EP0662045B2 - Vorrichtung und verfahren zur herstellung einseitiger wellpappe - Google Patents

Vorrichtung und verfahren zur herstellung einseitiger wellpappe Download PDF

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Publication number
EP0662045B2
EP0662045B2 EP94922934A EP94922934A EP0662045B2 EP 0662045 B2 EP0662045 B2 EP 0662045B2 EP 94922934 A EP94922934 A EP 94922934A EP 94922934 A EP94922934 A EP 94922934A EP 0662045 B2 EP0662045 B2 EP 0662045B2
Authority
EP
European Patent Office
Prior art keywords
cylinder
sheet
order
fluted
speed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94922934A
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English (en)
French (fr)
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EP0662045B1 (de
EP0662045A1 (de
Inventor
Jean-Jacques Barny
Jean-Marie Paultes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Otor SA
Original Assignee
Otor SA
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Filing date
Publication date
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Application filed by Otor SA filed Critical Otor SA
Publication of EP0662045A1 publication Critical patent/EP0662045A1/de
Publication of EP0662045B1 publication Critical patent/EP0662045B1/de
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F1/00Mechanical deformation without removing material, e.g. in combination with laminating
    • B31F1/20Corrugating; Corrugating combined with laminating to other layers
    • B31F1/24Making webs in which the channel of each corrugation is transverse to the web feed
    • B31F1/26Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions
    • B31F1/28Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions combined with uniting the corrugated webs to flat webs ; Making double-faced corrugated cardboard
    • B31F1/2845Details, e.g. provisions for drying, moistening, pressing
    • B31F1/2854Means for keeping the sheet in contact with one of the corrugating rollers after corrugating, but before applying the facer sheet, e.g. by air pressure, suction or pressing fingers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F1/00Mechanical deformation without removing material, e.g. in combination with laminating
    • B31F1/20Corrugating; Corrugating combined with laminating to other layers
    • B31F1/24Making webs in which the channel of each corrugation is transverse to the web feed
    • B31F1/26Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions
    • B31F1/28Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions combined with uniting the corrugated webs to flat webs ; Making double-faced corrugated cardboard
    • B31F1/2845Details, e.g. provisions for drying, moistening, pressing
    • B31F1/285Heating or drying equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F1/00Mechanical deformation without removing material, e.g. in combination with laminating
    • B31F1/20Corrugating; Corrugating combined with laminating to other layers
    • B31F1/24Making webs in which the channel of each corrugation is transverse to the web feed
    • B31F1/26Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions
    • B31F1/28Making webs in which the channel of each corrugation is transverse to the web feed by interengaging toothed cylinders cylinder constructions combined with uniting the corrugated webs to flat webs ; Making double-faced corrugated cardboard
    • B31F1/2845Details, e.g. provisions for drying, moistening, pressing
    • B31F1/2877Pressing means for bringing facer sheet and corrugated webs into contact or keeping them in contact, e.g. rolls, belts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1007Running or continuous length work
    • Y10T156/1016Transverse corrugating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1025Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina to form undulated to corrugated sheet and securing to base with parts of shaped areas out of contact

