EP0655749A2 - Composite comportant du papier et des polymères électroconducteurs et son procédé de fabrication - Google Patents
Composite comportant du papier et des polymères électroconducteurs et son procédé de fabrication Download PDFInfo
- Publication number
- EP0655749A2 EP0655749A2 EP95101495A EP95101495A EP0655749A2 EP 0655749 A2 EP0655749 A2 EP 0655749A2 EP 95101495 A EP95101495 A EP 95101495A EP 95101495 A EP95101495 A EP 95101495A EP 0655749 A2 EP0655749 A2 EP 0655749A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- paper
- composite
- group
- polymer
- conjugated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 68
- 239000002131 composite material Substances 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 33
- 239000002243 precursor Substances 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 125000001424 substituent group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000004958 1,4-naphthylene group Chemical group 0.000 claims description 2
- 150000002366 halogen compounds Chemical group 0.000 claims description 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 7
- 230000003647 oxidation Effects 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 239000000243 solution Substances 0.000 description 21
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 11
- -1 methoxy, ethoxy, propoxy Chemical group 0.000 description 11
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 10
- 230000005611 electricity Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 229910052697 platinum Inorganic materials 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 229910052737 gold Inorganic materials 0.000 description 6
- 239000010931 gold Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- 239000003822 epoxy resin Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 5
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 5
- 229920000647 polyepoxide Polymers 0.000 description 5
- ZZHIDJWUJRKHGX-UHFFFAOYSA-N 1,4-bis(chloromethyl)benzene Chemical compound ClCC1=CC=C(CCl)C=C1 ZZHIDJWUJRKHGX-UHFFFAOYSA-N 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000012300 argon atmosphere Substances 0.000 description 4
- GVXYYRZMASRTPS-UHFFFAOYSA-N dimethylsulfanium chloride Chemical compound [Cl-].C[SH+]C GVXYYRZMASRTPS-UHFFFAOYSA-N 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Substances OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 4
- 229920000767 polyaniline Polymers 0.000 description 4
- KBLZDCFTQSIIOH-UHFFFAOYSA-M tetrabutylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC KBLZDCFTQSIIOH-UHFFFAOYSA-M 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229930192474 thiophene Natural products 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- PXKGXXCANCSLDC-UHFFFAOYSA-N 1,4-bis(chloromethyl)-2,5-diethoxybenzene Chemical compound CCOC1=CC(CCl)=C(OCC)C=C1CCl PXKGXXCANCSLDC-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- VPUGDVKSAQVFFS-UHFFFAOYSA-N coronene Chemical compound C1=C(C2=C34)C=CC3=CC=C(C=C3)C4=C4C3=CC=C(C=C3)C4=C2C3=C1 VPUGDVKSAQVFFS-UHFFFAOYSA-N 0.000 description 2
- YDRSQRPHLBEPTP-UHFFFAOYSA-N cyclohexa-3,5-diene-1,2-diol Chemical class OC1C=CC=CC1O YDRSQRPHLBEPTP-UHFFFAOYSA-N 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000000502 dialysis Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000011174 green composite Substances 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- OJBWNBCXVFAMEX-UHFFFAOYSA-N 2,5-bis(chloromethyl)thiophene Chemical compound ClCC1=CC=C(CCl)S1 OJBWNBCXVFAMEX-UHFFFAOYSA-N 0.000 description 1
- PFHOSZAOXCYAGJ-UHFFFAOYSA-N 2-[(2-cyano-4-methoxy-4-methylpentan-2-yl)diazenyl]-4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)(C)OC PFHOSZAOXCYAGJ-UHFFFAOYSA-N 0.000 description 1
- VRVRGVPWCUEOGV-UHFFFAOYSA-N 2-aminothiophenol Chemical compound NC1=CC=CC=C1S VRVRGVPWCUEOGV-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical class C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- FENJKTQEFUPECW-UHFFFAOYSA-N 3-anilinopropanenitrile Chemical compound N#CCCNC1=CC=CC=C1 FENJKTQEFUPECW-UHFFFAOYSA-N 0.000 description 1
- JDQDSEVNMTYMOC-UHFFFAOYSA-N 3-methylbenzenesulfonic acid Chemical class CC1=CC=CC(S(O)(=O)=O)=C1 JDQDSEVNMTYMOC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- YUENFNPLGJCNRB-UHFFFAOYSA-N anthracen-1-amine Chemical compound C1=CC=C2C=C3C(N)=CC=CC3=CC2=C1 YUENFNPLGJCNRB-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- WPTMYRBAXYADTF-UHFFFAOYSA-N coronen-1-amine Chemical compound C1=C2C(N)=CC3=CC=C(C=C4)C5=C3C2=C2C3=C5C4=CC=C3C=CC2=C1 WPTMYRBAXYADTF-UHFFFAOYSA-N 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 230000005291 magnetic effect Effects 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002984 plastic foam Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- MABNMNVCOAICNO-UHFFFAOYSA-N selenophene Chemical compound C=1C=C[se]C=1 MABNMNVCOAICNO-UHFFFAOYSA-N 0.000 description 1
