EP0563777A2 - Procédé pour la production de gaz de synthèse par traitement thermique de matières premières contenant des substances métalliques et organiques - Google Patents

Procédé pour la production de gaz de synthèse par traitement thermique de matières premières contenant des substances métalliques et organiques Download PDF

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Publication number
EP0563777A2
EP0563777A2 EP19930104882 EP93104882A EP0563777A2 EP 0563777 A2 EP0563777 A2 EP 0563777A2 EP 19930104882 EP19930104882 EP 19930104882 EP 93104882 A EP93104882 A EP 93104882A EP 0563777 A2 EP0563777 A2 EP 0563777A2
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EP
European Patent Office
Prior art keywords
pyrolysis
stage
gasification
gases
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19930104882
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German (de)
English (en)
Other versions
EP0563777A3 (en
EP0563777B1 (fr
Inventor
Helmut Dobert
Hartmut Dr.-Ing. Rossel
Frank Krebber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thyssen Still Otto Anlagentechnik GmbH
Vaw Aluminium AG
Original Assignee
Still Otto GmbH
Thyssen Still Otto Anlagentechnik GmbH
Vereinigte Aluminium Werke AG
Vaw Aluminium AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Still Otto GmbH, Thyssen Still Otto Anlagentechnik GmbH, Vereinigte Aluminium Werke AG, Vaw Aluminium AG filed Critical Still Otto GmbH
Publication of EP0563777A2 publication Critical patent/EP0563777A2/fr
Publication of EP0563777A3 publication Critical patent/EP0563777A3/de
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Publication of EP0563777B1 publication Critical patent/EP0563777B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/62—Processes with separate withdrawal of the distillation products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen

