EP0585038B1 - Alkali containing silica solution - Google Patents

Alkali containing silica solution Download PDF

Info

Publication number
EP0585038B1
EP0585038B1 EP93306496A EP93306496A EP0585038B1 EP 0585038 B1 EP0585038 B1 EP 0585038B1 EP 93306496 A EP93306496 A EP 93306496A EP 93306496 A EP93306496 A EP 93306496A EP 0585038 B1 EP0585038 B1 EP 0585038B1
Authority
EP
European Patent Office
Prior art keywords
weight
solution
sodium
containing silica
alkali containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93306496A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0585038A1 (en
Inventor
Derek Aldcroft
Charlotte Ruth Owen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Silicas Ltd
Original Assignee
Joseph Crosfield and Sons Ltd
Crosfield Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Joseph Crosfield and Sons Ltd, Crosfield Ltd filed Critical Joseph Crosfield and Sons Ltd
Priority to EP93306496A priority Critical patent/EP0585038B1/en
Publication of EP0585038A1 publication Critical patent/EP0585038A1/en
Application granted granted Critical
Publication of EP0585038B1 publication Critical patent/EP0585038B1/en
Priority to GR20000402124T priority patent/GR3034433T3/el
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/14—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/32—Organic compounds containing nitrogen
    • C11D7/3245—Aminoacids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/36—Organic compounds containing phosphorus
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives

Definitions

  • the invention relates to alkali containing silica solution containing organic calcium sequestrant, to a bleaching bath formulation containing said silica solution and to a process for the alkaline hydrogen peroxide bleaching of textiles.
  • Silicates are well characterised in the literature, for example "The Chemistry of Silica” by R.K. Iler (published by Wiley Interscience 1979) and they have many forms depending on the cation associated with the silicate species, the ratio of metal oxide of this cation to the silicon dioxide content of the solution, and the total solids content.
  • Silicate liquors find uses as sealants adhesives, protective coatings, binders and also stabilisation system in the hydrogen peroxide bleaching of textiles, for example cotton and polyester/cotton (see “The Encyclopedia of organic Chemistry", Kirk Othmer, 3rd Edition, Supplement Vol.3, 1979, pages 877 and 949).
  • silicate containing either potassium or sodium oxide is recognised as being the best stabilising system for alkaline hydrogen peroxide bleaching of cotton and polyester/cotton (white goods), i.e. the reaction of the soluble silicate to prolong the active life of the hydrogen peroxide in the bleaching bath, the drawbacks of using silicate are well documented.
  • the whiteness values have been measured on the treated cloth, after bleaching for 20 minutes at 100°C in a Werner Mathis steamer. Listed below in Table 1 are the whiteness values obtained for the various silicate additions, the measurements being determined on an Elrepho spectrophotometer.
  • the blends have been prepared by adding the candidate neutralised organic acid calcium sequestrant (40% solution as its sodium salt) to the stirred alkali containing silica solution. After aeration has settled, caused by the mixing action of the stirrer, the blends are transferred to a glass sample bottle and sealed to prevent moisture escaping. The blends have been stored for up to a period of 3-months at ambient temperature. The observations recorded in Table II are on the blends after standing for one month.
  • the CCPL's for the range of modified alkali containing silica solutions containing 4% of the sequestrant in the form of its sodium salt, in the ratio range 1.6 to 2.0 are given in Table IV.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Silicon Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Saccharide Compounds (AREA)
  • Cosmetics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
EP93306496A 1992-08-28 1993-08-18 Alkali containing silica solution Expired - Lifetime EP0585038B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP93306496A EP0585038B1 (en) 1992-08-28 1993-08-18 Alkali containing silica solution
GR20000402124T GR3034433T3 (en) 1992-08-28 2000-09-18 Antifoaming agents.

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP92307886 1992-08-28
EP92307886 1992-08-28
EP93306496A EP0585038B1 (en) 1992-08-28 1993-08-18 Alkali containing silica solution

Publications (2)

Publication Number Publication Date
EP0585038A1 EP0585038A1 (en) 1994-03-02
EP0585038B1 true EP0585038B1 (en) 2000-07-26

Family

ID=8211472

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93306496A Expired - Lifetime EP0585038B1 (en) 1992-08-28 1993-08-18 Alkali containing silica solution

Country Status (9)

Country Link
EP (1) EP0585038B1 (da)
AT (1) ATE194998T1 (da)
BR (1) BR9303474A (da)
DE (1) DE69329089T2 (da)
DK (1) DK0585038T3 (da)
ES (1) ES2150436T3 (da)
GR (1) GR3034433T3 (da)
PT (1) PT585038E (da)
ZA (1) ZA935690B (da)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101545198B (zh) * 2009-04-30 2011-02-09 祝洪哲 用于纤维素纤维织物漂白的纳米材料组合物

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0750661B1 (en) * 1994-03-14 2003-02-26 The Procter & Gamble Company Granular bleaching compositions
DE4416208A1 (de) * 1994-05-07 1995-11-09 Henkel Kgaa Verwendung von phosphorfreien, wasserlöslichen Polymeren und Polyhydroxymono- oder dicarboxylaten zur Stabilisierung von Erdalkalisilikaten bei der Textilbleiche
US7044985B2 (en) * 1999-12-21 2006-05-16 Clariant Finance (Bvi) Limited Process for pre-treating cellulosic fibers and cellulosic fiber blends

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2838459A (en) * 1955-02-01 1958-06-10 Pennsalt Chemicals Corp Stabilization of solutions containing peroxygen compounds
GB923897A (en) * 1959-08-28 1963-04-18 Laporte Chemical Improvements in or relating to the bleaching of cellulosic fibres
US3150918A (en) * 1962-03-29 1964-09-29 Pittsburgh Plate Glass Co Method of bleaching cotton piece goods
GB1123071A (en) * 1964-11-12 1968-08-14 Bowmans Chemicals Ltd Improvements in or relating to the treatment of natural or synthetic fibres
US3449254A (en) * 1966-06-14 1969-06-10 Allied Chem Borax-sodium silicate stabilizers for peroxide bleaching
CA965327A (en) * 1970-09-24 1975-04-01 The Procter And Gamble Company Liquid hard surface cleanser
US4725281A (en) * 1985-07-19 1988-02-16 Ciba-Geigy Corporation Aqueous alkaline, silicate-containing composition and the use thereof for bleaching cellulosic fiber materials in the presence of per compounds
FR2643093B1 (fr) * 1989-02-15 1991-08-16 Protex Manuf Prod Chimiq Procedes ameliores de blanchiment oxydant de fibres cellulosiques
EP0407626A1 (de) * 1989-07-10 1991-01-16 Henkel Kommanditgesellschaft auf Aktien Phosphatfreies, flüssiges Wasch- und Reinigungsmittel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101545198B (zh) * 2009-04-30 2011-02-09 祝洪哲 用于纤维素纤维织物漂白的纳米材料组合物

Also Published As

Publication number Publication date
ZA935690B (en) 1995-02-06
ES2150436T3 (es) 2000-12-01
GR3034433T3 (en) 2000-12-29
EP0585038A1 (en) 1994-03-02
ATE194998T1 (de) 2000-08-15
DE69329089T2 (de) 2000-12-21
DK0585038T3 (da) 2000-12-18
DE69329089D1 (de) 2000-08-31
PT585038E (pt) 2000-11-30
BR9303474A (pt) 1994-03-15

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