- 238000003797 solvolysis reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/52—Separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0421—Methods of deposition of the material involving vapour deposition
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/045—Electrochemical coating; Electrochemical impregnation
- H01M4/0452—Electrochemical coating; Electrochemical impregnation from solutions
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/0464—Electro organic synthesis
- H01M4/0466—Electrochemical polymerisation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/137—Electrodes based on electro-active polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a composite comprising a paper and an electroconducting polymer having a grown conjugated system at the main chain thereof and a process for producing the same. More specifically, the invention relates to a composite comprising a paper and a conjugated electroconducting polymer having improved fabrication and stability without impairing inherent characteristics of the conjugated electroconducting polymer and a process for producing the same.
- An electroconducting polymer having a highly grown conjugated system at the main chain thereof causes insulator-metal transition by doping with a dopant which is an electron donor or an electron acceptor, whereby the conductivity thereof can be desirably controlled. Furthermore, with the transition, optical and magnetic properties of the compound are largely changed. Accordingly, such an electroconducting polymer has been widely noticed as a functional material capable of making various functional applications by utilizing the above-described properties.
- conjugated electroconducting polymer when a conjugated compound is subjected to electropolymerization, a conjugated electroconducting polymer may be obtained in a film form.
- conjugated electroconducting polymers keeping a film form cannot be obtained, and these compounds have a fault that they form a thin layer or deposit as a powder on an electrode.
- a conjugated electroconducting polymer when a precursor polymer of a conjugated electroconducting polymer is cast and heat treated, a conjugated electroconducting polymer may be obtained in a film form. However, in almost all cases, it was impossible to obtain a film having sufficient flexibility. Furthermore, it has been attempted to form composites with general-purpose polymer films by utilizing electropolymerization or chemical polymerization, but there is a limitation on obtainable composites.
- the present inventors have discovered a composite composed of a paper and a conjugated electroconducting polymer having improved fabrication and stability without impairing inherent characteristics of the conjugated electroconducting polymer and also a process of producing the aforesaid composite
- an object of the present invention is to provide a composite comprising a paper and a conjugated electroconducting polymer having improved fabrication and stability without impairing inherent characteristics of the conjugated electroconducting polymer.
- the invention provides a composite comprising a paper and a conjugated electroconducting polymer, the conjugated electroconducting polymer existing between or in close contact with fibers of the paper.
- the invention provides a process for producing a composite comprising a paper and a conjugated electroconducting polymer, the conjugated electroconducting polymer existing between or in close contact with fibers of the paper, which comprises subjecting a conjugated compound to electropolymerization or oxidation polymerization in the presence of a paper.
- the invention provides a process for producing a functional composite, which comprises impregnating a paper with a solution of a precursor polymer of a conjugated electroconducting polymer and heat treating the paper to form a conjugated electroconducting polymer between or on surfaces of fibers of the paper.
- the paper for use in this invention there is no particular restriction if the paper can sufficiently endure under the circumstances of the polymerization of the conjugated compound, or the circumstances of being impregnated with a solution of the soluble precursor polymer and of the heat treatment, and using the composite.
- uncoated papers for printing original papers for thermal recording papers, original papers for copying papers, packaging papers, electrical insulating papers, and synthetic papers such as synthetic fiber papers and plastic foam papers can be used.
