EP0449774A2 - Distributeur pour faire mousser un produit liquide - Google Patents

Distributeur pour faire mousser un produit liquide Download PDF

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Publication number
EP0449774A2
EP0449774A2 EP91810181A EP91810181A EP0449774A2 EP 0449774 A2 EP0449774 A2 EP 0449774A2 EP 91810181 A EP91810181 A EP 91810181A EP 91810181 A EP91810181 A EP 91810181A EP 0449774 A2 EP0449774 A2 EP 0449774A2
Authority
EP
European Patent Office
Prior art keywords
channel
container
outlet channel
dispenser according
sieve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91810181A
Other languages
German (de)
English (en)
Other versions
EP0449774A3 (en
EP0449774B1 (fr
Inventor
George Edgar Callahan
Harald Koch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6403029&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0449774(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Priority to AT91810181T priority Critical patent/ATE96699T1/de
Publication of EP0449774A2 publication Critical patent/EP0449774A2/fr
Publication of EP0449774A3 publication Critical patent/EP0449774A3/de
Application granted granted Critical
Publication of EP0449774B1 publication Critical patent/EP0449774B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005—Components or details
    • B05B11/0027—Means for neutralising the actuation of the sprayer ; Means for preventing access to the sprayer actuation means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005—Components or details
    • B05B11/0059—Components or details allowing operation in any orientation, e.g. for discharge in inverted position
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/04—Deformable containers producing the flow, e.g. squeeze bottles
    • B05B11/042—Deformable containers producing the flow, e.g. squeeze bottles the spray being effected by a gas or vapour flow in the nozzle, spray head, outlet or dip tube
    • B05B11/043—Deformable containers producing the flow, e.g. squeeze bottles the spray being effected by a gas or vapour flow in the nozzle, spray head, outlet or dip tube designed for spraying a liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/04—Deformable containers producing the flow, e.g. squeeze bottles
    • B05B11/042—Deformable containers producing the flow, e.g. squeeze bottles the spray being effected by a gas or vapour flow in the nozzle, spray head, outlet or dip tube
    • B05B11/045—Deformable containers producing the flow, e.g. squeeze bottles the spray being effected by a gas or vapour flow in the nozzle, spray head, outlet or dip tube designed for spraying particulate material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/0018—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam
    • B05B7/0025—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply
    • B05B7/0031—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/0018—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam
    • B05B7/0025—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply
    • B05B7/0031—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns
    • B05B7/0037—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns including sieves, porous members or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02—Spray pistols; Apparatus for discharge
    • B05B7/10—Spray pistols; Apparatus for discharge producing a swirling discharge

