EP0670921A1 - Gewebe mit kette und schuss auf basis von technischen multifilamenten garnen hauptsächlich ohne torsion und verfahren zur herstellung - Google Patents

Gewebe mit kette und schuss auf basis von technischen multifilamenten garnen hauptsächlich ohne torsion und verfahren zur herstellung

Info

Publication number
EP0670921A1
EP0670921A1 EP94900890A EP94900890A EP0670921A1 EP 0670921 A1 EP0670921 A1 EP 0670921A1 EP 94900890 A EP94900890 A EP 94900890A EP 94900890 A EP94900890 A EP 94900890A EP 0670921 A1 EP0670921 A1 EP 0670921A1
Authority
EP
European Patent Office
Prior art keywords
threads
fabric
weft
warp
yarns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP94900890A
Other languages
English (en)
French (fr)
Other versions
EP0670921B1 (de
Inventor
Jean Pierre-Blanche Aucagne
Bruno Bompard
Alain Bruyere
Christian Debaille
Bertrand Germain
Jean-Paul Lamarie
Laurent Martinet
Franck Perret
Jean-François VEAUVILLE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexcel Fabrics SA
Original Assignee
Brochier SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9436053&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0670921(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Brochier SA filed Critical Brochier SA
Publication of EP0670921A1 publication Critical patent/EP0670921A1/de
Application granted granted Critical
Publication of EP0670921B1 publication Critical patent/EP0670921B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/44Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape
    • D03D15/46Flat yarns, e.g. tapes or films
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D3/00Woven fabrics characterised by their shape
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/275Carbon fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/41Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific twist
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03JAUXILIARY WEAVING APPARATUS; WEAVERS' TOOLS; SHUTTLES
    • D03J1/00Auxiliary apparatus combined with or associated with looms
    • D03J1/06Auxiliary apparatus combined with or associated with looms for treating fabric
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/02Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
    • D10B2101/06Glass
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/02Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
    • D10B2101/08Ceramic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00Industrial
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/902High modulus filament or fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/30Self-sustaining carbon mass or layer with impregnant or other layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926Coated or impregnated inorganic fiber fabric
    • Y10T442/2984Coated or impregnated carbon or carbonaceous fiber fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926Coated or impregnated inorganic fiber fabric
    • Y10T442/2992Coated or impregnated glass fiber fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065Including strand which is of specific structural definition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3472Woven fabric including an additional woven fabric layer

