EP0615415A1 - Process for producing cast and set pieces of jewellery. - Google Patents

Process for producing cast and set pieces of jewellery.

Info

Publication number
EP0615415A1
EP0615415A1 EP92924652A EP92924652A EP0615415A1 EP 0615415 A1 EP0615415 A1 EP 0615415A1 EP 92924652 A EP92924652 A EP 92924652A EP 92924652 A EP92924652 A EP 92924652A EP 0615415 A1 EP0615415 A1 EP 0615415A1
Authority
EP
European Patent Office
Prior art keywords
model
stones
master
jewelry
molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92924652A
Other languages
German (de)
French (fr)
Other versions
EP0615415B1 (en
Inventor
Manfred Mueller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
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Publication of EP0615415A1 publication Critical patent/EP0615415A1/en
Application granted granted Critical
Publication of EP0615415B1 publication Critical patent/EP0615415B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D25/00Special casting characterised by the nature of the product
    • B22D25/02Special casting characterised by the nature of the product by its peculiarity of shape; of works of art
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44CPERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C17/00Gems or the like
    • A44C17/04Setting gems in jewellery; Setting-tools

Definitions

  • the invention is based on a method with the features specified in the preamble of claim 1.
  • a master model of the piece of jewelry is produced.
  • a master mold is produced by molding the master model.
  • the molding can be done by pouring a molding compound, for example a two-component silicone rubber mixture, into a container in which the master model is arranged, allowing the molding compound to harden, then cutting the body thus formed into two halves and takes the original model. It is also possible to place the master model between two blocks of thermoplastic material and to heat them under pressure until they plastically deform
  • the two-part archetypes formed in this way are also called rubber molds because they usually consist of more elastomeric material.
  • a modeling compound, in particular a wax is then poured into such a master mold by casting or injection molding. After the modeling compound has cooled, the master mold is opened and the model is removed.
  • Several models are usually put together to form a model tree and this is then embedded in a fireproof molding compound.
  • the molding composition is understood here as "fire-resistant” if it withstands the action of a molten metal from which the piece of jewelry is made without changing its shape.
  • the modeling compound of which the model tree consists is expelled by heating; if the modeling clay is a wax or a low-melting metal, it is melted out (lost wax process); if the modeling clay is plastic, it is burned out.
  • the molten metal from which the pieces of jewelry are to be made is then poured into the casting mold thus produced. So that the metal penetrates into the last corners and ramifications of the casting mold, it is rotated during casting (centrifugal casting) or the casting is supported by the use of negative pressure (vacuum casting). After solidification and cooling, the tree consisting of the pieces of jewelry is removed from the mold and the pieces of jewelry are separated from one another.
  • a master model of the piece of jewelry is produced, in which the stones are set, and this master model is molded to form the master form.
  • Such a master form which is a negative form of the piece of jewelry, accordingly contains recesses for the stones.
  • the stones for the piece of jewelry are inserted into these recesses of the original shape, then the shape is poured or injected with the modeling compound and the model of the piece of jewelry formed in this way is further processed in the manner described above.
  • the object of the present invention is to improve the method mentioned at the outset in such a way that stones which are positioned exactly in the piece of jewelry are obtained in the simplest possible manner.
  • This object is achieved by a method with the features specified in claims 1 or 2.
  • Advantageous developments of the invention are the subject of the dependent claims.
  • a master model is first produced from the piece of jewelry to be produced.
  • This master model has one or more settings corresponding to the number of gemstones provided, but the gemstones are not used in the master model.
  • a prong setting e.g. the prongs that are supposed to hold the gemstones are not bent inward, but they retain their original orientation that they had before the insertion of gemstones.
  • a negative form is then produced as the original form from the original model, in which no gemstone has yet been inserted, and a model of the piece of jewelry is cast in this original form.
  • Wax is preferably used as the modeling material, but other pourable or injectable modeling materials can also be used, which can be solidified by cooling, e.g.
  • low-melting metals or which can be solidified by crosslinking, e.g. Polyester resins, epoxy resins, polyurethanes and the like plastics.
  • the modeling clay must, however, be liquefied or decomposed (pyrolyzed) by heating and thus be able to be expelled.
  • the model produced in this way is now fitted with gemstones by inserting them into the frames provided for this purpose. Since the model is a positive form of the piece of jewelry, the stones can be inserted into the settings from the completely exposed top of the piece of jewelry as in the case of an original piece of jewelry, but do not have to be laboriously difficult as in the known lost wax technique accessible recesses of a negative form (original form) are inserted.
  • the stones can be inserted into the sockets of the model from the modeling compound (in particular wax model), for example by means of a slim suction applicator, with the aid of which the respective stone is sucked in, picked up, inserted into the socket and then left there by switching off the suction air. The stone then only needs to be fixed in the socket.
  • the model is made of a low-melting metal, it can be fixed like an original piece of jewelry, in the case of a claw setting by bending the claws inwards and thereby holding the respective gem in the setting.
  • the modeling clay is - as preferred - a wax or a plastic
  • the stones are preferably fixed in their holders by softening and plastically deforming them through the action of heat, and best of all by having the shape of the upper Tool adapted to the end of the holder is heated, placed on the holder and this is deformed in a single step by pressing the tool against the stone. This is not only possible in the case of prong or grain frames, which grip the stones in places like fingers, but also in frame frames, which encompass the stone over its entire circumference.