Definitions

  • the invention relates to a dispenser for foaming a liquid filling material according to the preamble of claim 1.
  • Dispensers in which an air-filling material mixture is foamed by means of an additional sieve attachment are widely known.
  • DE-C-29 25 528 a device with a hand pump.
  • the problem can arise that the re-expansion of the compressible container that is required after the dispenser is actuated takes place too slowly.
  • the sieve offers great resistance to the inflowing air, especially if it is wetted with a viscous product or is partially blocked due to prolonged use.
  • the dispenser must be made stiffer so that it reliably expands again.
  • this object is achieved with a dispenser having the features in claim 1.
  • the air flowing back can flow into the interior of the container without great resistance and the container is immediately ready for a new spraying process.
  • the refilling process with air can be further accelerated in that the outlet channel is connected to the interior of the container via an aeration channel and that the sieve has a closure body which closes the aeration channel when the outlet channel is covered and releases the aeration channel when the outlet channel is partially exposed.
  • the screen also has a kind of valve function, the valve actuation being effected by the negative pressure or the excess pressure in the outlet channel.
  • a common mixing chamber in front of the mixing nozzle ensures optimal swirling of the filling material with the expelled air, regardless of which of the two channels the filling material is introduced into the mixing chamber. Both channels can easily open tangentially into the mixing chamber. However, it is also possible for one of the two channels to open into the mixing chamber coaxially with the mixing nozzle.
  • the second channel is provided with a valve which, when the container is overhead, completely or partially closes the second channel.
  • This valve could also be arranged completely independently of whether the two channels open into a common mixing chamber. If the valve closes the second channel only partially, it acts as a throttle valve, so that the ratio of air to product to be filled can be maintained.
  • valve in the overhead position completely closes the second channel, so that no filling material can be ejected even when the container is pressed together.
  • the valve can particularly advantageously have a valve body which is freely movable in a cage-like holder and which, when it is upside down, rests against a valve seat.
  • the cage-like holder can be easily integrated into the spray head and, for example, a ball can be used as the valve body.
  • FIGS. 1-3 An embodiment of a dispenser according to the invention is shown in FIGS. 1-3.
  • a compressible container e.g. made of plastic material
  • a cap 2 is firmly connected.
  • This cap contains a spray insert 4, in which an approximately circular cross-section mixing chamber 8 and a conical mixture nozzle 7 are arranged.
  • a first channel 15 and a second channel 9 lead from the inside of the container to this mixing chamber.
  • a riser pipe 3 is fastened, which, as can be seen from FIG. 4, is immersed in the filling material 31 in the upright container position.
  • the nozzle 16 forms the container-side end of the first channel 15. This channel opens tangentially into the mixing chamber 8, as can be seen from FIG. 3.
  • the second channel 9 leads on the container side to a valve which is formed by a cage-like holder 14, a ball 13 and a valve seat 10.
  • the holder 14 is plugged onto the socket 16 and has lateral webs 12, between which the valve ball 13 made of metal, plastic or ceramic is held.
  • the height of the webs 12 is limited in such a way that the openings between them and the cap 2 11 remain.
  • the channels 18 run, which connect the interior of the container or the air space 33 above the filling material to the second channel 9 via the openings 11.
  • the second channel 9 opens coaxially with the mixture nozzle 7 into the mixing chamber 8.
  • the conical valve seat 10 is designed such that it completely closes the channel 9 when the valve ball 13 is in contact.
  • the valve seat can also be provided with a number of fine radial grooves, so that the valve only acts as a throttle valve and the flow rate is reduced when the ball is in contact.
  • the mixture nozzle 7 opens into an outlet channel 19 which, when a foamable liquid is used, is provided with a movable sieve 6 which is arranged at a distance from the mixture nozzle.
  • the outlet channel 19 can be closed with a hinged cover 5 which is attached to the spray insert 4 in a hinge-like manner.
  • the hinged lid 5 in particular prevents the screen 6 from drying and sticking.
  • the filling material 31 flows through the riser pipe 3 and the first channel 15 into the mixing chamber 8 due to the increased internal pressure.
