EP0604360B1 - Procédé d'évacuation controlée de matières insolubles ou difficilment solubles d'un système dans lequel circule de l'eau ozonisée - Google Patents

Procédé d'évacuation controlée de matières insolubles ou difficilment solubles d'un système dans lequel circule de l'eau ozonisée Download PDF

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Publication number
EP0604360B1
EP0604360B1 EP93810795A EP93810795A EP0604360B1 EP 0604360 B1 EP0604360 B1 EP 0604360B1 EP 93810795 A EP93810795 A EP 93810795A EP 93810795 A EP93810795 A EP 93810795A EP 0604360 B1 EP0604360 B1 EP 0604360B1
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EP
European Patent Office
Prior art keywords
water
bed reactor
substances
fluidized
region
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93810795A
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German (de)
English (en)
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EP0604360A1 (fr
Inventor
Kurt Meuli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Christ AG
Original Assignee
Christ AG
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Filing date
Publication date
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Publication of EP0604360A1 publication Critical patent/EP0604360A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02—Softening water by precipitation of the hardness
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02—Softening water by precipitation of the hardness
    • C02F5/06—Softening water by precipitation of the hardness using calcium compounds

Definitions

  • the invention relates to a method for the controlled removal (excretion) of insoluble and sparingly soluble substances from an ozone-containing system, which is defined in claim 1.
  • This is the treatment of water that circulates in aquatic systems that are partially open to the atmosphere.
  • the term "closed systems” also used for this is confusing and incorrect. It is more precisely replaced by the term “systems with trapped water”. Examples of such systems are swimming pools, decorative ponds, air washing systems and in particular cooling systems with an open cooling tower. It is characteristic of these systems that water evaporates or evaporates from them and the remaining water thickens. Evaporation and evaporation are used in the following as synonymous terms.
  • the concentration of foreign substances in the water increases with increasing thickening.
  • Dissolved water constituents which become insoluble, precipitate out and form deposits on the inner surfaces of the aquatic system, which hinder the flow through the system and heat transfer in cooling systems.
  • the thickening is limited by adding more water to the system than evaporation escapes from the system and withdrawing the excess water from the system. If, for example, twice as much water is evaporated from the system within a certain period of time as it evaporates, that is, half of the make-up water evaporates and the other half is drained off, the blowdown water contains practically all of the water components introduced with the make-up water. The concentration of all water components in the wastewater is then twice as high high as in the make-up water, and the wastewater inevitably has the same composition as the water of the system from which the wastewater drains. In this case one speaks of a double thickening.
  • Natural water and also water that is distributed by drinking water supply companies is located in or near the so-called lime-carbon dioxide balance. Lime separates from such water even after a slight thickening, so that cooling tower systems cannot use this water directly, but only after a pretreatment.
  • the pretreatment either removes at least the majority of the poorly soluble substances from the water or converts them into a more soluble form. Typically, a threefold thickening is then possible after such a pretreatment.
  • So-called side-flow filters are used in some cooling tower systems in order to remove the suspended matter which has separated out but is not deposited from the water by filtration from the system.
  • the aim of the present invention is to facilitate the elimination of poorly soluble substances from ozone, aquatic systems.
  • This goal is achieved by the formation of a sink at a suitable point in the water-carrying system in the form of an area in which the water constituents which have become insoluble or difficult to dissolve, i.e. for the transfer of these substances from the dissolved to the undissolved state, are particularly suitable advantageous conditions exist.
  • these conditions are met by a fluidized bed reactor in which the insoluble substances form grains which are removed continuously or periodically from the reactor and thus from the system.
  • Fluid bed reactors suitable for this purpose were used as so-called rapid reactors in the rapid decarbonization plants which were previously frequently used in water technology. With these systems, the majority of the hardness constituents bound to bicarbonate (the so-called carbonate hardness or the temporary water hardness) can be removed economically and very environmentally friendly from clean water.
  • the insoluble substances the main component of which is CaCO 3 , form a practically spherical hard grain with diameters of up to a few millimeters and a very low water content of the order of only one percent. The grain can be discharged from the reactor and thus from the system periodically or continuously.
  • Fluid bed reactors such as those used in rapid decarbonization plants, are therefore suitable for removing the water components which have become insoluble in these systems.
  • the grain removed from the aquatic system in this way is a pure natural product, composed of exclusively inorganic constituents of the water added to the aquatic system. Its organic components are broken down by the constant ozonation of water in the aquatic system. Thanks to its natural composition, the grain can advantageously be used again in water treatment, e.g. to filter the water and to adjust the lime-carbon dioxide equilibrium. This recycling avoids waste.
  • the grain Because of its great purity, the grain is also easy to deposit. Compared to sludge, which is obtained from conventional cleaning processes with which the make-up water is treated in order to allow only about five times thickening, the grain is cleaner, in particular free of additives not contained in natural water, and has a water content of only around one percent instead of 60 to 80% and thus a much lower volume of waste.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Removal Of Specific Substances (AREA)

