EP0636068B1 - Schaumstoffgriff - Google Patents

Schaumstoffgriff Download PDF

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Publication number
EP0636068B1
EP0636068B1 EP93905052A EP93905052A EP0636068B1 EP 0636068 B1 EP0636068 B1 EP 0636068B1 EP 93905052 A EP93905052 A EP 93905052A EP 93905052 A EP93905052 A EP 93905052A EP 0636068 B1 EP0636068 B1 EP 0636068B1
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EP
European Patent Office
Prior art keywords
foam
article
filler
latex
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93905052A
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English (en)
French (fr)
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EP0636068A4 (de
EP0636068A1 (de
Inventor
Mingchic M. Tseng
Nan Jae Lin
Michael J. Kwiecien
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gillette Co LLC
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Gillette Co LLC
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Publication date
Application filed by Gillette Co LLC filed Critical Gillette Co LLC
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Publication of EP0636068A4 publication Critical patent/EP0636068A4/de
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Publication of EP0636068B1 publication Critical patent/EP0636068B1/de
Anticipated expiration legal-status Critical
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K23/00—Holders or connectors for writing implements; Means for protecting the writing-points
    • B43K23/004—Holders specially adapted for assisting handicapped or disabled persons to write

Definitions

  • This invention relates to foam grips.
  • finger manipulated articles such as writing instruments
  • devices designed to provide a comfortable gripping area, as disclosed in, e.g., U.S. Patent No. 4,932,800.
  • Conventional finger gripping devices typically provide a sleeve of resilient compressible material, extending about or covering a portion of the gripping area. This compressible material is intended to deform on application of gripping pressure, and at least partially conform to the shape of the fingers during manipulation of the article. After removal of gripping pressure, the compressible material returns to its original shape.
  • U.S Patent US-A-4 474 276 which discloses a sealing composition for preventing or inhibiting leaks
  • German Patent DE-A-1 511 325 which discloses the use of a sleeve on a writing instrument
  • U.S. Patent US-A-4 158 087 which discloses polyurethane foam compositions
  • U.S. Patent US-A-4 725 627 which discloses a hand-squeezable toy with dimensional memory
  • Japanese Patent J-A-56 081 345 which discloses a plastic foam with uniform and fine open cells
  • U.S. Patent US-A-4 098 506 a removable hand grip for use on a tennis racket and the like
  • U.S. Patent US-A-4 932 800 which discloses a compressible finger-gripping device for finger-manipulated articles
  • British Patent GB-A-1 093 173 which discloses flexible polyurethane foams.
  • the invention features a finger manipulated article having a handle with a gripping surface including a foam having a recovery rate of less than 10 cm per minute, preferably less than 5 cm per minute, more preferably less than 3 cm per minute.
  • the invention features a finger manipulated article having a handle with a gripping surface including a foam having a spring rate of between 250 and 20,000 grams per cm, preferably between 500 and 16,000 grams per cm.
  • the invention features a finger manipulated article having a handle with a gripping surface including a foam having a percent peak force of less than 95%, preferably of less than 85%.
  • the invention features a finger manipulated article having a handle with a gripping surface including a polyurethane foam that was made from a mixture including a latex or a filler, or both.
  • the mixture also includes a polyurethane foam precursor, which can be, e.g., a foamable polyurethane prepolymer or the combination of a polyisocyanate and polyol that when mixed together react to provide a polyurethane foam.
  • the invention features a method of manufacturing a finger manipulated article having a foam gripping surface.
  • the method includes mixing the chemical precursor (e.g., polyol and isocyanate, or polyurethane prepolymer) used to form the foam, and a latex or a filler, or both, to induce foaming; molding the foam to a desired shape; and applying the foam to the gripping surface of the article.