  • air from the air space 33 passes through the channels 18, the openings 11 and the second channel 9 into the mixing chamber 8.
  • the first channel 15 leads tangentially into the mixing chamber, as a result of which the inflowing liquid is set in rotation and thus mixes with the air flow supplied centrally via the second channel 9.
  • This air-liquid mixture is accelerated through the conical mixture nozzle 7 to the outside of the container and released as a spray. When the sieve 6 is inserted, this mixture is foamed.
  • the valve In the normal container position shown in Figure 4, the valve is not effective.
  • the air can flow freely into the mixing chamber 8 without the ball 13 changing its position within the holder 14 and influencing the air flow.
  • the ratio of air to liquid is determined solely by the smallest cross sections of the channels 9 and 15.
  • the riser pipe 3 projects into the air space 33, so that the media in the channels exchange in this position.
  • the air now arrives tangentially into the mixing chamber 8 via the riser pipe 3 and the first channel 15.
  • the filling material is fed into the mixing chamber via the channels 18, the openings 11 and the second channel 9, where it mixes with the air flow now set in rotation becomes.
  • FIGS. 6 and 7 show a second embodiment of the dispenser according to the invention.
  • the valve also consists here of a holder 14 provided with the webs 12 and the slot-shaped openings 11, which is in the form of a cylindrical Cage is formed in which the ball is held freely. The blocking or reduction of the liquid flow in the overhead position is achieved with a corresponding change in position of the ball 13, which rests on the either polished or uneven valve surface 10 and closes the channel 9 'completely or partially.
  • the optional use of the central inlet according to FIGS. 1 to 3 or tangential inlet according to FIG. 6 is advantageous.
  • FIG. 8 shows a third embodiment of the dispenser according to the invention with the container in an upright position and in the open state. This shape is particularly easy to close due to the rotatable spout attachment 20.
  • FIG. 6 shows an embodiment with two tangential inlets as shown analogous to FIG. 6, a central inlet analogous to FIG. 2 could equally well be used.
  • the valve device described above is not shown here for the sake of simplicity.
  • a cap 2 is firmly connected to a container 1, the cap carrying a spout attachment 20 which can be pivoted about the cap axis, the inner wall of which lies in front of the sealing insert 21 in the closed state and thus closes the dispenser.
  • the cap 2 contains the spray insert 4 and the sealing insert 21 between which the sieve 6 is only attached on one side.
  • the unpaved underside is moved in the direction of the container interior by this air flow and reaches approximately a position 6 '.
  • an air gap 23 opens, through which part of the inflowing air can pass unhindered and without having to pass through the sieve into the container.
  • the re-expansion of the container is hereby significantly accelerated. This means that softer containers can be used from the outset, which makes it much easier to operate the dispenser.
  • the sieve 6, which is made of plastic fabric, for example, is movable because it is only held at its upper edge between the spray insert 4 and the sealing insert 21.
  • the flexible fabric deforms in the inflowing air flow so that it flows around the side and bottom in position 6 '.
  • a rigid sieve for example made of metal mesh, can also be movably supported by being injection-molded onto a thin plastic flap on one side - a so-called film hinge or by ultrasound welding.
  • FIG. 9 Such a rigid screen with a film hinge 25 is shown in FIG. 9, for example.
  • the back-flowing air reaches the interior of the container even more quickly via a ventilation duct 28.
  • This ventilation channel connects the air space 33 in the container directly to the outlet channel 19.
  • the sieve 6 has at its freely movable lower edge a cover 29 which closes the ventilation channel 28 when the air / filling material mixture flows out.
  • the open position with exposed ventilation duct 28 is interrupted Lines shown.
  • FIG. 10 Another embodiment of a screen provided with a closure body is shown in FIG. 10.
  • the sieve 6 is not clamped like a hinge here, but is arranged fixedly in a rotationally symmetrical hollow body.
  • the hollow body consists of a hollow cone 24 and a cylindrical extension 30.
  • the hollow cone is held axially displaceably in the outlet channel or in the sealing insert 21.
  • the hollow cone is in the position shown, so that an annular gap 27 is formed, through which the air can flow unhindered to the ventilation duct 28.
  • the extension 30 also closes the ventilation duct 28, so that air can no longer escape there.
  • the sieve is then about the position according to 6 '.

