EP0678118B1 - Parfümierte waschmittelpulvern - Google Patents

Parfümierte waschmittelpulvern Download PDF

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Publication number
EP0678118B1
EP0678118B1 EP94904603A EP94904603A EP0678118B1 EP 0678118 B1 EP0678118 B1 EP 0678118B1 EP 94904603 A EP94904603 A EP 94904603A EP 94904603 A EP94904603 A EP 94904603A EP 0678118 B1 EP0678118 B1 EP 0678118B1
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EP
European Patent Office
Prior art keywords
perfume
detergent
carrier
surfactants
carrier particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94904603A
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English (en)
French (fr)
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EP0678118A1 (de
Inventor
John Martin Behan
Richard Arthur Birch
John Leake
Jeremy Nicholas Ness
Anthony Nock
Keith Douglas Perring
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Givaudan Nederland Services BV
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Quest International BV
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Priority to EP94904603A priority Critical patent/EP0678118B1/de
Priority claimed from PCT/EP1993/003695 external-priority patent/WO1994016046A1/en
Publication of EP0678118A1 publication Critical patent/EP0678118A1/de
Application granted granted Critical
Publication of EP0678118B1 publication Critical patent/EP0678118B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Definitions

  • the invention relates to perfumed laundry detergent powders and to perfume-on-carrier systems for incorporation into laundry detergent powders.
  • Detergent powders for laundry use span a wide range of compositions.
  • Traditional (or "regular") products are typified by a detergent surfactant level of between 8% and 20% by weight in total, more commonly 10% to 15%.
  • the surfactants may be anionic, non-ionic, cationic, zwitterionic or amphoteric in nature, and commercial products may contain all classes of surfactants, but the predominant form is generally anionic (i.e. anionic surfactants typically account for 50% or more of the total surfactants).
  • Typical detergent surfactants are described in detail in "Surfactant Surface Agents and Detergents", volume II by Schwartz, Perry and Birch, Interscience Publishers (1958).
  • the remainder of a laundry detergent composition generally comprises builders, fillers, moisture, soil release and soil suspension and anti-redeposition agents, and other optional adjuncts such as processing aids, optical brighteners, dyes, foam control agents, anti-corrosion agents, perfumes, pH control agents, enzymes, stabilisers, bleaches and bleach activators.
  • the level of solid components in regular laundry detergent compositions is high, usually above 75%, often above 85%. Perfume loadings for such compositions are generally within the range 0.05% to 0.4%, more commonly 0.1% to 0.3%, and the ratio of solid constituents to organic liquid constituents in a regular detergent composition is usually at least 30:1, and is likely in practice to be considerably higher, e.g. at least 150:1 and up to 500:1.
  • Laundry detergent powder concentrates and hyperconcentrates represent a relatively new product segment which is assuming increasing commercial importance world-wide. These concentrated products have a rather different composition to that described above.
  • the total level of detergent surfactants in concentrates generally lies within the range 15% to 60% by by weight of the powder, more usually 20% to 40%.
  • another major point of difference concerns the level of low-functionality materials such as fillers.
  • the level of sodium sulphate for example, is rarely above 6% or even 2% by weight, whereas in regular powders levels of 20% to 30% are common.
  • the composition of the actives may be similar to that in regular products, i.e. predominantly anionics, but not restricted to this and, for example, a high proportion of non-ionics may be used advantageously.
  • a concentrate may be defined for the purposes of the present specification as comprising at least 15% (and preferably at least 20%) w/w total surfactant actives and at least 0.1% w/w perfume, preferably at least 0.4% w/w.
  • the ratio of total solid to total organic liquid components for certain concentrates may be less than 30:1, or even less than 10:1, and problems can arise in manufacture and storage of the product due to "stickiness" and lump formation.
  • processing problems may arise from agglomeration of particles, with handling difficulties during production, and with the possibility of forming large powder conglomerates which are unacceptable to the end user of the product.
