EP0492192B1 - Legierung für Brillendrähte und elektronische Bauteile - Google Patents
Legierung für Brillendrähte und elektronische Bauteile Download PDFInfo
- Publication number
- EP0492192B1 EP0492192B1 EP91120797A EP91120797A EP0492192B1 EP 0492192 B1 EP0492192 B1 EP 0492192B1 EP 91120797 A EP91120797 A EP 91120797A EP 91120797 A EP91120797 A EP 91120797A EP 0492192 B1 EP0492192 B1 EP 0492192B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- spectacle
- alloys
- alloy according
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 44
- 239000000956 alloy Substances 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052759 nickel Inorganic materials 0.000 abstract description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052742 iron Inorganic materials 0.000 abstract description 6
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 6
- 239000011574 phosphorus Substances 0.000 abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052802 copper Inorganic materials 0.000 abstract description 5
- 239000010949 copper Substances 0.000 abstract description 5
- 229910052725 zinc Inorganic materials 0.000 abstract description 5
- 239000011701 zinc Substances 0.000 abstract description 5
- 239000011521 glass Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- 229910000679 solder Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 229910017755 Cu-Sn Inorganic materials 0.000 description 1
- 229910016347 CuSn Inorganic materials 0.000 description 1
- 229910017927 Cu—Sn Inorganic materials 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 229910001096 P alloy Inorganic materials 0.000 description 1
- 229910007116 SnPb Inorganic materials 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/04—Alloys based on copper with zinc as the next major constituent
Definitions
- the invention relates to an alloy which is used on the one hand for the manufacture of eyeglass frames, in particular for the manufacture of temples and on the other hand as a connecting wire for electronic components. Furthermore, the invention relates to eyeglass frames, which were produced using the alloy, and eyeglass wire, which is used to produce the temples.
- the known alloys have the disadvantage that they are not or only partially suitable for certain requirements, since the material does not have sufficient strength or spring properties or loses strength during processing, for example during soldering or welding processes.
- Another disadvantage of the known alloys is that they contain a very high proportion of nickel. Since the percentage of the population who have allergies to nickel has increased significantly, many of these alloys cannot be used or can only be used with considerable effort, for example by applying additional coatings. Additional disadvantages of the known alloys are due to the relatively high price.
- Lead wires for electronic components must have a low electrical conductivity and thus a low thermal conductivity, so that a temperature protection of the electronic components during connection work, such as. B. soldering is obtained.
- the invention has for its object to provide an alloy for glasses or connecting wires, which has a low nickel content and low thermal conductivity with inexpensive to manufacture and favorable, high mechanical strengths.
- the object is achieved by an alloy which, in percentages by weight, has the following composition contains: 63 - 78% copper, 3 - 7% nickel, 1 - 3% iron, 0.01 - 0.20% phosphorus, balance zinc.
- the alloy according to the invention is distinguished by a number of considerable advantages.
- the alloy according to the invention has a very low nickel content of only 3-7%, while in the alloy which is described in DE-OS 26 26 251, the nickel content is up to 26% can, similar to the alloy according to DE-OS 38 34 186, which provides a nickel content of 17-25%.
- Another essential advantage of the alloy according to the invention is that it has a higher recrystallization temperature than the previously known eyeglass alloys. It is thus possible to weld or solder the alloy without significantly affecting the elastic properties.
- the spring behavior of the alloy which is particularly important in the case of eyeglass temples, therefore also remains in the area of the welded or soldered joints. Such critical points are in particular in the area at which the temple is connected to the hinge part. Conventional alloys tend to lose strength in this connection area, with the result that the eyeglass frame bends easily in practical use.
- the alloy according to the invention is easier to polish, as a result of which the overall appearance of the spectacle frame can be improved.
- the alloy according to the invention is also distinguished by a better optical appearance and in particular has a gold effect, so that it may be possible to work with a smaller edition when coating with gold.
- the alloy according to the invention has excellent spring properties, the iron and phosphorus content leads to increased strength compared to the previously known alloys.
- the alloy according to the invention has a low electrical conductivity of 5.5-6.5 m / ohm ⁇ mm2 (Siemens) and a low thermal conductivity of 38-44 W / mxk .
- the alloy has the following composition (in percent by weight): 64-68% copper, 4-5% nickel, 1-2% iron, 0.01-0.05 phosphorus, balance zinc. It can also prove to be particularly favorable if the alloy, also in percent by weight, is composed as follows: 65% copper, 4.6% nickel, 1.2% iron, 0.02% phosphorus, balance zinc.
- the object is also achieved by an alloy which has the following composition, in percent by weight: 74-78% copper, 3.5-4.5% nickel, 1-2% iron, 0.01-0.05% phosphorus, Balance zinc.
