EP0605227B1 - Zusammensetzungen zum Erhöhen der adhäsiven Kraft von Silikon-Papier-Trennschicht-Beschichtungen - Google Patents

Zusammensetzungen zum Erhöhen der adhäsiven Kraft von Silikon-Papier-Trennschicht-Beschichtungen Download PDF

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Publication number
EP0605227B1
EP0605227B1 EP93310528A EP93310528A EP0605227B1 EP 0605227 B1 EP0605227 B1 EP 0605227B1 EP 93310528 A EP93310528 A EP 93310528A EP 93310528 A EP93310528 A EP 93310528A EP 0605227 B1 EP0605227 B1 EP 0605227B1
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sio
denotes
release
coating
adhesive
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French (fr)
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EP0605227A1 (de
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Leroy Elton Thayer
John Darrell Jones
Eugene David Groenhof
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Dow Silicones Corp
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Dow Corning Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating

Definitions

  • the present invention relates to coating compositions which increase the release force of pressure sensitive adhesives (PSA's) adhered thereto.
  • PSA's pressure sensitive adhesives
  • the present invention further relates to a method of release control by crosslink density (or bulk modulus) control.
  • a support material such as paper or polymeric film
  • a cured silicone release coating and a pressure sensitive adhesive coating.
  • the resulting stock is rolled into a roll configuration so that the adhesive coating is adhered to the silicone release coating over substantially its entire surface.
  • the force required to separate the adhesive from the coating should be sufficiently low to allow the easy unwinding of the roll of tape, when desired, but sufficiently high to retain the tape in a roll configuration during the preparing, storing and handling of the roll.
  • release coatings in the art employ compositions containing olefinic hydrocarbon radicals, silicon-bonded hydrogen atoms and inhibitors in a metal catalyzed reaction: U.S. Patent Nos. 4,562,096, 4,609,574, 4,774,111 and 5,036,117.
  • EP-A-0446030 discloses a release coating composition comprising first and second polydiorganosiloxanes terminated by reactive groups, a polyorganosiloxane having at least three reactive groups, and a catalyst.
  • FR-A-2450642 discloses a release coating composition comprising a polydiorganosiloxane having at least three vinyl groups, a vinyl terminated siloxane copolymer, a methylhydrogenpolysiloxane having at least three silicon-bonded hydrogen atoms, and a catalyst.
  • silicone release coatings wherein adhesive-release forces can be increased when desired and also used to maintain release stability.
  • the present invention is therefore directed to the use of siloxane polymers to increase the release force of solventless paper release coatings while maintaining stable release control.
  • the present invention comprises a curable coating composition
  • a curable coating composition comprising a polydiorganosiloxane polymer endblocked with olefinic hydrocarbon radicals, a siloxane polymer having at least three silicon-bonded unsaturated organic groups per molecule, a silicon-bonded hydrogen endblocked polysiloxane, a platinum group metal-containing catalyst and an inhibitor.
  • the curable coating composition may additionally comprise an organohydrogenpolysiloxane crosslinking agent.
  • a pressure sensitive adhesive composition is applied to the cured coating to form an adhesive/release coating interface. The force that is required to separate the adhesive from the release coating is determined by the amount and type of siloxane polymers that are employed.
  • the present invention provides a composition which increases the release force of silicone paper release coatings and comprises a curable coating composition
  • a curable coating composition comprising (A) a polydiorganosiloxane having the general formula XR 2 SiO(R 2 SiO) a SiR 2 X wherein R denotes a monovalent hydrocarbon or halohydrocarbon radical free of aliphatic unsaturation and having 1 to 20 carbon atoms, X denotes an olefinic hydrocarbon radical having from 2 to 20 carbon atoms, at least 50 percent of R being methyl, and a has an average value of 1 to 1000, (B) a siloxane polymer having at least 3 silicon-bonded unsaturated organic groups per molecule and having the general formula YR 1 2 SiO(R 1 2 SiO) b (R 1 YSiO) c SiR 1 2 Y wherein R 1 denotes a monovalent hydrocarbon or halohydrocarbon radical free of aliphatic unsaturation and
  • the composition may additionally comprise crosslinking agent selected from (R 3 3 SiO) 4 Si, (HMe 2 SiO) 4 Si, (MeHSiO) 4 , R 3 Si(OSiR 3 3 ) 3 , PhSi(OSiMe 2 H) 3 , MeSi(OSiMe 2 H) 3 , (R 3 3 SiO(Me 2 SiO) 5 ) 4 Si, (HMe 2 SiO(Me 2 SiO) 5 ) 4 Si, (R 3 3 SiO(MeHSiO) 7 (Me 2 SiO) 2 ) 4 Si, (HMe 2 SiO(MeHSiO) 7 (Me 2 SiO) 2 ) 4 Si, and an organohydrogenpolysiloxane having the general formula ZR 3 2 SiO(Me 2 SiO) x -(MeR 4 SiO) y (MeHSiO) z SiR 3 2 Z wherein R 3 denotes a monovalent hydrocarbon or halohydrocarbon radical
  • curable generally denotes a chemical change which leads to a change in the state of the composition from a liquid to an elastomer.
  • curable has a more detailed meaning which encompasses the absence of smear, migration, and rub-off of the coating, as delineated below.
  • Components (A) and (C) of the present invention act as chain extenders for the compositions of this invention.
  • chain extender as applied to the compositions of this invention, is a composition which decreases the crosslink density and modulus of a curable coating composition.
  • compositions of the present invention is accomplished by a reaction between silicon-bonded olefinic hydrocarbon radicals in Component (A) and Component (B) with the silicon-bonded hydrogen atoms in Component (C).
  • the curing of the compositions of this invention is controlled by the platinum group metal-containing catalyst Component (D), and the inhibitor Component (E).
  • Component (A) is a polydiorganosiloxane having the general formula XR 2 SiO(R 2 SiO) a SiR 2 X wherein R denotes a monovalent hydrocarbon or halohydrocarbon radical free of aliphatic unsaturation and having 1 to 20 carbon atoms, X denotes an olefinic hydrocarbon radical having from 2 to 20 carbon atoms, at least 50 percent of R being methyl, and a has an average value of 1 to 1000.
  • the value of the subscript a in the formula XR 2 SiO(R 2 SiO) a SiR 2 X is such that the polydiorganosiloxane of Component (A) has a viscosity at 25°C.
  • a has a value of from 100 to 800.
  • the monovalent radicals in Component (A) contain up to 20 carbon atoms and include halohydrocarbon radicals free of aliphatic unsaturation and hydrocarbon radicals.
  • Monovalent hydrocarbon radicals include alkyl radicals, such as methyl, ethyl, propyl, butyl, hexyl and octyl; cycloaliphatic radicals, such as cyclohexyl; aryl radicals, such as phenyl, tolyl, and xylyl; aralkyl radicals, such as benzyl and phenylethyl.
  • Highly preferred monovalent hydrocarbon radical for the silicon-containing components of this invention are methyl and phenyl.
  • component (A) has the general formula: XMe 2 SiO(Me 2 SiO) a SiMe 2 X or ViMePhSiO(Me 2 SiO) a SiPhMeVi wherein Me denotes methyl, X is a radical selected from vinyl and 5-hexenyl radicals, Vi denotes vinyl, Ph denotes phenyl and a has a value of from 100 to 800.
  • Monovalent halohydrocarbon radicals free of aliphatic unsaturation include any monovalent hydrocarbon radical noted above which is free of aliphatic unsaturation and has at least one of its hydrogen atoms replaced with a halogen, such as fluorine, chlorine, or bromine.
