden hergestellt. So wird z.B. das Gemisch der Formel (10a) und (10b) vorzugsweise durch Umsetzung von Phosphortrichlorid, Essigsäure und gegebenenfalls Essigsäureanhydrid in wässrigem Medium hergestellt. Die oligomeren Anteile der Komponente (f1) werden in der wässrigen, erfindungsgemässen Zusammensetzung in Gegenwart eines Alkalimetallhydroxids mindestens teilweise zu den entsprechenden monomeren Verbindungen hydrolisiert. Demgemäß kommen als Komponente (f1) der erfindungsgemässe Zusammensetzungen vor allem auch monomere Verbindungen einer der Formeln (9a) bzw. (10a) in Frage.The mixtures of the monomeric and oligomeric compounds of the type indicated are known per se and are prepared by known methods. For example, the mixture of the formulas (10a) and (10b) is preferably prepared by reacting phosphorus trichloride, acetic acid and optionally acetic anhydride in an aqueous medium. The oligomeric components (f 1 ) are at least partially hydrolyzed in the aqueous composition according to the invention in the presence of an alkali metal hydroxide to give the corresponding monomeric compounds. Accordingly, component (f 1 ) of the compositions according to the invention are also, above all, monomeric compounds of one of the formulas (9a) or (10a).

    Die Komponente (f1) wird vorzugsweise als 35 bis 90, vorzugsweise 40 bis 85, insbesondere 40 bis 60 gewichtsprozentige, wässrige Lösung in der erfindungsgemässen Zusammensetzung eingesetzt.Component (f 1 ) is preferably used in the composition according to the invention as 35 to 90, preferably 40 to 85, in particular 40 to 60 percent by weight aqueous solution.

    Beispiele für die Komponente (f4) sind Nitrilotrimethylenphosphonsäure, das Na-Salz der Ethylendiamin-tetramethylenphosphonsäure, das Na-Salz der Diethylentriamin-pentamethylenphosphonsäure oder N,N-Bis(phosphonmethyl)glutaminsäure.Examples of component (f 4 ) are nitrilotrimethylenephosphonic acid, the Na salt of ethylenediamine-tetramethylenephosphonic acid, the Na salt of diethylenetriamine-pentamethylenephosphonic acid or N, N-bis (phosphonomethyl) glutamic acid.

    Verbindungen der Komponente (f) wirken als Komplexbildner für Erdalkali- und Schwermetalle in wässrigen Flotten, die eine Perverbindung, z.B. Wasserstoffperoxid enthalten, bei der Vorbehandlung, insbesondere bei Bleichprozessen von cellulosehaltigen Fasermaterialien. Insbesondere wird durch die Anwesenheit dieser Komponenten die Zersetzung der Perverbindung durch freie, d.h. nicht als Komplex vorliegende Schwermetalle, die im Betriebswasser des Fasermaterials oder im zugesetzten Alkali vorhanden sein können, unterdrückt.Compounds of component (f) act as complexing agents for alkaline earth and heavy metals in aqueous liquors containing a per-compound, e.g. Contain hydrogen peroxide, in pretreatment, especially in bleaching processes of cellulosic fiber materials. In particular, the presence of these components causes decomposition the per-connection by free, i.e. heavy metals not present as a complex, which are present in the process water of the fiber material or in the added alkali can suppressed.

    Als Komponente (g) kommen zwei- oder mehrwertige Alkohole in Betracht. Als zweiwertige Alkohole sind insbesondere solche mit 2 bis 6 C-Atomen im Alkylenteil wie Ethylenglykol, 1,2- oder 1,3-Propandiol, 1,3-, 1,4- oder 2,3-Butandiol, 1,5-Pentandiol und 1,6-Hexandiol oder 2-Methyl-2,4-pentandiol zu nennen. Die letztgenannte Verbindung wird in der erfindungsgemässen Zusammensetzung bevorzugt verwendet. Suitable as component (g) are dihydric or polyhydric alcohols. As bivalent Alcohols are in particular those with 2 to 6 carbon atoms in the alkylene part, such as ethylene glycol, 1,2- or 1,3-propanediol, 1,3-, 1,4- or 2,3-butanediol, 1,5-pentanediol and 1,6-hexanediol or to name 2-methyl-2,4-pentanediol. The latter connection is in the composition according to the invention is preferably used.

    Beispiele für mehrwertige Alkohole sind Glycerin, Erythrit, die Pentite, wie z.B. Arabit, Adonit und Xylit sowie die Hexite, wie z.B. D-Sorbit, D-Mannit und Dulcit.Examples of polyhydric alcohols are glycerol, erythritol, the pentites, e.g. arabitol, Adonite and xylitol as well as the hexites such as D-sorbitol, D-mannitol and dulcitol.