- the alloys according to the invention can preferably be processed to wire material of different cross-section, from which individual parts for an eyeglass frame can be manufactured in a known manner. It is thus possible without any problems to use the alloy according to the invention for the production of conventional spectacle frames. In particular, the required joining processes and joining steps can be carried out without the advantageous properties of the alloys according to the invention being impaired.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Eyeglasses (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE9017408U DE9017408U1 (de) | 1990-12-22 | 1990-12-22 | Brillendrahtlegierung |
| DE9017408U | 1990-12-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0492192A1 EP0492192A1 (de) | 1992-07-01 |
| EP0492192B1 true EP0492192B1 (de) | 1994-07-27 |
Family
ID=6860655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP91120797A Expired - Lifetime EP0492192B1 (de) | 1990-12-22 | 1991-12-04 | Legierung für Brillendrähte und elektronische Bauteile |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5259898A (enrdf_load_stackoverflow) |
| EP (1) | EP0492192B1 (enrdf_load_stackoverflow) |
| JP (1) | JPH04293744A (enrdf_load_stackoverflow) |
| AT (1) | ATE109213T1 (enrdf_load_stackoverflow) |
| BR (1) | BR9105516A (enrdf_load_stackoverflow) |
| DE (2) | DE9017408U1 (enrdf_load_stackoverflow) |
| ES (1) | ES2057721T3 (enrdf_load_stackoverflow) |
| HK (1) | HK49995A (enrdf_load_stackoverflow) |
| TW (1) | TW209251B (enrdf_load_stackoverflow) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4131426A1 (de) * | 1991-09-20 | 1993-03-25 | Berkenhoff Gmbh | Legierung, insbesondere zur verwendung zur herstellung von schmuck, brillengestellen etc. |
| JP2807398B2 (ja) * | 1993-08-03 | 1998-10-08 | 和明 深道 | 磁気抵抗効果材料、その製造方法および磁気抵抗素子 |
| DE19624731A1 (de) * | 1996-06-21 | 1998-01-02 | Berkenhoff Gmbh | Legierung, insbesondere zur Herstellung von Brillengestellen, Schmuck etc. |
| DE19624732A1 (de) * | 1996-06-21 | 1998-01-02 | Berkenhoff Gmbh | Legierung, insbesondere zur Herstellung von Brillengestellen, Schmuck etc. |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR501870A (fr) * | 1919-06-24 | 1920-04-28 | Knut Eenberg | Nouvel alliage et son procédé d'obtention |
| US2224095A (en) * | 1940-02-15 | 1940-12-03 | Scovill Manufacturing Co | Tube for heat exchanging apparatus |
| US4171972A (en) * | 1978-02-21 | 1979-10-23 | Olin Corporation | Corrosion resistant copper base alloys for heat exchanger tube |
| JPS5934222B2 (ja) * | 1981-11-13 | 1984-08-21 | 日本鉱業株式会社 | ラジエ−タ−用銅合金 |
| US5045411A (en) * | 1990-01-10 | 1991-09-03 | P.M. Refining, Inc. | Alloy compositions |
-
1990
- 1990-12-22 DE DE9017408U patent/DE9017408U1/de not_active Expired - Lifetime
-
1991
- 1991-12-04 EP EP91120797A patent/EP0492192B1/de not_active Expired - Lifetime
- 1991-12-04 ES ES91120797T patent/ES2057721T3/es not_active Expired - Lifetime
- 1991-12-04 DE DE59102355T patent/DE59102355D1/de not_active Expired - Fee Related
- 1991-12-04 AT AT91120797T patent/ATE109213T1/de not_active IP Right Cessation
- 1991-12-13 US US07/808,026 patent/US5259898A/en not_active Expired - Fee Related
- 1991-12-19 BR BR919105516A patent/BR9105516A/pt unknown
- 1991-12-20 JP JP3338074A patent/JPH04293744A/ja active Pending
- 1991-12-20 TW TW080109998A patent/TW209251B/zh active
-
1995
- 1995-04-06 HK HK49995A patent/HK49995A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04293744A (ja) | 1992-10-19 |
| ATE109213T1 (de) | 1994-08-15 |
| DE9017408U1 (de) | 1991-03-07 |
| ES2057721T3 (es) | 1994-10-16 |
| HK49995A (en) | 1995-04-13 |
| TW209251B (enrdf_load_stackoverflow) | 1993-07-11 |
| BR9105516A (pt) | 1992-09-29 |
| DE59102355D1 (de) | 1994-09-01 |
| EP0492192A1 (de) | 1992-07-01 |
| US5259898A (en) | 1993-11-09 |
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