Definitions

  • It also relates to a manufacturing process sheets of single-sided corrugated cardboard using in particular a machine of the above type.
  • the chain includes feeding means 3 and 4 respectively in flat sheet, cover, and in flat sheet intended to form the sheet grooved.
  • a preheater 6 for the cover sheet generally consisting of a steam-heated steel cylinder with small rollers called “bar feeders” which are used to vary the paper / cylinder contact area
  • a preconditioner 7 for the fluted sheet which in turn comprises, and in addition, a sheet humidification ramp which promotes the formation of grooves.
  • the chain 2 also includes means 8 of the single-sided cardboard obtained, consisting of by a system of belts in the upper part of the chain.
  • Figure 2 shows more specifically, in view cutting, the machine 1 single face of the chain of figure 1.
  • the machine 1 also includes a first cylinder 12, grooved, upper, stainless steel. he is hollow and arranged to be heated with steam from way known in itself.
  • the second cylinder is for example of the type known as "Air Drive”, manufactured by French company MARTIN.
  • the chamber includes 17 channels drilled on the entire length of the cylinder and communicates with the peripheral surface fluted by holes.
  • Machine 1 includes a third cylinder 18 lower, smooth surface, axis parallel to both first and for example of the same diameter.
  • This cylinder is steam heated in a similar fashion to both first and is arranged to compress the sheet of cover against the edges of the grooves of the corrugated sheet, in contact with the periphery of the cylinder central grooved, as we will see.
  • the machine 1 also includes means 19 for gluing the ridges of the grooves, known in themselves, comprising a laminating roller 20, a glue tank 21 and a glue roller 22.
  • the operating principle of the machine 1 is the next.
  • the sheet 23 is intended to form the sheet grooved.
  • the glue is for example based on starch.
  • the cover sheet 24 is inserted in the lower part and opposite the machine 1.
  • the adhesive joint is therefore obtained by the action combined with the high pressure and the temperature in a split second.
  • the training of the leaves is done by traction, the fluted sheet being driven by the meshing fluted cylinders 12 and 13, and the cover sheet being driven by clamping between the central cylinder 13 and the smooth cylinder 18.
  • EP-A-0 492 310 describes a machine corresponding to the preamble of claim 1, and using fragile, belted systems and exerting strong pressure.
  • the present invention aims to provide a machine and method for manufacturing corrugated cardboard single sided responding better than those previously known to the requirements of the practice, in particular in that that it practically eliminates cuts paper at resonant and / or high speeds speed i.e. for example greater than 300 m / min, and in that it makes it possible to obtain an excellent bonding, which produces a performance corrugated board improved at a low cost and easily enforce.
  • the present invention starts from a an entirely new idea, including significantly reduce the pressure, or even at the completely remove, between the grooved cylinder 12 and the cylinder 18 smooth on the contact surface between the leaves, contrary to what art taught previous, replacing the high pressure with a heater extended leaves against each other.
  • Control means and adjusting the speed of rotation of said fourth cylinder with respect to the speed of rotation of said second cylinder are provided.
  • the first determined value is between of the order of 30 ° and of the order of 80 °
  • the second determined value is between around 90 ° and around 200 °.
  • the invention also provides a method of manufacturing using a machine as described above, and more particularly a manufacturing process a sheet of single-sided corrugated cardboard, from a sheet of corrugated cardboard and a flat sheet of cardboard, called cover, by gluing one on the other according to claim 7.
  • the first determined value is between of the order of 30 ° and of the order of 80 °
  • the second determined value is between around 90 ° and around 200 °.
  • the machine according to the embodiment of the invention more particularly described here comprises on the one hand, a single-sided machine of the type described in reference to Figure 2, and secondly a fourth cylinder arranged as will be described below in reference to figure 4. To simplify, the same reference numbers are used when they designate the same items.
  • the machine according to the invention comprises a fourth cylinder 26 smooth, heating, axis 27, parallel to the axes previous cylinders and located above them, for example directly after the second cylinder on the path of the corrugated sheet.
  • This cylinder is steam heated so similar for example to reach a temperature cylinder skin between 160 ° C and 200 ° C.
  • Means (not shown) for adjusting the the speed of rotation of the cylinder 26, known in themselves, are provided.
  • the cylinder speed ratio 26 and the cardboard scroll is therefore adjustable to ensure the tension of the cover sheet which is rolled up and in contact with the smooth surface of the cylinder.
  • bonding is different from classic collage. Instead of making the joint glue instantly by combined action of heat and strong pressure, bonding is ensured essentially by heat, the pressure being reduced by importantly.
  • cylinder 26 has at least with respect to the plane tangent to the point of contact 29 with cylinder 13 part of its surface on the side of said cylinder 13.
  • the axis 27 of the cylinder 26 can also be located on the side of cylinder 13, relative to the vertical plane passing through the axis 31 of the smooth cylinder 18.
  • a small roller 32 smooth and full, known in itself, and suitable for being in contact with the sheet of corrugated cardboard, the corrugated side is for example provided.
  • the axis 35 of the cylinder 32 is located below the axis 27 of the cylinder 26.
  • Figure 5 shows a schematic view in section along V-V of cylinder 26.
  • It includes two cylindrical ends 37 and 38 mounted on bearings 39, and a cylindrical body 40, for example stainless steel or cast iron, fitted with a central recess 41 supplied with steam at 42 by the end 37.
  • a cylindrical body 40 for example stainless steel or cast iron
  • a motor with variable speed 44 allows you to vary the speed of rotation of the cylinder 26 in a manner known per se, depending on the desired tension for the cardboard corrugated.
  • a device according to the invention retains the qualities of resistance to humidity COBB of the cover paper, without alterations, contrary to what is observed with the devices of the prior art.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)
  • Laminated Bodies (AREA)
  • Making Paper Articles (AREA)
  • Paper (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Soil Working Implements (AREA)