  • Preferred monovalent halohydrocarbon radicals have the formula C n F 2n+1 CH 2 CH 2 - wherein the subscript n has a value of from 1 to 10, such as, for example, CF 3 CH 2 CH 2 - and C 4 F 9 CH 2 CH 2 -.
  • the several R radicals can be identical or different, as desired and preferably at least 50 percent of all R radicals are methyl.
  • Polydiorganosiloxanes most useful as Component (A) in the compositions of this invention are polydiorganosiloxane polymers having a viscosity at 25°C. of at least 25 mm 2 /s (centistokes). It is preferred that the polymer has a viscosity at 25°C. of 100 to 1000 mm 2 /s (centistokes) so that the coating compositions containing the polymer can be easily applied to substrates without adding significant amounts of solvent. It is even more preferred that the polymer have a viscosity at 25°C. of 200 to 600 mm 2 /s (centistokes) so that solventless coating compositions containing the polymer will not soak into or penetrate substrates such as paper to an undesirable degree and will provide more durable cured coatings.
  • the polymers useful as component (A) in this invention are made up of diorganosiloxane units of the formula R' 2 SiO and chain terminating units of the formula R 2 'R''SiO 1/2 wherein R' denotes a methyl radical and R" denotes a hydrocarbon radical containing terminal unsaturation.
  • R' denotes a methyl radical
  • R" denotes a hydrocarbon radical containing terminal unsaturation.
  • the olefinic hydrocarbon radicals of the present invention may have from 2 to 20 carbon atoms.
  • the higher alkenyl radicals include 5-hexenyl, 6-heptenyl, 7-octenyl, 8-nonenyl, 9-decenyl and 10-undecenyl.
  • Alkenyl radicals selected from 5-hexenyl, 7-octenyl, 9-decenyl, and 5,9- decadienyl, are preferred. It is more preferred that R denote -(CH 2 ) n - so that the radicals contain only terminal unsaturation and the most preferred radicals are the vinyl radical and the 5-hexenyl radical.
  • Specific examples of preferred polydiorganosiloxanes for use as Component (A) include ViMe 2 SiO(Me 2 SiO) a SiMe 2 Vi, HexMe 2 SiO(Me 2 SiO) a SiMe 2 Hex, PhMeViSiO(Me 2 SiO) a SiPhMeVi, HexMe 2 SiO(Me 2 SiO) 130 SiMe 2 Hex, ViMePhSiO(Me 2 SiO) 145 SiPhMeVi, ViMe 2 SiO(Me 2 SiO) 299 SiMe 2 Vi, ViMe 2 SiO(Me 2 SiO) 800 SiMe 2 Vi, ViMe 2 SiO(Me 2 SiO) 300 SiMe 2 Vi and ViMe 2 SiO(Me 2 SiO) 198 SiMe 2 Vi, wherein Me, Vi, Hex and Ph denote methyl, vinyl, 5-hexenyl and phenyl, respectively, and
  • polydiorganosiloxanes of Component (A) are described as linear and to bear only hydrocarbon radicals on silicon, there can be present trace amounts of non-linear siloxane units, i.e., SiO 2 and R'SiO 3/2 , wherein R' is as described above, and trace amounts of other silicon-bonded radicals, such as hydroxyl or alkoxyl, which are normally incidental in commercial polydiorganosiloxanes.
  • the polydiorganosiloxanes of Component (A) are free of the non-linear siloxane units and the other radicals.
  • Component (B) of the compositions of this invention is a siloxane polymer having at least 3 silicon-bonded unsaturated organic groups per molecule and having the general formula YR 1 2 SiO(R 1 2 SiO) b (R 1 YSiO) c SiR 1 2 Y wherein R 1 denotes a monovalent hydrocarbon or halohydrocarbon radical free of aliphatic unsaturation and having 1 to 20 carbon atoms, Y denotes an olefinic hydrocarbon radical having from 2 to 20 carbon atoms, at least 50 percent of R 1 being methyl, b has an average value of 1 to 500, and c has an average value of 1 to 100.
  • Monovalent radicals in Component (B) include monovalent hydrocarbon and halohydrocarbon radicals free of aliphatic unsaturation as delineated above for Component (A), including preferred examples.
  • the monovalent radicals that are present in Component (B) are preferably, but need not be, the same as the monovalent radicals that are present in Component (A).
  • Olefinic hydrocarbon radicals in Component (B) include olefinic hydrocarbon radicals as delineated above for Component (A), including preferred examples.
  • the olefinic hydrocarbon radicals that are present in Component (B) are preferably, but need not be, the same as the olefinic hydrocarbon radicals that are present in Component (A).
  • the value of the subscripts b and c in the formula YR 1 2 SiO(R 1 2 SiO) b (R 1 YSiO) c SiR 1 2 Y are such that the siloxane polymer of Component (B) has a viscosity at 25°C. of at least 25 millipascal-seconds (25 centipoise).
  • b and c that is needed to provide a viscosity value meeting said limit depends on the identity of the R 1 and Y radicals.
  • b has a value of from 10 to 200
  • c has a value of from 1 to 10.
  • component (B) has the general formula: YMe 2 SiO(Me 2 SiO) b (MeYSiO) c SiMe 2 Y wherein Me denotes methyl, Y is a radical selected from vinyl and 5-hexenyl radicals, b has a value of from 100 to 200 and c has a value of 1 to 10.
  • the value of b plus c in the formula YR 1 2 SiO(R 1 2 SiO) b (R 1 YSiO) c SiR 1 2 Y is sufficient to provide a viscosity at 25°C.
  • Component (B) of at least 100 mPa ⁇ s such as from 100 mPa ⁇ s to 100 Pa ⁇ s, preferably from 100 mPa ⁇ s to 10 Pa ⁇ s, and most preferably from 50 mPa ⁇ s to 1000 mPa ⁇ s.
  • the value of subscript c is preferably limited to less than 0.1 (b).
  • siloxane polymers useful as component (B) include HexMe 2 SiO(Me 2 SiO) b (MeHexSiO) c SiMe 2 Hex, ViMe 2 SiO(Me 2 SiO) b (MeViSiO) c SiMe 2 Vi, HexMe 2 SiO(Me 2 SiO) 196 (MeHexSiO) 4 SiMe 2 Hex, HexMe 2 SiO(Me 2 SiO) 198 (MeHexSiO) 2 SiMe 2 Hex, HexMe 2 SiO(Me 2 SiO) 151 (MeHexSiO) 3 SiMe 2 Hex, and ViMe 2 SiO(Me 2 SiO) 96 (MeViSiO) 2 SiMe 2 Vi, wherein Me, Vi and Hex denote methyl, vinyl and 5-hexenyl, respectively, b has a value of from 10 to 200 and c has a
  • Component (C) is a polysiloxane having the formula HR 2 2 SiO(R 2 2 SiO) d SiR 2 2 H wherein R 2 denotes a monovalent hydrocarbon or halohydrocarbon radical free of aliphatic unsaturation and having from 1 to 20 carbon atoms, at least 50 percent of R 2 being methyl, and d has an average value of from 1 to 1000.
  • the value of the subscript d in the formula HR 2 2 SiO(R 2 2 SiO) d SiR 2 2 H is such that the polysiloxane of Component (C) has a viscosity at 25°C. of at least 5 millipascal-seconds (centipoise).
  • the exact value of d that is needed to provide a viscosity value meeting said limit depends on the identity of the R 2 radical.
  • d has a value of from 1 to 500 for the compositions of the present invention.
  • Monovalent radicals in Component (C) include monovalent hydrocarbon and halohydrocarbon radicals free of aliphatic unsaturation as delineated above for Component (A), including preferred examples.