- cloths, nonwoven fabrics, etc. can be used.
- conjugated compound for obtaining the conjugated electroconducting polymer for use in this invention for example, the following compounds can be used.
- Benzene and substituted benzenes having no more than 4 substituent groups can be used. Specific examples include aniline, phenol, thiophenol, toluene, anisole, aminothiophenol, o- and m-toluenesulfonic acids, and substituted compounds thereof.
- substituent group for the substituted compounds examples include a straight chain alkyl group (such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, hexadecyl), a cyclic alkyl group (such as cyclohexyl, cyclopentyl), a branched alkyl group (such as isopropyl, t-butyl), an alkoxy group (such as methoxy, ethoxy, propoxy), an alkynyl group, an amino group, an aryl group, an allyl group, a carboxyl group, a nitro group, a halogen atom, a cyano group, and a sulfonic acid group.
- a straight chain alkyl group such as methyl, ethyl, propyl, butyl
- a part of the hydrogens of the alkyl group may be substituted by an alkoxy group, an alkenyl group, an amino group, an aryl group, an allyl group, a carboxyl group, a nitro group, a halogen atom, a cyano group, a sulfonic acid group, etc.
- naphthalene fluorene, anthracene, phenanthrene, pyrene, coronene, and substituted compounds thereof.
- substituted compounds include ⁇ - and ⁇ -aminonaphthalenes, aminoanthracene, aminocoronene, alkylfluorenes, and substituted compounds thereof.
- substituted compounds may have the substituent group as described in (1) above.
- pyrrole furan, thiophene, selenophene, carbazole, pyridine, oxazole, thiazole, and substituted compounds thereof.
- substituted compounds include 3-alkylpyrroles, N-alkylpyrroles, 3,4-dialkylpyrroles, 3-alkylfurans, 3,4-dialkylfurans, 3-alkylthiophenes, 3,4-dialkylthiophenes, 3-alkylselenophenes, 3,4-dialkylselenophenes, and substituted compounds thereof.
- substituted compounds may have the substituent group as described in (1) above.
- the precursor polymer of conjugated electroconducting polymer for use in the present invention for example, the following compounds can be used.
- R1 represents a lower alkyl group or a lower alkoxy group
- R2 and R3 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, an aryl group, or a halogen atom
- n represents an integer of 8 or more.
- the compounds shown by formula (I) can be obtained by radical polymerization of a 5,6-dihydroxycyclohexa-1,3-diene derivative represented by formula (II): wherein R1, R2, and R3 have the same meanings as described above.
- R6 represents a lower alkyl group;
- X represents a halogen atom or a halogen compound (such as BF4);
- Ar represents a p-phenylene group, a 1,4-naphthylene group, a 2,5-thienylene group, or a 2,5-furylene group, each of which groups may have a substituent group; and n represents an integer of 8 or more.
- Examples of the substituent group for Ar of the compounds shown by formulae (III) and (IV) include an alkyl group (such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, dodecyl, docosyl), an alkoxy group (such as methoxy, ethoxy, propoxy), an alkenyl group, an amino group, an aryl group, a halogen atom, and a cyano group.
- an alkyl group such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, dodecyl, docosyl
- an alkoxy group such as methoxy, ethoxy, propoxy
- an alkenyl group such as methoxy, ethoxy, propoxy
- the sulfonium salt of the polymer shown by formula (III) can be obtained by adding, for example, an aqueous solution of a basic hydroxide to an aqueous solution of a compound represented by formula (V): wherein R4, R5, Ar, and X have the same meanings as described above, and polymerizing the mixture.
- polymer derivative which is substituted by an alkoxy group as shown by formula (IV)
- polymer derivative which is substituted by an alkoxy group can be obtained by solvolysis of the compound shown by formula (III) with an alcohol shown by R6(OH), wherein R6 has the same meaning as described above.
- solvent for the precursor polymer shown by formulae (I), (III), or (IV) water, alcohol solvents (such as methanol, ethanol), ether solvents (such as tetrahydrofuran), amide solvents (such as N,N-dimethylformamide), other polar solvents, and mixtures thereof can be used.
- alcohol solvents such as methanol, ethanol
- ether solvents such as tetrahydrofuran
- amide solvents such as N,N-dimethylformamide
- other polar solvents and mixtures thereof.