    Vorzugweise werden Textilhilfsmittel verwendet, welche

  • (a) 10 bis 60 Gew.% eines oder mehrerer nichtionogener Tenside der Formel
    Figure 00110001
  • (b) 10 bis 60 Gew.% des Umsetzungsproduktes aus 5 bis 45 Gew.-% eines oder mehrerer nichtionogener Tenside der Formel
    Figure 00110002
    und 45 bis 5 Gew.-% Acrylsäure;
  • (c) 4 bis 20 Gew.% eines Hydrotropiermittels ausgewählt aus Natrium-cumol-4-sulfonat und Dodecyliminodipropionat-di-Na-Salz; und
  • (d) 0 bis 20 Gew.% eines nichtionogenen Tensids der Formel
    Figure 00110003
  • (e) 0 bis 8 Gew.% Magnesiummono- oder Digluconat;
  • (f) 0 bis 30 Gew.% D-Gluconsäure; und
  • (g) 0 bis 10 Gew.% 2-Methyl-2,4-pentadiol;
    • wobei eine der Komponenten (e) bis (g) im Textilhilfsmittel immer vorhanden sein muss,
    worin
    R6
    C8-C13-Alkyl;
    R7
    C8-C18-Alkyl;
    R12
    C9-C14-Alkyl;
    R13
    C1-C4-Alkyl;
    Y5
    Wasserstoff oder Methyl;
    Y6
    Wasserstoff, Methyl oder Ethyl;
    Y7, Y8, Y9, Y10,
    unabhängig voneinander, Wasserstoff, Methyl oder Ethyl, wobei einer der Reste Y7, Y8 bzw. Y9, Y10 immer Wasserstoff ist;
    m2
    4 bis 15;
    n2
    1 bis 40; und
    p3 und p4,
    unabhängig voneinander, eine ganze Zahl von 4 bis 8;
    bedeuten,
    enthalten.Textile auxiliaries are preferably used, which
  • (a) 10 to 60% by weight of one or more nonionic surfactants of the formula
    Figure 00110001
  • (b) 10 to 60% by weight of the reaction product from 5 to 45% by weight of one or more nonionic surfactants of the formula
    Figure 00110002
    and 45 to 5% by weight acrylic acid;
  • (c) 4 to 20% by weight of a hydrotroping agent selected from sodium cumene-4-sulfonate and dodecyliminodipropionate di-Na salt; and
  • (d) 0 to 20% by weight of a nonionic surfactant of the formula
    Figure 00110003
  • (e) 0 to 8% by weight magnesium mono- or digluconate;
  • (f) 0 to 30% by weight D-gluconic acid; and
  • (g) 0 to 10% by weight 2-methyl-2,4-pentadiol;
    • one of the components (e) to (g) must always be present in the textile auxiliary,
    wherein
    R 6
    C 8 -C 13 alkyl;
    R 7
    C 8 -C 18 alkyl;
    R 12
    C 9 -C 14 alkyl;
    R 13
    C 1 -C 4 alkyl;
    Y 5
    Hydrogen or methyl;
    Y 6
    Hydrogen, methyl or ethyl;
    Y 7 , Y 8 , Y 9 , Y 10 ,
    independently of one another, hydrogen, methyl or ethyl, where one of the radicals Y 7 , Y 8 or Y 9 , Y 10 is always hydrogen;
    m 2
    4 to 15;
    n 2
    1 to 40; and
    p 3 and p 4 ,
    independently of one another, an integer from 4 to 8;
    mean,
    contain.

    Die erfindungsgemässen Textilhilfsmittel können durch Eintragen der Komponenten (a), (b), (c), und gegebenenfalls (d), (e), (f) und (g) in Wasser (Komponente (h)) hergestellt werden, oder dadurch, dass man die entsprechenden Komponenten unter Rühren mischt und deionisiertes Wasser hinzugibt, bis eine homogene Lösung vorliegt. Es handelt sich dabei um einen rein mechanischen Vorgang, der gegebenenfalls bei erhöhter Temperatur, beispielsweise von 30 bis 40°C durchgeführt wird. Eine chemische Reaktion findet dabei nicht statt.The textile auxiliaries according to the invention can be prepared by adding components (a), (b), (c), and optionally (d), (e), (f) and (g) in water (component (h)) or by mixing the corresponding components with stirring and add deionized water until a homogeneous solution is obtained. It is about a purely mechanical process, which may take place at elevated temperature, for example from 30 to 40 ° C is carried out. A chemical reaction takes place not instead.

    Eine weitere Ausführungsform der Herstellung der erfindungsgemässen Textilhilfsmittel besteht darin, dass man zunächst die Komponente (b) durch Umsetzung von 5 bis 45 Gew.-% eines nichtionogenen Tensids der Formel (5) mit 45 bis 5 Gew.-% Acrylsäure oder Methacrylsäure in Anwesenheit eines Katalysators aus der Klasse der freien Radikale bildenden organischen Initiatoren, und anschliessender Teilneutralisation auf einen pH-Wert von 3 bis 6 mit 1 bis 8 Gew.-% einer anorganischen oder organischen Base herstellt, den pH-Wert auf ca. 4,5 einstellt und dann die restlichen Komponenten hinzugibt, bis eine homogene Lösung vorliegt.Another embodiment of the production of the textile auxiliaries according to the invention consists in that component (b) is first reacted from 5 to 45 % By weight of a nonionic surfactant of the formula (5) with 45 to 5% by weight of acrylic acid or methacrylic acid in the presence of a free radical class catalyst forming organic initiators, and then partial neutralization to one pH of 3 to 6 with 1 to 8 wt .-% of an inorganic or organic base manufactures, adjusts the pH to about 4.5 and then the remaining components add until a homogeneous solution is obtained.

    Die fertig hergestellten Textilhilfsmittel weisen einen pH-Wert von z. B. 2 bis 5, vorzugsweise von 2,5 bis 3,5 auf. Der pH-Wert bezieht sich dabei immer auf eine 1%ige wäsrige Lösung der erfindungsgemässen Formulierung. Für eine gegebenenfalls nachträgliche Einstellung des gewünschten pH-Wertes verwendet man z.B. Magnesiumhydroxid, Kaliumhydroxid, Mono-, Di- oder Triethanolamin und vor allem Natriumhydroxid.The finished textile auxiliaries have a pH of z. B. 2 to 5, preferably from 2.5 to 3.5. The pH value always refers to a 1% aqueous solution of the formulation according to the invention. For a possibly subsequent Setting the desired pH is used e.g. magnesium hydroxide, Potassium hydroxide, mono-, di- or triethanolamine and especially sodium hydroxide.

    Die neuen Formulierungen stellen lagerstabile, einphasige, schaumarme und silikonfreie Textilhilfsmittel mit guten komplexierenden und sequestrierenden Eigenschaften mit schmutzlösender Wirkung dar. Sie zeigen gutes Emulgiervermögen und sind in alkalischer Flotte stabil. In alkalischer Bleichflotte weisen sie keine Aufrahmungen oder Abscheidungen auf. Sie besitzen weiterhin gute peroxid-stabilisierende Eigenschaften und bewirken eine gute Wiederbenetzbarkeit des Textilguts. Ausserdem sind die Formulierungen gut biologisch abbaubar. Sie zeichnen sich auf Grund ihrer flüssigen Handelsform durch einfache Handhabung aus, weshalb sie besonders für moderne Dosiereinrichtungen geeignet sind. Die universelle Einsetzbarkeit der erfindungsgemässen Formulierungen ermöglicht verschiedene Anwendungen. Sie können beispielsweise als Netzmittel, Textilwaschmittel, Dispergiermittel oder als Stabilisator in Peroxid-Bleichflotten eingesetzt werden. Ferner eignen sie sich hervorragend als universelles Haushaltswaschmittel.The new formulations provide storage-stable, single-phase, low-foam and silicone-free Textile auxiliaries with good complexing and sequestering properties dirt-removing effect. They show good emulsifying power and are alkaline Fleet stable. In alkaline bleaching liquors, they have no creams or deposits on. They also have good peroxide-stabilizing properties and cause good rewettability of the textile goods. In addition, the wording readily biodegradable. They are characterized by their liquid trading form easy handling, which is why they are particularly suitable for modern dosing systems are suitable. The universal applicability of the formulations according to the invention enables various applications. For example, as a wetting agent, textile detergent, Dispersant or used as a stabilizer in peroxide bleaching liquors become. They are also ideal as a universal household detergent.