  • the monovalent radicals that are present in Component (C) are preferably, but need not be, the same as the monovalent radicals that are present in Component (A).
  • Polysiloxanes most useful as Component (C) in the compositions of this invention are silicon-bonded hydrogen endblocked polymers having a viscosity at 25°C. of at least 25 millipascal-seconds. It is preferred that the polymers have a viscosity at 25°C. of up to 500 millipascal-seconds so that the coating compositions containing the polymer can be easily applied to substrates without adding significant amounts of solvent. It is even more preferred that the polymers have a viscosity at 25°C. of up to 100 millipascal-seconds so that solventless coating compositions containing the polymer will not soak into or penetrate substrates such as paper to an undesirable degree and will provide more durable cured coatings.
  • the polymers are made up of diorganosiloxane units of the formula R' 2 SiO and chain terminating units of the formula HR' 2 SiO 1/2 wherein R' denotes a methyl radical or other hydrocarbon radical. Generally the R' radicals in the polymers are 90 to 99.5 mole percent methyl radicals.
  • Examples of silicon-bonded hydrogen endblocked polydiorganosiloxanes which are suitable as Component (C) include HMe 2 SiO(Me 2 SiO) d SiMe 2 H, HMe 2 SiO(Me 2 SiO) 13 SiMe 2 H, HMe 2 SiO(Me 2 SiO) 15 SiMe 2 H, HMe 2 SiO(Me 2 SiO) 50 SiMe 2 H, HMe 2 SiO(Me 2 SiO) 100 SiMe 2 H, HMe 2 SiO(Me 2 SiO) 150 SiMe 2 H, HMe 2 SiO(Me 2 SiO) 200 SiMe 2 H, and HMe 2 SiO(Me 2 SiO) 400 SiMe 2 H, wherein Me denotes methyl, and d has an average value of from 1 to 1000.
  • compositions of this invention are not narrowly limited. Said amounts, expressed in terms of the ratio of the number of silicon-bonded hydrogen atoms of Component (C) to the number of silicon-bonded olefinic hydrocarbon radicals of Components (A) and (B), are sufficient to provide a value of from 1/2 to 20/1 for said ratio and, preferably, from 1/2 to 2/1.
  • the value of said ratio should have a value of from 1/2 to 2/1.
  • Component (D) is any platinum group metal-containing catalyst component which facilitates the reaction of the silicon-bonded hydrogen atoms of Components (C) with the silicon-bonded olefinic hydrocarbon radicals of Components (A) and (B).
  • platinum group it is meant herein ruthenium, rhodium, palladium, osmium, iridium and platinum.
  • Component (D) is preferably a platinum containing catalyst component since they are the most widely used and available and because they provide a more favorable effect for the compositions of this invention in terms of improved release force.
  • Platinum-containing catalysts can be a compound or complex of a platinum group metal.
  • a preferred platinum-containing catalyst component in the compositions of this invention is a form of chloroplatinic acid, either as the commonly available hexahydrate form or as the anhydrous form, as taught in U.S. Patent No. 2,823,218.
  • a particularly useful catalyst is the composition that is obtained when chloroplatinic acid is reacted with an aliphatically unsaturated organosilicon compound such as divinyltetramethyldisiloxane, as disclosed in U.S. Patent No.
  • platinum catalysts which are useful in the present invention include those disclosed in U.S. Patent Nos. 3,159,601; 3,159,602; 3,220,972; 3,296,291; 3,516,946; 3,814,730 and 3,928,629.
  • the amount of platinum group metal-containing catalyst component that is used in the compositions of this invention is sufficient to accelerate a room temperature reaction between the silicon-bonded hydrogen atoms of Component (C) with olefinic hydrocarbon radicals of Components (A) and (B) and not so much as to make its action uncontrollable by the use of Component (E) (described hereinbelow).
  • the exact amount of this catalyst component will depend on the particular catalyst utilized and is not easily predictable. However, for platinum containing catalysts the amount can be as low as one part by weight of platinum for every one million parts by weight of Component (A). Preferably the amount is 50 to 250 parts by weight of platinum for every one million parts by weight of silicone.
  • Component (E) of the compositions of this invention is any material that is known to be, or can be, used as an inhibitor for the catalytic activity of platinum group metal-containing catalysts.
  • inhibitor it is meant a material that retards the room temperature curing of a curable mixture of Components (A), (B), (C), and (D), when incorporated therein in small amounts, such as less than 10 percent by weight of the composition, without preventing the elevated curing of the mixture.
  • Inhibitors for the platinum group metal catalysts are well known in the organosilicon art.
  • Examples of various classes of such metal catalyst inhibitors include unsaturated organic compounds such as ethylenically or aromatically unsaturated amides, U.S. Patent No. 4,337,332; acetylenic compounds, U.S. Patent Nos. 3,445,420 and 4,347,346; ethylenically unsaturated isocyanates, U.S. Patent No. 3,882,083; olefinic siloxanes, U.S. Patent No. 3,989,667; unsaturated hydrocarbon diesters, U.S. Patent Nos.
  • compositions of this invention can comprise an inhibitor from any of these classes of inhibitors.
  • Organic inhibitor compounds which bear aliphatic unsaturation and one or more polar groups, such as carbonyl or alcohol groups, display useful bath life extension benefits.
  • Examples thereof include the acetylenic alcohols of U.S. Patent No. 3,445,420, such as ethynylcyclohexanol and methylbutynol; the unsaturated carboxylic esters of U.S. Patent No. 4,256,870, such as diallyl maleate and dimethyl maleate; and the maleates and fumarates of U.S. Patent Nos. 4,562,096 and 4,774,111, such as diethyl fumarate, diallyl fumarate and bis-(methoxyisopropyl) maleate.
  • R 5 can be, for example, an alkyl radical such as methyl, ethyl, propyl, isopropyl, butyl, pentyl, or hexyl; an aryl radical such as phenyl or benzyl; an alkenyl radical such as vinyl or allyl; alkynyl radicals; or a cyclohydrocarbon radical such as cyclohexyl.
  • Q can be for example, -CH 2 CH 2 -, -CH 2 (CH 3 )CH-, -CH 2 CH 2 CH 2 -, -CH 2 CH 2 CH 2 CH 2 -, -CH 2 (CH 3 CH 2 )CH- and -CH 2 CH 2 (CH 3 )CH-.
  • the individual R 5 radicals and Q radicals of the maleates and fumarates can be identical or different, as desired.
  • the value of subscript t in the formula immediately above can have value equal to zero or 1.
  • the individual values of t can be identical or different, as desired.
  • the amount of Component (E) is not critical and can be any amount that will retard the above described catalyzed reaction at room temperature while not preventing said reaction at elevated temperature. No specific amount of inhibitor can be suggested to obtain a specified bath life at room temperature since the desired amount of any particular inhibitor to be used will depend upon the concentration and type of the platinum group metal containing catalyst, the nature and amounts of Components (A), (B) and (C) and the presence or absence of optional ingredients. A practical range appears to be 0.5 to 1.05 percent of the total formulation for a maleate inhibitor and 0.8 to 2.0 percent of the total formulation for a fumarate inhibitor. Greater amounts of maleates and fumarates can be used if desired; however, drifting or long cure times may result.
  • compositions of the present invention can additionally comprise a bath life extender composition such as those described in U.S. Patent No. 5,036,117.
  • a preferred bath life extender compound for the present invention is benzyl alcohol or n-octanol. Highly preferred for the present invention is a combination of diethyl fumarate as the inhibitor complexed with benzyl alcohol as the bath life extender.
