EP0569891A1 - Yarn and method for manufacturing a yarn - Google Patents

Yarn and method for manufacturing a yarn Download PDF

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Publication number
EP0569891A1
EP0569891A1 EP93107497A EP93107497A EP0569891A1 EP 0569891 A1 EP0569891 A1 EP 0569891A1 EP 93107497 A EP93107497 A EP 93107497A EP 93107497 A EP93107497 A EP 93107497A EP 0569891 A1 EP0569891 A1 EP 0569891A1
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EP
European Patent Office
Prior art keywords
yarn
core
dtex
multifilament yarn
multifilament
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Granted
Application number
EP93107497A
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German (de)
French (fr)
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EP0569891B1 (en
Inventor
Karl Greifeneder
Kurt Truckenmüller
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Amann and Soehne GmbH and Co KG
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Amann and Soehne GmbH and Co KG
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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/46Sewing-cottons or the like
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Definitions

  • the present invention relates to a core yarn with the features of the preamble of claim 1 and a method for producing such a core yarn with the features of the preamble of claim 16.
  • EP B1 0 367 938 describes a two-component yarn which has at least one multifilament first yarn component, which is arranged in the interior of the yarn and which is referred to as the core material, and at least one second multifilament effect material enveloping the core material.
  • the two aforementioned multifilament yarns are intermingled with one another in such a way that the necessary thread closure is achieved by intertwining the two yarn materials results.
  • such a filament yarn is used as the first yarn material, the specific strength of which is already very high as a starting material compared to a standard textile yarn.
  • EP B 0367 938 thus teaches that a high-strength multifilament yarn is already used as the starting material.
  • fiber yarns or threads are also known.
  • a yarn with the features of the preamble of claim 1 is described in DE-PS 24 36 997.
  • the known yarn has a multifilament core material, which is wound with a second yarn component to form a core yarn.
  • the core material of the well-known core yarn consists of stretched and fixed multifilament fibers, the high-strength multifilament yarns previously described for the intermingled yarn usually also being used for this. These high-strength multifilament yarns are considerably more expensive than standard textile fibers.
  • the present invention has for its object to provide a core yarn of the type specified, which has an extremely high resistance to mechanical stresses at a particularly low manufacturing price.
  • the yarn according to the invention which is also used in particular as a sewing thread, has at least one multifilament yarn component which forms a core.
  • the multifilament yarn component forming the core is wound with at least one second yarn component to form the core yarn.
  • the core of the core yarn forming at least one multifilament yarn component is a conventional textile standard multifilament yarn, the spun core yarn having a specific strength between 32 cN / tex and 55 cN / tex, preferably between 37 cN / tex and 48 cN / tex.
  • the core yarn according to the invention has a number of advantages. It was surprisingly found that a core yarn of this type has the previously stated high strengths between 32 cN / tex and 55 cN / tex, in particular between 37 cN / tex and 48 cN / tex, although a core material is used to produce this yarn. which, in contrast to the prior art described above, is not a high-strength multifilament yarn but a common textile standard multifilament yarn. This in turn leads to the core yarn according to the invention being particularly inexpensive to produce.
  • the core thread according to the invention is used as a sewing thread, such a sewing thread is characterized in that it performs the usual sewing operations, for example multidirectional sewing or buttonhole sewing, even at extremely high sewing speeds of up to 7,000 stitches per minute without one Damage to the core yarn survives.
  • the core yarn according to the invention does not cause any sewing disturbances in the area of the ready-to-wear.
  • a first embodiment of the core yarn according to the invention has a multifilament yarn component forming the core, which has an intrinsic viscosity between 0.5 dl / g and 0.75 dl / g, in particular an intrinsic viscosity between 0.55 dl / g and 0, 63 dl / g.
  • This is a multifilament polyester yarn component.
  • the values of the intrinsic viscosity mentioned above reflect the molecular structure (molecular weight, chemical composition) of the polyester multifilament yarn used, the degree of condensation of the polymers also correspondingly increasing with increasing viscosity.
  • the values given above refer to polymer solutions in dichloroacetic acid at 25 ° C.
  • this single-filament titer varies between 0.6 dtex and 6 dtex, preferably between 1.5 dtex and 4 dtex.
  • the core yarn according to the invention in particular has a multifilament yarn (multifilament yarn component) as a core, the number of filaments of which varies between 16 and 300, preferably between 24 and 96.
  • any yarn is suitable for this is that the soul adequately covers the outside.
  • a fiber yarn made of polyamide 6, polyamide 6.6, cotton and / or in particular polyester fibers is preferably used as the second yarn component.
  • Embodiments of the core yarn according to the invention have a particularly high strength in which the second yarn component comprises at least one fiber yarn, the specific strength of which varies between 40 cN / tex and 70 cN / tex.
  • the staple length of the individual fibers of the fiber yarn varies between 15 mm and 120 mm, in particular between 20 mm and 60 mm.
  • a particularly suitable embodiment of the yarn according to the invention provides that the yarn comprises at least two, preferably two to four core yarns twisted together, each individual core yarn having the structure described above or below.
  • the correspondingly twisted yarn preferably has a twist coefficient ⁇ between 120 and 180, the twist coefficient ⁇ being defined as follows:
  • Such a twisted yarn which, as already described above, comprises at least two, preferably two to four, twisted core yarns, can also be used particularly well as a sewing thread, since such a sewing thread, for example, multidirectional sewing or sewing buttonholes with high stitch densities (up to 7,000 stitches per minute) without yarn break.
  • the yarns according to the invention described above have a total titer which is between 100 dtex and 1,400 dtex, preferably between 100 dtex and 600 dtex.
  • the mass ratio of core to second yarn component varies in the yarn according to the invention from 70% (mass of core) to 30% (mass of the second yarn component) to 30% (mass of core) to 70% (mass of the second yarn component).
  • the yarn according to the invention have the same fiber substrate mentioned above both as core and as a second yarn component.
  • the invention Yarn has different fiber substrates in the soul and as a second yarn component.
  • the present invention is also based on the object of providing a production method with which the yarn according to the invention described above can be spun particularly economically.
  • the process according to the invention for producing the yarns described above provides that at least one multifilament yarn component serving as a core is spun with a second yarn component to form the core yarns.
  • a pre-oriented multifilament yarn (POY yarn) is selected for the soul-forming at least one multifilament yarn component, the molecular weight of the at least one pre-oriented multifilament yarn (POY yarn) corresponding to a textile standard multifilament yarn.
  • This pre-oriented multifilament yarn (POY yarn) is drawn in such a way that its strength varies between 60 cN / tex and 90 cN / tex, in particular between 71 cN / tex and 90 cN / tex.
  • the method according to the invention has a number of advantages. It should first be noted that the method according to the invention, using relatively inexpensive raw materials, leads to a high-quality yarn, in particular sewing thread, which is distinguished by the fact that it is used even under extreme sewing loads does not tear.
  • a thread or sewing thread produced in this way has low residual shrinkage values, which can be found, for example, in cooking shrinkage values (water, about 98 ° C.) in the order of 1%, preferably less than 0.5%, and in hot air shrinkage values (160 ° C.) on the order of about 2%, preferably less than 1%.
  • cooking shrinkage values water, about 98 ° C.
  • hot air shrinkage values 160 ° C.
  • a polyester multifilament yarn is preferably selected for this, the intrinsic viscosity of which is between 0.5 dl / g and 0.75 dl / g, preferably between 0.55 dl / g and 0.63 dl / g.
  • the polyester POY yarn described above is such a yarn whose chemical structure and in particular its molecular weight corresponds to a conventional textile standard multifilament yarn.
  • the aforementioned intrinsic viscosities represent values which are measured in corresponding solutions of the polymer in dichloroacetic acid at 25 ° C.
  • each pre-oriented multifilament yarn which is preferably polyester POY yarn
  • each pre-oriented multifilament yarn is drawn in such a way that this multifilament yarn is stretched over feeds a delivery godet wrapped in the yarn at a first speed to a main stretching zone.
  • the multifilament yarn is then withdrawn from the main drawing zone at a second speed via a take-off godet wrapped in the pre-oriented multifilament yarn, the second speed being 70% to 180%, preferably 100% to 160%, greater than the first speed.
  • the take-off godet is heated to a temperature between 160 ° C. and 240 ° C.
  • a degree of stretching of 1: 1.7 to 1: 2.8, preferably a degree of stretching of, is thus in the main stretching zone, which is formed exclusively from the delivery godet and the withdrawal godet 1: 2.0 to 1: 2.6.
  • these degrees of stretching are very high, surprisingly no filament breaks occur during such stretching, so that this stretching process is particularly insusceptible to faults.
  • the tensile strengths of a multifilament yarn stretched in this way are extremely high, ie, depending on the pre-oriented multifilament yarn (POY yarn) used, they are in the range between 60 cN / tex and 90 cN / tex, in particular between 71 cN / tex and 90 cN / tex .
  • a further development of the previously described embodiment variant of the method according to the invention provides that the delivery godet is also heated to a temperature between 60 ° C. and 160 ° C., preferably to a temperature between 80 ° C. and 140 ° C. heats up.
  • heating is carried out in the main stretching zone, i.e. between the delivery godet and the take-off godet, the pre-oriented multifilament yarn to a temperature between 80 ° C and 180 ° C.
  • This heating of the multifilament yarn in the main stretching zone is preferably carried out in such a way that a hot plate, an IR radiator and / or a laser are used for this purpose.
  • this residence time varies in particular between 0.01 s and 1 s.
  • the delivery godet and the take-off godet are looped with the pre-oriented multifilament yarn, as already described above. It has been shown here that particularly high strengths and particularly low shrinkage values of the stretched multifilament yarn result when the delivery godet and / or the take-off godet are looped 5 to 40 times, preferably 10 to 20 times, with the pre-oriented multifilament yarn.
  • These wrapping values refer to Godets, the diameter of which vary between approximately 40 mm and 250 mm, preferably 80 mm and 120 mm.
  • a pre-stretching zone is arranged in front of the main stretching zone, as seen in the transport direction of the pre-oriented multifilament yarn (POY yarn).
  • POY yarn which is preferably a polyester POY yarn, is first partially drawn in the pre-drawing zone and then finally drawn in the main drawing zone.
  • the pre-oriented multifilament yarn in the pre-stretching zone between 0.5% and 10%, preferably between 1% and 4%.
  • the pre-oriented multifilament yarn is thus lengthened in the pre-stretching zone between 0.5% and 10%, preferably between 1% and 4%.
  • the aforementioned high strengths and low shrinkage values can be achieved particularly economically and reproducibly if one selects take-off speeds that are greater than 300 m / min and preferably between 600 m / min and 1,200 m / min.
  • a relaxation zone is arranged behind the main drawing zone, in which the drawn multifilament yarn is heated to a temperature between 80 ° C and 240 ° C, preferably to a temperature between 140 ° C and 200 ° C, is heated. It has been shown here that such a relaxation zone further reduces the shrinkage values, in particular the cooking shrinkage value (water 98 ° C.) and the hot air shrinkage value (160 ° C.) of the drawn multifilament yarn. This is particularly true when the drawn multifilament yarn is introduced into the relaxation zone with lead, which is preferably between 0.5% and 10% and in particular between 1% and 3%.
  • the residence time of the multifilament yarn in the relaxation zone then varies depending on the respective transport speed of the yarn through the relaxation zone and is preferably 0.01 s to 1 s.
  • POY yarns used in the method according to the invention depends on the later use of the drawn yarn. POY multifilament yarns are preferably selected here whose single filament titer varies between 1 dtex and 12 dtex, preferably between 3 dtex and 8 dtex.
  • the titer of the pre-oriented multifilament yarn it should be noted that this varies between 40 dtex and 2,000 dtex, preferably between 80 dtex and 1,200 dtex.
  • the number of filaments of the pre-oriented multifilament yarn used is between 16 and 300, preferably between 24 and 96.
  • a further, particularly suitable embodiment of the processes described above provides that at least two, preferably two to four, of the core yarns produced by the processes described above are twisted together.
  • the resulting thread has excellent properties as a sewing thread, as has already been described for the thread.
  • a variant of the previously described embodiment of the method according to the invention provides that each core yarn is first individually twisted and then the core yarns present as pre-twine are twisted.
  • the twist coefficient ⁇ is between 90 and 140, the twist coefficient ⁇ being defined above for the yarn.
  • the subsequent twist of the twist is preferably carried out at a twist factor ⁇ between 120 and 180.
  • One embodiment of the core yarn according to the invention has particularly good results with regard to sewing behavior, the hairiness (sh) of between 2.5 and 7.5, in particular varies between 4 and 7. These hairiness values relate to measurement results as determined by the known method with a Uster yarn uniformity measuring device, type UT3.
  • the process according to the invention preferably uses a multifilament polyester core and a polyester spinning component as the starting material (second yarn component), so that accordingly a core yarn results which consists entirely of polyester.
  • Polyester in the sense of the present application is understood to mean polyethylene terephthalate.
  • a polyester POY yarn was pre-stretched between a delivery plant and a downstream delivery godet so that it was 5% elongated.
  • the temperature of the delivery godet was 100 ° C.
  • the pre-drawn multifilament yarn was then drawn in a main draw frame which consisted exclusively of the aforementioned delivery godet and a take-off godet at a draw ratio of 1: 2.4.
  • the temperature of the take-off godet was 160 ° C.
  • the polyester multifilament yarn was 20 times the supply godet and 20 times the Deduction godet wound. Both godets had a diameter of 150 mm.
  • the drawing speed was 600 m / min.
  • a thermal treatment (hot plate) was provided behind the take-off godet, the drawn multifilament yarn being introduced into the thermal aftertreatment with a lead of 3%.
  • the temperature of the thermal aftertreatment was 180 ° C., the residence time was 0.5 s.
  • the drawn polyester multifilament yarn which had a total denier of 138 dtex and a filament number of 30, was wound up.
  • the stretched polyester multifilament yarn described above was spun to form a core yarn with a polyester staple fiber (single fiber titer 1.3 dtex, staple length 38 mm). After spinning, the spun core yarn had a twist coefficient ⁇ of 105.7 and a titer of Nm 49.