  • GB-A-2066839 discloses detergent powders containing perfume sorbed onto a porous carrier at a level of 10% to 65% by weight.
  • the carrier is a large surface area sorbent selected from a wide variety of substrates such as polyacrylates, polyvinyl chloride, urea-formaldehyde resins, polystyrene, hydrated silicon dioxide, titanium dioxide, aluminium trioxide, or mixtures thereof.
  • the primary objective of the invention disclosed therein is to decrease perfume losses through volatilisation and chemical attack during storage of perfumed powder products.
  • GB-A-1306924 describes perfume particles in free-flowing powder form'' prepared from perfume and a particulate silica, or more particularly from a mixture of a finely divided silica and an absorbent silica gel.
  • the fragrance loading in these particles may be as high as 70%.
  • Manufacture is economical and involves simple mixing of perfume oil with the silicas, followed by sieving. Examples are disclosed of perfume particles suitable for use in talcum powders, scouring powders, deodorants, toilet blocks, bath crystals and foot powders. No disclosure is made of use in detergent powders, and nothing is revealed regarding perfume stability within concentrates, nor are specific physical properties such as hydrophilic character or bulk density disclosed.
  • US-A-4209417 teaches the use of perfume particles prepared using a water-soluble polymer together with an emulsifier.
  • the loading of perfume in these particles may be high (30% to 70%), but the manufacturing process involves drying large volumes of aqueous dispersions, with adverse consequences for throughput and economy.
  • the perfume must be water-insoluble.
  • the teachings of GB-A-2090278 are similar, except that the perfumed particle contains water but is rendered free flowing by the inclusion of excess powdered hydratable material such as anhydrous alkali metal salts. The maximum possible loading of perfume is thereby significantly reduced.
  • Perfume-on-carrier systems for laundry detergent compositions as disclosed in EP-A-334666 are designed to deliver perfume to fabric efficiently through the use of fabric substantive carriers such as selected solid non-ionic or cationic surfactants.
  • the processing involves melt blending the components followed by spray chilling, and the resulting perfume loading is likely to be low (25% w/w or less).
  • Similar targeted delivery of perfume is provided by the microcapsules described in EP-A-376385, where a complex coacervate prepared from perfume and polycationic and polyanionic materials is coated with a water-insoluble cationic fabric softener which facilitates perfume delivery to fabric. In both these inventions the cost of manufacture is relatively high and relatively complicated processing steps are involved.
  • GB-A-2140820 and GB-A-2141730 describe perfume-on-carrier systems based on zeolites or clays, with an optional coating of a fabric-adhesive agent, wherein the perfume loading in these carriers is low (10% or less).
  • the carrier systems are designed to deliver perfume to fabric via the zeolite or clay, which are likely to contact fabric and be dispersed thereupon during laundering, and are hydrophobic enough to retain sufficient perfume even in the wash solution.
  • EP-A-325457 describes a perfumed granular concentrated detergent compositions wherein the perfume is incorporated in clathrate granules comprising the perfume and a compound having clathration capability, which compound is preferably cyclodextrin.
  • the clathrate granules have an average size of 100-1500 micron.
  • EP-A-334490 describes a perfumed detergent composition wherein the perfume is incorporated in a combination of discrete particles of a water-soluble polymer and a water-insoluble polymer, the one being entrapped in the other.
  • the preparation of these particles involves a complicated process.
  • EP-A-478326 describes a process for encapsulation of perfumes, flavours and other materials involving high shear mixing of e.g. the perfume with an aqueous dispersion of very fine silica and gelling the emulsion thus obtained.
  • EP-A-332259 and EP-A-332260 detail the use of silica perfume carriers in detergent powders and fabric softeners, respectively.
  • the silicas span a wide range of types, with particle size of from 0.001 micron (fumed silica) through to 15 micron (silica gel), with a surface area of 100 - 800 m 2 /g.