  • the olefinic polydiorganosiloxane of Components (A) and (B), and the silicon-bonded hydrogen endblocked polysiloxane of Component (C), are mixed in the coating compositions of this invention in amounts that will provide a composition containing 0.8 to 1.5 silicon-bonded hydrogen radicals for every unsaturated radical in the composition.
  • compositions of this invention can optionally comprise an organohydrogenpolysiloxane crosslinking agent, compatible with components (A) and (B) and the organohydrogenpolysiloxane crosslinking agent, being selected from the group consisting of (R 3 3 SiO) 4 Si, (HMe 2 SiO) 4 Si, (MeHSiO) 4 , R 3 Si(OSiR 3 3 ) 3 , PhSi(OSiMe 2 H) 3 , MeSi(OSiMe 2 H) 3 , (R 3 3 SiO(Me 2 SiO) 5 ) 4 Si, (HMe 2 SiO(Me 2 SiO) 5 ) 4 Si, (R 3 3 SiO(MeHSiO) 7 (Me 2 SiO) 2 ) 4 Si, (HMe 2 SiO(MeHSiO) 7 (Me 2 SiO) 2 ) 4 Si, and an organohydrogenpolysiloxane having the general formula ZR 3 2 SiO(Me 2 Si
  • Monovalent radicals in the organohydrogenpolysiloxane crosslinking agent include monovalent hydrocarbon and halohydrocarbon radicals free of aliphatic unsaturation as delineated above for Component (A), including preferred examples.
  • the monovalent radicals that are present in the organohydrogenpolysiloxane crosslinking agent are preferably, but need not be, the same as the monovalent radicals that are present in Component (A).
  • Olefinic hydrocarbon radicals in the organohydrogenpolysiloxane crosslinking agent include olefinic hydrocarbon radicals as delineated above for Component (A), including preferred examples.
  • the olefinic hydrocarbon radicals that are present in the organohydrogenpolysiloxane crosslinking agent are preferably, but need not be, the same as the olefinic hydrocarbon radicals that are present in Component (A).
  • crosslinking agent is an organohydrogensiloxane crosslinking agent having the formula Me 3 SiO(MeHSiO) e SiMe 3 wherein e has an average value of from 3 to 100.
  • Organohydrogenpolysiloxane operates as a curing agent for the polydiorganosiloxanes of Components (A) and (B) in the coating composition and therefore must be soluble therein. It is preferable that all silicon atoms therein which bear the hydrogen radicals also bear at least one methyl radical.
  • the organohydrogenpolysiloxane crosslinking agent may also contain silicon-bonded phenyl radicals and alkyl radicals having from 2 to 6 carbon atoms, provided that it is soluble in Component (A).
  • organohydrogen-siloxanes that are suitable in this invention include (HMe 2 SiO) 4 Si, cyclo-(MeHSiO) y , (MeHSiO) 4 , PhSi(OSiMe 2 H) 3 , (HMe 2 SiO(Me 2 SiO) 5 ) 4 Si, (CF 3 CH 2 CH 2 )MeHSiO(Me(CF 3 CH 2 CH 2 )SiO) y SiHMe(CH 2 CH 2 CF 3 ), Me 3 SiO(MeHSiO) y SiMe 3 , HMe 2 SiO(Me 2 SiO) 0.5y (MeHSiO) 0.5y SiMe 2 H, HMe 2 SiO(Me 2 SiO) 0.5y (MePhSiO) 0.1y (MeHSiO) 0.4y SiMe 2 H, Me 3 SiO(Me 2 SiO) 0.3y (MeHSiO) 0.7y SiM
  • the organohydrogenpolysiloxane has a viscosity at 25°C. of from 5 to 100 millipascal-seconds.
  • the exact value of y needed to provide a viscosity value within said limits depends upon the number and identity of the organic radicals.
  • the higher molecular weight organohydrogenpolysiloxanes are preferred as the curing component for silicone release coating compositions because the higher molecular weight organohydrogenpolysiloxanes have a low volatility and will remain with and more effectively cure silicone release compositions at elevated temperatures.
  • Organosilicon polymers are, of course, well known in the organosilicon art. Their preparation is well documented and needs no intensive delineation herein. Organopolysiloxanes are clearly the most significant and most widely used form of organosilicon polymers in the art and in this invention; many are commercially prepared.
  • compositions of the present invention can contain any optional components commonly used in platinum group metal catalyzed organosilicon compositions, colorants, stabilizers, adhesion modifiers, and adhesive-release modifiers.
  • coating compositions of this invention which have adhesive-releasing properties can further comprise the well-known high release additives of the art.
  • compositions of this invention can be prepared by homogeneously mixing Components (A), (B), (C), (D), and (E), and any optional components in any order, using any suitable mixing means, such as a spatula, a drum roller, a mechanical stirrer, a three-roll mill, a sigma blade mixer, a bread dough mixer, and a two-roll mill.
  • any suitable mixing means such as a spatula, a drum roller, a mechanical stirrer, a three-roll mill, a sigma blade mixer, a bread dough mixer, and a two-roll mill.
  • the order of mixing Components (A) to (E) and any optional components is not critical, however, it is highly preferred that Component (B) be brought together in the presence of Components (A) and (C), most preferably in a preliminary mixing step. It is highly preferred to admix Component (B) to (A) and/or (C), followed by adding (D), and finally (E).
  • compositions of this invention have utility as formable compositions to provide organosilicon articles such as O-rings, tubing, wire-coating, gaskets, encapsulant and sealant compositions, and as coating compositions.
  • compositions of the present invention have particular utility as paper release coatings.
  • the present invention relates to a process for preparing a laminate of a substrate and an adhesive wherein the adhesive will release from the substrate, the process comprising the steps of: (I) coating a curable silicone release composition on the surface of the substrate wherein the composition comprises: (A) a polydiorganosiloxane having the general formula XR 2 SiO(R 2 SiO) a SiR 2 X wherein R denotes a monovalent hydrocarbon or halohydrocarbon radical free of aliphatic unsaturation and having 1 to 20 carbon atoms, X denotes an olefinic hydrocarbon radical having from 2 to 20 carbon atoms, at least 50 percent of R being methyl, and a has an average value of 1 to 1000, (B) a siloxane polymer having at least 3 silicon-bonded unsaturated organic groups per molecule and having the general formula YR 1 2 SiO(R 1 2 SiO) b (R 1 YSiO) c SiR 1 2 Y where
  • the curable silicone release composition is a composition of this invention comprising Components (A), (B), (C), (D), and (E) which are delineated above, including preferred embodiments thereof.
  • the composition in the process of this invention can optionally comprise an organohydrogensiloxane crosslinking agent, and a bath life extender, both of which are delineated above, including preferred embodiments thereof.
  • the amounts of Components (A), (B), (C), (D), (E), organohydrogensiloxane crosslinker, and bath life extender that used in the curable compositions of the process of this invention are also stated above.
  • actinic radiation it is meant ultraviolet light; electron beam radiation; and alpha-, beta-, gamma- and x-rays.
  • heat it is meant infrared radiation, hot-air and microwave radiation.
  • actinic radiation is frequently accompanied by heat.
  • the coating process can be accomplished by any suitable manner known in the art, such as by spreading, brushing, extruding, spraying, off-set gravure, kiss-roll, air-knife, or by the use of multi-roll coaters.
  • the substrate is a flexible sheet material such as paper, polyolefin film and polyolefin-coated paper or foil.
  • suitable substrates that can be coated by the process of this invention include other cellulosic materials such as wood, cardboard and cotton; metallic materials such as aluminum, copper, steel and silver; siliceous materials such as glass and stone; and synthetic polymer materials such as polyolefins, polyamides, polyesters and polyacrylates.