Claims (11)

  1. Maschine (1) zum Herstellen einer Bahn (36) aus einseitig gewelltem Karton durch Aufkleben einer Riffelbahn (23) aus Karton auf eine ebene Deckbahn (24), mit
    zwei motorisch angetriebenen Heizzylindern, die einander paarweise tangieren und deren Achsen parallel verlaufen, nämlich einem ersten geriffelten Zylinder (12) zum Vorformen der Riffelbahn und einem zweiten geriffelten Mittelzylinder (13), der mit Mitteln zum Anlegen der Riffelbahn an seinen Umfang versehen ist,
    Mitteln zur Druckbeaufschlagung und zum Andrücken der ebenen Bahn an die Riffelung der Riffelbahn am Umfang des genannten zweiten Zylinders, wobei die genannten Mittel dazu vorgesehen sind, um die ebene Bahn mit der Riffelung der Riffelbahn am Umfang des zweiten Zylinders in Kontakt zu bringen und um die Riffelbahn an den zweiten Zylinder über einen Kreisbogen anzudrücken, der einem Mittelpunktswinkel alpha mit einem bestimmten ersten Wert entspricht, wobei die genannten Druckbeaufschlagungs- und Andrückmittel zwei glatte Zylinder aufweisen, nämlich einen motorisch angetriebenen dritten Heizzylinder, der dazu vorgesehen ist, mit der ebenen Bahn (24) in Kontakt zu stehen und im Betrieb an einer Kontaktlinie (25) die Riffelung des zweiten Zylinders (18) mit Druck zu beaufschlagen, und einem vierten Zylinder (26), wobei der genannte dritte und vierte Zylinder achsparallel zur Achse des ersten und zweiten Zylinders verlaufen,
    und mit Mitteln (19) zum Beleimen der genannten Riffelung vor der genannten Kontaktierung,
    dadurch gekennzeichnet, dass
    der Mittelpunktswinkel alpha einen bestimmten ersten Wert zwischen etwa 30° und etwa 80° aufweist,
    der vierte Zylinder (26) heizt und motorisch angetrieben wird, sich vollständig in einem Abstand e und stromabwärts des zweiten Zylinders (13) befindet und dazu vorgesehen ist, selbst mit der Rückseite der ebenen Bahn (24) über einen Kreisbogen in Kontakt zu stehen, der einem Mittelpunktswinkel beta mit einem bestimmten zweiten Wert entspricht, der zwischen etwa 90° und etwa 200° einnimmt,
    der dritte Zylinder (18) mit Mitteln zum Einstellen des genannten Drucks der ebenen Bahn an der genannten Kontaktlinie mit der Riffelung des zweiten Zylinders versehen ist, der im Betrieb unter einem bestimmten Schwellwert von 3 kg/cm liegt, und
    dass sie Mittel (44) zum Steuern und Einstellen der Drehzahl des genannten vierten Zylinders bezüglich der Drehzahl des genannten zweiten Zylinders enthält.
  2. Maschine nach Anspruch 1, dadurch gekennzeichnet, dass der Mittelpunktswinkel alpha bei etwa 60° liegt.
  3. Maschine nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass der bestimmte zweite Wert bei etwa 180° liegt.
  4. Maschine nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass der vierte Heizzylinder (26) den gleichen Durchmesser aufweist wie die drei ersten Heizzylinder.
  5. Maschine nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass sie ferner einen kleineren glatten Zylinder aufweist (32), der achsparallel zur Achse der genannten Heizzylinder verläuft, stromabwärts der genannten Zylinder in der Wegstrecke der Wellpappe und unterhalb der horizontalen Ebene (34) liegt, welche die obere Mantellinie des vierten Zylinders tangiert.
  6. Maschine nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass der vierte Zylinder Mittel (44) zum Einstellen der Drehzahl des genannten vierten Zylinders zwischen etwa 1,02 V und etwa 1,25 V enthält, wobei V die Bandgeschwindigkeit der gebildeten Wellpappe ist.
  7. Verfahren zum Herstellen einer Bahn (36) aus einseitig gewelltem Karton ausgehend von einer geriffelten Kartonbahn (23) und einer ebenen Kartonbahn (24), die sogenannte Deckbahn, durch Aufkleben aneinander, bei dem die Spitzen der zuvor beleimten Riffelung der gewellten Bahn in Kontakt mit der ebenen Bahn über einen ersten Bereich (28) gehalten werden, der durch einen ersten Flächenabschnitt eines geriffelten mittleren Heizzylinders (13), dem sogenannten zweiten Zylinder, über einen Bogen gebildet ist, der einem Mittelpunktswinkel mit einem bestimmten ersten Wert entspricht,
    dadurch gekennzeichnet, dass
    der Mittelpunktswinkel alpha einen bestimmten ersten Wert zwischen etwa 30° und etwa 80° aufweist,
    vor dem genannten ersten Abschnitt und nach Beleimen mittels eines heizenden und motorisch angetriebenen Anpresszylinders, dem sogenannten dritten Zylinder (18), der den genannten zweiten Zylinder tangiert, ein längenbezogener Druck auf den zweiten Zylinder (13) am Kontaktpunkt ausgeübt wird, dessen Wert kleiner als 3 kg/cm zwischen den Spitzen der Riffelung und der ebenen Bahn (29) ist, und
    nach und in Abstand von dem genannten ersten Abschnitt des zweiten Zylinders, die geriffelte Kartonbahn und die ebene Bahn über einen zweiten Bereich (30) in Kontakt gehalten werden, der durch einen zweiten Flächenabschnitt eines motorisch angetriebenen, drehbaren, glatten Heizzylinder (26), dem sogenannten vierten Zylinder, gebildet wird, der bezüglich des geriffelten Mittelzylinders (13) um die Wegstrecke der Wellpappe über einen Bogen nachgelagert ist, welcher einem Mittelpunktswinkel beta mit einem bestimmten zweiten Wert zwischen etwa 90° und etwa 200° entspricht,
    indem die Drehzahl des genannten vierten Zylinders gesteuert und bezüglich der Drehzahl des genannten zweiten Zylinders eingestellt wird.
  8. Verfahren nach Anspruch 7, dadurch gekennzeichnet, dass der bestimmte erste Wert etwa 60° einnimmt.
  9. Verfahren nach einem der Ansprüche 7 und 8, dadurch gekennzeichnet, dass der bestimmte zweite Wert etwa 180° einnimmt.
  10. Verfahren nach einem der Ansprüche 7 bis 9, dadurch gekennzeichnet, dass die Geschwindigkeit des vierten glatten Heizzylinders (26) auf eine Geschwindigkeit zwischen etwa 1,02 V und etwa 1,25 V eingestellt wird, wobei V die Bandgeschwindigkeit der gebildeten Wellpappe ist.
  11. Verfahren nach Anspruch 10, dadurch gekennzeichnet, dass die Geschwindigkeit des vierten glatten Heizzylinders (26) etwa 1,06 V ist.
EP94922934A 1993-07-20 1994-07-18 Vorrichtung und verfahren zur herstellung einseitiger wellpappe Expired - Lifetime EP0662045B2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9308909 1993-07-20
FR9308909A FR2708011B1 (fr) 1993-07-20 1993-07-20 Machine et procédé de fabrication d'une feuille de carton ondulé simple face.
PCT/FR1994/000896 WO1995003166A1 (fr) 1993-07-20 1994-07-18 Machine et procede de fabrication d'une feuille de carton ondule simple face

