EP0589872A1 - Element structurel composite et procede de production - Google Patents

Element structurel composite et procede de production

Info

Publication number
EP0589872A1
EP0589872A1 EP91907310A EP91907310A EP0589872A1 EP 0589872 A1 EP0589872 A1 EP 0589872A1 EP 91907310 A EP91907310 A EP 91907310A EP 91907310 A EP91907310 A EP 91907310A EP 0589872 A1 EP0589872 A1 EP 0589872A1
Authority
EP
European Patent Office
Prior art keywords
casing
plug
binder
strands
fiber reinforcement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP91907310A
Other languages
German (de)
English (en)
Other versions
EP0589872A4 (fr
Inventor
Hartley Sandt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority claimed from PCT/US1991/001636 external-priority patent/WO1992016347A1/fr
Publication of EP0589872A4 publication Critical patent/EP0589872A4/fr
Publication of EP0589872A1 publication Critical patent/EP0589872A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00—Subject matter not provided for in other groups of this subclass
    • B29D99/0046—Producing rods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/542—Placing or positioning the reinforcement in a covering or packaging element before or during moulding, e.g. drawing in a sleeve
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/10—Cords, strands or rovings, e.g. oriented cords, strands or rovings
    • B29K2105/101—Oriented
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00—Tubular articles
    • B29L2023/22—Tubes or pipes, i.e. rigid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/001—Profiled members, e.g. beams, sections
    • B29L2031/003—Profiled members, e.g. beams, sections having a profiled transverse cross-section
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/06—Rods, e.g. connecting rods, rails, stakes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/774—Springs
    • B29L2031/7742—Springs helical springs