  • the substrate can be substantially sheet-like, such as a peelable release liner for pressure sensitive adhesive; a fabric or a foil; or substantially three-dimensional in form.
  • liquid curable composition After the liquid curable composition has been coated onto a substrate it may be heated and/or irradiated with actinic radiation, as noted herein, to cure the liquid coating and to adhere it to the substrate.
  • a flexible sheet material such as paper, metal foil or tapestock
  • a thin coating of the liquid curable composition preferably in a continuous manner and the thus-coated material is then heated and/or irradiated to rapidly cure the coating, to provide a sheetlike material bearing on at least one surface thereof an adhesive-releasing coating.
  • the adhesive-releasing coating is subsequently brought into contact with a pressure sensitive adhesive, optionally in an in-line manner, to form an article having a peelable, i.e. releasable, adhesive/coating interface.
  • a pressure sensitive adhesive can be non-silicone-based, such as the well-known acrylic or rubber types or silicone-based.
  • compositions of this invention are also applicable to adhesive materials, other than pressure sensitive adhesives.
  • adhesive materials include foods, asphalt and gum polymers.
  • Cure time for a composition means the time interval required for the composition, when coated onto S2S kraft paper, at a thickness of 454 g (1 pound) per 480 sheets (ream), to attain the no smear, no migration, no rub-off condition (NNN).
  • the no smear condition was determined by lightly streaking the coating with a finger and observing for the absence of haze in the streaked area.
  • the no migration condition was determined by firmly adhering a common, pressure sensitive adhesive tape to the coating, removing the tape and folding the removed tape together, adhesive surfaces to each other. Absence of migration of the coating to the tape was indicated by noting that the doubled tape was as difficult to separate as unused tape so doubled.
  • the no rub-off condition was determined by vigorously rubbing the coating with the index finger and noting that the coating could not be removed from the paper.
  • the following formulations were prepared and the cure time was measured at 93.3°C., 115.6°C., 148.9°C. and 176.7°C. (200°F., 240°F., 300°F. and 350°F).
  • the formulations were cured to NNN (No smear, No migration, No rub-off).
  • Sheets were coated with a composition of the present invention, and then were aged 1 day and 1 week before they were laminated with acrylic (GMS-263; Monsanto, St. Louis, MO. and SBR 36-6045; National Starch) adhesives.
  • the laminates were also aged 1 week at room temperature before their lease values were observed. The release values were observed at 10.2 m/min. (400 in./min.).
  • the cure time of the freshly prepared composition is reported in Table II below.
  • the physical state of the composition is also described in Table II.
  • Chain Extender B is a vinyl-endblocked polydimethylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 145 SiMe 2 Vi wherein Me,and Vi, denote methyl, and vinyl, respectively.
  • Chain Extender D is a silicon-bonded hydrogen endblocked polydiorganosiloxane having the average formula HMe 2 SiO(Me 2 SiO) 100 SiMe 2 H.
  • Polymer E is an organohydrogenpolysiloxane polymer having the average formula ⁇ HMe 2 SiO(Me 2 SiO) 5 ⁇ 4 Si. This polymer is specifically designed to lower crosslink density and is not the typical type of organohydrogenpolysiloxane polymer which is normally employed as a crosslinking agent.
  • the freshly prepared compositions were coated onto 24.5 kg (54 pound) paper and samples of the coated paper were heated at 82.2°C., 115.6°C. or 148.9°C. (180°, 240° or 300°F.) for various lengths of time and the thus cured coatings were laminated, in-line, with an acrylic adhesive (GMS-263; Monsanto, St. Louis, MO. or with SBR 36-6045; National Starch).
  • the adhesive solution was applied to the coatings at a wet thickness of 0.075 mm (3 mils) using a drawdown bar.
  • the applied adhesive was air-dried at room temperature for one minute, heated at 70°C. for one minute and cooled to room temperature for one minute.
  • a sheet of 27.2 kg (60 pound) matte litho was applied to the dried adhesive and the resulting laminates were pressed with a 2.04 kg. (4.5 pound) rubber-coated roller.
  • the test laminates were then aged at room temperature for 1 day and cut into 2.54 cm (1-inch) strips.
  • Adhesive release testing was done by pulling the substrate/coating from the matte/adhesive of the 2.54 cm (1-inch) strips at an angle of 180 degrees and at a rate of 10 meters per minute. The force needed to separate the adhesive/coating interface was noted several times during the separation and adhesive release was noted as an average of the several readings.
  • compositions of this invention provide higher release values in an in-line process of adhesive lamination than those of the prior art.
  • the compositions of the present invention produced release values ranging from 19.7 to 68.9 g/cm (50 to 175 g/in) against an acrylic adhesive.
  • compositions containing a vinyl or hexenyl endblocked polydimethylsiloxane alone produced release values of from 19.7 to 33.5 g/cm (50 to 85 g/in) against the acrylic adhesive.
  • the hard brittle films gave very low release values, and as the films became softer and more elastic the release values increased. Thus release forces with stable release both in terms of coated paper aging and of laminate aging have been achieved.
  • the following formulations were prepared and the cure time was measured at 121.1°C., 148.9°C. and 176.7°C. (250°F., 300°F. and 350°F).
  • the formulations were cured to no migration.
  • the sheets were coated with a composition of the present invention, and then were aged 1 day before they were laminated with acrylic (GMS-263; Monsanto, St. Louis, MO and SBR 36-6045; National Starch) adhesives.
  • the laminates were also aged 1 day at room temperature before the release values were observed. The release values were observed at 10.2 m/min (400 in./min.).
  • films 2-5 mm thick were cast in aluminum dishes to examine the physical nature.
  • the SiH to SiVi ratios for the compositions in Examples 7-13 were all one to one (i.e. one silicon bonded hydrogen radical exists for every silicon bonded vinyl radical).
  • the cure time of the freshly prepared composition is reported in Table V below.
  • the physical state of the composition is also described in Table V.
  • Chain Extender B is a vinyl-endblocked polydimethylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 145 SiMe 2 Vi wherein Me, Vi, and Ph denote methyl, vinyl, and phenyl, respectively.
  • Polymer C is an organohydrogenpolysiloxane polymer having the average formula ⁇ HMe 2 SiO(MeHSiO) 7 (Me 2 SiO) 2 ⁇ 4 Si.
  • Chain Extender D is a silicon-bonded hydrogen endblocked polydiorganosiloxane having the average formula HMe 2 SiO(Me 2 SiO) 100 SiMe 2 H.
  • Chain Extender E is a silicon-bonded hydrogen endblocked polydiorganosiloxane having the average formula HMe 2 SiO(Me 2 SiO) 400 SiMe 2 H. CHAIN EXTENDER POLYMER CATALYST INHIBITOR Ex.
  • compositions of this invention provide higher release values in an in-line process of adhesive lamination than those of the prior art.
  • the compositions of the present invention produced release values ranging from 24.8 to 61.0 g/cm (63 to 155 g/in) against an acrylic adhesive.
  • compositions containing a vinyl or hexenyl endblocked polydimethylsiloxane alone i.e. those samples without a silicon-bonded hydrogen endblocked polydiorganosiloxane chain extender
  • the following formulations were prepared, coated on S2S kraft paper. The formulations were cured to no migration. The sheets were coated with a composition of the present invention, and then were aged 24 hours before they were laminated with an acrylic adhesive. The release values were observed at 10.2 m/min (400 in./min.).