Abstract

There is described a yarn, in particular a sewing yarn, containing at least one multifilament yarn component which forms a core. This multifilament yarn component has been overwrapped with at least a second yarn component to form a core yarn. The at least one multifilament yarn component forming the core of the core yarn is a customary textile standard multifilament yarn. The tenacity of the spun core yarn varies between 32 cN/tex and 55 cN/tex, preferably between 37 cN/tex and 48 cN/tex. There is also described a process for manufacturing the core yarn. It involves overspinning at least one multifilament yarn component serving as the core with a second yarn component. The at least one multifilament yarn component forming the core is a partially oriented (pre-oriented) multifilament yarn (POY) which in its molecular structure corresponds to a textile standard multifilament yarn. The multifilament yarn forming the core is drawn in such a way that its tenacity varies between 60 cN/tex and 90 cN/tex, in particular between 71 cN/tex and 90 cN/tex.

Description

Die vorliegende Erfindung betrifft ein Coregarn mit den Merkmalen des Oberbegriffs des Patentanspruchs 1 sowie ein Verfahren zur Herstellung eines derartiges Coregarnes mit den Merkmalen des Oberbegriffs des Patentanspruchs 16.The present invention relates to a core yarn with the features of the preamble of claim 1 and a method for producing such a core yarn with the features of the preamble of claim 16.

Garne und insbesondere Nähgarne sind in unterschiedlichen Konstruktionen bekannt.Yarns and especially sewing threads are known in different constructions.

So beschreibt beispielsweise die EP B1 0 367 938 ein Zweikomponentengarn, das mindestens eine multifile erste Garnkomponente, die im Inneren des Garnes angeordnet ist und die als Kernmaterial bezeichnet wird, und mindestens ein zweites, das Kernmaterial umhüllendes multifiles Effektmaterial aufweist. Hierbei sind die beiden zuvor genannten Multifilamentgarne derart miteinander verwirbelt, daß durch das Ineinanderverschlingen der beiden Garnmaterialien der erforderliche Fadenschluß resultiert. Um bei diesem bekannten verwirbelten Garn die erforderliche Garnfestigkeit sicherzustellen, wird als erstes Garnmaterial ein solches Filamentgarn verwendet, dessen spezifische Festigkeit bereits als Ausgangsmaterial im Vergleich zu einem textilen Standardgarn sehr hoch liegt. Mit anderen Worten lehrt somit die EP B 0367 938, als Ausgangsmaterial bereits ein hochfestes Multifilamentgarn einzusetzen.For example, EP B1 0 367 938 describes a two-component yarn which has at least one multifilament first yarn component, which is arranged in the interior of the yarn and which is referred to as the core material, and at least one second multifilament effect material enveloping the core material. Here, the two aforementioned multifilament yarns are intermingled with one another in such a way that the necessary thread closure is achieved by intertwining the two yarn materials results. In order to ensure the required yarn strength in this known intermingled yarn, such a filament yarn is used as the first yarn material, the specific strength of which is already very high as a starting material compared to a standard textile yarn. In other words, EP B 0367 938 thus teaches that a high-strength multifilament yarn is already used as the starting material.

Neben den zuvor beschriebenen verwirbelten Garnen sind noch Fasergarne oder Zwirne bekannt.In addition to the intermingled yarns described above, fiber yarns or threads are also known.

Ein Garn mit den Merkmalen des Oberbegriffs des Patentanspruchs 1 ist in der DE-PS 24 36 997 beschrieben. Hierbei weist das bekannte Garn ein multifiles Seelenmaterial auf, das mit einer zweiten Garnkomponente unter Ausbildung eines Coregarnes umsponnen ist. Das Seelenmaterial des bekannten Coregarnes besteht aus verstrecktem und fixiertem Multifilamentfasern, wobei üblicherweise hierfür ebenfalls die zuvor beim verwirbelten Garn beschriebenen hochfesten Multifilamentgarne eingesetzt werden. Diese hochfesten Multifilamentgarne sind im Vergleich zu einer textilen Standardfaser erheblich teuerer.A yarn with the features of the preamble of claim 1 is described in DE-PS 24 36 997. Here, the known yarn has a multifilament core material, which is wound with a second yarn component to form a core yarn. The core material of the well-known core yarn consists of stretched and fixed multifilament fibers, the high-strength multifilament yarns previously described for the intermingled yarn usually also being used for this. These high-strength multifilament yarns are considerably more expensive than standard textile fibers.