  • a tool with a frame-shaped contact surface at its tip as a tool for plastically deforming the mount, which tool is placed on the edge of the frame mount and then pressed against the surrounding stone edge.
  • a prong or grain it is expedient to use a tool which has projections corresponding to the position of the prongs or grains, with which the heated tool is placed on the prongs or projections, as a result of which they soften, flow and encompass the adjacent stone edges, for which purpose a short touch with the tool is enough.
  • this particularly advantageous variant of the invention is suitable for gripping larger stones.
  • the insertion of a stone into a wax model setting with an elastic widening of the setting is possible not only with prong settings, but also with frame settings, in particular with round settings, which completely enclose a gem along a circumferential edge of the gem.
  • a support for the edge of the stone to be gripped in the frame is expediently molded into the wax model after it has been poured, in particular by milling notches in the prongs of a prong setting or by milling a circumferential groove in the case of a frame setting, the milling being simple in view of the soft modeling clay and goes very quickly.
  • the stones are so easy to insert and fix in the model that even unskilled workers can master them after a short briefing.
  • the method according to the invention is therefore particularly suitable for the industrial mass production of jewelry.
  • the cost of setting gemstones can be drastically reduced: compared to the conventional technique of inserting the stones into the cast ring band, the cost of setting can be reduced to 1/10; compared to the conventional wax casting process, in which the stones are already poured into the wax model, the costs can still be reduced to 1/4.
  • Model is done as it is known per se in centrifugal casting or vacuum casting of jewelry.
  • the examples given below serve to illustrate this.
  • a master model is made of metal from a piece of jewelry, for example a ring, which is said to have several gemstones.
  • the original model has prong settings for the stones, but the stones are not used.
  • the master model is placed between two blocks of thermoplastic silicone elastomer which are subsequently heated and pressed against one another. As a result, the silicone elastomer is plastically deformed and conforms to the original model, whereby a true-to-nature impression of the original model is produced in the two blocks.
  • the two blocks formed in this way form the two parts of a master mold, into which a wax is then injected. After the wax has cooled, the master mold is opened and the wax model of the piece of jewelry is removed.
  • the intended ones are then used by means of a suction applicator
  • Stones are inserted and fixed by placing a fork-shaped tool, the two tines of which are electrically heated and at a distance from two opposing prongs, on two opposing prongs of the respective setting and briefly pressing on them, which softens and compresses the prongs and encompass the stone edge that is adjacent to them.
  • a wax model tree is then formed from a number of wax models produced in this way in a manner known per se, inserted into a cuvette and this is coated with a fine plaster, e.g. with alabaster, poured out. After the plaster has set, the cuvette is heated and the wax is melted out; The plaster cast of the wax model tree remains in the cuvette.
  • the cuvette is heated to a temperature of approximately 750 ° C., inserted into a centrifugal casting machine and a molten 14-carat gold alloy is poured in, which is allowed to solidify in the rotating cuvette. After the cuvette has cooled to about 40 ° C, the plaster is broken up, exposing the cast tree. The pieces of jewelry are now cut from the tree, cleaned and polished if necessary.
  • the method described in the first example is particularly suitable for pieces of jewelry with small gemstones, for the setting of which one gets by with short prongs that are no more than 2.5 or 3 mm long.
  • FIG. 1 as a second example, a cross section through a wax model of a ring rail with a holder consisting of four prongs or stumps,
  • Figure 2 is a plan view of the wax model of Figure 1 with a set gem and
  • FIG. 3 shows, as a third example, a cross section through a wax model of a ring rail with a frame mount.
  • the wax model of a ring rail 1 shown in FIG. 1 has a socket made of four prongs or stubs 2 to 5, which are 3 mm long.
  • the prongs 2 to 5 have a notch 6 near their upper ends, which can be milled into the prongs 2 to 5 of the wax model or can already be created in the original model, surprisingly the prongs have 2 to 5 sufficient elasticity, the gemstone 7 resiliently snap into the notches 6.
  • the gemstone 7 with its edge to be grasped can first be divided into two adjacent notches e.g. insert prongs 2 and 5 and then press its opposite edge into the notches of the other two prongs 3 and 4. A snapped in this way in prongs 2 to 5
  • Gemstone 7 does not have to be additionally fixed by thermally deforming the prongs, rather the wax part 1 can be used with the gemstone 7 which is only locked in place
  • Wax model tree can be processed further. Otherwise, the procedure is the same as in the first example.
  • the wax model of a ring rail 11 shown in FIG. 3 has a frame socket 12 provided as a recess in the ring rail, in particular a round socket for a round-ground stone 13.
  • the socket 12 has an annular groove 15.
  • This socket 12 can largely be pre-formed in the original model and then finished in the wax model, in particular by milling the groove 15 into the wax model.
  • the stone 13 can be snapped into place by pressing it into the socket and is then fixed by the spring action of the socket modeled in the wax; it is neither necessary to separate the round frame 12 into segments, nor is it necessary to thermally deform the round frame after inserting the stone 13 in order to fix the stone. Otherwise, the procedure in this third example can be the same as in the first example.
  • the second and third examples are particularly simple and inexpensive to manufacture and have the further advantage that the frames in the finished piece of jewelry look exactly the same as frames in which stones are only inserted after centrifugal casting or vacuum casting.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Adornments (AREA)
  • Mold Materials And Core Materials (AREA)
  • Cosmetics (AREA)