  • an amount (g) of polydiorganosiloxane chain extender B, C, D or E noted in Table VII and also described hereinbelow
  • an amount (g) of a platinum catalyst a soluble platinum complex containing 0.67% platinum formed from chloroplatinic
  • Chain Extender B is a vinyl-endblocked polydimethylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 299 SiMe 2 Vi wherein Me,and Vi, denote methyl, and vinyl, respectively.
  • Chain Extender E is an silicon-bonded hydrogen endblocked polydiorganosiloxane having the average formula HMe 2 SiO(Me 2 SiO) 100 SiMe 2 H.
  • EX. POLYMER A CHAIN EXTENDER CATALYST INHIBITOR (g) Ident amt(g) (g) (g) 13 36.50 C 12.10 1.95 1.10 E 51.90 14 31.50 C 10.50 1.95 1.10 E 58.00 15 36.40 B 12.10 1.95 1.10 E 51.50 16 31.50 B 10.50 1.95 1.10 E 58.00 17 36.50 C 12.10 1.95 0.83 E 51.90 18 36.50 C 12.10 1.95 0.55 E 51.90 19 36.50 C 12.10 1.95 0.28 E 51.90 20 36.90 D 12.30 1.95 1.10 E 50.20
  • the adhesive release forces were determined for the compositions according to the procedures described in Examples 1-6 hereinabove except that the samples of the coated paper were heated at 93.3°C., 121.1°C., 148.9°C. and 176.7°C. (200°F., 250°F., 300°F. and 350°F.) for various lengths of time prior to the cured coatings being laminated. Also the cured coatings were laminated with an acrylic adhesive (GMS-263; Monsanto, St. Louis, MO.).
  • compositions of this invention consistently provided higher release values in an in-line process of adhesive lamination than did the compositions without the above described chain extenders.
  • the compositions of the present invention produced release values ranging from 43.3 to 59.1 g/cm (110 to 150 g/in) against an acrylic adhesive and had a stable release profile.
  • the hard brittle films gave very low release values, and as the films became softer and more elastic the release values increased.
  • release forces with stable release both in terms of coated paper aging and of laminate aging have been achieved.
  • the coating had been aged for 1 day at room temperature.
  • ADHESIVE RELEASE FORCE OF LAMINATES ADHESIVE RELEASE (g/cm) TEMP.
  • the following formulations were prepared, coated on Nicolet paper.
  • the formulations were cured to no migration at 93.3°C. and 204.4°C. (200°F and 400°F).
  • the sheets were coated with a composition of the present invention, and then were aged 24 hours before they were laminated with an acrylic adhesive.
  • the laminates were then aged for 7 days.
  • the release values were observed at various speeds.
  • the coatings were also cured with various times at 93.3°C. (200°F.) and immediately laminated. The release values were then observed 1 day later.
  • a platinum catalyst a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane
  • an inhibitor bis(2-methoxyisopropyl) maleate
  • Chain Extender B is an silicon-bonded hydrogen endblocked polydiorganosiloxane having the average formula HMe 2 SiO(Me 2 SiO) 100 SiMe 2 H.
  • Polymer D is an organohydrogenpolysiloxane polymer having the average formula Me 3 SiO(MeHSiO) 13 SiMe 3 .
  • the freshly prepared compositions were coated onto 24.5 kg. (54 pound) paper and samples of the coated paper were heated at 93.3°C., 121.1°C., 148.9°C. and 176.7°C. (200°F., 250°F., 300°F. and 350°F.) for various lengths of time and then aged for 1 day.
  • the thus cured coatings were laminated, in-line, with an acrylic adhesive (GMS-263; Monsanto, St.Louis, MO.).
  • the adhesive solution was applied to the coatings at a wet thickness of 0.075 mm (3 mils) using a drawdown bar.
  • the applied adhesive was air-dried at room temperature for one minute, heated at 70°C. for one minute and then cooled to room temperature for one minute.
  • a sheet of 27.2 kg (60 pound) matte litho was applied to the dried adhesive and the resulting laminates were pressed with a 2.04 kg (4.5 pound) rubber-coated roller.
  • the test laminates were then aged at room temperature for 7 days and cut into 2.54 cm (1-inch) strips.
  • a second test was also run wherein the cured coatings were laminated immediately after curing and these laminates were then aged at room temperature for 1 day.
  • Adhesive release testing was done by pulling the substrate/coating from the matte/adhesive of the 2.54 cm (1-inch) strips at an angle of 180 degrees and at a rate of 10 meters per minute. The force needed to separate the adhesive/coating interface was noted several times during the separation and adhesive release was noted as an average of the several readings.
  • the compositions of the present invention produced release values ranging from two to three times greater than compositions without chain extenders against an acrylic adhesive.
  • the hard brittle films gave very low release values, and as the films became softer and more elastic the release values increased. Thus release forces with stable release both in terms of coated paper aging and of laminate aging have been achieved.
  • Example 22 CURE TEMP 93.3°C. 204.4°C. 93.3°C. 240.4°C.
  • the following formulations were prepared, and coated on 16.8 Kg (37 pound) Nicolet ( TM ) paper.
  • the formulations were cured to no migration at 93.3°C., 121.1°C., 148.9°C, 176.7°C and 204.4°C. (200°F., 250°F., 300°F., 350°F. and 400°F).
  • the sheets were coated with a composition of the present invention, and then were aged various amounts of time before they were laminated with an acrylic adhesive. The laminates were then aged. The release values were observed at 10.2 m/min (400 in./min.).
  • a platinum catalyst a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane
  • Chain Extender C is an silicon-bonded hydrogen endblocked polydiorganosiloxane having the average formula HMe 2 SiO(Me 2 SiO) 100 SiMe 2 H.
  • Polymer E is an organohydrogenpolysiloxane polymer having the average formula Me 3 SiO(MeHSiO) 13 SiMe 3 .
  • EX. COATING A/POLYMER B (g) CHAIN EXTENDER CATALYST INHIBITOR POLYMER E Ident amt(g) (g) (g) 23 A 100.00 ---------- ---- ---- 3.50 24 B 36.50 C 51.90 1.95 0.83 D 12.10 ⁇
  • the thus cured coatings were laminated, in-line, with an acrylic adhesive (GMS-263; Monsanto, St.Louis, MO.). The adhesive solution was applied to the coatings at a wet thickness of 0.075 mm (3 mils) using a drawdown bar.
  • the applied adhesive was air-dried at room temperature for one minute, heated at 70°C. for one minute and cooled to room temperature for one minute.
  • a sheet of 27.2 kg (60 pound) matte litho was applied to the dried adhesive and the resulting laminates were pressed with a 2.04 kg (4.5 pound) rubber-coated roller.
  • the test laminates were then aged for various amounts of time and cut into 2.54 cm (1-inch) strips.
  • Adhesive release testing was done by pulling the substrate/coating from the matte/adhesive of the 2.54 cm (1-inch) strips at an angle of 180 degrees and at a rate of 10 meters per minute. The force needed to separate the adhesive/coating interface was noted several times during the separation and adhesive release was noted as an average of the several readings.
  • the release values show that the compositions of this invention provided consistently high release values while maintaining stable release profiles in the in-line process of adhesive lamination.
  • the compositions of the present invention produced release values ranging from two to three times greater than compositions without chain extenders against an acrylic adhesive.
  • the hard brittle films gave very low release values, and as the films became softer and more elastic the release values increased. Thus release forces with stable release both in terms of coated paper aging and of laminate aging have been achieved.
  • curable coating compositions were prepared by mixing, an amount of: a chain extender A, B, or C noted in Table XIV and described hereinbelow, in 100 parts of Coating D described hereinbelow; and adding an amount of an organohydrogenpolysiloxane crosslinker E, noted in Table XIV and also described hereinbelow.