Definitions

  • the invention relates to a process for producing synthesis gas by thermal treatment of residues containing metallic and organic constituents, in particular for producing a hydrogen-rich synthesis gas.
  • Residual materials of the type mentioned at the outset occur, for example, in the separate collection and sorting of packaging materials from the household sector or as production residues and usually consist of plastics of different compositions in connection with thin metal foils made of, for example, aluminum.
  • Packaging materials are usually provided with lacquers and / or adhesive layers which, when processed, result in products containing harmful substances, which make recycling to a great extent difficult.
  • organically bound chlorine content which can be attributed to polyvinyl chloride PVC contained in the mixed plastics, as well as to polychlorinated hydrocarbons such as PCB (polychlorinated biphenyls) and other, sometimes very toxic, compounds.
  • the blazing coke bed is thereby caused by the smoldering coke and / or by other carbon carriers, e.g. Charcoal or brown coal smoked coke and supplied preheated fresh air are formed. So much preheated fresh air is supplied to the coke bed that a temperature level of 1000 to 1200 ° C. is maintained and the longer molecular chains contained in the carbonization gas can be split. It is disadvantageous for the environmental compatibility of such a system that the remaining solids accumulating in the coke bed are not melted and pollutants, such as heavy metal compounds, are not incorporated in them in an eluate-safe manner, so that they are washed out or leached out over time when stored open in a landfill can.
  • pollutants such as heavy metal compounds
  • the object of the present invention is to provide a method and a device for producing synthesis gas by thermal treatment of residues containing metallic and organic components, in which the pollutant potential contained in the residues is destroyed and the formation of new pollutants is prevented, the resulting process products solid fillers can be used in construction, for example, or at least are suitable for landfill and the chemical energy contained in the residues is used at the highest possible level to produce a high-quality synthesis gas.
  • the gas and solid streams are fed separately for further treatment.
  • the reusable components are comminuted and separated, e.g. of metals. This takes place in a metal separator 4, from where the metal parts reach the melting furnace 5 in cleaned form.
  • the non-metallic parts of the pyrolysis solids also contain heavy metals and salts as well as elementary carbon and also non-volatile hydrocarbon parts. These enter a gasification zone, where CO, CO2, H2 and H2O are formed as gaseous products and liquid slag when oxygen-enriched air or oxygen is added at temperatures above 1300 ° C. The slag is withdrawn from the gasification zone, cooled, and can be used as filler material or fed to the landfill.
  • the gaseous products withdrawn from the gasification stage are mixed in the decomposition stage with the gaseous constituents from the pyrolysis, the amount of steam required for the production of synthesis gas being fed in at the same time.
  • the stoichiometrically required amounts can be obtained from the analysis of the starting materials and the remaining solids from the Calculate pyrolysis and the oxygen content of the blown air. They are to be calculated in such a way that the cracking and decomposition reactions required for the complete conversion of the hydrocarbons contained in the pyrolysis gases take place automatically and the result is a synthesis gas with the desired composition.
  • An essential idea of the invention is that the feed containing metallic and organic constituents is gasified in several temperature stages, namely first at low temperatures in the pyrolysis (degassing) and then - separated from the pyrolysis gases - in a gasification zone at very high temperatures, while the pyrolysis gases at much lower temperatures, for example at 1000 ° C in the presence of steam to a gas mixture with a high proportion of H2 and CO are converted.
  • a regression of the polychlorinated hydrocarbons (denovo synthesis) is also ruled out, so that the raw synthetic gases coming from the decomposition stage only have to be subjected to wet cleaning in order to remove pollutants such as hydrogen chloride, ammonia and inorganic sulfur compounds from the gas.
  • Another important feature of the synthesis gas production method according to the invention is that the oxygen is added at a location where neither organochlorine components nor hydrogen chloride are present. In addition, at this point at temperatures counteracts a dioxin formation above 1300 ° C, so that even in the oxygen-containing gasification stage, the requirements set out above with regard to an environmentally friendly and energetically favorable synthesis gas process are met.
  • the low-volatility hydrocarbons obtained with the solid from the pyrolysis can be used in the gasification, in that they contribute to an acceleration of the process step and thus the desired reactions can take place completely and without residue under the influence of the high temperatures.
  • steam jet compressors can advantageously be used for the task described, which compress the gas removed from the pyrolysis into the second gasification stage inject under pressure.