Definitions

  • Warp and weft fabric based on predominantly twist-free multifilament technical yarns and process for obtaining it
  • the invention relates to the field of textile structures intended for the production of composite materials. It relates more particularly to a warp and weft fabric produced, for the most part, based on multifilament technical yarns of relatively high titer for a relatively low grammage, and to the corresponding production process.
  • composite materials are experiencing great development, due to their excellent mechanical properties combined with low weight.
  • Such materials essentially comprise a textile reinforcement and a resin matrix.
  • Those skilled in the art know that the production of these materials causes a number of difficulties. Indeed, for certain uses, in particular in the aeronautical field, the mechanical properties of the composite materials are strictly defined.
  • the textile structures used in the composite materials be tight enough to maintain a regular geometry and a suitability for handling, while allowing satisfactory penetration of the resin during the manufacture of the composite. This makes it possible to obtain satisfactory mechanical properties in the final composite.
  • fibers that are sufficiently fine to constitute such tight structures.
  • a wire is chosen which makes it possible to obtain perfect coverage, that is to say a regular spreading which does not reveal porosities or even correlatively, making it possible to obtain a high volume rate.
  • the lower the grammage of the textile structure the lower the titer of the fibers, that is to say the linear mass of each fiber.
  • composite materials must be offered at prices lower than those currently practiced.
  • the price of a composite part corresponds to that of the aluminum part, which requires significant cost reductions.
  • a fabric based on 6K yarns is approximately 30% cheaper than a fabric based on 3K yarns, for the same grammage.
  • a fabric made from 12K yarn is about 50% cheaper than a fabric of the same weight, made from 3K yarn.
  • Fabrics weighing less than 90 g / m 2 can be produced from 1K yarns, but they have a porosity incompatible with a perfect coverage objective.
  • the grammage of the fabrics is generally between 180 and 400 g / m 2 ; for 6K wires, it usually ranges from 260 to
  • the remark made for carbon fabrics based on 1K threads relating to the minimum mass of fabrics is also applicable to carbon fabrics obtained from 3K, 6K and 12K threads.
  • document FR-2 418 693 describes a process making it possible to reduce the porosity of a prepreg fabric, and more particularly an impregnated fabric consisting of carbon fibers, without requiring finer fibers.
  • This process successively consists of forming a fiber of filaments having a relatively circular cross section, weaving the fiber to form a fabric having relatively large interstices, impregnating the fabric with an uncured resin, loading a cylinder against one side of the fabric impregnated while supporting the other side of the fabric at least in front of the cylinder and moving the cylinder on the fabric a sufficient number of times to obtain the desired flattening of the fiber.
  • the calendering thus carried out makes it possible to flatten the fiber and thus to reduce the dimensions of the interstices, which makes it easier to fill the interstices when the resin hardens and therefore to reduce the porosity in the finished cured laminated product.
  • the quantity by fiber ratio (TVF) will denote the quantity defined as follows: mass of the fabric / density of the material of the yarn
  • TVF unit width x unit length x thickness
  • volume ratio of the fibers can be calculated at any point of the fabric.
  • the invention therefore relates to a warp and weft fabric based on technical yarns of microns, of which at least 80% by weight of the yarns have the following characteristics in combination:
  • the volume content of fibers being substantially constant in the fabric and greater than or equal to that of a traditional fabric based on threads of equal or lower titer.
  • the volume content of fibers is substantially constant in the fabric and greater than or equal to that of a traditional fabric based on yarns of equal or lower titer.
  • the invention also relates to a fabric such that the weight share of the warp (or weft) threads is less than or equal to 20%, these threads constituting the binding weave of the unidirectional weft (or warp) fabric.
  • the warp and weft fabric according to the invention is produced on the basis of carbon, glass, high density polyethylene, aramid, silicon carbide, ceramic yarns or else based on mixtures and combinations of such sons.
  • the invention relates to a warp and weft fabric made from 6K carbon yarns, the grammage of the fabric being approximately 200 g / m 2 , in particular 193 g / m 2 and the volume content of fibers d '' about 38%, under a pressure of 10 4 Pa.
  • the invention also relates to a warp and weft fabric made from 12K carbon threads, the grammage of the fabric being approximately 200 g / m 2 , in particular
  • It also relates to a warp and weft fabric made from aramid yarns, the titer of which is approximately 240 tex, the grammage of the fabric being approximately 180 g / m 2 , in particular 175 g / m 2 and the volume rate. of fibers greater than or equal to 42%, under a pressure of 10 4 Pa.
  • the invention further relates to a fabric made from glass yarns, 80% by weight of the weft (or warp) yarns being yarns whose title is approximately 320 tex, the grammage of the fabric being approximately 120 g / m 2 and the volume rate of fibers being greater than or equal to 26%, under a pressure of 10 4 Pa.
  • the invention also relates to a process for obtaining a warp and weft fabric based on multifilament technical yarns of which at least 80% by weight are yarns with 0 twist turn / m whose title, for a given grammage of the fabric , is higher than that traditionally used, consisting of:
  • the method also consists in spreading the threads in the fabric obtained.
  • the spreading step is carried out after weaving.
  • the spreading step is carried out before a subsequent transformation of the fabric, such as dusting, prepreg or laminating.
  • the method also consists in spreading the threads before weaving. This means contributes to obtaining an appropriate volume content of fibers in the final fabric.
  • the invention also relates to a device for spreading the threads in the fabric, in accordance with the production process according to the invention.
  • the device comprises a vibrator on which is mounted a rotating roller, intended to come into contact with the fabric.
  • the vibrator is a pneumatic vibrator whose frequency is 100 Hertz under a pressure of 6 10 5 Pa.
  • FIG. 1 schematically illustrates an overview of an installation for obtaining a fabric according to the invention