Publications (3)

Publication Number Publication Date
EP0662045A1 EP0662045A1 (de) 1995-07-12
EP0662045B1 EP0662045B1 (de) 1999-04-21
EP0662045B2 true EP0662045B2 (de) 2002-11-20

Family

ID=9449424

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94922934A Expired - Lifetime EP0662045B2 (de) 1993-07-20 1994-07-18 Vorrichtung und verfahren zur herstellung einseitiger wellpappe

Country Status (21)

Country Link
US (1) US5614048A (de)
EP (1) EP0662045B2 (de)
JP (1) JPH08501740A (de)
CN (1) CN1112781A (de)
AT (1) ATE179113T1 (de)
AU (1) AU690914B2 (de)
BR (1) BR9405547A (de)
CA (1) CA2144984A1 (de)
CZ (1) CZ101695A3 (de)
DE (2) DE69418015T3 (de)
DK (1) DK0662045T3 (de)
ES (1) ES2132418T5 (de)
FI (1) FI951229A0 (de)
FR (1) FR2708011B1 (de)
NO (1) NO951043L (de)
NZ (1) NZ278300A (de)
PL (1) PL175160B1 (de)
TR (1) TR28247A (de)
TW (1) TW290496B (de)
WO (1) WO1995003166A1 (de)
ZA (1) ZA945270B (de)