  • This has the further advantage that the pyrolysis gases containing tar and oil vapor can be introduced into the gasification chamber in a very finely divided form.
  • the inlet openings for the pyrolysis gases and the water vapor feed are arranged opposite one another, so that complete mixing of the gas components to a homogeneous reaction mixture is made possible.
  • the temperature in the gasification stage must be reduced if the amount of water vapor in the decomposition stage cannot be increased.
  • the conditions in the pyrolysis must be changed in such a way that the carbon content is reduced by increasing the pyrolysis temperature.
  • this only works satisfactorily up to an upper temperature limit of 500 ° C.
  • the composition of the pyrolysis gases would be changed such that they could no longer be completely broken down to CO and H2 in the decomposition stage at the temperatures of 900 to 1300 ° C.
  • the amount of oxygen required for the complete gasification of the pyrolysis residues is adjusted by regulating the gasification temperature in the range between 1700 and 1850 ° C.
  • the pyrolysis gases are decomposed in an endothermic reaction, the temperature being regulated between 900 and 1300 ° C. by a controlled addition of steam.
  • the optimal composition of the raw synthesis gas generated is used as a control means for regulation.
  • Fluctuating residues can be compensated for by their temperature control in the gasification and decomposition stage by regulating the temperature of the pyrolysis process. This takes place in an advantageous manner by controlling the content of “low-volatility hydrocarbons”, the proportion of which is varied depending on the pyrolysis temperature in the pyrolysis solid. The content of low-volatility hydrocarbons in turn influences the temperature of the gasification process and the composition of the raw gases leaving the gasification.
  • the proposed procedure a regression of the polychlorinated hydrocarbons (denovo synthesis) is prevented with certainty, since the oxygen is added at a place where neither organochlorine components nor hydrogen chloride are present.
  • the raw synthetic gases coming from the decomposition stage only have to be subjected to wet purification in order to remove the pollutants which may have formed in the decomposition stage, such as hydrogen chloride, ammonia and inorganic sulfur compounds from the raw gas.
  • the pressure energy of the water vapor can be used to increase the pressure of the pyrolysis gas.
  • the introduction of the pyrolysis gas into the decomposition stage is facilitated by the excess pressure. Furthermore, advantageous operation of the gasification and decomposition stage under increased pressure is possible.
  • Steam jet compressors can advantageously be used to inject the gas removed from the pyrolysis into the decomposition stage under pressure.
  • the tar and oil-containing pyrolysis gases can be introduced into the decomposition space in a very finely divided form.
  • the basic diagram of synthesis gas production is explained in more detail below.
  • the input materials E or residual materials such as packaging materials and plastic / metal composites are entered in pyrolysis 1. After a temperature treatment between 300 and 500 ° C, the pyrolysis gases PG and the pyrolysis solids PFM leave the pyrolysis 1 via separate lines.
  • the pyrolysis solid PFM is very homogeneous and well prepared by the pyrolysis treatment, so that metal deposition can be carried out in the metal separator 4, with the result that the metal portion is fed to an oven 5, while the remaining constituents are fed into the gasification zone 3.1 as pyrolysis solid PF .
  • Oxygen O also reaches the gasification zone 3.1, as a result of which the temperature in the gasification zone is regulated between 1700 ° C. and 1850 ° C.
  • this gas is introduced into the decomposition stage 3.2 together with the pyrolysis gas PG and water vapor WD.
  • a raw synthesis gas SR is generated, which is cleaned in a gas purification 6 and then leaves the system after a gas scrubbing 8 as a purified synthesis gas SG.
  • the washing water can be passed through evaporator 9, the vapors B being advantageously introduced into the decomposer 3.2.
  • the salts SA leave the evaporators 9 with the evaporated water.
  • slag SC and from the furnace 5 a metal melt can be obtained, which can be processed to secondary metal in an advantageous manner.
  • Feed water W is used for gas cleaning, which is introduced into gas cleaning 6 and leaves it as water vapor WD.
  • the water vapor is input into the decomposition stage 3.2 to form synthesis gas and can advantageously also be used for the production of pressure energy in a steam jet compressor 2.
EP93104882A 1992-03-24 1993-03-24 Procédé pour la production de gaz de synthèse par traitement thermique de matières premières contenant des substances métalliques et organiques Expired - Lifetime EP0563777B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4209549A DE4209549A1 (de) 1992-03-24 1992-03-24 Verfahren zur thermischen Behandlung von Reststoffen, z.B. zur Trennung und Verwertung von Metallverbunden mit organischen Anteilen, mittels einer Kombination aus Pyrolyse und Vergasung
DE4209549 1992-03-24