Der vorliegenden Erfindung liegt die Aufgabe zugrunde, ein Coregarn der angegebenen Art zur Verfügung zu stellen, das bei einem besonders günstigen Herstellungspreis eine extrem hohe Beständigkeit gegenüber mechanischen Beanspruchungen aufweist.The present invention has for its object to provide a core yarn of the type specified, which has an extremely high resistance to mechanical stresses at a particularly low manufacturing price.

Diese Aufgabe wird erfindungsgemäß durch ein Garn mit den kennzeichnenden Merkmalen des Patentanspruchs 1 gelöst.This object is achieved by a yarn with the characterizing features of claim 1.

Das erfindungsgemäße Garn, das insbesondere auch als Nahgarn verwendet wird, weist mindestens eine eine Seele ausbildende multifile Garnkomponente auf. Hierbei ist die die Seele ausbildende multifile Garnkomponente mit mindestens einer zweiten Garnkomponente unter Ausbildung des Coregarnes umsponnen. Die die Seele des Coregarnes bildende mindestens eine multifile Garnkomponente ist ein übliches textiles Standardmultifilamentgarn, wobei das gesponnene Coregarn eine spezifische Festigkeit zwischen 32 cN/tex und 55 cN/tex, vorzugsweise zwischen 37 cN/tex und 48 cN/tex, besitzt.The yarn according to the invention, which is also used in particular as a sewing thread, has at least one multifilament yarn component which forms a core. Here, the multifilament yarn component forming the core is wound with at least one second yarn component to form the core yarn. The core of the core yarn forming at least one multifilament yarn component is a conventional textile standard multifilament yarn, the spun core yarn having a specific strength between 32 cN / tex and 55 cN / tex, preferably between 37 cN / tex and 48 cN / tex.

Das erfindungsgemäße Coregarn weist eine Reihe von Vorteilen auf. So konnte überraschend festgestellt werden, daß ein derartiges Coregarn die zuvor wiedergegebenen hohen Festigkeiten zwischen 32 cN/tex und 55 cN/tex, insbesondere zwischen 37 cN/tex und 48 cN/tex, aufweist, obwohl zur Herstellung dieses Garnes ein Seelenmaterial eingesetzt wird, das abweichend vom vorstehend beschriebenen Stand der Technik kein hochfestes Multifilamentgarn sondern ein übliches textiles Standardmultifilamentgarn ist. Dies wiederum führt dazu, daß das erfindungsgemäße Coregarn besonders preiswert herstellbar ist. Wird das erfindungsgemäße Coregarn als Nähgarn eingesetzt, so zeichnet sich ein derartiges Nähgarn dadurch aus, daß es die hierfür üblichen Nähoperationen, so zum Beispiel ein multidirektionales Nähen oder das Nähen von Knopflöchern, selbst bei extrem hohen Nähgeschwindigkeiten von bis zu 7.000 Stichen pro Minute ohne eine Beschädigung des Coregarnes übersteht. Hierdurch wird erklärlich, daß das erfindungsgemäße Coregarn keine Störungen des Vernähens im Bereich der Konfektion verursacht.The core yarn according to the invention has a number of advantages. It was surprisingly found that a core yarn of this type has the previously stated high strengths between 32 cN / tex and 55 cN / tex, in particular between 37 cN / tex and 48 cN / tex, although a core material is used to produce this yarn. which, in contrast to the prior art described above, is not a high-strength multifilament yarn but a common textile standard multifilament yarn. This in turn leads to the core yarn according to the invention being particularly inexpensive to produce. If the core thread according to the invention is used as a sewing thread, such a sewing thread is characterized in that it performs the usual sewing operations, for example multidirectional sewing or buttonhole sewing, even at extremely high sewing speeds of up to 7,000 stitches per minute without one Damage to the core yarn survives. Hereby it is explained that the core yarn according to the invention does not cause any sewing disturbances in the area of the ready-to-wear.

Eine erste Ausführungsform des erfindungsgemäßen Coregarnes weist eine die Seele bildende multifile Garnkomponente auf, die eine Intrinsic-Viskosität zwischen 0,5 dl/g und 0,75 dl/g, insbesondere eine Intrinsic-Viskosität zwischen 0,55 dl/g und 0,63 dl/g, hat. Hierbei handelt es sich um eine multifile Polyestergarnkomponente. Die zuvor genannten Werte der Intrinsic-Viskosität geben den molekularen Aufbau (Molekulargewicht, chemische Zusammensetzung) des eingesetzten Polyestermultifilamentgarnes wieder, wobei mit zunehmender Viskosität sich auch der Kondensationsgrad der Polymeren entsprechend erhöht. Die zuvor wiedergegebenen Werte beziehen sich auf Polymerenlösungen in Dichloressigsäure bei 25 °C.A first embodiment of the core yarn according to the invention has a multifilament yarn component forming the core, which has an intrinsic viscosity between 0.5 dl / g and 0.75 dl / g, in particular an intrinsic viscosity between 0.55 dl / g and 0, 63 dl / g. This is a multifilament polyester yarn component. The values of the intrinsic viscosity mentioned above reflect the molecular structure (molecular weight, chemical composition) of the polyester multifilament yarn used, the degree of condensation of the polymers also correspondingly increasing with increasing viscosity. The values given above refer to polymer solutions in dichloroacetic acid at 25 ° C.

Bezüglich des Einzelfilamenttiters der die Seele bildenden multifilen Garnkomponente ist festzuhalten, daß bei dem erfindungsgemäßen Coregarn dieser Einzelfilamenttiter zwischen 0,6 dtex und 6 dtex, vorzugsweise zwischen 1,5 dtex und 4 dtex, variiert.With regard to the single-filament titer of the multifilament yarn component forming the core, it should be noted that in the core yarn according to the invention this single-filament titer varies between 0.6 dtex and 6 dtex, preferably between 1.5 dtex and 4 dtex.

Das erfindungsgemäße Coregarn weist insbesondere als Seele ein Multifilamentgarn (multifile Garnkomponente) auf, dessen Filamentzahl zwischen 16 und 300, vorzugsweise zwischen 24 und 96, variiert.The core yarn according to the invention in particular has a multifilament yarn (multifilament yarn component) as a core, the number of filaments of which varies between 16 and 300, preferably between 24 and 96.

Bezüglich der zweiten Garnkomponente, die mit der Seele versponnen ist, ist festzuhalten, daß hierfür jedes Garn geeignet ist, das die Seele hinreichend nach außen hin abdeckt. Vorzugsweise wird als zweite Garnkomponente ein Fasergarn aus Polyamid-6-, Polyamid-6.6-, Baumwoll- und/oder insbesondere Polyesterfasern eingesetzt.Regarding the second yarn component, which is spun with the core, it should be noted that any yarn is suitable for this is that the soul adequately covers the outside. A fiber yarn made of polyamide 6, polyamide 6.6, cotton and / or in particular polyester fibers is preferably used as the second yarn component.

Eine besonders hohe Festigkeit weisen solche Ausführungsformen des erfindungsgemäßen Coregarnes auf, bei denen die zweite Garnkomponente mindestens ein Fasergarn umfaßt, dessen spezifische Festigkeit zwischen 40 cN/tex und 70 cN/tex variiert.Embodiments of the core yarn according to the invention have a particularly high strength in which the second yarn component comprises at least one fiber yarn, the specific strength of which varies between 40 cN / tex and 70 cN / tex.

Weist das erfindungsgemäße Coregarn als zweites Garnkomponente ein Fasergarn auf, so variiert hierbei die Stapellänge der einzelnen Fasern des Fasergarnes zwischen 15 mm und 120 mm, insbesondere zwischen 20 mm und 60 mm.If the core yarn according to the invention has a fiber yarn as the second yarn component, the staple length of the individual fibers of the fiber yarn varies between 15 mm and 120 mm, in particular between 20 mm and 60 mm.

Bezüglich des Einzelfasertiters der als Fasergarn vorliegenden zweiten Garnkomponente ist festzuhalten, daß dieser zwischen 0,6 dtex und 4 dtex, vorzugsweise zwischen 0,8 dtex und 2 dtex, variiert.With regard to the individual fiber titer of the second yarn component present as fiber yarn, it should be noted that this varies between 0.6 dtex and 4 dtex, preferably between 0.8 dtex and 2 dtex.