    Gegenstand der vorliegenden Erfindung ist demnach auch ein Verfahren zum Netzen, Waschen und/oder Bleichen von Fasermaterialien, das dadurch gekennzeichnet ist, dass man diese Materialien in wässrigem Medium in Gegenwart eines in Anspruch 1 definierten Textilhilfsmittels behandelt.The present invention accordingly also relates to a method for wetting, Washing and / or bleaching fiber materials, which is characterized in that to these materials in an aqueous medium in the presence of one defined in claim 1 Textile auxiliaries treated.

    Die Einsatzmengen, in denen die erfindungsgemässen Textilhilfsmittel den Behandlungsflotten zugesetzt werden, betragen 0,1 bis 60, vorzugsweise 1 bis 20 g pro Liter Behandlungsflotte. Diese Flotten können noch weitere Zusätze enthalten, z.B. Entschlichtungsmittel, Farbstoffe, optische Aufheller, Alkalien wie Natriumhydroxid und Wasserstoffperoxid.The amounts in which the textile auxiliaries according to the invention are added to the treatment liquors added are 0.1 to 60, preferably 1 to 20 g per liter of treatment liquor. These fleets can also contain other additives, e.g. desizing, Dyes, optical brighteners, alkalis such as sodium hydroxide and hydrogen peroxide.

    Als Fasermaterialien kommen in Betracht: Cellulose, insbesondere unvorbehandelte natürliche Cellulose wie z.B. Hanf, Leinen, Jute, Zellwolle, Viskose, Azetatreyon, native Cellulosefaser und besonders Rohbaumwolle, Wolle, Polyamid-, Polyacrylnitril- oder Polyesterfasermaterialien sowie Fasermischungen, z.B. solche aus Polyacrylnitril/Baumwolle oder Polyester/Baumwolle.Possible fiber materials are: cellulose, in particular untreated natural ones Cellulose such as Hemp, linen, jute, rayon, viscose, acetate treyon, native cellulose fiber and especially raw cotton, wool, polyamide, polyacrylonitrile or polyester fiber materials as well as fiber blends, e.g. those made of polyacrylonitrile / cotton or polyester / cotton.

    Das zu behandelnde Fasermaterial kann in verschiedenen Verarbeitungsstufen vorliegen, so z.B. das cellulosehaltige Material als loses Material, Garn, Gewebe oder Gewirke. Hierbei handelt es sich also in der Regel stets um textile Fasermaterialien, die aus reinen textilen Cellulosefasern oder aus Gemischen von textilen Cellulosefasern mit textilen Synthesefasern hergestellt werden. Das Fasermaterial kann kontinuierlich oder diskontinuierlich in wässriger Flotte behandelt werden.The fiber material to be treated can be in different processing stages, so e.g. the cellulose-containing material as loose material, yarn, woven or knitted fabric. As a rule, these are always textile fiber materials made from pure textile cellulose fibers or from mixtures of textile cellulose fibers with textile synthetic fibers getting produced. The fiber material can be continuous or discontinuous be treated in an aqueous liquor.

    Die wässrigen Behandlungsflotten können in bekannter Weise auf die Fasermaterialien aufgebracht werden, vorteilhaft durch Imprägnieren am Foulard, wobei die Flottenaufnahme etwa 70 bis 120 Gew.% beträgt. Das Foulardierverfahren kommt insbesondere beim Pad-Steam- sowie Pad-Batch-Verfahren zur Anwendung. The aqueous treatment liquors can be applied to the fiber materials in a known manner be applied, advantageously by impregnation on the foulard, the liquor intake is about 70 to 120% by weight. The padding process comes in particular for pad-steam and pad-batch processes.

    Die Imprägnierung kann bei 10 bis 60°C, vorzugsweise jedoch bei Raumtemperatur, vorgenommen werden. Nach der Imprägnierung und Abquetschung wird das Cellulosematerial gegebenenfalls einer Hitzebehandlung, z.B. bei Temperaturen von 80 bis 140°C unterworfen. Vorzugsweise erfolgt die Hitzebehandlung durch Dämpfen bei 95 bis 140, insbesondere bei 100 bis 106°C. Je nach Art der Hitzeentwicklung und des Temperaturbereiches kann die Hitzebehandlung 30 Sekunden bis 60 Minuten dauern. Bei dem Pad-Batch-Verfahren wird die imprägnierte Ware ohne Trocknung aufgerollt und anschliessend gegebenenfalls mit einer Plastikfolie verpackt, und bei Raumtemperatur 1 bis 24 Stunden gelagert.The impregnation can be carried out at 10 to 60 ° C, but preferably at room temperature become. After impregnation and squeezing, the cellulose material optionally heat treatment, e.g. Subject at temperatures from 80 to 140 ° C. The heat treatment is preferably carried out by steaming at 95 to 140, in particular at 100 to 106 ° C. Depending on the type of heat development and the temperature range the heat treatment can take 30 seconds to 60 minutes. With the pad-batch process the impregnated goods are rolled up without drying and then optionally wrapped with plastic wrap, and at room temperature 1 to 24 Stored for hours.