- the composite of this invention can be produced by electropolymerization or oxidation polymerization of the conjugated compound in the presence of a paper.
- the electropolymerization is carried out by bring a paper in close contact with an electrode or attaching a metal to a paper by vapor deposition, plating, etc. to form a working electrode, placing the paper in a solution of the conjugated compound, and undergoing electropolymerization under a condition of constant potential, constant current, constant voltage, etc.
- a solvent for dissolving the conjugated compound water, an organic solvent, or a mixture thereof can be used.
- a noble metal electrode such as those made of gold, platinum, etc.
- a nickel electrode a chromium electrode, a carbon electrode, and a glass electrode having vapor deposited thereon indium(II) oxide, stannic oxide, etc.
- the invention is not limited to these kinds of electrode materials and forming method of working electrodes and counter electrodes.
- oxidation polymerization method a method for impregnating a paper with a solution of the conjugated compound and bringing the paper into contact with an oxidizing agent, a method for impregnating a paper with an oxidizing agent and bringing the paper into contact with the conjugated compound.
- oxidizing agent for example, ammonium persulfate, hydrogen peroxide, potassium permanganate, and ferric chloride can be used.
- the composite of this invention can be produced by impregnating a paper with a solution of the conjugated polymer, followed by drying.
- a method of impregnation by an immersion method using an immersion apparatus For impregnating a paper with a solution of the precursor polymer, a method of impregnation by an immersion method using an immersion apparatus, a method of impregnation by an on-machine coating using a wet type paper making machine, or a method of coating by an off-machine using a coating apparatus may be used.
- the heat treatment after impregnation is carried out in an inert gas such as a nitrogen gas or an argon gas, or under reduced pressure.
- the heating temperature is preferably from 100°C to 500°C, and the heating time-is usually from 10 minutes to 24 hours.
- the conjugated electroconducting polymer formed by the above-described heat treatment is poly-p-phenylene and derivatives thereof from the precursor polymer shown by formula (I) and polyarlylenevinylenes and derivatives thereof from the precursor polymer shown by formula (III) or (IV), respectively.
- the composite comprising a paper and a conjugated electroconducting polymer of this invention can be applied for use of wide ranges such as, for example, electrodes for primary and secondary batteries, packing papers having an antistatic function, electromagnetic shielding materials, etc., by properly selecting the form and shape of paper as a substrate. Furthermore, even a conventional conjugated electroconducting polymer which is obtained only as a powder or a conventional conjugated electroconducting high molecular weight compound which scarcely grows on an electrode can be used in the present invention while utilizing the characteristics thereof.
- An electrical insulating paper having a thickness of 30 ⁇ m was vapor deposited with gold, and after connecting a leading wire thereto, the vapor deposited portion was fixedly covered with an epoxy resin to electrically insulate the portion.
- An electrode thus prepared was immersed in an electrolyte having an aniline concentration of 0.1 mole/liter and a hydrochloric acid concentration of 0.2 mole/liter, and electropolymerization was carried out by using a platinum plate as a counter electrode at a constant voltage of 1.5 volts and at a quantity of electricity of 3 coulombs.
- polyaniline deposited on the substantially entire surface of the paper.
- the composite was used as a positive electrode as it was and the charging and discharging characteristics thereof were measured in a propylene carbonate solution of 0.1 mole/liter of lithium perchlorate, the coulomb efficiency was 98%, which showed excellent electric conducting property.
- a paper for printing having a thickness of 60 ⁇ m was vapor deposited with gold, and after connecting a leading wire thereto, the vapor deposited portion was fixedly covered with an epoxy resin to electrically insulate the portion.
- An electrode thus prepared was immersed in an electrolyte having an aniline concentration of 0.1 mole/liter and a hydrochloric acid concentration of 0.2 mole/liter, and electropolymerization was carried out by using a platinum plate as a counter electrode at a constant voltage of 1.5 volts and at a quantity of electricity of 3 coulombs.
- the coulomb efficiency of the composite was 96% as in Example 1, which showed excellent electric conducting property.