Eine besonders geeignete Ausführungsform des erfindungsgemäßen Garnes sieht vor, daß das Garn mindestens zwei, vorzugsweise zwei bis vier, miteinander verzwirnte Coregarne umfaßt, wobei jedes einzelne Coregarn den zuvor oder nachfolgend noch beschriebenen Aufbau aufweist. Hierbei besitzt das entsprechend ausgezwirnte Garn vorzugsweise einen Drehungsbeiwert α zwischen 120 und 180, wobei der Drehungsbeiwert α wie folgt definiert ist:

Figure imgb0001

Ein derartig ausgezwirntes Garn, das, wie bereits vorstehend beschrieben, mindestens zwei, vorzugsweise zwei bis vier, miteinander verzwirnte Coregarne umfaßt, kann insbesondere auch ausgezeichnet als Nähgarn eingesetzt werden, da ein derartiges Nähgarn beispielsweise ein multidirektionales Nähen oder ein Nähen von Knopflöchern mit hohen Stichdichten (bis zu 7.000 Stiche pro Minute) ohne Garnriß übersteht.A particularly suitable embodiment of the yarn according to the invention provides that the yarn comprises at least two, preferably two to four core yarns twisted together, each individual core yarn having the structure described above or below. The correspondingly twisted yarn preferably has a twist coefficient α between 120 and 180, the twist coefficient α being defined as follows:
Figure imgb0001

Such a twisted yarn, which, as already described above, comprises at least two, preferably two to four, twisted core yarns, can also be used particularly well as a sewing thread, since such a sewing thread, for example, multidirectional sewing or sewing buttonholes with high stitch densities (up to 7,000 stitches per minute) without yarn break.

Die zuvor beschriebenen erfindungsgemäßen Garne besitzen einen Gesamttiter, der zwischen 100 dtex und 1.400 dtex, vorzugsweise zwischen 100 dtex und 600 dtex, liegt.The yarns according to the invention described above have a total titer which is between 100 dtex and 1,400 dtex, preferably between 100 dtex and 600 dtex.

Das Massenverhältnis von Seele zur zweiten Garnkomponente variiert bei dem erfindungsgemäßen Garn von 70 % (Masse der Seele) zu 30 % (Masse der zweiten Garnkomponente) bis 30 % (Masse der Seele) zu 70 % (Masse der zweiten Garnkomponente).The mass ratio of core to second yarn component varies in the yarn according to the invention from 70% (mass of core) to 30% (mass of the second yarn component) to 30% (mass of core) to 70% (mass of the second yarn component).

Um ein einfaches Anfärben mit einer Farbstoffklasse von Seelenmaterial und gleichzeitig der zweiten Garnkomponente sicherzustellen, empfiehlt es sich, daß das erfindungsgemäße Garn sowohl als Seele als auch als zweites Garnkomponente das gleiche, vorstehend genannte Fasersubstrat aufweist. Selbstverständlich ist es jedoch auch möglich, daß das erfindungsgemäße Garn unterschiedliche Fasersubstrate in der Seele und als zweite Garnkomponente besitzt.In order to ensure a simple dyeing with a dye class of core material and at the same time the second yarn component, it is recommended that the yarn according to the invention have the same fiber substrate mentioned above both as core and as a second yarn component. Of course, however, it is also possible that the invention Yarn has different fiber substrates in the soul and as a second yarn component.

Der vorliegenden Erfindung liegt desweiteren die Aufgabe zugrunde, ein Herstellungsverfahren zur Verfügung zu stellen, mit dem das zuvor beschriebene erfindungsgemäße Garn besonders wirtschaftlich gesponnen werden kann.The present invention is also based on the object of providing a production method with which the yarn according to the invention described above can be spun particularly economically.

Diese Aufgabe wird durch ein Verfahren mit den Merkmalen des Patentanspruchs 16 gelöst.This object is achieved by a method having the features of patent claim 16.

Das erfindungsgemäße Verfahren zur Herstellung der zuvor beschriebenen Garne sieht vor, daß man mindestens eine als Seele dienende multifile Garnkomponente mit einer zweiten Garnkomponente unter Ausbildung des Coregarne verspinnt. Hierbei wählt man für die die Seele bildende mindestens eine multifile Garnkomponente ein vororientiertes Multifilamentgarn (POY-Garn) aus, wobei das mindestens eine vororientierte Multifilamentgarn (POY-Garn) in seinem Molekulargewicht einem textilen Standardmultifilamentgarn entspricht. Dieses vororientierte Multifilamentgarn (POY-Garn) verstreckt man derart, daß seine Festigkeit zwischen 60 cN/tex und 90 cN/tex, insbesondere zwischen 71 cN/tex und 90 cN/tex, variiert.The process according to the invention for producing the yarns described above provides that at least one multifilament yarn component serving as a core is spun with a second yarn component to form the core yarns. Here, a pre-oriented multifilament yarn (POY yarn) is selected for the soul-forming at least one multifilament yarn component, the molecular weight of the at least one pre-oriented multifilament yarn (POY yarn) corresponding to a textile standard multifilament yarn. This pre-oriented multifilament yarn (POY yarn) is drawn in such a way that its strength varies between 60 cN / tex and 90 cN / tex, in particular between 71 cN / tex and 90 cN / tex.

Das erfindungsgemäße Verfahren weist eine Reihe von Vorteilen auf. So ist zunächst festzuhalten, daß das erfindungsgemaße Verfahren unter Einsatz von relativ preisgünstigen Rohstoffen zu einem hochwertigen Garn, insbesondere Nähgarn, führt, das sich dadurch auszeichnet, daß es selbst bei extremen Nähbelastungen nicht reißt. Außerdem weist ein derartig hergestelltes Garn bzw. Nähgarn geringe Restschrumpfwerte auf, die sich beispielsweise in Kochschrumpfwerten (Wasser, etwa 98 °C) in der Größenordnung von 1 %, vorzugsweise weniger als 0,5 %, und in Heißluftschrumpfwerten (160 °C) in der Größenordnung von etwa 2 %, vorzugsweise unter 1 %, ausdrücken. Dies wiederum führt dazu, daß bei einer Verwendung des nach dem erfindungsgemäßen Verfahren hergestellten Garnes als Nähgarn kein Boldern von Nähten auftritt, wenn die hiermit vernähten konfektionierten Teile gedämpft, gebügelt oder beim späteren Gebrauch gewaschen werden.The method according to the invention has a number of advantages. It should first be noted that the method according to the invention, using relatively inexpensive raw materials, leads to a high-quality yarn, in particular sewing thread, which is distinguished by the fact that it is used even under extreme sewing loads does not tear. In addition, a thread or sewing thread produced in this way has low residual shrinkage values, which can be found, for example, in cooking shrinkage values (water, about 98 ° C.) in the order of 1%, preferably less than 0.5%, and in hot air shrinkage values (160 ° C.) on the order of about 2%, preferably less than 1%. This in turn leads to the fact that when the yarn produced by the method according to the invention is used as sewing thread, there is no seaming when the assembled parts sewn with it are steamed, ironed or washed during later use.

Bezüglich der Auswahl des zuvor beschriebenen POY-Garnes (Seelenmaterial) ist festzuhalten, daß hierfür vorzugsweise ein Polyester-Multifilamentgarn ausgewählt wird, dessen Intrinsic-Viskosität zwischen 0,5 dl/g und 0,75 dl/g, vorzugsweise zwischen 0,55 dl/g und 0,63 dl/g, variiert. Somit handelt es sich bei dem zuvor beschriebenen Polyester-POY-Garn um ein solches Garn, dessen chemischer Aufbau und insbesondere dessen Molekulargewicht einem üblichen textilen Standardmultifilamentgarnen entspricht. Die zuvor genannten Intrinsic-Viskositäten stellen solche Werte dar, die in entsprechenden Lösungen des Polymeren in Dichloressigsäure bei 25 °C gemessen sind.Regarding the selection of the POY yarn (core material) described above, it should be noted that a polyester multifilament yarn is preferably selected for this, the intrinsic viscosity of which is between 0.5 dl / g and 0.75 dl / g, preferably between 0.55 dl / g and 0.63 dl / g. Thus, the polyester POY yarn described above is such a yarn whose chemical structure and in particular its molecular weight corresponds to a conventional textile standard multifilament yarn. The aforementioned intrinsic viscosities represent values which are measured in corresponding solutions of the polymer in dichloroacetic acid at 25 ° C.