Landscapes

  • Nozzles (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Formation And Processing Of Food Products (AREA)
  • Closures For Containers (AREA)
  • Polyurethanes Or Polyureas (AREA)
EP91810181A 1990-03-24 1991-03-20 Distributeur pour faire mousser un produit liquide Expired - Lifetime EP0449774B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT91810181T ATE96699T1 (de) 1990-03-24 1991-03-20 Spender zum verschaeumen eines fluessigen fuellguts.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4009574 1990-03-24
DE4009574 1990-03-24

Publications (3)

Publication Number Publication Date
EP0449774A2 true EP0449774A2 (fr) 1991-10-02
EP0449774A3 EP0449774A3 (en) 1991-12-11
EP0449774B1 EP0449774B1 (fr) 1993-11-03

Family

ID=6403029

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91810181A Expired - Lifetime EP0449774B1 (fr) 1990-03-24 1991-03-20 Distributeur pour faire mousser un produit liquide

Country Status (4)

Country Link
US (1) US5156307A (fr)
EP (1) EP0449774B1 (fr)
AT (1) ATE96699T1 (fr)
DE (1) DE59100542D1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009139862A2 (fr) * 2008-05-14 2009-11-19 S.C. Johnson & Son, Inc. Produit de pulvérisation avec particules et soupape améliorée pour une distribution inversée sans obstruction
WO2014008274A1 (fr) * 2012-07-03 2014-01-09 The Procter & Gamble Company Distributeur de génération de mousse
CN110786345A (zh) * 2019-11-13 2020-02-14 申璐璐 一种天然植物抗菌剂

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4027749A1 (de) * 1990-09-01 1992-03-05 Pfeiffer Erich Gmbh & Co Kg Austragvorrichtung fuer medien
CH680582A5 (fr) * 1991-04-23 1992-09-30 Supermatic Kunststoff Ag
US5409136A (en) * 1991-05-01 1995-04-25 Interscents N.V. Spraying device for deformable container able to divert vertical spray into spray at an angle
US5373991A (en) * 1993-04-09 1994-12-20 Contico International, Inc. Foamer trigger dispenser with sealing device
US5335858A (en) * 1993-04-14 1994-08-09 Dunning Walter B Pump sprayer having leak preventing seals and closures
DE9308745U1 (de) * 1993-06-11 1993-08-12 Aerosol Technik Lindal Gmbh, 23843 Bad Oldesloe Spenderkopf für ein Schaumaerosol
US5431345A (en) * 1993-11-12 1995-07-11 The Procter & Gamble Company Foam dispensing system for a foamable liquid
US5445288A (en) * 1994-04-05 1995-08-29 Sprintvest Corporation Nv Liquid dispenser for dispensing foam
JP3697012B2 (ja) * 1996-03-22 2005-09-21 株式会社三谷バルブ 往復ポンプタイプの噴出器
US6082586A (en) * 1998-03-30 2000-07-04 Deb Ip Limited Liquid dispenser for dispensing foam
US6142338A (en) * 1998-12-16 2000-11-07 Pellicano; Joseph J. Foamer and process for dispensing non-aerosol fluoride foam
GB2365370A (en) * 2000-08-08 2002-02-20 Reckitt & Colman Ltda Squeeze bottle nozzle
US6612468B2 (en) * 2000-09-15 2003-09-02 Rieke Corporation Dispenser pumps
US6536685B2 (en) * 2001-03-16 2003-03-25 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Foamer
US6557783B1 (en) 2001-11-23 2003-05-06 Continental Sprayers International, Inc. Telescoping foamer nozzle
DE20209616U1 (de) * 2002-06-20 2003-07-31 RPC Wiko GmbH & Co. KG, 50259 Pulheim Spenderkopf mit Sperrventil
US6868990B2 (en) * 2002-09-26 2005-03-22 Emsar, Inc. Fluid dispenser with shuttling mixing chamber
ITRM20030055A1 (it) * 2003-02-10 2004-08-11 Emsar Spa Testa erogatrice a nebulizzazione per flacone deformabile elasticamente per schiacciamento.
DE10351288B3 (de) * 2003-10-31 2005-07-21 Seaquist Perfect Dispensing Gmbh Spenderpumpe
US20050098581A1 (en) * 2003-11-06 2005-05-12 Long John N. Foam generation assembly
EP1742692A4 (fr) * 2004-03-17 2012-06-27 Genzyme Corp Pulverisation anti-adherence
US7229067B2 (en) * 2004-04-29 2007-06-12 University Of Maryland Foam-generating assembly and foam generator used therein
US7802701B2 (en) * 2005-01-14 2010-09-28 Rieke Corporation Up-lock seal for dispenser pump
US7770874B2 (en) * 2005-04-22 2010-08-10 Gotohii.com Inc. Foam pump with spring
CA2504989C (fr) * 2005-04-22 2013-03-12 Gotohti.Com Inc. Pompe de distribution de mousse etagee
CA2509295C (fr) * 2005-04-22 2013-11-19 Gotohti.Com Inc. Distributeur a soufflet
US8662419B2 (en) * 2010-01-28 2014-03-04 Chang Ho Chang Multifunctional spraying mineral water bottle
CN101973430B (zh) * 2010-10-22 2014-08-13 (文莱)希米亚股份有限公司东莞代表处 一种运动型多功能喷雾矿泉水瓶
US20110180628A1 (en) * 2010-01-28 2011-07-28 Chang Ho Chang Portable air-conditioning unit
GB2479014B (en) * 2010-03-26 2016-05-11 Shenzhen Nozo Ip Operation Co Ltd A multifunctional spraying mineral water bottle
EP2792417B1 (fr) * 2011-08-31 2018-02-21 Yoshino Kogyosho Co., Ltd. Conteneur de distribution
JP6012947B2 (ja) * 2011-09-29 2016-10-25 株式会社吉野工業所 泡噴出容器
US8814005B2 (en) 2012-04-27 2014-08-26 Pibed Limited Foam dispenser
EP2700588B1 (fr) * 2012-08-21 2015-04-01 Aptar France SAS Fermeture de distribution munie d'une soupape de ventilation
JP6228364B2 (ja) * 2013-01-31 2017-11-08 日本クロージャー株式会社 泡出しキャップ
AU2015258718C1 (en) 2014-05-12 2020-01-16 Deb Ip Limited Improved foam pump
US10399100B2 (en) 2014-12-24 2019-09-03 Kao Corporation Foam dispenser