Publications (3)

Publication Number Publication Date
EP0563777A2 true EP0563777A2 (fr) 1993-10-06
EP0563777A3 EP0563777A3 (en) 1993-11-18
EP0563777B1 EP0563777B1 (fr) 1996-05-29

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ID=6454891

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93104882A Expired - Lifetime EP0563777B1 (fr) 1992-03-24 1993-03-24 Procédé pour la production de gaz de synthèse par traitement thermique de matières premières contenant des substances métalliques et organiques

Country Status (3)

Country Link
EP (1) EP0563777B1 (fr)
AT (1) ATE138679T1 (fr)
DE (2) DE4209549A1 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994021751A1 (fr) * 1993-03-17 1994-09-29 Siemens Aktiengesellschaft Procede et dispositif d'elimination de dechets
EP0648829A1 (fr) * 1993-10-19 1995-04-19 Mitsubishi Jukogyo Kabushiki Kaisha Procédé pour la gazéification de matériaux organiques, procédés pour la gazéification de matières plastiques renforcées de fibres de verre et appareillage
DE4404673A1 (de) * 1994-02-15 1995-08-17 Entec Recycling Und Industriea Verfahren zur Erzeugung von Brenngas
DE4435144A1 (de) * 1994-09-30 1996-04-04 Kloeckner Humboldt Deutz Ag Verfahren und Anlage zur thermischen Verwertung von Abfallstoffen
DE4446803A1 (de) * 1994-12-24 1996-06-27 Noell Energie & Entsorgung Verfahren und Vorrichtung zur thermischen und stofflichen Verwertung von Rest- und Abfallstoffen
EP0795595A1 (fr) * 1996-01-19 1997-09-17 Texas Instruments Inc. Méthode de traitement industriel de déchets liquides et solides
EP0844297A2 (fr) * 1993-10-19 1998-05-27 Mitsubishi Jukogyo Kabushiki Kaisha Procédé pour la gazéification de matières plastiques renforcées de fibres de verre et appareillage
NL1007710C2 (nl) * 1997-12-05 1999-06-08 Gibros Pec Bv Werkwijze voor het verwerken van afval- respectievelijk biomassamateriaal.
EP1002854A2 (fr) * 1998-11-20 2000-05-24 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé de combustion, notamment pour l'élaboration de la fonte ou la fabrication de ciment
DE102007034139A1 (de) 2007-07-21 2009-01-22 Helmut Hoffmann Verfahren zur thermischen Behandlung von feuchten Abfällen, Produktionsrückständen und sonstigen Reststoffen mit nativ-organischen und/oder synthetisch-organischen Bestandteilen
US20120264995A1 (en) * 2011-04-13 2012-10-18 Alter Nrg Corp. Process and apparatus for treatment of incinerator bottom ash and fly ash
US10450520B2 (en) 2009-11-20 2019-10-22 Rv Lizenz Ag Thermal and chemical utilization of carbonaceous materials, in particular for emission-free generation of energy
EP3805340A1 (fr) 2019-10-09 2021-04-14 Reissner, Markus Procédé et système de production d'un mélange gazeux contenant de l'hydrogène et d'hydrogène à partir de matière synthétique

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DE4402565B4 (de) * 1994-01-28 2005-05-04 Siemens Ag Verwendung midestens eines Abscheidehilfsmittels zur Abscheidung klebriger Stäube bei einer Einrichtung zur Müllverarbeitung
DE19513832B4 (de) * 1995-04-12 2005-08-11 Future Energy Gmbh Verfahren zur Verwertung von Rest- und Abfallstoffen durch Kombination einer Wirbelschichtthermolyse mit einer Flugstromvergasung
DE19730385C5 (de) * 1997-07-16 2006-06-08 Future Energy Gmbh Verfahren zur Erzeugung von Brenn- und Synthesegas aus Brennstoffen und brennbaren Abfällen und eine Vorrichtung zur Durchführung des Verfahrens
DE19843613C2 (de) * 1998-09-23 2000-12-07 Harald Martin Verfahren und Vorrichtung zur Aufarbeitung von Abprodukten und Abfallstoffen
DE19937521A1 (de) 1999-08-03 2001-02-15 Harald Martin Verfahren und Vorrichtung zum Trocknen, Trennen, Klassieren und Zersetzen von Abprodukten
DE19937524A1 (de) * 1999-08-03 2001-02-15 Harald Martin Verfahren und Vorrichtung zum Beseitigen von Abprodukten und Abfallstoffen
DE102012017107A1 (de) 2012-08-28 2014-03-06 Linde Aktiengesellschaft Erwärmung eines Prozessabgases
DE102013008519A1 (de) 2013-05-16 2014-11-20 Linde Aktiengesellschaft Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial
DE102013008518A1 (de) 2013-05-16 2014-11-20 Linde Aktiengesellschaft Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial
DE102013009950A1 (de) 2013-06-13 2014-12-18 Linde Aktiengesellschaft Verfahren und Anlage zur Aufbereitung und thermischen Vergasung von wasserhaltigem organischem Einsatzmaterial
DE102013012661A1 (de) 2013-07-30 2015-02-05 Linde Aktiengesellschaft Verfahren und Anlage zur Anreicherung eines mittels Vergasung erzeugten Synthesegases mit Wasserstoff
DE102013014042A1 (de) 2013-08-22 2015-02-26 Linde Aktiengesellschaft Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial
DE102013015539A1 (de) 2013-09-18 2015-03-19 Linde Aktiengesellschaft Anlage und Verfahren zur zumindest teilweisen Vergasung von festem organischen Einsatzmaterial
DE102013015536A1 (de) 2013-09-18 2015-03-19 Linde Aktiengesellschaft Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischen Einsatzmaterial
DE102013017546A1 (de) 2013-10-22 2015-04-23 Linde Aktiengesellschaft Verfahren und Anlage zur Vergasung von Einsatzmaterial
DE102013017945A1 (de) 2013-10-29 2015-04-30 Linde Aktiengesellschaft Kraftwerk
DE102013018332A1 (de) 2013-10-31 2015-04-30 Linde Aktiengesellschaft Vorrichtung zur Einbringung von festem organischen Einsatzmaterial in eine Vergasungsanlage
DE102013018992A1 (de) 2013-11-13 2015-05-13 Linde Aktiengesellschaft Vorrichtung für eine Zuführung von Vergasungsmittel in einen Niedertemperaturvergaser
DE102013019655A1 (de) 2013-11-23 2015-05-28 Linde Aktiengesellschaft Behälter für einen Niedertemperaturvergaser
DE102013020792A1 (de) 2013-12-11 2015-06-11 Linde Aktiengesellschaft Verfahren und Anlage zur Vergasung von festem, organischem Einsatzmaterial
DE102013020889A1 (de) 2013-12-11 2015-06-11 Linde Aktiengesellschaft Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial
DE102013020890A1 (de) 2013-12-11 2015-06-11 Linde Aktiengesellschaft Verfahren und Anlage zur zumindest teilweisen Vergasung von festem, organischem Einsatzmaterial
DE102014016401A1 (de) 2014-11-05 2016-05-12 Linde Aktiengesellschaft Verfahren zur Nutzung von CO2 bei der Synthesegasproduktion
DE102014016407A1 (de) 2014-11-05 2016-05-12 Linde Aktiengesellschaft Verfahren zur Produktion von Synthesegas

