EP0622468B1 - Verwendung einer Kupfer-Aluminium Legierung zur Herstellung von nickelfreien Gebrauchsgegenständen - Google Patents
Verwendung einer Kupfer-Aluminium Legierung zur Herstellung von nickelfreien Gebrauchsgegenständen Download PDFInfo
- Publication number
- EP0622468B1 EP0622468B1 EP19940105831 EP94105831A EP0622468B1 EP 0622468 B1 EP0622468 B1 EP 0622468B1 EP 19940105831 EP19940105831 EP 19940105831 EP 94105831 A EP94105831 A EP 94105831A EP 0622468 B1 EP0622468 B1 EP 0622468B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- copper
- production
- nickel
- alloy
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/01—Alloys based on copper with aluminium as the next major constituent
Definitions
- the invention relates to the use of a copper-aluminum alloy with manganese and iron as further constituents for the production of nickel-free everyday objects, in particular glasses, jewelry, cutlery, donrdashery, etc., which do not trigger any allergic reactions.
- Spectacle parts are to be understood in particular as spectacle arms, spectacle frames, eye edge profiles and spectacle hinges.
- Nickel-free copper alloys should be able to replace conventional nickel-containing alloys such as nickel silver (such as CuNil8Zn20). This can be achieved if the properties of the alternative nickel-free alloys meet or can be surpassed the requirements that are also placed on the nickel-containing alloys.
- a good alloy of glasses is sufficient high mechanical strength (tensile strength> 600 MPa, hardness 180 to 300 HV), sufficient softening temperature (after brief annealing for 30 seconds at 650 ° C at least 150 HV), an attractive appearance and good polishability expected. Esp. the softening behavior is of interest since the parts of the glasses should still have residual hardnesses of> 150 HV after connection work with hard solder.
- the invention is therefore based on the object of proposing a copper alloy for the abovementioned use which, with inexpensive producibility and sufficient mechanical parameters, has no nickel.
- EP-A-568 094 is a non-ferrous metal alloy for jewelry and metal objects with more than 5.0 to 15.00% Mn, 4.0 to 7.50% Al, 1.0 to 2.80% Fe, the rest Cu known.
- EP-A-532 929 describes a layer for the production of jewelry and spectacle frames with 86.0 to 90.0% Cu, 2.8 to 4.5% Al, 0.4 to 1.3% Mn, 1.0 up to 2.5% Fe 0 to 0.5% Si, rest Zn known.
- Alloys of 2 to 10% aluminum, up to about 8% manganese, chromium, iron and / or cobalt, alone or in groups, the rest of copper are known from DE-PS 757,956, but these alloys are used for the production of objects with high Long-term fatigue strength, such as of pipes for preheaters on ships, turbine blades, sea water-cooled mufflers, etc. Like. Used.
- the alloy can be derived from the known ⁇ / ⁇ multicomponent aluminum bronzes CuA110NiFe (alloy designation according to DIN 17.665) by replacing manganese with the element nickel and reducing aluminum so that there is only an ⁇ -phase structure for further processing of the pressed semi-finished product.
- Iron is present as Fe particles because of its poor solubility.
- the alloy can be conventionally continuously cast and hot pressed.
- Hot-pressed semi-finished products, such as wires can be cold-formed sufficiently well for optical wire production because of the ⁇ -phase-free structure that is always present after the hot-pressing process.
- Iron has a grain refining effect, so that a smooth surface desirable for optical quality can be drawn.
- the average grain size in wire sections recrystallized at 700 ° C. is 10 ⁇ m. After temper hardening at 300 to 400 ° C, the softening starts at 500 ° C, but at 700 ° C, residual hardnesses of HV 10 out of 200 are still registered if the annealing time does not exceed 30 seconds. This short-term annealing is intended to simulate the temperature conditions during the connection work with hard solder between 620 and 680 ° C. After 3 hours of annealing at 750 ° C, residual hardnesses of 150 are still measured.
- the use of a copper alloy according to the compositions according to claims 2 to 4 is recommended.
- the optional addition of lead is essential for machining in the manufacture of everyday items.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Eyeglasses (AREA)
- Adornments (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4314243 | 1993-04-30 | ||
DE19934314243 DE4314243C1 (de) | 1993-04-30 | 1993-04-30 | Verwendung einer Kupfer-Aluminium-Legierung zur Herstellung von nickelfreien Gebrauchsgegenständen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0622468A1 EP0622468A1 (de) | 1994-11-02 |
EP0622468B1 true EP0622468B1 (de) | 1996-09-11 |
Family
ID=6486812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19940105831 Expired - Lifetime EP0622468B1 (de) | 1993-04-30 | 1994-04-15 | Verwendung einer Kupfer-Aluminium Legierung zur Herstellung von nickelfreien Gebrauchsgegenständen |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0622468B1 (el) |
DE (2) | DE4314243C1 (el) |
DK (1) | DK0622468T3 (el) |
GR (1) | GR3021487T3 (el) |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE757956C (de) * | 1939-09-08 | 1953-03-23 | Finow Kupfer Und Messingwerke | Die Verwendung von Kupfer-Aluminium-Legierungen fuer Gegenstaende hoher Warmdauerstandfestigkeit |
JPS592130B2 (ja) * | 1975-12-03 | 1984-01-17 | タナカキキンゾクコウギヨウ カブシキガイシヤ | サンカブツブンサンガタノ デンキセツシヨクブヒンノ セイゾウホウ |
US5104457A (en) * | 1988-02-23 | 1992-04-14 | Country Club Golf Equipment (Proprietary) Limited | Golf clubs and method of making thereof |
US4917967A (en) * | 1989-01-13 | 1990-04-17 | Avon Products, Inc. | Multiple-layered article and method of making same |
DE4131426A1 (de) * | 1991-09-20 | 1993-03-25 | Berkenhoff Gmbh | Legierung, insbesondere zur verwendung zur herstellung von schmuck, brillengestellen etc. |
DE4214304A1 (de) * | 1992-04-30 | 1993-11-04 | Deutsche Nickel Ag | Nickelfreie buntmetallegierung und deren verwendung |
-
1993
- 1993-04-30 DE DE19934314243 patent/DE4314243C1/de not_active Expired - Fee Related
-
1994
- 1994-04-15 DE DE59400623T patent/DE59400623D1/de not_active Expired - Fee Related
- 1994-04-15 DK DK94105831T patent/DK0622468T3/da active
- 1994-04-15 EP EP19940105831 patent/EP0622468B1/de not_active Expired - Lifetime
-
1996
- 1996-10-25 GR GR960402851T patent/GR3021487T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
EP0622468A1 (de) | 1994-11-02 |
DE59400623D1 (de) | 1996-10-17 |
DE4314243C1 (de) | 1994-04-07 |
GR3021487T3 (en) | 1997-01-31 |
DK0622468T3 (el) | 1997-02-24 |
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