  • the mixing, molding, and applying steps may occur simultaneously, for example, by conventional insert molding.
  • the foam preferably extends circumferential around the gripping surface of the article.
  • the foam can be disposed on a portion of the surface in the form of a discontinuous surface (e.g., strips, dots), or can be disposed within, e.g., a hollow razor handle that has openings in its surface through which the foam extends. In the latter alternative, the fingers of the user will contact the foam extending through the holes.
  • the foam alternatively can be the major component of the handle of the finger-manipulated device.
  • Finger-manipulated article means an article having a handle that can be easily maneuvered by the fingers of a user's hand. Typically, the handle of such an article will have a maximum diameter of less than 3.5 cm. Examples of finger manipulated articles include writing instruments like pens and pencils; razors; and toothbrushes.
  • “Foam”, as used herein, is a cellular polymer consisting of two phases, a fluid (liquid or gas) and a solid.
  • the fluid phase in a cellular polymer is distributed in voids or pockets called cells. These cells can be interconnected to form an open-cell foam, or the cells can be discrete and independent of other cells to form a closed cell foam.
  • the foams of the invention have sufficient rigidity that they can be used in a thin layer on a handle without the underlying handle causing discomfort for the user. Further, the foam has slow recovery, such that it is easily deformed by the user, does not exert significant force against the user's fingers, and returns slowly to its original shape when compressive force is removed. These properties provide comfort to the user of the article, and reduces user fatigue, particularly on writing instruments.
  • Another aspect of the invention is the preferred foams themselves, which can be used in other applications (e.g., on hand grips for tennis rackets).
  • the figure is a perspective view of a pen having a preferred gripping surface.
  • the writing end of pen 10 has a cylindrical body 12 that includes a foam gripping surface 14 extending around the circumference of the instrument in the finger gripping area.
  • the foam layer is less than 1.5 cm thick (more preferably 0.05-0.5 cm thick).
  • the preferred foam is a polyurethane. Some of the significant properties of the foam are spring rate, recovery rate, and percent peak force. These properties are measured as described subsequently, in the Examples.
  • the preferred foam may be any cured polyurethane prepolymer having a spring rate of from 250 to 20,000 grams/cm, a recovery rate of less than 5 cm per minute, and a percent peak force of less than 95%.
  • Suitable polyurethane foams include those prepared from compositions having two components: a foamable, curable polyurethane prepolymer, and an aqueous phase containing a latex and a surfactant.
  • One of the two phases also includes a filler.
  • Either phase can also include a conventional catalyst (or other reaction rate modifier) to either speed up or slow down the reaction.
  • the preferred foamable polyurethane prepolymers are polyisocyanate capped polyoxyethylene polyols, for example the TREPOL® prepolymers described in U.S. Pat. No. 4,828,542, which is owned by Twin Rivers Engineering of Boothbay, Maine and is hereby incorporated by reference.
  • Other preferred polymers are sold by W.R. Grace & Co. and include HYPOL® FHP 2000 and Hydrogel®, which are derived from toluene diisocyanate, and the FHP 4000 series, which are derived from methylene diisocyanate.
  • Preferred latexes include styrene-butadienes, polystyrenes, nitriles, acrylics, polyvinyl acetates, and polyvinyl chlorides.
  • Acrylic latexes generally are produced as copolymer of methyl or ethyl methacrylate and an other monomer like styrene and vinyl acetate.
  • the preferred latexes are stable aqueous dispersion of a polymeric substance having a particle size in the range of about 500 ⁇ to 50,000 ⁇ (0.05 ⁇ m to 5 ⁇ m).
  • Particularly preferred latexes are those having low resilience properties, e.g.
  • the latex provides the composition with reduced resiliency.
  • the starting mixture used to produce the foam should include between 15% and 80% of the latex by weight, where the latex includes 30% to 60% solids by weight.