- An electrical insulating paper having a thickness of 30 ⁇ m was immersed in an electrolyte having an aniline concentration of 0.1 mole/liter and a hydrochloric acid concentration of 0.2 mole/liter, and after sandwiching the paper between two platinum plates, electropolymerization was carried out at a constant voltage of 1.5 volts and at a quantity of electricity of 3 coulombs.
- polyaniline deposited on the substantially entire surface of the paper to provide a green composite in a doped state.
- the coulomb efficiency of the composite was 95% as in Example 1, and the electric conductivity thereof was 0.1 S/cm in a dry state.
- An electrical insulating paper having a thickness of 30 ⁇ m was vapor deposited with gold, and after connecting thereto a leading wire, the vapor deposited portion was fixedly covered with a epoxy resin to electrically insulate the portion.
- An electrode thus prepared was immersed in an electrolyte having a 3-anilinopropionitrile concentration of 0.1 mole/liter and a hydrochloric acid concentration of 0.2 mole/liter, and electropolymerization was carried out by using a platinum plate as a counter electrode at a constant voltage of 1.5 volts and at a quantity of electricity of 1 coulomb.
- the coulomb efficiency of the composite was 95% as in Example 1, which showed excellent electric conducting property.
- An electrical insulating paper having a thickness of 30 ⁇ m was vapor deposited with gold, and after connecting thereto a leading wire, the vapor deposited portion was fixedly covered with an epoxy resin to electrically insulate the portion.
- An electrode thus prepared was immersed in a propylene carbonate solution containing 2 mmole of thiophene and 1 mmole of tetraethylammoniumtetrafluoroborate, and electropolymerization was carried out in an argon atmosphere by using a nesa glass as a counter electrode at a constant voltage of 10 volts and at a quantity of electricity of 1 coulomb.
- a blue paper having the polymer grown in the inside thereof was obtained.
- the coulomb efficiency of the composite was almost 95% as in Example 1.
- the composite was red in an undoped state, and the electric conductivity was 10 ⁇ 11 S/cm. Furthermore, doping and undoping were repeatedly applied, and according thereto, the composite could show blue and red.
- a nesa glass was brought into close contact with an electrical insulating paper having a thickness of 30 ⁇ m.
- the assembly was used as an electrode and immersed in a propylene carbonate solution containing 2 mmole of thiophene and 1 mmole of tetraethylammonium tetrafluoroborate, and electropolymerization was carried out in an argon atmosphere by using a platinum plate as a counter electrode at a constant voltage of 12 volts and at a quantity of electricity of 1 coulomb.
- a blue paper having the polymer grown in the inside thereof was obtained.
- the coulomb efficiency of the composite was 95% as in Example 1. In this case, the composite was red in an undoped state, and the electric conductivity was 10 ⁇ 11S/cm. Furthermore, doping and undoping were repeatedly applied, and according thereto, the composite could show blue and red.
- An electrical insulating paper having a thickness of 30 ⁇ m was vapor deposited with gold, and after connecting thereto a leading wire, the vapor deposited portion was fixedly covered with an epoxy resin to electrically insulate the portion.
- An electrode thus prepared was immersed in a propylene carbonate solution containing 2 mmole of pyrrole and 1 mmole of tetraethylammoniumtetrafluoroborate, and electropolymerization was carried out in an argon atmosphere by using a platinum plate as a counter electrode at a constant voltage of 1.5 volts and at a quantity of electricity of 1 coulomb. In this case, the polymer grew in the inside of the paper.
- the coulomb efficiency of the composite was 95% as in example 1, which showed excellent electric conducting property.
- a nesa glass was brought into close contact with an electrical insulating paper having a thickness of 30 ⁇ m.
- the assembly was used as an electrode and immersed in an aqueous solution containing 2 mmole of pyrrole and 3 mmole of p-toluenesulfonic acid, and electropolymerization was carried out in an argon atmosphere by using a nesa glass as a counter electrode at a constant voltage of 2.0 volts and at a quantity of electricity of 1 coulomb.
- the polymer grew in the inside of the paper.
- the coulomb efficiency of the composite was 95% as in Example 1, which showed excellent electric conducting property.
- the compound was dissolved in toluene, and a paper for printing having a thickness of 60 ⁇ m was immersed in the solution, sufficiently impregnated with a precursor polymer shown by formula (I), and then heat treated at 200°C for 3 hours under reduced pressure to provide a pale yellow functional composite.