  • Figure 2 which schematically shows a frame unwinding device, is a partial section of Figure 1 along II-II;
  • FIG. 3 schematically represents a device for spreading the fibers in the fabric
  • Figure 4 includes Figures 4a to 4d which are histograms illustrating the volume rate fibers for a given fabric, obtained by three different embodiments,
  • Figure 5 includes Figures 5a to 5c which illustrate Example 1, Figure 5a showing a warp and weft fabric made according to a standard weaving, Figure 5b a fabric made according to a weaving with unwound weft and Figure 5c a fabric obtained by weaving with an unwound weft and vibration and - Figure 6 includes Figures 6a and 6b and illustrates the Fabric n ° 4 of Example n ° 1, Figure 6a representing the Fabric n ° 4 after weaving with unwound weft and Figure 6b, Fabric # 4 after weaving with unwound weft and vibration.
  • the elements common to the different figures will be designated by the same references.
  • FIG. 1 is a diagram illustrating the continuous production of warp and weft fabrics according to the invention. As shown in Figure 1, a device
  • the weaving loom 4 allows the weaving loom 4 to be supplied with warp threads 2. It is designed to unwind warp threads without providing them with torsion, and by giving them appropriate tension. Thus, the warp threads 2 do not have a twist greater than the original twist of the threads.
  • warp threads are used which do not initially have a twist. These threads are commonly called twist / twist yarns or "twist" threads.
  • twist / twist yarns or "twist" threads.
  • the advantage of not making the wires twist will be explained in more detail with regard to the weft wires.
  • the warp threads 2 are brought (arrow FI) to the weaving loom 4. This is shown diagrammatically and comprises frames 5, a comb 6 and a lance 7.
  • the lance 7 introduces, in the warp threads, a weft thread 8 which comes (arrow F2) from a weft reel 9 unwound by a device 10, here called weft unwinder.
  • This device 10 is designed not to twist or twist the weft threads.
  • the weft threads 8, inserted by the lance 7, do not have a twist greater than the original twist of the threads.
  • the coil of wire 9 is unwound using two pressure rollers 13 which drive the wire by means of a direct current motor 14.
  • the wire 8 forms a loop whose position is transmitted to the using a puppet 15 connected to a potentiometer 16 acting on an amplifier 17.
  • This amplifier controls the motor 14 so that the length differences absorbed by the loom are compensated for by accelerating or slowing down the motor 14.
  • the fabric 18 obtained after passing through the loom 4 is routed (arrow F3) in the rest of the manufacturing operations, after having passed over a trio 19.
  • the fabric 18 is then optionally led into a spreading device 20. As will be seen later on reading " the examples, this spreading device is not always necessary.
  • This additional step makes it possible to obtain a volume rate of fibers which is substantially constant in the fabric and suitable for the use of fabric to obtain composite materials having satisfactory mechanical properties.
  • FIG. 3 illustrates a non-limiting example of embodiment of such a spreading device 20. It essentially comprises a vibrator 21 on which is mounted a rotating roller 22, intended to come into contact with the fabric 18.
  • roller 22 One can envisage other means than the roller 22. This can be replaced by another device coming into contact with the fabric 18.
  • the vibrator 21 is a pneumatic vibrator whose frequency is 100 Hertz, under a pressure of 6 x 10 & Pa. It is understood that by passing over the fabric 18, the device 20 makes it possible to spread the wires in the fabric, by means of the vibrations communicated by the roller 22.
  • the term “spreading the threads in the fabric” is understood to mean increasing a dimension of the cross section of the threads in the plane of the fabric and correspondingly decreasing a dimension of the cross section threads in a direction perpendicular to the plane of the fabric.
  • the device 20 is only effective if the warp and weft threads do not have a twist greater than the original twist of the threads before weaving. Indeed, if the weft threads, or even only some of them, were twisted, gaps would still be present at the twists, even after passing under the device 20. This remark must be qualified for the unidirectional fabrics which will be described later.
  • the spreading step is not necessarily carried out as soon as the fabric is obtained, that is to say as soon as it leaves the loom, after any intermediate storage.
  • the fabric is generally not used immediately after its weaving. It can be stored for some time before n • a transformation takes place such as dusting, prepreg or laminating. It appeared advantageous to spread the fibers in the fabric just before the transformation to be carried out.
  • a spreading device can be provided before weaving, after weaving or before and after weaving.
  • the method according to the invention has been applied to all the threads of the fabric, both in warp and in weft. It is also possible to envisage applying this process to only part of the threads, in particular for obtaining unidirectional fabrics.
  • unidirectional fabric means a fabric comprising at least 80% by weight of warp or weft threads.
  • weight ratio of warp threads and weft threads will also be used to denote the warp / weft or weft / warp ratio, the most important ratio being retained.
  • a unidirectional warp fabric will be a fabric of which 80% by weight of the threads are warp threads while a unidirectional weft fabric will be a fabric of which 80% by weight of the threads are weft threads, these two fabrics having a ratio by weight of warp threads and weft threads greater than or equal to 80/20.
  • a unidirectional weft fabric The warp threads of such a fabric constitute in practice binding threads.
  • the warp threads can be any.
  • the device 1 for supplying the weaving loom with warp threads can be a classic device, possibly bringing a twist to the wires.
  • a device such as that referenced 10 is used for the weft yarns which does not bring any twist to the yarns.
  • the method according to the invention may be used only for part of the son when it is desired to carry out a unidirectional weave.
  • no weft thread has a twist greater than the original twist of the threads.
  • the width of the thread would be less than the original width of the threads before weaving and it would not be possible to obtain a fabric having a high volume content of fibers.
  • the spreading device 20 would not be effective. It has been observed that, insofar as the fabric has at least 80% of the threads by weight in the weft direction, which are woven according to the method according to the invention, the fabric has a volume ratio of satisfactory fibers even if the warp threads are woven in a conventional manner.