  • any inert filler may be used.
  • Preferred fillers include barium sulfate, calcium carbonate, diatomaceous earth, carbon black, silica, clay, TiO 2 , fibers, and other inorganic compounds.
  • the filler helps provide the foam with good mechanical properties, including rigidity, density, and other viscoelastic properties.
  • the final foam includes up to 30% of filler by weight. Too little filler in the composition may provide a foam that is not rigid enough, resulting in discomfort to the user because the fingers may feel the body of the pen through the grip. Too much filler results in a foam that may be too viscous to process. Sufficient filler is added to the composition to provide a composition density of from 0.32 to 1.5 g/cm 3 .
  • the amounts of the polyurethane prepolymer (and thus the polyurethane resin in the cured foam), latex and filler can be varied in order to provide a desired balance of properties.
  • the properties of the composition will also be affected by the specific polyurethane prepolymer, latex, and filler selected.
  • the percentage of open cells and the degree of openness of cells in a flexible foam are related to resiliency.
  • the surfactant can be e.g., Pluronic-62, Brij 72, and DC 190.
  • Other suitable surfactants are described in U.S. Pat. No. 4,158,087, which is hereby incorporated by reference.
  • the surfactants help to control the cell size and surface properties of the foam. They also make the latex more compatible with the resin during mixing.
  • composition may also comprise other conventional additives, e.g., colorants, catalysts, and foaming agents.
  • additives e.g., colorants, catalysts, and foaming agents.
  • the spring rate of the grip is measured on a standard Instron (e.g., Model 1122) compression tester.
  • a standard Instron e.g., Model 1122
  • the procedure involves fixedly positioning the grip in alignment with a probe which consists of a cylindrical aluminum rod having a radius of 0.8 cm; the end of the rod has a curvature with a tip radius of 0.6 cm and a chamber radius of 0.2 cm.
  • the probe is arranged for reciprocal movement through a vertical distance after the bottom surface of the probe contacts the grip.
  • the probe is moved downward at 0.13 cm/min to a distance corresponding to approximately 70% of the thickness of the grip before returning to its original position.
  • the force of compression versus distance of compression is recorded on an X-Y graph.
  • the spring rate value corresponds to the slope of the force/compression distance curve at a compression distance of 0.025 cm.
  • Peak force is the maximum force of compression resulting from the spring rate measurement.
  • the instron probe is held at the point of maximum grip compression (for the spring rate measurement) for sixty seconds.
  • the force at this time divided by the peak force, expressed as a percentage, is the percent peak force.
  • the recovery rate is measured concurrently with the spring rate measurement.
  • the probe is held at the point of maximum grip compression for sixty seconds, and is then lifted instantly to a position which is below the original probe-grip contact position by approximately 20% of the thickness of the foam.
  • the time for the grip to recover to reach the probe is recorded by the Instron.
  • the recovery rate is defined as the time for the grip to recover to reach the probe divided by the grip recovery distance.
  • a foam gripping surface may also be utilized on other finger manipulated articles, besides pens and pencils, such as razors (typically having an elongate handle with a cutting edge at one end), toothbrushes (typically having an elongate handle with an array of bristles disposed at one end), and other similar personal care items.
  • the surfactant like the filler, can be included in either the prepolymer or aqueous phase.
  • the polyurethane foam precursor is a foamable polyurethane prepolymer
  • the foam may be produced from the reaction of a polyol (polyester-type or polyether-type) with an isocyanate (such as TDI (toluene diisocyanate), MDI (methylene bis (4-phenyl isocyanate), or H-MDI (dicyclohexylmethane-4,4'-diisocyanate)).
  • TDI toluene diisocyanate
  • MDI methylene bis (4-phenyl isocyanate
  • H-MDI dicyclohexylmethane-4,4'-diisocyanate