  • the preferred silica is a fumed type, with particle size in the range 0.007 micron to 0.025 micron, although silica gels may also be used, the preferred particle size being 1 to 8 micron.
  • silica carriers are optimised for application in detergent compositions providing perfume at a level of 0.01 to 0.5%, and where the perfume includes components which require protection from hostile bleaching agents present in the detergent composition.
  • the detergent compositions contain preferably 10% to 25% of detersive surfactants.
  • the examples given are high in anionic type surfactants, and can have high solid to organic liquid ratios. It is stated in EP 332259 that "in addition to separating and protecting the perfume from the bleach, it is believed that the silica particles deposit on fabrics and enhance the delivery of the perfume to the fabrics".
  • the invention provides perfumed, free flowing concentrated laundry detergent powders (concentrates), having a ratio of total solid constituents to total liquid constituents of less than 30:1 and containing at least 0.1 w/w of perfume, wherein the perfume is sorbed onto inorganic carrier particles having a mean diameter of at least 20 micrometres, which carry at least 25% w/w of perfume and which release at least 60% w/w of the perfume in the Perfume Release Test as described herein below and which are inert as defined by the Perfume Stability Test described herein below.
  • the invention provides perfume-on-carrier systems wherein inorganic carrier particles having a mean diameter of at least 20 micrometres and which carry at least 25% w/w of perfume release at least 60% w/w of the perfume in the Perfume Release Test as described herein below and are inert as defined by the Perfume Stability Test described herein below.
  • a concentrated laundry detergent powder (or “concentrate”) is defined as a detergent powder comprising:
  • concentrates preferably have a bulk-density of at least 600 g/l.
  • concentrates generally contain other components, such as builders (phosphates such as sodium tripolyphosphate, zeolites or NTA), soil suspension and anti-redeposition agents, enzymes, optical brighteners, processing aids, dyes, foam control agents, anti-corrosion agents, pH control agents, stabilisers.
  • bleaching detergents also contain bleaches and bleach activators.
  • the invention is particularly concerned with concentrates in which a substantial proportion, i.e. 35% w/w or more, of the surfactants is liquid at ambient temperature.
  • a particular surfactant is in fact a mixture of chemically closely related but slightly different components, e.g. a mixture of polymers with varying degrees of polymerization. Therefore, such products do not have a sharp melting point.
  • a surfactant is considered liquid when at a temperature of 25°C and above it contains no more than 50% solids.
  • the invention is therefore also particularly concerned with concentrates in which a substantial part of the surfactant is of the nonionic type.
  • concentrates comprising mainly nonionic and anionic surfactants in which the ratio of nonionic to anionic surfactant is at least 3:2 and wherein at least 35% w/w of the total quantity of surfactants is liquid.
  • these concentrates generally at least 60% w/w of the nonionics is liquid.
  • concentrates in which all of the surfactants are nonionics, of which at least 35%/ w/w is liquid.
  • the concentrates according to the invention contain the perfume-on-carrier systems according to the invention in a quantity to give at least 0.1% w/w (calculated on the total concentrate) of perfume in the concentrate, preferably 0.4-2.5% of perfume, more preferably 0.5-1.5% w/w of perfume in the concentrate.
  • the actual quantity of perfume-on-carrier system to be added thus also depends on the perfume content in the perfume-on-carrier system as hereinbelow described.
  • perfume denotes a substantially water-insoluble composition of matter consisting of one or more perfume components, optionally mixed with a suitable solvent or diluent, which is used to impart a desired odour to the detergent product to which it is added and/or to the wash liquor, the skin, hair or the fabric.
  • Perfume components are those constituents of a perfume which are added thereto only or primarily for their olfactive contribution.
  • Perfume components may be natural products such as extracts, essential oils, absolutes, resinoids, resins or concretes, but also synthetic materials such as hydrocarbons, alcohols, aldehydes, ketones, ethers, acids, esters, acetals, ketals or nitriles, including saturated and unsaturated compounds, aliphatic, carbocyclic and heterocyclic compounds.