Abstract

In order to produce pieces of jewellery with one or several set stones, a master pattern with settings for the stones is produced, a master mould is produced by moulding from the master pattern, a model is produced in the master mould with a castable or injection mouldable modelling mass that can be ejected by heating from the master mould, the stones are inserted into the model and set by deformation of the setting, a casting mould is produced by embedding the model in a fire-resistant moulding mass and by ejecting the modelling mass from the casting mould, metal is cast into the casting mould by a spin casting or vacuum moulding process and the piece of jewellery is removed from the mould once the metal has cooled down.

Description

Verfahren zum Herstellen von gefaßten, gegossenen SchmuckstückenProcess for the production of set, cast jewelry
Die Erfindung geht aus von einem Verfahren mit den im Ober¬ begriff des Anspruchs 1 angegebenen Merkmalen.The invention is based on a method with the features specified in the preamble of claim 1.
In der DE-38 24 574 AI ist ein Wachsausschmelz-Gießverfahren zum Herstellen von Schmuckstücken beschrieben. Nach diesemDE-38 24 574 AI describes a lost wax casting process for the manufacture of jewelry. After this
Verfahren wird zunächst ein Urmodell des Schmuckstücks herge¬ stellt. Dann wird durch Abformen des Urmodells eine Urform hergestellt. Das Abformen kann dadurch geschehen, dass man in einen Behälter, in welchem das Urmodell angeordnet ist, eine Formmasse, beispielsweise ein Zweikomponenten-Silikon-Kaut¬ schuk-Gemisch, eingießt, die Formmasse aushärten läßt, den so gebildeten Körper dann in zwei Hälften aufschneidet und das Urmodell entnimmt. Es ist auch möglich, das Urmodell zwi¬ schen zwei Blöcke aus thermoplastischem Material zu legen und diese unter Druck zu erwärmen bis sie sich plastisch ver- First, a master model of the piece of jewelry is produced. Then a master mold is produced by molding the master model. The molding can be done by pouring a molding compound, for example a two-component silicone rubber mixture, into a container in which the master model is arranged, allowing the molding compound to harden, then cutting the body thus formed into two halves and takes the original model. It is also possible to place the master model between two blocks of thermoplastic material and to heat them under pressure until they plastically deform
formen und dem Urmodell anschmiegen, wodurch in den beiden Blöcken ein naturgetreuer Abdruck des Urmodells entsteht (DE-35 46 188 AI) . Die auf diese Weise gebildeten zweiteili¬ gen Urformen werden auch, weil sie üblicherweise aus elasto- merem Material bestehen, Gummiformen genannt. In eine solche Urform wird nun durch Gießen oder Spritzgießen eine Modellier¬ masse, insbesondere ein Wachs, eingefüllt. Nach dem Abkühlen der Modelliermasse wird die Urform geöffnet und das Modell entnommen. Mehrere Modelle werden üblicherweise zu einem Modellbaum zusammengefügt und dieser dann in eine feuerfeste Formmasse eingebettet. Die Formmasse wird hier dann als "feuerfest" verstanden, wenn sie der Einwirkung eines schmelz¬ flüssigen Metalls, aus welchem das Schmuckstück hergestellt wird, ohne Formänderung standhält. Nach dem Einbetten des Modellbaums in die feuerfeste Formmasse wird die Modellier¬ masse, aus welcher der Modellbaum besteht, durch Erhitzen ausgetrieben; ist die Modelliermasse ein Wachs oder ein niedrig schmelzendes Metall, wird sie ausgeschmolzen (Wachs¬ ausschmelzverfahren) ; ist die Modelliermasse ein Kunststoff, so wird sie ausgebrannt. In die so hergestellte Gießform wird dann das schmelzflüssige Metall eingegossen, aus wel¬ chem die Schmückstücke bestehen sollen. Damit das Metall bis in die letzten Winkel und Verästelungen der Gießform vordringt, läßt man sie beim Gießen rotieren (Schleuderguß) oder unterstützt das Gießen durch Anwendung von Unterdr ck (Vakuumguß) . Nach dem Erstarren und Abkühlen wird der aus den Schmuckstücken bestehende Baum entformt und werden die Schmuckstücke voneinander getrennt. Es ist auch bereits bekannt, zum Herstellen von Schmuck¬ stücken mit einem oder mehreren gefaßten Steinen diese mit einzugießen. Zu diesem Zweck wird ein Urmodell des Schmuck¬ stückes hergestellt, in welchem die Steine gefaßt sind, und dieses Urmodell abgeformt, um die Urform zu bilden. Eine solche Urform, welche eine Negativform des Schmuckstückes ist, enthält demgemäss Ausnehmungen für die Steine. In die¬ se Ausnehmungen der Urform werden die Steine für das Schmuck¬ stück eingesetzt, danach wird die Form mit der Modelliermasse ausgegossen oder ausgespritzt und das auf diese Weise gebil¬ dete Modell des Schmuckstückes in der oben beschriebenen Art und Weise weiterverarbeitet. Es ist allerdings schwierig, die Steine lagerichtig in die Urform einzusetzen und so zu fixieren, dass sie nach dem Eingießen oder Einspritzen der Modelliermasse genau die Lage haben, die sie auch im späteren Schmuckstück haben sollen. Es kommt vielmehr immer wieder vor, dass die Lage der Steine durch das Umgießen bzw. Um- spritzen geändert wird und dass das Ausmaß des Umspritzens von Modell zu Modell variiert, mitverursacht durch Abwei- chungen der Gestalt der Steine untereinander.shape and nestle the original model, creating a lifelike impression of the original model in the two blocks (DE-35 46 188 AI). The two-part archetypes formed in this way are also called rubber molds because they usually consist of more elastomeric material. A modeling compound, in particular a wax, is then poured into such a master mold by casting or injection molding. After the modeling compound has cooled, the master mold is opened and the model is removed. Several models are usually put together to form a model tree and this is then embedded in a fireproof molding compound. The molding composition is understood here as "fire-resistant" if it withstands the action of a molten metal from which the piece of jewelry is made without changing its shape. After the model tree has been embedded in the refractory molding compound, the modeling compound of which the model tree consists is expelled by heating; if the modeling clay is a wax or a low-melting metal, it is melted out (lost wax process); if the modeling clay is plastic, it is burned out. The molten metal from which the pieces of jewelry are to be made is then poured into the casting mold thus produced. So that the metal penetrates into the last corners and ramifications of the casting mold, it is rotated during casting (centrifugal casting) or the casting is supported by the use of negative pressure (vacuum casting). After solidification and cooling, the