Definitions

  • Structural elements such as rods, tubes, and beams are normally made by casting, extruding, or rolling techniques to produce plastic or metal tubing, sheets, rods, beams, and the like.
  • These structural elements normally comprise a single material which is chosen for its combination of physical properties, e.g., strength and weight, as well as corrosion resistance, color, and texture.
  • Plastic molding and extrusion procedures have provided the possibility of preparing plastic structural elements with selected combinations of physical properties, chemical properties, color, texture, etc.
  • Fiber reinforcement of plastic materials has provided much higher physical strength properties than the plastic material alone could offer. In general, these fiber reinforced materials are made by extruding through a die a plastic melt having continu ⁇ ous strnads of fiber distributed therein.
  • the extrudate is then solidified in the form of a continuous rod, beam, or strand and can be cut into whatever length is desired for use.
  • the disadvantages of the prior art procedures are (1) that the extrudate can not be made into a curved or non-linear article, and (2) the surface properties at the extrudate cannot be changed from that inherent in the extruded plastic.
  • This invention relates to an elongated solid or tubular structural element having a substantially identical cross section over its entire length, the element having a solic core of thermoplastic or thermosetting resin material em ⁇ bedded in which is a plurality of elongated continuous strands of lengthwise fiber reinforcement material, preferably in substantially parallel array, and a continuous casing around the core.
  • This invention also relates to a process for preparing an elongated structural element comprising:
  • the process and element may include a tubular shape employing an external casing and an internal casing with the space therebetween being filled with the plastic material and fiber reinforcement materials.
  • the element may also be shaped before solidification, or thereafter by reheating, into a helical coil or spring, or other shape like an I-beam or an H-beam or any irregular shape. Sometimes this requires the displacement and/or removal of some of the plastic mater ⁇ ial.
  • FIG. 1 is a side elevational view of one embodiment of the structural element of this invention
  • FIG. 2 is an end elevational view of the structural element shown in FIG. 1;
  • FIG. 3 is an end elevational view of a second embodi ⁇ ment of the structural element of this invention.
  • FIG. 4 is an end elevational view of a third embodiment of the structural element of this invention
  • FIG. 5 is an end elevational view of a fourth embodi ⁇ ment of the structural element of this invention
  • FIG. 6 is an illustration of one type of article, e.g., a coil spring, that can be made from the structural element of this invention
  • FIG. 7 is an illustration of one embodiment of the process of this invention.
  • FIG. 8 is an illustration of a second embodiment of the process of this invention.
  • FIG. 9 is an illustration of a third embodiment of the process of this invention.
  • FIG. 10 is an illustration of the structural element of this invention with end caps attached
  • FIG. 11 is an end elevational view of a hollow struc ⁇ tural element of this invention.
  • FIG. 12 is an illustration of a fourth embodiment of this invention.
  • FIG. 13 is an illustration of a fifth embodiment of this invention.
  • FIG. 14 is an illustration of a process for changing a structural element having a round cross section to one having a non-round cross section.
  • This invention relates to articles of manufacture which are shown in FIGS. 1-6, 10, and 11 of the attached drawings, and to processes for preparing such articles which are shown in FIGS. 7-9, and 12-14.
  • FIGS. 1-6, 10 and 11 there are depicted several types of structural elements according to this invention.
  • a cylindrical rod element having three components; namely, an external casing 11, an internal binder 12, and strands 13 of fiber reinforcement material. These are all joined together into a single unitary structure which has an indefinite length and a substantially similar cross section at any place along that length.
  • External casing 11 is a flexible, semiflexible, or rigid pipe or tubing having whatever properties are important for the eventual use of the structural element. If corrosion resistance, abrasion resistance, or weather resistance is important, casing 11 must provide that property; and so on for other property requirements.
  • casing 11 should be a flexible or semiflexible thermoplastic material which is compatible with binder 12 and does not react chem ⁇ ically therewith.
  • casing 11 may be a metallic tube, an animal or human vein, intestine, or the like. Preferably there is no bond between the two, although in certain embodiments binder 12 and casing 11 may be bonded to each other.
  • Typical materials for casing 11 include poly- olefins, polyvinyls, polyesters, polyacetals, polyacrylics, polyamides, polyfluorocarbons, polycarbonates, and other plastics of similar properties, aluminum, human or animal tissue, and the like.
  • the internal space in casing 11 is filled with binder
  • Binder 12 must be capable of tightly adhering to strands 13.
  • binder 12 should be available in liquid form for ease in manufacturing the structural element of this invention, and capable of being transformed into solid form at ambient conditions for use as binder 13 in the structural element in ordinary use.
  • thermoplastic 13 may be a thermoplastic or a thermosetting material each of which exists in both liquid and solid forms.
  • the thermoplastic materials normally change from liquid to solid and from solid to liquid by temperature changes.