  • Such perfume components are mentioned, for example, in S. Arctander, Perfume and Flavor Chemicals (Montclair, N.J., 1969), in S. Arctander, Perfume and Flavor Materials of Natural Origin (Elizabeth, N.J., 1960) and in "Flavor and Fragrance Materials - 1991", Allured Publishing Co. Wheaton, Ill. USA.
  • perfume components are: geraniol, geranyl acetate, linalol, linalyl acetate, tetrahydrolinalol, citronellol, citronellyl acetate, dihydromyrcenol, dihydromyrcenyl acetate, tetrahydromyrcenol, terpineol, terpinyl acetate, nopol, nopyl acetate, 2-phenylethanol, 2-phenylethyl acetate, benzyl alcohol, benzyl acetate, benzyl salicylate, styrallyl acetate, benzyl benzoate, amyl salicylate, dimethylbenzyl carbinol, trichloromethylphenylcarbinyl acetate, p-tert-butyl cyclohexyl acetate, isononyl acetate, vetiveryl acetate, vetiverol
  • Suitable solvents and diluents for perfumes as mentioned above are, for example, diethyl phthalate, triethyl citrate, ethanol, isopropanol or dipropylene glycol.
  • the perfume-on-carrier systems (hereinafter for brevity referred to as "POC systems") according to the invention comprise a perfume as defined above and an inert inorganic particulate carrier. Inertness of the carrier is tested with a test perfume as described below in the "Perfume Stability Test". For the purposes of this invention a carrier is considered inert if each component in the test perfume 1 of Table 1 below suffers no more than 5% deterioration under the test conditions.
  • the POC systems should easily release a substantial proportion of its perfume content when immersed in a laundry wash liquor. This ability requires the carrier to be sufficiently hydrophobic and the suitability of a carrier can be determined with the "Perfume Release Test" described below. For the purposes of this invention a carrier is considered to pass the test if under the test conditions it is found to release at least 60% of the test perfume 2 of Table 2 below.
  • the POC systems comprise at least 25% w/w of perfume, preferably at least 40% and more preferably at least 70% w/w. Yet the POC system should remain free-flowing.
  • the inert carrier particles have a mean diameter in the range 20-50 microns. Also, they should preferably have a surface area in the range 100-450 m 2 /g, more preferably in the range 100-350m 2 /g, most preferably in the range 100-300 m 2 /g.
  • An inorganic carrier is used, such as a silica, zeolite or clay. Typically the carrier particles are of amorphous silica.
  • the concentrates according to the invention may comprise up to 20% w/w of the total perfume quantity, and preferably no more than 10%, in microencapsulated form (e.g. as spray dried starch encapsulates).
  • the POC systems are conveniently prepared by mixing the perfume with the carrier particles.
  • the mixing of the perfume and the carrier may be carried out in a variety of ways known to the practitioner in the art, for example by spraying the perfume onto the particles contained in a rotary drum or positioned on a conveyor belt.
  • a non-limiting example of a suitable procedure involves the use of a Tatham-Forberg mixer in a low speed, short duration operation.
  • the equipment comprises a twin-drum assembly with a rotary twin-shaft arrangement. Attached to each shaft is a set of carefully profiled paddles positioned at specific angles.
  • the powder charge is fluidised by the paddle rotation and the perfume oil is sprayed on and mixing is continued until perfume take up is complete.
  • the perfumed particle mass is then dropped through the bottom of the mixer into a suitable container.
  • perfumes into or onto inert carrier particles will not necessarily protect the perfumes against attack by bleaching compounds.
  • the perfume is preferably one which is resistant to such attack and retains high performance even when stored in the presence of such hostile ingredients. Suitable non-limiting examples are disclosed in EP-A-299561 and US-A-4663068.