  • the proportion of warp threads cannot however be greater than 20%.
  • the method according to the invention must be applied to all of the threads of the fabric, in accordance with the initial description.
  • the device making it possible to feed the loom with weft threads can be a conventional device and a device such as that referenced 1 is used for the warp threads which does not bring any twist to the threads.
  • balanced fabric denotes a fabric comprising substantially as many warp threads as weft.
  • the weave of the fabrics is a taffeta.
  • the title of the sons is a taffeta.
  • Fabric # l High resistance carbon wires TORAYCA FT 300B 3K 40B (commercial reference from the supplier Toray).
  • weft yarns are unwound by "unwound” weft unwinders, which do not twist the yarn.
  • Fabric n ° 1 is intended to serve as a reference for other fabrics, for " the three weaving processes envisaged. It is woven only according to standard weaving (S). It is recognized that such a fabric has a volume content of fibers which is entirely compatible with use in the manufacture of a composite material having 21
  • the volume content of fibers in Fabric No. 1 is 38%.
  • FIG. 4 also illustrates the preceding results in the form of histograms, FIGS. 4a to 4d for each of the tissues 2 to 4 .
  • a fabric based on 6K yarns (Fabric n ° 2) has a constant volume density of fibers in the fabric and which is greater than or equal to that of a fabric based on 3K yarns (Fabric n ° 1) obtained by standard weaving.
  • Fabrics 3, 4 and 5 are fabrics made from 12K yarns. When obtained by traditional weaving, the volume content of fibers in the fabric is much lower than that of a fabric made from yarns. 3K (Fabric n ⁇ l) obtained by this same weaving. Such fabrics would therefore not be suitable for producing composite materials having acceptable mechanical properties.
  • These fabrics based on 12 K wires can therefore be used to obtain composite materials having satisfactory mechanical properties.
  • the width of the warp and weft threads is, over the entire length of the threads, greater than or equal to the original width of the threads before weaving (Fabric n ° 3: 6; 7 or 8 mm and 6 mm; Fabric n ° 4: 5.2; 7 or 8 mm and 5 mm; Fabric n ° 5: 7 mm and 3.2 mm).
  • FIG. 5 illustrates the three types of weaving that are used (S, SD, SDV).
  • FIG. 5b A weaving with an unwound weft leads to fabrics having a smaller thickness and therefore to a higher volume content of fibers.
  • Figure 4 also shows this increase in the fiber volume rate.
  • weaving with an unwound weft and vibration Figure 5c makes it possible to obtain a fabric whose thickness is even thinner and the volume rate of fibers is greater. This is shown by the results appearing in Figure 4.
  • the two fabrics compared are balanced fabrics, made from aramid yarns: KEVLAR 49 1270 dtex T968 for Fabric n ° l and KEVLAR 49 2400 dtex T968 for Fabric n ° 2, (Dupont de Nemours commercial reference) and have a surface mass of 175 g / m 2 .
  • the density of the wires is 1.45 g / cm 3 and the wires have a twist / m turn.
  • Fabric # 1:. Thread count 127 tex
  • Thread count 240 tex.
  • Initial wire width on spool 1.8 mm
  • Example 1 three weaving methods are used: standard weaving (S), weaving with unrolled weft (SD) and weaving with unrolled weft and vibration (SDV).
  • S standard weaving
  • SD weaving with unrolled weft
  • SDV weaving with unrolled weft and vibration
  • Fabric no. 1 serves as a reference for Fabric no. 2, for the three weaving processes used.
  • Fabric n ° 1 is woven only according to standard weaving (S).
  • This fabric has a volume content of fibers that is entirely compatible with use in the manufacture of a composite material having satisfactory mechanical properties.
  • the volume rate of fibers in Fabric 1 is 42%.
  • the method according to the invention makes it possible to obtain a fabric produced from yarns with a higher titer than Fabric n ° 1, while having a constant volume density of fibers in the fabric and greater than that Fabric # 1.
  • the width of the warp and weft threads is, over the entire length of the threads, greater than or equal to the original width of the threads before weaving.
  • FIG. 5 also illustrates this exemplary embodiment of the invention.
  • EXAMPLE 3 The two fabrics of this example are unidirectional fabrics produced on the basis of glass strands and have a surface mass of 120 g / m 2 .
  • the chosen armor is taffeta.
  • the weight distribution of the threads is as follows: 80% in weft and 20% in warp, for the two fabrics. These therefore practically have the form of a unidirectional ply, the warp threads playing the role of binding threads. In this example, it is more particularly a unidirectional weft fabric.
  • Warp material Yarns with the same characteristics as the warp yarns of Fabric No. l
  • the method according to the invention is applied here only to the weft threads, the warp threads being woven in a conventional manner.
  • Fabric no. 1 serves as a reference for Fabric no. 2, for the three weaving processes used.
  • Fabric n ° l is woven only according to standard weaving (S). It has a volume content of fibers compatible with use in the manufacture of a composite material having satisfactory mechanical properties.
  • the volume content of fibers in fabric No. 1 is 26%.
  • the process according to the invention therefore makes it possible to obtain a fabric produced from yarns which are, in a proportion of 80% by weight corresponding to the weft yarns, of higher titer than the weft yarns of Fabric No. 1, this fabric having a volume content of fibers constant in the fabric and greater than that of Fabric No. 1.
  • the width of the weft threads is greater than or equal to the original width of the threads before weaving.
  • Such properties are obtained in particular by the fact that the warp and / or weft threads are used so that the twist which they present in the fabric is not greater than their original twist.
  • the absence of additional twisting allows it to be fully effective and to lead to maximum spreading of the fibers in order to obtain a closed fabric.
EP94900890A 1992-11-30 1993-11-30 Gewebe mit kette und schuss auf basis von technischen multifilamenten garnen hauptsächlich ohne torsion und verfahren zur herstellung Expired - Lifetime EP0670921B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9214399A FR2698640B1 (fr) 1992-11-30 1992-11-30 Tissu chaîne et trame à base de fils techniques multifilaments à prédominance sans torsion et procédé d'obtention.
FR9214399 1992-11-30
PCT/FR1993/001175 WO1994012708A1 (fr) 1992-11-30 1993-11-30 Tissu chaine et trame a base de fils techniques multifilaments a predominance sans torsion et procede d'obtention