  • the SiH to Vinyl ratio in each of the curable compositions is reported in Table XIV.
  • Strips of 2.54 cm (1 inch) were cut from the laminates and tested for release force by pulling the liner from the label at 180° using a Finat High Speed Release tester at 1, 10, 100, and 300 meters per minute (M/min). The results are shown as the average of two tests from the same laminate.
  • Chain Extender A is a vinyl-endblocked polydimethylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 800 SiMe 2 Vi wherein Me denotes methyl and Vi denotes vinyl.
  • Chain Extender B is a vinyl-endblocked polydimethylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 300 SiMe 2 Vi wherein Me denotes methyl and Vi denotes vinyl.
  • Chain Extender C is an silicon-bonded hydrogen-endblocked polydimethylsiloxane having the average formula HMe 2 SiO(Me 2 SiO) 15 SiMe 2 H wherein Me denotes methyl.
  • Coating D is a blend of 97 parts by weight of vinyl-endblocked polydimethyl-co-methylvinylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 96 (MeViSiO) 2 SiMe 2 Vi wherein Me denotes methyl and Vi denotes vinyl, 2 parts of a platinum catalyst (a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane), and 1 part of bis(2-methoxyisopropyl) maleate inhibitor, all parts being based on the total weight of the blend.
  • a platinum catalyst a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane
  • bis(2-methoxyisopropyl) maleate inhibitor all parts being based on the total weight of the blend.
  • Crosslinker E is an organohydrogenpolysiloxane crosslinker having the average formula Me 3 SiO(MeHSiO) 13 SiMe 3. COMPOSITIONS OF Comparative Examples 25-28, and EXAMPLES 29-32 PARTS PER 100 PARTS OF COATING D CHAIN EXTENDER Ex.
  • a B C COATING D CROSSLINKER E SiH/Vi ratio 25 - - - 100 3.25 1.1 26 - - 20 100 0.985 1.1 27 25 - - 100 3.31 1.1 28 - 25 - 100 3.43 1.1 29 25 - 20 100 1.05 1.1 30 13.1 - 16.9 100 1.34 1.0 31 73 - 23.5 100 0.65 0.9 32 - 25 20 100 1.17 1.1
  • Table XV shows the results of mixing a vinyl-endblocked chain extender and silicon-bonded hydrogen endblocked chain extender with a crosslinker in a coating formulation.
  • the release forces at 10 M/min. and above are much higher and the cure time is shortened for the compositions of the present invention. None of the references of the art disclose the unexpected result produced by the compositions of this invention.
  • curable coating compositions were prepared this time by mixing, in the order given, an amount (g) of: a chain extender A, or B, noted in Table XVI and described hereinbelow; an amount of a high release additive F, noted in Table XVI and described hereinbelow; 100 parts of coating D described hereinbelow; an amount of chain extender C noted in Table XVI and described hereinbelow; and an amount of an organohydrogenpolysiloxane crosslinker E, noted in Table XVI and also described hereinbelow.
  • the coating compositions were prepared by first mixing the vinyl-ended chain extender (A or B) and the high release additive (F) to coating D in parts by weight, stirring until uniform and then adding the SiH-ended chain extender C and then adding organohydrogenpolysiloxane crosslinker E.
  • the SiH to Vinyl ratio in each of the curable compositions is also reported in Table XVI.
  • Strips of 2.54 cm (1 inch) were cut from the laminates and tested for release force by pulling the liner from the label at 180° using a Finat High Speed Release tester at 1, 10, 100, and 300 meters per minute (M/min). The results are shown as the average of two tests from the same laminate.
  • Chain Extender A is a vinyl-endblocked polydimethylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 800 SiMe 2 Vi wherein Me denotes methyl and Vi denotes vinyl.
  • Chain Extender B is 98 parts of a vinyl-endblocked polydimethylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 800 SiMe 2 Vi wherein Me denotes methyl and Vi denotes vinyl, and 2 parts of a platinum catalyst (a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane), all parts being based on the total weight of the blend.
  • a platinum catalyst a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane
  • Chain Extender C is a silicon-bonded hydrogen-endblocked polydimethylsiloxane having the average formula HMe 2 SiO(Me 2 SiO) 15 SiMe 2 H and a viscosity of 11 mm 2 /s (centistokes) wherein Me denotes methyl.
  • Coating D is a blend of 97 parts by weight of vinyl-endblocked polydimethyl-co-methylvinylsiloxane having the average formula ViMe 2 SiO(Me 2 SiO) 96 (MeViSiO) 2 SiMe 2 Vi wherein Me denotes methyl and Vi denotes vinyl, 2 parts of a platinum catalyst (a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane), and 1 part of bis(2-methoxyisopropyl) maleate inhibitor, all parts being based on the total weight of the blend.
  • a platinum catalyst a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane
  • bis(2-methoxyisopropyl) maleate inhibitor all parts being based on the total weight of the blend.
  • Crosslinker E is an organohydrogenpolysiloxane crosslinker having the average formula Me 3 SiO(MeHSiO) 47 SiMe 3 .
  • High Release Additive (HRA) F is a blend of 97 parts of a compound comprising 46 percent by weight of a vinyl capped silicone resin dispersed in 54 percent by weight of a vinyl functional polymer, the compound having a viscosity of 8500 mPa ⁇ s (centipoise), 2 parts of a platinum catalyst (a soluble platinum complex containing 0.67% platinum formed from chloroplatinic acid and divinyltetramethyldisiloxane), and 1 part of bis(2-methoxyisopropyl) maleate inhibitor, all parts being based on the total weight of the blend.
  • Table XVII shows that in release coatings of Coating D containing 20 parts of the high release additive (HRA F) and crosslinked with Crosslinker E the combination of silicon-bonded hydrogen endblocked chain extender C and vinyl endblocked chain extender A increases the release force at release speeds of 10M/min. or higher and has an acceptable cure time in contrast to compositions having only the Coating D, Crosslinker E, and HRA F, or even those compositions which have D, E, and F cited hereinabove and a silicon-bonded hydrogen-endblocked chain extender.
  • HRA F high release additive
  • Table XVII shows that a combination of a vinyl endblocked chain extender B and a silicon-bonded hydrogen endblocked chain extender C significantly increased the release force at 10 M/min. and higher release speeds when used with Coating D and HRA F. Those compositions containing only Coating D, Crosslinker E, or compositions containing D, E, and HRA F also do not provide the advantageous release speeds as compared to the compositions of the present invention. Table XVII further shows that the compositions of the present invention while providing a high release force at elevated delamination speeds also maintain an acceptable cure time.
  • Examples 33-39 The procedure employed in Examples 33-39 was repeated except that two different silicon-bonded hydrogen-ended chain extenders (C1 and C2) were compared to the silicon-bonded hydrogen-endblocked chain extender C tested in Comparative Examples 33-34 and 36-37, and Examples 35,38-39 and described hereinabove. Also the crosslinker utilized is the same crosslinker that was employed in Comparative Examples 25-28, and Examples 29-32. The crosslinker used and the three different SiH endblocked polymers are described below. All other-components are the same as those described in Comparative Examples 33-34 and 36-37, and Examples 35,38-39.
  • Chain Extender C is a silicon-bonded hydrogen-endblocked polydimethylsiloxane having the average formula HMe 2 SiO(Me 2 SiO) 15 SiMe 2 H.
  • Chain Extender C1 is a silicon-bonded hydrogen-endblocked polydimethylsiloxane having the average formula HMe 2 SiO(Me 2 SiO) 50 SiMe 2 H.