    Die Behandlung der Fasermaterialien kann aber auch in langen Flotten bei einem Flottenverhältnis von z.B. 1:3 bis 1:100, vorzugsweise 1:4 bis 1:25 und bei 10 bis 100, vorzugsweise 60 bis 98°C während etwa 1/4 bis 3 Stunden unter Normalbedingungen, d.h. unter atmosphärischem Druck in üblichen Apparaturen, z.B. einem Jigger, Jet oder einer Haspelkufe erfolgen. Gegebenenfalls kann aber auch die Behandlung bis 150°C, vorzugsweise 105 bis 140°C unter Druck in sogenannten Hochtemperatur-Apparaturen (HT-Apparaturen) durchgeführt werden.The treatment of the fiber materials can also in long liquors with a liquor ratio from e.g. 1: 3 to 1: 100, preferably 1: 4 to 1:25 and 10 to 100, preferably 60 to 98 ° C for about 1/4 to 3 hours under normal conditions, i.e. under atmospheric pressure in conventional equipment, e.g. a jigger, jet or one Reel skids take place. If necessary, however, the treatment can also be carried out up to 150 ° C., preferably 105 to 140 ° C under pressure in so-called high-temperature equipment (HT equipment) be performed.

    Anschliessend werden die Fasermaterialien, wenn es das Verfahren verlangt, mit heissem Wasser von etwa 90 bis 98°C und dann mit warmem und zuletzt mit kaltem Wasser gründlich gespült, gegebenenfalls neutralisiert und hierauf vorzugsweise bei erhöhten Temperaturen getrocknet.The fiber materials are then, if required by the process, with hot Water from about 90 to 98 ° C and then with warm and finally with cold water rinsed thoroughly, neutralized if necessary and then preferably at elevated Temperatures dried.

    Aus der EP-A-0 420 802 sind ähnliche Netzmittel bekannt, die sich in charakteristischer Weise dadurch von dem erfindungsgemässen Textilhilfsmittel unterscheiden, dass sie keine Komponente b) enthalten. Gegenüber diesem Stand der Technik zeichnet sich das erfingungsgemässe Textilhilfsmittel durch überraschende vorteilhafte Eigenschaften aus.Similar wetting agents are known from EP-A-0 420 802, which are more characteristic Differentiate it from the textile auxiliary according to the invention in that they contain no component b). This distinguishes itself from this state of the art textile auxiliaries according to the invention are characterized by surprising advantageous properties.

    In den nachfolgenden Beispielen, die zur Veranschaulichung der Erfindung dienen, beziehen sich die Prozente stets auf das Gewicht.In the following examples, which serve to illustrate the invention, refer the percentages always refer to the weight.

    Herstellung der Einzelkomponenten:Manufacture of the individual components: Beispiel 1: Herstellung der Komponente (b)Example 1: Preparation of component (b)

    In einem Planschliffkolben mit Heizmantel werden 360,0 g deionisiertes Wasser, 76,0 g des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 9 Mol Ethylenoxid, 48 g des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 10 Mol Ethylenoxid bei 20 bis 30°C vorgelegt und auf 88 bis 92°C erwärmt. Es entsteht eine milchig trübe Emulsion.In a flat-bottomed flask with a heating jacket 360.0 g deionized water, 76.0 g the reaction product from one mole of a C 13 oxo alcohol and 9 moles of ethylene oxide, 48 g of the reaction product from one mole of a C 13 oxo alcohol and 10 moles of ethylene oxide submitted at 20 to 30 ° C and heated to 88 to 92 ° C. A milky, cloudy emulsion is formed.

    Bei 90°C werden gleichzeitig

  • 124,0 g Acrylsäure und eine Initiatorlösung, bestehend aus
  • 0,75 g Kaliumpersulfat, gelöst in 60,0 g deionisiertem Wasser zudosiert. Die Dosierzeit für die Acrylsäure beträgt 180 Minuten, die der Initiatorlösung 195 Minuten. Anschliessend wird die entstandene Polymerlösung noch etwa 15 bis 30 Minuten nachgerührt und danach auf 25°C abgekühlt. Während der Abkühlphase werden unterhalb 70°C
  • 9,7 g 30%ige Natronlauge
    • unter gutem Rühren zugegeben.At 90 ° C at the same time
  • 124.0 g of acrylic acid and an initiator solution consisting of
  • 0.75 g of potassium persulfate, dissolved in 60.0 g of deionized water, are metered in. The dosing time for acrylic acid is 180 minutes, that of the initiator solution 195 minutes. The resulting polymer solution is then stirred for a further 15 to 30 minutes and then cooled to 25 ° C. During the cooling phase are below 70 ° C
  • 9.7 g 30% sodium hydroxide solution
    • added with good stirring.

    Es entsteht ein klares, farbloses Produkt.The result is a clear, colorless product.

    Beispiel 2: Herstellung der Komponente (b)Example 2: Preparation of component (b)

    In einem Planschliffkolben mit Heizmantel werden 346,0 g deionisiertes Wasser, 138,0 g des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 9 Mol Ethylenoxid, bei 20 bis 30°C vorgelegt und auf 88 bis 92°C erwärmt. Es entsteht eine milchig trübe Emulsion.In a flat-bottomed flask with a heating jacket 346.0 g deionized water, 138.0 g the reaction product from one mole of a C 13 oxo alcohol and 9 moles of ethylene oxide, submitted at 20 to 30 ° C and heated to 88 to 92 ° C. A milky, cloudy emulsion is formed.

    Bei 90°C werden gleichzeitig 124,0 g Acrylsäure und eine Initiatorlösung, bestehend aus 0,75 g Kaliumpersulfat, gelöst in 60,0 g deionisiertem Wasser zudosiert. Die Dosierzeit für die Acrylsäure beträgt 180 Minuten, die der Initiatorlösung 195 Minuten. Anschliessend wird die entstandene Polymerlösung noch etwa 15 bis 30 Minuten nachgerührt.At 90 ° C at the same time 124.0 g Acrylic acid and an initiator solution consisting of 0.75 g Potassium persulfate, dissolved in 60.0 g of deionized water added. The dosing time for acrylic acid is 180 minutes, that of the initiator solution 195 minutes. The resulting polymer solution is then stirred for a further 15 to 30 minutes.

    Bei 85 bis 95°C wird nun 13,9g Magnesiumhydroxid eingerührt und die entstandene homogene Lösung auf 25°C abgekühlt. Während der Abkühlphase werden unterhalb 70°C 321,6 g deionisiertes Wasser unter gutem Rühren zugegeben. At 85 to 95 ° C is now 13.9 g magnesium hydroxide stirred in and the resulting homogeneous solution cooled to 25 ° C. During the cooling phase are below 70 ° C 321.6 g Deionized water added with good stirring.