tree consisting of the pieces of jewelry is removed from the mold and the pieces of jewelry are separated from one another. It is also known to cast jewelry with one or more set stones for the manufacture of jewelry. For this purpose, a master model of the piece of jewelry is produced, in which the stones are set, and this master model is molded to form the master form. Such a master form, which is a negative form of the piece of jewelry, accordingly contains recesses for the stones. The stones for the piece of jewelry are inserted into these recesses of the original shape, then the shape is poured or injected with the modeling compound and the model of the piece of jewelry formed in this way is further processed in the manner described above. However, it is difficult to insert the stones in the correct position in the master mold and to fix them in such a way that after pouring or injecting the modeling clay, they have exactly the position that they should also have in the later piece of jewelry. Rather, it happens again and again that the position of the stones is changed by the casting or overmolding, and that the extent of the molding varies from model to model, partly due to deviations in the shape of the stones from one another.
Aus der FR-PS 1,599,866 ist es bereits bekannt, Schmucksteine in ein Wachsmodell einzubetten, solche Wachsmodelle zu einem Wachsmodellbaum zusammenzubauen und nach einem Wachsausschmelz- verfahren zu gegossen Schmuckstücken weiterzuverarbeiten. Da¬ bei werden die Schmucksteine jedoch nicht in eine besondere Fassung am Wachsmodell eingesetzt, sondern in ein fassungs¬ los hergestelltes Wachsmodell eingesteckt. Dementsprechend hat auch das gegossene Schmuckstück keine besondere Fassung für die Steine.From FR-PS 1,599,866 it is already known to embed gemstones in a wax model, to assemble such wax models into a wax model tree and to further process them into cast jewelry pieces using a lost wax process. In this case, however, the gemstones are not inserted into a special setting on the wax model, but instead are inserted into a wax model produced without a setting. Accordingly, the cast piece of jewelry has no special setting for the stones.
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, das eingangs genannte Verfahren so zu verbessern, dass man auf möglichst einfache Art und Weise exakt positionierte Steine im Schmuckstück erhält. Diese Aufgabe wird gelöst durch ein Verfahren mit den in den Ansprüchen 1 oder 2 angegebenen Merkmalen. Vorteilhafte Weiterbildungen der Erfindung sind Gegenstand der abhängigen Ansprüche.The object of the present invention is to improve the method mentioned at the outset in such a way that stones which are positioned exactly in the piece of jewelry are obtained in the simplest possible manner. This object is achieved by a method with the features specified in claims 1 or 2. Advantageous developments of the invention are the subject of the dependent claims.
Beim erfindungsgemässen Verfahren wird wie beim bekannten Ver¬ fahren von dem herzustellenden Schmuckstück zunächst ein Ur¬ modell hergestellt. Dieses Urmodell hat eine oder mehrere Fassungen entsprechend der Anzahl der vorgesehenen Schmuck- steine, doch werden die Schmucksteine nicht in das Urmodell eingesetzt. Bei einer Krappenfassung z.B. werden die Krappen, die die Schmucksteine fassen sollen, nicht einwärts gebogen, sondern sie behalten ihre ursprüngliche Ausrichtung, die sie vor dem Einsetzen von Schmucksteinen haben. Es wird dann von dem Urmodell, in welches noch kein Schmuckstein eingesetzt ist, eine Negativform als Urform hergestellt und in dieser Urform ein Modell des Schmuckstücks gegossen. Dabei dient als Modellier¬ masse vorzugsweise Wachs, doch können auch andere gießbare oder einspritzbare Modelliermassen verwendet werden, die sich durch Abkühlen verfestigen lassen, wie z.B. niedrigschmelzende Me¬ talle, oder die sich durch Vernetzung verfestigen lassen wie z.B. Polyesterharze, Epoxidharze, Polyurethane und dergleichen Kunststoffe. Die Modelliermassen müssen sich allerdings durch Erhitzen verflüssigen oder zersetzen (pyrolisieren) und da- durch austreiben lassen.In the method according to the invention, as in the known method, a master model is first produced from the piece of jewelry to be produced. This master model has one or more settings corresponding to the number of gemstones provided, but the gemstones are not used in the master model. With a prong setting e.g. the prongs that are supposed to hold the gemstones are not bent inward, but they retain their original orientation that they had before the insertion of gemstones. A negative form is then produced as the original form from the original model, in which no gemstone has yet been inserted, and a model of the piece of jewelry is cast in this original form. Wax is preferably used as the modeling material, but other pourable or injectable modeling materials can also be used, which can be solidified by cooling, e.g. low-melting metals, or which can be solidified by crosslinking, e.g. Polyester resins, epoxy resins, polyurethanes and the like plastics. The modeling clay must, however, be liquefied or decomposed (pyrolyzed) by heating and thus be able to be expelled.
Das so hergestellte Modell wird nun mit Schmucksteinen bestückt, indem diese in die dafür vorgesehenen Fassungen eingesetzt wer¬ den. Da es sich bei dem Modell um eine Positivform des Schmuck- Stücks handelt, können die Steine wie bei einem Originalschmuck¬ stück von der völlig freiliegenden Oberseite des Schmuckstückes her in die Fassungen eingesetzt werden, müssen aber nicht wie bei dem bekannten Wachsausschmelzverfahren mühsam in schwer zugängliche Ausnehmungen einer Negativform (Urform) einge¬ fügt werden. Das Einfügen der Steine in die Fassungen des Modells aus der Modelliermasse (insbesondere Wachsmodell) kann z.B. mittels eines schlanken Saugapplikators geschehen, mit dessen Hilfe man den jeweiligen Stein ansaugt, aufnimmt, in die Fassung einsetzt und dann darin durch Abschalten der Saugluft beläßt. Der Stein muss danach in der Fassung nur noch fixiert werden. Soweit das Modell aus einem niedrig¬ schmelzenden Metall besteht, kann das Fixieren wie bei einem Originalschmuckstück erfolgen, im Falle einer Krappenfassung dadurch, dass die Krappen einwärts gebogen werden und dadurch den jeweiligen Schmuckstein in der Fassung festhalten. Ist die Modelliermasse hingegen - wie bevorzugt - ein Wachs oder ein Kunststoff, dann geschieht das Fixieren der Steine in ihren Fassungen vorzugsweise dadurch, dass diese durch Wärme¬ einwirkung erweicht und plastisch verformt werden, und zwar am besten dadurch, dass ein der