Publications (2)

Publication Number Publication Date
EP0670921A1 true EP0670921A1 (de) 1995-09-13
EP0670921B1 EP0670921B1 (de) 2001-04-04

Family

ID=9436053

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94900890A Expired - Lifetime EP0670921B1 (de) 1992-11-30 1993-11-30 Gewebe mit kette und schuss auf basis von technischen multifilamenten garnen hauptsächlich ohne torsion und verfahren zur herstellung

Country Status (10)

Country Link
US (2) US5732748A (de)
EP (1) EP0670921B1 (de)
JP (2) JP3954090B2 (de)
AT (1) ATE200312T1 (de)
AU (1) AU673872B2 (de)
CA (1) CA2150468C (de)
DE (1) DE69330100T2 (de)
ES (1) ES2155469T3 (de)
FR (1) FR2698640B1 (de)
WO (1) WO1994012708A1 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000040791A1 (fr) * 1999-01-06 2000-07-13 Kabushiki Kaisha O.B.S. Feuille de fils ouverts, tissu de fils ouverts et materiau composite renforce par des fibres
WO2011086266A1 (fr) 2009-12-22 2011-07-21 Hexcel Reinforcements Nouveaux materiaux intermediaires realises par entrecroisement avec entrelacement de fils voiles
WO2014135806A1 (fr) 2013-03-08 2014-09-12 Hexcel Reinforcements Procede et machine d'etalement d'une nappe textile de type tissu