    Es entsteht ein klares, farbloses, homogenes Produkt.The result is a clear, colorless, homogeneous product.

    Herstellung der erfindungsgemässen FormulierungenPreparation of the formulations according to the invention Beispiel 3: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 3: The following components are mixed with one another with stirring:

    24 %24% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 6 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 6 moles of ethylene oxide, 22 %22% der Komponente (b) gemäss Beispiel 1,component (b) according to Example 1, 2,4 %2.4% Dinatriumdicarboxyethylcocopropylendiamin,Dinatriumdicarboxyethylcocopropylendiamin, 10 %10% des Umsetzungsproduktes aus einem Mol eines C12-Fettalkohols und 6 Mol Ethylenoxid/4 Mol Propylenoxidof the reaction product from one mole of a C 12 fatty alcohol and 6 moles of ethylene oxide / 4 moles of propylene oxide 7,2 %7.2% 1-Hydroxy-1,1-ethandiphosphonsäure,1-hydroxy-1,1-ethandiphosphonsäure, 3 %3% D-Gluconsäure,D-gluconic acid, 6 %6% 2-Methyl-2,4-pentandiol und2-methyl-2,4-pentanediol and 25,4 %25.4% Wasser.Water.

    Es entsteht ein niederviskoses, klares und homogenes Produkt.The result is a low-viscosity, clear and homogeneous product.

    Die Formulierung findet Verwendung als Textilhilfsmittel für alkalische Aufschlussverfahren, Laugieren und Mercerisieren.The formulation is used as a textile auxiliary for alkaline digestion processes, Leach and mercerize.

    Beispiel 4: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 4: The following components are mixed with one another with stirring:

    32 %32% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 7 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 7 moles of ethylene oxide, 8 %8th % des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 6 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 6 moles of ethylene oxide, 28 %28% der Komponente (b) gemäss Beispiel 1,component (b) according to Example 1, 2,4 %2.4% Dinatriumdicarboxyethylcocopropylendiamin,Dinatriumdicarboxyethylcocopropylendiamin, 4,8 %4.8% 1-Hydroxy-1,1-ethandiphosphonsäure,1-hydroxy-1,1-ethandiphosphonsäure, 3 %3% D-Gluconsäure,D-gluconic acid, 6 %6% 2-Methyl-2,4-pentandiol und 2-methyl-2,4-pentanediol and 14,6 %14.6% Wasser.Water.

    Es entsteht ein niederviskoses, klares und homogenes Produkt.The result is a low-viscosity, clear and homogeneous product.

    Die Formulierung findet Verwendung als Textilhilfsmittel für alkalische Aufschlussverfahren, Laugieren und Mercerisieren.The formulation is used as a textile auxiliary for alkaline Digestion process, leaching and mercerization.

    Beispiel 5: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 5: The following components are mixed with one another with stirring:

    32 %32% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 6 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 6 moles of ethylene oxide, 40 %40% der Komponente (b) gemäss Beispiel 2,component (b) according to Example 2, 1,8 %1.8% Dinatriumdicarboxyethylcocopropylendiamin,Dinatriumdicarboxyethylcocopropylendiamin, 4,8 %4.8% 1-Hydroxy-1,1-ethandiphosphonsäure,1-hydroxy-1,1-ethandiphosphonsäure, 3 %3% D-Gluconsäure,D-gluconic acid, 8 %8th % 2-Methyl-2,4-pentandiol und2-methyl-2,4-pentanediol and 10,4 %10.4% Wasser.Water.

    Es entsteht ein niederviskoses, klares und homogenes Produkt.The result is a low-viscosity, clear and homogeneous product.

    Die Formulierung findet Verwendung als Textilhilfsmittel für die Kaltlager-Peroxidbleiche.The formulation is used as a textile aid for cold storage peroxide bleaching.

    Beispiel 6: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 6: The following components are mixed with one another with stirring:

    15 %15% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 3 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 3 moles of ethylene oxide, 15%15% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 5 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 5 moles of ethylene oxide, 42 %42% der Komponente (b) gemäss Beispiel 1,component (b) according to Example 1, 4 %4% Talgfettamphopolycarboxyglycinat,Talgfettamphopolycarboxyglycinat, 12 %12% des Umsetzungsproduktes aus einem Mol eines C10-Fettalkohols und 6 Mol Ethylenoxid/1 Mol Butylenoxid, methylendgruppenverschlossen,the reaction product from one mole of a C 10 fatty alcohol and 6 moles of ethylene oxide / 1 mole of butylene oxide, methyl end groups, 6 %6% 2-Methyl-2,4-pentandiol und2-methyl-2,4-pentanediol and 6 %6% Wasser.Water.

    Es entsteht ein niederviskoses, klares und homogenes Produkt. The result is a low-viscosity, clear and homogeneous product.

    Die Formulierung findet Verwendung als Textilhilfsmittel für Abkoch- und Bleichprozesse.The formulation is used as a textile aid for boiling and bleaching processes.

    Beispiel 7: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 7: The following components are mixed with one another with stirring:

    3,5 %3.5% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 5 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 5 moles of ethylene oxide, 9,5 %9.5% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 6 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 6 moles of ethylene oxide, 2 %2% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 9 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 9 moles of ethylene oxide, 12,6 %12.6% der Komponente (b) gemäss Beispiel 1,component (b) according to Example 1, 4 %4% des Natriumsalzes der Cumol-4-sulfonsäure,the sodium salt of cumene-4-sulfonic acid, 2,5 %2.5% Magnesiumdigluconat undMagnesium digluconate and 65,9 %65.9% Wasser.Water.

    Es entsteht ein niederviskoses, klares und homogenes Produkt.The result is a low-viscosity, clear and homogeneous product.

    Die Formulierung findet Verwendung als Textilhilfsmittel für die Pad-Steam-Peroxid-Bleiche.The formulation is used as a textile aid for pad steam peroxide bleaching.

    Beispiel 8: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 8: The following components are mixed with one another with stirring:

    15 %15% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 6 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 6 moles of ethylene oxide, 20,7 %20.7% der Komponente (b) gemäss Beispiel 2,component (b) according to Example 2, 4 %4% des Natriumsalzes der Cumol-4-sulfonsäure,the sodium salt of cumene-4-sulfonic acid, 2,4 %2.4% Magnesiumdigluconat undMagnesium digluconate and 57,9 %57.9% Wasser.Water.