Gestalt des oberen Endes der Fassung angepaßtes Werkzeug erwärmt, auf die Fassung aufge¬ setzt und diese durch Andrücken des Werkzeugs gegen den Stein in einem einzigen Schritt verformt wird. Dies geht nicht nur bei Krappen- oder Körnerfassungen, welche die Steine stellen¬ weise fingerartig umgreifen, sondern auch bei Rahmenfassungen, die den Stein auf seinem gesamten Umfang umfassen. Bei einer Rahmenfassung würde man als Werkzeug zum plastischen Verformen der Fassung zweckmässigerweise ein Werkzeug mit einer rahmen- förmigen Auflagefläche an seiner Spitze verwenden, welche man auf den Rand der Rahmenfassung aufsetzt und dann gegen die umlaufende Steinkante drückt. Bei einer Krappen- oder Körner- fassung hingegen verwendet man zweckmässigerweise ein Werk¬ zeug, welches der Lage der Krappen bzw. Körner entsprechende Vorsprünge hat, mit denen das erwärmte Werkzeug auf die Krappen bzw. Vorsprünge aufgesetzt wird, wodurch diese er- weichen, fließen und die benachbarten Steinkanten umgreifen, wozu eine kurze Berührung mit dem Werkzeug reicht. Dabei hat es sich gezeigt, dass keineswegs alle Krappen oder Körner ver¬ formt werden müssen, um die Schmucksteine zu fixieren, denn eine durch Wärmeeinwirkung verformte Krappe hat einen innigeren Kontakt zur Steinkante als eine metallische, in herkömmlicher Weise gegen die Steinkante gedrückte Krappe. Es wird deshalb bevorzugt, dass bei Krappen- oder Körnerfassungen nur eine Teilmenge der Krappen bzw. Körner verformt wird, die übrigen hingegen unverformt stehen bleiben. Auf diese Weise bleibt trotz der Verformung einzelner Krappen wegen der nach wie vor unverformten Krappen der gewohnte Eindruck einer üblichen Krappenfassung erhalten. Bei einer Krappenfassung mit vier Krappen je Stein werden vorzugsweise nur zwei einander gegen¬ überliegende Krappen verformt, bei einer Fassung mit sechs Krappen werden vorzugsweise drei Krappen verformt.The model produced in this way is now fitted with gemstones by inserting them into the frames provided for this purpose. Since the model is a positive form of the piece of jewelry, the stones can be inserted into the settings from the completely exposed top of the piece of jewelry as in the case of an original piece of jewelry, but do not have to be laboriously difficult as in the known lost wax technique accessible recesses of a negative form (original form) are inserted. The stones can be inserted into the sockets of the model from the modeling compound (in particular wax model), for example by means of a slim suction applicator, with the aid of which the respective stone is sucked in, picked up, inserted into the socket and then left there by switching off the suction air. The stone then only needs to be fixed in the socket. If the model is made of a low-melting metal, it can be fixed like an original piece of jewelry, in the case of a claw setting by bending the claws inwards and thereby holding the respective gem in the setting. If, on the other hand, the modeling clay is - as preferred - a wax or a plastic, then the stones are preferably fixed in their holders by softening and plastically deforming them through the action of heat, and best of all by having the shape of the upper Tool adapted to the end of the holder is heated, placed on the holder and this is deformed in a single step by pressing the tool against the stone. This is not only possible in the case of prong or grain frames, which grip the stones in places like fingers, but also in frame frames, which encompass the stone over its entire circumference. In the case of a frame mount, one would expediently use a tool with a frame-shaped contact surface at its tip as a tool for plastically deforming the mount, which tool is placed on the edge of the frame mount and then pressed against the surrounding stone edge. With a prong or grain Conversely, it is expedient to use a tool which has projections corresponding to the position of the prongs or grains, with which the heated tool is placed on the prongs or projections, as a result of which they soften, flow and encompass the adjacent stone edges, for which purpose a short touch with the tool is enough. It has been shown that all prongs or grains do not have to be deformed in order to fix the gemstones, because a prong deformed by the action of heat has more intimate contact with the stone edge than a metallic pretzel pressed in a conventional manner against the stone edge. It is therefore preferred that only a subset of the prongs or grains is deformed in the case of claw or grained frames, while the rest remain undeformed. In this way, despite the deformation of individual prongs because of the still undeformed prongs, the usual impression of a conventional prong setting is retained. In a claw setting with four claws per stone, preferably only two claws lying opposite one another are deformed, in a setting with six claws preferably three claws are deformed.
Anstatt die Fassung nach dem Einsetzen des Steins plastisch zu verformen, kann man sie auch beim Einsetzen des Steins elastisch aufweiten, um den Stein federnd zu fassen. Uber- raschenderweise hat es sich gezeigt, dass das sogar möglich ist, wenn man als Modelliermasse für die in der Urform her¬ zustellenden Modelle ein handelsübliches Wachs verwendet. Bei einer Krappenfassung kann man Steine allein durch Instead of plastically deforming the socket after inserting the stone, you can also expand it elastically when inserting the stone in order to hold the stone resiliently. Surprisingly, it has been shown that this is even possible if a commercially available wax is used as the modeling compound for the models to be produced in the original mold. With a prong setting you can go through stones alone
elastisches Aufweiten der Fassung im Wachsmodell fixieren, wenn die Krappen mindestens 2,5 bis 3 mm lang sind. Bei dieser Mindestlänge kann man sie trotz der geringen Elasti¬ zität des Wachses weit genug elastisch abbiegen, um einen Stein in die Fassung einführen zu können. Wegen der er¬ forderlichen Mindestlänge der Krappen eignet sich diese besonders vorteilhafte Variante der Erfindung für das Fassen größerer Steine. Das Einsetzen eines Steins in eine Wachsmodellfassung unter elastischem Aufweiten der Fassung ist aber nicht nur bei Krappenfassungen möglich, sondern auch bei Rahmenfassungen, insbesondere bei Rundfassungen, welche einen Schmuckstein vollständig längs einer umlaufen¬ den Kante des Schmucksteins umfassen.Fix the elastic expansion of the socket in the wax model when the prongs are at least 2.5 to 3 mm long. At this minimum length, despite the low elasticity of the wax, it can be bent elastically far enough to be able to insert a stone into the socket. Because of the required minimum length of the prongs, this particularly advantageous variant of the invention is suitable for gripping larger stones. The insertion of a stone into a wax model setting with an elastic widening of the setting is possible not only with prong settings, but also with frame settings, in particular with round settings, which completely enclose a gem along a circumferential edge of the gem.