Bei einer besonders geeigneten Ausführungsform des erfindungsgemäßen Verfahrens verstreckt man jedes vororientierte Multifilamentgarn, bei dem es sich vorzugsweise um Polyester-POY-Garne handelt, derart, daß man dieses Multifilamentgarn über eine vom Garn umschlungene Liefergalette mit einer ersten Geschwindigkeit einer Hauptstreckzone zuführt. Über eine von dem vororientierten Multifilamentgarn umschlungene Abzugsgalette zieht man dann das Multifilamentgarn mit einer zweiten Geschwindigkeit aus der Hauptstreckzone ab, wobei die zweite Geschwindigkeit 70 % bis 180 %, vorzugsweise 100 % bis 160 %, größer ist als die erste Geschwindigkeit. Die Abzugsgalette wird bei dieser Ausführungsform des erfindungsgemäßen Verfahrens auf eine Temperatur zwischen 160 °C und 240 °C aufgeheizt. Bedingt durch die zuvor wiedergegebenen Geschwindigkeitsdifferenzen zwischen der ersten Geschwindigkeit und der zweiten Geschwindigkeit wird somit in der Hauptstreckzone, die ausschließlich aus der Liefergalette und der Abzugsgalette gebildet ist, ein Verstreckungsgrad von 1:1,7 bis 1:2,8, vorzugsweise ein Verstreckungsgrad von 1:2,0 bis 1:2,6, erreicht. Obwohl diese Verstreckungsgrade sehr hoch liegen, treten bei einem derartigen Verstrecken überraschenderweise keine Filamentbrüche auf, so daß dieses Verstreckungsverfahren besonders störungsunanfällig ist. Desweiteren sind die Reißfestigkeiten eines derart verstreckten Multifilamentgarnes extrem hoch, d.h. sie liegen abhängig von dem jeweils eingesetzten vororientierten Multifilamentgarn (POY-Garn) im Bereich zwischen 60 cN/tex und 90 cN/tex, insbesondere zwischen 71 cN/tex und 90 cN/tex.In a particularly suitable embodiment of the method according to the invention, each pre-oriented multifilament yarn, which is preferably polyester POY yarn, is drawn in such a way that this multifilament yarn is stretched over feeds a delivery godet wrapped in the yarn at a first speed to a main stretching zone. The multifilament yarn is then withdrawn from the main drawing zone at a second speed via a take-off godet wrapped in the pre-oriented multifilament yarn, the second speed being 70% to 180%, preferably 100% to 160%, greater than the first speed. In this embodiment of the method according to the invention, the take-off godet is heated to a temperature between 160 ° C. and 240 ° C. Due to the previously described speed differences between the first speed and the second speed, a degree of stretching of 1: 1.7 to 1: 2.8, preferably a degree of stretching of, is thus in the main stretching zone, which is formed exclusively from the delivery godet and the withdrawal godet 1: 2.0 to 1: 2.6. Although these degrees of stretching are very high, surprisingly no filament breaks occur during such stretching, so that this stretching process is particularly insusceptible to faults. Furthermore, the tensile strengths of a multifilament yarn stretched in this way are extremely high, ie, depending on the pre-oriented multifilament yarn (POY yarn) used, they are in the range between 60 cN / tex and 90 cN / tex, in particular between 71 cN / tex and 90 cN / tex .

Eine Weiterbildung der zuvor beschriebenen Ausführungsvariante des erfindungsgemäßen Verfahrens sieht vor, daß man auch die Liefergalette auf eine Temperatur zwischen 60 °C und 160 °C, vorzugsweise auf eine Temperatur zwischen 80 °C bis 140 °C, aufheizt.A further development of the previously described embodiment variant of the method according to the invention provides that the delivery godet is also heated to a temperature between 60 ° C. and 160 ° C., preferably to a temperature between 80 ° C. and 140 ° C. heats up.

Bei einer weiteren Ausführungsvariante des zuvor beschriebenen erfindungsgemäßen Verfahrens heizt man in der Hauptstreckzone, d.h. somit zwischen der Liefergalette und der Abzugsgalette, das vororientierte Multifilamentgarn auf eine Temperatur zwischen 80 °C und 180 °C auf. Hierbei wird diese Aufheizung des Multifilamentgarnes in der Hauptstreckzone vorzugsweise derart durchgeführt, daß man zu diesem Zwecke insbesondere eine hot plate, einen IR-Strahler und/oder einen Laser verwendet.In a further embodiment variant of the method according to the invention described above, heating is carried out in the main stretching zone, i.e. between the delivery godet and the take-off godet, the pre-oriented multifilament yarn to a temperature between 80 ° C and 180 ° C. This heating of the multifilament yarn in the main stretching zone is preferably carried out in such a way that a hot plate, an IR radiator and / or a laser are used for this purpose.

Bezüglich der Zeit, bei dem man das vororientierte Multifilamentgarn in der Hauptstreckzone aufheizt und auf die zuvor genannten Temperaturen (80 °C bis 180 °C) verweilen läßt, ist festzuhalten, daß diese Verweilzeit insbesondere zwischen 0,01 s und 1 s variiert.Regarding the time at which the pre-oriented multifilament yarn is heated in the main stretching zone and allowed to dwell at the aforementioned temperatures (80 ° C. to 180 ° C.), it should be noted that this residence time varies in particular between 0.01 s and 1 s.

Um bei den zuvor beschriebenen Ausführungsformen des erfindungsgemäßen Verfahrens die für die Verstreckung in der Hauptstreckzone erforderlichen Klemmpunkte zu erhalten, werden, wie bereits vorstehend beschrieben ist, die Liefergalette und die Abzugsgalette mit dem vororientierten Multifilamentgarn umschlungen. Hier hat es sich gezeigt, daß insbesondere dann besonders hohe Festigkeiten und besonders geringe Schrumpfwerte des verstreckten Multifilamentgarnes resultieren, wenn die Liefergalette und/oder die Abzugsgalette mit dem vororientierten Multifilamentgarn 5 bis 40mal, vorzugsweise 10 bis 20mal, umschlungen wird. Diese Umschlingungswerte beziehen sich auf Galetten, deren Durchmesser zwischen etwa 40 mm und 250 mm, vorzugsweise 80 mm und 120 mm, variieren.In order to obtain the clamping points required for drawing in the main drawing zone in the previously described embodiments of the method according to the invention, the delivery godet and the take-off godet are looped with the pre-oriented multifilament yarn, as already described above. It has been shown here that particularly high strengths and particularly low shrinkage values of the stretched multifilament yarn result when the delivery godet and / or the take-off godet are looped 5 to 40 times, preferably 10 to 20 times, with the pre-oriented multifilament yarn. These wrapping values refer to Godets, the diameter of which vary between approximately 40 mm and 250 mm, preferably 80 mm and 120 mm.

Eine andere, besonders geeignete Weiterbildung der zuvor beschriebenen Ausführungsvarianten des erfindungsgemäßen Verfahrens sieht vor, daß man in Transportrichtung des vororientierten Multifilamentgarnes (POY-Garn) gesehen vor der Hauptstreckzone eine Vorverstreckungszone anordnet. Mit anderen Worten wird hierbei somit das vororientierte Multifilamentgarn (POY-Garn), bei dem es sich vorzugsweise um ein Polyester-POY-Garn handelt, zunächst in der Vorverstreckungszone teilweise verstreckt und anschließend in der Hauptstreckzone endverstreckt.Another, particularly suitable development of the previously described embodiment variants of the method according to the invention provides that a pre-stretching zone is arranged in front of the main stretching zone, as seen in the transport direction of the pre-oriented multifilament yarn (POY yarn). In other words, the pre-oriented multifilament yarn (POY yarn), which is preferably a polyester POY yarn, is first partially drawn in the pre-drawing zone and then finally drawn in the main drawing zone.

Bei der zuvor beschriebenen Weiterbildung des erfindungsgemäßen Verfahrens bietet es sich an, das vororientierte Multifilamentgarn in der Vorverstreckungszone zwischen 0,5 % und 10 %, vorzugsweise zwischen 1 % und 4 %, vorzuverstrecken, d.h. das vororientierte Multifilamentgarn wird somit in der Vorverstreckungszone zwischen 0,5 % und 10 %, vorzugsweise zwischen 1 % und 4 %, gelängt.In the development of the method according to the invention described above, it is advisable to pre-stretch the pre-oriented multifilament yarn in the pre-stretching zone between 0.5% and 10%, preferably between 1% and 4%. the pre-oriented multifilament yarn is thus lengthened in the pre-stretching zone between 0.5% and 10%, preferably between 1% and 4%.

Bezüglich der Vorverstreckungs- bzw. Verstreckungsgeschwindigkeiten ist festzuhalten, daß man dann besonders wirtschaftlich und reproduzierbar die zuvor genannten hohen Festigkeiten und geringen Schrumpfwerte erzielt, wenn man Abzugsgeschwindigkeiten auswählt, die größer als 300 m/min sind und vorzugsweise zwischen 600 m/min und 1.200 m/min liegen.Regarding the pre-drawing or drawing speeds, it should be noted that the aforementioned high strengths and low shrinkage values can be achieved particularly economically and reproducibly if one selects take-off speeds that are greater than 300 m / min and preferably between 600 m / min and 1,200 m / min.

Um durch das zuvor beschriebene Verstreckungsverfahren ein besonders schrumpfarmes und verstrecktes Garn zu erzeugen, sieht eine andere, besonders geeignete Weiterbildung des zuvor beschriebenen Verfahrens vor, daß in Transportrichtung des Multifilamentgarnes gesehen hinter der Hauptstreckzone eine Relaxierzone angeordnet ist, in der das verstreckte Multifilamentgarn auf eine Temperatur zwischen 80 °C und 240 °C, vorzugsweise auf eine Temperatur zwischen 140 °C und 200 °C, erwärmt wird. Hier hat sich gezeigt, daß eine derartige Relaxierzone die Schrumpfwerte, insbesondere den Kochschrumpfwert (Wasser 98 °C) und den Heißluftschrumpfwert (160 °C) des verstreckten Multifilamentgarnes weiter reduziert. Dies trifft insbesondere dann im verstärkten Maße zu, wenn man das verstreckte Multifilamentgarn in die Relaxierzone mit Voreilung, die vorzugsweise zwischen 0,5 % und 10 % und insbesondere zwischen 1 % und 3 % liegt, einführt.In order to produce a particularly low-shrinkage and drawn yarn by the previously described drawing process, another, particularly suitable development of the previously described process provides that, viewed in the direction of transport of the multifilament yarn, a relaxation zone is arranged behind the main drawing zone, in which the drawn multifilament yarn is heated to a temperature between 80 ° C and 240 ° C, preferably to a temperature between 140 ° C and 200 ° C, is heated. It has been shown here that such a relaxation zone further reduces the shrinkage values, in particular the cooking shrinkage value (water 98 ° C.) and the hot air shrinkage value (160 ° C.) of the drawn multifilament yarn. This is particularly true when the drawn multifilament yarn is introduced into the relaxation zone with lead, which is preferably between 0.5% and 10% and in particular between 1% and 3%.