Landscapes

  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Golf Clubs (AREA)
  • Gloves (AREA)
  • Laminated Bodies (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

Claims (14)

  1. Fingermanipulierter Artikel (10) mit einem Griff, der sich mit den Fingern leicht manövrieren läßt, welcher Griff ein Hauptstück (12) aufweist und eine Greifoberfläche, umfassend eine Schaumstoffschicht auf einer äußeren Oberfläche des Hauptstückes (12), welcher Schaumstoff dadurch gekennzeichnet ist, daß er eine Dichte von 0,32 ... 1,5 g/cm3 hat und mit den Fingern des Benutzers des Artikels deformierbar ist.
  2. Artikel nach Anspruch 1, der ein Schreibinstrument, ein Rasierapparat oder eine Zahnbürste ist.
  3. Artikel nach Anspruch 1 oder 2, bei welchem der Schaumstoff ein oder mehrere der folgenden Merkmale hat:
    (a) eine Rückstellgeschwindigkeit von weniger als 5 cm pro Minute und bevorzugt weniger als 3 cm pro Minute;
    (b) er umfaßt ein Polyurethanharz;
    (c) er wird aus einer Mischung erzeugt, umfassend ein verschäumbares Polyurethanharz und einen Latex, wobei der Latex ausgewählt wird aus der Gruppe, bestehend aus Styrol/Butadienen, Polystyrolen, Nitrilen, Acrylharzen, Polyvinylacetaten und Polyvinylchloriden;
    (d) ferner aufweisend einen Füllstoff, welcher Füllstoff ausgewählt wird aus der Gruppe, bestehend aus Kieselgur, Ruß, Siliciumdioxid, Fasern und anorganischen Verbindungen;
    (e) eine mittlere Dicke von weniger als 1,5 cm;
    (f) eine Federkonstante zwischen 250 und 20.000 gf/cm; sowie
    (g) eine relative Kompressionskraft von weniger als 95 %.
  4. Artikel nach Anspruch 1 oder 2, bei welchem der Schaumstoff eine relative Kompressionskraft von weniger als 95 %.
  5. Artikel nach Anspruch 4, welcher Artikel ein Schreibinstrument ist und bei welchem der Schaumstoff ein oder mehrere der folgenden Merkmale hat:
    (a) eine Rückstellgeschwindigkeit von weniger als 5 cm pro Minute;
    (b) er wird aus einer Mischung erzeugt, umfassend ein verschäumbares Polyurethanharz und einen Latex;
    (c) ferner aufweisend einen Füllstoff sowie
    (d) eine Federkonstante zwischen 250 und 20.000 g/cm.
  6. Fingermanipulierter Artikel nach Anspruch 1 oder 2, bei welchem der Schaumstoff eine Federkonstante zwischen 250 und 20.000 gf/cm hat.
  7. Artikel nach Anspruch 6, wobei der Artikel ein Schreibinstrument ist und der Schaumstoff ein oder mehrere der folgenden Merkmale hat:
    (a) eine Rückstellgeschwindigkeit von weniger als 10 cm pro Minute;
    (b) eine relative Kompressionskraft von weniger als 95 %,
    (c) er wird aus einem verschäumbarem Polyurethanharz erzeugt,
    (d) er wird aus einer Mischung erzeugt, umfassend ein verschäumbares Polyurethanharz und einen Latex, oder
    (e) ferner umfassend einen Füllstoff.
  8. Fingermanipulierter Artikel nach Anspruch 1 oder 2, bei welchem der Schaumstoff erzeugt wird aus einer Mischung, umfassend ein Polyurethanharz und einen Latex.
  9. Artikel nach Anspruch 8 mit einem oder mehreren der folgenden Merkmale:
    (a) der Latex wird ausgewählt aus der Gruppe, bestehend aus Styrol/Butadienen, Polystyrolen, Nitrilen, Acrylharzen, Polyvinylacetaten und Polyvinylchloriden;
    (b) der Schaumstoff umfaßt ferner einen Füllstoff;
    (c) der Artikel ist ein Schreibinstrument; sowie
    (d) der Schaumstoff hat eine Dicke von Weniger als 1,5 cm.
  10. Fingermanipulierter Artikel nach Anspruch 1 oder 2, bei welchem der Schaumstoff einen Füllstoff einschließt.
  11. Artikel nach Anspruch 10, bei welchem der Füllstoff aus Kieselgur, Ruß, Siliciumdioxid, Fasern und/oder anorganischen Verbindungen besteht.
  12. Verfahren zum Herstellen eines fingermanipulierten Artikels nach Anspruch 1, umfassend:
    (a) Mischen eines Polyurethan-Schaumstoffprekursors, eines Latex oder eines Füllstoffes oder beider, um eine Schaumbildung herbeizuführen, wobei der entstandene Schaumstoff eine Dichte von 0,32 ... 1,5 g/cm3 hat;
    (b) Formgeben des Schaumstoffes zu einer angestrebten Gestalt;
    (c) Aufbringen des geformten Schaumstoffes auf das Hauptstück des Artikels.
  13. Verfahren nach Anspruch 12, bei welchem Verfahren:
    (a) ein Latex gemischt wird mit dem Polyurethan-Schaumstoffprekursor;
    (b) der Latex ausgewählt wird aus der Gruppe, bestehend aus Styrol/Butadienen, Polystyrolen, Nitrilen, Acrylharzen, Polyvinylaceteaten und Polyvinylchloriden;
    (c) der Füllstoff mit dem Polyurethan-Schaumstoffprekursor gemischt wird;
    (d) der Füllstoff ausgewählt wird aus der Gruppe, bestehend aus Kieselgur, Ruß, Siliciumdioxid, Fasern und/oder anorganischen Verbindungen;
    (e) der Prekursor ein Polyol und ein Isocyanat umfaßt;
    (g) der Artikel ein Instrument zum Schreiben ist;
    (h) alle drei Schritte gleichzeitig ausgeführt werden, oder
    (i) diese Schritte mit Hilfe der Insert-Technik ausgeführt werden
  14. Verfahren zum Herstellen des Schaumstoffes nach Anspruch 1, umfassend das Mischen eines Latex, eines Füllstoffes und eines Polyurethan-Schaumstoffprekursors, wobei das Mischen die Schaumbildung zur Schaffung des Schaumstoffes bewirkt.
EP93905052A 1992-02-14 1993-02-12 Schaumstoffgriff Expired - Lifetime EP0636068B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US83612192A 1992-02-14 1992-02-14
US836121 1992-02-14
PCT/US1993/001316 WO1993015917A1 (en) 1992-02-14 1993-02-12 Foam grip