    Es entsteht ein niederviskoses, klares und homogenes Produkt.The result is a low-viscosity, clear and homogeneous product.

    Die Formulierung findet Verwendung als Textilhilfsmittel für die Pad-Steam-Peroxid-Bleiche.The formulation is used as a textile aid for pad steam peroxide bleaching.

    Beispiel 9: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 9: The following components are mixed with one another with stirring:

    30 %30% des Umsetzungsproduktes aus einem Mol eines C11-Oxoalkohols und 4 Mol Ethylenoxid, the reaction product from one mole of a C 11 oxo alcohol and 4 moles of ethylene oxide, 42 %42% der Komponente (b) gemäss Beispiel 1, aber mit einem Umsetzungsprodukt aus einem Mol eines C13-Oxoalkohols mit 6 Mol Ethylenoxid anstelle des Umsetzungsproduktes aus einem Mol eines C15-Oxoalkohols mit 9 und 10 Mol Ethylenoxid,component (b) according to Example 1, but with a reaction product of one mole of a C 13 oxo alcohol with 6 moles of ethylene oxide instead of the reaction product of one mole of a C 15 oxo alcohol with 9 and 10 moles of ethylene oxide, 12 %12% des Umsetzungsproduktes aus einem Mol eines C10-Fettalkohols und 6 Mol Ethylenoxid sowie 1 Mol Butylenoxid, methylendgruppenverschlossen,the reaction product from one mole of a C 10 fatty alcohol and 6 moles of ethylene oxide and 1 mole of butylene oxide, methyl end groups, 3 %3% Dodecyliminodipropionat-di-Na-Salz,Dodecyliminodipropionat-di-sodium salt, 6 %6% 2-Methyl-2,4-pentandiol und2-methyl-2,4-pentanediol and 7 %7% Wasser.Water.

    Es etnsteht eine klare, niederviskose Formulierung.A clear, low-viscosity formulation is created.

    Beispiel 10: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 10: The following components are mixed with one another with stirring:

    30 %30% des Umsetzungsproduktes aus einem Mol eines C11-Oxoalkohols und 4 Mol Ethylenoxidof the reaction product from one mole of a C 11 oxo alcohol and 4 moles of ethylene oxide 42 %42% der Komponente (b) gemäss Beispiel 1, aber mit einem Umsetzungsprodukt aus einem Mol eines C13-Oxoalkohols mit 8 Mol Ethylenoxid anstelle des Umsetzungsproduktes aus einem Mol eines C15-Oxoalkohols mit 9 und 10 Mol Ethylenoxid,component (b) according to Example 1, but with a reaction product of one mole of a C 13 oxo alcohol with 8 moles of ethylene oxide instead of the reaction product of one mole of a C 15 oxo alcohol with 9 and 10 moles of ethylene oxide, 12 %12% des Umsetzungsproduktes aus einem Mol eines C10-Fettalkohols und 6 Mol Ethylenoxid sowie 1 Mol Butylenoxid, methylendgruppenverschlossen,the reaction product from one mole of a C 10 fatty alcohol and 6 moles of ethylene oxide and 1 mole of butylene oxide, methyl end groups, 3 %3% Dodecyliminodipropionat-di-Na-Salz,Dodecyliminodipropionat-di-sodium salt, 6 %6% 2-Methyl-2,4-pentandiol und2-methyl-2,4-pentanediol and 7 %7% Wasser.Water.

    Es entsteht eine klare, niederviskose Formulierung.The result is a clear, low-viscosity formulation.

    Beispiel 11: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 11: The following components are mixed with one another with stirring:

    30 %30% des Umsetzungsproduktes aus einem Mol eines C11-Oxoalkohols und 4 Mol Ethylenoxidof the reaction product from one mole of a C 11 oxo alcohol and 4 moles of ethylene oxide 42 %42% der Komponente (b) gemäss Beispiel 1, aber mit einem Umsetzungsprodukt aus einem Mol eines C13-Oxoalkohols mit 4 Mol Ethylenoxid anstelle des Umsetzungsproduktes aus einem Mol eines C15-Oxoalkohols mit 9 und 10 Mol Ethylenoxid,component (b) according to Example 1, but with a reaction product of one mole of a C 13 oxo alcohol with 4 moles of ethylene oxide instead of the reaction product of one mole of a C 15 oxo alcohol with 9 and 10 moles of ethylene oxide, 12 %12% des Umsetzungsproduktes aus einem Mol eines C10-Fettalkohols und 6 Mol Ethylenoxid sowie 1 Mol Butylenoxid, methylendgruppenverschlossen, the reaction product from one mole of a C 10 fatty alcohol and 6 moles of ethylene oxide and 1 mole of butylene oxide, methyl end groups, 3 %3% Dodecyliminodipropionat-di-Na-Salz,Dodecyliminodipropionat-di-sodium salt, 6 %6% 2-Methyl-2,4-pantandiol und2-methyl-2,4-pantanediol and 7 %7% Wasser.Water.

    Es entsteht eine klare, niederviskose Formulierung.The result is a clear, low-viscosity formulation.

    Beispiel 12: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 12: The following components are mixed with one another with stirring:

    30 %30% des Umsetzungsproduktes aus einem Mol eines C11-Oxoalkohols und 4 Mol Ethylenoxidof the reaction product from one mole of a C 11 oxo alcohol and 4 moles of ethylene oxide 42 %42% der Komponente (b) gemäss Beispiel 2,component (b) according to Example 2, 12 %12% des Umsetzungsproduktes aus einem Mol eines C10-Fettalkohols und 6 Mol Ethylenoxid sowie 1 Mol Butylenoxid, methylendgruppenverschlossen,the reaction product from one mole of a C 10 fatty alcohol and 6 moles of ethylene oxide and 1 mole of butylene oxide, methyl end groups, 3 %3% Dodecyliminodipropionat-di-Na-Salz,Dodecyliminodipropionat-di-sodium salt, 6 %6% 2-Methyl-2,4-pentandiol und2-methyl-2,4-pentanediol and 7 %7% Wasser.Water.