Die Verweilzeit des Multifilamentgarnes in der Relaxierzone variiert dann abhängig von der jeweiligen Transportgeschwindigkeit des Garnes durch die Relaxierzone und beträgt vorzugsweise 0,01 s bis 1 s.The residence time of the multifilament yarn in the relaxation zone then varies depending on the respective transport speed of the yarn through the relaxation zone and is preferably 0.01 s to 1 s.

Die Auswahl des bei dem erfindungsgemäßen Verfahren eingesetzten Multifilamentgarnes (POY-Garnes) richtet sich nach der späteren Verwendung des verstreckten Garnes. Vorzugsweise werden hier solche POY-Multifilamentgarne ausgewählt, deren Einzelfilamenttiter zwischen 1 dtex und 12 dtex, vorzugsweise zwischen 3 dtex und 8 dtex, variiert.The selection of the multifilament yarn (POY yarns) used in the method according to the invention depends on the later use of the drawn yarn. POY multifilament yarns are preferably selected here whose single filament titer varies between 1 dtex and 12 dtex, preferably between 3 dtex and 8 dtex.

Bezüglich des Titers des vororientierten Multifilamentgarnes ist festzuhalten, daß dieser zwischen 40 dtex und 2.000 dtex, vorzugsweise zwischen 80 dtex und 1.200 dtex, variiert. Die Elementarfadenzahl des eingesetzten vororientierten Multifilamentgarnes liegt zwischen 16 und 300, vorzugsweise zwischen 24 und 96.Regarding the titer of the pre-oriented multifilament yarn, it should be noted that this varies between 40 dtex and 2,000 dtex, preferably between 80 dtex and 1,200 dtex. The number of filaments of the pre-oriented multifilament yarn used is between 16 and 300, preferably between 24 and 96.

Eine weitere, besonders geeignete Ausführungsform der zuvor beschriebenen Verfahren sieht vor, daß man mindestens zwei, vorzugsweise zwei bis vier der nach den vorstehend beschriebenen Verfahren hergestellten Coregarne miteinander verzwirnt. Der hierbei entstehende Zwirn besitzt als Nähgarn ausgezeichnete Eigenschaften, wie dies bereits vorstehend bei dem Garn beschrieben ist.A further, particularly suitable embodiment of the processes described above provides that at least two, preferably two to four, of the core yarns produced by the processes described above are twisted together. The resulting thread has excellent properties as a sewing thread, as has already been described for the thread.

Eine Variante der zuvor beschriebenen Ausführungsform des erfindungsgemäßen Verfahrens sieht vor, daß man zunachst jedes Coregarn einzeln mit einer Garndrehung und anschließend die als Vorzwirn vorliegenden Coregarne mit der Zwirndrehung versieht. Hierbei wählt man vorzugsweise eine Garndrehung aus, der Drehungsbeiwert α zwischen 90 und 140 liegt, wobei der Drehungsbeiwert α vorstehend beim Garn definiert ist. Die sich hieran anschließende Zwirndrehung wird vorzugsweise bei einem Drehungsbeiwert α zwischen 120 und 180 durchgeführt.A variant of the previously described embodiment of the method according to the invention provides that each core yarn is first individually twisted and then the core yarns present as pre-twine are twisted. Here, one preferably selects a yarn twist, the twist coefficient α is between 90 and 140, the twist coefficient α being defined above for the yarn. The subsequent twist of the twist is preferably carried out at a twist factor α between 120 and 180.

Besonders gute Ergebnisse bezüglich des Nähverhaltens weist eine Ausführungsform des erfindungsgemäßen Coregarnes auf, deren Haarigkeit (sh) zwischen 2,5 und 7,5, insbesondere zwischen 4 und 7, variiert. Hierbei beziehen sich diese Werte der Haarigkeit auf Meßergebnisse, wie diese nach dem bekannten Verfahren mit einem Uster-Garngleichmäßigkeitsmeßgerät, Typ UT3, bestimmt werden.One embodiment of the core yarn according to the invention has particularly good results with regard to sewing behavior, the hairiness (sh) of between 2.5 and 7.5, in particular varies between 4 and 7. These hairiness values relate to measurement results as determined by the known method with a Uster yarn uniformity measuring device, type UT3.

Wie dies bereits vorstehend mehrfach erwähnt ist, setzt das erfindungsgemäße Verfahren als Ausgangsmaterial vorzugsweise eine multifile Polyester-Seele und eine Polyester-Umspinnungskomponente auf (zweite Garnkomponente) ein, so daß dementsprechend ein Coregarn resultiert, das vollständig aus Polyester besteht. Hierbei wird unter Polyester im Sinne der vorliegenden Anmeldung Polyethylenterephthalat verstanden.As has already been mentioned several times above, the process according to the invention preferably uses a multifilament polyester core and a polyester spinning component as the starting material (second yarn component), so that accordingly a core yarn results which consists entirely of polyester. Polyester in the sense of the present application is understood to mean polyethylene terephthalate.

Vorteilhafte Weiterbildungen des erfindungsgemäßen Garnes sowie des erfindungsgemäßen Verfahrens sind in den Unteransprüchen angegeben.Advantageous developments of the yarn according to the invention and of the method according to the invention are specified in the subclaims.

Das erfindungsgemäße Verfahren wird nachfolgend anhand eines Ausführungsbeispiels näher erläutert.The method according to the invention is explained in more detail below using an exemplary embodiment.

Ein Polyester-POY-Garn wurde zwischen einem Lieferwerk und einer hier nachgeschalteten Liefergalette derart vorverstreckt, daß es 5 % gelängt wurde. Hierbei betrug die Temperatur der Liefergalette 100 °C. Anschließend wurde das vorverstreckte Multifilamentgarn in einer Hauptstrecke, die ausschließlich aus der zuvor genannten Liefergalette und einer Abzugsgalette bestand, bei einem Verstreckungsgrad von 1:2,4 verstreckt. Die Temperatur der Abzugsgalette betrug 160 °C. Das Polyester-Multifilamentgarn war 20mal um die Liefergalette und 20mal um die Abzugsgalette gewunden. Beide Galetten wiesen einen Durchmesser von 150 mm auf. Die Verstreckungsgeschwindigkeit betrug 600 m/min.A polyester POY yarn was pre-stretched between a delivery plant and a downstream delivery godet so that it was 5% elongated. The temperature of the delivery godet was 100 ° C. The pre-drawn multifilament yarn was then drawn in a main draw frame which consisted exclusively of the aforementioned delivery godet and a take-off godet at a draw ratio of 1: 2.4. The temperature of the take-off godet was 160 ° C. The polyester multifilament yarn was 20 times the supply godet and 20 times the Deduction godet wound. Both godets had a diameter of 150 mm. The drawing speed was 600 m / min.

Hinter der Abzugsgalette war eine thermische Behandlung (hot plate) vorgesehen, wobei das verstreckte Multifilamentgarn in die thermische Nachbehandlung mit einer Voreilung von 3 % eingeführt wurde. Die Temperatur der thermischen Nachbehandlung lag bei 180 °C, die Verweilzeit betrug 0,5 s.A thermal treatment (hot plate) was provided behind the take-off godet, the drawn multifilament yarn being introduced into the thermal aftertreatment with a lead of 3%. The temperature of the thermal aftertreatment was 180 ° C., the residence time was 0.5 s.

Am Auslaß der thermischen Nachbehandlung wurde das verstreckte Polyestermultifilamentgarn, das einen Gesamttiter von 138 dtex und eine Filamentzahl von 30 aufwies, aufgewickelt.At the outlet of the thermal aftertreatment, the drawn polyester multifilament yarn, which had a total denier of 138 dtex and a filament number of 30, was wound up.

Das vorstehend beschriebene verstreckte Polyestermultifilamentgarn wurde unter Ausbildung eines Coregarnes mit einer Polyester-Stapelfaser (Einzelfasertiter 1,3 dtex, Stapellänge 38 mm) versponnen. Das gesponnene Coregarn wies nach dem Spinnen einen Drehungsbeiwert α von 105,7 und einen Titer von Nm 49 auf.The stretched polyester multifilament yarn described above was spun to form a core yarn with a polyester staple fiber (single fiber titer 1.3 dtex, staple length 38 mm). After spinning, the spun core yarn had a twist coefficient α of 105.7 and a titer of Nm 49.

Zwei dieser so hergestellten Coregarne wurden unter Ausbildung eines Nähzwirns miteinander verzwirnt, wobei das ausgezwirnte Nähgarn einen Drehungsbeiwert α von 153,5 aufwies.Two of these core threads produced in this way were twisted together to form a sewing thread, the twisted thread having a twist factor α of 153.5.