  • Chain Extender C2 is a silicon-bonded hydrogen-endblocked polydimethylsiloxane having the average formula HMe 2 SiO(Me 2 SiO) 150 SiMe 2 H.
  • Crosslinker E is an organohydrogenpolysiloxane crosslinker having the average formula Me 3 SiO(MeHSiO) 13 SiMe 3 .
  • Table XIX shows that higher molecular weight silicon-bonded hydrogen-endblocked polydiorganosiloxanes (chain extender C1 has a degree of polymerization (DP) of 50 and chain extender C2 has a DP of 150), also provide higher release values at high delamination speeds.

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Claims (11)

  1. Härtbare Beschichtungszusammensetzung, enthaltend:
    (A) ein Polydiorganosiloxan mit der allgemeinen Formel XR2SiO(R2SiO)aSiR2X, worin R für einen einbindigen Kohlenwasserstoff- oder Halogenkohlenwasserstoffrest steht, der frei von aliphatischen Ungesättigtheiten ist und 1 bis 20 Kohlenstoffatome aufweist, X für einen olefinischen Kohlenwasserstoffrest mit 2 bis 20 Kohlenstoffatomen steht, wenigstens 50 % von R Methyl sind und a einen Mittelwert von 1 bis 1000 aufweist,
    (B) ein Siloxanpolymer mit wenigstens 3 an Silicium gebundenen ungesättigten organischen Gruppen pro Molekül und mit der allgemeinen Formel: YR1 2SiO(R1 2SiO)b(R1YSiO)cSiR1 2Y, worin R1 für einen einbindigen Kohlenwasserstoff- oder Halogenkohlenwasserstoffrest steht, der frei von aliphatischen Ungesättigtheiten ist und 1 bis 20 Kohlenstoffatome aufweist, Y für einen olefinischen Kohlenwasserstoffrest mit 2 bis 20 Kohlenstoffatomen steht, wenigstens 50 % von R1 Methyl sind, b einen Mittelwert von 1 bis 500 aufweist und c einen Mittelwert von 1 bis 100 aufweist,
    (C) ein Polysiloxan mit der allgemeinen Formel HR2 2SiO(R2 2SiO)dSiR2 2H, worin R2 für einen einbindigen Kohlenwasserstoff- oder Halogenkohlenwasserstoffrest steht, der frei von aliphatischen Ungesättigtheiten ist und 1 bis 20 Kohlenstoffatome aufweist, wenigstens 50 % von R2 Methyl sind und d einen Mittelwert von 1 bis 1000 aufweist,
    (D) einen Katalysator, der ein Metall der Platingruppe enthält, und
    (E) eine Inhibitorverbindung.
  2. Zusammensetzung nach Anspruch 1, wobei die Zusammensetzung zusätzlich ein Organohydrogenpolysiloxanvernetzungsmittel, ausgewählt aus (R3 3SiO)4Si, (HMe2SiO)4Si, (MeHSiO)4, R3Si(OSiR3 3)3, PhSi(OSiMe2H)3, MeSi(OSiMe2H)3, (R3 3SiO(Me2SiO)5)4Si, (HMe2SiO(Me2SiO)5)4Si, (R3 3SiO(MeHSiO)7(Me2SiO)2)4Si, (HMe2SiO(MeHSiO)7(Me2SiO)2)4Si, und ein Organohydrogenpolysiloxan mit der allgemeinen Formel: ZR3 2SiO(Me2SiO)x(MeR4SiO)y(MeHSiO)zSiR3 2Z enthält, worin R3 für einen einbindigen Kohlenwasserstoff- oder Halogenkohlenwasserstoffrest steht, der frei von aliphatischen Ungesättigtheiten ist und 1 bis 20 Kohlenstoffatome aufweist, Z für ein Wasserstoffatom oder einen R3-Rest steht, wobei wenigstens 50 % von R3 Methyl sind, R4 für einen einbindigen Kohlenwasserstoff- oder Halogenkohlenwasserstoffrest steht, der frei von aliphatischen Ungesättigtheiten ist und 1 bis 20 Kohlenstoffatome aufweist, x einen Mittelwert von 0 bis 500 aufweist, y einen Mittelwert von 0 bis 500 aufweist und z einen Mittelwert von 1 bis 100 aufweist.
  3. Zusammensetzung nach Anspruch 1, wobei Komponente (A) die allgemeine Formel: XMe2SiO(Me2SiO)aSiMe2X oder ViMePhSiO(Me2SiO)aSiPhMeVi aufweist, worin Me für Methyl steht, X ein Rest ist, der aus Vinyl- und 5-Hexenylresten ausgewählt ist, Vi für Vinyl steht, Ph für Phenyl steht und a einen Wert von 100 bis 800 aufweist.
  4. Zusammensetzung nach Anspruch 1, wobei Komponente (B) die allgemeine Formel YMe2SiO(Me2SiO)b(MeYSiO)cSiMe2Y aufweist, worin Me für Methyl steht, Y ein Rest ist, der aus Vinyl- und 5-Hexenylresten ausgewählt ist, b einen Wert von 10 bis 200 aufweist und c einen Wert von 1 bis 10 aufweist.
  5. Zusammensetzung nach Anspruch 1, wobei Komponente (C) die allgemeine Formel HMe2SiO(MeSiO)dSiMe2H, aufweist, worin Me für Methyl steht und d einen Wert von 1 bis 500 aufweist.
  6. Zusammensetzung nach Anspruch 1, wobei Komponente (E) die Formel R5(OQ)tO2CCH=CHCO2(QO)tR5 aufweist, worin R5 unabhängig voneinander für einen einbindigen Kohlenwasserstoffrest mit 1 bis 10 Kohlenstoffatomen steht, jedes Q unabhängig voneinander für einen Alkylenrest mit 2 bis 4 Kohlenstoffatomen steht und t einen Wert von 0 oder 1 aufweist.
  7. Zusammensetzung nach Anspruch 6, worin Komponente (E) Bis-methoxyisopropylmaleat ist.
  8. Zusammensetzung nach Anspruch 6, worin Komponente (E) Diethylfumarat ist.
  9. Zusammensetzung nach Anspruch 1, wobei die Zusammensetzung zusätzlich eine Zusammensetzung enthält, die die Badlebensdauer verlängert.
  10. Zusammensetzung nach Anspruch 2, wobei das Organohydrogensiloxanvernetzungsmittel die Formel Me3SiO(MeHSiO)eSiMe3 aufweist, worin e einen Mittelwert von 3 bis 100 hat.
  11. Verfahren zur Herstellung eines Laminats aus einem Substrat und einem Klebstoff, wobei der Klebstoff von dem Substrat trennbar ist und das Verfahren die Schritte umfaßt:
    (I) Beschichten der Oberfläche des Substrats mit der härtbaren Silicontrennzusammensetzung nach Anspruch 1, und
    (II) Aussetzung der Beschichtung an eine Energiequelle, die aus (i) Wärme und (ii) aktinischer Strahlung ausgewählt ist, um die Beschichtung zu härten, und
    (III) Aufbringen eines Klebstoffs auf die Beschichtung.
EP93310528A 1992-12-30 1993-12-23 Zusammensetzungen zum Erhöhen der adhäsiven Kraft von Silikon-Papier-Trennschicht-Beschichtungen Expired - Lifetime EP0605227B1 (de)

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US07/998,493 US5281656A (en) 1992-12-30 1992-12-30 Composition to increase the release force of silicone paper release coatings
US998493 1992-12-30

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US5281656A (en) 1994-01-25
KR100304470B1 (ko) 2001-11-22
KR940014712A (ko) 1994-07-19

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