  • Thermosetting materials normally involve two or more starting components which are mixed together to produce a liquid which is hardened by chemical reaction between the components and cannot later be liquefied.
  • Typical thermoplastics include polyolefins, poly ⁇ esters, polyvinyls, polyacetals, polyacrylics, polyamides, polyfluorocarbons, polycarbonates, and the like.
  • Typical thermosetting binders include phenol-formaldehyde resins, melamine resins, epoxy resins, urea-formaldehyde resins, polyesters, and the like.
  • the fiber reinforcement material 13 is a plurality of strands of fiber or filament that are distributed throughout the binder and are in substantially parallel arrangement running lengthwise of the structural element.
  • the strands may be in a linear arrangement or in a sinuous or helical arrangement preferably mutually parallel to each other, although there may be embodiments where strands 13 are in any desired nonparallel arrangement.
  • the strands 13 would be separated from each other and equally distributed throughout all of the binder 12. From a practical point of view this may not be achieved, but preferably, the strands are extended lengthwise throughout the structural element and distributed as evenly as possible in the binder.
  • Each strand 13 may be a single filament or a plurality of filaments twisted together, or may be a single fiber or a plurality of fibers twisted into a thread; or may be any other combination of fibers, filaments, threads, yarns or the like that are relatively small in diameter and relatively long and contin ⁇ uous in length.
  • Tubular filaments, threads, yarns and the like are also useful as strands 13.
  • the word "strand" herein is meant to be generic and to include all of the above con ⁇ figurations.
  • the material of the strands may be organic or inorganic.
  • the organic strands include materials such as cotton, wool, bagassee, hemp, polyamide, polyacrylonitrile, polyester, rayon and the like.
  • Inorganic strands include materials such as glass, steel, copper, aluminum, titanium, graphite, and the like.
  • FIGS. 3-5 there are shown other structural elements of other cross sectional shapes, e.g., square (FIG. 3), oblong (FIG. 4) , and triangular (FIG. 5) , which may be solid as shown, or tubular with an internal open space, as shown in FIG. 11. Any of these shapes may be prepared in finite lengths and end- capped, as shown in FIG. 10, if it is desirable to protect the open ends from the surrounding medium in which the structural element is used. Still other shapes are within the scope of this invention since any geometric design like an H-beam, an I-beam or star shaped cross section is acceptable.
  • the structural element of this invention can be sawed, drilled, tapped, twisted, bent, and otherwise used to form useful. rticles of manufacture.
  • the element may be coiled into a helix to form a coil spring as shown in FIG. 6.
  • a preformed straight length of element may be heated, and formed into another shape, e.g., coiled to form the spring of FIG. 6, and cooled to solidify the binder 12, and thereby produce a stable shape.
  • the element may employ a thermoplastic molten binder 12 in casing 11, and the element may be coiled into a spring or formed into another shape before the binder 12 is allowed to sol ⁇ idify.
  • the binder 12 is a thermosetting material, it must be formed into the final desired shape, e.g., coiled into the spring of FIG. 6, before binder 12 has had time to set to a solid.
  • the struc ⁇ tural element of this invention including ropes, rods, struc ⁇ tural beams for chemical processing equipment, articles used under sea water, strands or bones used in human surgical pro ⁇ cedures, and the like.
  • a plug 17 is moved through the internal hollow of casing 11 with binder 12 and fiber reinforcement strands 13 filling the hollow behind the plug 17 as it moves along.
  • a length of casing 11 is fitted with a feed funnel 16 into which is fed a continuous length of a plurality of strands 13 and at the same time is fed liquid or molten binder 12 from a supply reservoir 15.
  • Plug 17 is slidable within casing 11 and has an eye 18 to which the hank of strands 13 is attached.
  • a pull cable 19 is attached to the front of plug 17 to pull plug 17 through casing 11 by windup drum 20.
  • casing 11 and plug 17 may take any shape, such as those in FIGS. 2-5.
  • hollow shapes as shown in FIG. 11 may be made by making plug 17 into an annular object and sliding between an inner casing 29 and an outer casing 11 (see FIG. 11) .
  • inner casing 29 may be supported by an internal mandrel (not shown) to support inner casing against collapse until binder 12 hardens.
  • FIG. 8 the same general arrangement as that of FIG. 7 is shown except that instead of a windup drum 20 and a cable 19 to move plug 17 there is a vacuum pump 21 to produce a lower pressure in the space 25 ahead of plug 17 causing plug 17 to move toward vacuum pump 21.
  • FIG. 9 there also is the same general arrangement of casing 11, plug 17 and strnads 13, attached to eye 18.
  • the force to move plug 17 through casing 11 is provided by the pressure on binder 12.
  • Inlet pipe 22 feeds liquid binder 12 to pump 23 which pumps binder into pressure vessel 27 which has an outlet into casing 11.
  • Roll 14 of fiber reinforcement strands 13 is mounted inside vessel 27 in a pressurized space 26 designed to offset the pressure on binder 12 emitted from pump 23.
  • Binder 13 is supplied to space 24 under pressure and this bears against plug 17 causing it to move to the right and fill up casing 11.
  • the strands will be substantially linear and parallel to each other and to the longitudinal axis of casing 11 if plug 17 is simply pulled through casing 11. If plug 11 is rotated about its axis of travel as it is pulled through casing 11, strands 13 can be made into a sinuous or helical orientation while the individual strands 13 remain generally parallel with each other.