Um einen Schmuckstein allein durch Federkraft in einerTo a gemstone by spring force in one
Wachsmodellfassung fixieren zu können, sollte man in der Fassung eine Auflage für die zu fassende Kante des Steins haben. Eine solche Auflage wird zweckmässigerweise erst nach dem Giesen des Wachsmodells in dieses eingeformt, insbesondere durch Einfräsen von Kerben in die Krappen einer Krappenfassung oder durch Einfräsen einer umlaufen¬ den Rille im Falle einer Rahmenfassung, wobei das Ein¬ fräsen angesichts der weichen Modelliermasse einfach ist und sehr rasch geht.To be able to fix the wax model frame, you should have a support for the edge of the stone to be gripped in the frame. Such a support is expediently molded into the wax model after it has been poured, in particular by milling notches in the prongs of a prong setting or by milling a circumferential groove in the case of a frame setting, the milling being simple in view of the soft modeling clay and goes very quickly.
Das Einsetzen und Fixieren der Steine in dem Modell sind so leicht, dass es auch von ungelernten Arbeitskräften nach kurzer Einweisung beherrscht wird. Das erfindungsgemässe Ver¬ fahren eignet sich deshalb besonders für die industrielle Massenfertigung von Schmuckstücken. Bereits in der Erpro¬ bungsphase des erfindungsgemässen Verfahrens hat sich ge- zeigt, dass die Kosten für das Fassen von Schmucksteinen drastisch gesenkt werden können: Verglichen mit der her¬ kömmlichen Technik, die Steine in die fertig gegossene Ringschiene einzusetzen, lassen sich die Kosten des Fassens auf 1/10 senken; verglichen mit dem herkömmlichen Wachsaus¬ schmelzverfahren, bei welchem die Steine bereits in das Wachs¬ modell eingegossen werden, lassen sich die Kosten immerhin noch auf ein 1/4 senken.The stones are so easy to insert and fix in the model that even unskilled workers can master them after a short briefing. The method according to the invention is therefore particularly suitable for the industrial mass production of jewelry. Already in the testing phase of the method according to the invention, shows that the cost of setting gemstones can be drastically reduced: compared to the conventional technique of inserting the stones into the cast ring band, the cost of setting can be reduced to 1/10; compared to the conventional wax casting process, in which the stones are already poured into the wax model, the costs can still be reduced to 1/4.
Die Weiterverarbeitung des erfindungsgemäss hergestelltenThe further processing of the manufactured according to the invention
Modells geschieht so, wie es beim Schleudergießen oder Vakuum¬ gießen- von Schmuckstücken an sich bekannt ist. Zur Verdeut¬ lichung dienen die nachstehend wiedergegebenen Beispiele.Model is done as it is known per se in centrifugal casting or vacuum casting of jewelry. The examples given below serve to illustrate this.
1. Beispiel:1st example:
Von einem Schmuckstück, z.B. einem Ring, welcher mehrere Schmuck¬ steine aufweisen soll, wird in an sich bekannter Weise ein Ur¬ modell aus Metall gemacht. Das Urmodell hat Krappenfassungen für die Steine, die Steine werden jedoch nicht eingesetzt. Das Ur¬ modell wird zwischen zwei Blöcke aus thermoplastischem Silikon- Eiastomer gelegt, die nachfolgend erhitzt und gegeneinander ge¬ drückt werden. Dadurch wird das Silikon-Elastomer plastisch ver¬ formt und schmiegt sich dem Urmodell an, wodurch in den beiden Blöcken ein naturgetreuer Abdruck des Urmodells entsteht. Die beiden- auf diese Weise umgeformten Blöcke bilden die beiden Teile einer Urform, in welche anschließend ein Wachs eingespritzt wird. Nach dem Erkalten des Wachses wird die Urform geöffnet und das Wachsmodell des Schmuckstücks entnommen. In die im Wachsmodell ausgebildeten Fassungen aus beispielsweise je vier Krappen wer¬ den anschließend mittels eines Saugapplikators die vorgesehenen A master model is made of metal from a piece of jewelry, for example a ring, which is said to have several gemstones. The original model has prong settings for the stones, but the stones are not used. The master model is placed between two blocks of thermoplastic silicone elastomer which are subsequently heated and pressed against one another. As a result, the silicone elastomer is plastically deformed and conforms to the original model, whereby a true-to-nature impression of the original model is produced in the two blocks. The two blocks formed in this way form the two parts of a master mold, into which a wax is then injected. After the wax has cooled, the master mold is opened and the wax model of the piece of jewelry is removed. In the wax-up frames made of, for example, four prongs, the intended ones are then used by means of a suction applicator
Steine eingesetzt und fixiert, indem man ein gabelförmiges Werkzeug, dessen zwei Zinken elektrisch beheizt sind und den Abstand von zwei einander gegenüberliegenden Krappen haben, auf zwei einander gegenüberliegende Krappen der je- weiligen Fassung aufsetzt und kurz leicht andrückt, wodurch die Krappen erweichen und gestaucht werden und die ihnen je¬ weils benachbarte Steinkante umgreifen. Aus einer Anzahl von so hergestellten Wachsmodellen wird dann in an sich bekannter Weise ein Wachsmodellbaum gebildet, in eine Küvette einge- setzt und diese mit einem feinen Gips, z.B. mit Alabaster, ausgegossen. Nach dem Abbinden des Gipses wird die Küvette erhitzt und dadurch das Wachs ausgeschmolzen; in der Kü¬ vette bleibt der Gipsabguss des Wachsmodellbaums zurück. Die Küvette wird auf eine Temperatur von ungefähr 750° C er- hitzt, in eine Schleudergussmaschine eingesetzt und eine ge¬ schmolzene 14-karätige Goldlegierung eingegossen, die man in der rotierenden Küvette erstarren läßt. Nach dem Abkühlen der Küvette auf etwa 40° C wird der Gips zerschlagen und dadurch der gegossene Baum freigelegt. Die Schmuckstücke werden nunmehr vom Baum abgeschnitten, gereinigt und ggfs. poliert.Stones are inserted and fixed by placing a fork-shaped tool, the two tines of which are electrically heated and at a distance from two opposing prongs, on two opposing prongs of the respective setting and briefly pressing on them, which softens and compresses the prongs and encompass the stone edge that is adjacent to them. A wax model tree is then formed from a number of wax models produced in this way in a manner known per se, inserted into a cuvette and this is coated with a fine plaster, e.g. with alabaster, poured out. After the plaster has set, the cuvette is heated and the wax is melted out; The plaster cast of the wax model tree remains in the cuvette. The cuvette is heated to a temperature of approximately 750 ° C., inserted into a centrifugal casting machine and a molten 14-carat gold alloy is poured in, which is allowed to solidify in the rotating cuvette. After the cuvette has cooled to about 40 ° C, the plaster is broken up, exposing the cast tree. The pieces of jewelry are now cut from the tree, cleaned and polished if necessary.