- the composite could be doped. When the composite was exposed to an iodine vapor, it changed to black, and the electric conductivity was 0.5 S/cm. Also, the tensile strength of the composite was 130 MPa, which was stronger than the paper. Furthermore, the composite could be electrochemically doped, and by doping the composite with AsF6 ⁇ in a propylene carbonate solution of 0.1 M of LiAsF6, the composite changed to blue.
- a battery was formed by combining with lithium and a propylene carbonate solution of 0.1 M of LiAsF6.
- the voltage at the open end was 4.1 volts, and an energy density was 75 wh/kg.
- the composite obtained could be doped, and when the composite was exposed to an iodine vapor, it changed to black.
- the electric conductivity of the composite was 10 ⁇ 5 S/cm (measured by a 4-terminal method).
- the tensile strength of the composite was 120 MPa, which was stronger than the paper.
- the composite could be electrochemically doped, and when the composite was doped with a perchloric acid ion in an acetonitrile solution of 0.1 M of tetra-n-butylammonium perchlorate, it changed to blue.
- a battery was formed by combining with lithium and a propylene carbonate solution of 0.1 M of lithium perchlorate.
- the voltage at the open end was 3.6 volts, and the energy density was 55 wh/kg.
- the tensile strength of the composite was 110 MPa, which was stronger than the paper.
- the composite could be electrochemically doped, and by doping the composite with a perchloric acid ion in an acetonitrile solution of 0.1 M of tetra-n-butylammonium perchlorate, it changed to blue.
- a battery was formed by combining with lithium and a propylene carbonate solution of 0.1 M of lithium perchlorate.
- the voltage at the open end was 3.5 volts, and the energy density was 60 wh/kg.
- the tensile strength of the composite was 110 MPa, which was stronger than the paper.
- the composite could be electrochemically doped, and by doping the composite with a perchloric acid ion in an acetonitrile solution of 0.1 M of tetra-n-butylammonium perchlorate, it changed to blue.
- a battery was formed by combining with lithium and a propylene carbonate solution of 0.1 M of lithium perchlorate.
- the voltage at the open end was 3.5 volts, and the energy density was 65 wh/kg.
- the composite could be electrochemically doped, and by doping the composite with a perchloric acid ion in an acetonitrile solution of 0.1 M of tetra-n-butylammonium perchlorate, it changed to blue.
- a battery was formed by combining with lithium and a propylene carbonate solution of 0.1 M of lithium perchlorate.
- the voltage at the open end was 3.0 volts, and the energy density was 50 wh/kg.
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Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
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JP11877890 | 1990-05-10 | ||
JP118778/90 | 1990-05-10 | ||
JP2118778A JPH0670319B2 (ja) | 1990-05-10 | 1990-05-10 | 複合体の製造方法 |
JP3657091 | 1991-02-07 | ||
JP3657091A JPH0663196B2 (ja) | 1991-02-07 | 1991-02-07 | 機能性複合体の製造方法 |
JP36570/91 | 1991-02-07 | ||
EP91107482A EP0456211B1 (fr) | 1990-05-10 | 1991-05-08 | Procédé de fabriquer un composite comportant du papier et des polymères électroconducteurs |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
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EP91107482A Division EP0456211B1 (fr) | 1990-05-10 | 1991-05-08 | Procédé de fabriquer un composite comportant du papier et des polymères électroconducteurs |
EP91107482.1 Division | 1991-05-08 |
Publications (3)
Publication Number | Publication Date |
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EP0655749A2 true EP0655749A2 (fr) | 1995-05-31 |
EP0655749A3 EP0655749A3 (fr) | 1996-03-27 |
EP0655749B1 EP0655749B1 (fr) | 2000-01-26 |
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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EP95101495A Expired - Lifetime EP0655749B1 (fr) | 1990-05-10 | 1991-05-08 | Composite comportant du papier et des polymères électroconducteurs et son procédé de fabrication |