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GB2068014A (en) * 1980-01-24 1981-08-05 Tosco Corp Process for the gasification of coal
EP0055840A1 (fr) * 1980-12-27 1982-07-14 Forschungszentrum Jülich Gmbh Procédé et installation pour la combustion de matières organiques
EP0120397A2 (fr) * 1983-03-23 1984-10-03 C. Deilmann AG Installation pour produire de l'énergie à partir de déchets carbonés pyrolysables de composition variable
WO1990002162A1 (fr) * 1988-08-23 1990-03-08 Roessle Gottfried Procede allothermique pour produire un gaz combustible a partir d'ordures menageres ou d'ordures menageres conjointement avec du charbon, et dispositif permettant la mise en ×uvre du procede
WO1991004306A1 (fr) * 1989-09-20 1991-04-04 American Waste Reduction Corporation Reduction au minimum de dechets environnementaux

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FR2261974A1 (fr) * 1974-02-21 1975-09-19 Shell Int Research
GB1479257A (en) * 1974-09-23 1977-07-13 Cogas Dev Co Coal gasification
US4229185A (en) * 1975-11-10 1980-10-21 Occidental Petroleum Corporation Process for the gasification of carbonaceous materials
GB2068014A (en) * 1980-01-24 1981-08-05 Tosco Corp Process for the gasification of coal
EP0055840A1 (fr) * 1980-12-27 1982-07-14 Forschungszentrum Jülich Gmbh Procédé et installation pour la combustion de matières organiques
EP0120397A2 (fr) * 1983-03-23 1984-10-03 C. Deilmann AG Installation pour produire de l'énergie à partir de déchets carbonés pyrolysables de composition variable
WO1990002162A1 (fr) * 1988-08-23 1990-03-08 Roessle Gottfried Procede allothermique pour produire un gaz combustible a partir d'ordures menageres ou d'ordures menageres conjointement avec du charbon, et dispositif permettant la mise en ×uvre du procede
WO1991004306A1 (fr) * 1989-09-20 1991-04-04 American Waste Reduction Corporation Reduction au minimum de dechets environnementaux