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3709437A (en) * 1968-09-23 1973-01-09 Hershel Earl Wright Method and device for producing foam
US4836422A (en) * 1987-02-11 1989-06-06 Henkel Kommanditgesellschaft Auf Aktien Propellantless foam dispenser

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Publication number Priority date Publication date Assignee Title
US4044923A (en) * 1976-05-19 1977-08-30 Glasrock Products, Inc. Foam generating dispenser having a movable and stationary porous element
US4429834A (en) * 1981-04-08 1984-02-07 Toyo Seikan Kaisha, Ltd. Mouth closure assembly for mouth of foam liquid dispensing container
US4925106A (en) * 1988-04-13 1990-05-15 Afa Products, Inc. Foam-off nozzle assembly with barrel screen insert for use in a trigger sprayer
ES2057844T3 (es) * 1990-02-16 1994-10-16 Sterisol Ab Valvula de distribucion de un fluido.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3709437A (en) * 1968-09-23 1973-01-09 Hershel Earl Wright Method and device for producing foam
US4836422A (en) * 1987-02-11 1989-06-06 Henkel Kommanditgesellschaft Auf Aktien Propellantless foam dispenser

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009139862A2 (fr) * 2008-05-14 2009-11-19 S.C. Johnson & Son, Inc. Produit de pulvérisation avec particules et soupape améliorée pour une distribution inversée sans obstruction
WO2009139862A3 (fr) * 2008-05-14 2010-03-04 S.C. Johnson & Son, Inc. Produit de pulvérisation avec particules et soupape améliorée pour une distribution inversée sans obstruction
US8087548B2 (en) 2008-05-14 2012-01-03 S.C. Johnson & Son, Inc. Spray products with particles and improved valve for inverted dispensing without clogging
WO2014008274A1 (fr) * 2012-07-03 2014-01-09 The Procter & Gamble Company Distributeur de génération de mousse
CN110786345A (zh) * 2019-11-13 2020-02-14 申璐璐 一种天然植物抗菌剂

Also Published As

Publication number Publication date
ATE96699T1 (de) 1993-11-15
US5156307A (en) 1992-10-20
EP0449774A3 (en) 1991-12-11
EP0449774B1 (fr) 1993-11-03
DE59100542D1 (de) 1993-12-09

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