Publications (3)

Publication Number Publication Date
EP0636068A1 EP0636068A1 (de) 1995-02-01
EP0636068A4 EP0636068A4 (de) 1995-03-29
EP0636068B1 true EP0636068B1 (de) 1999-04-21

Family

ID=25271296

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93905052A Expired - Lifetime EP0636068B1 (de) 1992-02-14 1993-02-12 Schaumstoffgriff

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EP (1) EP0636068B1 (de)
JP (1) JP3454431B2 (de)
AU (1) AU3619393A (de)
CA (1) CA2130109C (de)
DE (1) DE69324577T2 (de)
ES (1) ES2130254T3 (de)
MX (1) MX9300762A (de)
MY (1) MY130433A (de)
WO (1) WO1993015917A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6017477A (en) * 1996-07-23 2000-01-25 The Gillette Company Extrusion apparatus and process
JP2003512960A (ja) * 1999-11-02 2003-04-08 サンフォード エル．ピー． 変形可能グリップ
US20060062628A1 (en) * 2004-09-20 2006-03-23 Ken Kostecki Deformable grip for a writing implement

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1511325A1 (de) * 1966-08-30 1969-07-31 Gunther Zickwolff Vorrichtung fuer vorzugsweise stiftartige Schreib- oder Zeichengeraete zur Schonung der Finger
DE2162132A1 (de) * 1971-12-15 1973-06-20 Wolfgang Huebsch Anpassbares schreibhalter-system
US4008350A (en) * 1972-08-31 1977-02-15 Minnesota Mining And Manufacturing Company Visco-elastic material comprising a polymeric foam impregnated with an acrylic resin
US4098506A (en) * 1976-12-27 1978-07-04 Gaiser Conrad J Hand grip sleeve for hand tools and the like
US4158087A (en) * 1977-05-27 1979-06-12 W. R. Grace & Co. Urethane foams having low resiliency
JPS5939320B2 (ja) * 1977-08-12 1984-09-21 ぺんてる株式会社 鉛筆の製造法
US4476276A (en) * 1979-06-25 1984-10-09 Minnesota Mining And Manufacturing Company Latex-reinforced polyurethane sewer sealing composition
US4283808A (en) * 1979-09-17 1981-08-18 Beebe Lee M Gripping device for tooth brushes
JPS5681345A (en) * 1979-12-05 1981-07-03 Otsuka Chem Co Ltd Preparation of open-cell foam
US5000599A (en) * 1987-01-05 1991-03-19 Boyd I. Willat Writing implement
US4725627A (en) * 1987-03-16 1988-02-16 Signastone Incorporated Squeezable toy with dimensional memory
US4949457A (en) * 1988-08-03 1990-08-21 Warner-Lambert Company Soft resilient razor handle
US4932800A (en) * 1989-05-08 1990-06-12 The Gillette Company Finger gripping device

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
'CHAMBERS SCIENCE AND TECHNOLOGY DICTIONARY, PAGES 954, 955', WALKER CHAMBERS CAMBRIDGE, CAMBRIDGE *
'CONCISE OXFORD DICTIONARY, PAGES 486, 487', FOWLER OXFORD PRESS, OXFORD *

Also Published As

Publication number Publication date
JP3454431B2 (ja) 2003-10-06
MY130433A (en) 2007-06-29
DE69324577D1 (de) 1999-05-27
CA2130109A1 (en) 1993-08-19
AU3619393A (en) 1993-09-03
WO1993015917A1 (en) 1993-08-19
ES2130254T3 (es) 1999-07-01
MX9300762A (es) 1993-11-01
EP0636068A4 (de) 1995-03-29
EP0636068A1 (de) 1995-02-01
JPH07504131A (ja) 1995-05-11
DE69324577T2 (de) 1999-10-28
CA2130109C (en) 2000-01-04

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