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT400954B (de) * 1993-12-17 1996-05-28 Fischer Adv Components Gmbh Gewebe, prepreg aus diesem gewebe, leichtbauteil aus derartigen prepregs, überkopf-gepäckablage für flugzeuge
CN1046974C (zh) * 1995-03-08 1999-12-01 东丽株式会社 增强织物及其制造方法和制造装置
GB9806853D0 (en) * 1998-03-30 1998-05-27 Hexcel Corp Fiber laminates
US6523578B1 (en) 1998-10-20 2003-02-25 The Boeing Company Composite prepreg material form with improved resistance to core crush and porosity
GB9913119D0 (en) * 1999-06-05 1999-08-04 Carr Reinforcing Limited Textile structures based upon multifilament fibres and method for producing same
CN100540290C (zh) * 2003-01-10 2009-09-16 赫世普罗股份有限公司 增强纤维板和其制造方法以及使用该板的装饰板
ATE488631T1 (de) * 2003-09-05 2010-12-15 Toray Industries Verfahren und vorrichtung zur herstellung eines verstärkungsgewebes
FR2868440B1 (fr) * 2004-03-31 2006-08-18 Porcher Tissages Sarl Procede d'obtention d'un tissu technique et tissu de carbone susceptible d'etre obtenu par ce procede
JP5425380B2 (ja) * 2007-08-10 2014-02-26 株式会社有沢製作所 織物の開繊方法
US20090107575A1 (en) * 2007-10-29 2009-04-30 Yucheng Ma Mixed Fabric Woven by Untwisted Yarns and Twisted Yarns
FR2952052B1 (fr) * 2009-10-30 2012-06-01 Snecma Propulsion Solide Piece en materiau composite thermostructural de faible epaisseur et procede de fabrication.
CN103114363B (zh) * 2013-02-28 2014-07-09 江苏大生集团有限公司 超舒适抑菌生物质纤维混纺针织面料
CN103361920A (zh) * 2013-07-08 2013-10-23 吴江龙纺纺织有限公司 一种蔬果种植用防蚊虫网布的制作工艺
DE102013109477A1 (de) * 2013-08-30 2015-03-05 Hermann Hogg Verfahren zur Herstellung von Fingernagel-Tips
CN104452034B (zh) * 2014-11-20 2017-07-18 江苏金太阳纺织科技股份有限公司 高支彩色竹节纱床品面料及其制备方法
EP3280835B1 (de) 2015-04-08 2021-01-06 Shaw Industries Group, Inc. Vorrichtung und verfahren zur garntexturierung
CN104894724B (zh) * 2015-04-23 2017-07-28 江苏金太阳纺织科技股份有限公司 一种高支高密防羽面料及其加工方法
CN105568481A (zh) * 2015-12-15 2016-05-11 桐乡市亿源鞋业有限公司 高弹性高韧性面料
JP2019167668A (ja) * 2019-07-02 2019-10-03 日東紡績株式会社 ガラスロービングクロス及びガラス繊維強化樹脂シート
US20230193541A1 (en) * 2021-12-20 2023-06-22 Raytheon Technologies Corporation Gradient tow ribbonizing for chemical vapor infiltration ceramic matrix composites
US20230191656A1 (en) * 2021-12-20 2023-06-22 Raytheon Technologies Corporation Ribbonized tows for optimized improved composite performance
US20230193525A1 (en) * 2021-12-20 2023-06-22 Raytheon Technologies Corporation Fabric structure control using ultrasonic probe