  • end caps 28 sealed onto any cut ends of the structural element so as to leave only the material of the casing exposed as shown in FIG. 10. End cap 28 can be heat sealed or otherwise attached to casing 11 so as to be leak proof and therefore completely corrosion-resistant.
  • the fiber reinforcing component is a continuous strand and not a plurality of chopped fivers.
  • the continuous strands employed in this invention provide a greatly improved modulus of elasticity as compared to that of the strand containing short lengths of reinforcing fibers or filaments. It is for this reason that an excellent coil spring can be made from the structural element of this inven ⁇ tion, while such a coil spring from the prior art would not be operable.
  • FIGS. 12-14 show alternate embodiments of the process of making the structural elements of FIGS. 2-5 and 11.
  • FIG. 12 there is illustrated a procedure to make hollow tubular structural elements as shown in FIG. 11.
  • Outer casing 11 is attached to funnel 16 by clamp 30.
  • Inner casing 29 with a plug at its lower or forward end is introduced into funnel 16 along with plug 33 into which the forward ends of fiber strands 13 have been embedded by previously molding plug 33 with strands 13 embedded therein.
  • Plug 33, inner casing 29, and plug 34 are moved downwardly in the direction of arrow.35 while outer casing 11 and funnel 16 remain stationary and filled with liquid binder 12.
  • Plug 34 As inner casing 29, plug 34, plug 33 and strands 13 move downwardly the annular space between casings 11 and .29 fills with binder 12 and fiber strands 13 are dispersed throughout. Plug 34 is needed to prevent binder 12 from leaking into the interior hollow of internal casing 29. Plug 34 may be independent of plug 33 or attached thereto in different embodiments of this process.
  • Centering guides 31 and 32 keep inner casing 29 centered in casing 11 as casing 29 advances.
  • Guides 31 ar.d 32 are spider legs.
  • Guide 31 is attached to funnel 16 with its distal ends rubbing against inner casing 29 as it moves forward.
  • Guides 32 are attached to casing 29 or its plug 34 with its distal ends rubbing against outer casing 11 as inner casing 29 moves forward.
  • guides 31 and 32 are spring biased to bear against casings 29 and 11, respectively. Furthermore, guides 31 preferably are pivotable so as to be no obstacle to the initial entrance of plug 33 into and through funnel 16 to the top of outer casing 11. When the desired length of tubular structural element 11 has been made, the process can be repeated by starting again with a new length of outer casing 11.
  • FIG. 13 there is shown an alternative to the process of FIG. 9 for making the structural element by fluid pressure causing the movement of the plug to which fiber strands 13 are attached.
  • a plurality of fiber strands 13 are introduced over a feed roller 37 in header box 38 and downward through funnel 16 into outer casing 11 which is temporarily attached to funnel 16 by clamp 20.
  • the forward ends of strands 13 are embedded in plug 36.
  • Casing 11 rests on a base plate 39 which will serve as a stop to plug 36 which moves downward in the process.
  • Binder 12 is kept in container 40 which is con ⁇ nected by passageway 43 to funnel feeder 16 permitting the level of binder 12 to be the same in funnel 16 and in container 40.
  • Air pressure is maintained in tank 44 which is connected by lines 45, 46 and 47 to both of header box 38 and binder con ⁇ tainer 40 to equalize the pressure on both surfaces of liquid binder 12.
  • the pressure is transmitted to plug 36 causing it to move forward in casing 11 until it reaches base plate 39.
  • Lid 41 is provided for adding binder 12 to container 40, and lid 42 is provided for replacing a supply of strands 13 over roller 37 in head box 38.
  • FIG. 14 there is shown a procedure for transforming an element of circular cross section, as in FIG. 2, to an ele ⁇ ment of noncircular cross section, as in FIGS. 3-5, when outer casing 11 is flexible and capable of being bent and formed into different shapes.
  • the problem in such modifications is that the cross sectional area and circumference of the begin ⁇ ning element, e.g., circular, may not be the same as those of the final element, e.g., a rectangle.
  • the limiting factor normally is that the circumference or perimeter of the beginning element and final element must be the same if the outer casing 11 is to remain smooth, continuous, and un- wrinkled.
  • an element of circular cross section (2.865 square inches) must be squeezed to a cross sectional area of 2.0 square inches to be reshaped into a rectangular cross section of one inch by two inches.
  • a circular cross section element 50 with a cross sectional area of 2.865 square inches and with binder 12 in a liquid form is squeezed by rollers 49 turning in the direction of arrows 52 as the element moves past an internal solid of about 0.865 square inch cross section to reduce the cross sectional area to 2.0 square inches.
  • Rollers 49 with or without the assistance of other forming devices can then shape element 51 into a rectangular cross section of one inch by two inches before binder 12 sol ⁇ idifies. It may be seen that this procedure may be applied to the end of the procedures of FIGS. 7-9 and 13 or before binder 12 solidifies, or alternatively, a rigid element may be heated to liquefy binder 12 (if it is thermoplastic) and then subjected to the reshaping procedure of FIG. 14. While the beginning element may have any shape, it preferably is circular because it is easier to make and it automatically provides a better dispersion of strands 13 than any other sha e.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