Claims (5)

  1. Procédé d'évacuation dirigée de substances insolubles ou peu solubles à partir d'un système partiellement ouvert sur l'atmosphère et dans lequel circule de l'eau ozonée, caractérisé en ce que, dans ce système aquatique, il est formé un domaine au sein duquel il règne des conditions plus favorables à la précipitation desdites substances qu'elles ne le sont à l'extérieur de ce domaine, et que le domaine qui favorise la précipitation est formé par la zone de réaction d'un réacteur à lit fluide à partir duquel les substances précipitées sont éliminées.
  2. Procédé selon la revendication 1, caractérisé en ce que l'on ajoute à la zone de réaction du réacteur à lit fluide une substance qui favorise la précipitation, de préférence, un alcali et notamment de la chaux vive ou de la chaux éteinte.
  3. Procédé selon la revendication 1 ou 2, caractérisé en ce que, pour réaliser une élimination plus poussée des corps étrangers à partir de l'eau, on installe en aval du réacteur à lit fluide des dispositifs pour la séparation mécanique de substances solides à partir de l'eau, par exemple, un ou plusieurs échelons d'épuration tels qu'un séparateur à lamelles ou un filtre.
  4. Procédé selon l'une quelconque des revendications 1 à 3, caractérisé en ce que l'on utilise dans un filtre, comme matériel de filtration, les grains durs retirés du réacteur à lit fluide, pour filtrer mécaniquement l'eau qui passe à travers et/ou l'introduire dans l'équilibre chaux/acide carbonique.
  5. Procédé selon l'une quelconque des revendications 1 à 4, caractérisé en ce que l'on place d'autres résidus dans l'espace libre de la couche de grains durs, afin d'évacuer les grains durs retirés du réacteur à lit fluide ou les grains durs utilisés comme matériel de filtration.
EP93810795A 1992-12-14 1993-11-16 Procédé d'évacuation controlée de matières insolubles ou difficilment solubles d'un système dans lequel circule de l'eau ozonisée Expired - Lifetime EP0604360B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH380792 1992-12-14
CH3807/92 1992-12-14

Publications (2)

Publication Number Publication Date
EP0604360A1 EP0604360A1 (fr) 1994-06-29
EP0604360B1 true EP0604360B1 (fr) 1997-04-16

Family

ID=4263883

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93810795A Expired - Lifetime EP0604360B1 (fr) 1992-12-14 1993-11-16 Procédé d'évacuation controlée de matières insolubles ou difficilment solubles d'un système dans lequel circule de l'eau ozonisée

Country Status (4)

Country Link
EP (1) EP0604360B1 (fr)
JP (1) JPH06206083A (fr)
AT (1) ATE151732T1 (fr)
DE (1) DE59306185D1 (fr)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2156571C3 (de) * 1971-11-15 1981-07-30 Hans-Ulrich Ing.(Grad.) 6200 Wiesbaden Klein Verwendung eines Filterbettes in Vorrichtung zur komplexen Wasseraufbereitung mit Ozon
CA1042572A (fr) * 1976-12-31 1978-11-14 John Filby Epuration de l'eau de chaudiere
DE3711407A1 (de) * 1987-04-04 1988-10-20 Bruno Bachhofer System zur wasseraufbereitung mit ozon
AU7339991A (en) * 1990-02-09 1991-09-03 Alden L. Coke Method and apparatus for treating water in a cooling system

Also Published As

Publication number Publication date
JPH06206083A (ja) 1994-07-26
DE59306185D1 (de) 1997-05-22
ATE151732T1 (de) 1997-05-15
EP0604360A1 (fr) 1994-06-29

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