Nach dem Färben und Avivieren wurde das Nähverhalten des zuvor beschriebenen Nähzwirnes geprüft. Hier konnte festgestellt werden, daß dieser Nähzwirn, der aus zwei miteinander verzwirnten Coregarnen bestand, ein ausgezeichnetes Nähverhalten aufwies, was sich dadurch ausdrückte, daß der Nähzwirn weder beim multidirektionalen Nähen mit bis zu 7.000 Stichen pro Minute noch beim Knopflochnähen riß.After dyeing and finishing, the sewing behavior of the sewing thread described above was checked. It was found here that this sewing thread, which consisted of two core threads twisted together, had excellent sewing behavior showed, which was expressed in that the sewing thread did not tear when multidirectional sewing at up to 7,000 stitches per minute or when buttonhole sewing.

Claims (36)

Garn, insbesondere Nähgarn, mit mindestens einer eine Seele ausbildenden multifilen Garnkomponente, die mit mindestens einer zweiten Garnkomponente unter Ausbildung eines Coregarnes umsponnen ist, dadurch gekennzeichnet, daß die die Seele des Coregarnes bildende mindestens eine multifile Garnkomponente ein übliches textiles Standardmultifilamentgarn ist und daß die spezifische Festigkeit des gesponnenen Coregarnes zwischen 32 cN/tex und 55 cN/tex, insbesondere zwischen 37 cN/tex und 48 cN/tex, variiert.Yarn, in particular sewing thread, with at least one multifilament yarn component forming a core, which is wound with at least a second yarn component to form a core yarn, characterized in that the core of the core yarn forming at least one multifilament yarn component is a customary standard textile multifilament yarn and that the specific The strength of the spun core yarn varies between 32 cN / tex and 55 cN / tex, in particular between 37 cN / tex and 48 cN / tex. Garn nach Anspruch 1, dadurch gekennzeichnet, daß die die Seele bildende multifile Garnkomponente eine Intrinsic-Viskosität zwischen 0,5 dl/g und 0,75 dl/g aufweist.Yarn according to claim 1, characterized in that the multifilament yarn component forming the core has an intrinsic viscosity between 0.5 dl / g and 0.75 dl / g. Garn nach Anspruch 2, dadurch gekennzeichnet, daß die die Seele bildende multifile Garnkomponente eine Intrinsic-Viskosität zwischen 0,55 dl/g und 0,63 dl/g aufweist.Yarn according to claim 2, characterized in that the multifilament yarn component forming the core has an intrinsic viscosity between 0.55 dl / g and 0.63 dl / g. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die die Seele bildende multifile Garnkomponente aus Polyester besteht.Yarn according to one of the preceding claims, characterized in that the multifilament yarn component forming the core consists of polyester. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die die Seele bildende multifile Garnkomponente einen Einzelfilamenttiter zwischen 0,6 dtex und 6 dtex, vorzugsweise einen Einzelfilamenttiter zwischen 1,5 dtex und 4 dtex, aufweist.Yarn according to one of the preceding claims, characterized in that the multifilament yarn component forming the core has a single filament titer between 0.6 dtex and 6 dtex, preferably a single filament titer between 1.5 dtex and 4 dtex. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die die Seele bildende multifile Garnkomponente eine Filamentzahl zwischen 16 und 300, vorzugsweise eine Filamentzahl zwischen 24 und 96, besitzt.Yarn according to one of the preceding claims, characterized in that the multifilament yarn component forming the core has a filament number between 16 and 300, preferably a filament number between 24 and 96. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die zweite Garnkomponente ein Fasergarn aus Polyester-, Polyamid-6-, Polyamid-6.6- und/oder Baumwollfaser ist.Yarn according to one of the preceding claims, characterized in that the second yarn component is a fiber yarn made of polyester, polyamide-6, polyamide-6.6 and / or cotton fiber. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die zweite Garnkomponente mindestens ein Fasergarn umfaßt, dessen spezifische Festigkeit zwischen 40 cN/tex und 70 cN/tex variiert.Yarn according to one of the preceding claims, characterized in that the second yarn component comprises at least one fiber yarn, the specific strength of which varies between 40 cN / tex and 70 cN / tex. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die zweite Garnkomponente ein Fasergarn mit einer Stapellänge der Einzelfaser zwischen 15 mm und 120 mm, insbesondere zwischen 20 mm und 60 mm, aufweist.Yarn according to one of the preceding claims, characterized in that the second yarn component has a fiber yarn with a staple length of the individual fiber between 15 mm and 120 mm, in particular between 20 mm and 60 mm. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die zweite Garnkomponente ein Fasergarn aufweist, dessen Fasern einen Einzelfasertiter zwischen 0,6 dtex und 4 dtex, vorzugsweise zwischen 0,8 dtex und 2 dtex, besitzen.Yarn according to one of the preceding claims, characterized in that the second yarn component has a fiber yarn, the fibers of which have a single fiber titer between 0.6 dtex and 4 dtex, preferably between 0.8 dtex and 2 dtex. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß das Garn mindestens zwei, vorzugsweise zwei bis vier, miteinander verzwirnte Coregarne umfaßt.Yarn according to one of the preceding claims, characterized in that the yarn comprises at least two, preferably two to four, twisted core yarns. Garn nach Anspruch 11, dadurch gekennzeichnet, daß das ausgezwirnte Garn einen Drehungsbeiwert α zwischen 120 und 180 aufweist.Yarn according to claim 11, characterized in that the twisted yarn has a twist coefficient α between 120 and 180. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß es einen Gesamttiter zwischen 100 dtex und 1.400 dtex, vorzugsweise einen Gesamttiter zwischen 100 dtex und 600 dtex, besitzt.Yarn according to one of the preceding claims, characterized in that it has a total titer between 100 dtex and 1,400 dtex, preferably a total titer between 100 dtex and 600 dtex. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß es ein Massenverhältnis von Seele zur zweiten Garnkomponente von 70 % zu 30 % bis 30 % zu 70 %, aufweist.Yarn according to one of the preceding claims, characterized in that it has a mass ratio of core to second yarn component of 70% to 30% to 30% to 70%. Garn nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß das Seelenmaterial und die zweite Garnkomponente aus dem gleichen Fasersubstrat bestehen.Yarn according to one of the preceding claims, characterized in that the core material and the second yarn component consist of the same fiber substrate. Verfahren zur Herstellung des Garnes nach einem der vorangehenden Ansprüche, bei dem man mindestens eine als Seele dienende multifile Garnkomponente mit einer zweiten Garnkomponente unter Ausbildung eines Coregarnes verspinnt, dadurch gekennzeichnet, daß man als die die Seele bildende mindestens eine multifile Garnkomponente ein vororientiertes Multifilamentgarn (POY-Garn) auswählt, wobei das vororientierte Multifilamentgarn in seinem molekularem Aufbau einem textilen Standardmultifilamentgarn entspricht, und daß man das Multifilamentgarn (POY-Garn) derart verstreckt, daß seine Festigkeit zwischen 60 cN/tex und 90 cN/tex, vorzugsweise zwischen 71 cN/tex und 90 cN/tex, variiert.A process for producing the yarn according to one of the preceding claims, in which at least one multifilament yarn component serving as a core is spun with a second yarn component to form a core yarn, characterized in that a pre-oriented multifilament yarn (POY.) Is used as the at least one multifilament yarn component forming the core Yarn) is selected, the molecular structure of the pre-oriented multifilament yarn corresponding to that of a standard textile multifilament yarn, and that the multifilament yarn (POY yarn) is drawn such that its strength is between 60 cN / tex and 90 cN / tex, preferably between 71 cN / tex and 90 cN / tex, varies. Verfahren nach Anspruch 16, dadurch gekennzeichnet, daß man ein Polyester-POY-Garn auswählt, dessen Intrinsic-Viskosität zwischen 0,5 dl/g und 0,75 dl/g, vorzugsweise zwischen 0,55 dl/g und 0,63 dl/g, variiert.Process according to Claim 16, characterized in that a polyester POY yarn is selected whose intrinsic viscosity is between 0.5 dl / g and 0.75 dl / g, preferably between 0.55 dl / g and 0.63 dl / g, varies. Verfahren nach einem der Ansprüche 16 oder 17, dadurch gekennzeichnet, daß man das vororientierte Multifilamentgarn über eine vom Garn umschlungene Liefergalette mit einer ersten Geschwindigkeit einer Hauptstreckzone zuführt und über eine vom Garn umschlungene Abzugsgalette mit einer zweiten Geschwindigkeit aus der Hauptstreckzone abzieht, wobei die zweite Geschwindigkeit 70 % bis 180 %, vorzugsweise 100 % bis 160 %, größer ist als die erste Geschwindigkeit, daß man die Verstreckung in der Hauptstreckzone ausschließlich zwischen der Liefergalette und der Abzugsgalette durchführt und daß man die Abzugsgalette auf eine Temperatur zwischen 160 °C und 240 °C, aufheizt.Method according to one of claims 16 or 17, characterized in that the pre-oriented multifilament yarn is fed at a first speed to a main stretching zone via a delivery godet wrapped in the yarn and withdrawn from the main stretching zone at a second speed via a withdrawal godet wound around the yarn, the second speed 70% to 180%, preferably 100% to 160%, greater than the first speed, that the stretching in the main stretching zone is carried out exclusively between the delivery godet and the take-off godet and that the take-off godet is heated to a temperature between 160 ° C. and 240 ° C. Verfahren nach Anspruch 18, dadurch gekennzeichnet, daß man die Liefergalette auf eine Temperatur zwischen 60 °C und 160 °C, vorzugsweise auf eine Temperatur zwischen 80 °C und 140 °C, aufheizt.Process according to Claim 18, characterized in that the delivery godet is heated to a temperature between 60 ° C and 160 ° C, preferably to a temperature between 80 ° C and 140 ° C. Verfahren nach Anspruch 18 oder 19, dadurch gekennzeichnet, daß man in der Hauptstreckzone das vororientierte Multifilamentgarn auf eine Temperatur zwischen 80 °C und 180 °C aufheizt.Process according to Claim 18 or 19, characterized in that the pre-oriented multifilament yarn is heated to a temperature between 80 ° C and 180 ° C in the main stretching zone. Verfahren nach Anspruch 20, dadurch gekennzeichnet, daß man zum Aufheizen des Multifilamentgarnes in der Hauptstreckzone eine hot plate, einen IR-Strahler und/oder einen Laser verwendet.A method according to claim 20, characterized in that a hot plate, an IR radiator and / or a laser is used to heat the multifilament yarn in the main stretching zone. Verfahren nach Anspruch 20 oder 21, dadurch gekennzeichnet, daß man das vororientierte Multifilamentgarn in der Hauptstreckzone zwischen 0,01 s und 1 s aufheizt.Process according to Claim 20 or 21, characterized in that the pre-oriented multifilament yarn is heated in the main stretching zone between 0.01 s and 1 s. Verfahren nach einem der Ansprüche 18 bis 22, dadurch gekennzeichnet, daß man die Liefergalette und/oder die Abzugsgalette mit dem vororientierten Multifilamentgarn 5 bis 40mal, vorzugsweise 10 bis 20mal, umschlingt.Method according to one of claims 18 to 22, characterized in that the delivery godet and / or the take-off godet are looped with the pre-oriented multifilament yarn 5 to 40 times, preferably 10 to 20 times. Verfahren nach einem der Ansprüche 18 bis 23, dadurch gekennzeichnet, daß man in Transportrichtung des Multifilamentgarnes gesehen vor der Hauptstreckzone eine Vorverstreckungszone anordnet.Method according to one of claims 18 to 23, characterized in that a pre-stretching zone is arranged in front of the main stretching zone, seen in the direction of transport of the multifilament yarn. Verfahren nach Anspruch 24, dadurch gekennzeichnet, daß man das Multifilamentgarn in der Vorverstreckungszone zwischen 0,5 % bis 10 %, vorzugsweise zwischen 1 % und 4 %, vorverstreckt.Process according to Claim 24, characterized in that the multifilament yarn is pre-drawn in the pre-stretching zone between 0.5% and 10%, preferably between 1% and 4%. Verfahren nach einem der Ansprüche 18 bis 25, dadurch gekennzeichnet, daß man die Vorverstreckung und/oder die Verstreckung bei einer Abzugsgeschwindigkeit größer als 300 m/min, vorzugsweise bei einer Geschwindigkeit zwischen 600 m/min und 1.200 m/min, durchführt.Method according to one of claims 18 to 25, characterized in that the pre-stretching and / or the stretching is carried out at a take-off speed greater than 300 m / min, preferably at a speed between 600 m / min and 1,200 m / min. Verfahren nach einem der Ansprüche 18 bis 25, dadurch gekennzeichnet, daß man in Transportrichtung des vororientierten Multifilamentgarnes gesehen hinter der Hauptstreckzone eine Relaxierzone anordnet, in der man das verstreckte Multifilamentgarn auf eine Temperatur zwischen 80 °C und 240 °C, vorzugsweise auf eine Temperatur zwischen 140 °C und 200 °C, erwärmt.Method according to one of claims 18 to 25, characterized in that, viewed in the direction of transport of the pre-oriented multifilament yarn, a relaxation zone is arranged behind the main drawing zone, in which the drawn multifilament yarn is heated to a temperature between 80 ° C and 240 ° C, preferably to a temperature between 140 ° C and 200 ° C, heated. Verfahren nach Anspruch 27, dadurch gekennzeichnet, daß man das verstreckte Multifilamentgarn in die Relaxierzone mit einer Voreilung einführt.A method according to claim 27, characterized in that the drawn multifilament yarn is introduced into the relaxation zone with a lead. Verfahren nach Anspruch 28, dadurch gekennzeichnet, daß man verstreckte Multifilamentgarn in die Relaxierzone mit einer Voreilung zwischen 0,5 % und 10 %, vorzugsweise 1 % und 3 %, einführt.A method according to claim 28, characterized in that stretched multifilament yarn is introduced into the relaxation zone with a lead of between 0.5% and 10%, preferably 1% and 3%. Verfahren nach einem der Ansprüche 16 bis 29, dadurch gekennzeichnet, daß man als vororientiertes Multifilamentgarn ein solches Garn auswählt, dessen Einzelfilamenttiter zwischen 1 dtex und 12 dtex, vorzugsweise zwischen 3 dtex und 8 dtex, variiert.Method according to one of claims 16 to 29, characterized in that a yarn is selected as the pre-oriented multifilament yarn, the individual filament titer of which varies between 1 dtex and 12 dtex, preferably between 3 dtex and 8 dtex. Verfahren nach einem der Ansprüche 16 bis 30, dadurch gekennzeichnet, daß das vororientierte Multifilamentgarn einen Gesamttiter zwischen 40 dtex und 2.000 dtex, vorzugsweise zwischen 80 dtex und 1.200 dtex, aufweist.Method according to one of claims 16 to 30, characterized in that the pre-oriented multifilament yarn has a total denier between 40 dtex and 2,000 dtex, preferably between 80 dtex and 1,200 dtex. Verfahren nach einem der Ansprüche 16 bis 31, dadurch gekennzeichnet, daß das vororientierte Multifilamentgarn eine Elementarfadenzahl zwischen 16 und 300, vorzugsweise zwischen 24 und 96, besitzt.Method according to one of claims 16 to 31, characterized in that the pre-oriented multifilament yarn has an elementary thread number between 16 and 300, preferably between 24 and 96. Verfahren nach einem der Ansprüche 16 bis 32, dadurch gekennzeichnet, daß man zwei bis vier Coregarne miteinander verzwirnt.Method according to one of claims 16 to 32, characterized in that two to four core yarns are twisted together. Verfahren nach Anspruch 33, dadurch gekennzeichnet, daß man zunächst jedes Coregarn mit einer Garndrehung und anschließend die Coregarne mit einer Zwirndrehung versieht.A method according to claim 33, characterized in that first each core yarn is twisted and then the core yarns are twisted. Verfahren nach Anspruch 34, dadurch gekennzeichnet, daß man die Garndrehung bei einem Drehungsbeiwert α zwischen 90 und 140 durchführt.A method according to claim 34, characterized in that the yarn twist is carried out at a twist coefficient α between 90 and 140. Verfahren nach Anspruch 34 oder 35, dadurch gekennzeichnet, daß man die Zwirndrehung bei einem Drehungsbeiwert α zwischen 120 und 180 durchführt.A method according to claim 34 or 35, characterized in that the twisting is carried out at a twist factor α between 120 and 180.
EP93107497A 1992-05-12 1993-05-08 Yarn and method for manufacturing a yarn Expired - Lifetime EP0569891B1 (en)