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE538079A (de) *
FR990557A (fr) * 1948-07-13 1951-09-24 Procédé de tissage de fils ou fibres de verre ou matières analogues
US2810405A (en) * 1955-04-29 1957-10-22 Huau Marguerite Material in glass fibre and new industrial product resulting therefrom
US2887132A (en) * 1957-12-09 1959-05-19 Joseph P Manning Unidirectional woven fabric
US3669158A (en) * 1969-03-10 1972-06-13 Technology Uk Continuous carbon fiber tapes
US3919028A (en) * 1972-09-13 1975-11-11 Kaiser Glass Fiber Corp Method of making unidirectional webbing material
US3914494A (en) * 1973-04-03 1975-10-21 Celanese Corp Pervious low density carbon fiber reinforced composite articles
US3955256A (en) * 1973-04-03 1976-05-11 Celanese Corporation Process for the production of a carbon tape
US3908808A (en) * 1973-09-17 1975-09-30 Nakajima All Co Ltd Ultrasonic calendering of paper webs
CA998233A (en) * 1974-04-26 1976-10-12 Bay Mills Limited Substantially closed fabric made by compressive redistribution of the filaments of at least some yarns of an open mesh fabric
JPS5530974A (en) * 1978-08-29 1980-03-05 Toray Industries Fabric construction for composite material
FR2478693A1 (fr) * 1980-03-20 1981-09-25 Hexcel Corp Procede pour reduire la porosite d'un tissu, notamment de fibres de carbone, pre-impregne
JPS63152637A (ja) * 1986-12-16 1988-06-25 Toray Ind Inc 樹脂の補強用プリフオ−ム材
JPS6440663A (en) * 1987-08-03 1989-02-10 Mitsubishi Rayon Co Method for correcting mesh size of fabric
JPH05125639A (ja) * 1991-10-31 1993-05-21 Nitto Boseki Co Ltd 繊維強化熱可塑性樹脂成形材料用織物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9412708A1 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000040791A1 (fr) * 1999-01-06 2000-07-13 Kabushiki Kaisha O.B.S. Feuille de fils ouverts, tissu de fils ouverts et materiau composite renforce par des fibres
WO2011086266A1 (fr) 2009-12-22 2011-07-21 Hexcel Reinforcements Nouveaux materiaux intermediaires realises par entrecroisement avec entrelacement de fils voiles
WO2014135806A1 (fr) 2013-03-08 2014-09-12 Hexcel Reinforcements Procede et machine d'etalement d'une nappe textile de type tissu
WO2014135805A1 (fr) 2013-03-08 2014-09-12 Hexcel Reinforcements Tissu notamment de fils de carbone présentant une faible variabilité d'épaisseur combinée à une gamme spécifique de masse surfacique
US9637850B2 (en) 2013-03-08 2017-05-02 Hexcel Reinforcements Method and machine for spreading a fabric-type textile sheet

Also Published As

Publication number Publication date
JP2007169873A (ja) 2007-07-05
WO1994012708A1 (fr) 1994-06-09
AU5567494A (en) 1994-06-22
JPH08503747A (ja) 1996-04-23
FR2698640B1 (fr) 1995-02-17
AU673872B2 (en) 1996-11-28
JP3954090B2 (ja) 2007-08-08
US5732748A (en) 1998-03-31
ES2155469T3 (es) 2001-05-16
DE69330100T2 (de) 2001-11-15
CA2150468C (fr) 2008-07-22
FR2698640A1 (fr) 1994-06-03
EP0670921B1 (de) 2001-04-04
US5939338A (en) 1999-08-17
ATE200312T1 (de) 2001-04-15
DE69330100D1 (de) 2001-05-10
CA2150468A1 (fr) 1994-06-09

Similar Documents

Publication Publication Date Title
EP0670921B1 (de) Gewebe mit kette und schuss auf basis von technischen multifilamenten garnen hauptsächlich ohne torsion und verfahren zur herstellung
EP0270411B1 (de) Textilstruktur zum Herstellen von geschichteten Verbundgegenstanden durch Einspritzgiessen
CA1327504C (fr) Structure textile pour la realisation de stratifies a hautes proprietes mecaniques
EP2516138B1 (de) Neue verbundmaterialien mit ineinander greifenden bändern
FR2954210A1 (fr) Procede de fabrication d'une piece en materiau composite obtenue par depot de couches de fibres renforcantes plaquees sur un mandrin
EP0402443B1 (de) Als verstärkung zur herstellung von verbundwerkstoffen verwendbare textilstrukturen und fäden für solche strukturen
CA2894488A1 (fr) Piece structurale en materiau composite renforcee
FR2643656A1 (fr) Structure textile en forme de spirale, procede d'obtention et machine a tisser correspondante
EP2964825A1 (de) Verfahren und vorrichtung zum ausbreiten eines gewebeartigen textilstoffs
EP2657385B1 (de) Textile Verstärkungseinlage, und Verfahren zu deren Hestellung
FR3003266A1 (fr) Ruban d'enroulement pour cables pour le carter moteur d'une automobile.
FR2558488A1 (fr) Procede pour filer des fibres coupees
CA2258334C (fr) Procede de depose simultanee par bobinage sur un support de plusieurs meches de fibres pre-impregnees, dispositif pour sa mise en oeuvre et structures en materiau composite ainsi obtenues
FR2518979A1 (fr) Procede de fabrication d'articles enroules de filaments
FR2668176A1 (fr) Structure filiforme guipee comprenant des fibres metalliques.
FR2477584A1 (fr) Cables metalliques ameliores pour le renforcement des articles en caoutchouc, procede et dispositifs de fabrication
EP1244834A1 (de) Verfahren und vorrichtung zur herstellung einer mehrachsigen faserbahn
EP0227570A2 (de) Gegenstand aus Verbundwerkstoff auf der Basis einer vorzugsweise gewebten oder gestrickten, spiralig gewickelten oder aus konzentrischen Schichten aufgebauten Faden- oder Faserverstärkung
EP0271418A1 (de) Verfahren zur Herstellung von Kerngarnen auf einer Ringspinnmaschine, wobei das Kerngarn aus langen Fasern besteht, die von einer äusseren Hülle umgeben sind
FR3090461A1 (fr) Corde composite
EP4304847A1 (de) Neue verstärkungsmaterialien auf der basis von s- und z-verdrillten garnen zur herstellung von verbundteilen, verfahren und verwendung
FR3075689A1 (fr) Procede de fabrication d'un semi-produit pour une piece de vehicule automobile
FR2854172A1 (fr) Armature textile utilisable pour la realisation de renforts employes notamment pour la fabrication d'articles moules
WO2020128368A1 (fr) Outil de repartition pour module de guipage
FR2582588A1 (fr) Nappes de renfort avec corps de fibres non tissees; enveloppes de pneumatiques comportant ces nappes; procedes pour obtenir ces nappes