Das im 1. Beispiel beschriebene Verfahren eignet sich be¬ sonders für Schmuckstücke mit kleinen Schmucksteinen, für deren Fassung man mit kurzen Krappen auskommt, die nicht mehr als 2,5 oder 3 mm lang sind. Für das Fassen von größeren Schmucksteinen gibt es in vorteilhafter Weiter¬ bildung der Erfindung besonders einfache Verfahren, die anhand der beigefügten Zeichnungen erläutert werden, in denenThe method described in the first example is particularly suitable for pieces of jewelry with small gemstones, for the setting of which one gets by with short prongs that are no more than 2.5 or 3 mm long. In an advantageous further development of the invention, there are particularly simple methods for setting larger gemstones: are explained with reference to the accompanying drawings, in which
Figur 1 als 2. Beispiel einen Querschnitt durch ein Wachs¬ modell einer Ringschiene mit einer aus vier Krappen oder Stotzen bestehenden Fassung,FIG. 1 as a second example, a cross section through a wax model of a ring rail with a holder consisting of four prongs or stumps,
Figur 2 eine Draufsicht auf das Wachsmodell aus Figur 1 mit gefaßtem Schmuckstein undFigure 2 is a plan view of the wax model of Figure 1 with a set gem and
Figur 3 als 3. Beispiel einen Querschnitt durch ein Wachε- modell einer Ringschiene mit einer Rahmenfassung zeigt.FIG. 3 shows, as a third example, a cross section through a wax model of a ring rail with a frame mount.
Das in Figur 1 dargestellte Wachsmodell einer Ringschiene 1 hat eine Fassung aus vier Krappen oder Stotzen 2 bis 5, die 3 mm lang sind. Als Auflage für einen größeren zu fassenden Stein, z.B. einen Rosenquarz im Emerald-Schliff, haben die Krappen 2 bis 5 in der Nähe ihrer oberen Enden jeweils eine Kerbe 6, welche in die Krappen 2 bis 5 des Wachsmodells ein¬ gefräst oder schon im Urmodell angelegt sein können, über¬ raschenderweise haben die Krappen 2 bis 5 genügend Elastizi¬ tät, tun den Schmuckstein 7 federnd in die Kerben 6 einzurasten. Dazu kann man den Schmuckstein 7 mit seiner zu fassenden Kante zunächst in zwei benachbarte Kerben z.B. der Krappen 2 und 5 einfügen und dann seine gegenüberliegende Kante in die Kerben der beiden anderen Krappen 3 und 4 eindrücken. Ein auf diese Weise in die Krappen 2 bis 5 eingerasteterThe wax model of a ring rail 1 shown in FIG. 1 has a socket made of four prongs or stubs 2 to 5, which are 3 mm long. As a support for a larger stone to be gripped, e.g. a rose quartz in Emerald cut, the prongs 2 to 5 have a notch 6 near their upper ends, which can be milled into the prongs 2 to 5 of the wax model or can already be created in the original model, surprisingly the prongs have 2 to 5 sufficient elasticity, the gemstone 7 resiliently snap into the notches 6. For this purpose, the gemstone 7 with its edge to be grasped can first be divided into two adjacent notches e.g. insert prongs 2 and 5 and then press its opposite edge into the notches of the other two prongs 3 and 4. A snapped in this way in prongs 2 to 5
Schmuckstein 7 muss nicht zusätzlich durch thermisches Ver- formen der Krappen fixiert werden, vielmehr kann das Wachs- modeil 1 mit dem lediglich eingerasteten Schmuckstein 7 zum Gemstone 7 does not have to be additionally fixed by thermally deforming the prongs, rather the wax part 1 can be used with the gemstone 7 which is only locked in place
Wachsmodellbaum weiterverarbeitet werden. Im übrigen kann wie im ersten Beispiel verfahren werden.Wax model tree can be processed further. Otherwise, the procedure is the same as in the first example.
Das in Figur 3 dargestellte Wachsmodell einer Ringschiene 11 hat eine als Ausnehmung in der Ringschiene vorgesehene Rahmenfassung 12, insbesondere eine Rundfassung für einen rund geschliffenen Stein 13. Zum Aufnehmen der am Umfang des Steins vorgesehenen Kante 14 hat die Fassung 12 eine ringförmig verlaufende Rille 15. Diese Fassung 12 kann weitgehend im Urmodell vorgebildet und dann im Wachsmodell, insbesondere durch Einfräsen der Rille 15 in das Wachs o- dell, fertiggestellt werden. Der Stein 13 läßt sich über¬ raschenderweise durch Eindrücken in die Fassung einrasten und ist dann durch die Federwirkung der in das Wachs modellierten Fassung fixiert; dazu ist es weder nötig, die Rundfassung 12 in Segmente aufzutrennen noch ist es nötig, die Rundfassung nach dem Einsetzen des Steins 13 thermisch zu verformen, um den Stein zu fixieren. Im übrigen kann in diesem dritten Beispiel wie im ersten Bei- spiel verfahren werden.The wax model of a ring rail 11 shown in FIG. 3 has a frame socket 12 provided as a recess in the ring rail, in particular a round socket for a round-ground stone 13. To accommodate the edge 14 provided on the circumference of the stone, the socket 12 has an annular groove 15. This socket 12 can largely be pre-formed in the original model and then finished in the wax model, in particular by milling the groove 15 into the wax model. Surprisingly, the stone 13 can be snapped into place by pressing it into the socket and is then fixed by the spring action of the socket modeled in the wax; it is neither necessary to separate the round frame 12 into segments, nor is it necessary to thermally deform the round frame after inserting the stone 13 in order to fix the stone. Otherwise, the procedure in this third example can be the same as in the first example.
Das zweite und dritte Beispiel sind besonders einfach und preisgünstig in der Herstellung und haben den weiteren Vorteil, dass die Fassungen im fertigen Schmuckstück äußerlich genauso aussehen wie Fassungen, in welche Steine erst nach dem Schleudergießen oder Vakuumgießen eingesetzt werden. The second and third examples are particularly simple and inexpensive to manufacture and have the further advantage that the frames in the finished piece of jewelry look exactly the same as frames in which stones are only inserted after centrifugal casting or vacuum casting.