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WO2002018702A2 (en) * 2000-08-30 2002-03-07 Warwick Mills, Inc. Methods for improving the dyeability and puncture resistance of fabrics comprising high tenacity fibers and fabrics produced by such methods
US6668868B2 (en) 2000-08-30 2003-12-30 Warwick Mills, Inc Woven fabric constructions having high cover factors and fill yarns with a weight per unit length less than the weight per unit length of warp yarns of the fabric
EP2463418A1 (en) * 2010-11-29 2012-06-13 Amann & Söhne GmbH & Co. KG Yarn, particular sewing yarn or embroidery yarn as well as method for producing such a yarn

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DE10343848A1 (en) * 2003-09-23 2005-04-21 Falke Kg Core yarn and method of making a core yarn
DE10343847A1 (en) * 2003-09-23 2005-04-21 Falke Kg Yarn and method of making a yarn

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EP1036866A2 (en) * 1999-03-16 2000-09-20 Amann & Söhne GmbH & Co. Sewing thread and method for the production of a sewing thread
EP1036866A3 (en) * 1999-03-16 2003-11-05 Amann & Söhne GmbH & Co. Sewing thread and method for the production of a sewing thread
WO2002018702A2 (en) * 2000-08-30 2002-03-07 Warwick Mills, Inc. Methods for improving the dyeability and puncture resistance of fabrics comprising high tenacity fibers and fabrics produced by such methods
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US6668868B2 (en) 2000-08-30 2003-12-30 Warwick Mills, Inc Woven fabric constructions having high cover factors and fill yarns with a weight per unit length less than the weight per unit length of warp yarns of the fabric
EP2463418A1 (en) * 2010-11-29 2012-06-13 Amann & Söhne GmbH & Co. KG Yarn, particular sewing yarn or embroidery yarn as well as method for producing such a yarn
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HK61397A (en) 1997-05-16
DE4215212A1 (en) 1993-11-18

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