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19950504

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES GB GR IT LI NL SE

17Q First examination report despatched

Effective date: 19951106

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: HEXCEL FABRICS

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE ES GB GR IT LI NL SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20010404

REF Corresponds to:

Ref document number: 200312

Country of ref document: AT

Date of ref document: 20010415

Kind code of ref document: T

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: KIRKER & CIE SA

Ref country code: CH

Ref legal event code: EP

ITF It: translation for a ep patent filed

Owner name: STUDIO TORTA S.R.L.

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20010404

REF Corresponds to:

Ref document number: 69330100

Country of ref document: DE

Date of ref document: 20010510

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2155469

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PLBQ Unpublished change to opponent data

Free format text: ORIGINAL CODE: EPIDOS OPPO

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

26 Opposition filed

Opponent name: TENAX FIBERS GMBH & CO.KG

Effective date: 20011222

NLR1 Nl: opposition has been filed with the epo

Opponent name: TENAX FIBERS GMBH & CO.KG

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

PLCK Communication despatched that opposition was rejected

Free format text: ORIGINAL CODE: EPIDOSNREJ1

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

APAA Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOS REFN

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PLBN Opposition rejected

Free format text: ORIGINAL CODE: 0009273

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: OPPOSITION REJECTED

REG Reference to a national code

Ref country code: CH

Ref legal event code: PFA

Owner name: HEXCEL REINFORCEMENTS

Free format text: HEXCEL FABRICS#3, AVENUE CONDORCET#69100 VILLEURBANNE (FR) -TRANSFER TO- HEXCEL REINFORCEMENTS#3, AVENUE CONDORCET#69100 VILLEURBANNE (FR)

NLT1 Nl: modifications of names registered in virtue of documents presented to the patent office pursuant to art. 16 a, paragraph 1

Owner name: HEXCEL REINFORCEMENTS

27O Opposition rejected

Effective date: 20050930

NLR2 Nl: decision of opposition

Effective date: 20050930

REG Reference to a national code

Ref country code: ES

Ref legal event code: PC2A

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20121128

Year of fee payment: 20

Ref country code: CH

Payment date: 20121113

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20121212

Year of fee payment: 20

Ref country code: SE

Payment date: 20121113

Year of fee payment: 20

Ref country code: IT

Payment date: 20121117

Year of fee payment: 20

Ref country code: BE

Payment date: 20121113

Year of fee payment: 20

Ref country code: GB

Payment date: 20121128

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20121029

Year of fee payment: 20

Ref country code: NL

Payment date: 20121110

Year of fee payment: 20

BE20 Be: patent expired

Owner name: S.A. *HEXCEL REINFORCEMENTS

Effective date: 20131130

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 69330100

Country of ref document: DE

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 69330100

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: V4

Effective date: 20131130

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20131129

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK07

Ref document number: 200312

Country of ref document: AT

Kind code of ref document: T

Effective date: 20131130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20131129

Ref country code: DE

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20131203

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20140306

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20131201