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FR2719521B1 (fr) * 1994-05-06 1996-07-19 Otor Sa Machine et procédé de fabrication d'une feuille de carton ondulé simple face par encollage sous traction.
DE19506779A1 (de) * 1995-02-27 1996-08-29 Bhs Corr Masch & Anlagenbau Verfahren und Vorrichtung zum Beheizen einer bewegten Bahn, insbesondere Wellpappenbahn
EP0739711B1 (de) * 1995-04-24 1998-12-23 PETERS MASCHINENFABRIK GmbH Glattpresse für eine Vorrichtung zur Herstellung von Wellepappe
EP0739710B1 (de) * 1995-04-24 1998-11-25 PETERS MASCHINENFABRIK GmbH Pressplatte für eine Vorrichtung zur Herstellung von Wellepappe
GB2303385A (en) * 1995-07-14 1997-02-19 Scm Container Mach Ltd Apparatus for producing corrugated paperboard
DE19603015A1 (de) * 1996-01-17 1997-07-24 Europa Carton Ag Andrückleiste
JPH09300493A (ja) * 1996-05-14 1997-11-25 Isowa Corp 片面段ボール製造装置
US5766410A (en) * 1996-09-10 1998-06-16 Wu; Shiung Kuang Corrugating machine with an elastic press plate
US6149751A (en) * 1996-11-01 2000-11-21 Marquip, Inc. Low pressure single facer
US6050316A (en) * 1997-04-18 2000-04-18 United Container Machinery, Inc. Single facer preheater
US6110095A (en) * 1997-04-18 2000-08-29 United Container Machinery Inc. Apparatus for heating corrugated paperboard
US6155320A (en) * 1997-04-24 2000-12-05 United Container Machinery, Inc. Method and apparatus for injecting steam at a single facer bonding nip
JP3517110B2 (ja) * 1998-04-03 2004-04-05 株式会社イソワ 片面段ボール製造方法および装置
IT1301887B1 (it) * 1998-07-30 2000-07-07 Ingg Terzaghi & De Castiglione Dispositivo per la produzione di cartone ondulato ad una sola facciapiana
US6921450B2 (en) * 2001-10-31 2005-07-26 Marquip, Llc Soft contact roll for a single facer
DE10312600A1 (de) * 2003-03-21 2004-10-07 Bhs Corrugated Maschinen- Und Anlagenbau Gmbh Wellpappe-Anlage sowie Verfahren zur Herstellung von Wellpappe-Bögen
CN114261147A (zh) * 2021-12-31 2022-04-01 长兴县泗安民丰彩印厂 一种无压痕瓦楞纸生产方法

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Also Published As

Publication number Publication date
TR28247A (tr) 1996-03-28
EP0662045B1 (de) 1999-04-21
DE9421377U1 (de) 1995-12-21
CZ101695A3 (en) 1995-12-13
US5614048A (en) 1997-03-25
PL175160B1 (pl) 1998-11-30
AU690914B2 (en) 1998-05-07
DE69418015D1 (de) 1999-05-27
DK0662045T3 (da) 1999-11-01
ZA945270B (en) 1995-08-08
DE69418015T2 (de) 1999-11-18
FR2708011B1 (fr) 1995-10-13
FI951229A (fi) 1995-03-16
DE69418015T3 (de) 2003-05-22
EP0662045A1 (de) 1995-07-12
NO951043L (no) 1995-05-22
ATE179113T1 (de) 1999-05-15
CA2144984A1 (fr) 1995-02-02
FR2708011A1 (fr) 1995-01-27
AU7266594A (en) 1995-02-20
ES2132418T3 (es) 1999-08-16
PL308126A1 (en) 1995-07-24
NO951043D0 (no) 1995-03-17
WO1995003166A1 (fr) 1995-02-02
JPH08501740A (ja) 1996-02-27
FI951229A0 (fi) 1995-03-16
BR9405547A (pt) 1999-09-08
TW290496B (de) 1996-11-11
CN1112781A (zh) 1995-11-29
ES2132418T5 (es) 2003-03-16
NZ278300A (en) 1996-05-28

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