    Es entsteht eine opale, niederviskose Formulierung.The result is an opal, low-viscosity formulation.

    Beispiel 13: Folgende Komponenten werden unter Rühren miteinander gemischt: Example 13: The following components are mixed with one another with stirring:

    38 %38% des Umsetzungsproduktes aus einem Mol eines C13-Oxoalkohols und 7 Mol Ethylenoxid,the reaction product from one mole of a C 13 oxo alcohol and 7 moles of ethylene oxide, 24 %24% der Komponente (b) gemäss Beispiel 1,component (b) according to Example 1, 6 %6% Citronensäure Monohydrat,Citric acid monohydrate, 4,8 %4.8% 1-Hydroxy-1,1-ethandiphosphonsäure,1-hydroxy-1,1-ethandiphosphonsäure, 3 %3% D-Gluconsäure,D-gluconic acid, 6 %6% 2-Methyl-2,4-pentandiol und2-methyl-2,4-pentanediol and 18,2 %18.2% Wasser.Water.

    Es entsteht eine klare, niederviskose Formulierung. The result is a clear, low-viscosity formulation.

    Applikationsbeispieleapplication examples Beispiel 14: Alkalischer Aufschluss nach dem Pad-Steam-VerfahrenExample 14: Alkaline digestion using the pad-steam method

    Rohbaumwollgewebe wird auf einem Foulard bei Raumtemperatur mit einer Behandlungsflotte der folgenden Zusammensetzung imprägniert: 2 g/l des gemäss Beispiel 4 hergestellten Textilhilfsmittels und 30 g/l NaOH(100%). Die Flottenaufnahme beträgt 100%. Die Ware wird nun für 10 Minuten in einen Dämpfer mit Sattdampf von 102°C geführt und anschliessend mit heissem Wasser ausgewaschen.Raw cotton fabric is impregnated on a foulard at room temperature with a treatment liquor of the following composition: 2 g / l of the textile auxiliary produced according to Example 4 and 30 g / l NaOH (100%). The fleet intake is 100%. The goods are then fed into a steamer with saturated steam at 102 ° C for 10 minutes and then washed out with hot water.

    Es resultiert eine entschlichtete Ware mit hoher Saugfähigkeit.The result is a desized product with high absorbency.

    Beispiel 15: Kaltlager-Peroxid-Bleiche Example 1 5 : Cold storage peroxide bleach

    Rohbaumwollgewebe wird auf einem Foulard bei Raumtemperatur mit einer Behandlungsflotte der folgenden Zusammensetzung imprägniert: 12 g/l des gemäss Beispiel 5 hergestellten Textilhilfmittels, 30 g/l NaOH (100%) und 50 ml/l Wasserstoffperoxid. Raw cotton fabric is impregnated on a foulard at room temperature with a treatment liquor of the following composition: 12 g / l the textile auxiliary produced according to Example 5, 30 g / l NaOH (100%) and 50 ml / l Hydrogen peroxide.

    Die Flottenaufnahme beträgt 100%. Die feuchte Ware wird auf eine Docke aufgewickelt, mit Plastikfolie verpackt und mit langsamer Drehbewegung der Docke 20 Stunden bei Raumtemperatur gelagert. Anschliessend wird die Ware mit heissem Wasser ausgewaschen. Es resultiert ein saugfähiges Gewebe mit hohem Weissgrad und nur geringer Faserschädigung.The fleet intake is 100%. The damp goods are wound up on a dock, packed with plastic wrap and with slow rotation of the dock 20 hours Stored at room temperature. The goods are then washed out with hot water. The result is an absorbent fabric with a high degree of whiteness and only low Fiber damage.

    Beispiel 16: Pad-Steam-Peroxidbleiche Example 1 6 : Pad-Steam Peroxide Bleach

    Rohbaumwollgewebe wird mit einer Behandlungsflote der folgenden Zusammensetzung besprüht: 20 g/l des gemäss Beispiel 8 hergestellten Textilhilfsmittels 40 g/l NaOH (100%) und 30 ml/l Wasserstoffperoxid (35%). Raw cotton fabric is sprayed with a treatment liquor of the following composition: 20 g / l of the textile auxiliary produced according to Example 8 40 g / l NaOH (100%) and 30 ml / l Hydrogen peroxide (35%).

    Die Besprühung erfolgt z.B. in einer Raco-Yet-Anlage der Firma Rimisch-Kleinwefers. Die Auftragsmenge beträgt 140 %. Die feuchte Ware wird für 2 Stunden in einem Dämpfer mit Sattdampf von 102°C behandelt und anschliessend mit heissem Wasser ausgewaschen.The spraying takes place e.g. in a Raco-Yet system from Rimisch-Kleinwefers. The order quantity is 140%. The damp goods are kept in a steamer for 2 hours treated with saturated steam at 102 ° C and then washed out with hot water.

    Es resultiert ein saugfähiges Gewebe mit hohem Weissgrad und nur geringer Faserschädigung.The result is an absorbent fabric with a high degree of whiteness and little fiber damage.

    Claims (12)