  • the POC systems of the present invention may be incorporated into concentrates using standard powder handling equipment, known in the art, e.g. by utilisation of weigh-belts.
  • a particulate sample (2g) was prepared by incorporating 20% of the perfume test mixture 1 detailed in Table 1 into an inorganic carrier under evaluation.
  • the sample was stored in glass vials (10ml) for one week at 37°C prior to analysis.
  • the vials were tightly sealed and free movement of air throughout the test system was minimised by packing the free headspace volume with cotton wool.
  • Suitable carriers according to this test are those for which each of the indicator materials suffer no more than 5% degradation (i.e. each component in the system displays at least 95% stability). Such carriers are defined as passing the Perfume Stability Test for the purposes of the present application.
  • the POC system under evaluation (containing at least 20% by weight of Perfume Test Mixture 2, Table 2) were equilibrated for 3 days and then added at ambient temperature to an aqueous model wash liquor at a level yielding a theoretical maximum perfume concentration of 40 ppm.
  • the wash liquor (10g) comprised Ca. 0.05% of a mixture of a non-ionic surfactant (Dobanol 24TM, a mixture of ethoxylated fatty alcohols with an average of 7 ethoxyl groups) and an anionic surfactant (sodium lauryl sulphate) in a weight ratio of 2.3 to 1.
  • the mixture was shaken for 10 seconds and immediately placed in a centrifuge and spun for 5 minutes at 2000 RPM.
  • the bulk of the supernatant liquid was withdrawn (ca. 95% by weight of the aqueous phase, measured accurately) and filtered prior to extraction with ethyl acetate (10g, containing hexadecane as an internal standard).
  • the ethyl acetate was obtained by centrifugation and was analysed by gas chromatography. The amount of perfume released into the aqueous phase was then calculated.
  • a perfume release efficiency of 60% or over is taken as indicative of bulk release of the perfume under actual wash conditions where temperatures of 35°C to 65°C or higher are common, and longer wash times are likely (e.g. 15-30 minutes, or longer in a soak regime). Carrier materials achieving this are considered to pass the Perfume Release Test.
  • POC system particles containing 50% perfume were prepared from Neosyl GPTM and fragrance "A" as specified in Table 5. These were incorporated into concentrate powder (formulation A, Table 1) at a level of 1.1% to yield a perfume loading of 0.55%. The powder was stored in domestic laminated cardboard containers at 37°C/70% RH (relative humidity) for 4 weeks and examined. No adverse effect was noted on powder flow properties.
  • POC system particles containing 50% perfume were prepared from Neosyl GPTM and fragrance "A as specified in Table 5. These were incorporated into a concentrate powder (formulation B, Table 1) at a level of 1.1% to yield a perfume loading of 0.55%. The powder was stored in domestic laminated carboard containers at 37°C/70% RH (relative humidity) for 4 weeks and examined. No adverse effect was noted on powder flow properties.
  • POC system particles containing 55% perfume were prepared were prepared from Neosyl GPTM and fragrance "B" as specified in Table 6. These were incorporated into a concentrate powder (formulation B, Table 1) at a level of 1.45% to yield a perfume loading of 0.8%. The powder was stored in domestic laminated cardboard containers at 37°C/70% RH for 4 weeks and examined. No adverse effects was noted on powder flow properties.
  • POC system particles containing 55% perfume were prepared from HP 39TM and fragrance "B" as specified in Table 6. These were incorporated into a concentrate powder (formulation B, Table 1) at a level of 1.45% to yield a perfume loading of 0.8%. The powder was stored in domestic laminated carboard containers at 37°C/70% RH for 4 weeks and examined. No adverse effect was noted on powder flow properties.
  • a starch encapsulate was prepared containing 40% perfume oil.
  • the starch was a modified waxy maize starch (capsulTM, National Starch) and the perfume was a freshness accord (Fragrance C, Table 7) of perfume materials susceptible to attack by bleach components in laundry powder.