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994021751A1 (fr) * 1993-03-17 1994-09-29 Siemens Aktiengesellschaft Procede et dispositif d'elimination de dechets
EP0844297A2 (fr) * 1993-10-19 1998-05-27 Mitsubishi Jukogyo Kabushiki Kaisha Procédé pour la gazéification de matières plastiques renforcées de fibres de verre et appareillage
EP0648829A1 (fr) * 1993-10-19 1995-04-19 Mitsubishi Jukogyo Kabushiki Kaisha Procédé pour la gazéification de matériaux organiques, procédés pour la gazéification de matières plastiques renforcées de fibres de verre et appareillage
EP0844297A3 (fr) * 1993-10-19 1998-06-10 Mitsubishi Jukogyo Kabushiki Kaisha Procédé pour la gazéification de matières plastiques renforcées de fibres de verre et appareillage
US5849050A (en) * 1994-02-15 1998-12-15 Crg Kohlenstoffrecycling Ges.Mbh Process for generating burnable gas
DE4404673A1 (de) * 1994-02-15 1995-08-17 Entec Recycling Und Industriea Verfahren zur Erzeugung von Brenngas
DE4435144A1 (de) * 1994-09-30 1996-04-04 Kloeckner Humboldt Deutz Ag Verfahren und Anlage zur thermischen Verwertung von Abfallstoffen
DE4446803A1 (de) * 1994-12-24 1996-06-27 Noell Energie & Entsorgung Verfahren und Vorrichtung zur thermischen und stofflichen Verwertung von Rest- und Abfallstoffen
DE4446803C2 (de) * 1994-12-24 1998-05-28 Krc Umwelttechnik Gmbh Verfahren und Vorrichtung zur thermischen und stofflichen Verwertung von Rest- und Abfallstoffen
EP0795595A1 (fr) * 1996-01-19 1997-09-17 Texas Instruments Inc. Méthode de traitement industriel de déchets liquides et solides
US6084139A (en) * 1997-12-05 2000-07-04 Gibros Pec B.V. Method for processing waste or biomass material
NL1007710C2 (nl) * 1997-12-05 1999-06-08 Gibros Pec Bv Werkwijze voor het verwerken van afval- respectievelijk biomassamateriaal.
EP0921182A1 (fr) * 1997-12-05 1999-06-09 Gibros Pec B.V. Méthode pour le traitement de déchets ou de biomasse
AU736172B2 (en) * 1997-12-05 2001-07-26 Droan B.V. Method for processing waste or biomass material
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EP1002854A3 (fr) * 1998-11-20 2001-03-07 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé de combustion, notamment pour l'élaboration de la fonte ou la fabrication de ciment
FR2786196A1 (fr) * 1998-11-20 2000-05-26 Air Liquide Procede de combustion, notamment pour l'elaboration de la fonte ou la fabrication de ciment
DE102007034139A1 (de) 2007-07-21 2009-01-22 Helmut Hoffmann Verfahren zur thermischen Behandlung von feuchten Abfällen, Produktionsrückständen und sonstigen Reststoffen mit nativ-organischen und/oder synthetisch-organischen Bestandteilen
US10450520B2 (en) 2009-11-20 2019-10-22 Rv Lizenz Ag Thermal and chemical utilization of carbonaceous materials, in particular for emission-free generation of energy
US10844302B2 (en) 2009-11-20 2020-11-24 Rv Lizenz Ag Thermal and chemical utilization of carbonaceous materials, in particular for emission-free generation of energy
US20120264995A1 (en) * 2011-04-13 2012-10-18 Alter Nrg Corp. Process and apparatus for treatment of incinerator bottom ash and fly ash
US9314655B2 (en) * 2011-04-13 2016-04-19 Alter Nrg Corp. Process and apparatus for treatment of incinerator bottom ash and fly ash
US9468787B2 (en) 2011-04-13 2016-10-18 Alter Nrg Corp. Process and apparatus for treatment of incinerator bottom ash and fly ash
US9669248B2 (en) 2011-04-13 2017-06-06 Alter Nrg Corp. Process and apparatus for treatment of incinerator bottom ash and fly ash
EP3805340A1 (fr) 2019-10-09 2021-04-14 Reissner, Markus Procédé et système de production d'un mélange gazeux contenant de l'hydrogène et d'hydrogène à partir de matière synthétique
WO2021069394A1 (fr) * 2019-10-09 2021-04-15 Reissner Markus Procédé et système de production d'un mélange gazeux contenant des hydrocarbures et contenant de l'hydrogène à partir de plastique

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ATE138679T1 (de) 1996-06-15
EP0563777A3 (en) 1993-11-18
DE4209549A1 (de) 1993-09-30
DE59302721D1 (de) 1996-07-04
EP0563777B1 (fr) 1996-05-29

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