    1. A multifunctional textile auxiliary formulation comprising
      (a) 10 to 60% by weight of a nonionic surfactant of formula
      Figure 00290001
      (b) 10 to 60% by weight of a polymeric compound prepared by reacting 5 to 45% by weight of one or more than one nonionic surfactant of formula
      Figure 00290002
      with 45 to 5% by weight of acrylic or methacrylic acid in the presence of a catalyst from the class of organic free-radical initiators followed by partial neutralization to a pH from 3 to 6 with 1 to 8% by weight of an organic or inorganic base and
      (c) 4 to 20% by weight of a hydrotropic agent
      aromatic alcohols of formula
      Figure 00300001
         in which
      X1 is -(CH2)1-6-, -CH=CH-CH2- or -O-(CH2)2-6- and
      R8, R9 and R10 each independently of one another are hydrogen, hydroxy, halogen or C1-C6alkoxy
      - compounds of formula
      (7) R11O-SO3X2    in which
      R11 is an aliphatic saturated, branched or straight-chain radical having 4 to 24 carbon atoms and
      X2 is hydrogen, alkali metal or ammonium,
      an amphoteric surfactant selected from sodium lauriminodipropionate, dihydroxyethyltallow fatty glycinate, disodium cocoamphodiacetate, disodium capryloamphodiacetate or preferably disodium dicarboxyethylcocopropylenediamine or tallow fatty amphopolycarboxyglycinate,
      (d) 0 to 20% by weight of a nonionic surfactant of formula
      Figure 00300002
      (e) 0 to 8% by weight of a magnesium salt of an organic carboxylic acid
      (f) 0 to 30% by weight of a chelating agent or sequestrant selected from
      (f1)
      a mixture of monomers and oligomers of formulae
      Figure 00310001
      and
      Figure 00310002
      in which
      • Y7 is hydrogen or -COT1,
      • R14, X3 and T1 are each independently of one another C1-C4alkyl, and
      • q1 is 1 to 16,
      (f2)
      D-gluconic acid,
      (f3)
      citric acid, and
      (f4)
      aminophosphonic acid,
      (g) 0 to 10% by weight of a diol or polyol, and
      (h) 0 to 60% of water,
      with the proviso that said textile auxiliary must always comprise one of components (e) to (g),
      where in the formulae (3), (4) and (5)
      R4
      is C9-C14alkyl,
      R5
      is C1-C8alkyl, a cycloaliphatic radical having at least 5 carbon atoms, lower alkylphenyl or styryl,
      R6
      is C8-C13alkyl,
      R7
      is C8-C18alkyl,
      Y1, Y2, Y3 and Y4
      are each independently of one another hydrogen, methyl or ethyl, with the proviso that one of Y1, Y2, and Y3, Y4 is always hydrogen,
      Y5
      is hydrogen or methyl,
      Y6
      is hydrogen, methyl or ethyl,
      m2
      is 3 to 15,
      p1
      is an integer from 4 to 10, and
      p2
      is an integer from 0 to 8.
    2. A textile auxiliary formulation according to claim 1, wherein component (c) is sodium cumene-4-sulfonate.
    3. A textile auxiliary formulation according to one of claims 1 and 2, wherein component (c) is disodium dicarboxyethylcocopropylenediamine or tallow fatty amphopolycarboxyglycinate.
    4. A textile auxiliary formulation according to one of claims 1 to 3, wherein component (d) is a nonionic surfactant of formula
      Figure 00320001
      in which
      R12
      is C9-C14alkyl;
      R13
      is C1-C4alkyl;
      Y7, Y8, Y9 and Y10
      are each independently of one another hydrogen, methyl or ethyl, with the proviso that one of Y7, Y8 and Y9, Y10 is always hydrogen;
      p3 and p4
      are each independently of the other an integer from 4 to 8.
    5. A textile auxiliary formulation according to one of claims 1 to 4, wherein component (e) is magnesium mono- or digluconate.
    6. A textile auxiliary formulation according to one of claims 1 to 5, wherein component (f) comprises compounds selected from
      (f1)
      a mixture of monomers and oligomers of formula
      Figure 00330001
      in which
      Y7
      is hydrogen or -COT1,
      R14, X3 and T1
      are each independently of one another C1-C4alkyl, and
      q1
      is 1 to 17,
      (f2)
      D-gluconic acid,
      (f3)
      citric acid, and
      (f4)
      aminophosphonic acid.
    7. A textile auxiliary formulation according to claim 6, wherein component (f) is D-gluconic acid.
    8. A textile auxiliary formulation according to one of claims 1 to 7, wherein component (g) is 2-methyl-2,4-pentadiol.
    9. A textile auxiliary formulation according to one of claims 1 to 8, comprising
      (a) 10 to 60% by weight of one or more nonionic surfactants of formula
      Figure 00330002
      (b) 10 to 60% by weight of the reaction product of 5 to 45% by weight of one or more nonionic surfactants of formula
      Figure 00340001
      and 45 to 5% by weight of acrylic acid;
      (c) 4 to 20% by weight of a hydrotropic agent selected from sodium cumene-4-sulfonate and dodecyliminodipropionate disodium salt;
      (d) 0 to 20% by weight of a nonionic surfactant of formula
      Figure 00340002
      (e) 0 to 8% by weight of magnesium mono- or digluconate;
      (f) 0 to 30% by weight of D-gluconic acid; and
      (g) 0 to 10% by weight of 2-methyl-2,4-pentadiol; with the proviso that said textile auxiliary formulation must always comprise one of components (e) to (g),
      in which formulae above
      R6
      is C8-C13alkyl;
      R7
      is C8-C18alkyl;
      R12
      is C9-C14alkyl;
      R13
      is C1-C4alkyl;
      Y5
      is hydrogen or methyl;
      Y6
      is hydrogen, methyl or ethyl;
      Y7, Y8, Y9 and Y10
      are each independently of one another hydrogen, methyl or ethyl, with the proviso that one of Y7, Y8 and Y9, Y10 is always hydrogen;
      m2
      is 4 to 15;
      n2
      is 1 to 40; and
      p3 and p4
      are each independently of the other an integer from 4 to 8.
    10. A process for the preparation of a textile auxiliary formulation according to one of claims 1 to 9, which comprises first preparing component (b) by reacting 5 to 45% by weight of a nonionic surfactant of formula (5) with 45 to 5% by weight of acrylic or methacrylic acid in the presence of a catalyst from the class of organic free-radical initiators followed by partial neutralization to a pH of 3 to 6 with 1 to 8% by weight of an organic or inorganic base, adjusting the pH to about 4.5 and then adding the remaining components until a homogeneous solution is obtained.
    11. A process for wetting, washing and/or bleaching fibre materials in aqueous medium in the presence of a textile auxiliary formulation as defined in claim 1.
    12. A process according to claim 1, wherein the textile auxiliary formulation is used in an amount of 0.1 to 60 g, preferably of 1 to 20 g, per litre of liquor.
    EP95810494A 1994-08-11 1995-08-02 Multifunctionnal textile agents compositions Expired - Lifetime EP0696661B1 (en)

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    CH248694 1994-08-11

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    TW293051B (en) 1996-12-11
    DE59510431D1 (en) 2002-11-28
    ES2182880T3 (en) 2003-03-16
    KR960007926A (en) 1996-03-22
    BR9503609A (en) 1996-04-09
    JPH0881696A (en) 1996-03-26
    US6200948B1 (en) 2001-03-13
    EP0696661A1 (en) 1996-02-14

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