  • the encapsulate was prepared by normal spray-drying procedures, well known to those experience in the art.
  • An emulsion of 40% starch in water was prepared and sufficient perfume added to constitute 40% of the total of starch and perfume. This emulsion was then spray-dried using a conventional spray-dryer (Niro Mobile Minor) with rotary atomizer, inlet temperature 240°C, outlet temperature 100°C.
  • POC system particles containing 50% perfume were prepared from Neosyl GPTM and fragrance "B" (see Table 6). These were mixed into a concentrate powder (formulation B, Table 1) at a level of 1.1% to yield a perfume loading of 0.55%. To this product was then mixed in 0.2% of the starch encapsulate detailed above, yielding an overall perfume level of 0.63%. The powder was stored in domestic laminated cardboard containers at 37°C/70% RH for 4 weeks and examined. No adverse effect was noted on powder flow properties.
  • fragrance "A" Material Quantity % Anther () 1.0 Coumarin 2.0 Gyrane () 0,5 Hexyl cinnamic aldehyde 18.0 Jasmacyclene () 5.0 Jasmopyrane Forte () 4.0 Lilial () 10.0 Lixetone () 8.0 Methyl ionone alpha iso () 5.0 4-tert.butylcyclohexyl acetate () 5.0 2-Phenylethyl alcohol 15.0 Pivacyclene () 0.5 Tetrahydrolinalol 6.0 Traseolide () 20.0 Formulation of fragrance "B” Material Quantity % Dimethylbenzyl carbinyl acetate 15.0 4-tert.butylcyclohexyl acetate () 17.5 Tetrahydrolinalol 15.0 Anther () 3.5 Traseolide () 5.0 Decanol 5.0 Phenylpropanol 6.0 Herboxane 10.0 Diphenylmethane

Claims (16)

  1. Parfümiertes, frei fließendes konzentriertes Waschmittelpulver, das ein als Parfüm-auf-Träger-System zugegebenes Parfüm umfaßt, dadurch gekennzeichnet, daß das Waschpulver mindestens 15 Gew.-% an grenzflächenaktiven Waschstoffen und weniger als 10 Gew.-% an Füllmaterialien umfaßt, ein Verhältnis von der Gesamtmenge an festen Bestandteilen zu der Gesamtmenge an flüssigen Bestandteilen von weniger als 30 : 1 aufweist und mindestens 0,1 Gew.-% an Parfüm enthält, wobei das Parfüm-auf-Träger-System aus anorganischen Trägerpartikeln mit einem mittleren Durchmesser von mindestens 20 µm besteht, die mindestens 25 Gew.-% an Parfüm tragen, die mindestens 60 Gew.% des Parfüms in dem hier beschriebenen Parfümfreisetzungstest freisetzen und die inert sind, wie durch den hier beschriebenen Parfümstabilitätstest definiert.
  2. Waschpulver nach Anspruch 1, dadurch gekennzeichnet, daß das Pulver eine Schüttdichte von mindestens 600 g/l besitzt.
  3. Waschpulver nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß die Menge an grenzflächenaktiven Waschstoff mindestens 20 Gew.-% beträgt und die Menge an Füllmaterial weniger als 6 Gew.-% beträgt.
  4. Waschpulver nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß mindestens 35 Gew.-% der grenzflächenaktiven Stoffe Flüssigkeiten wie hier definiert sind.
  5. Waschpulver nach Anspruch 4, dadurch gekennzeichnet, daß die grenzflächenaktiven Stoffe nicht ionische und anionische grenzflächenaktive Waschstoffe umfassen, wobei das Verhältnis von nicht ionischen grenzflächenaktiven Waschstoffen zu anionischen grenzflächenaktiven Waschstoffen mindestens 3 : 2 ist und mindestens 60 Gew.-% der nicht ionischen grenzflächenaktiven Waschstoffe flüssig sind.