EP91107482A Expired - Lifetime EP0456211B1 (fr) | 1990-05-10 | 1991-05-08 | Procédé de fabriquer un composite comportant du papier et des polymères électroconducteurs |
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EP91107482A Expired - Lifetime EP0456211B1 (fr) | 1990-05-10 | 1991-05-08 | Procédé de fabriquer un composite comportant du papier et des polymères électroconducteurs |
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EP (2) | EP0655749B1 (fr) |
DE (2) | DE69117337T2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2001038084A1 (fr) * | 1999-11-23 | 2001-05-31 | Fact Future Advanced Composites & Technology Gmbh | Matiere plastique composite electroconductrice, composant de ladite matiere et son procede de fabrication |
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FR2072068A1 (en) * | 1969-12-27 | 1971-09-24 | Tomoegawa Paper Mfg Co Ltd | Sulphonated polystyrene in electrostatic recording papers |
US3708289A (en) * | 1969-01-29 | 1973-01-02 | Agfa Gevaert Nv | Electroconductive layers |
US4528118A (en) * | 1983-04-28 | 1985-07-09 | Agency Of Industrial Science And Technology | Highly electroconductive conjugated polymer composition and process for producing the same |
JPS6436012A (en) * | 1987-07-31 | 1989-02-07 | Asahi Glass Co Ltd | Solid electrolytic capacitor |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0206133B1 (fr) * | 1985-06-12 | 1991-07-31 | BASF Aktiengesellschaft | Utilisation de polypyrrole pur déposer de cuivre métallique sur des matériaux non-électriquement conductibles |
IT1202322B (it) * | 1985-06-21 | 1989-02-02 | Univ Parma | Procedimento chimico per conferire proprieta' conduttrici antistatiche e antifiamma a materiali porosi |
US4981718A (en) * | 1988-06-27 | 1991-01-01 | Milliken Research Corporation | Method for making electrically conductive textile materials |
JPH1036012A (ja) * | 1996-07-17 | 1998-02-10 | Sando Iron Works Co Ltd | 糸巻き用ボビン |
-
1991
- 1991-05-08 EP EP95101495A patent/EP0655749B1/fr not_active Expired - Lifetime
- 1991-05-08 DE DE69117337T patent/DE69117337T2/de not_active Expired - Fee Related
- 1991-05-08 EP EP91107482A patent/EP0456211B1/fr not_active Expired - Lifetime
- 1991-05-08 DE DE69131945T patent/DE69131945T2/de not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3708289A (en) * | 1969-01-29 | 1973-01-02 | Agfa Gevaert Nv | Electroconductive layers |
FR2072068A1 (en) * | 1969-12-27 | 1971-09-24 | Tomoegawa Paper Mfg Co Ltd | Sulphonated polystyrene in electrostatic recording papers |
US4528118A (en) * | 1983-04-28 | 1985-07-09 | Agency Of Industrial Science And Technology | Highly electroconductive conjugated polymer composition and process for producing the same |
JPS6436012A (en) * | 1987-07-31 | 1989-02-07 | Asahi Glass Co Ltd | Solid electrolytic capacitor |
Non-Patent Citations (2)
Title |
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JOURNAL OF ELECTRONIC MATERIALS, vol. 13, no. 1, 1984 USA, pages 211-230, R. B. BJORKLUND ET AL. 'Some properties of polypyrrole-paper composites' * |
PATENT ABSTRACTS OF JAPAN vol. 13 no. 226 (E-763) ,25 May 1989 & JP-A-01 036012 (ASAHI GLASS CO LTD) 7 February 1989, * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001038084A1 (fr) * | 1999-11-23 | 2001-05-31 | Fact Future Advanced Composites & Technology Gmbh | Matiere plastique composite electroconductrice, composant de ladite matiere et son procede de fabrication |
Also Published As
Publication number | Publication date |
---|---|
EP0456211A3 (en) | 1992-02-19 |
DE69131945D1 (de) | 2000-03-02 |
DE69131945T2 (de) | 2000-06-15 |
EP0456211B1 (fr) | 1996-02-28 |
DE69117337T2 (de) | 1996-08-29 |
EP0655749A3 (fr) | 1996-03-27 |
DE69117337D1 (de) | 1996-04-04 |
EP0655749B1 (fr) | 2000-01-26 |
EP0456211A2 (fr) | 1991-11-13 |
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