EP0621914B1 - Procede de teinture en continu de fils - Google Patents
Procede de teinture en continu de fils Download PDFInfo
- Publication number
- EP0621914B1 EP0621914B1 EP93902153A EP93902153A EP0621914B1 EP 0621914 B1 EP0621914 B1 EP 0621914B1 EP 93902153 A EP93902153 A EP 93902153A EP 93902153 A EP93902153 A EP 93902153A EP 0621914 B1 EP0621914 B1 EP 0621914B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dye
- dyeing
- dyes
- vat
- yarn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000010014 continuous dyeing Methods 0.000 title description 5
- 239000000975 dye Substances 0.000 claims abstract description 35
- 238000004043 dyeing Methods 0.000 claims abstract description 12
- 239000006185 dispersion Substances 0.000 claims abstract description 11
- 238000009970 yarn dyeing Methods 0.000 claims abstract 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 6
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 6
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 3
- 229940097275 indigo Drugs 0.000 claims description 3
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 claims description 2
- 239000000984 vat dye Substances 0.000 abstract description 9
- 238000010924 continuous production Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000126 substance Substances 0.000 description 6
- ZLHGTHCCYUEAIK-UHFFFAOYSA-N 5,7-dibromo-2-(5,7-dibromo-3-hydroxy-1H-indol-2-yl)indol-3-one Chemical compound [O-]c1c([nH]c2c(Br)cc(Br)cc12)C1=[NH+]c2c(cc(Br)cc2Br)C1=O ZLHGTHCCYUEAIK-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000009189 diving Effects 0.000 description 3
- QTWZICCBKBYHDM-UHFFFAOYSA-N leucomethylene blue Chemical compound C1=C(N(C)C)C=C2SC3=CC(N(C)C)=CC=C3NC2=C1 QTWZICCBKBYHDM-UHFFFAOYSA-N 0.000 description 3
- FDTLQXNAPKJJAM-UHFFFAOYSA-N 2-(3-hydroxyquinolin-2-yl)indene-1,3-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C1C1=NC2=CC=CC=C2C=C1O FDTLQXNAPKJJAM-UHFFFAOYSA-N 0.000 description 2
- KDVDMQVITMTCAH-UHFFFAOYSA-N 3,12-dinitroanthra[9,1,2-cde]benzo[rst]pentaphene-5,10-dione Chemical compound C12=C3C4=CC=C2C2=CC=C([N+]([O-])=O)C=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC([N+](=O)[O-])=CC=C3C3=CC=C4C1=C32 KDVDMQVITMTCAH-UHFFFAOYSA-N 0.000 description 2
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 description 2
- 235000019239 indanthrene blue RS Nutrition 0.000 description 2
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- JXUKQCUPTNLTCS-UHFFFAOYSA-N vat green 1 Chemical compound C1=CC=C[C]2C(=O)C(C3=C45)=CC=C4C(C4=C67)=CC=C7C(=O)[C]7C=CC=CC7=C6C=C(OC)C4=C5C(OC)=CC3=C21 JXUKQCUPTNLTCS-UHFFFAOYSA-N 0.000 description 2
- ILYBWLBYEIZMCE-UHFFFAOYSA-N 2,9-bis(4-chlorophenyl)anthra(2,1,9-def:6,5,10-d'e'f')diisoquinoline-1,3,8,10(2h,9h)-tetrone Chemical compound C1=CC(Cl)=CC=C1N(C(=O)C=1C2=C3C4=CC=1)C(=O)C2=CC=C3C(C=C1)=C2C4=CC=C3C(=O)N(C=4C=CC(Cl)=CC=4)C(=O)C1=C23 ILYBWLBYEIZMCE-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- -1 C.I.Vat Blue 5 Chemical compound 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000004048 vat dyeing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/228—Indigo
Definitions
- the task was to avoid the problem of oversaturated or too little concentrated vats in continuous dyeing.
- aqueous dispersions of vat dyes are suitable which contain dyes with a vatting half-life of, 20, preferably ⁇ 5 minutes.
- the dyes can be used, for example, in very small pieces.
- the dyes or preparations supplied by the well-known vat dye manufacturers are usually already suitable. In the case of dyes which have not already been optimized, they can be converted into a suitable form by known methods, for example ultrasound dispersion.
- the rate of vatting is essentially determined by the chemical structure, the crystallinity and crystal structure as well as by the particle size. Given the chemical structure, high vatting rates are obtained, for example, from amorphous, finely divided dyes.
- a high vatting rate is desirable because the concentration of non-veined dye in the diving liquor is kept low.
- Another possibility for limiting the concentration of non-coated dye in the immersion bath results from the metering of the dye via a bypass mixing tank.
- vat dyes can be used both individually and in combination.
- the dye supply can be controlled by separate metering devices.
- Suitable substrates to be dyed are cellulose yarns or blended yarns containing cellulose, which are then primarily processed into denim articles.
- the number of dives usually varies between 1 and 8. Depending on the dye and reducing agent, color temperatures of 20 to 95 ° C can be used.
- Suitable compounds are those known for vat dyeing, for example sodium dithionite, thiourea dioxide or organic reducing agents such as hydroxyacetone. Mixtures of reducing agents are also suitable.
- Dyes suitable for the process according to the invention are, in particular, the compounds listed in the Color Index under vat dyes and combinable dispersion dyes, if appropriate after appropriate dispersion.
- Preferred are e.g. C.I. Vat Blue 5 (C.I. 73065), C.I. Vat Orange 2 (C.I. 59705), C.I. Vat Blue 4 (C.I. 69800), C.I. Vat Red 32 (C.I. 71135), C.I. Vat Green 1 (C.I. 59825), C.I. Vat Green 9 (C.I. 59850) or Disperse Yellow 54 (C.I. 47020).