Elément structurel allongé comprenant une enveloppe tubulaire externe (11) présentant un espace intérieur creux rempli d'un liant plastique (12) contenant un ensemble de longs torons continus parallèles en un matériau fibreux de renforcement (13) s'étendant dans le sens de la longueur de l'élément. Un procédé de préparation de cet élément consiste à remplir une enveloppe tubulaire préformée (11) d'un liant plastique (12) sous forme liquide, dans lequel est dispersé le matériau fibreux de renforcement (13), et à laisser se solidifier le liant plastique. L'élément peut être façonné avant la solidification, ou réchauffé de manière à lui conférer une autre forme, telle qu'un enroulement ou un ressort hélicoïdal. On peut également utiliser une enveloppe interne (29), les torons en fibres de renforcement (13) étant alors placés entre l'enveloppe externe (11) et l'enveloppe interne (29).
EP91907310A 1991-03-13 1991-03-13 Element structurel composite et procede de production Withdrawn EP0589872A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PCT/US1991/001636 WO1992016347A1 (fr) 1991-03-13 1991-03-13 Element structurel composite et procede de production
CA002105983A CA2105983A1 (fr) 1991-03-13 1991-03-13 Element structural composite et procede pour sa fabrication

Publications (2)

Publication Number Publication Date
EP0589872A4 EP0589872A4 (fr) 1993-12-16
EP0589872A1 true EP0589872A1 (fr) 1994-04-06

Family

ID=4152300

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91907310A Withdrawn EP0589872A1 (fr) 1991-03-13 1991-03-13 Element structurel composite et procede de production

Country Status (4)

Country Link
EP (1) EP0589872A1 (fr)
JP (1) JPH06506406A (fr)
AU (1) AU658140B2 (fr)
CA (1) CA2105983A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3231592B1 (fr) * 2014-12-12 2021-07-21 Fundació Eurecat Procédé pour fabriquer une pièce en matériau composite

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2852424A (en) * 1957-04-30 1958-09-16 Frank W Reinhart Reinforced plastic springs
DE2021347A1 (de) * 1969-04-30 1970-11-19 Nat Res Dev Verfahren zur Herstellung faserverstaerkter Verbundkoerper
FR2082872A5 (en) * 1970-03-31 1971-12-10 Pigeon Daniel Prefabricated frames - of glass fibre reinforced plastics

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1304015A (fr) * 1969-04-30 1973-01-24
FR2547768B1 (fr) * 1983-06-24 1986-01-10 Ugine Kuhlmann Materiau composite polymere thermoplastique allege polymere thermodurcissable et ses procedes de fabrication

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2852424A (en) * 1957-04-30 1958-09-16 Frank W Reinhart Reinforced plastic springs
DE2021347A1 (de) * 1969-04-30 1970-11-19 Nat Res Dev Verfahren zur Herstellung faserverstaerkter Verbundkoerper
FR2082872A5 (en) * 1970-03-31 1971-12-10 Pigeon Daniel Prefabricated frames - of glass fibre reinforced plastics

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO9216347A1 *

Also Published As

Publication number Publication date
EP0589872A4 (fr) 1993-12-16
AU658140B2 (en) 1995-04-06
JPH06506406A (ja) 1994-07-21
CA2105983A1 (fr) 1992-09-14
AU7555991A (en) 1992-10-21

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