  6. Waschpulver nach Anspruch 4, dadurch gekennzeichnet, daß alle grenzflächenaktiven Waschstoffe nicht ionisch sind, von denen mindestens 35 Gew.-% flüssig sind.
  7. Waschpulver nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß die Trägerpartikel mindestens 40 Gew.-% an Parfüm tragen.
  8. Waschpulver nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß die Trägerpartikel einen mittleren Durchmesser in einem Bereich von 20 bis 50 µm aufweisen.
  9. Waschpulver nach Anspruch 7 oder 8, dadurch gekennzeichnet, daß die Trägerpartikel eine Oberfläche im Bereich von 100 bis 450 m2/g besitzen.
  10. Waschpulver nach Anspruch 9, dadurch gekennzeichnet, daß die Trägerpartikel eine Oberfläche im Bereich von 100 bis 350 m2/g besitzen.
  11. Waschpulver nach einem der Ansprüche 7 bis 10, dadurch gekennzeichnet, daß die Trägerpartikel amorphes Siliciumdioxid sind.
  12. Parfüm-auf-Träger-System, bestehend aus anorganischen Partikeln, die das Parfüm tragen, dadurch gekennzeichnet, daß die Partikel mindestens 25 Gew.-% des Parfüms tragen, mindestens 60 Gew.-% des Parfüms in dem hier beschriebenen Parfümfreisetzungstest freisetzen, inert sind, wie durch den hier beschriebenen Parfümstabilitätstest definiert, und einen mittleren Durchmesser von mindestens 20 µm besitzen.
  13. Parfüm-auf-Träger-System nach Anspruch 12, dadurch gekennzeichnet, daß die Trägerpartikel mindestens 40 Gew.-% des Parfüms tragen.
  14. Parfüm-auf-Träger-System nach Anspruch 12 oder 13, dadurch gekennzeichnet, daß die Trägerpartikel eine Oberfläche im Bereich von 100 bis 450 m2/g besitzen.
  15. Parfüm-auf-Träger-System nach Anspruch 14, dadurch gekennzeichnet, daß die Trägerpartikel eine Oberfläche im Bereich von 100 bis 350 m2/g besitzen.
  16. Parfüm-auf-Träger-System nach einem der Ansprüche 12 bis 15, dadurch gekennzeichnet, daß die Trägerpartikel aus amorphem Siliciumdioxid sind.
EP94904603A 1993-01-11 1993-12-23 Parfümierte waschmittelpulvern Expired - Lifetime EP0678118B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP94904603A EP0678118B1 (de) 1993-01-11 1993-12-23 Parfümierte waschmittelpulvern

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP93300147 1993-01-11
EP93300147 1993-01-11
EP93300180 1993-01-13
EP93300180 1993-01-13
EP94904603A EP0678118B1 (de) 1993-01-11 1993-12-23 Parfümierte waschmittelpulvern
PCT/EP1993/003695 WO1994016046A1 (en) 1993-01-11 1993-12-23 Perfumed laundry detergent powders

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EP0678118A1 EP0678118A1 (de) 1995-10-25
EP0678118B1 true EP0678118B1 (de) 2000-03-01

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0332260A2 (de) * 1988-03-07 1989-09-13 The Procter & Gamble Company Parfümteilchen enthaltende weichmachende Zusammensetzung
EP0332259A2 (de) * 1988-03-07 1989-09-13 The Procter & Gamble Company Waschmittelzusammensetzungen, die Peroxysäure-Bleiche und Riechstoff enthalten

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0332260A2 (de) * 1988-03-07 1989-09-13 The Procter & Gamble Company Parfümteilchen enthaltende weichmachende Zusammensetzung
EP0332259A2 (de) * 1988-03-07 1989-09-13 The Procter & Gamble Company Waschmittelzusammensetzungen, die Peroxysäure-Bleiche und Riechstoff enthalten

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