- the dye is fixed on the yarn, which must be replaced continuously to prevent the dye baths from becoming poor, i.e. add 50 g of dye per minute. It is continuously added as a dye dispersion in 1 liter of water. This dye dispersion is constantly stirred slowly.
- a brilliant blue color is obtained with the desired properties of low through-coloring (ring coloration) and thus a slight wash down.
- a slightly dyed Bw yarn is obtained which has the properties required for colored denim in the wash (wash down).
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Claims (4)
- Procédé de teinture continue de fils à l'aide de colorants pouvant être employés en cuve, caractérisé en ce que dans les installations de teinture des fils travaillant en continu, par exemple des installations de teinture en indigo, ou ajoute une dispersion aqueuse du colorant au bain de teinture en circulation.
- Procédé suivant la revendication 1, caractérisé en ce que l'on utilise des colorants qui possèdent une durée de demi-vie en cuve de ≤ 20 minutes, de préférence, ≤ 5 minutes.
- Procédé suivant la revendication 1, caractérisé en ce que le colorant est ajouté sous une forme facilement mise en cuve.
- Procédé suivant la revendication 1, caractérisé en ce que l'on utilise, à titre d'agent réducteur, du dithionite de sodium, du dioxyde de thiourée, des agents réducteurs organiques, ou des mélanges de tels agents réducteurs.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4201052 | 1992-01-17 | ||
DE4201052A DE4201052A1 (de) | 1992-01-17 | 1992-01-17 | Verfahren zum kontinuierlichen faerben von garnen |
PCT/EP1993/000021 WO1993014257A1 (fr) | 1992-01-17 | 1993-01-08 | Procede de teinture en continu de fils |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0621914A1 EP0621914A1 (fr) | 1994-11-02 |
EP0621914B1 true EP0621914B1 (fr) | 1996-06-26 |
Family
ID=6449657
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93902153A Expired - Lifetime EP0621914B1 (fr) | 1992-01-17 | 1993-01-08 | Procede de teinture en continu de fils |
Country Status (8)
Country | Link |
---|---|
US (1) | US5518508A (fr) |
EP (1) | EP0621914B1 (fr) |
JP (1) | JPH07506152A (fr) |
KR (1) | KR940703950A (fr) |
BR (1) | BR9305753A (fr) |
DE (2) | DE4201052A1 (fr) |
ES (1) | ES2089786T3 (fr) |
WO (1) | WO1993014257A1 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6308506B2 (en) * | 1998-12-18 | 2001-10-30 | Burlington Industries, Inc. | Production of color blended yarn for denim construction |
US8523957B2 (en) * | 2005-08-09 | 2013-09-03 | Sanko Tekstil Isletmeleri San. Ve Tic. A.S. | Process for introducing vat dyes and chemicals into textiles |
US10246590B2 (en) | 2016-06-17 | 2019-04-02 | Sanko Tekstil Isletmeleri San. Ve Tic. A.S. | Use of indigo derivatives for dyeing synthetic textiles, novel indigo derivatives and process for dyeing synthetic textiles |
PL3257900T3 (pl) * | 2016-06-17 | 2019-05-31 | Sanko Tekstil Isletmeleri San Ve Tic A S | Zastosowanie pochodnych indygo jako nieodwracalnych zmieniających kolor barwników do materiałów włókienniczych, nowe związki i sposób barwienia materiałów włókienniczych |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1399230A (en) * | 1920-09-08 | 1921-12-06 | Benjamin F Touchstone | Process of dyeing and apparatus therefor |
US1652649A (en) * | 1925-02-28 | 1927-12-13 | Dutchess Bleachery Inc | Dyeing process |
FR2552789B1 (fr) * | 1983-10-01 | 1986-12-19 | Sandoz Sa | Procede de teinture par epuisement de fibres textiles |
DE3639919A1 (de) * | 1986-11-22 | 1988-06-01 | Hoechst Ag | Verfahren zum egalfaerben von cellulosefasermaterial mit leukokuepenester-farbstoffen |
DE3833194A1 (de) * | 1988-09-30 | 1990-04-05 | Basf Ag | Verfahren zum faerben von textilen materialien aus cellulosefasern |
EP0470932A1 (fr) * | 1990-08-08 | 1992-02-12 | Ciba-Geigy Ag | Procédé de teintures de matériaux fibreux contenant de la cellulose avec des colorants de cuve |
-
1992
- 1992-01-17 DE DE4201052A patent/DE4201052A1/de not_active Withdrawn
-
1993
- 1993-01-08 ES ES93902153T patent/ES2089786T3/es not_active Expired - Lifetime
- 1993-01-08 EP EP93902153A patent/EP0621914B1/fr not_active Expired - Lifetime
- 1993-01-08 WO PCT/EP1993/000021 patent/WO1993014257A1/fr active IP Right Grant
- 1993-01-08 JP JP5512120A patent/JPH07506152A/ja active Pending
- 1993-01-08 KR KR1019940702346A patent/KR940703950A/ko not_active Application Discontinuation
- 1993-01-08 DE DE59303078T patent/DE59303078D1/de not_active Expired - Lifetime
- 1993-01-08 BR BR9305753A patent/BR9305753A/pt not_active Application Discontinuation
- 1993-01-08 US US08/256,340 patent/US5518508A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH07506152A (ja) | 1995-07-06 |
DE4201052A1 (de) | 1993-07-22 |
WO1993014257A1 (fr) | 1993-07-22 |
BR9305753A (pt) | 1997-01-28 |
DE59303078D1 (de) | 1996-08-01 |
KR940703950A (ko) | 1994-12-12 |
US5518508A (en) | 1996-05-21 |
ES2089786T3 (es) | 1996-10-01 |
EP0621914A1 (fr) | 1994-11-02 |
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