Claims

Patentansprüche: Claims:
1. Verfahren zum Herstellen von Schmuckstücken mit einer oder mehreren gefaßten Steinen durch1. Method of making jewelry with one or more set stones by
- Herstellen eines Urmodells mit Fassungen für die Steine,- making a master model with frames for the stones,
- Herstellen einer Urform durch Abformen des Urmodells,- production of an original form by molding the original model,
- Herstellen eines Modells aus einer gieß- oder spritzgieß- fähigen, durch Erhitzen austreibbaren Modelliermasse in der Urform,- producing a model from a casting or injection-moldable modeling material which can be expelled by heating in the original mold,
- Herstellen einer Gießform durch Einbetten des Modells in eine feuerfeste Formmasse und Austreiben der Modellier¬ masse aus der Gießform,Producing a casting mold by embedding the model in a refractory molding compound and expelling the modeling compound from the casting mold,
- Gießen von Metall in die Gießform,- pouring metal into the mold,
-"Entformen des Schmuckstücks nach Erstarren des Metalls,- " De-molding the piece of jewelry after the metal has solidified,
dadurch gekennzeichnet,characterized,
dass die Urform durch Abformen des noch keine Steine ent¬ haltenden Urmodells gebildet wird, dass die Steine vielmehr erst in das mit der Urform herge- stellte Modell eingesetzt und durch Verformen der Fassungen gefaßt werden. that the master form is formed by molding the master model that does not yet contain any stones, that the stones are rather only inserted into the model produced with the master mold and are grasped by deforming the frames.
2. Verfahren zum Herstellen von Modellen aus einer gieß- oder spritzgießfähigen, durch Erhitzen austreibbaren2. Process for producing models from a castable or injection-moldable, expellable by heating
Modelliermasse,Modeling clay,
zum Zwecke der Verwendung in einem Verfahren zum Herstellen von Schmuckstücken mit einem oder mehreren gefaßten Steinen, in welchem durch Einbetten des Modells in eine feuerfeste Formmasse und anschließendes Austreiben der Modelliermasse eine Gießform gebildet, Metall in die Gießform gegossen und das jeweilige Schmuckstück nach Erstarren des Metalls ent¬ formt wird,for the purpose of use in a method for producing jewelry with one or more set stones, in which a mold is formed by embedding the model in a refractory molding compound and then expelling the modeling compound, metal is poured into the casting mold and the respective item of jewelery after the metal has solidified is demolded,
durch Herstellen eines Urmodells mit Fassungen für die Steine und Herstellen einer Urform durch Abformen des Urmodells,by producing a master model with frames for the stones and producing a master form by molding the master model,
dadurch gekennzeichnet, dass die Urform durch Abformen des noch keine Steine enthaltenden Urmodells gebildet wird, dass die Steine vielmehr erst in das mit der Urform hergestellte Modell eingesetzt und durch Verformen der Fassungen gefaßt werden.characterized in that the master form is formed by molding the master model that does not yet contain any stones, that the stones are rather only inserted into the model produced with the master form and are grasped by deforming the frames.
3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeich¬ net, dass die aus der Modelliermasse bestehenden3. The method according to claim 1 or 2, characterized gekennzeich¬ net that the existing from the modeling clay
Fassungen nach dem Einsetzen der Steine plastisch verformt werden.Sockets are plastically deformed after inserting the stones.
4. Verfahren nach Anspruch 3, dadurch gekennzeichnet, dass die Fassungen thermisch verformt werden. 4. The method according to claim 3, characterized in that the sockets are thermally deformed.
5. Verfahren nach Anspruch 4, dadurch gekennzeichnet, dass ein der Gestalt des oberen Endes der jeweiligen5. The method according to claim 4, characterized in that one of the shape of the upper end of each
Fassung angepaßtes Werkzeug erwärmt, auf die Fassung auf¬ gesetzt und diese in einem einzigen Schritt durch Andrücken des Werkzeuges verformt wird.Tool adapted to the socket is heated, placed on the socket and this is deformed in a single step by pressing the tool.
6. Verfahren nach einem der vorstehenden Ansprüche, da¬ durch gekennzeichnet, dass die Fassungen nur stellen¬ weise verformt werden.6. The method according to any one of the preceding claims, characterized in that the sockets are only deformed in places.
7. Verfahren nach Anspruch 6, dadurch gekennzeichnet, dass bei Krappen- oder Körnerfassungen nur eine Teil¬ menge der Krappen bzw. Körner verformt wird.7. The method according to claim 6, characterized in that only a partial amount of the prongs or grains is deformed in claw or grain settings.
8. Verfahren nach Anspruch 1 oder 2, dadurch gekenn¬ zeichnet, dass die Fassung (2-9, 11) beim Einsetzen des Steins (7, 13) elastisch aufgeweitet wird.8. The method according to claim 1 or 2, characterized gekenn¬ characterized in that the socket (2-9, 11) is elastically expanded when inserting the stone (7, 13).
9. Verfahren nach Anspruch 8, dadurch gekennzeichnet, dass als Modelliermasse ein handelsübliches Wachs verwendet wird.9. The method according to claim 8, characterized in that a commercially available wax is used as modeling clay.
10. Verfahren nach Anspruch 8 oder 9, dadurch gekennzeich¬ net, dass eine Auflage (6, 15) für den Stein (7, 13) erst nach dem Gießen des Modells in dieses eingeformt wird.10. The method according to claim 8 or 9, characterized gekennzeich¬ net that a support (6, 15) for the stone (7, 13) is molded into the model only after it has been cast.
11. Verfahren nach Anspruch 10, dadurch gekennzeichnet, dass die Auflage (6, 15) in das Modell eingefräst wird. 11. The method according to claim 10, characterized in that the support (6, 15) is milled into the model.
12. Verfahren nach einem der Ansprüche 8 bis 11, dadurch gekennzeichnet, dass es angewendet wird auf Krappen¬ fassungen mit mindestens 2,5 mm langen Krappen (2 bis 5) .12. The method according to any one of claims 8 to 11, characterized in that it is applied to prong settings with at least 2.5 mm long prongs (2 to 5).
13. Verfahren nach einem der Ansprüche 8 bis 11, dadurch gekennzeichnet, dass es angewendet wird auf Rund¬ fassungen (11) . 13. The method according to any one of claims 8 to 11, characterized in that it is applied to round versions (11).
EP92924652A 1991-12-05 1992-12-03 Process for producing cast and set pieces of jewellery Expired - Lifetime EP0615415B1 (en)

Applications Claiming Priority (3)

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DE4140121 1991-12-05
DE4140121A DE4140121C2 (en) 1991-12-05 1991-12-05 Process for the production of set, cast jewelry
PCT/EP1992/002792 WO1993010686A1 (en) 1991-12-05 1992-12-03 Process for producing cast and set pieces of jewellery

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AU3084592A (en) 1993-06-28
HUT67814A (en) 1995-05-29
ATE134488T1 (en) 1996-03-15
EP0615415B1 (en) 1996-02-28
DE4140121C2 (en) 1994-06-30
DE59205524D1 (en) 1996-04-04
HU9401683D0 (en) 1994-09-28
CN1078182A (en) 1993-11-10
WO1993010686A1 (en) 1993-06-10
JPH07505061A (en) 1995-06-08
CA2125152A1 (en) 1993-06-10
SK67694A3 (en) 1995-01-12
DE4140121A1 (en) 1993-06-09
FI942629A0 (en) 1994-06-03
AU674836B2 (en) 1997-01-16
FI942629A (en) 1994-06-03
CZ136794A3 (en) 1995-08-16

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